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 CONTENTS
 Mock Test – 1 1 – 13

 Mock Test – 2 1 – 14

 Mock Test – 3 1 – 14

 Mock Test – 4 1 – 12

 Mock Test – 5 1 – 14

 Mock Test – 6 1 – 14

 Mock Test – 7 1 – 12

 Mock Test – 8 1 – 13

 Mock Test – 9 1 – 12

 Mock Test – 10 1 – 13

 Mock Test – 11 1 – 14

 Mock Test – 12 1 – 13

 Mock Test – 13 1 – 12

 Mock Test – 14 1 – 12

 Mock Test – 15 1 – 13

 Solved Papers 2019

– January 1 – 18
– April 1 – 15
 MOCK TEST – 1
5. A stretched rope having linear mass density
PHYSICS (SECTION – A) 5 × 10–2 kg/m is under a tension of 80 N. The power
1. A solid uniform ball of volume V floats on the interface that has to be supplied to the rope to generate
of two immiscible liquids (see the figure). The specific harmonic waves at a frequency of 60 Hz and an
gravity of the upper liquid is 1 and that of lower one 2 2
m is
amplitude of
15
is 2 and the specific gravity of ball is (1    2 ).
(a) 215 W (b) 251 W
The fraction of the volume of the ball in the upper
(c) 512 W (d) 521 W
liquid is
6. A source of sound of frequency 256 Hz is moving
rapidly towards a wall with a velocity of 5 m/s. If
sound travels at a speed of 330 m/s, then number of
beats per second heard by an observer between the
wall and the source is
(a) 7.7 Hz (b) 9 Hz
(c) 4 Hz (d) none of these
7. Two strings A and B, made of same material, are
stretched by same tension. The radius of string A is
2 2  
(a)  (b)    double of the radius of B. A transverse wave travels
1 2 1 on A with speed vA and on B with speed vB. The ratio
vA/vB is
  1 1
(c)    (d)  (a) 1/2 (b) 2
2 1 2
(c) 1/4 (d) 4
2. A water drop is divided into 8 equal droplets. The 8. In YDSE of equal width slits, if intensity at the center
pressure difference between inner and outer sides of of screen is I0, then intensity at a distance of /4
the big drop from the central maxima is
(a) will be the same as for smaller droplet I0
(a) I0 (b)
(b) will be half of that for smaller droplet 2
(c) will be one-fourth of that for smaller droplet I0 I0
(d) will be twice of that for smaller droplet (c) (d)
4 3
3. A rod of length l and cross-sectional area A has a 9. When resonance is produced in a series L-C-R
variable conductivity given by x = T, where  is a circuit, then which of the following is not correct?
positive constant and T is temperatures in kelvin. (a) Inductive and capacitive reactance are equal
Two ends of the rod are maintained at temperatures
(b) If R is reduced, the voltage across capacitor will
T1 and T2(T1 > T2). Heat current flowing through the
increase
rod will be
(c) Current in the circuit is in phase with the applied
A(T12  T22 ) A(T12  T22 ) voltage.
(a) (b)
l l (d) Impedance of the circuit is maximum.
A(T12  T22 ) A(T12  T22 ) 10. When the current changes from +2 A to –2 A in 0.05
(c) (d)
3l 2l s, an emf of 8 V is induced in the coil. The self-
4. During an adiabatic process, the pressure of a gas induction of the coil is__________
is found to be proportional to the cube of its absolute 11. A letter A (in capital letters) is constructed of a
temperature. The ratio Cp/Cv for the gas is
uniform wire with resistance 1   cm1 . The sides
3 4
(a) (b) of the letter are 20 cm each and the cross piece in
2 3
the middle is 10 cm long. The apex angle is 60°, the
5 resistance between the ends of the legs is
(c) 2 (d)
3 approximately __________
2 MOCK TEST 1

12. A uniform electric field E exists between the plates
of a charged condenser. A charged particle enters
the space between the plates and perpendicular to
E. The path of the particle between the plates is
(a) straight line (b) parabola
(c) circle (d) hyperbola
13. A smooth sphere is moving on a horizontal surface
with velocity vector 2iˆ  2jˆ immediately before it
hits a vertical wall. The wall is parallel to ĵ vector
and the coefficient of restitution between the
sphere and the wall is e = 1/2. The velocity vector
of the sphere after it hits the wall is
(a) ˆi  ˆj (b) ˆi  2ˆj
(c) ˆi  ˆj (d) 2iˆ  ˆj
14. A solid sphere rests on a horizontal surface. A
horizontal impulse is applied at height h from
centre. The sphere starts rotating just after the
application of impulse. The ratio h/r will be
16. The radii of two plantes are respectively R1 and R2
and and their densities are respectively 1 and 2 .
The ratio of the acceleration due to gravity at their
surfaces is
1 2
(a) g1 : g2  :
R12 R22
(b) g1 : g2  R1R2 : 12
(c) g1 : g2  R12 : R2 1
(d) g1 : g2  R11 : R2 2
17. A student performs an experiment to determine the
Young's modulus of a wire, exactly 2 m long, by
Searle's method. In a particular reading, the student
measures the extension in the length of the wire to
be 0.8 mm with an uncertainty of 0.05 mm at a load
of exactly 1.0 kg. The student also measures the
diameter of the wire to be 0.4 mm with an uncentainty
of 0.01 mm. Take g = 9.8 m/s2 (exact). The Young's
modulus obtained from the reading is
(a) (2.0  0.3)  1011 Nm 2

I (b) (2.0  0.2)  1011 Nm 2

h (c) (2.0  0.1)  1011 Nm 2

(d) (2.0  0.05)  1011 Nm 2

R 18. A proton and an  -particle enters a uniform magnetic
field perpendicularly with the same speed. If proton
takes 25 s to make 5 revolutions, then the periodic

2 time for the  -particle would be __________

1
(a) (b) 19. A magnetic needle is kept in a non-uniform
2 5
magnetic field. It experiences
1 2 (a) a torque but not a force
(c) (d)
5 3 (b) neither a force nor a torque
15. A uniform circular disc of radius r is placed on a (c) a force and a torque
rough horizontal surface and given a linear velocity (d) a force but not a torque
v0 and angular velocity 0 as shown. The disc comes 20. A coil of inductance 300 mH and resistance
to rest after moving some distance to the right. It 2 is connected to a source of voltage 2 V..
follows that The current reaches half of its steady state
value in __________
21. In the circuit shown here, the voltage across L and
C are respectively 300 V and 400 V. The voltage E
of the AC source is
0 v0 L

(a) 3v0 = 20r (b) 2v0 = 0r E

(a) 400 V (b) 500 V
(c) v0 = 0r (d) 2v0 = 30r
(c) 100 V (d) 700 V
 MOCK TEST 1 3
22. In a meter bridge experiment, null point is obtained (a) The surface should be rough.
at 40 cm from one end of the wire when resistance
X is balanced against another resistance Y. If X < Y, 2 2P
(b) After 3s of motion the velocity of point A is
then the new position of the null points from the M
same end, if one decides to balance a resistance of (c) Acceleration of the centre of mass is constant
3X against Y, will be close to __________ 2P
and is equal to
23. A particle of mass m moving with a velocity v makes 3M
a head-on elastic one dimensional collision with a (d) All of the above
stationary particle of mass m establishing a contact
with it for extremely small time T. Their force of CHEMISTRY (SECTION – B)
contact increases from zero to F0 linearly in time
T/4, remains constant for a further time T/2 and O
decreases linearly from F0 to zero in further time
T/4 as shown in figure. The magnitude possessed C
CH2  (A)  CHBr3 
Br2
by F0 is 26. KOH

F C
O
F0
Product (A) of the reaction is:
CO2H
(a)

t CO2H
O T/4 3T/4 T CO2H
mu 2mu
(a) (b) (b)
T T
4mu 3mu C – CH3
(c) (d)
3T 4T O
24. Angular acceleration of the cylinder C (mass m, CO–2
radius R) shown in figure is (all strings and pulley (c)
are ideal):
CO–2
m A CH3
(d)
m CO2H
C
27. Give the best conditions for this transformation
m
H3C O
2g 2g OCH3
(a) (b)
3R 5R
2g g H3C OCH3
(c) (d) +
R 2R (a) CH3OH, H (cat), heat
25. A solid cylinder of mass M and radius R is being (b) H2O, H+(cat.), heat
pulled along a horizontal surface on which it performs
(c) Mg, ether, CH3OH
pure rolling, by a horizontal force P applied at its
centre. For this situation, mark the correct (d) SOCl2, CH3OH
statement(s). 28. Which are not cleaved by HIO4?
I : glycerol
M.R II : ethylene glycol
III : 1, 3-propanediol
A P
IV : 2-methoxy propanol
(a) 1, II, III, IV (b) I, II
(c) II, III (d) III, IV
4 MOCK TEST 1
CH3 33. H2C = CH – CH = CH – OMe + H2C = CH – CHO


 (A)
Br H (major )
29. + Nal  product; SN 2
H CH3 CHO OMe
CHO
CH2 CH3
product of the reaction is :
(a) (b)
CH3
I H OMe
(a) (c) (d) OMe
H CH3 CHO
OMe
CH2 CH3
CH3
CHO
H I
(b)
H CH3 CH3
Cl + I  
–
CH2 CH3 34. Cl CH2 C CH2 CH2 DMF

CH3
CH3
I CH3 product; Major product of this reaction is :
(c)
H CH3
CH3
CH2 CH3
(a) l CH2 C CH2 CH2 Cl
CH3
CH3
I H
(d)
CH3 H CH3
CH2 CH3 (b) Cl CH2 C CH2 CH2 I

30. Number of moles of MnO needed to react with 7.5
4 CH3
2
moles of SO 3
in the acidic medium is __________
CH3
31. Correct order of basic strengths of given amines is:
(a) Me2NH > MeNH2 > Me3N > NH3 (Protic solvent) (c) H 2C C CH CH2 Cl
2° 1° 3°
CH3
(b) Et2NH > Et3H > EtNH2 > NH3 (Protic solvent)
2° 3° 1° (d) Cl CH2 C CH CH2
(c) Me3N > Me2NH > Me – NH2 > NH3 (Gas phase)
CH3
(d) All are correct.
32. Compare relative stability of following resonating 35. The gas absorbs 100 J heat and is simultaneously
structure. compressed by a constant external pressure of
O O– 1.50 atm from 8 litres to 2 litre. Hence E will
+ be__________
36. A 100 watt, 110 volt lamp is connected in series with
(i) C (ii) C an electrolytic cell containing cadmium sulphate
solution. What mass of cadmium will be deposited
N N
O by the current flowing for 10 hours? (Given, Atomic
+ mass of Cd = 112.4)__________
37. Standard electrode potential (E°) for OCl– / Cl– and
(iii) C Cl– / Cl2 are respectively 0.94 V and –1.36 V. The
E° value for OCl– / Cl2 will be
N–
(a) (i) > (ii) > (iii) (b) (ii) > (i) > (iii) (a) – 0.42 V (b) –2.20 V
(c) (i) > (iii) > (ii) (d) (ii) > (iii) > (i) (c) 0.52 V (d) 1.04 V
 MOCK TEST 1 5

38. In the reaction, 2SO2(g) + O2(g)  2SO3(g) at

 46. When Cr2 O72  is heated with Cl and conc. H2SO4
t°C., the ratio of number of moles of SO2, O2 and SO3 deep red vapours of chromyl chloride are formed
in the equilibrium mixture is 2 : 3 : 5. If the equilibrium deep red vapours have formula:
pressure be 3 atms., then Kp is __________ (a) CrOCl2 (b) (CrO)2Cl2
 3C(g) + D(g) (c) CrO2Cl2 (d) CrO3Cl
39. For the reaction : 2A(g) + B(g) 
47. The true statement for the acids of phosphorus
two mole each of A and B were taken into a flask. The
H3PO2, H3PO3 and H3PO4 is
following must always be true when the system
(a) Their acidic nature H 3PO 4 < H3PO 3 < H3PO 2
attained equilibrium:
(b) All of them are tribasic acids
(a) [A] = [B] (b) [A] < [B]
(c) The geometry of phosphorus is tetrahedral in
(c) [B] = [C] (d) [A] > [B] all the three acids
40. The degree of dissociation of PCl5 at one atmosphere (d) None of these
is 0.3. The pressure at which PCl5 is dissociated to 48. When light of frequency 3.2 × 10 16 Hz is used to
50% is irradiate a metal surface, the maximum kinetic
(a) 2.73 atm (b) 0.3 atm
3
(c) 0.05 atm (d) 1.67 atm energy of the emitted photoelectron is of the
4
41. 2 moles of a perfect gas at 27°C is compressed energy of irradiating photon, then the threshold
reversibly and isothermally from a pressure of 1.01 × frequency of the metal would be
105 Nm–2 to 5.05 × 106 Nm–2. Maximum work done on
(a) 2.4 × 1025 Hz (b) 2.4 ×1016 Hz
the gas in this process is [log 5 = 0.6990]
(c) 1.6 × 10 Hz
15
(d) 8 × 1015 Hz
(a) – 1.95 ×104 Joule (b) + 1.95 ×104 Joule
(c) – 1.95 ×103 Joule (d) + 1.95 ×103 Joule 48. At pH = pKln + 1 (where Kln = dissociation constant for
indicator) the ratio of [ln–]/[Hln] in the solution is
42. S° will be the highest for the reaction
1  10 
(a) Ca(s)  O2 (g) 
 CaO(s)  1  for this pH the % dissociation of the indicator
2  

(b) CaCO3(s) 
 CaO(s) + CO2(g) is __________
50. For a mixture of two volatile component A and B,
(c) C(s)  O 2 (g)  CO 2 (g)
vapour pressure of solution (in mm Hg) is PS = 210 –
(d) N2(g) + O2(g) 
 2NO(g) 120 XA where XA = mole fraction of A in liquid mixture.
43. The work function of a metal is 4.2 eV. If the Hence, PA and PB (in mm Hg) should be

radiation of 2000 A falls on the metal, then kinetic (a) 210, 120 (b) 90, 210
energy of the fastest photoelectron is (c) 110, 210 (d) 120, 210
(a) 1.66 × 10–19 J (b) 3.22 × 10–19 J
(c) 1.66 × 10–20 J (d) 3.22 × 10–18 J MATHEMATICS (SECTION – C)
44. Among NO3 , AsO33  , CO32  , ClO3 , SO32  , and BO33  7
51. Let f(x) = 3x2 – 7x + a, x > , the value of a such
ions, the non-planar species are 6
that f(x) touches its inverse f–1(x) is
(a) AsO33  , SO32  and ClO3 (a) 3 (b) – 3
(b) NO3 , SO32  and ClO3 16 49
(c) (d)
3 12
(c) CO23  , AsO33  and SO32 
52. If 2f(xy) = (f(x))y + (f(y))x for all x, y  R and f(1) = 3,
10
(d) NO3 , CO32  and ClO3
then the value of  f(r)
r 1
45. MeMgBr + D2O 
 ?
3 10 3 9
Which of the following is product of the above (a) (3  1) (b) (3  1)
reaction? 2 2
(a) CH3OD (b) CH3D 310  1
(c) (d) None of these
(c) CH2D2 (d) CH4 2
6 MOCK TEST 1
53. The fundamental period of the function f(x) = [x] + 1
 1  2 61.  sin4 x  cos4 x dx 
 x  3    x  3   3x  sin 3x  1 is:
   
1  tan2 x  1
1 2 (a) tan 1   c
(a) (b) 2  tan x 
3 3
4  tan2 x  1
(c)
3
(d) None of these (b) tan1   c
 2 tan x 
1
 xn  1  x 1  tan2 x  1
  e , then p is equal to
p
54. If lim  1
x 1 n(x  1)
  (c) tan1   c
2  2 tan x 
n 1 n 1
(a) (b) 1  tan2 x  1
2 2 tan 1 
(d)  c
n3 n3 2  2 tan x 
(c) (d)
2 2 62. If A = {a, b, c, d} and B = {1, 2, 3}, then the number

1/ x
 of on-to function possible from A to B satisfying
55. xlim  tan1 x  is equal to
  2 f  a   1 is __________
 
(a) 0 (b) 1 63. The value of ‘a’ if the line 3x + 4y + a = 0 is a tangent
(c) – 1 (d) 2 to the circle x2 + y2 – 4x + 6y + 9 = 0 is
56. Number of solutions to x + y + z = 10 where 1  x, (a) 4 (b) –16
y, z  6 & x, y, z  N __________
5
57. If f(x) is a continuous function and attains only (c) 16 (d)
2
rational values, also f(0) = 3,
then roots of equation f(1)x2 + f(3)x + f(5) = 0 are 3
64. If eccentricity of a given hyperbola is , then then
(a) imaginary (b) rational 2
(c) irrational (d) real and equal eccentricity of its conjugate hyperbola is

 4
58. Let 1, 2, 3, .... be a sequence with 1 = and (a) (b) 3
3 3
sec n = sec n–1 + 2 cos n–1, n  2. Then 4 < |sec 3
n| < 6, if value of n is (c) (d) 2
5
(a) 13, 14 (b) 4, 5
(c) 15, 16 (d) 26, 27 65. If the equation of a given hyperbola is xy – 3x + 4y –
6 = 0, then the equation of its conjugate hyperbola
59. The value of the expression is
 22  1  5  1  5  (a) xy – 3x + 4y – 18 = 0
sin1  sin   cos  cos   tan  tan  
 7  3 7
(b) xy – 3x + 4y = 0
sin–1 (cos2) is
(c) xy – 3x + 4y + 6 = 0
17
(a) 2 (b) – 2 (d) xy – 3y + 4y – 12 = 0
42
 66. The system of equation |x – 1| + 3y = 4, x – |y – 1|
(c) 2 (d) none of these
21 = 2 has
  x   {x} (a) no solution
 x 1
60. If f(x) =  1 ; then {where [ . ] and (b) a unique solution
  x 1
 x  {x} (c) two solution
2

{ . } represents greatest integer part and fractional (d) more than two solutions
part respectively.]
67. The 1025th term in the sequence 1, 22, 4444,
(a) f(x) is continuous at x = 1 but not differentiable
88888888, ... is
(b) f(x) is not continuous at x = 1
(c) f(x) is differentiable at x = 1 (a) 29 (b) 210
(c) 211 (d) 212
(d) xlim
1
f(x) does not exist
 MOCK TEST 1 7

68. If a1, a2, ..., an are positive real numbers whose 72. Equation of angle bisector of the lines
product is a fixed number c, then the minimum value 3x  4y  1  0 and 12x  5y  3  0 containing
of a1 + a2 + ... + an–1 + 2an is the point (1, 2) is
(a) n(2c) 1/n
(a) 3x  11y  4  0 (b) 99x  27y  2  0
(b) (n + 1)c1/n
(c) 3x  11y  4  0 (d) 99x  27y  2  0
(c) 2nc1/n
(d) (n + 1) (2c)1/n x2 y2
73. If a tangent of slope 2 of the ellipse   1 is
69. The remainder obtained, when 1! + 2! + 3! + ... + a2 b2
175! is divided by 15 is __________ 2 2
normal to the circle x  y  4x  1  0 then the
70. Let A = {x1, x2, x3, x4, x5, x6}, B = {y1, y2, y3, y4, y5, maximum value of ab is __________
y6}. Then the number of one-one mappings from A to 74. The sequence a1, a2, a3 , ..... satisfies a1 = 19,
B such that f(xi)  yi, i = 1, 2, 3, 4, 5, 6 is__________
a9 = 99, and for all n  3, an is the arithmetic mean
71. Sum to infinite terms of the series
of the first n  1 terms. Then a2 is equal to
1  2
3  3  3
cot  1    cot 1  22    cot 1  32    .... (a) 179 (b) 99
 4  4  4
is (c) 79 (d) 59

 75. If p  (~ p  q) is false, the truth values of p & q are

(a) (b) tan1 2
4 respectively:
1 (a) F, T (b) F, F
(c) tan1 3 (d) cot 3
(c) T, T (d) T, F

ANSWERS
1. (b) 2. (b) 3. (d) 4. (a) 5. (c) 6. (d) 7. (a) 8. (b) 9. (d) 10. (0.1H)
11. (26.7) 12. (b) 13. (b) 14. (b) 15. (b) 16. (d) 17. (b) 18. (10s) 19. (c) 20. (0.1 s)
21. (c) 22. (67 cm) 23. (c) 24. (b) 25. (d) 26. (c) 27. (a) 28. (d) 29. (b) 30. (3)
31. (d) 32. (a) 33. (d) 34. (b) 35. (1011J) 36. (19g) 37. (c) 38. (6.94) 39. (b) 40. (b)
41. (b) 42. (b) 43. (b) 44. (a) 45. (b) 46. (c) 47. (c) 48. (d) 49. (91) 50. (b)
51. (c) 52. (a) 53. (b) 54. (a) 55. (b) 56. (27) 57. (a) 58. (b) 59. (a) 60. (c)
61. (d) 62. (12) 63. (c) 64. (c) 65. (a) 66. (c) 67. (b) 68. (a) 69. (3) 70. (265)
71. (b) 72. (b) 73. (4) 74. (a) 75. (T, F)
8 MOCK TEST 1

EXPLANATIONS
1. Let V be the total volume of the ball and v be the 6. For a stationary observer between wall and source,
volume of ball in upper liquid. Then V – v is the volume frequency from direct source is
of lower liquid displaced.
 v 
Using law of floatation, we have   f0
 v  vs 
Vg  v1g  (V  v)2g
Frequency from reflected sound is
V  v1  v2  v2
 v 
  f0
 v  vs 
H2O
So no beats will be heard.
1
v
 v A DB 1
V v 7.  
v B DA 2
Hg
8. Let the intensity of individual waves be I.
Then
or V(  2 )  v(1  2 )

v   2   P
  2
V 1  2 2  1

2. Suppose, R = radius of water drop

y = /4
andr = radius of droplets
4 4 
 3 R  8  3 r
3 3

d O

(Since, volume remains constant)

R
 r2
D
Since, excess pressure inside drop  2T
R

(T-Surface tension, R-radius) I0 = 4I  I  I0

4
 Pressure difference between inner and outer
At P, x = d sin
surface of big drop will be half of that for smaller
dy d  d D 
droplet.  x = d sin  x  D  4  D  4d  4
D
3. Heat current:
2  
dT      4  2 [ = k x]
i  kA , idx  kAdT
dx
 I
l T2 I  I  I  2 I2 cos  2I  0
2 2
i dx   A  TdT
0 T1 9. For L-C-R circuit, the current
(T  T ) E0
sin  t   
2 2
il   A 2 1 i
2 2
2  1 
R   L  
A(T12  T22 )  C 
i
2l
2
At resonance, impedance, Z  R2   L 
1 
4. Given P  T3 . But for adiabatic process P  T  /  1.  
C 
 3 3 Cp
So,   1  3    2  C  2 is minimum   0
v
Also reducing R, will increase the current in the
5. P  1 2 A 2 v where v  T circuit, which thereby increases the voltage
2 
across the capacitor.
 MOCK TEST 1 9

 Y = 2 × 10 × 0.1125 = 0.225 × 10
11 11
10. L  0.1H
i / t
[  The value of Y = 2 × 10111 in all the four options]
11. P

18. 5 
2mp
& T 
2m 2 4mp

 
 2  5  10s
qpB qB 2qp B  
Q R 19. In a non-uniform magnetic field both Force
and Torque are non-zero
A B
PQ, PR, QR, AQ and BR are all of 10 each. Further,,  
20. Use i  io 1  e R t L   io  io 1  e R t L 
2  
PQ and PR are in series, whose combination is in e 
 Rt L 1 L
  t  ln 2  0.1s
parallel with QR. Finally the three resistors are in 2 R

series across A-B. Hence, equivalent resistance 21. The potential difference across inductor and capacitor
across A-B is 26.7 have a phase difference of 180o. Hence, Esource= 400
12. The motion is two dimensional, with constant velocity – 300 = 100 V
along one direction and constant acceleration along
22. At 1st null point: x  40 2
 ........... 1
the other direction. Hence, path is parabolic. y 100  40 3

13. ĵ component, i.e., component of velocity parallel At 2nd null point:

3x l l 200
to wall remains unchanged while î component  2 l  67cm
y 100  l 100  l 3
1
ˆ or . Therefore, velocity vector
will become 2 (2i) ĵ 23. Impulse = area of trapezium
1 T 3TF0
of the sphere after it hits the wall is – ˆi  2jˆ .  T   F0 
2  2 4
14. J = mv ...(i)
According to impuse-momentum theorem.
Jh = I ...(ii) Impulse = Change in momentum
h 2
 3TF0 4mu
R 5   mu  F0 
4 3T
15. Since the disc comes to rest, it stops rotating and   
translating simultaneously v = 0 and  = 0. 24. aA  atrans  arot
That means, the angular momentum about the
instantaneous point of contact just after the time of  a – R
stopping is zero. W e know that the angular
B A m T2
momentum of the disc about P remains constant
because frictional force f N and mg pass through a

point p and thus produce no torque about this point

 Linitial – Lfinal  mvr – l00 = 0
1
 mvr = 2 mr 0  2v 0  0r
2
T1
T2 
16. g  R
mg L m
17. We know that Y 
D2 l

4
a
Y 2D l mg
  T1
Y D l mg

[  the values of m, g and L are exact] a A  a  R

0.01 0.05 aB  a  R
2   2  0.025  0.0625
0.4 0.8
mg  T1  m(a  R) (i)
= 0.05 + 0.0625 = 0.1125
T1 + mg – T2 = ma (ii)
10 MOCK TEST 1
T2 = m(a – R) (iii) O – Me
C O OMe
mR2
T 1R + T 2R =  (iv)
2 33. + CH  


On solving these equations, we get CHO

2g 2g CH2
a , 
3 5R 34. SN2 reaction is favourable at least crowded site.
25. If the surface is smooth, then rolling would not be
35. Q absorb = 100 J
possible without friction. There would not be any
force which would produce some rotational effect. H = +Qabsorb = 100 J
So, surface should be rough. Pext = 1.50 atm
V1 = 8
V2 = 2
R
v E = H + PV
P 
= 100 + 1.50 (8 – 2) = 109
a
36. P = 100 watt
V = 110 volt
Time = 10 hrs = 10  60  60 = 3.6  104 sec
As cylinder is performing pure rolling motion, friction
is static in nature. P=VI
The equation of motion is given as P 100
i= 
P – f = Ma V 110
fR = I Eit 112.4 100 3.6  10 4
W = Zit = 96500 =   = 19.05 gm
a = R 2 110 96500

P Approx = 19 gm
a = I/ R2  M which is a constant.
37. 2e– + OCl–  Cl– E10 = 0.9 V
After 3s,
Cl– + e– = –1.36 V
 P  1
3    t    3  3  
 I/ R  M  R
2
e– + OC– Cl2

 P  G03  G10  G02

v  at  3  
 I/ R  M 
2

– 1  F  = – 2  F  0.94 + –1  F (–1.36)
So, net velocity of point A
E03 = 2  0.94 – 1.36 = 0.52 V
 3 2P
v A  v 2  (R)2 
I/ R 2  M 

38. 2SO2 (g)  O2 (g)  2SO3 (g)
OCH3 2 3 5
27. 

CH3OH
2
O H PSO2  3   0.6
OH 10
3
OCH3 PO2  3   0.9
10

CH3OH
H

OCH3 5
(Acetal) PSO3  3   1.5
10
28. HIO4 will not oxidize diol from 1, 3 atom & not used 2
PSO (1.5)2
for cleavage of ether. KP  3
 = 6.94
2
PSO2  PO2 (0.6)2  0.9
29. Inversion of configuration takes place.
39. 2A(g) 

+ B(g) 
 3C(g) + D (g)
32. (1) Neutral R.S. are most stable.
2 –2x 2–x 3x x
(2) With the increase in charge separation stability
of R.S. decreases, so stability order is (3x)3  x
KC 
(2  2x)2  (2  x)
i > ii > iii
[A] < [B] at equilibrium
 MOCK TEST 1 11


 OD
40.  PCl3  Cl2
PCl5 
1 0 0 45. CH3MgBr + D2O  CH3D + Mg

(1   )   Br
2
46. CrO2Cl2 (chromyl chloride)
   2 (1   )  2P
Kp    P   O O O
 1   (1   )P (1   2 )
since  = 0.3 at 1 atm pressure P P P

0.3  0.3  1 0.09 9  10 2 9 47. H H OH HO OH H

Kp     HO OH OH
1  0.09 0.91 91 10 2 91 (H3PO2) (H3PO3) (H3PO4)
9 3
Kp  48. E = E0 + E
91 4
when  = 50% = 0.5, the pressure can be calculated 1
as follows E0 = 1 E or 0  
4 4

 2P 1
Kp  0 = 4  3.2  1016  8  1015
(1   2 )
50. Ps = PBo  PAo  PBo  X A
9 0.5  0.5  P 0.5  0.5 P
 
91 (1  0.52 ) 0.75 Comparing it with given equation, we get

9  0.75 PBo  210 and PAo  90

or P   0.297  0.3 atm
91 0.5  0.5
7
41. For an isothermal reversible process involving a 51. f(x) = 3x2 – 7x + a, x > 6
perfect gas, work done on the system is a +ve
quantity. f(x) is invertible in its domain, and it is increasing in
7
5.05  106 x > 6 . Since f(x) touches its inverse, it means f(x)
w = 2.303 × nRT log
1.01 105
touches y = x line.
= 2.303 × 2 × 300 × 8.314 log 50  3x2 – 7x + a = x has only one root
= 2.303 × 2 × 300 × 8.314 × 1.6990 3x2 – 8x + a = 0
= 4.606 × 2494.2 × 1.6990 D=0
= +1.95 × 104 Joules 64 – 12a = 0
42. solid  solid + gas has the maximum S°.
16
43. Work function of a metal = 4.2 eV  a= 3

E0 = 4.2 × 1.6 × 10 –19 J 52. From given functional equation 2f(xy)

= 6.72 × 10 –19 J = (f(x))y + (f(y))x,  x, y  R
Energy absorbed by the electron: putting y = 1
6.63  10  3  10
hc 34 8
2f(x) = f(x) + (f(1))x
E = h =  , E
2000  10 10 f(x) = 3x
6.63  3  10 26 10 10
3(310  1) 3 10
   f(r)   3r   (3  1)
2  10 7 r 1 r 1 3 1 2
E = 9.94 × 10 –19 J
53. f(x) = [x]   x     x    3x  sin3x  1
1 2
Kinetic energy of the photoelectron emitted  3  3
= E – E0
= (9.94 – 6.72) × 10 –19 J 1  1 2  2
 x  {x}  x   x    x    x    3x  sin3x  1
3  3 3  3
= 3.22 × 10 –19 J
  1  2 
44. AsO33   tetrahederal; SO23   tetrahederal  sin3x   x  x     x   
  3  3 
ClO3  tetrahederal; CO32   trigonal planar
2
 3
sin 3x is periodic with period 3
NO  trigonal planar; BO
3 3  trigonal planar
12 MOCK TEST 1

 1  2 1  22 5   5   
{x}   x     x   is periodic with period 3 59. 3  7   2  3      2
 3  3   7  2
3 5 18  35 17
 Period of f(x) = LCM  ,  
2 1 2
  2 2 2
3 3 3 7 6 42 42
1
 x  {x}
 (x  1)(x n 1  xn  2  ....  1)  x 1  x 1
54. lim   (1 form) 60. f(x)   1
x 1
 n(x  1)  x 1
 
1  x  {x}2
 xn 1  x 1  xn1  xn 2  ....  1 n   xn 1 1 xn  2 1 x 1 11  1
lim   lim     

e
lim  1
x 1 n( x  1)
  e
x 1
 n( x 1) 

e
x 1
 x 1 x 1 x 1 x 1  n Consider the function f(x) in the interval (0, 2)
((n 1)  (n  2)  (n  3)  ....  2  1)
1 n 1  x
e n
e 2  0  x 1
f(x)   1
1  2 1 x  2
 1   x  1   x  1
55. Let y  xlim   tan x 

2 
1
f(1) = 1 xlim
1 f(x) = 1
 lim(cot x)
x 
1 x (0° form)
continuous at x = 1
lncot 1 x   form 
lny  xlim  
 x   1 sec 4 x
1
61.  sin 4
x  cos x
4
dx  
tan4 x  1
dx
 lim 
x  (1  x 2 )cot 1 x
Let tan x  t
(1  x 2 )1  0 form 
  lim 0 
x  cot 1 x  
1  t  dt 
1
2x 2 1
t 2 dt
  lim
(1  x 2 )2 x  t4  1
 1
x  1  2 lim t2 
 x  1  x2 t2
1  x2
1
 2 lim 0 1 dt 1  z 
x  2x Let t   z    tan1  c
t 2
t 2 2  2 
y = e° = 1
56. x + y + z = 10
1  t 2  1
number of solution is equal to coefficient of x10 in  tan1   c
2  2t 
expression
 (x + x2 ........x6)3 = x3(1 – x6)3(1 – x)–3 62. No of function = 33  2 C1·23  2 C2 ·13  12
Coeff. of x7 in (1 – x6)3 (1 – x)–3
63. Distance from centre to the line should be equal to
Coeff. of x7 in (1 – 3x6)(1 – x)–3
radius
= 7 + 3 – 1C7' – 31 + 3 – 1C1 = 9C2 – 9 = 27
57. f(x) is a constant function so 6  12  a
d   2  a  6  10  a  6  10
5
f(1) = f(3) = f(5) = f(0) = 3
Now 3x2 + 3x + 3 = 0  x2 + x + 1 = 0  a  16 or  4

This equation has imaginary roots. 1 1 4 1 9 3

64.   1   1  e22   e2 
58. sec 2 n  sec 2 n1  4  4 cos2 n1 e12 e22 9 e22 5 5

65. Equation of pair of asymptops is given by

0 < 4cos2θn-1 < 4
s+l=0
4 + sec 2 θn-1 < sec 2θn < 8 + sec 2θn-1
 xy  3x  4y  18  0

4n < sec 2θn < 8n - 4 for the above equation to represent a pair of lines l
= –6
2 n < | secθn | < 8n - 4
 equation of conjugate hyperbola is
n = 4 4 < | sec θ4 | < 2 7 < 6 s + 2l = 0

n = 5 2 5 < | secθ5 | < 6

xy – 3x + 4y – 18 = 0
 MOCK TEST 1 13

66. The given equations are 69.  5, 6, 7, 8, ..., 175 each multiple of 15
|x – 1| + 3y = 4
and 1  2  3  4  33
 x  3y  5, x  1 ...(i)
  Hence, required remainder = 3.
 x  3y  3, x  1 ...(ii)
70.  f(xi)  yi
andx – |y – 1| = 2 ie, no object goes to its scheduled place. Then
 x  y  1, y  1 ...(iii) number of one-one mappings
 
x  y  3, y  1 ...(iv)  1 1 1 1 1 1
 6 1       
 1 2 3 4 5 6
Solving Eqs. (i) and (iii), we get
x = 2, y = 1 1 1 1 1 1
 6     
 2 3 4 5 6
no solution
= 360 – 120 + 30 – 6 + 1
Solving Eqs. (i) and (iv), we get (  x  1, y < 1)
= 265
x = 2, y = 1
 
 
no solution 71. Tn  cot 1  n2  3   tan1  1

 4 3
 n  
2
Solving Eqs. (ii) and (iii), we get  4
x = 3, y = 2 no solution (  x < 1, y  1)  1  1
 tan1  n    tan1  n  
Solving Eqs. (ii) and (iv), we get  2  2
x = 5/2, y = 3/2 (  x < 1, y < 1) n
 1 1
Sn   tn  tan1  n  2   tan1 2
no solution n 1

Hence, solution is x = 2, y = 1 (a unique solution)  1 1

 S   tan1  cot 1  tan1 2
2 2 2
67. The number of digits in each term of the sequence
are 1, 2, 4, 8, .... 72. Since 3  1  4  2  1 and 12  1  5  2  3 are of the
Which are in GP opposite sign, so required angle bisector is given
by
Let 1025th term is 2n.
Then 1 + 2 + 4 + 8 + ... + 2n–1 < 1025  1 + 2 + 4 + 3x  4y  1  12  5y  3 
  
8 + ... + 2n 5  13 

(2n  1) (2n  1  1) 73. A tangent of slope 2 is y  2x  4a2  b2 this is normal

 1.
(2  1)
 1025  1.
(2  1)
to x2  y 2  4x  1  0 then
 2n – 1 < 1025  2n+1 –1
 2n < 1026  2n+1 0  4  4a2  b2  4a2  b2  16
or 2n+1  1026 > 1024 using Am  GM ab  4
 2n+1 > 210 74. n  3 , a3 = ...(1)
or n + 1 > 10
a4   a4  a3
 n>9
 n = 10 (which is always satisfy Eq. (i)), a5   a4

 1025 term is 2 .
th 10
a3  a4  a5  ....  a9  99
68. Given a1 a2 a3 ... an–1 an = c
put in equation (1)
 AM  GM
99   a2  179
a1  a2  ...  an 1  2an
  (a1 a2 ...an 1 2an )1/ n
n 75. p  (~ p  q) is the false means p is true & ~ p  q is
= (2c)1/n[from Eq. (i)] false
 a1 + a2 + ... + an–1 + 2an  n(2c)1/2  p is true & both ~ p & q are false  p is true & q
is flase
Hence, minimum value of a1 + a2 + ... + an–1 +2an is
n(2c)1/n.
 MOCK TEST – 2
5. The minimum horizontal acceleration of the container
PHYSICS (SECTION – A) so that the pressure at the point A of the container
1. A plank of mass 12 kg is supported by two identical becomes atmospheric is (the tank is of sufficient
springs as shown in figure. The plank always remains height)
horizontal. When the plank is pressed down and
released, it performs simple harmonic motion with
time period 3 s. When a block of mass m is attached
to the plank the time period changes to 6 s. The
mass of the block is_________(kg) 2m a
m
12 kg
A
3m
3 4
(a) g (b) g
2 3
4 3
2. A string of length 2L, obeying Hooke’s law, is stretched (c) g (d) g
2 4
so that its extension is L. The speed of the transverse
6. Two rods of length L 2 and coefficient of linear
wave travelling on the string is v. If the string is further
expansion 2 are connected freely to a third rod of
stretched so that the extension in the string becomes
length L1 of coefficient of linear expansion 1 to form
4L. The speed of transverse wave travelling on the
string will be an isosceles triangle. The arrangement is supported
on the knife edge at the midpoint of L1 which is
1 horizontal. The apex of the isosceles triangle is to
(a) v (b) 2v
2 remain at a constant distance from the knife edge if
1
(c) v (d) 2 2 v L1  2 L1 2
2 (a) L   (b) L  1
3. Ten tuning forks are arranged in increasing order of 2 1 2

frequency in such a way that any two nearest forks

L1 2 L1 2
produce 4 beats/s. The highest frequency is twice (c) L  2  (d) L  2 
that of the lowest. Possible lowest and highest 2 1 2 1

frequencies are: 7. The relation between the internal energy U and

(a) 40 and 80 (b) 50 and 100 adiabatic constant  is
(c) 22 and 44 (d) 36 and 72
4. In figure, find the total magnification after two PV PV 
(a) U  (b) U 
successive reflection first on M1 and then on M2.  1  1
f = 10 cm f = 20 cm

(d) U  
PV
(c) U 
 PV
8. A solid cylinder of mass M and radius R is connected
to a spring as shown in figure. The cylinder is placed
on a rough horizontal surface. All the parts except
M2 M1 the cylinder shown in the figure are light. If the cylinder
10 cm 30 cm is displaced slightly from its mean position and
(a) + 1 (b) – 2 released, so that it performs pure rolling back and
forth about its equilibrium position, determine the
(c) + 2 (d) – 1
time period of oscillation?
2 MOCK TEST 2

14. A current in a coil of self-inductance 2.0 H is

increasing as i = 2 sin t2. The amount of energy
spend during the period when the current changes
K from 0 to 2 A is _________ (J)
15. A particle of charge q and mass m starts moving
from the origin under the action of an electric field
  
E  E0 ˆi and B  B0 ˆi with a velocity v  v 0 ˆj . The
R speed of the particle will become 2v0 after a time

2mv 0 2Bq
(a) t  (b) t 
qE mv 0
M 3M
(a) 2 (b) 2
k 2k 3Bq 3mv 0
(c) t  (d) t 
3M mv 0 qE
(c) 2 (d) None of these
k
16. An ideal choke takes a current of 10 A when
9. The maximum number of possible interference connected to an ac supply of 125 V and 50 Hz. A
maxima for slit-separation equal to twice the pure resistor under the same conditions takes a
wavelength in Young's Double slit experiment is: current of 12.5 A. If the two are connected to an ac
(a) zero (b) five supply of 100 V and 40 Hz, then the current in series
combination of above resistor and inductor
(c) infinite (d) three
is_________(A)
10. When an unpolarised light of intensity I0 is incident
17. A stone of mass 1 kg tied to a light inextensible
on a polarizing sheet, the intensity of the light which
string of length L = 10/3 m is whirling in a circular
does not get transmitted is path of radius L in a vertical plane. If the ratio of the
(a) I0 (b) zero maximum tension in the string to the minimum
tension is 4 and if g is taken to be 10 m/s2, the
I0 I0 speed of the stone at the highest point of the circle
(c) (d)
2 4 is_________(m/s)
11. An astronomical telescope has a large aperture to 18. Two blocks of masses m1 = 2 kg and m2 = 4 kg are
(a) reduce spherical aberration moving in the same direction with speeds v1 = 6 m/
s and v2 = 3 m/s, respectively on a frictionless
(b) have low dispersion
surface as shown in figure. An ideal spring with spring
(c) have high resolution constant k = 30000 N/m is attached to the back
(d) increase span of observation side of m2. Then the maximum compression of the
12. Light is incident from a medium into air at two spring after collision will be
possible angles of incidence (i) 20° and (ii) 40°. In v1 v2
the medium, light travels 3.0 cm in 0.2 ns. The ray k
will m1 m2
(a) suffer total internal reflection in case (ii) only
(b) have partial reflection and partial transmission in (a) 0.06 m (b) 0.04 m
case (ii)
(c) 0.02 m (d) none of these
(c) have 100% transmission in case (i)
19. Consider a metal exposed to light of wavelength 600
(d) suffer total internal reflection in both cases (i)
and (ii) nm. The maximum energy of the electron doubles
when light of wavelength 400 nm is used. Find the
13. Which of the following are not electromagnetic
waves ? work function in eV.

(a) X-rays (b) Cosmic rays (a) 2.83 eV (b) 2 eV

(c) -rays (d) Ultraviolet rays (c) 1.02 eV (d) 3.42 eV
 MOCK TEST 2 3

20. When uranium is bombarded with neutrons, it CHEMISTRY (SECTION – B)

undergoes fission. The fission reaction can be written
26. In which of following reaction, Markovnikoff’s rule is
as 92 U235  0n1 
56 Ba141  36 Kr 92  3X  Q violated.
(energy) where three particles names X are produced
CH2  
HBr
and energy Q is released. What is the name of the (a) CH 3 O CH CCl4

particle X ?
CH2  
HBr
(a) electron (b)  -particle (b) CH 3 NH CH CCl4

(c) neutron (d) neutrino

CH2  
HBr
21. For the given combination of gates, if the logic states (c) CH 3 S CH CCl4

of inputs A, B and C are as follows. A = B = C = 0 and

CH2  
HBr
A = B = 1, C = 0, then the logic states of output D are (d) O2N CH CCl4

A 27. CH3 – CH = CH2 

Br2 (low conc.)
h
Mg
Dry ether

B O

C D CH3 – C – CH3 H
 (X)
NH4Cl 
(major)
(a) 0, 0 (b) 0, 1
End product (X) of the above reaction is:
(c) 1, 0 (d) 1, 1
22. In the middle of the depletion layer of reverse biased CH2
p-n junction, the (a) CH2 = CH – CH 2 C CH3
(a) electric field is zero (b) H2C = CH – CH = C CH3
(b) potential is maximum
CH3
(c) electric field is maximum
(d) potential is zero OH
23. A positive point charge 50 C is located in the plane (c) H2C = CH – CH2 C CH3
xy at a point with radius vector r̂0  2iˆ  3ˆj . Evaluate CH3

the electric field vector E at a point with radius vector (d) H2C = CH – CH2 – CH – CH2 OH

r  8iˆ  5ˆj , where r0 and r are expressed in meters.
CH3
(a) (1.4iˆ  2.6ˆj)kNC1 (b) (1.4iˆ  2.6ˆj)kNC1
28. Which one of the following reactions is not correct?
(c) (2.7iˆ  3.6ˆj)kNC1 (d) (2.7iˆ  3.6ˆj)kNC1 (a) PbO + 2NaOH  Na2PbO2 + H2O
24. A capacitor of capacitance C 0 is charged to a
(b) PbO + 2HNO3 
 Pb(NO3)2 + H2O
potential V0 and then isolated. A small capacitor C
is then charged from C0, discharged and charged (c) 4BCl3 + 3LiAlH4  2B2H6 + 3AlCl3 + 3LiCl
again; the process being repeated n times. Due to
this, potential of the large capacitor is decreased to (d) Al2S3 + 12H2O  Al2(SO4)3 + 12H2
V. Value of C is 29. Which of the following pairs of compounds is a pair
of enantiomers?
V 
1/ n
 V 1/ n 
(a) C0  0  (b) C0  0   1
 V   V   Br Br

 V  
n
  V n 
(d) C0    1 (a)
(c) C0    1
 V0    V0   Cl Cl
25. In an a.c. sub-circuit (figure), the resistance R = 0.2
. At a certain instant VA – VB = 0.5 V, I = 0.5 A,
I
 8A / s. Find the inductance of the (b)
t
coil_________(H)
A L R B
4 MOCK TEST 2

34. Which curve does not confirm Boyle’s law?

(c)

(a) P
Cl Cl
V
(d)
Cl Cl Cl Cl
(b) P
+ BrMgCH2CH2CH2CH2MgBr  
(i) THF
30. (ii) H O 3


O
O
product; Product of the reaction is : V
O

(a) HO – (CH2)3 C CH2 CH2 CH3

(c) log P
(b)

log V
HO (CH2)3 – OH

(c)
(d) log V

HO CH – CH2 – CH3

OH log P
35. Radial probability distribution curves are the plots of
(d)
R[  4 r 2 dr 2 ] vs distance from the nucleus. The
curve has number of maxima which is different for
HO CH2 – CH2 – CH3 different orbitals. The number of spherical nodes
31. The ratio of Kp/Kc for the reaction present in 3p orbital are_________

1 36. By which of the following reagent butanoic acid

CO(g)  

O2 (g) 
 CO2 (g) can be converted into butane?
2
(a) HI/P red (b) NaOH/CaO
(a) 1 (b) RT
(c) CH3MgBr (d) All of these
(c) (RT)1/2 (d) (RT)–1/2
32. When NH4Cl is added to an aqueous solution of 37. Type of isomerism shown by the product of the
NH4OH, reaction between benzaldehyde and
hydroxylamine is
(a) conc. of [OH–] ions increases
(b) conc. of [OH–] ions decreases (a) Syn and anti geometrical
(b) Position isomerism
(c) conc. of NH4  ions decreases

(c) d and l optical
(d) none of these
(d) conc. of NH4  ions as well as conc [OH–] ions


38. Superphosphate of lime is:

increase
(a) Ca3(PO4)2·CaSO4
33. Which of the following elements have the different
value of electronegativity? (b) Ca(H2PO4)2
(a) Hydrogen (b) Sulphur (c) Ca(H2PO4)2·CaSO4
(c) Tellurium (d) Phosphorus (d) Ca(H2PO4)2·H2O·2CaSO4·2H2O
 MOCK TEST 2 5

39. Which one of the following does not show the Iodoform 44. For the reaction NH3  OCl  N2H4  Cl occurring
test?
in basic medium, the coefficient of N 2H4 in the
(a) Ethanol (b) Propan-1-ol
balanced equation is_________
(c) 2-butanol (d) Acetone
45. 100 mL of 0.1 N Na2S2O3 solution decolourised iodine
40. The IUPAC name of the following complex compound produced by the addition of x g of crystalline copper
is K2[Cr(CN)2O2(O2) NH3]
sulphate (Mol. Wt. = 250) to excess of KI solution.
(a) Potassium amminedicyanodioxoperoxochromate (VI) The value of x is_________(g)
(b) Potassium amminedioxoperoxodicyanochromate (VI) 46. In the reaction Na 2S 2O 3 + 4Cl 2 + 5H 2O 
(c) dipotassium amminedicyanodioxoperoxochromate (VI) Na 2SO 4 + H 2SO 4 + 8HCl
(d) Potassium amminedicyanobis (dioxo) chromate (V) The equivalent weight of Na 2S2O 3 will be [M
NH2 O–H = Mol. wt of Na 2S 2O 3]
(a) M/4 (b) M/8
41. 
(A)
NaNO2 / HCl
(B), (c) M/1 (d) M/2
(mild basic medium) (major)
47. At constant temperature of 273K, 1/V vs P are plotted
CH3 for two ideal gases A & B as shown below. Ratio of
Product (B) of this reaction is: number of moles of gas A and gas B are
CH3 gas B

1 gas A
(a) V
60°

45°
N = N – Ph P
OH
3 1
(a) (b)
1 3
(b)
1 3
(c) (d)
3 1
N=N CH3 48. Phenol is heated with chloroform and alcoholic KOH
when salicyladehyde is produced. This reaction is
OH
known as
(a) Fridel-Crafts reaction
(c) (b) Reimer-Tiemann reaction
(c) Rosenmund reaction
Ph (d) Sommelet reaction
OH
49. In the given diagram a cylinder is divided by partition
P. In compartment A, two gases O2 and O3 are in
(d) equilibrium with each other. The compartment B is
in the state of vacuum. The partition P is removed
N=N CH3
and the equilibrium tends to re-establish. Which of
42. At what temperature, will the average speed of CH4 the following is likely to be observed?
molecules have the same value, as O2 molecules
have at 300 K?
A B
(a) 300°C (b) 300 K
(c) 150°C (d) 150 K
43. When BaCrO4 is used as oxidizing agent in acidic
 
(a) The total pressure, pO2  pO3 , remains alters

medium, the equivalent weight of barium chromate (b) Number of moles of O3 increases
is_________ (c) Number of mole of O3 decreases
[At. wt. of Ba = 137.34; Cr = 52.0; O = 16] (d) Number of moles of O3 remains same
6 MOCK TEST 2

50. A, B, C forms compound in which C follows ccp 56. If f(x) = cosec 2x + cosec 22x + .......... + cosec 2nx
arrangement whileA occupies one third of tetrahederal
and g(x) = f(x) + cot 2nx, then xlim
0
((cos x)g(x) + (sec
2
holes and B occupies th of octahederal holes. The x)cosec x) is equal to_________
5
57. If f(x) is thrice differentiable function with f'"(x0)  0
possible formula of compound will be AnBmCl.
and
Then n + m + l = ________
Lim | f "(x 0  h)  f "(x 0  h) | Lim | f "(x 0  h) |  Lim | f "(x 0  h) |,
h 0 h0 h 0

MATHEMATICS (SECTION – C) then

(a) x0 is a point of extremum
51. If f(x) = [x2] + {x 2 } , where [.] and {.} denote the (b) tangent at x0 lies below the curve
greatest integer and fractional part functions (c) tangent at x0 crosses the curve
respectively, then
(d) none of these
(a) f(x) is continuous at all integral points
2 3 0 
(b) f(x) is continuous and differentiable at x = 0  2 2 
1 sin x - cos x  ,
(c) f(x) is discontinuous for all x  I 58. If A =  then det [adj {adj
cos x cos4 x sin4 x 
2
(d) none of these  
{adj ..........{adj A}}}], (adjoint is taken r times)
52. Let f(x) = sin x
(a) (–1)r (b) 1
 {max.f(t), 0  t  x} for 0  x   (c) r (d) r – 1

g(x) = 1  cos x 59. How many perfect squares are divisors of the product
 for x  
2 1! . 2!. 3! ... 9!?
Then number of points in (0, ) where f(x) is not (a) 504 (b) 672
differentiable is_________ (c) 864 (d) 936
53. f(x)  2 and f differentiable for x  R. If f(1) = 2, and 60. The area of the smaller region in which the curve
f(4) = 8, then f(2) has the value equal to
 x3 x 
(a) 4 (b) 2 y   , where [.] denotes the greatest
 100 50 
(c) 1 (d) 5
integer function, divides the circle (x – 2)2 + (y + 1)2
54. The value of 2 sin x. cos ec 4x dx is equal to = 4, is equal to
2  3 3 3 3 
1 1  2 sin x 1 1  sin x (a) sq. units (b) sq. units
(a) ln  ln C 3 3
2 2 1  2 sin x 4 1  sin x
4  3 3 5  3 3
1 1  2 sin x
1 1  sin x (c) sq. units (d) sq. units
ln  ln C 3 3
(b)
2 2 1  2 sin x 4 1  sin x
61. If a,b,c  R  and a  b  c  6 , then the maximum
1 1  2 sin x 1 1  sin x
(c) ln  ln C value of a·b2 ·c 3 is_________
2 2 1  2 sin x 4 1  sin x
62. The set of values ‘a’ if the roots of the equation ax2
(d) none of these + (3a – 2)x + (a – 3) = 0 are opposite in sign is
x
2t (a) (0, 3) (b) (3, )
55. 0 2[t] dt, where [.] denotes the greatest integer (c) (– , 0) (d) [0, 3]
63. The number of 4 digit numbers in which the digits
function and x  R+, is equal to
are in ascending order is_________
(a)
1
ln 2
([x]  2[x ]  1) (b)
1
ln 2
2x  2[ x]  [x]  64. Number of 4 digit numbers that are divisible by 2 if
repetition of digits is not allowed is
(c)
1
ln 2

[x]  2[ x]  (d)
1
ln 2
[x]  2[x]  1 (a) 1800 (b) 5000
(c) 2520 (d) 2296
 MOCK TEST 2 7

2 2 2 2   x2 
65. 10 C0 10 C1 10 C2  ... 10 C10  71. The domain of the function f  x   sin1  log2   
  2 
  
(a) 220 (b) 20! is

(a)  2,2  (b)  2, 1

(d) 10!
2
(c) 20 C10

66. Let AB be a chord of the circle x2 + y2 = r2 subtanding (c) 1,2 (d)  2, 1  1,2
a right angle at the centre, then the locus of the 72. The number of positive integral solutions of the
centroid of the triangle PAB as p moves on the circle
y3  1 y2z y2 x
is
(a) a parabola (b) a circle equation yz2 z3  1 z2 x  11

(c) an ellipse (d) a pair of straight line yx 2 x2 z x3  1

67. PQ is any focal chord of the parabola y2 = 32x. The is _________
length of PQ can never be less than
sin2 x
(a) 8 unit (b) 16 unit  n cosec 2 x 
(c) 32 unit (d) 48 unit 73. lim  r
x 0 
 


 r 1 
x2 y3 z5
68. The point on the line   at a (a) 0 (b) 
1 2 2
distance of 6 from the point (2, – 3, – 5) is 1
(c) n (d)
(a) (3, – 5, – 3) (b) (4, – 7, – 9) n
(c) (0, 2, – 1) (d) (3, 2, 1)
4  3xn
74. Let x1  1 and xn 1 
2 4 3  2xn
69. If x = y cos  z cos , then xy + yz + zx is
3 3
(a) 2 (b) 1
equal to
(a) – 1 (b) 0 (c) 2 (d) 2 1
(c) 1 (d) 2
75. The function f  x   x is differentiable in
70. The number of real solutions of
1 x
1 
tan–1 {x(x  1)}  sin {x 2  x  1}  is
2 (a) R (b) R  0
(a) zero (b) one
(c) two (d) infinite (c) 0,   (d)  0,  

ANSWERS
1. (36 kg) 2. (d) 3. (d) 4. (c) 5. (b) 6. (d) 7. (a) 8. (b) 9. (b) 10. (c)
11. (c) 12. (a) 13. (b) 14. (4J) 15. (d) 16. (10A) 17. (10m/s) 18. (c) 19. (c) 20. (c)
21. (d) 22. (a) 23. (c) 24. (b) 25. (0.05H) 26. (d) 27. (b) 28. (d) 29. (b) 30. (b)
31. (d) 32. (b) 33. (b) 34. (a) 35. (1, 0) 36. (a) 37. (a) 38. (d) 39. (b) 40. (a)
41. (b) 42. (d) 43. (84.45) 44. (1) 45. (2.5g) 46. (b) 47. (d) 48. (b) 49. (c) 50. (A10B6C15)
51. (c) 52. (0) 53. (a) 54. (a) 55. (b) 56. (2) 57. (c) 58. (b) 59. (b) 60. (c)
61. (108) 62. (a) 63. (126) 64. (d) 65. (c) 66. (b) 67. (c) 68. (b) 69. (b) 70. (c)
71. (d) 72. (3) 73. (c) 74. (a) 75. (a)
8 MOCK TEST 2

EXPLANATIONS
1. Let spring constant of each spring be k, then the A L1/2 D L1/2 B
equivalent spring constant of the two spring system
in parallel is 2 k.
Without mass,
L2 L2
12
T=3s= 2
2k

With mass C

12  m Before expansion: In triangle ADC

T1 = 65 = 2
2k 2
  L
(DC)2 = L22   21  ... (i)
T 1 12  
 
T1 2 12  m
After expansion:
m = 36 kg 2
  L
(DC)2 = [L2(1 +2t)]2 –  1 (1  1t) ... (ii)
T 2 
2. v 

Equating Eqs. (i) and (ii) we get
T can be calculated by using Hooke’s law and on 2 2
L  L 
stretching  also changes. L22   1   [L2 (1   2t)]2   1 (1  1t)
2 2 
3. In ten forks, there are nine intervals
n2 = n11 + 9 × 4 (Also given n2 = 2n1) L21 L2 L2
L22   L22  L22  2 2  t  1  1  21  t
4 4 4
2n1 = n1 + 36
n1 = 36 Hz (Neglecting higher terms)

so n2 = 2n1 = 72 Hz L21 L1 
 (21t)  L22 (2 2 t)  2 2
4. For M1 : V = – 60, m1 = – 2 4 L2 1

For M1 : u = +20, F = 10 7. Change in internal energy

1 1 1 U = cvT
   V  20
V 20 10  U2 – U1 = cv(T2 – T1)
20 Let initially T1 = 0 so U1 = 0 and finally T2 = T and U2
 M2 =  20  1 =U
 M = m1 × m 2 = +2 U  c v T  T  c v 
PV

R

PV
R  1  1
5. Volume equality gives
(As PV = RT, T = PV/R and cv = R/(–1))
8. Let us say in displaced position, the axis of cylinder
a
is at a distance x from its mean position and its
2m h
velocity of centre of mass is v and angular velocity

A
is . Then, as cylinder is not slipping, v = R. In this
3m 3m position, the spring elongates by x.
1 Using energy method we can find frequency of
2 × 3 = 2 h3  h  4 m oscillation very easily.
4 a Total energy of oscillation is
 tan = 
3 g
I2 Mv 2 kx 2
6. The apex of the isosceles triangle to remain at a E  
2 2 2
constant distance from the knife edge DC should
remain constant before and after heating. 2
We have I  MR , so E  3 Mv 2  kx
2

2 4 2
 MOCK TEST 2 9
As no damping forces are present, i.e.,dW = 8t sin 2t dt 2

dE  Total work done,

0
dt t
W   8t sin 2t 2 dt ... (i)
 3  M  2v dv  k  2x dx  0
0

4 dt 2 dt
When I = 0, t = 0
2k 
 a   3M x I = 2A, sint2 = 1 = sin
2

dx
where v and dv  a  t2 
dt dt 2

To solve integral in equation (i), put 2t2 = y

So   2k
3M 4t dt = dy

3M  W  2 sin ydy  2[1  cos y]
T  2
2k  0
0

9. For maxima, the condition is: dsin   n . As = – 2[cos – cos0] = 4 J

d  2  (given), hence, n  2sin  . W=4J
Therefore, n   2,  1 and 0. Hence, possible number   
15. E is parallel to B and v is perpendicular to both.
of maxima’s is five. Therefore, path of the particle is a helix with
10. The intensity of transmitted light is reduced by half. increasing pitch. Speed of particle at any time t is
Hence, the intensity of the light which does not
v  v 2x  v 2y  v 2z (1)
I0
transmitted is remaining half i.e., .
2 Here, v 2y  v 2z  v 02

3  10 2 and v = 2v0
12. Speed of light in the medium   1.5  108 ms 1
0.2  109
Substituting the values in equation (1), we get
Hence, refractive index    of the medium 3mv 0
t
8 qE
3  10
 2
1.5  108 125
16. R  12.5  10 
1 1
Now, sinic    ic  30
 medium air  2 V 125
XL  L  2nL   = 12.5
I 10
(where ic is critical angle).
Hence, total internal reflection occurs for case (ii)  2nL = 12.5
whereas partial transmission and partial reflection 12.5
occurs for case (i). or 2L = 50  0.25
13. Cosmic rays are highly energetic particles  XL = 2L × n = 0.25 × 40 = 10 
travelling through space.
Impedance of the circuit
14. Heat L = 0.2 H, I = 2 sin t2
Z  R2  XL2  10 2 
Induced e.m.f.,
dI d 100 2
E  L   2 (2sin t 2 )  Current =  10 A
dt dt 10 2

= – 4 cos t2 2t 17. m = 1 kg
= 8t cos t (numerically)
2
10
L m
Work done for increasing charge dq 3

dW = Edq = 8t cost2(I dt) Tmax

4 ... (i)
= 8t cost2 2sint2 dt Tmin
= 8t(2 sint2 cost2)dt
10 MOCK TEST 2
  
and VL  VH2  4 gL MN  r  r0  (8iˆ  5ˆj)  (2iˆ  3 ˆj) = (6iˆ  8ˆj)
 
r  r0  6 2  82  10 m
mv H2
Tension at highest point, Tmin =  mg
L  50  10 6 ˆ
E  9  109  (6i  8 ˆj)
mv L2 (10)3
Tension at lowest point, Tmax =  mg 
L E  (2.7iˆ  3.6ˆj)kNC1

m(v H2  4gL) | E |  4500 NC1
=  mg
L
24. Potential of larger capacitor after 1st charging
Now Eq. (i) can be written as
C0 V0
 v 2  4gL   v2  V1 
m H  g  4  m  H  g  (C  C0 )
 L   L 
VH  3gL  10 m / s After second charging
C0 V1
18. At the time of maximum compression, the speeds V2 
(C  C0 )
of blocks will be same. Let that speed is v and
2
maximum compression is x.   C0 
V2    V0
Applying conservation of momentum,  C  C0 
After nth charging,
(m1 + m2)v = m1v1 + m2v2 n
 C0 
 v = 4 m/s Vn    V0
 C  C0 
Applying conservation of mechanical energy,
 1

 V n
1 2 1 1 1 C  C0  0   1
kx  (m1  m2 )v 2  m1v12  m2 v 22  V  
2 2 2 2  

Solving, we get, x = 0.02 m. LdI

25. VA – VB = VL + VR = dt  IR
19. Given
L × 8 + 0.5 × 0.2 = 0.5 V
hc hc 8L = 0.5 – 0.1 = 0.4;
K  ............. 1 and 2K   ........... 2 
600 400
L = 0.05 H
Solve (1) and (2) for 
H – Br + Br +
20. Balance the number of nucleons. 26. H2C = CH – NO2 CH2 – CH2 – NO2
(Stable)

21. The output D =  A  B C   A  B   C for the and

+
combination of gates given: Br – CH2 – CH2 – NO2 CH3 – CH  NO2
(unstable)
Substitute the values of A,B & C given, D will be 1 27. CH3 – CH = CH 2 Br – CH2 – CH = CH 2

 Br2

for both the cases.

 Mg
ether
22. Due to reverse biasing, the width of depletion region + –
BrMg – CH2 – CH = CH2
increases and current flowing through the
p-n junction is almost zero. In this case, electric
field is almost zero at the middle of the depletion O
region. OH
 1 q    1 q 

23. As E (r  r0 )  E . rˆ CH3 – C – CH2 – CH = CH2 

H

CH – CH = CH2
40 (r  r0 )3 4 0 r 2
CH3
Y
28. Al2S3 + H2O  Al(OH)3 + H2S
Me Me
q0
M
r0
29. &
O X

r Me Me
are mirror image and are not super imposable on
Z N
   each other so are enantiomers.
OM  MN  ON
 MOCK TEST 2 11

38. Ca(H2PO4)2·H2O·2CaSO4·2H2O
30. + BrMg – (CH2)4 – MgBr
39. OH
|
O I /OH
O CH3  CH2 
2
 CHI3  HCOO 
Ethanol
O
Propan-1-ol does not give idoform test
 O – (CH2)3
–
– C – CH2 – CH2 – CH2 – CH2 – MgBr
– OH 
|
 CHI3  CH3CH2COO 
I /OH
CH3  CH  CH2  CH3 
2

bu tan  2  ol

O 
– + ||
 CHI3  CH3COO 
O MgBr I /OH
OH CH3  C  CH3 
2
H – +
(CH2)3 – OH  (CH2)3 – O MgBr acetone

V(CH4 ) TCH4 .MO2

32. NH4Cl is added to an aqueous solution of NH4OH. 42. 
V(O2 ) TO2 .MCH4

The common ion NH suppresses the dissociation
4

of NH4OH. Hence conc. of [OH–] ion decreases. TCH4  32 2TCH4

12  
33. Electronegativities of H, Te and P are same namely 300  16 300
2.1 in Pauling scale. Sulphur has the
300  12
electronegativity value of 2.5. TCH4   150 K
2
34. According to Boyle’s Law
43. In acidic medium , CrO24  is converted into
1
P at constant temperature
V [Cr2O7]2–, which undergoes reduction to Cr3+ ion
cons tant 2CrO24   2H  Cr2O72   H2 O
P
V
log P = log(constant) – log V (represents graph C) Cr2O72   14H  6e  2Cr 3   7H2O

or log V = log constant – log P (represents graph D) Therefore, 2BaCrO4 = 6e  or BaCrO4 = 3e–
P
1
. Hence P vs V is a curve but not a straight  equivalent weight of Barium chromate =
V
253.34
line.  84.45
3
35. The number of spherical node = n – l – 1
–3 –2
For 3p orbital, n – l – 1 = 3 – 1 – 1 = 1 44. NH 3  N2H4 (Oxidation)
For 3d orbital, n – l – 1 = 3 – 2 – 1 = 0
2NH3  N2H4 + 2e–
HI/Pr ed
36. CH3CH2CH2COOH 
 CH3–CH2 CH2–CH3
2NH3 + 2OH–  N2H4 + 2H2O + 2e– ... (1)
NaOH
CH3CH2CH2COOH   CH3CH2CH3
CaO 
 1  1
CH3MgBr O Cl  Cl (Re duction)
CH3– CH2CH2 – COOH  CH3CH2CH2COOMgBr  
+ CH4
37. 1
O Cl + 2e–  Cl–1
OH
H C O H C N OCl– + H2O + 2e  Cl– + 2OH–
(in basic medium, OH– will be either in reactant side
+ NH2OH or product side)
Adding (1) and (2),
Anti phenyl aldoxime
or 2NH3 + OCl–  N2H4 + H2O + Cl–
Thus the coefficient of N2H4 is one.
OH
C
45. CuSO4.5H2 O + 2Kl + CuI2 Cu2I2 + I2 + 5H2O + K2SO4
N

H
Hence equivalent weight of CuSO4.5H2O
syn phenyl ketoxime
12 MOCK TEST 2

Molecular Weight sin xdx

=  250 54. I  2 sin x.cos ec 4x dx  2
1 4 sin x cos x cos2x
100 mL of 0.1 N thio  100 ml of 0.1 N CuSO4.5H2O
1 cos xdx
2  (1  sin2 x)(1  2sin2 x)
100  0.1 250  Put sinx = t, then cos x dx
 = 2.5 g of CuSO4.5H2O
1000
= dt
+2 +6
46. Na2S2O3 Na2SO4  I 1 dt
2 (1  t 2 )(1  2t 2 )

 1 2 
   dt   dt [By partial fraction]
in O. state = +4 per atom  1 t
2
1  2t 2 

For two atom = 8

1  1 1 t 2  1 2 t  
   ln  ln  
47. PV = nRT 2  2 1  t 2 2  1  2 t  
 
nRT
P
V 1  1  2 sin x  1  1  sin 
 ln    ln   C
2 2  1  2 sin x  4  1  sin x 
nA slope of gas B tan60 3
  
nB slope of gas A tan 45 1
55. Let n  x n + 1, where n  I, I > 0

49. 

3O2 
 2O3 1 x
x n x
 2t   2t 
I =  2(t )dt   2(t )dt   2{t} dt  n    
On increasing volume reaction moves in backward 0 0 n  ln2 0  ln2 n
direction.
= ln2  2x  2[ x]  [x]
1
50. C = 1
1 8
A 8  56. g(x) = cosec 2x + cosec22x + ......... + cosec 2nx +
3 3
cot2nx
2 8
B 4  
5 5 since cosec  + cot = cot
2
A 8 B 8 C4  A10B 6C15  g(x) = cot x
3 5
lim  cosx-1cotx lim  secx-1 cos ecx
lim  cos x  +  secx 
cotx cosecx
= e x 0  ex 0
x 0
 
 f(x) ; 0  x  2
 cos x sin x tan2 x
lim  lim
   e x 0 1 cos x
 e x 0 sin x(sec x 1)  e0  e0  2
52. a g(x)   1 ; x
 2
 2x 57. Since f'"(x0)  0 and f"(x0+)f"(x0–)  0
sin 2 ; x
  at x0 curve change its curvature
 tangent cross the curve at x = x0
53. Using LMVT for f in [1, 2]  c  (1, 2),
58. |A| = –1  |adj A| = |A|3 – 1 = |A|2 = 1
f(2)  f(1) |adj (adj A)| = |adj A|2 = 1
 f (c)  2, f(2)  f(1)  2 ... (i)
2 1 ........
 f(2)  4 again LMVT in [2, 4]  d  [2, 4], ........
|adj (adj ....... adj A)| = 1
f(4)  f(2)
 f (d)  2 59. We have
42
1! . 2! . 3! ... 9! = (1) (1.2)(1.2.3)...(1.2...9)
f(4) – f(2)  4
= 19 28 37 46 55 64 73 82 91 = 230 313 55 73.
8 – f(2)  4
The perfect square divisors of that product are the
f(2)  4 ... (ii) numbers of the form
from (i) and (ii) f(2) = 4
 MOCK TEST 2 13

22a 32b 52c 72d 63. By selecting any 4 digits out of 1 to 9 in 9C4 ways,
with 0  a  15, 0  b  6, 0  c  2, and 0  d  1. we can arrange them only in one way. Ans 9C4
Thus there are (16) (7) (3) (2) = 672 such numbers. 64. If units place is ‘o’ then no of ways is 9 × 8 × 7
60. Circle has (2, –1) as it's center and radius of this otherwise 8 × 8 × 7 × 4
circle is 2.  total possibilities = 9 × 8 × 7 + 8 × 8 × 7 × 4
Thus, if P(x, y) be any point on it. then x  [0, 4] = 56 × 41 = 2296
3 2 n2 2 2 2
x x 3x 1 65. C0  n C1  n C2  ...  n Cn  2nCn
Let g(x) =   g'(x) =   0  x  0, 4 
100 50 100 50
20
C10
Thus g(x) is increasing in [0, 4].
18 66. Let P  (r cos , r sin )
g(0) = 0, g(4) = .
25 Centroid of PAB is
 18  y
Hence g(x)  0,   x  0, 4    g(x)  0  x  0, 4 .
 25 
B (0, r)
 x3 x 
Thus y =   , simply represents the x-axis.
100 50  P
G
A D B
X
x
 O A(r, 0)

CA = CB = 2, CD = 1
 r  0  r cos  0  r  r sin  
CD 1  G , 
 cos      3 3 
CA 2 3
r  r cos 
2
Let x   3x  r  r cos  ... (i)
3
 ACB 
3
r  r sin 
and y  3
 3y  r  r sin  ... (ii)
1 2
 ACB  .22.sin  3 sq. units
2 3 Squaring and adding Eqs. 9i) and (ii), we get
(3x – r)2 + (3y – r)2 = r2
1 2 2 4 
Area of sector ACB = .2 .  sq. units
2 3 3 2

67. Length of focal chord is a  t  1  , if (at2, 2at) is one

Thus area of smaller segment is  t
extremity of the parabola y = 4ax 2

4 4  3 3
=  3 sq. units
3 3 1
 t t 2 (AM  GM)
b b c c c
61. Apply A.M.  G.M. for the forms as a, , , , , 2
2 2 3 3 3
 a  t  1   4a.
 t
b c
a  2   3  1
Here, 4a = 32
 3   a  b  · c  
2 3 6
2
     
b   2   3   68. DC’s of the given line is
1 2 2
 ab2c 3  108 , ,
3 3 3
62. For roots to be of opposite sign
Hence, the equation of line can be point in the form
c a3
0  0  a   0,3  x2 y3 z5
a a   r
1/ 3 2 / 3 2 / 3
14 MOCK TEST 2

 Point is  2  r ,  3  2r ,  5  2r 
3 3 3 
  
1 x3  1  z3  y3 1  11  x 3  y 3  z3  10

 r6 So solution are (1, 1, 2), (1, 2, 1) or (2, 1, 1)

Points are (4, – 7, – 9) and (0, 1, – 1) sin2 n
73. L  lim 1cosec n  2cosec n  __  ncosec n 
2 2 2

2 4 x 0  
69. x = y cos 3 = z cos 3 = k
sin n
2 4  cosec b cosec n cosec n 
cos cos  1 2  n  1
1 1 1 3 ,1 3 lim       __     1 ·n
 ,  x 0 
 n  n  n  
x k y k z k  
1 1 1 1 2 4 
 x  y  z  k 1  cos 3  cos 3 0
  0  0  0  __  1 ·n  n
0
 
 xy + yz + zx = 0
43 7
 74. We have x1  1, x2  
70. Since, tan–1 x(x  1)  sin1 (x 2  x  1)  32 5
2

   7
1 4  3 
 cos1  2   sin1 (x 2  x  1) 
 4  3x 2  5   41  x
 (x  x  1)  2 x3   2
3  2x 2  7  29
3  2 
1 5
Hence,  (x 2  x  1)
(x  x  1)
2

We can easily verify that xn  xn 1 and hence xn is

or x2 + x = 0
strictly increasing sequence of positive terms. Let
or x = – 1, 0
lim xn  l .
n 
  x2    x2 
71. f  x   sin1  log2     R  1  log2    1 Therefore
  2   2 
    
 4  3xn 
l  lim xn 1  lim  
1 x2 n  n  3  2xn 
   2  1  x2  4  x   2, 1  1,2
2 2
4  3 lim xn 4  3l
72. Multiply by y, z and x in rows 1, 2 and 3 respectively  n  
and then take common y, z and x from column 1, 2 3  2 lim xn 3  2l
n 
and 3 respectively, then
Hence, 3l  2l2  4  3l or
3 3 3
y 1 y y
z3 z3  1 z3  11 l2  2 l 2  xn  0  n 
3 3 3
x x x 1 75. The function f(x) is an odd function with
range  1,1  it is differentiable every where
3
1 0 y
f  x   f 0 1
 1 1 z3  11  C1  C1  C2 and C2  C2  C3  f '  0   lim  lim 1
x 0 x0 x 0 1  x
0 1 x 3  1
 MOCK TEST – 3
PHYSICS (SECTION – A)
1. In a Young’s double-slit experiment setup, source S A
of wavelength 50 nm illuminates two slits S1 and S2 60°
which act as two coherent sources. The source S
oscillates about its own position according to the 6gR
equation y = 0.5 sint, where y is in nm and t in
seconds. The minimum value of time t for which the B
intensity at point P on the screen exactly in front of
the upper slit becomes minimum is_________(s) (a) 0.25 (b) 0.35
(c) 0.45 (d) 0.55
5. Two particles are interacting only because of
P y conservative forces. They complete round trips,
S1
ending at the point from where they started. Over
x this trip
S (a) the total KE might have a different value at the
1 mm beginning and the end
(b) the PE might have a different value at the
S2 beginning and the end

1m 2m (c) the total mechanical energy might have a different

value at the beginning and the end
2. How many photons of a radiation of wavelength = 5 (d) none of the above
× 10–7 m must fall per second on a blackened plate 6. A ring of radius R is first rotated with an angular
in order to produce a force of 6.62 × 10–5 N? velocity 0 and then carefully placed on a rough
(a) 3 × 1019 (b) 5 × 1021 horizontal surface. The coefficient of friction between
(c) 2 × 1022 (d) 1.67 × 1018 the surface and the ring is . Time after which its
angular speed is reduced to half is
3. The fraction of a radioactive material which remains
active after time t is 9/16. The fraction which remains
0 R 0 g
active after time t/2 will be (a) (b)
2g 2R
4 7
(a) (b)
5 8 20R 0R
(c) g (d) 2g
3 3
(c) (d) 7. A uniform sphere of mass m, radius r and moment
5 4
of inertia I about its centre moves along the x-axis
4. Figure shows a smooth vertical circular track AB of as shown in figure. Its centre of mass moves with
radius R. A block slides along the surface AB when velocity = v0, and it rotates about its centre of mass
it is given a velocity equal to 6gR at point A. The with angular velocity = 0. Let L = I0 + mv0r. The
angular momentum of the body about the origin O
ratio of the force exerted by the track on the block
is
at point A to that at point B is
2 MOCK TEST 3

y (c) B and C are transmitted via ground wave while A

via sky wave
(d) B is transmitted via ground wave while A and C
0 via space wave
V0
r 12. The output of OR gate is 1

x (a) if either or both inputs are 1

O
(b) only if both inputs are 1
(a) L, only if v0 = 0r (c) if either input is zero
(b) greater than L, if v0 > 0r (d) if both inputs are zero
(c) less than L if v0 > 0r
13. The transition from the state n = 4 to n = 3 in a
(d) L, for all values of 0 and v0 hydrogen like atom results in ultraviolet radiation.
8. Suppose the gravitational force varies inversely as Infrared raditation will be obtained in which transition?
the nth power of the distance. Then, the time period
(a) n = 2 to n = 1 (b) n = 4 to n = 2
of a planet in circular orbit of radius R around the
sun will be proportional to (c) n = 5 to n = 4 (d) n = 3 to n = 2
(n 1) 14. A radioactive nucleus undergoes a series of decays
(a) Rn (b) R 2
according to the scheme:
(n 1)
   
(c) R 2 (d) R–n A1  A 2  A 3  A 4  A 5
9. A point P is on the axis of a fixed ring of mass M If the mass number and atomic number A1 are 180
and radius R, at a distance 2R from the centre O. A and 72 respectively, these numbers for A5 are:
small particle starts from P and reaches O under
gravitational attraction only. Its speed at O will be (a) 172,68 (b) 171,69
(c) 177,69 (d) 172,69
2GM
(a) zero (b)
R 15. Consider a metal exposed to light of wavelength 600
nm. The maximum energy of the electron doubles
2GM 2GM  1 
(c) ( 5  1) (d) 1   when light of wavelength 400 nm is used. Find the
R R  5
work function of the metal eV_________
10. A gas bubble formed from an explosion under water
16. A pendulum of length L and bob of mass M has a
oscillates with a period proportional to PadbEc, where
spring of force constant k connected horizontally to
P is the static pressure, d is the density of water
it at a distance h below its point of suspension. The
and E is the energy of explosion. Then, a, b, c are,
rod is in equilibrium in vertical position. The rod of
respectively
length L used for vertical suspension is rigid and
1 1 5 massless. The frequency of vibration of the system
(a) 1, 1, 1 (b) , , for small values of  is
3 2 6

5 1 1 1 5 1
(c) , , (d) , , h
6 2 3 2 6 3 
L
k
11. Three waves A, B and C of frequencies 1600 kHz, 5
MHz and 60 MHz respectively are to be transmitted
from one place to another. Which of the following is
the most appropriate mode of communication ?
1 kh 1 mgL  k
(a) A is transmitted via space wave whereas B and (a) gL (b)
2L m 2L m
C via sky wave
(b) A is transmitted via ground wave, B via sky wave mL2 1  kh2 
(c) 2 (d) gL   
and C via space wave mgL  kh 2L  m 
 MOCK TEST 3 3

17. A boy is walking away from a wall at a speed of 23. The amplitude of a damped oscillator decreases to
1.0 m/s in a direction at right angles to the wall. The 0.9 time its original magnitude is 5s. In another 10 s
boy blows a whistle steadily. An observer towards it will decreases to  times its original magnitude,
whom the boy is moving hears 4 beats/s. If the speed where  equals
of sound is 340 m/s, the frequency of whistle (a) 0.7 (b) 0.81
is_________(Hz)
(c) 0.729 (d) 0.6
24. The total energy of a particle, executing simple
harmonic motion is

(a)  x (b)  x 2
Wall
(c) independent of x (d)  x1/2
observer
Boy where x is displacement from the mean position.

18. An electric field is expressed as E  2iˆ  3ˆj. Find 25. A player catches a cricket ball of mass 150 g, moving
the potential difference (VA – VB) between two points at a rate of 20 ms-1. If the catching process is
A and B whose position vectors are given by completed in 0.1 s, the force of the blow exerted by
the ball on the hand of the player is equal
rA  ˆi  2ˆj and rB  2iˆ  ˆj  3k.
ˆ
to_________(N)
(a) – 1 V (b) 1 V
(c) 2 V (d) 3 V CHEMISTRY (SECTION – B)
19. A parallel plate air capacitor is charged to 100 V 26. In which of the following reactions 1, 3-butadiene will
and is then connected to an identical capacitor in be obtained as a major product?
parallel. The second capacitor has some dielectric
(a) Br – CH2 – CH2 – CH2 – CH2 – Br  
(CH3 )3 COK(2 mole)
(CH3 )3 COH
mdium between its plates. If the common potential
is 20 V, the dielectric constant of the medium is
(b) HO – CH2 – CH2 – CH2 – CH2 – OH  
Conc. H2 SO4

(a) 2.5 (b) 4

CH 
H2 (1mole)
(c) 5 (d) 8 (c) H 2C CH C Ni2B

20. In a series RC circuit a steady state charge of 10C (d) All of these
is established in time of 10 ms. If 1 ms is the time
H
constant of the circuit and 3C is the charge at any
Ph H
instant for the growth part then the decay charge in
the circuit is 27. 
NaOEt

major product
(a) qd = 3C (b) qd = 7C
Me Ph
(c) qd = – 3C (d) qd = – 7C NMe3
+
21. If the terminal speed of a sphere of gold (density Major product of this reaction is:
= 19.5 kgm-3) is 0.2 ms-1 in a viscous liquid (density
Ph Ph
= 1.5 kgm-3), find the terminal speed of a sphere of
(a) C C
silver (density = 10.5 kgm-3) of the same size in the
Ph Ph
same liquid.
Ph Ph
(a) 0.4 ms-1 (b) 0.133 ms-1
(b) C C
(c) 0.1 ms-1 (d) 0.2 ms-1 Ph Me
22. Two narrow bores of diameter 3.0 mm and 6.0 mm Ph H
are joined together to form a U-tube open at both (c) C C
ends. If the U-tube contains water, what is the
Me Ph
difference in its levels in the two limbs of the tube?
Surface tension of water at the temperature of Me Me
experiment is 7.3 × 10-2 N/m. Take the angle of (d) C C
contact to be zero and density of water to Ph OEt
be_________(mm) 1.0 × 103 kg/m3. (g = 9.8 m/s2)
4 MOCK TEST 3

28. For the diazonium ions the order of reactivity towards 35. The threshold frequency of a metal ‘M’ is 1.5 × 1015
diazo-coupling with phenol in the presence of dilute s–1. The maximum K.E. of the photoelectrons, when
NaOH is: the metal is irradiated with radiations of frequency
2.5 × 1015 s–1, would be
Me2N
+
N2 O2N N2
+
(a) 6.63 × 10–20 J (b) 1.0 × 10–19 J
(c) 6.63 × 10–19 J (d) 1.0 × 10–18 J
(I) (II)
36. The wave number of the limiting line in Lyman series
of hydrogen is 109678 cm–1. The wave number of the
+ +
CH3O N2 CH3 N2 limiting line in Balmer series of He+ would be
(a) 54839 cm–1 (b) 219356 cm–1
(III) (IV)
(c) 109678 cm–1 (d) 438712 cm–1
(a) I < IV < II < III (b) I < III < IV < II
37. Which is paramagnetic
(c) III < I < II < IV (d) III < I < IV < II (a) N2 (b) O2
29. Which of the following is correct order of mobility of (c) H2 (d) Cl2
ions in aqueous solution?
38. Vander Waal constant ‘a’ related with
(a) Be2+ < Mg2+ < Na+ < K+
(a) Attractive force between the molecules
(b) Be2+ > Mg2+ > Na+ > K+ (b) Repulsive force between the molecules
(c) Na+ > K+ > Be2+ > Mg2+ (c) Volume of the molecules
(d) Na+ < K+ < Be2+ < Mg2+ (d) Eneregy of the molecules
30. Reactivity order among atomic hydrogen (H), 39. A vessel has 6 g of oxygen at pressure p and
molecular hydrogen (H2) and nascent hydrogen ([H]) temperature 400 K. A small hole is made in it so that
is oxygen leaks out. How much oxygen leaks out if the
(a) H2 > [H] > H (b) [H] > H > H2 p
final pressure is and temperature is 300
(c) [H] > H2 > H (d) H > [H] > H2 2
31. Caesium Bromide has CsCl structure (body-centered K_________(g)
cubic type of lattice). Its density is 4.49 g/cm3. The 40. An oxide of a metal (M) contains 40% by mass of
side of the unit cell is_________(A°) oxygen. The metal (M) has a relative atomic mass
of 24. The empirical formula of the oxide is
(Given: Molar Mass of CsBr = 212.8 g/mol)
(a) M2O (b) MO
32. A 4g sample of NH4NO3 is exploded. The total volume
of gas produced at 527°C and 745 torr (c) MO2 (d) M2O3
is_________(L) 41. 20 ml of decinormal HCl solution was added to
10 ml of a decinormal AgNO 3 solution. AgCl was
1 precipitated out and the excess acid was titrated
NH4NO3  2H2O(g)  N2 (g)  O2 (g)
2 against a decinormal NaOH solution. The volume
of NaOH required for this back titration is
33. The wavelength of radiation emitted when an electron
in H-atom makes a transition from an energy level (a) 10 ml (b) 5 ml
with n = 3 to a level with n = 2 is_________(A°) (c) 20 ml (d) 30 ml
34. The very large increase in the rate of the reaction 42. Which of the following isomeric hydrocarbons is most
due to rise in temperature is due to acidic?
(a) lowering of activation energy
(a) (b)
(b) increase in collision frequency
(c) significant increase in the number of effective
collisions
(c) (d)
(d) increase in Arrhenius constant
 MOCK TEST 3 5

43. The major product formed during the reaction of 47. Consider the following reactions:
1-methyl cyclopentene with CF3CO3H is
CH3ONa
CH3 A
CH3 CH3OH
(a) (b) H3C CH3
OH
OH C C
CH3
CH3 H2SO4
CH3 H O B
(c) (d) CH3OH
O and choose correct answer ?
OH (a) A and B both are CH3 CH C(CH3) 2
44. Among the given halides, which one will give same
product in both SN1 and SN2 reactions. HO OCH3
CH3 CH3
(I) CH3 – CH2 – CH – CH – CH3 (b) A and B both are CH3 CH C
CH3
H3CO OH
Br
CH3 CH3
(c) A = CH3 CH C ;
(II) CH3
H3CO OH
Cl
CH3
Cl
B = CH3 CH C
(III) CH3
HO OCH3
(IV) CH3 – CH – Br (d) A = CH3 CH C(CH3) 2; B = CH3 CH C(CH3)2

Et HO OCH3 H3CO OH
(a) (III) only (b) (I) & (II)
48.
(c) (III) & (IV) (d) (I), (III) & (IV)
H2 C CH3
45. In the following there are three carbon
OH
oxygen bonds are denoted by x, y and z.
Their lengths are in order. (A)

O H2 C CH2 OH
x CH CH2
H3C C O CH3
y z
(B)
(a) x = y = z (b) x < y < z
(c) x < y = z (d) z < y < x OH
CH CH3
46. A compound 'X' having molecular formula,
C4H10O gave on oxidation a ketone (C 4H 8O). (C)
Which of the following is the structure of 'X'?
(a) CH3   CH2   OH Which of the following reagent gives major product
3
"B"
(b)  CH3 2 CHCH2  OH (a) H2O/H+
(b) (i) BH3/THF (ii) H2O2/OH-
(c) CH3  CH  OH CH2  CH3 (c) (i) Hg(OAC)2 (ii) NaBH4
(d) All of the above
(d)  CH3 3 C  OH
6 MOCK TEST 3

49. Ozonolysis of C7H14 gave 2-Methyl-3-pentanone. The 57. The sum of series 84C4 + 6. 84C5 + 15. 84C6 + 20. 84C7
alkene is: + 15. 84C8 + 6. 84C9 + 84C10 is equal to
(a) 2-ethyl-3-methyl-1-butene (a) 86C10 (b) 88C10
(b) 3-ethyl-2-methyl-3-butene (c) C10
90
(d) 90C12
(c) 2,5-dimethyl-3,4-dimethylhex-3-ene
(d) 3-ethyl-2-methyl-1-butene 58. Let P =
50. How many different octahedral complexes of Co 3+

are possible using only ethylenediamine and/or 5a2 + 2bc 6 8  a2 + 6ab 3 5 
   
Cl– ion as ligands_________  13 8b2 - 10ac - 9  , Q =  12 - b2 6  ,
   1 4 17bc 
MATHEMATICS (SECTION – C)  -7 5 25c 2  

/2
a, b, c  N. if trace(P) = trace (Q) and a, b, c are
sides of ABC with BC = a, CA = b and AB = c,
51. 
 / 2
[tan x]dx, (where [.] denotes the greatest integer
then cos A is (trace (P) = sum of principal diagonal
function) is equal to elements of matrix P)
(a) irrational number (b) positive real number 79 89
(c) rational number (d) none of these (a) (b)
120 120
52. If Ai is the area bounded by |x – ai| + |y| = bi i  N,
33 31
3 b (c) (d)
where a i+1 = ai  bi and bi1  i , a 1= 0 and 40 40
2 2
b1= 32, then
x2 y2
(a) A3 = 64 (b) A3 = 256 59. If a tangent of slope 2 of an ellipse   1, (a, b
a2 b 2
n
8 n
4 > 0) is normal to circle x2 + y2 + 4x + 1 = 0 then area
(c) nlim

 Ai 
i 1 3
(32)2 (d) lim  A i  (16)2
n 
i 1 3 of the locus of (a, b) is
(a) 64 (b) 16
53. Solution of the differential equation
(c) 8 (d) 2
2
d y  dy
2
 60. The numbers 2, 3, 4, 5, 6, 7, 8 are to be placed, one
x 2y  x  y   0 is
dx 2  dx  per square, in the diagram shown so that the sum
of the four numbers in the horizontal row equals 21
(a) y  x(c 2 x  2c1 ) (b) y  x(c1  2c 2 x )
2 2 and the sum of the four numbers in the vertical column
also equals 21. In how many different ways can this
(c) y  x(c 2 x  2c1 ) (d) y  x(c 2 x  2c1 )
2 be done_________

54. If 2x2 + y2 – 2xy – 4y + 8 = 0 then pair (x, y) is

(a) (2, 4) (b) (8, 4)
(c) (4, 2) (d) none of these
55. Value of k so that equation (x2 – 2x)2 – 3(x2 – 2x) +
(k + 2) = 0 has four real solution

 1  1
(a)  2,  (b)  6, 
 4  4 61. The locus of z if z  i  z  i  4 is
(c) (– 6, – 2) (d) not possible (a) line segment (b) ellipse
56. The equation of the curve satisfying the differential (c) hyperbola (d) null set
equation y2(x2 + 1) = 2xy1 passing through the point
(0, 1) and having slope of tangent at x = 0 is 3, is 62. The period of the function y  f  x  if
(a) y = x2 + 3x + 2 (b) y2 = x2 + 3x + 1
f  x   f  x  2   2·f  x  1 is_________
(c) y = x3 + 3x + 1 (d) y = x3 – 3x + 1
 MOCK TEST 3 7

63. The set of values of ‘a’ if the function 69. Two small squares on a chess board are chosen at
random. Probability that they have a common side is

y  cot 1 x 2  2x  a   
; R   0,  is an on-to
 2
1 1
(a) (b)
3 9
function is
1 5
(a) {1} (b) (1, ) (c) (d)
18 18
(c) [1, ) (d) R
70. The number of integral values of m for which the x
64. The value of ‘a’ if the line 2x – 3y + a = 0 is a tangent coordinate of the point of intersection of the lines
to the parabola x2 = 8y 3x + 4y = 9 and y = mx + 1 is also an integer
(a) 9 (b) 3 is_________
nx
8 8  a1/ x  a1/2 x  ...  a1/x 
(c) (d) 71. The value of lim  1 n

3 9 x   n 
 
65. The locus of point whose chord of contact subtends a  a ... an
a right angle at the centre of the circle x2 + y2 = a2 (a) a1  a2  ...  an (b) e 1 2
is
a1  a2  ...  an
(a) x2 + y2 = 2a2 (b) x2 – y2 = a2 (c) (d) a1 a2 .... an
n
(c) x2 + y2 = 4a2 (d) xy = a2
72. A window is in the shape of rectangle surmounted by
66. The value of a semi circle. If the perimeter of the window is of fixed
 30   30   30   30   30   30   30   30  length 'l' then the maximum area of the window is
               ...      ,
0 10 1
         11 2 12  20   30  l2 l2
(a) (b)
2  4 8
n
where    n Cr , is l2 l2
r  (c) (d)
2  8 8  4
73. A point 'P' is given on the circumference of a circle
 30   30 
(a)   (b)   of radius 'r'. The chord 'QR' is parallel to the tangent
 10   15  line at 'P' the maximum area of the triangle PQR is

 60   31 3 2 2 3 3 2
(c)   (d)   (a) r (b) r
 10  4 4
 30 
3 2 3 2
67. The equations x – y = 2, 2x – 3y = –, 3x – 2y (c) r (d) r
8 4
= – 1 are consistent for
x 1
(a)  = – 4 (b)  = – 1, 4 74. The number of critical point of f  x  
x2
(c)  = + 1 (d)  = 1, – 4 is_________
 1 0 1 1
68. If A    and A = 8A + kI2, then k is equal to
2
1 1
 cot (1  x  x )dx    tan xdx , then '' is
2
 1 7  75. If
(a) – 1 (b) 1 0 0

(c) – 7 (d) 7 equal to_________

8 MOCK TEST 3

ANSWERS
1. (15) 2. (b) 3. (d) 4. (d) 5. (d) 6. (d) 7. (d) 8. (b) 9. (d) 10. (c)
11. (b) 12. (a) 13. (c) 14. (d) 15. (1.02 eV) 16. (d) 17. (680Hz) 18. (a) 19. (b) 20. (b)
21. (c) 22. (5 mm) 23. (c) 24. (c) 25. (30M) 26. (d) 27. (c) 28. (b) 29. (a) 30. (d)
 
31. (4.3 A ) 32. (11.75L)33. (6560 A )34. (c) 35. (c) 36. (c) 37. (b) 38. (a) 39. (2g) 40. (b)
41. (a) 42. (b) 43. (c) 44. (c) 45. (b) 46. (c) 47. (c) 48. (b) 49. (a) 50. (c)
51. (a) 52. (c) 53. (c) 54. (a) 55. (b) 56. (c) 57. (c) 58. (b) 59. (d) 60. (5)
61. (b) 62. (8) 63. (a) 64. (c) 65. (a) 66. (a) 67. (b) 68. (c) 69. (c) 70. (72)
71. (d) 72. (c) 73. (b) 74. (2) 75. (2)

EXPLANATIONS
A
1. y  , at point P exactly in front of S1
2 Since F  P  n h
2
t 
yd d
x  
D 2D
 n  F
P h

S1
6.62  10 5  5  107
y n=  5  10 21
S 6.62  10 34
y
t
9  1 T
3.  
16  2 
S2
t
N  1  2T

N0  2 
D D


For minimum intensity, x = (2n – 1) (n  1) N
2 t
N
2
2  1 T 9
    or   
N
 0 2 N
 0 16
Putting the values, we get
500
(0.5 sin t) × 10–6 + 0.25 × 10–6 = 2  10
9
N 3
or 
N0 4
0.5
0.5 sin t + 0.25 = 2 Note the special technique used in the problem.
sin t = 0  t = 0, , 2, ... mv 2A
4. NA  mg cos 60 
 t=1s R

2. As seen the momentum of photon = h/ mv 2A

NA   mg cos 60  6 mg  0.5 mg  5.5 mg
If n is the number of photons falling per second on R
the plate, then total momentum per second of the
incident photons is 1 1
mv 2A  mgR(1  cos60)  mv B2
2 2
h
P  n
  1
v 2A  2gR  1    v B2
Since the plate is blackened, all photons are  2
absorbed by it.
vB2  9gR  v B  9gR
P h
n
t  mvB2
NB  mg   10 mg
R
 MOCK TEST 3 9
2
mv /R Gravitational potential at 'P'
GM
A A vp 
N 5R
60°
N Gravitational potential at 'O',
mg cos 60° 60°
6gR 2
mvB/R  v0   GM
mg R
B
5. Factual. Using work energy theorem,
6. Taking  about CM W  K  m[vP  v 0 ] 
1
mv 2
2

 GM GM  1
m    mv
2

 R 5R  2

2GM  1 
1  V
R  5
mg
10. Let T  PadbEc
mgR = MR  2
Writing dimensions on both sides.
g = R
[M0L0T] = [ML–1T–2]a[ML–3]b[ML2T–2]c
g [M0L0T] = Ma+b+cL–a–3b+2cT–2a–2c

R
Thus, a + b + c = 0, – a – 3b + 2c = 0, – 2a – 2c
g 
  0  f 0 =0
R 2
on solving these equations, we get
0 g R
 ff  0
2 R 2g 5 1 1
a ,b  and c 
6 2 3
7. Y 11. For ground wave propagation, the frequency range
is 530 kHz. For sky wave propagation, the frequency
range is 1710 kHz-40 MHz. For space wave
0 propagation, the frequency range is 54 MHz-4.2
v0 GHz.
R 12. The truth table of OR gate is
X
O INPUTS OUTPUTS
   
L  R  mv 0  I0 X Y Z

 mv 0r  I0 (which is constant) 0 0 0

8. T  2R 1 0 1
v
0 1 1
1/ 2
1 GMm  2GM 
E  mv 2  n 1 or v   n 1  1 1 1
2 R R 
13. Energy of infrared radiation is less than the energy
 2R 2
T   R(n  1) / 2 of ultraviolet radiation. In options (a), (b) and (d),
2GM / Rn 1 2GM
energy released will be less.
 T  R(n 1) / 2 14. Mass number will decrease by 8(= 4 + 4 + 0) and
atomic number will decrease by 3(= 2 + 2 – 1)
9. M, R
hc
5R 15. E …(1)
 600 nm
m
P
hc
O and    2E …(2)
 400 nm
Solving (1) and (2) we get   1.02 eV
10 MOCK TEST 3
16. The extension developed in the string due to small
2 1

values of ‘’ is VB  VA     2dx   3dy 
1 2 
x = h sin   h
Torque about ‘O’ VB – VA = – [2(2 – 1) + 3(1 – 2)]
VB – VA = – [2 – 3] = 1 V
Hence, VA – VB = – 1 V
19. c1 = c, c2 = KC, 1  100 V

L VC = 20 V, V2 = 0
C  100  KC  0
20 
kx C  KC
K=4
20. qg + qd = q0 = 10C  qd = 7C
mg sin 2r 2      g
21. As terminal velocity, VT  where,
9
mg
  density of material of the body,   density of
0 = (Mg sin)L + (kx)h liquid
or 0  MgL + kh2 = (mgL + kh2) From the above equation:
Also0 = I0 = mL2 VT  Ag   Ag   10.5  1.5
  VT  Ag   0.2  0.1ms1
From Eqs. (i) and (ii), VT  Au  Au   19.5  1.5
mL2 = (mgL + kh2) 22. Height (h) of water column rise in the tubes:
1 kh2  2Scos 
  2  gL   h where, S-Surface tension,   Angle of
L  m  gr
Now
contact,   density of liquid, r-radius of tube
 
T  2  2
  
1
 gL 
kh2 
 The height difference, h  h1  h2  2Scos   1  1 
L2  m  g r r  1 2 

1 1  kh  2
 bt 
v   gL    
T 2L  m  23. Amplitude of damped oscillator, A  A oe  2m 

17. The frequency of direct sound of whistle heard by  5b   5b 

   
observer is After 5s, 0.9A o  A oe  2m   0.9  e  2m  ...................
1
v 340 340 After 10 more seconds,
n1  n n  n ... (i)
v  vs 340  1 339
3
 15b     5b  
Frequency of sound of whistle reflected by wall is  
 A o  e  2m    A o  0.9   0.729A o
3
A  Ao e  2m 
 
v  v0 340  1 339  
n2  n n n ... (ii)
v 340 340
Given, n1 – n2 = 4 1
24. Total energy of a particle in SHM is : m2 A 2 , which
2
340 339 is constant.
Therefore, 339 n  340 n  4
p 0.15  20
25. F    30N
 1  1  n  1  1  n  4 t 0.1
339  
340 
26. In (a) E2 reaction take place
  1 1 
In (b) dehydration take place
n  4
 339 340 
In (c) alkyne is more reaction then alkene toward
4  339  340 catalytic reductions
 n  680 Hz
679
27. The reaction was shown to be second-order (hence
f the bimolecular mechanism), and it was also shown
18. Vf  Vi   (Ex ˆi  Ey ˆj  Ezk).(dxi
ˆ ˆ  dyjˆ  dzk)
ˆ
that the erythro form of the ion gave the cis alkene,
i
whereas the threo form gave the trans alkene (for
f f f
 the meanings of these prefixes). These results are
VB  VA     E x dx   E y dy   E z dz 
i i i  in keeping with trans elimination.
 MOCK TEST 3 11

28. More electron withdrawing group, more will be v  R  109678 cm–1

electrophilic nature.
for the limiting line of Balmer Series of He+
29. Effective size of cations in aqueous medium
n1 = ?, n2 = , ZHe  ?
cationic charge

cationic size 2
1 RZHe R  4
v    R = R = 109678 cm–1
 n12 4
1
Mobility 
Effective size 37. O2 is paramagnetic O2 (16)  1s2, *1s2 , 2s2,
*2s2 , 2pz , 2p  2p ,  * 2p x   * 2p y
2 1 1 11 1 1
30. Activities of nascent hydrogen depends upon the x y

reaction by which it is obtained (due to different

unpaired e– = 2
amount of energy).
6
212.8
31. Molar Volume = 4.49  47.39 cm
3 39. WO = 6 gm n1 
2 32

(6.023 × 1023 molecules) corresponds to 47.39 cm3 P1 = P

1 molecule corresponds to = T1 = 400 K
P2 = P/2
47.39
 7.868  1023 cm3
6.023  1023 T2 = 300 K
 side of unit cell = (7.868 × 10–23)1/3 P1V1 P2 V2
 V1 = V2 (given)
= 4.285 × 10 cm –8 n1T1 n2 T2

or 4.3 A° n1 P1T2 P  300 6

  
n2 P2 T1 P 4
4  400
32. 80 mole of NH4NO3 gives = 3.5  4  0.175 moles of 2
80
4 6 4 1
gases n2  n1    
6 32 6 8
P1V1 P2 V2 760  3.92 745  V2 6 1
Now  or  moles of oxygen leaks out = 
T1 T2 273 800 32 8
64 2
or V2 = 11.72 L 
32 32
1 1 1
33.  R 2  2  2
  n1 n2  WO2 leaks out =  32  2gm
32
 1  1
= 1.0974 × 107  22  32  40. Wt. of metal (M) = 100 – 40 = 60 g
 
= 0.1525 × 107 m –1 Wt. of oxygen = 40 g
Relative mass of the metal = 24
1
   6.56  107 m = 6560 A°
0.1525  107 60 40
Relative ratio of atoms of M : Oxygen = 24 : 16
35. 0 = 1.5  1015 s–1
5 5
 = 2.5  1015 s–1  :  1: 1
2 2
KEmax = h ( – 0) Hence empirical formula of the oxide is MO.
= 6.63  10–34 (2.5  1015 – 1.5  1015)
= 6.63  10–34  1.0  1015 41. No. of milli equivalents of HCl = 20  1  2
10
= 6.63  10–19 J
No. of milli equivalents of AgNO 3 = 10  1  1
1 1 1 10
36. v   RZ2  2  2 
  n1 n2 
1
No. of milli equivalents of NaOH = V   0.1 V
for limiting line of Lymar Series of Hydrogen 10

n1 = 1, n2 = , ZH = 1 Since total HCl reacted with AgNO 3 as well as

NaOH
2
1 RZH
v  2 = 109678 cm–1 2 = 1 + 0.1 V or 0.1 V = 1 milli equivalent or
 n1
V = 10 ml
12 MOCK TEST 3

H –
42. 


 32
1
Ai  (2bi )2  2(bi )2
2 48 72 80
Non aromatic
"So" Above compound is acidic.

– A i 1 2(bi 1 )2 1
 
Ai 2(bi )2 4

So the area from a GP series
Aromatic anion So the sum of the GP upto infinite terms
44. In III & IV No. rearrangement of C takes place so +
A1 1 8
SN1 and SN2 products are same.  2(32)2 .  (32)2 sq. units
1 r 1
1 3
4
 
O  O– 
   2

53. x 2  y d y2   dy    2xy dy  y 2  0
2
||   |
45. CH3  C  O  CH3  CH3  C  O  CH3  dx  dx   dx

More stable structure Less stable structure dy
2 2xy  y2
d2 y  dy  dx
y 2    0
dx  dx  x2
OH O
| || d  dy  d  y 2 
O   
46. CH3  CH  CH2  CH3   CH3  C  CH2  CH3 y  0
dx  dx  dx  x 

47. In acidic medium It follows through carbocation dy y 2

 y  c
mechanism dx x

CH3 put y = t
2

| O3 / Zn
49. CH2  C  CH  CH3   HCHO
| H2O  2y dy  dt
C2H5 dx dx

O 1 dt t
||  c
2 dx x
 C2H5  C  CH  CH3
|
CH3 dt 2t
  c1
dx x
/2
51. I    tan(0  x) dx 2
I.F  e  x  2
 / 2
 dx 1
x
/2
I    tan x  dx t c
x2  x 2
 / 2  1 dx

/2 /2
2I    tan x     tan x dx
 / 2
 
 / 2
1 dx t c
  1  c2
x2 x

2I    x   / 2  
/2

y 2 c 2 x  c1

I = – /2 x2 x

3 y   x(c 2 x  c1 )
52. a1= 0, b1= 32, a2 = a1 + b1  48
2
54. 2x2 + y2 – 2xy – 4y + 8 = 0
b2 
b1 3
 16, a3  48  .16  72, b3  8  4x2 + 2y2 – 4xy – 8y + 16 = 0
2 2
(2x – y)2 + (y – 4)2 = 0
So, the three loops from i = 1 to i = 3 are alike now
 2x – y = 0
1
area of i loop (square) =
th (diagonal)2 andy = 4(x, y)  (2, 4)
2
 MOCK TEST 3 13

55. x2 – 2x = t  – 1
a1
t2 – 3t + (k + 2) = 0 a2
for four real solution t must lies in (–1, ) 60. a5 a3 a6 a7
D = 9 – 4(k + 2) > 0 a4

9 – 4k – 8 > 0 (a1 + a2 + a3 +a4) = 21,

1 a5 + a3 + a6 + a7 = 21,
4k < 1  k  4
a1 + a2 + a3 + a4 + a5 + a6 + a7 = 35
f(–1) > 0  a3 = 7, a1 + a2 + a4 = 14, a5 + a6 + a7 = 14
1+3+k+2>0 a1, a2, a4  {2,4,8}, a5, a6, a7  {3,5,6}
k>–6 or

so k   6, 1  a1, a2, a4  {3,5,6}, a5, a6, a7  {2,4,8}

 4
Required number of ways = (3! × 3!) + (3! × 3!) = 72
2
56. d y2  x2  1  2x dy 61. If PA + PB = k, where k > AB, then locus of Z is
dx dx ellipse
d2 y
62. f  x   f  x  2   2·f  x  1
dx 2 dx  2x  dy 

dy  x2  1 dx  ln  dx   ln  x2  1  ln c Substituting xx2
dx
f  x  2   f  x  4   2f  x  3 
 c  x 2  1  c = 3 as at x  0,
dy dy
 =3
dx dx Adding f  x   2f  x  2   f  x  4   2  f  x  1  f  x  3  

 3  x 2  1 
dy
 y = x3 + 3x + 1  2· 2f  x  2 
dx
57. The sum of series 84C4 + 6. 84C5 + 15. 84C6 + 20. 84C7  f  x   f  x  4  0
+ 15. 84C8 + 6. 84C9 + 84C10 f  x  4  f  x  8  0
= (84C4 + 84C5) + 5 (84C5 + 84C6) + 10(84C6 + 84C7)
= 10(84C7 + 84C8) + 5 (84C8 + 84C9) + (84C9 + 84C10)  f  x   f  x  8

= 85C5 + 5. 85C6 + 10. 85C7 + 10 85C8 + 5 85C9 + 85C10 63. For function to be onto range = co-domain
= ( C5 + C6)+ 4 ( C6 + C7) + 6 ( C7 + C8) + 4
85 85 85 85 85 85

(85C8 + 85C9) + (85C9 + 85C10) 

 cot 1 x 2  2x  a  should take all values from  0, 2 
= 86C6 + 4. 86C7 + 6. 86C8 + 4. 86C9 + 86C10
 x 2  2x  a should take all values from  0, 
= 87C7 + 3. 87C8 + 3. 87C9 + 87C10
D0
= 88C8 + 2. 88C9 + 88C10
= 89C9 + 89C10 = 90C10  4  4a  0

58. 5a + 2bc + 8b – 10ac + 25c = a + 6ab – b + 17bc

2 2 2 2 2  a 1

4a + 9b + 25c = (2a) (3b) + 15bc + 10ac

2 2 2 64. Equation of tangent to x2 = 4ay will be in the form y
(2a)2 + (3b)2 + (5c)2 = (2a)(3b) + (3b)(5c) + (5c)(2a) = mx – am2

a b c 3
a  2 8
 2a = 3b = 5c      (say)   2    a 
15 10 6 3  3 3
b2  c 2  a2 100 2  36 2  225 2 89 2 89 65. Let P(h, k) be a point in the locus
cos A    
2bc 2(10 )(6 ) 120 2 120
Equation of chord of constant is hx + ky = a2.
59. Equation of tangent y = 2x + 4a2  b2 Pair of lines passing through origin & points of cotact
passes (–2, 0)  4 = 4a2  b2  hx  ky 
2
is x 2  y 2  a2  
 4a2 + b2 = 16 a2 

 locus of (a, b) is 4x2 + y2 = 16  h2  k 2 

As angle between pair of lines is 90°  2  a2  
1  a4 
Area = (2)(4) = 2
4  Locus is x2 + y2 = 2a2
14 MOCK TEST 3

66. To find (30 C0 )( 30 C10 )  (30 C1 )( 30 C11 )  ( 30 C2 )(30 C12 ) 2 4 2 8

 m   4 ,  4 , 4 , 4
 ...( 30 C20 )( 30 C30 )
So m has two integral values.
( difference of lower suffices = 10)
 (1 + x)30 = 30C0 + 30C1x + 30C2x2 + ... + 30C20x20 71. Let x  1 Then, x  , y  0
y
+ ... + 30C30x30 ... (i)
nx
 (x – 1) = C0x – C1x + ... + C10x – C11x19
30 30 30 30 29 30 20 30  a1/ x  a1/ x 1/ x 
2  ...  an
 lim  1 
x   n 
+ 30
C12x18 + ... + 30C30 ... (ii)  
Multiplying Eq. (i) and Eq. (ii) and comparing n/y
 a y  a y  ...  any 
coefficient of x20, then we get  lim  1 2   1
y 0  n 
 
(30 C0 )( 30 C10 )  (30 C1 )( 30 C11 )  ( 30 C2 )(30 C12 )
n/y
+ ... + (30 C20 )( 30 C30 )  1 a y  ay ... a y n 
 1 2 n 
lim  
y  0 n 
= 30C10  e  
[  (1 + x)30(x – 1)30 = (x2 – 1)30 = (1 x2)30]
 30   y y y 
n  a  a ... an 
 ay 1 a y 1

y 
a 1 
  lim  1 2 1 lim  1  2 .... n 
 10  y 0 y 

n 

y  0 y

y y 

 e  e
 1 2
67. 2 3  0  eloga1 loga2  loga3 .... logan  elog a1·a2 ·a3 .....an 
3 2 1
  a1·a2·a3 .....an 
 (– 3 + 2) + 1(2 – 3) – 2(– 4 + 9) = 0
 22 – 6– 8 = 0
72. l  2x  2r  r A  2rx  1 r 2
 2 – 3– 4 = 0 2
 ( – 4) (+ 1) = 0 1 2
A  2rx  r
  = –1, 4 2
 1 0  1 0  1 0  73. The area maximum when the triangle is equilateral
68. A 2     
 1 7   1 7   8 49 
x 1
 1 0 1 0 74. f  x   ,f  x   0 for x  2
and8A + kI2 = 8  k  x2
 1 7  0 1
8  k 0   1  1 
 f  x     x    f '  x    1  2   0
  x  x 
 8 56  k 
 A2 = 8A + kI2 1

 1 0  8  k 0  75. I   cot 1(1  x  x 2 )dx

    0
 8 49   8 56  k 
On comparing, we get 8 + k = 1  k = – 7. 1

  tan1 
1 
dx
2 
69. Total number of ways to choose two squares 0  1 x  x 

64.63 1
 x  (x  1) 
1
 64C2   32.63
 tan  dx   [tan x  tan (x  1)]dx
1 1 1
2 
0  1  x(x  1)  0

For favourable ways we must chosen two

1 1 1 1
consecutive small squares for any row or any   tan1 xdx   tan1(x  1)dx   tan1 xdx   tan1(1  x)dx
columns. 0 0 0 0

 Number of favourable ways = 7.8 + 8.7 = 2.8.7 1 1

I   tan1 xdx   tan1[1  (1  x)]dx
2.8.7 1
 Required probability = 32.63  18 0 0

1 1
70. Solving given equations we get I  2 tan1 xdx    tan1xdx
0 0
5
x
3  4m 2

x is an integer, if 3 + 4m = 1,  5
 MOCK TEST – 4
PHYSICS (SECTION – A) 3. A cube of side a and mass m is to be tilted at point
A by applying a Force F as shown in figure. The
1. A disc of radius R rolls without slipping at speed v minimum force required is
along positive x-axis. Velocity of point P at the
instant shown in figure is
F

y
3/4 a

P
r v
 a A
2
(a) mg (b) mg
3
x 3 3
(c) mg (d) mg
2 4
4. A body is fired with a velocity of magnitude

 gR  V  2gR at an angle of 30° with the radius

(a) VP   v 
vr sin   ˆ vr cos  ˆ
i j
 R  R vector of earth. If at the highest point the speed of
the body is V/4, the maximum height attained by
 the body is equal to
vr sin   ˆ vr cos  ˆ
(b) VP   v  i j
 R  R V2
(a) (b) R
8g
 vr sin  ˆ vr cos  ˆ
(c) V P  i j (c) 2R (d) none of these
R R
5. If the velocity (V), acceleration (A) and force (F) are
 vr sin  ˆ vr cos  ˆ taken as fundamental quantities instead of mass
(d) V P  i j (M), length (L) and time (T), the dimensions of
R R
Young's modulus (Y) would be
2. A uniform thin rod of length l and mass m is hinged
(a) FA2V–4 (b) FA2V–5
at a distance l/4 from one of the end and released
from horizontal position as shown in figure. The (c) FA2V–3 (d) FA2V–2
angular velocity of the rod as it passes the vertical 6. In a photoelectric emission, electrons are ejected
position is from metals X and Y by light of frequency f. The
potential difference V required to stop the electrons
l/4 is measured for various frequencies. If Y has a greater
work function than X, which graph illustrates the
l
expected results?
5g 6g
(a) 2 (b) 2 V X V X
7l 7l
Y
(a) (b) Y
3g g
(c) (d) 2
7l l 0 0
0 f 0 f
2 MOCK TEST 4

V V 11. A screw gauge gives the following reading when

Y Y
X used to measure the diameter of a wire.
X
(c) (d) Main Scale reading 0 mm
0 0 Circular Scale reading 52 divisions
0 f 0 f
Given that 1 mm on main scale corresponds to
7. The ratio of maximum wavelength of the Lyman series 100 divisions of the circular scale. The diameter
in hydrogen spectrum to maximum wavelength in of the wire from the above data is:
Paschen series, is (a) 0.52 cm (b) 0.005 cm
(c) 0.052 cm (d) 0.026 cm
3 6
(a) (b) 12. 500 g of water and 100 g of ice at 0°C are in a
105 15
calorimeter whose water equivalent is 40 g. 10 g
52 7 of steam at 100°C is added to it. Then water in
(c) (d)
7 108 the calorimeter is: [Latent heat of ice = 80 cal/g.
8. A proton, a deuteron, and an alpha particle are Latent heat of steam = 540 cal/g]
accelerated through potentials of V, 2V and 4V, (a) 610 g (b) 580 g
respectively. Their velocities will bear a ratio (c) 600 g (d) 590 g
(a) 1 : 1 : 1 (b) 1: 2 : 1 13. PV-diagram of a diatomic gas for certain
thermodynamic process is a straight line passing
(c) 2 : 1: 1 (d) 1: 1: 2 through origin. The molar specific heat capacity of
9. A slab S of mass m is released from a height h0 the gas in the process will be:
from the top of a spring of force constant k. The (a) 4R (b) 3R
maximum compression x of the spring is given by 4R
the equation (c) (d) 2.5 R
3
S 14. A uniform wire (Young's Modulus = 2 × 1011 Nm–2)
is subjected to a longitudinal tensile stress of
h0
5 × 107 Nm–2. If the overall volume change in the
wire is 0.02%, the fractional decrease in the radius
of the wire is close to:
(a) 0.25 × 10–4 (b) 1.0 × 10–4
(c) 1.5 × 10–4 (d) 5 × 10–4
15. A source of sound of frequency 600 Hz is placed
1 2 inside water. The speed of sound in water is 1500
(a) mgh0  kx
2 ms–1 and in air is 300 m–1. The frequency of sound
1 2 recorded by an observer who is standing in air
(b) mg(h0  x)  kx
2 is__________(Hz)
1 16. In a U-tube in which the cross sectional area of the
(c) mgh0  k(h0  x)2 limb on the left is one quarter of that on the right.
2
The limb on the right contains mercury (density 13.6
1 2 g/cm 3), and the level of mercury in the narrow limb
(d) mg(h0  x)  kx
2 is at a distance of 36 cm from the upper end of the
10. A pendulum consists of a wooden bob of mass m tube. What will be the rise in the level of mercury in
and of length l. A bullet of mass m1 is fired towards the right limb if the left limb is filled to the top with
the pendulum with a speed v1. The bullet emerges water__________(cm)
out of the bob with a speed v1/3 and the bob just
completes motion along a vertical circle. Then v1 is
water
m 3 m 
(a)  m  5gl (b) 2  m  5gl
 1  1
3  m1   m1  mercury
(c)  5gl  gl
2  m 
(d) 
m
 MOCK TEST 4 3

17. A cube is compressed at 0°C equally from all sides 22. An ideal gas undergoes four different processes from
by an external pressure P. By what amount should the same initial state. Four processes are adiabatic,
its temperature be raised to bring it back to the size isothermal, isobaric and isochoric. Out of 1, 2, 3
it had before the external pressure was applied? and 4 which one is adiabatic.
(Given: K is bulk modulus of elasticity of the material P
4
of the cube and  is the coefficient of linear
3
expansion;  =12 × 10–6/K)
2
1
P P V
(a) (b) (a) 4 (b) 3
K 3K
(c) 2 (d) 1
3 K
(c) (d) 23. Two moles of helium are mixed with n moles of
P 3P
hydrogen. The root mean square speed of the gas
18. Water rises to a height h in a capillary tube of cross
molecules in the mixture is 2 times the speed of
sectional area A, the height to which water will rise
in a capillary tube of cross-sectional area 4A will be sound in the mixture. Then value of n is__________

(a) h (b) h/2 24. Helium gas goes through a cycle ABCDA (consisting
of two isochoric and isobaric lines) as shown in
(c) h/4 (d) 4h figure. Efficiency of this cycle is nearly (assume the
19. The energy spectrum of a black body exhibits a gas to be close to ideal gas).
maximum around a wavelength 0. The temperature
of the black body is now changed such that the 2p0
energy is maximum around a wavelength 30/4. The
power radiated by the black body will now increase p0
by a factor of
(a) 256/81 (b) 64/27 V0 2V0
(c) 16/9 (d) 4/3 (a) 15.4% (b) 9.1%
20. Two moles of an ideal monoatomic gas undergoes a (c) 10.5% (d) 12.5%
cyclic process as shown in the figure. The
25. If the tem perature of the sun were to
temperatures in different states are given as 6T1 =
increase from T to 2T and its radius from R
3T2 = 2T4 = T3 = 1800 K. Determine the work done
to 2R, then the ratio of the radiant energy
by the gas during the cycle.
received on earth to what it was previously,
T
will be__________
3
CHEMISTRY (SECTION – B)
26. For the reaction



 O3 , H   ve, formation of ozone is
O2 
favoured by
2 4 (a) Decrease in pressure
(b) Decrease in temperature
1
P (c) Removal of inert gas (if present initially) at
(a) – 10 kJ (b) – 20 kJ constant pressure
(c) – 15 kJ (d) – 30 kJ
(d) Addition of alkaline pyrogallol
21. An object, moving with a speed of 6.25 m/s, is
27. In which of the following compounds, iron has lowest
dv oxidation state?
decelerated at a rate given by  2.5 v , where
dt (a) Fe(CO)5 (b) Fe3O4
v is the instantaneous speed. The time taken by the
(c) K4[Fe(CN)6] (d) FeSO4.Al2(SO4)3.24H2O
object, to come to rest, would be__________(s)
4 MOCK TEST 4

28. Which of the following does not have peroxide 38. Two liquid A and B form an ideal solution. When total
linkage? pressure of above solution is 600 torr, the amount
(a) K3CrO8 (b) H2S2O8 fraction of A in the vapour phase is 0.35 and in liquid
(c) Na2O2 (d) H2C2O4 phase is 0.70. The vapour pressure of pure A
29. Which of the following cannot have a conjugate base? is__________
39. W hat is the oxidation state of iron in
(a) H2PO 2 (b) OH–
K4Fe(CN)6__________
(c) H2O2 (d) HSO 4 40. [Co(NH 3) 5NO 2]Cl 2 and [Co(NH 3) 5ONO]Cl 2 are
30. One mole of N2O4(g) at 310 K is 25% dissociated at related to each other as:
1 atm pressure. The percentage dissociation at 0.1 (a) geometrical isomers
atm and 310 K is (b) linkage isomers
(a) 63% (b) 50% (c) coordination isomers
(c) 75% (d) 25%
(d) ionisation isomers
31. The solubility products of MA, MB, MC and MD are
41. The possible number of isomers for the complex
1.8 × 10–10, 4 × 10–3, 4 × 10–8 and 6 × 10–5 respectively.
[MCl2Br2]SO4 is__________
If a 0.01 M solution of MX is added dropwise to a
mixture containing A–, B–, C– and D– ions, then the 42. Which of the following metallic sols cannot be
one to be precipitated first will be: prepared by Bredig's arc method?
(a) MD (b) MC (a) Gold (b) Silver
(c) MB (d) MA (c) Platinum (d) Sodium
32. The vapour pressure of a dilute aqueous solution of 43. Which of the following statements is wrong?
glucose is 750 mm of Hg at 373 K. The mole fraction (a) Among halogens, oxidising behaviour increases
of solute is: down the group
(a) 1.316 (b) 1.316 × 10–2 (b) Among alkali metals, reducing character increases
–4
(c) 1.316 × 10 (d) 13.16 down the group
33. Cl and K are isoelectronic then
– +
(c) Fluorine is the most electronegative atom.
(a) their size are same (d) Lithium is the hardest metal among alkali metals.
– +
(b) Cl is relatively bigger than K ion 44. Which of the following reacts with HBr at faster rate?
+ –
(c) K ion is bigger than Cl ion OH
(a)
(d) their reactivity is same
34. The bond length in LiF will be: OH
(a) less than that of NaF(b) equal to that of KF
(b) CH3
(c) more than that of KF(d) equal to that of NaF
35. Which of the following allotropes represents Prismatic
Sulphur? OH
(a) Rhombic Sulphur (b) Monoclinic Sulphur
(c) Plastic Sulphur (d) Colloidal Sulphur (c)
36. ABABABA.... type of arrangement of different layers CH3
in close packed structure is called OH
(a) Hexagonal close packed
(b) Cubic close packed (d)
CH3
(c) Face centred close packed
45. During the electrolysis of water, 4 mol of electrons
(d) Body centred close packed
were transferred from anode to cathode. The total
37. A weak acid HX (Ka = 10–5) reacts with caustic soda volume of the gases produced at STP will be
to form salt NaX (0.1 M) degree of dissociation of NaX approximately__________
will be__________ (Kw = 10–14)
 MOCK TEST 4 5

46. Which is/are not the correct configuration of s-block n m

elements
53. 
m0 p 0
2n
C2m .2m C2p 

(a) [Ar] 3d10 4s 2 (b) [Ar] 3d10 4s1

3 2n  1 3n  1
(c) both (a) and (b) (d) None of these (a) (b)
4 4
47. N2 and O2 are converted into mono anions N2 and 3 2n  1
(c) (d) None of these
4
O2 respectively. Which of the following statements
s
54. The number of different ways the letters of the word
is wrong? ORANGE can be placed in the 8 boxes of the given
(a) In N2, the N-N bond weaknes below such that no row remains empty, is equal to

(b) In O2 , O-O bond length increases

(c) In O2 , bond order decreases

(d) N2 becomes diamagnetic

(a) 26 (b) 26 × 6!
48. Which reaction is not feasible
(c) 6! (d) 2! × 6!
(a) 2KI + Br2  2KBr + I2
55. If N is the number of positive integral solutions of
(b) 2KBr + I2 
 2KI + Br2 x1x2x3x4 = 880, then N is__________
56. Let: R  R and g: R  R be two one - one and onto
(c) 2KBr + Cl2  2KCl + Br2
functions such that they are mirror images of each
(d) all of the above other about the line y = 0, then h(x) = f(x) + g(x) is
49. Which of the following polymers have more than one (a) one - one and onto
monomer. (b) one - one but not onto
I - Nylon-6 ; II - Nylon-6,6 ; III - Teflon ; IV - Buna-S (c) not one - one but onto
(a) I and II (b) II and IV (d) None of these
(c) II and III (d) II, III, IV 57. Let f be a differentiable function satisfying f(xy) =
50. 3 moles of mixture of ethene and ethane are f(x) . f(y),  x > 0, y > 0 and f(1 + x) = 1 + x{1 +
decolourised by 2 moles of Br2. % of ethene in the f(x)
mixture is: g(x)}, where lim g(x) = 0 then  dx is equal to
x0 f '(x)
(a) 50% (b) 66.66% x2 x3
(a) +C (b) +C
(c) 33.33% (d) 25% 2 2
x3 x2
MATHEMATICS (SECTION – C) (c) +C (d) +C
3 3
3
1 1 1 58. The area bounded by y = 2 – |2 – x| & y = | x | is:
51. If H n = 1    ....  , then the value of
2 3 n
4  3l n3 4  3l n3
3 5 99 (a) (b)
Sn= 1    ....  2 2
2 3 50 3 1
(c)  l n3 (d)  l n3
(a) H50 + 50 (b) 100 – H50 2 2
(c) 49 + H50 (d) H50 + 100 59. let f(t) be a continous function for t  R. Let I1 =
1 cos2 t 1cos2 t

52. If a, b, c  R then
+
bc

ac

ab sin2 t x f(x(2  x))dx and I2 = sin2 t f(x(2  x))dx,
bc ac ab then
1 1 I1 I1
(a)  (a  b  c) (b)  abc 2 1
2 3 (a) (b)
I2 I2
1 1
(c)  (a  b  c) (d)  abc I1 I1 1
3 2 (c) is not defined (d) 
I2 I2 2
6 MOCK TEST 4

60. a ten digited number is formed without repeating 70. Let f:R  R be a function such that
any digit. The probability that the difference of the  x  y  f(x)  f(y)
f  , f(0) = 3 and f(0) = 3, then
digits at equal distances from the begining and the  3  3
end is always 1, is
f(x)
(a) is differentiable in R
17 4 x
(a) (b)
1944 27 (b) f(x) is continuous but not differentiable in R
1 34 (c) f(x) is continuous in R
(c) (d)
945 243 (d) f(x) is bounded in R
61. The point of local maxima o the curve y = f(x) if
71. If 'z' lies on the circle z  2i  2 2 , then the value
f   x    x  2  x  3  x  4   x  5 
2 3 4 5
is  z2
of arg   is equal to
(a) –2 (b) 3 z2
(c) –4 (d) 5  
(a) (b)
62. The value of tan–1(tan 10) is 3 4
(a) 10 (b) 3   10  
(c) (d)
6 2
(c) 10  3  (d) 4   10
72. For all complex numbers z1,z 2 satisfying z1  12
3 4 3  and z2  3  4i  5 the minimum value of z1  z2
 
63. If A   2 5 7  then Adj  Adj A   __________ is__________
 1 2 3 
2
 3  cos x 
64. (1 + tan 5°)(1 + tan 10°) … (1+ tan 45°)__________
73.  x ln  3  cos x  dx  ___
0
65. The equation of director circle to the the circle x2
 
+ y2 – 8x + 6y – 25 = 0 is (a) ln3 (b) ln3
2 6
(a) x2 + y2 – 8x + 6y + 25 = 0

(b) x2 + y2 – 8x + 6y – 75 = 0 (c) ln3 (d) 0
12
(c) x2 + y2 – 8x + 6y = 0
x8  4
(d) x2 + y2 – 8x + 6y – 50 = 0 74. x 4
 2x 2  2
dx 
66. Let f(x) = [9 – 3 + 1]  x  (  ,1), then range of
x x

x5 2x 3 x5 2x 3
f(x) is ([.] denotes the greatest integer function) (a)   2x  C (b)   2x  C
5 3 5 3
(a) {0, 1, 2, 3, 4, 5, 6}
(b) {0, 1, 2, 3, 4, 5, 6, 7} x5 2x3 x5 2x3
(c)   2x  C (d)   2x  C
(c) {1, 2, 3, 4, 5, 6} 5 3 5 3
75. The area of the smaller portion enclosed by the
(d) {1, 2, 3, 4, 5, 6, 7}
curves x 2  y 2  9 and y2  8x is
67. If f(2x + 3y, 2x – 7y) = 20x, then f(x, y) equals
(a) 7x – 3y (b) 7x + 3y 2 9 9 1  1 
(a)   sin  
(c) 3x – 7y (d) 3x + 7y 3 4 2 3

(cos x  1)(cos x  e x )  2 9 9 1  1  
68. The integer n for which lim is (b) 2    sin   
x 0 xn  3 4 2  3  

a finite non-zero number is__________
 2 9 9 1  1  
(c) 2    sin   
69. If lim( (x  x  1)  ax  b)  0, then
4 2 2  3 4 2  3  
x  
(a) a = 1, b = – 2 (b) a = 1, b = 1 2 9  9 1  1 
(d)   sin  
(c) a = 1, b = – 1/2 (d) none of these 3 4 2 3
 MOCK TEST 4 7

ANSWERS
1. (b) 2. (b) 3. (b) 4. (b) 5. (a) 6. (a) 7. (d) 8. (d) 9. (d) 10. (b)
11. (c) 12. (d) 13. (b) 14. (a) 15. (600Hz) 16. (0.56cm) 17. (b) 18. (b) 19. (a)
20. (a) 21. (2s) 22. (c) 23. (2) 24. (a) 25. (64) 26. (c) 27. (a) 28. (d) 29. (a)
30. (a) 31. (d) 32. (b) 33. (b) 34. (a) 35. (b) 36. (a) 37. (0.0001) 38. (300 torr)
39. (2) 40. (b) 41. (5) 42. (d) 43. (a) 44. (b) 45. (67.2L) 46. (c) 47. (d) 48. (b)
49. (b) 50. (b) 51. (b) 52. (a) 53. (a) 54. (b) 55. (560) 56. (d) 57. (a) 58. (b)
59. (b) 60. (c) 61. (b) 62. (c) 63. (256) 64. (32) 65. (b) 66. (c) 67. (b) 68. (3)
69. (c) 70. (c) 71. (b) 72. (2) 73. (d) 74. (d) 75. (b)

EXPLANATIONS
1. Here, 4. Conservation of angular momentum of the body about
v O yields.

R
V
 v 
VPx   v  r sin   ˆi 30°
 R 
A
v 
VPy    r cos   ˆj
R 
 vr sin   ˆ vr cos  ˆ R
  B
VP   v  i j O n
 R  R
V
 vr sin   ˆ vr cos  ˆ
 v  i j
 R  R
(mv sin 30°)R = nV(R + h)
V V  V
r sin
R  (R  h)  V   4 
2 4  
90° – 
 Therefore, h = R
v
r 5. Let Y = [VaAbFc]
r cos
[ML–1T–2] = [Lt–1]a[LT–2]b[MLT–2]c
ML–1T–2 = McLa+b+cT–a–2b–2c
1  ml2   c = 1, a + b + c = – 1, – a – 2b – 2c = – 2
2
  l   1
2. mg      m    2
 4  2  12  4   On solving, we get a = – 4, b = 2 and c = 1
24g 6g 6. From Einstein’s photoelectric theory, we have
 2
7l 7l eV = hf – 
3. See figure
where V is the potential difference and  is the work
function of metal
F Y > X, fY > f X
FY is the threshold frequency of Y.
3 a FX is the threshold frequency of X.
4
Furthermore, V versus f has a constant slope of h/e.
7. Maximum wavelength means minimum energy and
vice-versa.
mg
a F3a 2mg 1  1  3K
mg   ; F i.e.,  K 1   
2 4 3 1  4 4
8 MOCK TEST 4

For maximum wavelength in Paschen series, 15. The frequency is a source dependent quantity. It will
transition corresponds to n = 4 to n = 3. not change due to change in medium.
1  1 1  7K 16. If the rise of level in the right limb be x cm, the fall of
K   
2  9 10  144 level of mercury in left limb is 4x.
1 74 7 Therefore, level of water in the left limb is (36 + 4x)
So,  
 2 144  3 108 cm. Equating pressure at interface of mercury and
water, we have (at A1 and B1)
8. Apply v  2qV
m (36 + 4x) × 1g = 5x × 13.6 × g
9. Equate loss of gravitational potential energy with gain Solving, we get x = 0.56 cm
of elastic potential energy.
10. Applying the law of conservation of momentum,
36 cm
v 2m1v1 x
m1v1  m1 1  mv or v
A
3 3m
Initial
To describe a vertical circle v should be 5gl . So, 4x level of Hg
A1
2m1v1  m 3
 5gl or v1    5gl B1
3m  m1  2
11. Diameter = (main scale reading) + (circular scale
reading) × (least count)
1mm
Least count   0.01mm
100 divisions
17. K  PV  PV  P
12. Amount of heat extracted from converting steam at V VT 3 T
100°C to water at 0°C = 10 × 540 + 10 × 1 (100 – 0) P
or T  3K
= 6400 cal
Amount of ice which will melt using the above heat 18. h  2Scos 
6400 rg
  80g
80 Cross sectional area increases 4 times, which
Hence, final amount of water = 500 + 80 + 10 means radius gets doubled.
= 590 g
13. The process equation will be p = kV So, h  2S  h
2(rg) 2
V2
kV22  kV12 p2 V2  p1V1 nRT 19. According to Wien’s law, wavelength corresponding
W   kVdV  2

2

2 to m aximum energy decreases. W hen the
V1
temperature of black body increases,
Using: Q  W  U
i.e., mT = constant
We can write:
T2 1 0 4
nRT    
nCT   nCV T T1  2 3 0 / 4 3
2
R R 5R Now according to Stefan’s law
C  CV    3R 4
2 2 2 E 2  T2  4 256
4

    
14. Volume (V) of the wire  R L 2 E1  T1  3 81

V 2R L
20. 6T1 = 3T2 = 2T4 = T3 = 1800 K
Now, V  R  L ...(1) T1 = 300 K;T2 = 600 K

L tensile stress 5  10 7
T4 = 900 K;T3 = 1800 K
   2.5  10 4 and
L Young's Modulus 2  1011 1  4 and 2  3 are isochoric processes.
Work done = 0
V
 0.02%  2  104
V W 12 = P(V2 – V1) = nR(T2 – T1)
= 2 × R(600 – 300) = 600 R
Substituting in (1), we get: R  0.25  104 . Hence,
R W 14 = P(V4 – V3) = nR(T4 – T3)
fractional decrease in R is 0.25  104 = 2 × R(900 – 1800) = – 1800R
W Total = 600R – 1800R = – 1200 R
 MOCK TEST 4 9

dv
0 t 32. P = 760 mm = Vapour pressure of water at 373 K
21.   2.5 dt   v 1/ 2dv  2.5  dt  t  2s
v 6.25 0 760  750

760
= mole fraction of solute = 1.316×10–2
22. The slope of curve-2 is more negative as compared
to curve-3 for a certain volume. 37. HX + NaOH  NaX
 Na+ + X
–
3RT RT NaX
23. vrms  , v sound  Given, vrms  2 v sound
M M –
X + H2O 


 HX + OH
3
Solving we get,  for the mixture c 0 0
2
c – c c c
 5R   7R  C 2
2  n K
n1CP1  n2CP2
3  2  
 2  n2 Kh = Kw  (1   ) If   0. 1
Now, mix    a
n1C V1  n2C V2 2  3R   5R 
2   n 2 
 2    Kw 10 14
W Areaunder P-V diagram  =   10 4 = 0.0001
24. Efficiency,      15.4% K a XC 10 5  0.1
Q Q AB  QBC
38. Ptotal = 600 torr
25. E1  e  4R  T 2 4

& E2  e 4  2R 
2
 2T  4
 64E1 PA = P  XA … (i) (P = total pressure)
XA = mole fraction of A in vapour pressure
26. 

 2O 3 (g); H   ve
3O 2 (g)  YA = mole fraction of A in liquid solution
 Removal of inert gas (at constant P) increases PA = PA0  YA …(ii)
the partial pressure of gaseous components.
PA = vapour pressure of pure A
 Alkaline pyrogallol absorbs O2.
from Eq. (i) and (ii)
27. In Fe(CO)5, Fe has zero oxidation state.
O OH PA0  YA = Ptotal  XA
C
28. H2C2O4  PA0  0.70  600  0.35
C
0.35 600
O OH PA0  600   = 300 torr
0.70 2
O
41. [MCl 2 Br 2 ]SO 4 gives [MCl 2 BrSO 4 ]Br and
29. H2PO2  P [MClBr2SO4]Cl as ionization isomers and also cis
(–)
H O and trans geometrical isomers are expected.
H
30. N2O4(g) 
 2NO2(g)
 42. Bredig’s arc method can not be used for the
t=0 1 mole 0 preparation of colloidal sol of Na because it reacts
teq (1 – ) 2 with water vigorously.
Total moles = (1 – ) + 2 = (1 + ) 43. Oxidising behaviour among halogens decreases
2 down, the group. Fluorine is the strongest oxidising
 2 
 P agent.
[NO2 ]2  (1   )  4 2P
Kp =  
[N2O 4 ]  1   1  2 44. 3° alcohol when reacts with HBr, SN1 reaction takes
  .P
1   place
4(0.25)2 OH
 = 0.25, Kp =  0.267 +
1  (0.25)2 H  Br CH3
CH3 
(S 1 )

At a pressure of 0.1 atm; N

(3° carbocation)
4 2 (0.1)
0.267 = :   0.63 1  2 1
1  2
45. H2O  H2 + 2
O2
i.e., percentage dissociation = 63
31. KSP = [M+] [anion] 1 mol 22.4 L 11.2 L
1.8  10 10 4  10 8 Decomposition of 1 mol of water required 2 mol of
 A    C  
0.01 0.01 electrons
 4 mol of electrons produce 2 × 22.4 L
4  10 3 6  10 5
B   D  


0.01   0.01 = 48.8 L of H2

Thus [A–] is smallest and the product of ionic conc. and2 × 11.2 L = 22.4 L of oxygen
will exceed its KSP first. Total volume produced at STP = 44.8 + 22.4 = 67.2 L
10 MOCK TEST 4
46. Both are d-block element 57. Put x = y = 1, we get f(1) = f2(1)  f(1) = 1[  f(1)  0]
47. N2 becomes paramagnetic Differentiating with respect to x partially, we get
y f'(xy) = f(y) f'(x)
48. Order of oxidising power Cl2 > Br2 > I2
f(y) y
50. CH2 = CH2 + Br2  CH2  CH2 putting x = 1  y f'(y) = f(y) f'(1)  
f '(y) f '(1)
| |
Br Br f(x) x 1  x2 
1 1
Hn  1    ..... 
1 Now,  f '(x) dx   f '(1) dx  f '(1)  2
 c

51.
2 3 n
f(1  h)  f(1)
 1  1 
Sn  (2  1)   2     2    .....   2 
1  f'(1) = hlim
0 h
 2  3  50 
1  h  hg(h)  1
 1 1 1  lim
Sn  2.50  1    .....  h0 h
 2 3 50 
 lim 1  g(h)  1  lim g(h)  0
Sn  100  H50 h 0 h 0

2
52. A.M.  H.M. f(x) x
  f '(x) dx  2
C
b  c 2bc bc 1
   (b  c) ... (1) 58.
2 bc bc 4
Similarly
ac 1
 (a  c) ... (2)
ac 4
ab 1
 (a  b) ... (3)
ab 4
add all these
bc ac ab 1 3 (2, 0) 3 (4, 0)
   2(a  b  c)
bc ac ab 4
2 3
bc ac ab 1  3  3
    (a  b  c)
bc ac ab 2
A   x  x  dx    4  x  x  dx
3 2
n m

53.  C2m  2m C2p

2n
2 3 3
3 1 3 3 4  3l n3
m 0 p 0   xdx   4  x  dx   dx    l n3 
2
x 2 2 2 2
n 3 3
1 n 2n

m 0
2n
C2m .22m 1   C2m .2m
2 m0
Hence (b).

1 1  1 1 cos2 t
 .
2  2
 
(1  2)2n  (1  2)2n   .(32n  1)
 4 59. I1 =  xf(x(2  x) dx
sin2 t
54. Coeff of t6 : [ 4 C1t  4 C2 t 2 .....  4 C4 t 4 ][2 C1t  2 C2 t 2 ]2
= [(1 + t)4 – 1] [(1 + t)2 – 1]2 1+cos2t
b b

= (1 + t)8 –(1 + t)6

=  (2 - x) f((2 - x)x)dx (Use  f(x)dx  f(a  b  x)dx )
sin2t a a
= 8C2 – 2. 6C6 = 26
I1 = 2. I2 – I1
No. of ways with arrangement = 26.6!
55. x1x2x3x4 = 24 × 51 × 111 I1
1. Hence (b)
No. of solutions = 4+4–1C4–1 × 1+4–1C4–1 × 1+4–1C4–1 I2

= 7 C3 × 4 C3 × 4 C3 60. Split the digits into pairs viz : (0, 1), (1, 2), ..... (8, 9)
 N = 35 × 4 × 4 Disjoint pairs out of these are
56. f: R  R & g: R  R be two one-one onto functions (0, 1), (2, 3), (4, 5), (6, 7), (8, 9)
such that f & g are mirror images of each other about
(there is no other set of 5 disjoints pairs)
line y = 0. It means one is -ve of the other
i.e. f(x) = –g(x) Now two cases are
 f(x) + g(x) = 0 (a) When the pair (0, 1) is not used for first and the
last place.
 h(x) = 0
The number of ways = 4 × 4! × 25
h(x) is not onto as well as not one-one
 MOCK TEST 4 11

(b) When the pair (0, 1) is used for first and last
place.
69. xlim


(x 4  x 2  1)  ax 2  b  0 
The number of ways = 1 × 4! × 24 1
Put x  t
 Total number of favourable cases = 9 × 4! × 24

9  4!  24 1 (1  t 2  t 4 )  a  bt 2
 Probability =   lim 0 ... (i)
9  9! 945 t 0 t2

61. + + + – + Since, RHS is finite.

–4 –2 3 5  Numerator must be equal to 0 at t  0
As f’(x) changes from + to – at x = 3,  x = 3, is a  1–a=0
point of local maxima  a=1

  
From Eq. (i),
62. As range of tan–1x is   , 
2 2 (1  t 2  t 4 )  1  bt 2
lim 0
t 0 t2
tan 1  tan10   n  10
 (1  t 2  t 4 )1/ 2  (1)1/ 2 
lim( 1  t 2 )  b
= – 3p + 10 t 0
 (1  t 2  t 4 )  1 

= 10 – 3p  1
 ( 1)    b
2
63. Adj  AdjA   A n 1  44 = 256
2
1
 a = 1, b =  2
64. If A + B = 45°, then (1 + tanA)(1 + tanB) = 2
65. (x – y)2 + (y + 3)2 = 2.50 70. Given, f  x  y   f(x)  f(y)
 3  3
 x2 + y2 – 8x + 6y – 75 = 0
Replacing x by 3x and y by zero,
2 2

66.  9x – 3x + 1 =  3x  1   1  1 =  3 x  1   3  3 f(3x)  f(0)

 2 4  2 4 4 thenf(x) = 3
 For x  ( , 1)  f(3x) – 3f(x) = – f(0)
3
 9x  3x  1 
28 f(x  h)  f(x)
 andf(x) = hlim
4 4 0 h
Now, [9x – 3x + 1] = {1, 2, 3, 4, 5, 6}  3x  3h 
f   f(x)
 lim  
 Rf = {1, 2, 3, 4, 5, 6} 3
h 0 h
67. Let 2x + 3y = A and 2x – 7y = B
f(3x)  f(3h)
Then, 7A + 3B = 20x  f(x)
 lim 3
 f(A, B) = 7A + 3B h0 h

 f(x, y) = 7x + 3y f(3x)  f(3h)  3f(x)

 lim
h0 3h
(cos x  1)(cos x  e x ) (1  cos x)(e x  cos x)
68. lim  lim f(3h)  f(0)
x 0 n
x x 0 n
x  lim [from Eq. (i)]
h 0 3h
(1  cos x){(e  1)  (1  cos x)}
x
 lim = f(0)
x 0 xn
=3
(1  cos x)(1  cos x){(e x  1)  (1  cos x)}
 lim  f(x) = 3x + c
x0 xn (1  cos x)

 sin x 
2
  ex  1   1  cos x    f(0) = 0 + c = 3
 x      
   x   x   c=3
 lim
x 0 xn  3 (1  cos x) Then, f(x) = 3x + 3
For n = 3 Hence, f(x) is continuous and differentiable
(1)2 ((1)  0) 1
everywhere.
   non  zero finite
1.(2) 2
12 MOCK TEST 4

x   x  2   2x 
2 2
71. CA  CB  2 2·OC  2  OA  OB  2 8
 4  4x 4  4x 4 4 2

74.  dx   dx
 A  2  0i, B  2  0i x 4  2x 2  2  x  2x  2
4 2

Im

x 4
 2  2x 2  x 4
 2  2x 4 dx  x 5

2x3
 2x  C
P(z)
C (2i)
x 4 2
 2x  2  5 3

Re (0, 3)
B O A

75. (-3, 0) O (3, 0)


Clearly, BCA 
2 (0, -3)

 x2  y2  9 , x2  y2  9
 BPA 
4
8  64  36 8  10
x x  9,1 x=1
 z  2  2 2
 arg  
 z  2 4 Area enclosed

 2   2 2xdx   9  x 2 dx 
1 3
2 2
3  cos x   3  cos x 
73. I    2  x  ln  dx   2I  2  ln   dx
 0 1 
0  3  cos x  0  3  cos x 
 2 2 2  xdx   9  x 2 dx 
1 3

 0 1 
 
 3  cos x   3  cos x  on simplifying we get
I  2  ln   dx  2  ln  3  cos x  dx  I  I  0
0  3  cos x  0  
 2 9 9  1 
 2   sin1   
 3 4 2  3  
 MOCK TEST – 5
PHYSICS (SECTION – A) (a) 4 s (b) 2 s
(c) 3 s (d) 1 s
1. Two point masses 1 and 2 move with uniform
  5. The masses of the blocks A and B are m and M.
velocities 1 and 2 , respectively. Their initial
Between A and B there is a constant frictional force
 
position vectors are r1 and r2 , respectively. Which F, and B can slide frictionlessly on horizontal surface
of the following should be satisfied for the collision (see figure). A is set in motion with velocity while B
of the point masses? is at rest. What is the distance moved by A relative
to B before they move with the same velocity?
       
r2  r1 2  1 r r  
(a)      (b) 2 1   2  1 v0
| r2  r1 | | 2  1 | | r2  r1 | | 2  1 |
        A m
r2  r1 2  1 r2  r1 2  1
(c)      (d)      B M
| r2  r1 | | 2  1 | | r2  r1 | | 2  1 |

2. A body is dropped from a height of 39.2 m. After it

crosses half distance, the acceleration due to gravity mV02 mV02
(a) (b)
ceases to act. The body will hit the ground with F(m  M) 2F(m  M)
velocity (take g = 9.8 m/s2)
(a) 19.6 m/s (b) 20 m/s mV20 mV02
(c) (d)
F(m  M) 2F(m  M)
(c) 1.96 m/s (d) 196 m/s
3. The trajectory of a projectile in a vertical plane is 6. Charges –q, Q and – q are placed at equal distance
y = ax – bx2, where a and b are constants and x and on a straight line. If the total potential energy of the
y are respectively horizontal and vertical distances system of three charges is zero, then find the ratio
of the projectile from the point of projection. The Q/q.
maximum height attained by the particle and the
–q Q –q
angle of projection from the horizontal are
r r
b2
a2 2r
(a) ,tan1(b) (b) ,tan1(2b)
2a b (a) 1/2 (b) 1/4
(c) 2/3 (d) 3/4
a2 2a2
(c) ,tan1(a) (d) ,tan1(a) 7. An uncharged parallel plate capacitor having a
4b b dielectric of dielectric constant K is connected to a
4. An inclined plane makes an angle 30° with the similar air cored parallel plate capacitor charged to
horizontal. A groove (OA) of length 5 m cut, in the a potential V0. The two share the charge and the
plane makes an angle 30° with OX. A short smooth common potential becomes V. The dielectric
cylinder is free to slide down the influence of gravity. constant K is
The time taken by the cylinder to reach from A to O
V0 V0
is (g = 10 m/s2) (a) 1 (b) 1
V V

Cylinder V V
A (c) 1 (d) 1
V0 V0

30°
O X
2 MOCK TEST 5

8. For a cell, a graph is plotted between the potential
difference V across the terminals of the cell and the
current I drawn from the cell (see figure). The e.m.f
and internal resistance of the cell is E and r,
respectively.
9. The cell in the circuit shown in figure is ideal. The
coil has an inductance of 4 mH and a resistance of
2 m. The switch is closed at t = 0. The amount of
energy stored in the inductor at t = 2 s is (take e =
3)

V(volt)
E = 2V
2.0
L = 4 mH
1.5 R = 2 m
S
1.0
4 8
(a) J (b)  103 J
0.5 3 9

I (amp) 8
(c)  10 3 J (d) 2 × 103 J
1 2 3 4 5 3

(a) E = 2V, r = 0.5  (b) E = 2V, r = 0.4 

(c) E > 2V, r = 0.5  (d) E > 2V, r = 0.4 


10. If the magnetic field at ‘P’ can be written as K tan   , then K is
2

P 

d

 0I 0I  0I 20I
(a) (b) (c) (d)
4d 2d d d
11. A sonometer wire of length 114 cm is fixed at both the ends. Where should two bridges be placed so as to divide
the wire into three segments whose fundamental frequencies are in the ratio 1 : 3 : 4 ?
(a) At 24 cm and 72 cm from one end
(b) At 72 cm and 96 cm from one end
(c) At 36 cm and 84 cm from one end
(d) At 48 cm and 96 cm from one end
 MOCK TEST 5 3

12.The length of the spring is L 1 when a force of 4 N 2  2

is applied on it. The length of the spring is L 2, (a) (b)
1  1 
when a force of 5 N is applied on it. Assuming
the force is applied from both sides, find the  1 
(c) (d)
length of the spring when a force of 9 N is applied  1 1 
on it. 18. Representing the stopping potential V along y-axis
(a) 5L1 – 4L2 (b) L2 – L1 and (1/) along x-axis for a given photocathode, the
curve is a straight line, the slope of which is equal
(c) 5L2 – 4L1 (d) 9(L2 – L1)
to
13. A body is released from a point at a distance r
from the center of the earth. If R is the radius of e hc
(a) (b)
the earth and r > R, then the velocity of the body hc e
at the time of striking the earth will be: [g –
acceleration due to gravity at the surface of the ec he
(c) (d)
earth] h c
19. The ratio of the speed of the electron in the first
2grR
(a) gR (b) Bohr orbit of hydrogen and the speed of light is equal
r R
to (where e, h, and c have their usual meanings in
cgs system)
2gR  r  R 
(c) 2g  r  R  (d)
r 2hc er 2h
(a) (b)
e2 2c
14. A hoop of radius 2 m, weighs 100 kg. It rolls along
horizontal floor so that its centre of mass has a speed
e2 c 2e2
of 20 cm/s. How much work has to be done to stop (c) (d)
2h hc
it ?
(a) 4.0 J (b) 4.8 J 20. The half-life of radium is 1620 years and its atomic
weight is 226. The number of atoms that will decay
(c) 7.2 J (d) 6.2 J
from its 1 g sample per second will be
15. A body of mass 500 g is taken up along an inclined
(a) 3.6 × 1010 (b) 3.6 × 1012
plane of length 10 m and height 5 m and then released
to slide down to the bottom. The coefficient of friction (c) 3.1 × 1015 (d) 31.1 × 1015
between the body and the plane is 0.1. What is the 21. A plate of face area 5 cm 2 and thickness
amount of work done in the round trip ? [Take g = 0.5 cm is fixed rigidly at the lower surface.
10 ms–2] A tangential force of 100 N is applied at the
upper surface. The lateral displacement of the
(a) 15 J (b) 5 3 J
upper surface w.r.t. lower surface will be
5    5  1010 Nm 2 
(c) 5 J (d) J
3
(a) 2  108 m (b) 2m
16. A luminous object and a screen are at a fixed distance
D apart. A converging lens of focal length f is placed (c) 8  107 m (d) 10m
between the object and screen. A real image of the
22. The property of metals which allows them to be drawn
object in formed on the screen for two lens positions
readily into thin wires beyond the elastic limit without
if they are separated by a distance d equal to
rupturing, is known as
(a) D(D  4f) (b) D(D  4f ) (a) malleability (b) ductility
(c) elasticity (d) hardness
(c) 2D(D  4f ) (d) D2  4f )
23. At what speed, the velocity head of water is equal to
17. Two coherent sources of intensity ratio  interfere. pressure head of 40 cm of Hg
I I (a) 10.3 ms -1 (b) 2.8 ms -1
Find the ratio max min in the interference pattern.
Imax  Imin (c) 5.6 ms -1 (d) 8.4 ms -1
4 MOCK TEST 5

24. A source of sound of frequency 600 Hz is placed 31. Chemical formula of Malachite ore and Cerrusite ore
inside water. The speed of sound in water is 1500 respectively is:
ms-1 and in air it is 300 ms-1. The frequency of sound (a) 2CuCO3.Cu(OH)2 and PbSO4
recorded by an observer who is standing in air is (b) 2CuCO3.Cu(OH)2 and PbCO3
(a) 200 Hz (b) 3000 Hz (c) CuCO3.Cu(OH)2 and PbCO3
(c) 120 Hz (d) 600 Hz (d) MgCO3.CaCO3 and PbSO4
25. A coil has an inductance of 0.7 H and is joined in 32. Froth floatation process for the concentration of ores
series with a resistance of 220. W hen an is applied for the extraction of:
alternating e.m.f. of 220 V at 50 cps is applied to it, (a) Cu (b) Al
then the wattles component of the current in the
(c) Fe (d) Na
circuit is
33. Upon heating a litre of N/2 HCl solution, 2.675 g of
(a) 5 A (b) 0.5 A
HCl is lost and the volume of the solution shrinks to
(c) 0.7 A (d) 7 A 750 ml. The normality of the resultant solution is:
CHEMISTRY (SECTION – B) (a) 0.1 (b) 0.57 (c) 5.6 (d) 1.2
34. For the complex ion [Cr(H2O)6]3+, the hybridization
26. When 0.1 mol of CH3NH2 (Kb = 5 × 10–4) is mixed
and magnetic moment are respectively.
with 0.08 mol of HCl and diluted to 1 L, the H+ ion
concentration in the solution is (a) sp3d2, paramagnetic
(a) 8 × 10–2 M (b) 8 × 10–11 M (b) d2sp3, paramagnetic
(c) 1.6 × 10–11 M (d) 8 × 10–5 M (c) sp3d2, diamagnetic
27. For the reaction (d) d2sp3, diamagnetic
35. An aqueous solution containing 5.0 gm of horse
 Ag(CN)2 (aq) 
–

 
 Ag(aq)  2CN(aq) , the equilibrium
–
haemoglobin in 1 litre of water shows an osmotic
constant at 25°C is 4.0 × 10–19. Calculate the silver pressure of 1.80  10 –3 atm at 298 K. What is the
ion concentration in a solution which was originally molecular weight of horse haemoglobin ?
0.10 M in KCN and 0.03 M in AgNO3.
(a) 6800 (b) 34000
(a) 1.5 × 10–18 M (b) 2.5 × 10–18 M
(c) 68000 (d) 3400
(c) 7.5 × 10–18 M (d) 5.5 × 10–18 M
28. The number of moles of urea (solute) needs to be 36. N2O 4 + H 2O  A + B
dissolved in 100 g of water in order to decrease the

vapour pressure of water by 25% is B  C + NO + H2O
(a) 1.39 (b) 2.9
C + H2O  A + B
(c) 3.9 (d) 2.0
Identify B and C (respectively)

29. The correct order of acidic strengths is (a) HNO3, N2O (b) HNO2, HNO3
(a) Cl2O7 > SO3 > P4O10 (c) HNO2, NO2 (d) NO2, HNO3
(b) CO2 > N2O5 > SO3  2HI(g)
37. For the reaction H2(g) + I2(g) 
(c) Na2O > MgO > Al2O3
K = 55.3 at 699 K. In a mixture that consists of 0.70
(d) K2O > CaO > MgO
atm of HI and 0.02 atm each of H2 and I2 at 699 K,
30. Which one of the following statements is not correct?
what will happen?
(a) The first ionization energy of Be is greater than
(a) HI will be consumed
that of B
(b) HI will be formed
(b) 2p-orbital is lower in energy than 2s
(c) NO change
(c) F atom has a less electron affinity than Cl atom
(d) The increasing order of size, Ca2+ < Ar < Cl– < (d) HI may be consumed or formed.
S2–
 MOCK TEST 5 5

38. Which of the following is not aromatic ? 44. Consider a reaction; aG + bH  products. When
concentration of both the reactants G and H is
doubled, the rate increase by eight times. However,
(a) (b) when concentration of G is doubled keeping the
concentration of H fixed, the rate is doubled. The
overall order of the reaction is:
(a) 0 (b) 1
(c) (d) (c) 2 (d) 3
..
N
.. N
x
H 45. Graph between log and log P is a straight line
m
39. Which of the following carbides, on hydrolysis, yields
inclined at an angle q = 45°. When pressure of 0.5
methane?
atm and log k = 0.699, the amount of solute adsorbed
(a) Be2C (b) MgC2 per gram of adsorbent will be (log k = intercept)
(c) CaC2 (d) Mg2C3 (a) 1 g/g adsorbent (b) 1.5 g/g adsorbent
40. Chlorine gas is dried over (c) 2.5 g/g adsorbent (d) 0.25 g/g adsorbent
(a) CaO (b) NaOH 46. Heat of atomization of NH3and N2H4 are x kcal mol-
(c) KOH (d) Conc. H2SO4
1
and y kcal mol-1 respectively. Calculate average
bond energy of N-N bond.
41. In analytical chemistry, solid K 2Cr 2O 7 is used to
detect the presence of which acid radicals? 4y  3x 2y  3x
(a) kcal mol-1(b) kcal mol-1
(a) F (b) Cl 3 3
(c) Br (d) I 4y  3x 3y  4x
(c) kcal mol-1 (d) kcal mol-1
4 3
42. W hen a large amount of KMnO 4 is added to 47. The optical rotation of the  -form of a
concentrated H 2SO 4, then explosive compound pyranose is +150.7°, that of the  -form is
formed is:
+52.8°. In solution an equilibrium mixture of
(a) Mn2O7 (b) Mn3O4 the anomers has an optical rotation of 80.2°.
(c) MnO3 (d) MnO 3 The percentage of the  -form at equilibrium
is
O
(a) 28% (b) 32%
C
(c) 68% (d) 72%
43. O
O
C
O SeO2
48.   (A); Product (A) of the reaction
HO
 (A) 
PCl5 LiAIH4
(B) 
PCC
(C) 

(D) ,
Product D is
is:
CH2 – OH CO–
2
O O
(a) (b)
OH O
CO–
2 CO–
2 (a) (b)

–
CH2 – OH CH2 – O
O O
(c) (d)
O
CH2 – OH CH2 – O–
(c) (d)
6 MOCK TEST 5

53. The equation of the plane through the line of

OH intersection of planes ax + by + cz + d = 0, ax + by
NH2
+ cz + d=0 and parallel to the line y = 0, z = 0 is
Br / KOH
49. O 
2  product; (a) (ab – ab)x + (bc – bc)y + (ad – ad) = 0
(b) (ab – ab)x + (bc – bc)y + (ad – ad)z = 0
(-hydroxy amide)
(c) (ab – ab)y + (ac – ac)z + (ad – ad) = 0
Product of this Hoffmann bromamide reaction is: (d) (ab + ab)y + (ac + ac)z + (ad + ad) = 0
54. Let a, b, c be the sides of a triangle whose perimeter
O
is P and area is A, then
(a) Ph – C – CH3 (b) Ph – CHO (a) P3  27(b + c – a) (c + a – b) (a + b – c)
(b) P2  3(a2 + b2 + c2)
OH
(c) Ph – CH (d) Ph – CH2 – NH2 (c) a2 + b2 + c2  8 3 A
NO2
(d) P4  25 < A
55. Number of values of x  R which satisfy the equation
50. What are the products of the following reaction?
cos(  x  4)cos(  x )  1 is
excess HBr (a) 1 (b) 0
OCH2CH2OH  
heat
(c) 2 (d) none of these
      
56. Let r   a  b  sin x   b  c  cos y + 2  c  a 
(a) Br OCH2CH2Br
   
where a, b & c are three noncoplanar vectors. If r
  
is perpendicular to a  b + c, then minimum value
(b) Br + BrCH2CH2OH of x2 + y2 is
2
(a)  (b)
4
(c) OH + BrCH2CH2Br 52
(c) (d) None of these
4
57. Three points are chosen randomly on the circle. The
probability that they lie on a semicircle is
(d) Br + BrCH2CH2Br 1 1
(a) 4 (b)
2
2
MATHEMATICS (SECTION – C) (c) (d) None of these
3
6 11 58. If adj B = A. |PBQ| = 1 and |P|, |B|, |Q| belongs to
51. Matrix A is given by A    , then the set of natural numbers then (Q–1 B P–1)–1 is equal to
2 4 
determinant of (A2005 – 6.A2004), is (a) PAQ (b) PBQ
(a) 22006 (b) (–11).22005 (c) QAP (d) QBP
(c) –22005 (d) (– 9).(2)2004 59. The number of common tangents to the hyperbola
xy = c2 and the circle x2 + y2 = 2c2 is
52. If origin and non-real roots of 2z2 + 2z +  = 0 form
three vertices of an equilateral triangle in argand (a) 4 (b) 2
plane then  is (c) 8 (d) infinite
60. If x1 x2 x3 = 2.5.7 , then the number of different
2
2
(a) 2 (b) solutions for the ordered triplets (x1, x2, x3) where xi
3
 N, xi > 1 is
3
(c) – 1 (d) (a) 24 (b) 81
2
(c) 36 (d) 21
 MOCK TEST 5 7

69. The coordinate of the point on y = 8x, which is2

61. The foci of the hyperbola

 x  22   y  3  2  1
closest from x2 + (y + 6)2 = 1 is/are
16 9 (a) (2, – 4) (b) (18, – 12)
are (c) (2, 4) (d) none of these

(a)   5, 0 (b)  0,  5
1
70. x 2
(x 4  1)3 / 4
dx is equal to
(c) (–2, –2); (–2, 8) (d) (3, 3) & (–7, 3) 1/ 4
 1
62. The numerically greatest term is the expansion of (a)  1  4  c (b) (x4 + 1)1/4 + c
 x 
3 1/ 4 1/ 4
(2 – 3x)12 when x = is  1  1
4 (c)  1  4   c (d)   1  4   c
 x   x 
(a) T5 (b) T6 71. Number of ordered triplets of natural number (a, b,
(c) T7 (d) T8 c) for which abc  11 is
63. Find the value of l if the points (2, 3, –1), (5, –1, 2), (a) 52 (b) 53
(– 4, 1, 3) & (0, 2, l) are coplanar
(c) 55 (d) 56
2 1 
(a)
3
(b)
3 72. The position vector of a point P is r  xiˆ  yjˆ  zkˆ ,
 
2 1 when x,y,z  N and a  ˆi  ˆj  kˆ and r·a  10 , the
(c) – (d) – number of possible position of P is
3 3
64. Distance between the two parallel planes 3x – 4y + (a) 36 (b) 72
12z – 17 = 0 & 6x – 8y + 24z + 18 = 0 is (c) 66 (d) 9C2
(a) 2 (b) 4 73. In the next World Cup of cricket there will be 12
(c) 1 (d) 3 teams, divided equally in two groups. Teams of each
65. Find the value of [a] if the lines group will play a match against each other. From
each group 3 top teams will qualify for the next round.
x  2 y  4 z 1 x 1 y 1 z  a
  &   are In this round each team will play against others once.
3 2 5 2 3 4 Four top teams of this round will qualify for the
coplanar where [ ] denotes greatest integer function
semifinal round, where each team will play against
(a) 7 (b) 8
the others once. Two top teams of this round will go
(c) 9 (d) 10 to the final round, where they will play the best of
three matches. The minimum number of matches
[cos x], x 1
66. If f(x) =  ([.] denotes the in the next World Cup will be
 | x  2 |, 1  x  2
(a) 54 (b) 53
greatest integer function), then f(x) is
(c) 38 (d) 58
(a) continuous and non-differentiable at x = – 1 and 74. Let A(0, 2), B and C are points on parabola y2 = x +
x=1

(b) continuous and differentiable at x = 0 4 and such that CBA  then the range of
2
(c) discontinuous at x = 1/2 ordinate of C is
(d) none of these (a)  ,0    4,   (b)  ,0    4,  
67. The value of m for which the area of the triangle
(c) 0,4  (d)  ,0    4,  
included between the axes and any tangent to the
curve xmy =bm is constant, is 75. The locus point of intersection of tangents to the
(a) 1 (b) 2 parabola y2 = 4ax, the angle between them being
always 45° is
(c) 3 (d) 4
68. Let f(x) = x + ax + bx + 5sin2x be an increasing
3 2 (a) x 2  y 2  6ax  a2  0
function in the set of real numbers R. Then, a and b (b) x 2  y 2  6ax  a2  0
satisfy the condition
(a) a2 – 3b – 15 > 0 (b) a2 – 3b + 15 > 0 (c) x 2  y 2  6ax  a2  0
(c) a2 – 3b + 15 < 0 (d) a > 0 and b > 0 (d) x 2  y 2  6ax  a2  0
8 MOCK TEST 5

ANSWERS
1. (b) 2. (19.6 m/s) 3. (c) 4. (b) 5. (d) 6. (b) 7. (a) 8. (b) 9. (b) 10. (b)
11. (b) 12. (c) 13. (d) 14. (4.0J) 15. (b) 16. (b) 17. (a) 18. (b) 19. (d) 20. (a)

21. (a) 22. (b) 23. (2.8ms–1) 24. (600Hz) 25. (0.5 A ) 26. (b) 27. (c) 28. (1.39)
29. (a) 30. (b) 31. (c) 32. (a) 33. (0.57) 34. (b) 35. (c) 36. (c) 37. (a) 38. (a)
39. (a) 40. (d) 41. (b) 42. (a) 43. (a) 44. (3) 45. (2.5) 46. (d) 47. (28%) 48. (b)
49. (b) 50. (c) 51. (b) 52. (b) 53. (c) 54. (b) 55. (1) 56. (c) 57. (a) 58. (a)
59. (2) 60. (21) 61. (c) 62. (b) 63. (a) 64. (2) 65. (a) 66. (c) 67. (1) 68. (c)
69. (a) 70. (d) 71. (d) 72. (a) 73. (b) 74. (b) 75. (c)

EXPLANATIONS
1. For collision, 4. Acceleration of the cylinder down the plane is
       
r1  1t  r2  2t or r1  r2  ( 2  1)t
a = (g sin 30°) (sin 30°) = 10  1  1
   2.5 m / s
2

V2t  2  2 

2s 25
Time taken: (t) =  2s
a 2.5
v 2t
+
r2 r2 v 1t V1t 5. Free body diagrams (figure):
+
r1

mg mg N
r1 F
A B
Equating unit vectors, we get
    F = N N N
r2  r1  
    2 1
| r2  r1 | | 2  1 |

2. Suppose  be the velocity of the body after falling Equations of motion:

through half the distance. Then F
aB  (in  x  direction)
39.2 M
s  19.6 m, u  0 and g  9.8 m / s2
2
F
2  u2  2gh  02  2  9.8  19.6 aA  (in  x  direction)
M
   19.6 ms.
Relative acceleration of A w.r.t. B:
When the acceleration due to gravity ceases to act,
the body travels with the uniform velocity of 19.6    F F m M
a A , B  a A  aB     F  
m/s. So it hits the ground with velocity 19.6 m/s. m M  mM 

3. y = ax – bx2, for height or y to be maximum: dy  0 (along – x – direction)

dx
Initial relative velocity of A w.r.t. B
a
or a – 2bx = 0 or x  uA,B = 0
2b

2
Final relative velocity of A w.r.t. B = 0
 a   a  a2
i. ymax = a   b   Using
 2b   2b  4b 2  u2  2as

F(m  M)
 dy  0  02  2 S
ii.    a  tan 0 mM
 dx  x  0
Fm 20
S
where 0 = angle of projection 0 = tan–1a. 2F(m  M)
 MOCK TEST 5 9

2 12. Assume L0 is the natural length of the spring.

6. U  kqQ  kqQ  kq  0
r r 2r Hence, k L1  L0   4 ...(1)

Q 1 k L 2  L0   5 ...(2)
 
q 4
and k L3  L0   9 ...(3)
7. C1 = C, V1 = V0, C2 = KC, V2 = 0, and
Solving (1) and (2), we get L0  5L1  4L 2 and
Vcommon = V
1
k
L 2  L1
C1V1  C2 V2
We know that Vcommon = C1  C2 substituting these in (3), we get L3  5L2  4L1

CV0  KC  0 13. Apply Mechanical energy conservation:

V
C  KC GMm GMm 1
   mv 2 and solve for v and use
r R 2
V0 GM
K 1 g
V R2
14. Work to be done to stop the hoop = Kinetic energy
V 2
8. r    0.4  of the hoop
I 5
2
v
when i = 0, the potential reading is 2 V. hence emf
1 1 1 1
 
 I2  mv 2  mR2    mv 2  mv 2  4.0 J
2 2 2 R 2
= 2V
15. The amount of work done in the round trip =

9. From Kirchhoff’s rule, L di   and U  1 Li2 Work done against friction

dt 2
3
10. =  mgcos    d  0.1 0.5  10   20  5 3 J
2

I
16. Let the object distance be x. Then, the image
distance is D – x.
From lens equation,
P

  1 1 1
d  
x Dx f
ds
in


On algebraic rearrangement, we get

On solving for x, we get

Let us compute the magnetic field due to any one D  D(D  4f )

x1 
segment: 2

0i D  D(D  4f )
B (cos 0  cos(180   )) x2 
4 (dsin  ) 2

0I I  The distance between the two object positions is

 (1  cos  )  0 tan
4(dsin  ) 4d 2
d = x2 – x1 = D(D  4f )
Resultant field will be:
0I  I
17. It is given a1  I1  
Bnet = 2B = tan  K 0 a2 I2
2d 2 2d
Imax = (a1 + a2)2
f f f Imin = (a1 – a2)2
11. : :  1: 3 : 4
2L1 2L 2 2L 3
Imax  Imin a1  a2 )2  (a1  a 2 )2 2a1a2
1 1 = 
 L1 : L 2 : L 3  1: :  12 : 4 : 3 Imax  Imin a1  a2 )2  (a1  a2 )2 a12  a22
3 4
a 
Now, 12x + 4x + 3x = 114  x=6 2 1 
  a2   2 
Therefore, L1 = 72 cm, L2 = 24 cm, L3 = 18 cm,  a1 
2
 1
which is 72 cm and 96 cm from one end.   1
 a2 
10 MOCK TEST 5
18. The maximum KE of the photoelectron is given by 25. Wattless component of AC
Ev 200 L
1 2 = IV sin = sin  = 
 mv   h  W Z R 2  2L2 R 2  2L2
2 max
200  L
= (R2  2L2 )
c 1 
Now, v   and  mv 2   eV
2  As L = 0.7 × 2p × 50
Hence, wattless component of AC
hc
 eV  W 200  (0.7  2  50) 1
    0.5 A
(220 2  2202 ) 2
  hc 1 W
or V   e    e 26. CH3NH2 + HCl 

 
 CH3NH3 Cl
–
 
t=0 0.1 0.08 0
Since V is represented along y-axis and (1/) along
teq (0.1 – 0.08)
x-axis, the above equation represents a straight line.
= 0.02 0 0.08
Slope of straight line = hc/e
This is a basic buffer
Intercept of straight line = – (W/e)
K b [Base]
OH–  
2e 2 [salt]
19. vn  k
nh Kw K [salt] 1014  0.08
H    w 
We know that in cgs system k = 1 [OH ] K b [Base] 5  104  0.02
–

4 10
2e 2 2e 2 = 5  10  8  1011 M
 vn   v1 
nh h
27. 2KCN + AgNO3 
 K[Ag(CN)2] + KNO3


v1 2e 2
So 
c ch 0.1 M 0.03 0
20. According to Avogadro’s hypothesis, (0.1 – 0.06) 0 0.03
6.02  10 23 = 0.04
N0   2.66  10 21
226 Again by dissociation some Ag+ is formed
0.693 [Ag(CN)2]– 
 Ag + 2CN

 + –
Half-life = T   1620 years

0.03 0 0.04
0.6931
  = 1.35 × 10 s –11
1 –1 (0.03 – a) a (0.04 + 2a) where a is
1620  3.16  107
Because half-life is very much large as compared to the new Ag ion concentration
+

its time interval, hence N = N0. Now,  Ag  CN– 

2
a(0.04  2a)2
K  4  1019 
 Ag(CN)2  (0.03  a)
–
dN
 N  N0
dt
2
a(0.04)
or dN = N0dt on solving 4 × 10–19 
0.03
= (1.35 × 10–11) (2.66 × 1021) × 1= 3.61 × 1010
i.e., a = 7.5 × 10 –18
M

21. 
F A
x
Fh


100  0.5  10 2 
 2  10 8 m
28. By Raoult’s law,
xh A 
5  10 4  5  1010    p w  M

p0 m  W
22. The metals used beyond elastic limit without being
ruptured are called ductile materials and this 25 w  18
 ; w  83.33 g
property is called ductility. 100 60  100
2 P
23. Velocity head  v and pressure head  Number of moles of urea =
83.33
 1.388 = 1.39
2g g 60

2 29. Cl2O7 > SO3 > P4O10

Given, v  0.4  v  2  9.8  0.4  2.8ms-1 In the periodic table, acidic nature of oxides
2g
increases from left to right and it decreases down
24. No change in frequency of sound due to change in
the group.
medium.
 MOCK TEST 5 11

30.  The first ionization energy of Be is greater than = 35  35

that of B because of its relatively stable electronic Q>K
configuration.
 reaction will move towards backward.
Be4 1s2 2s2
B5 1s2 2s2 2p1 (unpaired electron).
 2p orbital is of higher energy than 2s 38.
(n + l) value for 2p (2 + 1) = 3
(n + l) value for 2s (2 + 0) = 2 cyclic e– cloud contains only 12e– not 14e–
 in F atom, due to its small size, the electrons are It will be anti – aromatic.
already crowded. Entry of further electron results in
repulsion. 39. Be2C  4H2O  2Be(OH)2  CH4
 All
the ions Ca2+, Ar, Cl– and S2– are isoelectronic. 40. All others are base.
As the number of protons (at. no.) increases, size 41. When any salt containing chloride is heated with
decreases due to stronger attraction on the electrons. solid K2Cr2O7 and H2SO 4, red vapours of chromyl
chloride escapes which is soluble in water.
33. 1000 ml. of N/2 HCl contains 36.5  18.25 g of HCl
2 42. 2KMnO4 + 3H2SO4  Mn2O7  2K   H3O  3HSO4
Weight of HCl lost on evaporation = 2.675 g (exp losive)

Weight of HCl in 750 ml. of solution after evaporation O

= 15.575 g C – Cl CH2OH
15.575  1000
Weight of HCl in 1 L solution = 43. (A) (B)
750
C – Cl CH2OH
weight per litre
Normality of the resultant solution = gm. equivalent O
15.575  1000
=  0.569 O
750  36.5
–
34. Cr24  1s2 2s2 2p6 3s2 3p6 3d5 4s1 C–H CO2

Cr3+  1s2 2s2 2p6 3s2 3p6 3d3 4s0 (C) 
KOH, 
 (D)

3d 4s 4p C–H CH2OH
xx xx xx xx xx xx O

e– pairs donated by 6H 2O (Intramolecular Cannizaro reaction).

ligands (weak field)
44. Rate  K Gx Hy
 d2sp3 – paramagnetic
From the data: 8 = 2x · 2y21 = 2x|
 1.80  10 3
35. C =  = 0.74×10 –4 mole/litre x=1 y=2  x+y=3
RT 0.0821  298
x 1
5.0 45. m  K P n

molecular weight = = 68,000

0.74  10 4
x 1
log  log P  log K
36. N2O 4 + H 2O  HNO 3 + HNO 2 m n

 1
2HNO2   NO2 + NO + H2O slope   tan   tan 45
x
(C)
x
H2O log  log0.5  0.699
2NO2   HNO3 + HNO2 m

(C) (A) (B) x

 log0.5  log5 log  log2.5
37. At 699 K; Reaction quotient m

x
PHI 2  2.5
0.7  0.7 m
= 
PH PI 
2 2
0.02  0.02
12 MOCK TEST 5
46. 53. Let the plane be ax + by + cz + d + (ax + by + cz
H N H + d) = 0
N + 3H  H = x kcal/mol
H since it is parallel to x-axis
H N N H
a
2N + 4H  H = y kcal/mol  (a + a).1 = 0i.e.   
H H a
47.  form is = x%
 form is = (100 - x)%
 equation of the plane is ax + by + cz +
100  x  a
150.7   
x
  52.8   80.2 x = 28% d – a (ax + by + cz + d) = 0
100  100 
48. SeO2 oxidizes active methylene and methyl groups i.e. (ab – ab)y + (ac – ac)z + (ad – ad) = 0
to ketonic and aldehydic groups respectively. 54. in ABC
Besides oxidation of the active methylene and
methyl groups, the reagent has been employed for b + c – a > 0, c + a – b > 0, a + b – c > 0, so
allylic hydroxylation, allylic oxidation, (b  c  a)  (c  a  b)  (a  b  c)
dehydrogenation and as a catalyst in some 3
reactions.
1
Activated ring methylene groups are also oxidized  {(b  c  a)(c  a  b)(a  b  c)} 3
to carbonyl groups.
1
O O P
SeO2   {(b  c  a)(c  a  b)(a  b  c)} 3
2
O  P3  27(b  c  a)(c  a  b)(a  b  c) ... (i)
Cyclohexanone Cyclohexan-1,2-dione
49. Also (a  b  c)  (b  c  a)  (c  a  b)  (a  b  c)
4
OH O OH O 1
Br2  {(a  b  c)(b  c  a)(c  a  b)(a  b  c)} 4
Ph CH C NH2 Ph CH NH2 Ph C H
KOH
(Hoffmann (unstable)
bromamide 2P
  (16A)1/ 4
reaction) 4

O CH2 CH2 OH OH  P  4A1/4

HBr Br  P4  256A
50. +
Br For a given perimeter equilateral  has the greatest
2
51. A 2005  6A 2004 | A |2004 | A  6I2 | 3 P
area. So area of any triangle A   
4 3
0 11
 (2)2004  ( 22)(22004 )  ( 11)(22005 ) 3 2
2 2 A P ...(ii)
36
52. 2z + 2z +  = 0
2
Now P2 = (a + b + c)2
2  4  8 = a2 + b2 + c2 + 2(ab+ bc + ca)
z
4 = 3(a2 + b2 + c2) – (a2 + b2 + c2 – ab – bc – ca)
for non-real roots 4 – 8 < 0 P2  3(a2 + b2 + c2) ...(iii)
1
 >  A 3
2 3(a2  b2  c 2 )
36
for equilateral triangle
z1  z2  z 2  z3  z3  z1 a2 + b2 + c2  4 3 A
55. Given equation is true only when
1  i 2  1 1  i 2  1 1  i 2  1
 0  
2 2 2 cos(  x  4)  1 and cos(  x )  1

1  i 2  1 or cos(  x  4)  1 and cos(  x )  1

 0
2
 either  x  4 and  x both are even integer
1
or (1  2  1)  ( 2  1)2
4 or both are odd integer
 2  x = 4 is the only solution
  2  1   
2 3  number of solution = 1
 MOCK TEST 5 13
 
56. r   a  b  sin x  b  c  cos y  2  c  a  dy y c/t
59. dx   x   ct    2
1
t
   
r.  a  b  c   0 c 1
y  (x  ct)
   t t2
a,b,c   sin x  cos y  2   0
x + t2y – 2ct = 0
  
a,b,c   0  sinx + cosy = –2 it will be tangent to the circle if
This is possible only when sin x = –1 and cos y 2ct
 2c i.e. 2t2 = 1 + t4
= –1 1  t4

 i.e. t = ± 1
for x 2 + y 2 to be minimum x =  and
2  there are two common tangents.

2 5 2
It is clear from the diagram also.
y =   minimum value of (x2 + y2) is =  2 
4 4 60. x1 x2 x3 = 2.5.72
57. Total 10 × 7 × 7  3 ways
x 14 × 5 × 7  6 ways
A B
35 × 2 × 7  6 ways
r 2 × 5 × 49  6 ways
Total number of ways = 21
y
25 5
61. 16 = 9(e2 – 1)  e2  e
9 3
2r – x – y foci are  2, 3  5 = (–2, –2); (–2, 8)
C
9
x > 0, y > 0, 2pr – x – y > 0 13 
62. P 8  117
Favourable: 9 17
1
8
x B  Greatest term is T 47   T7
A y  17   1
 
C x > 0, y > 0, x + y < r 3 6 2
2
63. 4 2 1  0   
3
3 4  1

y 18  34 52
64. d   2
2 2
6  8  24 2 26

3 5 1  a
x 102
+ 65. 3 2 5 0a
y 13
=
2 2 3 4
x r
+
y
=
r 66. We have, f(x)   [cos x], x  1
| x  2 |, 1  x  2
x
= 2 – x, 1 x  2

 1
1, 2  x  1
1 
r.r 1 0, 0  x  1
Probability = 2  
1 2
2r.2r 4 
2 1, x  0
 1
0,   x  0
58. |PBQ| = 1  |P| |B| |Q| = 1  |B| = 1 (as |P|, |B|, |Q|  2
 3 1
are natural numbers) 1,   x  
 2 2
 B–1 = adjB = A
It is evident from the definition that f(x) is
 (Q–1BP–1)–1 = PB–1Q = PAQ discontinuous at x = 1/2.
14 MOCK TEST 5
67.  xmy = bm dD
 163  2(4  6).4  0
Taking logarithm d
m logex + logey = m logeb  23 + 4 + 6 = 0  3 + 2 + 3 = 0
m 1 dy
 0
 (2 –  + 3) ( + 1) = 0

x y dx
  =–1 (  2 –  + 3  0)
dy my
  d2D
dx x Now,  48 2  8.4
d 2
Equation of tangent at (x, y) is
= 482 + 32 > 0 at  = – 1
my
Y–y=  (X  x)  D is minimum at  = – 1.
x

xY – xy = – myX + mxy Point on parabola (2, – 4).

 my X + xY = xy(1 + m)
dx dx
X Y
70.    1 
3/4

 1
3/4
  1 x 2 x 4 1  4  x5  1  4 
x(1  m) y(1  m)
  x   x 
m
1 1
 Area of triangle OAB = 2 .OA.OB Put 1   t4,
x4
4
  dx  4t 3 dt
x5
B 1/ 4
t 3dt  1
  t3
 t  c    1  4 
 x 
c

71. abc = 1 in 1 ways

abc = 2, 3, 5, 7, 11 in 15 ways
abc = 4, 9 in 10 ways
O A
abc = 8 in 10 ways
1 x(1  m) abc = 6, 10 in 18 ways
 . | y(1  m) |
2 m
So, total number of solution is 56
| xy | (1  m)2
 72. r·a  10
2|m|
For m = 1,  x  y  z  10, x,y,z  N

| xy | (4) 10 1
 no. of solutions = C3 1  36
2
73. Use selection
= 2|xy| (  xy = b)
= 2|b| = constant   
74. A  0,2 , B  t1  4, t1 C  t  4, t
2 2

68. f(x) > 0
2  t1 t1  t 1 1
·  1  ·  1
 3x2 + 2ax + b + 5 sin 2x > 0 4  t12 t12  t 2 2  t1 t  t1
 3x2 + 2ax + b – 5 > 0 (  sin 2x  – 1)
 t12   2  t  t1   2t  1  0
 D<0
For real t1 ,
4a2 – 4.3.(b – 5) < 0
  2  t   4  2t  1  0  t 2  4t  0  t   ,0   4,  
2
 a2 – 3b + 15 < 0.
69. Let point on parabola y2 = 8x be (22, 4) a
75. Equation of tangent is y  mx 
Centre of circle = (0, – 6) m
Distance between centre of circle and point on  m2 x  my  a  0  m1  m2 
y
,m m 
a
parabola x 1 2 x
2 2
m1  m2 y a  a
S  (2 2 )2  (4  6)2 tan 45      4    1  
1  m1m2 x x  x
D = 44 + (4 + 6)2
x 2  y 2  6ax  a 2  0
where D = S2
 MOCK TEST – 6
PHYSICS (SECTION – A) 5. A particle of charge per unit mass  is released

1. The variation of potential with distance R from fixed from origin with velocity V   V0 ˆj in a magnetic field
point is shown in figure. The electric field at R = 5 m
 3 v0 
is B  B0kˆ for x and B0 for
2 V0 
VIV
5 3 v0
x . The x-coordinate of the particle at time
4 2 B0 
3
2   
t  would be
1  3B 0 

R/m
1 2 3 4 5 6
3 v0 3   
(a)  v0  t  
(a) 2.5 Vm –1
(b) – 2.5 Vm –1
2 B0  2  B0  
(c) 0.4 Vm –1
(d) – 0.4 Vm–1
2. A parallel plate capacitor has plates of area A and 3 v0   
(b)  v0  t  
separation d and is charged to a potential difference 2 B0  3B 0 

V. The charging battery is then disconnected and
the plates are pulled apart until their separation is
3 v0 v   
2d. What is the work required to separate the plates (c)  0 t  
__________(V) 2 B0  2  3B0  
3. In the given circuit of figure, with steady current, the
potential drop across the capacitor must be 3 v0 v t
(d)  0
2 B0  2
V R
6. A ball is thrown from the top of a tower in vertically
V C upward direction. Velocity at a point hm below the
point of projection is twice of the velocity at a point
2V 2R h m above the point of projection. Find the maximum
(a) V (b) V/2 height reached by the ball above the top of the tower.
(c) V/3 (d) 2V/3 (a) 2h
4. In the circuit shown in figure, switch S is closed at (b) 3h
time t = 0. The charge that passes through the (c) (5/3)h
battery in one time constant is
(d) (4/3)h
7. At a height 0.4 m from the ground, the velocity of a
L R

projectile in vector form is   (6iˆ  2ˆj) m / s. The
angle of projection is
E S (a) 45°
2
eR E (b) 60°
(b) E  
L
(a)
L  
R (c) 30°
EL eL (d) tan–1(3/4)
(c) (d)
eR 2 ER
2 MOCK TEST 6

8. In the figure, the ball A is released from rest, when 11. A body starts from rest on a long linclined plane of
the spring is at its natural (unstretched) length. For inclination 45°. The coeffiecient of friction between
the block B of mass M to leave contact with ground
the body and the plane varies as   0.3 x , where x
at some stage, the minimum mass of A must be
is the distance travelled down the plane. The body
will have maximum speed when x is equal
to__________(m) [Take g = 10 ms–2]
12. A man slides down a light rope whose breaking
strength is  times his weight. What should be his
maximum acceleration so that the rope does not
A break ?
g
(a) g (b)
1 
B
g
M (c) g 1  (d)
1 
(a) 2 M (b) M 13. A ball whose kinetic energy is E, is projected at
(c) M/2 (d) M/4 angle of 45° with the horizontal. The kinetic energy
9. Velocity of point A on the rod is 2 m/s (leftward) at of the ball at the highest point of its trajectory will
the instant shown in the figure. The velocity of the be :
point B on the rod at this instant is E
(a) E (b)
1m 2
E
B (c) (d) zero
2
14. A sphere, a cube and a thin circular plate, all of
5m same material and same mass are initially heated
to same high temperature. Choose the correct
statement:
(a) Plate will cool fastest and sphere the slowest
VA = 2 ms–1 (b) Plate will cool fastest and cube the slowest
60°
A (c) Sphere will cool fastest and cube the slowest
2 (d) Cube will cool fastest and plate the slowest
(a) m/s (b) 1 m/s
3 15. Two particles A and B are oscillating about a point O
1 along a common line such that equation of A is given
m/s 3
(c) m/s
(d) as: x1  acos t and equation of B is given as:
2 3 2
10. A block of mass 4 kg is pressed against the wall by  3 
x 2  b sin  t   , then the motion of A w.r.t. B is
a force of 80 N as shown in the figure. Determine  2
the value of friction force and block’s acceleration,
(a) a simple harmonic with amplitude a  b
(Take s = 0.2, k = 0.15).
(b) a simple harmonic with amplitude a2  b2
(c) a simple harmonic with amplitude  a  b
(d) not a simple harmonic motion
4 kg
80 N 16. A 2 m wide truck is moving with a uniform speed
0  8 m / s along a straight horizontal road. A
37°
pedestrian starts to cross the road with a uniform
speed  when the truck is 4 m away from him. The
(a) 8 N, 0 m/s2 (b) 32 N, 6 m/s2 minimum value of  so that he can cross the road
safely is__________(m/s)
(c) 8 N, 6 m/s2 (d) 32 N, 2 m/s2
 MOCK TEST 6 3

22. The electric potential V at any point (x, y,

17. A projectile is given an initial velocity of ˆi  2ˆj .
z) in space is given by V = 4x 2 volt. The
The cartesian equation of its path is (g = 10 electric field at (1, 0, 2) m in Vm -1 IS
m/s2). (a) 8, along the positive x-axis
(a) y = 2x – 5x2 (b) 8, along the negative x-axis
(b) y = x – 5x2 (c) 16, along the x-axis
(c) 4y = 2x – 5x2
(d) 16, along the z-axis
(d) y = 2x – 25x2
23. This question has Statement 1 and Statement 2. of
18. A small block of mass m rests on a smooth the four choices given after the Statements, choose
wedge of angle . W ith what horizontal the one that best describes the two Statements.
acceleration a should the wedge be pulley, as
Statement I: Very large size telescopes are
shown in the figure, so that the block falls freely.
reflecting telescopes instead of refracting
telescopes.
Statement II: It is easier to provide mechanical
m
a support to large size mirrors than large size lenses.
(a) Statement I is true, Statement II is false.
 (b) Statement I is false, Statement II is true
(c) Statement I is true, Statement II is true and
(a) g cos  (b) g sin  Statement II is the correct explanation of
(c) g cot  (d) g tan  Statement I
19. In the figure if f1, f2, and T be the frictional forces on (d) Statement I is true, Statement II is true but
2 kg block, 3 kg block and the tension in string, Statement II is not the correct explanation of
respectively, then their values are Statement I
1 = 0.1
24. The acceleration-time graph of a particle moving
8N
along a straight line is as shown in figure. At what
1N 2 kg 3 kg 1 = 0.2 time the particle acquires its initial velocity
__________(s)
(a) 2 N, 6 N, 3.2 N
(b) 2 N, 6 N, 0 N a(ms–2)
10
(c) 1 N, 6 N, 2 N
(d) Data insufficient to calculate the required value

7
20. Refractive index of a prism is and the angle of
3 t(s)
prism is 60°. The minimum angle of incidence of a 4
ray that will be transmitted through the prism is
25. A car is going in south with a speed of 5 m/s. To
(a) 30° (b) 45° a man sitting in car a bus appears to move
(c) 15° (d) 50°
towards west with a speed of 2 6 m / s. What is
21. A point charge of magnitude 1C is fixed the actual speed of the bus __________(ms –1)
at (0, 0, 0). An isolated uncharged spherical
conductor, is fixed with its centre at (4, 0, CHEMISTRY (SECTION – B)
0). The potential and the induced electric
26. Number of p – d bonds present in SO3 molecule
field at the centre of the sphere is
is__________
(a) 1.8 × 105 V and -5.625 × 106 V/m
27. Which one of these is not an acid salt?
(b) 0 V and 0 V/m
(a) NaH2PO4 (b) NaH2PO2
(c) 2.25 × 105 V and -5.625 × 106 Vm-1
(c) NaH2PO3 (d) Na2H2S2O7
(d) 2.25 × 105 V and 0 V/m
4 MOCK TEST 6

N O O
28. The percentage hydrolysis of NaCN in   aqueous
 80  33. H – O – C – (CH2)n – C – O – H   product, At
solution [Dissociation constant of HCN is 1.3 × 10–9 

and Kw = 1.0 × 10–14] is what value of (n) above compound will not evolve CO2
(a) 2.48 (b) 5.26 gas __________
(c) 8.2 (d) 9.6
29. At higher altitude, the boiling point of water lowers HC – OH
because C – OH
(a) atmospheric pressure is low 34. HO H , the given is enol form of:
(b) temperature is low H OH
(c) atmospheric pressure is high H OH
(d) temperature is high
CH2OH
30. The surface tension of water at 27°C is 72.75 dyne
cm–1. Its value in SI system is
(a) D-glucose (b) D-mannose
(a) 2.275 Nm–1 (b) 07275 Nm–1 (c) D-fructose (d) All of these
(c) 0.07275 Nm–1 (d) 0.2275 Nm–1 NH2 NH2
31. What is the major product of the following reaction?
OH CH3 35. and
CH3 – CH2 – C – CH 

H

Product
(aniline) (cyclohexyl amine)
CH3 CH3
can be differentiated by:
CH3 CH3 (a) Hinsberg test
CH3 CH CH3 CH CH3 (b) Iso-cyanide test
H
(a) C=C (b) C=C (c) NaNO2, HCl, then -Napthol
H CH3 (d) NaOH
CH3 CH3
CH3 36. Correct order of boiling point of following amines
Primary amine (I), secondary amines (II) and tertiary
CH CH3 CH3 CH3
H amine (III)
(c) C=C (d) C=C
(a) (I) > (II) > (III) (b) (III) > (II) > (I)
H CH2CH3 CH3CH2 CH3
(c) (II) > (III) > (I) (d) (II) > (I) > (III)
32. The correct order of rate of reaction toward
37. Which of the following is chiral.
nucleophilic addition reaction
CHO CHO CHO O
(a) CH3
H

(b) D
NO2 OMe
(a) (b) (c) H
O Cl
C Ph
(c) Cl
O
CH3 – C – Et H3C O
(d)
(d) (e)
O CH3
(a) a > b > c > d > e (b) a > b > d > c > e
(c) a > d > e > b > c (d) a > b > e > d > c
 MOCK TEST 6 5

38. One of the products of the following reaction, 41. Which of the following mixtures of solutions can
O function as a buffer solution?
(a) 50 ml of 0.2 M NH3 + 50 ml of 0.1 M HCl
C H
NaOD (Conc.) (b) 50 ml of 0.2 M NH3 + 50 ml of 0.2 M HCl
; is
(c) 50 ml of 0.2 M HCl + 05 ml of 0.2 M NaOH
(d) 50 ml of 0.1 CH3COOH + 50 ml of 0.1 M HCl
CH2 OD
42. Standard electrode potential of reactions are given
(a)
below:

CH2 OH (i) Sn4   2e   Sn2  , Eo  0.15 V

(b)
(ii) 2Hg2   2e   Hg22 , Eo  0.92 V

O (iii) PbO2  4H  2e   Pb 2   2H2O, Eo  1.45 V

C O D For these which statement is correct?
(c) (a) Pb2+ is more powerful reducing agent than Sn 2+
(d) Sn4+ is more powerful oxidising agent than Pb4+
OD (c) Hg2+ is more powerful oxidising agent than Pb 4+
C C (d) Sn2+ is more powerful reducing agent than Hg22 
(d) H O
43. The activation energy of reaction I is 80 kJ mol–1 and
39. Compound which undergoes nucleophilic substitution that of reaction II is 60 kJ mol–1. Which of the following
reactions most readily is statements is correct?
Cl (a) The rate constant of reaction I is greater than
that of II
(a) (b) (b) The rate constant of reaction II is greater than
that of I

OMe
(c) The order of reaction I is greater than that of II

Cl (d) The molecularity of reaction II is less than that

Cl Cl
of I.
O
(c) (d)

NO2 44. 
NaBH4
(A) 
H

(B) ;
NO2
O
40. Arrange the following in decreasing order of acidity?
Product (B) of the reaction is :
(I) (II) (III) (IV)
O O
OH OH OH OH
Cl
(a) (b)

Cl
OH
Cl O
O
(a) III > II > IV > I
(b) III > II > I > IV (c) (d)
(c) II > III > I > IV
(d) II > III > IV > I OH
6 MOCK TEST 6

45. The Lassaigne's extract is boiled with dil. HNO3 before  t t 

testing for halogens because 54. If P  1  ,2  be any point on a line, then
 2 2
(a) Na2S and NaCN are precipitated by HNO3 the range of values of t for which the point P lies
(b) Na2S and NaCN are decomposed by HNO 3 between the parallel lines x + 2y = 1 and 2x + 4y
= 15 is
(c) Ag2S is soluble in HNO 3
(d) AgCN is soluble is HNO 3 4 2 5 2 5 2
(a)  <t< (b) 0 < t <
46. A 10 L cylinder of oxygen at 4 atm pressure and 3 6 6
17°C developed a leak. When the leak was repaired 4 2
2.5 atm of O2 remained in the cylinder, still at 17°C. (c)  t0 (d) none of these
5
The no. of moles of gas escaped. 55. Number of normals drawn from the point (– 2, 2) to
(a) 1.2 mol (b) 0.30 mol the parabola y2 – 2y – 2x – 1 = 0 is__________
(c) 0.63 mol (d) 2.4 mol 56. The locus of the middle points of chords of an ellipse
47. A sample of wusitite FexO contains one Fe(III) for the tangents at the ends of which intersect at right
every three Fe(II). Calculate the value of x. x 2 y2
angles for the ellipse   1 is
(a) 2/5 (b) 19/5 a2 b2
(c) 8/9 (d) 16/15 (a) a4b4(x2 + y2) = (b2x2 + a2y2)2
48. How many grams of sucrose (M.wt = 342) should (b) a4b4(x2 + y2) = (a2 + b2)(b2x2 + a2y2)2
be dissolved in 100 g water in order to produce a
(c) a2b2(x2 + y2) = b2x2 + a2y2
solution with a 105°C difference between freezing
point and boiling point temperatures? (d) x2 + y2 = a2b2(b2x2 + a2y2)2
__________(g) (Kb = 0.51 and Kf = 1.86) 57. If the pairs of lines x2 + 2xy + ay2 = 0 and ax2 + 2xy
+ y2 = 0 have exactly one line in common then the
49. A bottle which contains 200 ml of 0.1 M NaOH absorbs
joint equation of the other two lines is given by
one m mol of CO2 from the air. If the solution then
treated with standard acid using phenolphthalein (a) 3x2 + 8xy – 3y2 = 0
indicator the normality found will be__________ (b) 3x2 + 10xy + 3y2 = 0
50. The molar concentration of NH 3 which provides (c) y2 + 2xy – 3x2 = 0
1.5 × 10 –3 M OH – ions will be__________(M) (d) x2 + 2x y – 3y2 = 0
[Kb(NH 4OH) = 1.8 × 10 –5]
58. Equation of the circle for which straight lines x2 + 3y
MATHEMATICS (SECTION – C) + xy + 3x = 0 are normals and size is just sufficient
so that it contains the circle x2 + y2 + 2x – 6y + 9
51. AA1, BB1 and CC1 are the medians of triangle ABC = 0 is
whose centroid is G. If points A , C1, G and B1 are
(a) (x + 3)2 + (y – 3)2 = 1
concyclic, then
(b) (x – 3)2 + (y + 3)2 = 1
(a) 2b2 = a2 + c2 (b) 2c2 = a2 + b2
(c) (x + 3)2 + (y – 3)2 = 9
(c) 2a2 = b2 + c2 (d) None of these
(d) (x – 3)2 + (y + 3)2 = 9
1  x2  1 2n 1
52. If tan1
x
 4 , then; 59. If (1 + 2x) (1 + x + x2)n = a x
r 0
r
r
and (1 + x + x2)s

(a) x = tan 2° (b) x = tan 4° n 2s

2s  b
a x r r
(c) x = tan (1/4)° (d) x = tan 8° = r , then s0 r 0
2n 1
r 0  ar 
53. If the variable takes values 0, 1, 2, 3, ..... n with
  r  1 
frequencies proportional to nC0, nC1, nC2, ...., nCn r 0

respectively, the variance is 2n  1

(a) 2n + 1 (b)
n n 2
(a) (b)
4 3 n 1
(c) (d) n + 1
2n 2
(c) (d) None of these
5
 MOCK TEST 6 7

60. The value of the expression 67. If [x] denotes the greatest integer less than or equal
 2 
2( + 1) ( + 1) + 3(2 + 1) (2 + 1) + 4(3 + 1)
2 2
to x, then   x  dx is equal to
(32 + 1) + .... + (n + 1) (n + 1) (n2 + 1) is ( is the 0
e 
cube root of unity)
(a) loge 2 (b) e2
2
n2 (n  1)2  n(n  1) 
(a)
4
(b)   n (c) 0 (d)
2
 2  e
2
 n(n  1)  68. If z = rei, then |eiz| is equal to
(c)   n (d) None of these
 2  (a) er sin  (b) re
r sin 

61. The minimum value of the expression (sinA +

r cos 
cosecA)2 + (cosA + secA)2 + (tanA + cotA)2 is (c) e r cos  (d) re
__________ 69 If |z1 – 1| < 1, |z2 – 2| < 2, |z3 – 3| < 3, then |z1 + z2 +
62. Let A and B are events of an experiment and P(A) = z3|
1 1 (a) is less than 6 (b) is more than 3
, P(A  B) = , then P(B/Ac) is
4 2 (c) is less than 12 (d) lies between 6 and 12
2 1
(a) (b) 70. If xy = 2(x + y), x  y and x, y  N, the number of
3 3 solutions of the equation
5 1 (a) two (b) three
(c) (d)
6 2 (c) no solution (d) infinitely many solutions
63. Consider the following statements.
71. Two natural numbers a and b are selected at random.
P: Suman is brilliant The probability that a2 + b2 is divisible by 7 is
Q: Suman is rich (a) 3/8 (b) 1/7
R: Suman is honest (c) 3/49 (d) 1/49
The negation of the statement “Suman is brilliant 72. A bag contains 7 black and 4 white balls two balls
and dishonest if and only if Suman is rich” can be are drawn at a time from the bag. The probability at
expressed as least one white ball is selected is
(a) ~  Q  P ~ R   (b) ~ Q  ~ P  R 7 5
(a) (b)
(c) ~ P ~ R  Q (d) ~ P   Q ~ R
11 11
28 34
64. If y = 3[x] + 1 = 4[x – 1] – 10. Then [x + 2y] is equal (c) (d)
55 55
to__________
73. From origin, chords are drawn to the circle
65. The value of
x 2  y 2  2y  0 . The locus of the middle points of
  2  3  12  


sin1 cot sin1    cos 1    sec
1
 
2  these chords is
   4   4   
2 2
is equal to (a) x 2  y 2  y  0 (b) x  y  y  0
 2 2 2 2
(a) 0 (b) (c) x  y  2x  0 (d) x  y  x  y  0
4
  74. If 2 tan2 x  5 sec x  1 for exactly 7 distinct values
(c) (d)
6 2
 n 
 1 of x  0,  , n  N then the greatest value of n
sin  n   x  2 
66. The value of the integral 
  2
dx (n  N) is__________
0 sin x / 2
is 3(z) 2
75. Number of solution of the equation, z3  0,
(a)  (b) 2 |z|
(c) 3 (d) none of these where z is a complex number is__________
8 MOCK TEST 6

ANSWERS
1. (a) 2. (300V) 3. (c) 4. (c) 5. (c) 6. (c) 7. (c) 8. (c) 9. (b) 10. (a)
11. (3.3m) 12. (c) 13. (b) 14. (a) 15. (c) 16. (3.57m/s) 17. (a) 18. (c) 19. (c)
–1
20. (a) 21. (c) 22. (b) 23. (c) 24. (8s) 25. (7ms ) 26. (2) 27. (b) 28. (a)
29. (a) 30. (c) 31. (d) 32. (a) 33. (n = 2) 34. (d) 35. (c) 36. (a) 37. (a) 38. (a)
39. (b) 40. (d) 41. (a) 42. (d) 43. (b) 44. (b) 45. (b) 46. (c) 47. (c) 48. (72g)
49. (0.095N) 50. (0.125M) 51. (c) 52. (d) 53. (a) 54. (a) 55. (one) 56. (b)
57. (b) 58. (c) 59. (c) 60. (b) 61. (13) 62. (b) 63. (a) 64. (107) 65. (a) 66. (a)
67. (a) 68. (a) 69. (c) 70. (a) 71. (d) 72. (d) 73. (a) 74. (15) 75. (None of these)

EXPLANATIONS
1. E   dV = negative of the slope of V–r graph. Here i0 = E/R and  
L
dr R
 t

2. W  U2  U1  q  1  1 
2
 q   idt   i0 (1  e t /  )dt
2 C C 2 1  0 0

 E  L 
0 A C  A
C1  , C2  1  0 i0   R  
 R   EL
d 2 2d  
e e eR 2
0 AV
q = C1 V = mv 0 v
d 5. r  0
B 0 q B0 

Solve to get, W  1 0 AV
2

x 3
2 d   sin     60
r 2
3. In the steady state conduction, no current will flow
through the capacitor C. u2
6. H given 2  21 ...(1)
2g
Current in the outer circuit,
A to B: 12  u2  2gh ...(2)
V R
A to C: 22  u2  2g( h) ...(3)
V A C
I I=0 I Solving (1), (2) and (3), find the value of u2 and then
u2
2V 2R get the value of H by using H
2g
2V  V V
I 
2R  R 3R
v1 H
Potential difference between A and B.
B
VA – V + V + IR = VB
u h
 V  V
 VB – VA = IR =   R  A
 3R  3
h
4. The current at time t is given by C
v2
i = i0(1 – e–t/)
 MOCK TEST 6 9

7. 2  u2  2gh or u2  2  2gh As 4g < 80 sin 37°, so the frictional force will act
downwards.
or u2x  u2y  2x  2y  2gh
Net applied force in upward direction (excluding
u    2gh
2 2
or u  (2)  2  10  0.4  12
2 2 friction force) is.
y y y

80 sin 37° – 40 = 48 – 40 = 8 N
uy = 12  2 3 m / s, ux  x  6 m / s
As Fapplied in vertical direction is < fL so block won’t
uy 2 3 1 move in vertical direction and value of static friction
tan    
ux 6 3 force is, f = 8 N.
  = 30° Y
8. The spring will exert maximum force when the ball
is at its lowest position. If the ball has descended
through a distance x to reach the position.
V0

1 2
mgx = Kx or x = 2 mg/K ...(i) 
2
For the block B to leave contact spring force A

Kx = Mg ...(ii)
Comparing equations (i) and (ii), m = M/2
9. x2 + y2 = l2
On differentiating, we get
xVx + yVy = 0 O

 Vy = y component of velocity of B which is along x

the rod, i.e., BA (Figure)
T 
t OA  
B 6 3B0 

11. If the body has slid by a distance x, its acceleration

(a) will be:
y g
l a  gsin   gcos   1  0.3x 
2

Now, speed will be maximum when a = 0 i.e.,

60°
A 1
x x  3.3
0.3

x
|Vy| = Vx 
2
m/s 12. Fnet  mg  mg  ma  a  g 1  
y 3
13. If the initial speed is V, the speed at the highest
2 V E
Hence, VB cos 30° = m/s
point is . Therefore, the KE is
3 2 2
 VB = 1 m/s 14. Rate of cooling is directly proportional to the surface
10. The FBD of the block is shown in the figure area of the body. Plate has the highest surface area
N = 80 cos 37° = 64 N and sphere the least.
3
80 sin 37°
15. Motion A w.r.t. B  x1  x2  a cos t  b sin  t  
80 N  2 
N
  a  b  cos t

16. Let the man starts crossing the road at an angle 

80 cos 37°
with the roadside. For safe crossing, the condition
f is that the man must cross the road by the time
4 kg truck describes the distance (4 + 2 cot)
So, fL = 0.2 × 64 = 32 N
10 MOCK TEST 6

4  2cot  2lsin  8 sin r1 > sin(A – c)

So,  or  
8  2sin   cos  sini
 sin(A – c )

d
For minimum , 0
sin i > (sin A cos c – cos A sin c)
d

8(2cos   sin ) 7 3 3 3 1 1 1
or 0 or 2 cos – sin = 0  1  .   1 
(2 sin   cos )2 3  2 7 7 2  2 2

2 1 1
or tan = 2, so sin = , cos   sin i > 2 or i > 30°
5 5

8 8 21. Use V  Q & Einduced  Epoint charge  

Q
min    3.57 m / s 4or 4or 2
 2  1 5
2 
 5 5
22. Use: Ex   V  8x  8 V m along negative x-axis
x
usin  2
17. tan   ucos   1 , The desired equation is 23. The large size telescopes both reflecting and
refracting will be having huge mirrors and lenses
gx 2 10x 2 respectively. As in case of lens the support can only
y = x tan  – 2u2 cos2   x  2 
   15 
2
2 be provided at the edge, which is thin and hence
2 22  12
fragile. Whereas in case of mirrors, the entire
silvered/polished surface can be provided the support
or y = 2x – 5x 2 without interfering with the optical phenomenon.
24. Particle will acquire the initial velocity when areas
18. tan   g  a  gcot 
a A1 and A2 are equal (figure). For this t0 = 8 s
a
10
a

A1 t0
g t
4 A2

19. Net force without friction on system is 7 N in right

side so first maximum friction will come on 3 kg
 
block (figure). 25. c   5ˆj, b / c  2 6 ˆi
So f2 = 1 N, f3 = 6 N, T = 2 N   
b  b / c  c   2 6 ˆi  5ˆj

1N 2 kg T T 3 kg 8 b  (2 6)2  52  7 m / s

fmax = 2 fmax = 6 27. H3PO4 is tribasic, so NaH2PO4 is acidic salt. H3PO2

1 2 is monobasic. H – P = 0 Hence NaH2PO2 is not an
2 kg 2 3 kg 8
1 6
H OH
20. r2 < c; A – r1 < c acidic salt. It is a neutral salt. NaH 2PO 3 and
Na2H2S2O7 are also acidic salts.
A
28. NaCN undergoes hydrolysis in aqueous solution
60°


NaCN  H2O   
 Na OH  HCN
i (basic )
r1 r2
Kw 1 1014
Kh    0.77  105  7.7  106
 K a 1.3  109

B C
Kh 7.7  10 6

r1 > A –  c Degree of hydrolysis “h” = conc  1 
 
 80 
 MOCK TEST 6 11

= 7.7  80  106
42. Greater the reduction potential, stronger is the
oxidizing agent or weaker is the reducing agent.
= 616  106  24.8  103
1
43. K
Percentage of hydrolysis = 24.8 × 10–3 × 102 = 2.48. Ea
29. At boiling point, the vapour pressure of a liquid is
O O O
equal to atmospheric pressure. At higher altitudes,
the atmospheric pressure decreases, so the boiling 44. 
NaBH4

H


point of liquid also decreases.
30. 1 dyne cm–1 = (10–5 N) (10–2 m)–1 = 10–3 Nm–1 O OH
72.75 dyne cm–1 = 72.75 × 10–3 NM–1 45. HNO3 is added to decompose Na2S and NaCN
= 0.07275 Nm–1 otherwise Na2S will give black ppt. of Ag2S and NaCN
will give white ppt. of AgCN which would interfere
OH with the tests of halogens.

31. CH3 – CH2 – C – CH – CH3 
H
 46. At constant T, V
CH3 CH3 P  nP1V1 = n1 R T1

CH3 P1 n1
+   n1  1.68 moles
CH3 – CH2 – C – CH 1, 2- H–Shift P2 n2
CH3
CH3
 n2 
1.68  2.5   1.05 mole
4
CH3 – CH2 CH3
C=C Number of moles of gas leaked out = n1 - n2 = 0.63
CH3 CH3
mol
32. Aldehyde is more reactive than ketone toward 47. Let there be 1 mole of Iron atom:
nucleophilic attack. (Aliphatic aldehyde is more
reactive than aromatic aldehyde) 1
We will have amount of Fe (III) = 4 mol
O
3
CO2H amount of Fe (II) = 4 mol
33. (n = 2) 

 O
CO2H
O 1 3 9
Total positive charge due to 1 mole = 4  3   4  2  4
Succinic acid on heating form anhydride.
36. Due to higher value of intermolecular H-bonding in 9
Total positive charge due to x mole = 4 x
primary amine is show highest B.P
37. (C) and has plane of symmetry Total +ve charge = Total -ve charge
(D) has a centre of symmetry. 9 8
x2 x
38. 4 9

Fe8 O
O O O 9
C H
C H C H
48. Tf  Tb  K f  Kb  m
OD
+
OD OD

w 1000
5  1.86  0.51  w = 72 g
CH2OD O O 342 100
C O CH2O
C O D
+ deuterium
+
49. NaOH + CO2  NaHCO3
exchange
m.m. of NaOH reacted = m.m. of CO2 reacted
39. Benzyl carbonation will be be formed due to SN1 m.eq. of NaOH remaining = 19
which is stable one. eq. of NaOH = 0.019
41. It will behave as a mixture of NH and NH3 because 
0.019
Normality   0.095
4

0.2
some of the NH3 would react with HCl to form NH4 .
12 MOCK TEST 6

50. [OH–] = Kb  c
54. Point P  1  t , 2  t  lies between given line
(1.5 × 10–3)2 = 1.8 × 10–5 × c 2 2 

(1.5  103 )2
c= = 0.125 M 15
1.8  105 0,
4
51. A

1
0,
2
C1 B1
G 15
,0
4

(1, 0)
B A1 C
 A, C1, G and B1 are cyclic x + 2y – 1 = 0

 BC1. BA = BG.BB1  t   t 
Hence 1    2  2    1  0
c 2  2  2   
c   BB1  .BB1
2 3  5
3t
1 0  t  
4 2
2 3
c2 2 1
  (2c 2  2a2  b2 ) 
2 3 4
c2 + b2 = 2a2 Now, 2  1  t   4  2  t   15  0
2  2   

1  x2  1  10 
6t
 15  0  t 
5 2
52. tan1  4 x0
x 2 6
 4 2 5 2 
taking tan on both side Hence t   , 
 3 6 
1  x2  1 55. y2 – 2y – 2x – 1 = 0
 tan 4
x y2 – 2y + 1 = 2x + 2
1  x 2  1  x tan 4
(y – 1)2 = 2(x + 1)
Normal of slope ‘m’
1  x 2  2x tan 4  1  x 2 tan 2 4
1
(y – 1) = m(x + 1) – 2am – am3 at (– 2, 2) and a = 2
2 tan 4
x = 0, 1  tan2 4
since x  0
m3
x = tan8° 1 = m(–1) – m –
2
n n
m3
 r. C n
r n  n  1 C r 1
n.2n 1 n 1 = – 2m –
53.  
1 r 0
 r 1
  2
1 n
2n 2n 2
 r. C
r 0
n
r 2 = – 4m – m3
 m3 + 4m + 2 = 0
n

r 2 n
. Cr
1 n
only one real value of ‘m’ hence only one normal is
 
1
2
r 0
n
  {r(r  1)  r}.n Cr
2n r  0
possible as the above is a monotonically increasing

r 0
n
Cr function of m.
56. Let middle point of chord is P(h, k) then its equation
1  n n

n(n  1) Cr  2  n Cr 1 
n2 n 1
 is T = S1
2n  r 2 r 1 
xh yK h2 k2
1  2
 2
 2

 n [n(n  1).2n  2  n.2n 1] a b a b2
2
 b2hx + a2ky = b2h2 + a2k2
n(n  1) n
  Now tangents at extremities intersect on director
4 2
circle
Now variance   12  (11 )2
n(n  1) n  n  n
2  Let Q  a2  b2 cos , a2  b2 sin   is point of
    
4 2 2 4 intersection of tangents
 MOCK TEST 6 13

 Equation of chord of contact is radius = 3

a2  b2 cos  a2  b2 sin  y
equation is (x + 3)2 + (y – 3)2 = 9
 1
a2 b2
Equation (i) & (ii) are same so we have

b2 a2  b2 cos  a2 a2  b2 sin  a2b2

2
 2

b h a k b h  a2k 2
2 2

a2b2h a2b2 x (-3,3)

 
cos , sin   (-1,3)
 a2  b2 b2h2  a2k 2  a2  b2  b2h2  a2k 2 

 Locus is (a2 + b2) (b2x2 + a2y2)2 = a4b4(x2 + y2)

57. Let the common line be x

x+y=0
+
3
=
y = mx ...(1) 0

Putting this value we get

1 + 2m + am2 = 0 ...(2)
a + 2m + m2 = 0 ...(3) 2s n 2s n
3n1  1
On eliminating m we get 2 59.  br  3s ;   br   3s  2
r 0 s  0 r 0 s 0

1 a integrating both sides of (1 + 2x) (1 + x + x2)n

m
2
2n 1
a 1 =  ar x r on [0, 1]
From (2) we get  1 r 0
2
This gives  1  x  x 2  n  1
1
2n 1  xr 1 
1
3n1  1 2n 1 ar
    ar   ;  
a = 1, for this both lines are common and hence will  n 1  0  r  1 0 n1 r 0 r  1
r 0
be rejected.
3n 1  1
 a=–3 n1
Given expression = 2 
For this value of a we get the lines having different 3n 1  1 2
equation n 1

viz y + 3x = 0 60. Tn   n  1  n  1 n  1

& 3y + x = 0 Tn = (n + 1)(n2 + 1 – n)
and joint equation of these two lines is Tn = n3 + 1
2
3x2 + 10xy + 3y2 = 0  n  n  1 
Sn   Tr    r 3  1    n
58. x2 + 3y + xy + 3x = 0  2 

x(x + y) + 3 (x + y) = 0 61. Expanding all the terms we get

9 + 2(tan2A + cot2A)
(x + y)(x + 3) = 0
 maximum value is 9 + 2.2 = 13
Separate equations of the lines are

 P  A    P  A1BPAP  A   31
c
P BA
x+y=0 
62. P B A c  c
x+3=0
Circles is x2 + y2 + 2x – 6y + 9 = 0 64. y = 3[x] + 1 = 4[x] – 14  [x] = 15 & y = 46
Centre is (–1, 3) [x + 2y] = [x] + 2y = 15 + 92 = 107
radius = 1 2 3 42 3
65. sin1  sin1
 x + y = 0 and x + 3 = 0 are normals to the required 4 8
circle
3 1 
sin1 
 centre of the circle is (–3, 3) 2 2 12
and it contains the circle      
sin1 cot       0
x2 + y2 + 2x – 6x + 9 – 0  12 6 4  
14 MOCK TEST 6
70. xy = 2(x + y)  y(x – 2) = 2x
 1
sin  n   x
66. Let In  

 2 2x
dx  y but x, y  N
0 sin x / 2 x2
By trial,x = 3, 4, 6
  1  1 
sin  n   x  sin  n   x  theny = 6, 4, 3 by x  y
 2   2  
 

 In – In–1 dx  x = 3, 4 and y = 6, 4 two solutions.
0 x
sin
2 71. a1b are is of then form
 2cosnx.sin(x / 2)   sinnx 

a1b  7m, 7m  1,7m  2, 7m  3,7m  4,7m  6
 2cos nx dx  2 
0 sin(x / 2)
dx 
0  n 0

a12b2  7m1, 7m1  1,7m1  4, 7m1  2,7m1  2,7m1  4,7m1  1
=0–0=0
 In = In–1  a 2 ,b 2 must be of the form 7m.
Replacing n by n–1, n – 2, ...., then we get
1
In = In–1 = In–2 = ... = I1 Probability = 49
 sin(3x / 2)   sin 2x  sin x 
 In = I1 = 0 sin(x / 2)
dx  0 
 sin x  dx
  7 C2 
72. 1   11 
  C2 
 
0
(2cos x  1)dx  {2 sin x  x}0  

Hence, In =  73. T  S1

 2  1, if x  loge 2  i.e., xx1  yy1   y  y1   x12  y12  2y1

67.  e x   0, if x  log 2 
   e 
Passes through (0, 0)
loge 2 2   2 
 I  0  e x  dx  log 2  e x  dx  x2  y 2  y  0
   
loge 2 1
 
0
1.dx  0 74. sec x  3  cos x  3
 loge 2 Which gives two values of x in each of
68. z  rei  r(cos   isin ) 3 
0,2,  2,4,  4,6 and one value in 6   15
2 2
 (r cos )  i(r sin )
 iz  (r sin )  i(r cos )  greatest value of n = 15

eiz  e  r sin  ei(r cos  ) 3(z)2

75. z2 + | z |  0 Let z = rei
 | eiz | er sin  | ei(r cos ) |

 e  r sin 
 r3 ei3 + 3re–i2 = 0
69.  |z1 – 1| < 1, |z2 – 2| < 2, |z3 – 3| < 3 Since ‘r’ cannot be zero
 |z1 + z2 + z3| = |(z1 – 1) + (z2 – 2) + (z3 – 3) + 6|  r2 ei5 = – 3 which will hold for
 |z1 – 1| + |z2 – 2| + |z3 – 3| + 6 < 1 + 2 + 3 + 6 r= 3 and 5 distinct values of ‘’
 |z1 + z2 + z3| < 12
Thus there are five solution.
 MOCK TEST – 7
PHYSICS (SECTION – A)
1. Two particles start together from a point O and slide
down straight smooth wires inclined at 30° and 60°
to the vertical and in the same vertical plane and on
the same side of vertical through O. The relative
acceleration of second with respect to first will be in
magnitude and direction as:
g
(a) in the vertical direction
2
g 3
(b) inclined 45° to vertical
2 (d) will move in a vertical line if v1cos1 = v2cos2.
g 5. A ball of mass m approaches a moving wall of infinite
(c) inclined 60° to vertical
3 mass with speed v along the normal to the wall. The
(d) g in the vertical direction
2. Two particles A and B move on a straight line. A moves
with constant positive velocity. B moves with constant
positive acceleration. At t = 0, A and B are moving
equally fast. Which of the following is not possible?
(a) The distance between them keeps decreasing.
(b) The distance between them first decreases and
then increases.
(c) The distance between them first increases, then
decrease and finally keeps increasing.
(d) The distance between them first decreases, then
increases, then decreases and finally keeps
increasing.
3. From the fixed pulley, masses 2 kg, 1 kg and 3 kg are
suspended as shown in the figure. Find the extension
in the spring if k = 100 N/m ___________(m)
4. Two particles of equal mass 'm' are projected from
the ground with speeds v1 and v2 at angles 1 and 2
at the same time as shown in figure. The centre of
mass of the two particles;
v1 v2
1 2
m m
(a) will move in a vertical line if v1tan1 = v2tan2.
(b) will move in a vertical line if v1sin1 = v2sin2.
(c) will move in a vertical line if v1cot1 = v2cot2.
speed of the wall is u toward the ball. The speed of
the ball after 'elastic' collision with wall is:
(a) u + v away from the wall
(b) 2u + v away from the wall
(c) |u – v| away from the wall
(d) |v – 2u| away from the wall
6. In a wire of young's modulus Y, the longitudinal strain
produced is  then the strain energy per unit volume
store in the wire will be
(a) Y2 (b) 2Y2
(c) Y2/2 (d) Y2/2
7. A hollow thin walled pipe is projected on a rough
horizontal surface with speed v. As soon as the pipe
begins to roll, what will be its speed?

 1  1
(a)    v (b)    v
4 3

2 kg  1
(c)    v (d) v
2
1 kg
8. A block with mass 3M connected to a massless rod
of length L lies at rest on a fixed frictionless table.
A second block of mass M impinges on the system
with speed V0 strikes the opposite end of the rod at
a right angle and sticks
3 kg

(Neglect oscillations due to spring)

2 MOCK TEST 7

13. One end of a uniform rod of length l and mass m is

L
3M hinged at A. It isreleased from rest from horizontal
V0 position AB as shown. The forceexerted by the rod
on the hinge when it becomes vertical is
M
The velocity of the centre of the rod just after collision: A B

V0
(a) zero (b)
2
V0
(c) V0 (d) 3
4 (a) mg (b) 3 mg
2
9. A thin bar of mass M and length L is free to rotate
5
about a fixed horizontal axis through a point at its (c) 5 mg (d) mg
end. The bar is brought to a horizontal position and 2
then released. The angular velocity when it reaches 14. There are fom concentric shells A, B, C and D of
the lowest point is radii a, 2a, 3a and 4a respectively. Shells B & D are
(a) directly proportional to its length and inversely given charges +q & –q respectively. Shell C is now
proportional to its mass earthed. The potential difference VA – VC is
(b) Dependent upon mass and inversely proportional Kq Kq
(a) (b)
to the square root of its length 6a 2a
(c) dependent only upon the acceleration du to gravity Kq Kq
and the length of the bar (c) (d)
3a 4a
(d) directly proportional to its length and inversely 15. A capacitor and a coil in series are connected to 6V
proportional to the acceleration due to gravity AC source. By varying the frequency of the source,
10. A man can swim in still water at a speed of 5 km/hr. maximum current of 600 mA is observed. If the same
He wants to cross a rive 6 km wide, flowing at the coil is now connected to a cell of emf 6V DC and
rate of 4 km/hr. If he heads in a direction making an
internal resistance of 2  , the current through it will
angle of 127° with stream direction, then he will reach
a point on the other bank (approx) be___________(A)
(a) upstream at a distance of 1.5 km 16. A uniform magnetic field exists in the space along
the x-axis as shown in the figure. A rectangular loop
(b) downstream at a distance of 1.5 km of sides (a × b) isrotated in magnetic field about an
(c) directly on the other side of the bank axis passing through themid-point of side a and
parallel to side b with angular speed (this axis is
(d) never reach the other bank parallel to direction of B). The induced current in the
11. Four particles of masses 2kg, 4kg, 1kg and m loop if the resistance of loop is R, is
are placed at four corners of a square. What y B
should be the value of m so that the centre of
mass of all four particles is exactly at the centre
of square___________(kg)

m 1kg

x
2
B b B2a
2kg 4kg (a) (b)
2R 2R
12. A convex lens forms a real image three times larger (c) zero (d) None of these
than the object on a screen. Object and screen are 17. Three point charges q, 2q and 8q are to be placed on
moved until the image becomes twice the size of a 9 cm long straight line. Find the position where the
the object, if the shift in the position of object is charges should be placed such that the potential
6 cm the shift in the position of screen energy of this system is minimum. In this situation,
is___________(cm)
 MOCK TEST 7 3
what is the electric field at the position of the charge the new position of the null point from the same end,
q due to the other two charges? if one decides to balance a resistance of 3X against
(a) 20 cm, 24 N/C (b) 12 cm, 2 N/C Y, will be close to___________(cm)
(c) 3 cm, zero (d) 9 cm, zero 22. In the Bohr model an electron moves in a circular
orbit around the proton. Considering the orbiting
18. A conical pendulum consists of a slender bar AB of
electron to be a circular current loop, the magnetic
length Land mass M. If it rotates with constant
moment of the hydrogen atom, when the electron is
angular velocity , then value of cos will be
in nth excited state, is:
  e  n2 h  e  nh
(a)   (b)  
 m  2  2m  2
 e  n2 h  e  nh
(c)   2 (d)  
 2m   m  2

23. Consider two npn transistors as shown in figure. If 0
volts corresponds to false and 5 volts correspond to
true then the output at C corresponds to :
5V

C
g 2g 1
(a) cos   (b) cos  
2L 2L A
3g 3g 2
(c) cos   (d) cos  
2 L 2  L 2 B
19. A solid sphere and a thin loop of equal masses m
and radius R are harnessed together by rigging and
free to roll without slipping down the incline plane.
(a) A OR B (b) A NOR B
Neglect the mass of rigging, then compressive force
(c) A NAND B (d) A AND B
in rigging will be
24. From the following, the quantity (constructed from
the basic constants of nature), that has the dimen-
sions, as well as correct order of magnitude, vis-a-
vis typical atomic size, is :
e2 4 0 mc 2
(a) (b)
4 0 mc 2 e2

me 2 4 0 h2
3
mg sin  mgsin  (c) (d)
(a) (b) 4 0 h 2
me 2
17 17
25. If the ratio of lengths, radii and Young's moduli of
2mgsin  steel and brass wires in the figure are a, b, and c
(c) 3mg sin (d)
17 respectively, then the corresponding ratio of increase
20. An electron and a proton are separated by a large in their lengths is :
distance. The electron starts approaching the proton
with energy 2eV. The proton captures the electron Steel
and forms a hydrogen atoms in first excited state. M
The resulting photon is incident on a photosensitive
metal of threshold wavelength 4600 Å. The maximum Brass
KE of the emitted photoelectron is 2M
(a) 2.4 eV (b) 2.7 eV
3c 2a2 c
(c) 2.9 eV (d) 5.4 eV (a) (b)
2ab2 b
21. In a meter bridge experiment null point is obtained at
40 cm from one end of the wire when resistance X is 3a 2ac
(c) (d)
balanced against another resistance Y. If X < Y, then 2b 2 c b2
4 MOCK TEST 7

CHEMISTRY (SECTION – B) 32. Which one of the reagents given can be used to bring
out the following conversion?
26. When 20 g of CaCO3 is put into a 10 L flask and
heated to 800°C, 35% of CaCO 3 remains CH3
undissociated at equilibrium. Calculate the value of CH3
Kp ___________(atm) OD
27. For the reaction,
D


 2NH3 (g)  CO2 (g)
NH2COONH4 (s)  (a) Hg(OAc)2/D2O followed by NaBD4
equilibrium pressure was found to be 3 atm at 1000 (b) Hg(OAc)2/H2O followed by NaBH4
K. Hence Kp in atm3 is ___________
(c) Hg(OAc)2/D2O followed by NaBH4
28. The pH of a solution obtained by mixing equal volume
(d) Hg(OOCCD3)2/H2O followed by NaBH4
of solutions having pH = 3 and pH = 4 ___________
33. The Ksp of Mg(OH)2 is 1 × 10–12. At what maximum
[log 5.5 = 0.7404]
pH, Mg(OH)2 just begins to precipitate from a solution
29. The pH values of 1 M solutions of CH3COOH (I), containing 0.01 M MgCl2___________
CH3COONa (II), CH3COONH4 (III) and KOH (IV) will
34. Which one of the following is a non-aromatic spe-
be in the order
cies?
(a) (IV) > (III) > (II) > (I)
O
(b) (IV) > (II) > (III) > (I)
(a) (b)
(c) (I) > (III) > (II) > (IV)
(d) (II) > (I) > (III) > (IV)
O
30. The dissociation energy of H2 is 430.53 kJ mol–1. If +
H2 is dissociated by illuminating with the radiation of
wavelength 253.7 nm, the fraction of the radiant (c) (d)
energy which will be converted into kinetic energy is
given by___________ 35. At constant temperature, the equilibrium constant
31. Geraniol is a naturally occurring alcohol found in pinus (K p ) for the decomposition reaction,
tree. Geraniol converts into -terpineol in the presence
of aqueous acid


N2O4 (g) 
 2NO2 (g) is expressed by

4x 2P
OH Kp = where P = equilibrium pressure and
CH2 – OH – 1  x2
H/HOH
x = extent of decomposition. Which one of the
following statement is true?
(Geraniol) ( - Terpineol) (a) Kp increases with increase of P.
(b) Kp increases with increase of x.
The first step of this reaction is the formation of
(c) Kp increases with decrease of x.
carbocation. The carbocation which gives the above
mentioned product has the structure (d) Kp remains same with change in P and x.
36. Froth floation is a process of
+ (a) Oxidation (b) Reduction
+
CH2OH CH2OH (c) Refining (d) Concentration
(a) (b) 37. The true statement for the acids of phosphorus
H3PO2, H3PO3 and H3PO4 is
(a) Their acidic nature H3PO4 < H3PO3 < H3PO2
(b) All of them are tribasic acids
+
CH2OH CH2 (c) The geometry of phosphorus is tetrahedral in all
the three acids
(c) (d)
(d) None of these
+
 MOCK TEST 7 5

38. Which reaction is not feasible 46. The formula of Azurite is

(a) CuCO3.Cu(OH)2 (b) 2CuCO3.Cu(OH)2
(a) 2KI + Br2  2KBr + I2 (c) CuCO3.2Cu(OH)2 (d) CuSO4.Cu(OH)2
(b) 2KBr + I2  2KI + Br2 47. In this sequene X, Y, Z are respectively

(c) 2KBr + Cl2  2KCl + Br2 X

(d) all of the above
39. Which of the following polymers have more than one
monomer. Cr+3 yellow solution
I - Nylon-6 ; II - Nylon-6,6 ; III - Teflon ; IV - Buna-S
(a) I and II (b) II and IV Z
(c) II and III (d) II, III, IV
Blue
40. The acidic character of 1°, 2°, 3° alcohols H2O and solution
RC  CH is in the order Y
(a) H2O > 1° > 2° > 3° > RC  CH (a) Acidified H2O2, Alkaline H2O2, Acidified H2O2
(b) RC  CH > 3° > 2° > 1° > H2O (b) Alkaline H2O2, Acidified H2O2, Zn/HCl
(c) Acidified H2O2, Heat, alkaline H2O2
(c) 1° > 2° > 3° > H2O > RC  CH
(d) Alkalined H2O2, Acidified H2O2, on standing
(d) 3° > 2° > 1° > H2O > RC  CH
48. What will be the colour of the solution when Mn(OH)2
41. A certain metal when irradiated to light (v = 3.2 × is treated with conc. HNO3 and sodium bismuthate
1016 Hz) emits photoelectrons with twice kinetic
energy as did photo electrons when the same metal (or red lead or lead dioxide)?
is irradiated by light (v = 2.0 × 1016Hz). The v0 of (a) Yellow (b) Purple
metal is (c) Green (d) Blue
(a) 1.2 × 1014 Hz (b) 8 × 1015 Hz 49. In NaCl the centres of two nearest like charged ions
(c) 1.2 × 1016 Hz (d) 4 × 1012 Hz are present at a distance of
42. The reduction potential of hydrogen half-cell will be a a
negative if (a) (b)
2 2
(a) p(H2) = 1 atm and [H+] = 1 M
(b) p(H2) = 2 atm and [H+] = 2 M 3
(c) a (d) 2a
(c) p(H2) = 2 atm and [H+] =1M 2
(d) p(H2) = 1 atm and [H+] = 2 M 50. Complexes given below shows
43. Sodium peroxide on treatment with cold dil. H2SO4
Ph3P Cl PPh3 Ph3P Cl Cl
gives
Pt Pt Pt Pt
(a) H2O + Na2SO4 + O2 (b) H2O + Na2SO4 Cl PPh3
H 3C Cl H3 C Cl
(c) H2O2 + Na2SO4 (d) H2O + Na2SO3
44. Which of the following alkali metal carbonates gives (a) Optical isomer
CO2 on heating as well as on treating with acids? (b) Co-ordinate isomerism
(a) Na2CO3 (b) K2CO3 (c) Geometrical isomerism
(c) Rb2CO3 (d) Li2CO3 (d) Bridge isomerism
45. A nitrate decomposes thermally to give an oxide of
group 15 element. This oxide cannot be obtained by MATHEMATICS (SECTION – C)
direct combination of the element and the oxygen.
51. If a is any vector, then (a × i)2 + (a × j)2 + (a × k)2 is
The trichloride of this group 15 element can hydrolyse
equal to
only partially. The oxide is
(a) |a|2 (b) 0
(a) Bi2O3 (b) P2O3
(c) 3|a| 2
(d) 2|a|2
(c) Sb2O3 (d) N2O3
6 MOCK TEST 7

x 1 y 1 z 1 x 3 y k z 1 1 1
52. If the line   and   62. If tan1  tan1  tan1
2 3 4 1 2 1 1 2 1   2 3 1   3  4 
intersect, then k = 1
 ....  tan1  tan1 ,
2 9 1  n  n  1
(a) (b)
9 2
then  
(c) 0 (d) –1
53. In an upper triangular matrix n × n, minimum number n n1
(a) (b)
of zeros is n1 n2

n(n  1) n(n  1) n n 1
(a) (b) (c) (d)
2 2 n2 n2
63. The line x + y = 1 meets x-axis at A and y-axis at B.
2n(n  1)
(c) (d) None of these P is the mid-point of AB. P 1 is the foot of the
2 perpendicular from P to OA; M1 is that from P1 to
54. The vertices of triangle are (0, 3) (– 3, 0) and (3, 0). OP; P2 is that from M1 to OA; M2 is that from P2 to
The co-ordinate of its orthocentre are OP; P3 is that from M2 to OA and so on. If Pn denotes
(a) (0, – 2) (b) (0, 2) the n th foot of the perpendicular on OA from Mn – 1 ,
then OPn =
(c) (0, 3) (d) (0, – 3)
55. Let p be a non-singular matrix, 1 + p + p2 + ... + pn = 1 1
0 (0 denotes the null matrix), then p–1 = (a) (b)
2 2n
(a) p n
(b) – p n

1 1
(c) – (1 + p + ... + p ) (d) None of these
n
(c) (d)
n/2
56. Number of irrational terms in the expansion of 2 2
64. The line 9x + y – 28 = 0 is the chord of contact of the
( 2  3 )15 is equal to___________
point P(h, k) with respect to the circle 2x2 + 2y2 – 3x
57. Total number of non-negative integral solutions of x1 + 5y – 7 = 0, for
+ x2 + x3 = 10 is equal to (a) P(3, –1) (b) P(3, 1)
(a) 12C3 (b) 10C3 (c) P(–3, 1) (d) no position of P
(c) 12C2 (d) 10C2 65. If OA and OB are two equal chords of the circles x2 +
58. If 2ax – 2y + 3z = 0, x + ay + 2z = 0 and 2x + az y2 – 2x + 4y = 0, perpendicualr to each other and
= 0 have a non-trivial solution, then passing through the origin, the slopes of OA and OB
(a) a = 2 (b) a = 1 are the roots of the equation
(c) a = 0 (d) None of these (a) 3m2 + 8m – 3 = 0 (b) 3m2 – 8m – 3 = 0
(c) 8m2 – 3m – 8 = 0 (d) 8m2 + 3m – 8 = 0
0 1
59. If A    and I is the unit matrix of order 2, then 66. If the circle x2 + y2 + 2ax + 2by + c = 0 passes
0 0  through exactly three quadrants and does not pass
(al + bA)2, where 'a' and 'b' are given constants, is through origin, then
equal to (a) c > 0, a2 > b2
(a) a I + b A
2 2
(b) a I + 2abA
2
(b) c > 0, a2 + b2 > 2c
(c) a I + abA
2
(d) a – b A
2 2
(c) c(a2 – c) (b2 – c) > 0
(d) c > 0, a2 > c, b2 > c
 cos  sin    1 0
60. If A    and A(adj(A)) =    then 67. If the line x + y = a, touches the parabola y = x – x2,
  sin  cos    0 1
then the point of contact is
 is equal to___________
(a) (1, 0) (b) (0, 0)
61. Number of solutions of the equation tan x + sec x =
(c) (2, –2) (d) (–2, –6)
2 cos x lying in the interval  0, 2  is___________
 MOCK TEST 7 7
68. The total number of solutions of the equation 73. If the line joining the points 0,3 and 5, –2 is a tangent
3.cos ec 2 x  2 3 cos ecx.sec x  3 sec 2 x  0 c
to the curve y  , then value of c is
in the interval (0, 2) is equal to ___________ x 1
(a) 1 (b) – 2
2
69. In triangle ABC, C  and CD is internal angle (c) 4 (d) – 4
3
74. Equation of the plane through (3, 4, –1) which is
bisector of C, meeting the side AB at D. Length
CD is equal to  
parallel to the plane r· 2iˆ  3ˆj  5kˆ  7  0 is

(a)
ab
2(a  b)
(b)
2ab
ab
 
(a) r· 2iˆ  3ˆj  5kˆ  11  0

(c)
2ab
(d)
ab  
(b) r· 3iˆ  4 ˆj  4kˆ  11  0
3(a  b) ab

dy y
 
(c) r· 3iˆ  4ˆj  kˆ  7  0
70. Solution of the differential equation   x2 ,

satisfying y(1) = 1, is
dx x
 
(d) r· 2iˆ  3ˆj  5kˆ  7  0

(a) 4xy = x3 + 3 (b) 4xy = x4 + 3 75. The image of the point (–1, 3, 4) in the plane x – 2y
(c) 4xy = x2 +3 (d) 4xy = y3 +3 = 0 is

(a) 15, 11, 4 

71. If A and B are square matrices of order 3 such that
 17 19 
A  1, B  3 then 3AB is equal to (b)   ,  ,1
 3 3 
(a) – 9 (b) – 81
 9 13 
(c) – 27 (d) 81 (c)  ,  , 4 
5 5 
72. Let  and  be the roots of x 2  6x  2  0 with  17 19 
(d)   ,  , 4
   if an  n  n for n  1 then the value of  3 3 
a10  2a8
 ___________
3a9
8 MOCK TEST 7

ANSWERS
1. (a) 2. (a) 3. (0.2 m) 4. (d) 5. (b) 6. (c) 7. (c) 8. (b) 9. (c) 10. (b)
11. (None of these) 12. (36 cm) 13. (d) 14. (a) 15. (0.5A) 16. (c) 17. (c) 18. (c) 19. (a)
20. (b) 21. (67 cm) 22. (b) 23. (c) 24. (d) 25. (c) 26. (1.145 atm) 27. (4)
28. (3.26) 29. (b) 30. (8.74%)31. (d) 32. (a) 33. (9) 34. (d) 35. (d) 36. (d) 37. (c)
38. (b) 39. (b) 40. (a) 41. (b) 42. (c) 43. (c) 44. (d) 45. (a) 46. (b) 47. (d)
48. (b) 49. (a) 50. (c) 51. (d) 52. (b) 53. (a) 54. (c) 55. (a) 56. (16) 57. (c)
58. (a) 59. (b) 60. (1) 61. (2) 62. (c) 63. (b) 64. (d) 65. (b) 66. (d) 67. (a)
68. (4) 69. (d) 70. (b) 71. (b) 72. (2) 73. (c) 74. (a) 75. (c)

EXPLANATIONS
  When rod is vertical
1. Acceleration = gsin. Find . a–b
2. Use relative motion, taking A at rest. l
F  mg  m2
2
3. Find tension between 1 kg and 3 kg block.
3 5
T = kx  F  mg  mg  mg
 2 2
4. Find V cm . 14.
5. Taking m2 as infinite, use formula.

6. E  1  stress  strain
V 2 +q –q
A
7. MVR = MVcmR + Icm B
8. Apply conservation of angular momentum about C
the C.M. D
Kq KQ Kq
9. Mgl  1 Iw 2  
3a 3a 4a
0
2
   Q  q 4
10. VRM  VR  V m
Kq Kq 4 Kq Kq
11. Not possible for any value of m to get the com at the VA    
2a 3a 4a 6a
centre.
 VA  VC  Kq 6a
1 1 1
12.  
3x x F V 6
15. R    10 
i 0.6
4 1
 V 6
3x F i   0.5A
R  r 10  2
1 1 1 16.
 
2 6  x 6  x F b y

3 1 4 3 
  a
2  6  x  F 3x 2  6  x  x
x = 48 cm
 shift of screen = 3x – 2(6 + x) = 36 cm
13. Loss in PE = Gain in KE
l 1  ml2  2
Don’t be confused see clearly that the angle between
mg   the area vector of loop and B will always remain con-
2 2  3 
stant (90°).
3g  Induced emf = Ba cos 90 (no change in flux)
2 
l  Inducd current = 0
 MOCK TEST 7 9

cos   2  x 2dx   g xdx

L L
17. 2q q 8q
 0  0
x 9–x
2L3 gL2 3g
For potential energy to be minimum, the bigger cos    cos  
3 2 22L
charges should be farthest.
19. In FBD arrangement, we have
Suppose x be the distance of q to 2q. Then, potential
F = force in agging.
energy of the system is shown in figure would be
So, force for ring,
 (2q)(q) (8q)(q) (8q)(2q) 
UK    N2
 x (9  x) 9 

1 N1
Here, K
40 a
F
F
f2
For U to be minimum 2  8 should be minimum. mg
x 9x a
f1
d 2 8  mg
 0
dx  x 9  x 
mg sin – f1 + F = ma ... (i)

2

8
0x3
f1r = mr2 ... (ii)
x2 (9  x)2
Force equation for sphere
i.e., distance of charge q from 2q should be 3 cm. mg sin – f2 – F = ma ... (iii)
So, electric field at q
2 2
f2r  mr  ... (iv)
K(2q) K(8q) 5
E   zero
(3  10 2 )2 (6  10 2 )2
[a = r for pure rolling]
18. For equilibrium of rigid body net torque acting on Solve all equations
body should be zero
3
Here only two forces, one is gravity force and other F mg sin 
17
is centrifugal force (if rod is considered as frame of
reference). 20. Initial energy of electrons = 2eV
Here notice that centrifugal force is variable because Energy of electron in 1st excited state
distance of mass from axis is variable that’s why
12
radius is variable and because of that centrifugal force (i.e., n = 2) = – 13.6 × = – 3.4 eV
22
is variable.
Photon of energy = 2 – (– 3.4) = 5.4 eV will be
 emitted.
12400
 KEmax  Ephoton  W0  5.4 
4600
 x
= 5.4 – 2.7 = 2.7 eV
X Y 3
21.  Y  X
dm2r 40 60 2
r

3X Y  3X  1
So,   
l 100  l  2  100  l
(dm)g
(r = xsin)  l  66.7 cm

 e  2 e  rn  rn ev nrn
22. B  irn2    rn  
Torque due to centrifugal force = Torque due to weight  2  2 2

(dm 2r)(x cos  )  (dm)gx sin  nh

Using, mvr  ,
2
2 (x 2 sin  cos  )  gx sin 
 e  nh 
we get: B    
 2m  2 
10 MOCK TEST 7
23. Conceptual 36. (concentration)
 0n h2 2 O O O
24. The Bohr radius, rn 
me2 P P P
ls r Y 37. HO H H HO OH H HO OH
25.  a, s  b, s  c OH
lb rb Yb
(H3PO2) (H3PO3) (H3PO4)
Also, lb 
 2Mg l &b
ls 
 3Mg l . s

 r  Y
2
b b  r  Y
2
s s
38. order of oxidising power Cl2 > Br2 > I2
41. (K.E.)1 = 2(K.E)2
ls
Solve for hv1 – hv0 = 2(hv2 – hv0)
lb
or hv0 = 2hv2 – hv1
26. CaCO3 (s) 

 CaO(s)  CO2
 or v0 = (2v2 – v1) = 2 × 2 × 1016 – 3.2 × 1016
moles (initial) 0.2 0 0
= 8 × 1015 Hz
moles (equilib.) 0.2(1  0.65) 0.2  0.65 0.2  0.65
1
42. H+ (aq) + e– 2
H2(g)
0.2
KC   0.65
10 Here n = 1
0.0591V [pH2 ]1/ 2 0.0591V (pH )1/ 2
KP  K C (R  1073)  1.145 atm. E  E  log 0 log 2 
1 
[H ] 1 [H ]
27. 

 2NH3  CO2
NH2COONH4 (s)  (pH2 )1/ 2
2p p E will be negative if is more than 1.
[H ]
3p = 3  p = 1  when p(H2) = 2 atm and [H+] = 1 M
Kp = (2p)2(p) = 4 atm3. E will be negative.
28. At pH = 3,[H ] = 10 M + –3
45. The tri oxides of N and Bi can’t be obtained by direct
At pH = 4,[H ] = 10 M+ –4 combination with oxygen. But out of N and Bi, NCl3
When in equal volume of the two solutions are mixed, hydrolyses completely while BiCl 3 hydrolyses
the [H+] partially. Hence the oxide is Bi2O3. The reactions
involved are
10 3  104 10 3 [1  0.1] 1.1
    10 3 
Bi(NO3 )3  Bi2O3  3NO2
2 2 2

[H+] = 5.5 × 10–4 BiCl3  H2O  BiOCl  2HCl

– log[H ] = – log(5.5) – log 10
+ –4
46. Fact
pH = – 0.7404 + 4 = 3.26
47.  X  2Cr 3   10OH  3H2O2  2CrO24
29. CH3COO– when hydrolysed generates OH– ions green yellow
making the solution basic. CH3COONH4 results in a
neutral solution since Ka(CH3COOH) = Kb(NH4OH).  Y  CrO24  2H2O2  2H  2CrO5  3H2O
blue
hc
30. Energy of radiation emitted =   Cr2O3  7 / 2O2  H2SO4  Cr2  SO4 3  3H2O

48. Fact
3.99  10 13 kJs mol1  3  108 ms1
 = 471.8 kJ/mol 49. Fact
253.7  109 m
50. (cis/trans) i.e. Geometrical
Dissociation energy = 430.53 kJ/mol
51. Let a = a1i + a2j + a3k
 Extra energy, 471.80 – 430.53 = 41.27 kJ/mol,
 a × i = (a1i + a2j + a3k) × i = – a2k + a3j
is converted into kinetic energy.
(a × i)2 = (a × i) (a × i) = (– a2k + a3j) (– a2k +
41.27
Fraction   100  8.74% . a3j)  a22  a32
471.80

12 Similarly (a × j)2  a32  a12 and (a  k)2  a12  a22

33. OH   1 10  1 105  pOH = 5
  0.01
(a × i)2 + (a × j)2 + (a × k)2 = 2(a12  a22  a32 )  2 | a |2 .
 pH = 14 – 5 = 9
 MOCK TEST 7 11

52. x  1  y  1  z  1  r1 , any point is (2r1  1,3r1  1,4r1  1) 60. A(adj.(A))= | A | 

1 0

2 3 4 0 1 
x 3 y k z
   r2 , any point is (r2  3,2r2  k,r2 ) .   = |A|.
1 2 1
cos  sin  
If the lines are intersecting Now | A |   
  sin  cos 
 2r1  1  r2  3,3r1  1  2r2  k,4r1  1  r2 = cos2 + sin2 = 1
61. The given equation can be written as
9
On solving, r1  3 / 2,r2  5 , k = . 1  sin x
2
 2cos x
cos x
53. As we know a square matrix A  [aij ] is called an
 
1  sin x  2cos2 x  2 1  sin2 x 
upper triangular matrix if aij  0 for all i > j
 2 sin2 x  sin x  1  0
(n  1)n
Number of zeros = (n  1)  (n  2)  .....  2  1   1  sin x  2sin x  1  0
2
 sin x  1 or 1 2
55. We have, 1  p  p2      pn  0
Now sin x  1  x  3 2 for which the given equation
Multiplying both sides by p–1,
is not meaningful. and sin x  1 2  x   6 or 5 6
p1  I  Ip  .....  pn 1I  0.p 1  The required number of solutions is 2.
p1  I(1  p  ....  pn 1)  0 1 n  1 n
62. tan 1  tan1  tan1  n  1  tan 1  n
1  n  n  1 1  n  n  1
 p1  I(1  p  p2  ....  pn 1)
so that L.H.S. of the given equation is
  ( pn )  pn . tan1 2  tan1 1  tan1 3  tan 1 2  ...  tan1  n  1  tan1 n
15 n  1 1 n
56. ( 2  3 )15   15 Cr .( 2)r ( 3 )15  r  tan1  n  1  tan 1 1  tan1  tan1
r 0
1   n  1 n2
15  r n n
15
So that tan1  tan1    
  15 Cr 2r / 2.3 2
n2 n2
r 0
63. x + y = 1 meets x-axis at A(1, 0) and y-axis at
r 15  r B(0, 1)
For integral terms 2
must be a integer and
2 y
should also be a integer. But these two conditions B
cannot fullfilled at the same time. Hence all terms in
the expansion are irrational. Thus there are 16
P
irrational terms. M1
M2
57. Number of non-negative integral solutions
= coeff. of x10 in (1 + x + ... x10)3 x
O P3 P2 P1 A
= x10|(1 – x11)3 (1 – x)–3
= x10|(1 – x)–3 = 12C10 = 12C2 The coordinates of P are (1/2, 1/2) and PP1 is
perpendicular to OA.
58. For no trivial solution, we must have
 OP1  P1 P  1 2
2a 2 3
1 a 2 0
Equation of line OP is y = x.
2 0 a We have  OMn 1 2   OPn 2  PnMn 12  2  OPn 2
 2a(a2 – 0) + 2(a – 4) + 3(0 – 2a) = 0  2pn2  say 
 2a3 + 2a – 8 + 0 – 6a = 0 1
Also,  OPn 1 2   OMn 1 2  Pn 1Mn 12  2pn2  pn21
 (a – 2) (a + 2a + 2) = 0
2 2
1 2 1
 a=2  pn2  pn 1  pn  pn 1
4 2
59. (aI + bA)2 = (aI + bA) (aI + bA) 1 1
 OPn  pn  pn 1  2 pn  2  ...
= a II + b AA + ab(IA + IA)
2 2 2 2
1 1
= a2I + 2abA (as AA = 0, IA = AI)  n 1 p1  n
2 2
12 MOCK TEST 7
64. An equation of the chord of contact of P with respect 68. 3cos ec 2 x  2 3 cos ecx.sec x  3 sec 2 x  0
to the given circle is
 3cos2 x  2 3 sin x.cos x  3 sin2 x  0
3 5
2xh  2yk   x  h   y  k   7  0 3 cos 2x  3 sin 2x  0
2 2 

 3  5 3 5 sin2x
 x  2h    y  2k    h  k  7  0 … (i)   3  tan 2x  3
 2  2 2 2 cos2x
which should be same as the given line  n 
 2x  n   x 
9x + y – 28 = 0 ...(ii) 3 2 6

Comparing (i) and (ii) we get  2 5 5

 x , , ,
6 3 6 3
4h  3 4k  5 3h  5k  14
 
18 2 2  28 69. CD  2ab cos C  2ab cos   ab
then h  9k  12 and 3h  117k  126 ab 2 ab 2 ab

solving for h, k we get h = 3, k = –1 70. dy  y  x2

dx x
So, the point P is (3, –1). But we note that
 xdy + ydx = x3dx
S  3,  1  2  9  2  1  3  3   5  1  7  0
2
where
 x4 
 d(xy)  d 
S  2x 2  2y 2  3x  5y  7  4 
 
showing that P lies inside the given circle and the x4
 xy  C
cannot be the required point. Thus the given line 4
cannot be the chord of contact of the given circle for  4xy = x4 + 4C
any point P.
Since y(1) = 1, therefore
65. Let equations of OA and OB be y = mx and y =
 4 = 1 + 4C
–(1/m)x. Then the x-coordinates of the points of
intersection O and A chrod OA and the circle  4C = 3
x 2  y 2  2x  4y  0 are given by Thus solution is 4xy = x4 + 3

x 2  m2 x 2  2x  4mx  0 or 1  m2  x 2   4m  2 x  0 71. 3AB  33 A B  27  1  3  81

or  
x  1  m2 x  4m  2  0
 
72.  2  6  2  0

That is, x = 0 or x = (2 – 4m)(1 + m2). Therefore, the  10  6 9  2 8  0 ...(1)

 2  4m m  2  4m   2  6  2  0
coordinats of A are  , 
 1  m2 1  m2 
 10  69  28  0 ...(2)
2
 2  4m 2

 2  4m 
OA  2
 1  m2 

1  m2  
1  m2
Subtract (2) from (1)
73. Equation of the line joining given points is
Replacing m by –1/m, we get
2  3
OB2 
 2m  42 y2 x5
2
50
1 m
 yx3
Since OA = OB (given), we get
74. Equation of any plane through (3, 4, –1) which is
 2  4m2   2m  42  12m2  32m  12  0

 3m2  8m  3  0  
parallel to the plane is r· 2iˆ  3ˆj  5kˆ    0
66. It is possible if origin lies outside the circle and circle
intersects both co-ordinate axis in two distinct points. If r  xiˆ  yjˆ  zkˆ , we get 2x  3y  5k    0
 c > 0, a2 > c, b2 > c This plane passes through the point (3, 4, –1) if
67. a – x = x – x2 should have equal roots 2  3  3  4  5  1    0 or it x = 11 and hence the

 x2 – 2x + a = 0 should have equal roots

equation of the required plane is
 4 = 4a  
r· 2iˆ  3ˆj  5kˆ  11  0

 a=1 h 1 k 3 p  4  1  6 
75.    2  
and that equal root is 1 2 0  5 
2
x 1  9 13 
2 h, k, p    5 , , 4
 5 
 x = 1, y = 0.
 MOCK TEST – 8
5. Starting from the mean position a body oscillates
PHYSICS (SECTION – A)
simple harmonically with a period of 2 s.
1. A wire frame in the shape of an equilateral triangle is
(a) Its kinetic energy will become 75% of the total
hinged at one vertex so that it can swing freely in a
vertical plane, with the plane of the  always 1
energy after s
6
1
remaining vertical. The side of the frame is m. (b) Its kinetic energy will become 75% of the total
3
1
The time period in seconds of small oscillations of energy after s
the frame will be 12
(c) Magnitude of its momentum will become half of

(a) (b)  2 1
2 initial after s
12
  (d) Magnitude of its momentum will become half of
(c) (d)
6 5
1
initial after s
 7 6
2. In an adiabatic expansion of air     the volume
 5 6. A certain object floats in fluids of density
increases by 5%. Then, the percentage change in
pressure is approximately (i) 0.90 (ii) 0 (iii) 1.10
(a) + 7% (b) + 3% Which of the following statements is true?
(c) – 5% (d) – 7% (a) the buoyant force of fluid i is greater than the
3. A tube of length L1 is open at both ends. A second buoyant forces of the other two fluids
tube of length L2 is closed at one end and open at (b) the buoyant force of fluid 3 is greater than the
the other end. Both tubes have the same fundamental buoyant forces of the other two fluids
frequency of vibration of air in it. What is the value of (c) the three fluids exert the same buoyant force
L2?
(d) the object displace the same volume of all three
(a) 4L1 (b) 2L1 fluids
L1 L1 7. Two whistles A and B each have frequency of 500
(c) (d)
2 4 Hz. A is a stationary and B is moving towards the
4. A rectangular bar of soap had density 800 kg/m3 floats right (away from A) at a speed of 50 m/s. An observer
in water of density 1000 kg/m3. Oil of density 300 is between the two whistles moving towards the right
kg/m3 is slowly added, forming a layer that does not with a speed of 25 m/s. The velocity of sound in air
mix with the water. When the top surface of the oil is is 350 m/s. Assume that there is no wind. Which of
at the some level as the top surface of the soap. the following is false?
What is the ratio of the oil layer thickness to the (a) the apparent frequency of whistle B as heard by
x A is 437 Hz approximately.
soap's thickness, ? (b) the apparent frequency of whistle B as heard by
L
observer is 469 Hz approximately.
Oil x (c) the difference in the apparent frequencies of A
L Soap and B as heard by the observer is 4.5 Hz.
(d) the apparent frequencies of the whistles as
observer by each other are the same.
2 2 8. 3 moles of an ideal monoatomic gas at 400 K are
(a) (b)
10 7 mixed at constant volume with 2 moles of helium at
600 K in an insulated vessel. The temperature of the
3 3
(c) (d) resulting mixture is________(K)
10 8
2 MOCK TEST 8

9. Three identical metal rods A, B and C are placed 16. A conducting sphere is connected with earth and a
end to end and a temperature difference is maintained concentric spherical shell is given a charge Q.
between the free ends of A and C. If the thermal Choose the correct option.
conductivity of B(KB) is twice that of C(KC) and half
that of A(KA), then the effective thermal conductivity Q
of the system will be
r
KA 6KB
(a) (b)
7 7
R
6K A
(c) (d) none
7 (a) the charge on the sphere must be zero
10. A clock pendulum made of invar has a period of 0.5 (b) the charge on the sphere must be positive
sec at 20°C. If the clock is used in a climate where Qr
average temperature is 30°C, approximately how (c) the magnitude of charge on the inner sphere is
R
much fast or slow will the clock run in 106 sec. [invar
(d) None of the above
= 1×10–6/°C]
17. A half section of thin uniform pipe of mass m and
(a) 5 sec fast (b) 10 sec fast
radius r is released from rest. Pipe rolls without
(c) 10 sec slow (d) 5 sec slow slipping. The change in PE of pipe when it has rolled
11. Kinetic energy of a particle moving in a straight line through 90°.
varies with time t as K = 4t2. The force acting on it
is
(a) increasing (b) constant
(c) decreasing (d) None of these

12. What is  value for transistor whose   0.98

________
13. The velocity and acceleration vectors of particle
 4mgr 2mgr
undergoing circular motion are v  2iˆ m/s and (a) (b)
 

a  2iˆ  4ˆj m / s2 at some instant of time. The radius (c) mgr (d) 2 mgr
of circle is________(m)
18. A potentiometer has an uncertainty of 0.0001 V. If
14. 6 identical rods are connected as shown. The
it is used to measure current through a standard
temperature of junction B will be________(°C)
resistance of 0.1  0.1% (uncertainty). The voltage
across the resistance is measured to be 0.2514 V.
200°C 20°C
A B C D W hat is the percentage uncertainty in the
measurement of current?
(a) 1.04% (b) 2.01%
15. 4 resistances are connected to a DC battery as
shownmaximum power will be develop across ___ (c) 2.08% (d) 0.08%
ohm resistor 19. A ball rolls without slipping on horizontal surface and
then moves up the inclined shown. If the height
3 12 attained is h1 and h2 with sufficiently rough track
and with smooth track respectively then,

6 36
h
E
(a) 3 (b) 6
(c) 12 (d) 36 (a) h1 = h2 (b) h1 < h2
(c) h1 > h2 (d) h2 = 2h1
 MOCK TEST 8 3

25. Figure shows the variation in temperature  T  with

20. The object O is placed in front of mirrors as given. If
the velocity of image I3 is v (magnitude), then what
will be speed of object? the amount of heat supplied (Q) in an isobaric
process corresponding to a monoatomic (M),
I2 I3
diatomic (D) and a polyatomic (P) gas. The initial
state of all the gases are the same and the scales
for the two axes coincide. Ignoring vibrational
degrees of freedom, the lines a, b and c respectively
correspond to:
O I1
a
Q b
(a) v (b) 2v
c
(c) 3v (d) 5v T
21. An electric current is flowing through a circular coil (a) D, M and P (b) P, D and M
of radius R. The ratio of the magnetic field at the
(c) P, M and D (d) M, D and P
centre of the coil and that at a distance 2 2 R
from the centre of the coil and on its axis is: CHEMISTRY (SECTION – B)
(a) 8 (b) 27 26. Two vessels of volume 2V and 3V contain two
gases A and B separately at 1.5 and 4 atm
(c) 36 (d) 2 2
respectively. If the vessels are connected through
22. A shunt of resistance 1  is connected across a a tube (negligible volume) at constant temperature,
the total pr es sur e of gas eous m ixtur e
galvanometer of 120  resistance. A current of 5.5
is________(atm)
ampere gives full scale deflection in the
27. 1 L each of 1 M HCl and 1 M NaOH are mixed and
galvanometer. The current that will give full scale
rise in the temperature of solution, is x°C. When
deflection in the absence of the shunt is nearly:
500 ml each of 1 M H 2SO 4 and 1 M Ba(OH) 2 are
(a) 0.045 ampere (b) 0.004 ampere mixed, the temperature rise is y°C. Approximate
(c) 0.5 ampere (d) 5.5 ampere relation between x and y is
23. When two sound waves travel in the same direction (a) x = y (b) y = 2x
in a medium, the displacements of a particle located (c) x = 2y (d) y = 4x
at 'x' at time 't' is given by:
28. When one mole of gas is heated at constant
y1  0.05cos  0.50x  100t  volume, its temperature is raised from 298 K to
309 K. Heat supplied to the gas is 500 joule. Then
y 2  0.05cos  0.46x  92t  which one of the following statements is correct?
where y1 and y2 and x are in meters and t in seconds. (a) q = w = 500J, U = 0
The speed of sound in the medium is_______(m/s) (b) q = U = 500J, w = 0
  (c) q = w  500J, U = 0
24. Two point dipoles of dipole moment p1 and p2 are
  (d) U = 0, q = w = – 500J
at distance x from each other and p1 p2 . The force 29. The van der Waal's equation reduces itself to the
between the dipoles is ideal gas equation at:
(a) high pressure and low temperature
1 6p1p 2 1 3p1p2
(a) (b) (b) low pressure and low temperature
4 0 x 4 4 0 x 3
(c) low pressure and high temperature
1 8p1p2 1 4p1p 2 (d) high pressure alone
(c) (d)
4 0 x 4 4 0 x 4 30. The oxidation state of sulphur in H2S2O8 is________
4 MOCK TEST 8

31. Which of the following sets of quantum number is

38. For I2  2e 
 2I , E0  0.54 V for
correct for an electron in 4f orbital?
1 2Br  
 Br2  2e; E0  1.09V
(a) n = 3, I = 2, m = – 2, s = 
2
1  Fe2  2e ; E0  0.44 Volt .
For Fe 
(b) n = 4, I = 4, m = – 2, s = 
2
W hich of the following reactions is a non-
1 spontaneous reaction.
(c) n = 4, I = 3, m = + 1, s = 
2
1 (a) Br2  2I 
 2Br   I2
(d) n = 4, I = 3, m = + 4, s = 
2
32. How many moles of KMnO4 are needed to oxidize  Fe2  2Br 
(b) Fe  Br2 
a mixture of 1 mole of each FeSO 4 and FeC2O4 in
acidic medium?  Fe2  2I
(c) Fe  I2 

4 5
(a) (b) (d) I2  2Br   2I  Br2
5 4
39. If S  O2 
 SO2 ; H  298.2 kJ
3 5
(c) (d)
4 3
1
SO2  O2  SO3 ; H  98.7 kJ
33. Equal mass of methane and ethane have their 2
kinetic energy in the ratio 3 : 1. Then their
temperatures are in the ratio of SO3  H2O 
 H2SO4 ; H  130.2 kJ
(a) 5 : 8 (b) 45 : 8
(c) 15 : 8 (d) 8 : 5 1
H2  O2 
 H2 O ; H  227.3 kJ
2


34. In the reaction C(s)  CO2 (g) 
 2CO(g) the The enthalpy of formation of H2SO4 at 298 K will be
equilibrium pressure is 12 atm. If 50% of CO 2 (a) 754.4 kJ (b) 320.5 kJ
reacts then Kp will be________(atm)
35. Under the same conditions, how many ml of 1 M (c) 650.3 kJ (d) 433.7 kJ
KOH and 0.5 M H2SO4 solutions respectively when
mixed for a total volume of 100 ml produce the 40. For reaction A 2  2B 
 2AB
highest rise in temperature?
(a) 33 : 67 (b) 67 : 33 [A2] [B] Rate (M sec –1 )
–2
(c) 40 : 60 (d) 50 : 50 0.1 0.2 1  10
36. Carbohydrates which differ in configuration at the –2
0.2 0.2 210
glycosidic carbon (i.e. C1 is aldose and C2 in ketoses)
0.2 0.8 4  10–2
are called
(a) Anomers Then order w.r.t. A2 and B are respectively
(b) Epimers (a) 1, 2 (b) 2, 1
(c) Diastereomers 1
(c) 1, (d) 2, 2
(d) Enantiomers 2
37. If the total vapour pressure of the liquid mixture A 41. The correct order of decreasing acidic strength of
and B is given by the equation: oxyacids of group 15 elements is
P = 180 XA + 90 then the ratio of the vapour pressure (a) HNO3, H3SbO4, H3AsO4, H3PO4
of the pure liquids A and B is given by : (b) H3PO4, H3AsO4, H3SbO4, HNO3
(a) 3 : 2 (b) 4 : 1 (c) HNO3, H3PO4, H3AsO4, H3SbO4
(c) 3 : 1 (d) 6 : 2 (d) HNO3, H3AsO4, H3PO4, H3SbO4
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 MOCK TEST 8 5
42. Identify the incorrect statement: 48. Which of the following would not rearrage to a more
(a) CuSO4 reacts with KCl in aqueous solution to stable form?
give Cu2Cl2
(b) CuSO4 reacts with KI in aqueous solution to give
Cu2I2 (a) + (b) +
(c) CuSO4 reacts with NaOH and glucose in aqueous H
medium to give Cu2O
(d) CuSO4 on strong heating gives CuO
43. Which of the following hydrate is diamagnetic?
+
(c) (d)
3
+
(b) Cu(H2O)6 
2
(a) Mn(H2O)6 

3 2
(c) Co(H2O)6  (d) Co(H2O)6  H 2(1mole)Pt
49. A
44. The geometry of Ni(CO)4 and Ni(PPh3)2Cl2 are
(a) both square planar Double bond equivalent (degree of unsaturation) of
(b) tetrahedral and square planar (A) is________
(c) both tetrahedral 50. Gobar gas obtained by bacterial fermentation of
(d) square planar and tetrahedral animal refuse contains mainly methane. If heat of
combustion of CH 4 is 809 kJ, then gobar gas
45. The two isomers given below are
produced per day for small village community of
CO2H CO2H 100 families, assuming that each family has to
be supplied 20,000 kJ of energy per day to meet
H OH H OH all needs and that the methane content in gobar
HO H H OH gas is 80% by weight, would be________(kg)
CO2H CO2H
MATHEMATICS (SECTION – C)
(a) Enantiomers (b) Diastereomers
51. The G.M. of the numbers 3, 32, 33 ... 3n is
(c) Mesomers (d) Position isomers
2 n1
46. Relative rate reaction of following amine with methyl
(a) 3 n (b) 3 2
iodide is
n n1
(c) 3 2 (d) 3 2
N N
N
N 
52. If A  B  where A, B  R+, then maximum value
2
(A) (B) (C)
of sinA + sinB is equal to

(a) A > B > C (b) A > C > B (a) 1 (b) 3

(c) B > C > A (d) B > A > C (c) 2 (d) None of these
47. The two compounds shown below are
1 1 1
H H 53. The sum of the series    .... is
O O 3  7 7  11 11 15

and
1 1
(a) (b)
H 3 6
H
1 1
(i) (ii) (c) (d)
9 12
(a) Diastereomer (b) Enantiomer
(c) Epimer (d) None
6 MOCK TEST 8

54. If z and  are to non-zero complex numbers such  

60. If a and b be two non-collinear unit vectors such
 
that |z| = 1 and arg (z) – arg ()  , then z is  1 
2 that a  (a  b)  b then the angle between a and
2
equal to 
(a) 1 (b) – 1 b is equal to
(c) i (d) – i 
(a)
i
2
55. Real part of ee is 
(b)
4
(a) ecos  [cos(sin )] (b) ecos  [cos(cos )]
(c) Informations are inconsistent
(c) esin  [sin(cos )] (d) esin  [sin(sin )] (d) None of these
61. If z1, z 2 ,...., z3 lie on the circle z  2 , then value of
dy
56. General solution of (2x – 10y )  y  0, is 3
1 1 1
dx E  z1  z 2  ...  zn  4   ... 
z1 z2 zn
(a) 2x2y = y5 + C (b) 2xy2 = y5 + C
is________
(c) xy = 2y + C
2 5
(d) xy2 = y5 + C 62. The equation has
57. Area bounded by the curve, y = maximum {sinx,
x  3  4 x 1  x  8  6 x 1  1

cosx} and x-axis, between the lines x  and (a) no solution (b) only one solution
4
(c) only two solution (d) more than two solutions
x = 2 is equal to
 

63. If 0  ,   and x   sin2n , y   cos2n 
(4 2  1) 2
(a) sq. units (b) (4 2  1)sq. units n0 n0
2 
and z   cosn     cosn     , then
(4 2  1) n0
(c) sq. units (d) None of these (a) xyz + 1 = yz – zx (b) xyz – 1 = yz + zx
2
(c) xyz – xy = yz – zx (d) xyz + 1 = yz + zx
1 n n n  64. If a = log12 18, b = log2454 then the value of ab +
58. lim  1    ...   is equal
n n  n 1 n2 4n  3  5(a – b) is________
65. The number of positive integral solutions of the
to________
equation x1 x2 x3 x4 x5 = 1050 is________
sin x 66. If the slope of one line represented by a3x2 – 2hxy +
59.  sin 4x dx is equal to b3y2 = 0 is square of the slope of other line, then
(a) h = 2ab(a +b) (b) h = ab(a + b)
1 1  2 sin x
1 1  sin x (c) 3h = 2ab(a + b) (d) 2h = ab(a + b)
(a) ln  ln C
2 2 1  2 sin x 8 1  sin x 67. In triangle ABC; sinA, sinB and sinC are in A.P.,
then
1 1  2 sin x 1 1  sin x (a) altitudes are in H.P.
(b) ln  ln C
2 2 1  2 sin x 8 1  sin x (b) altitudes are in A.P.
(c) altitudes are in G.P.
1 1  2 sin x 1 1  sin x (d) none of these
(c) ln  ln C
4 2 1  2 sin x 8 1  sin x 68. If each pair of equations x2 + ax + bc = 0, x2 + bx +
ca = 0 and x2 + cx + ab = 0, where a, b, c are
distinct real numbers, has a common root, then sum
1 1  2 sin x 1 1  sin x of these three common roots is
(d) ln  ln C
4 2 1  2 sin x 8 1  sin x (a) a – b + c (b) – a – b – c
(c) a + b – c (d) a + b + c
 MOCK TEST 8 7
69. There are ‘n’ locks and ‘n’ matching keys. If all the 73. Let 'f' be a real valued function defined on the interval
locks and keys are to be perfactlky matched then
maximum number of trials is equal to
 1, 1 such that

(a) nC2 (b) n – 1C2 x

e  x ·f  x   2   t 4  1 dt x   1, 1 and let 'g' be
(c) n+1
C2 (d) None of these
0
70. A = {1, 2, 3, ...n}, B = {x1, y1, z1}
the inverse function of 'f'. Then g1  2   ___
The total number of function f: A  B that are onto is
equal to
1
(a) 3n – 3.2n + 3 (b) 3n + 3.2n – 3 (a) 3 (b)
2
(c) 3n – 3.2n + 1 (d) 3n – 3.2n – 3
1
  x2  (c) (d) 2
71. The domain of the function f  x   sin  log2  1
 
3

  2 
is 74. Let f  x   x 2  bx  c , b is a odd positive integer,,
f (x) = 0 have two prime numbers as roots and b+ c
(a)  2, 2 (b)  2,  1
= 35. Then the global minimum value of f(x) is
(c) 1, 2 (d)  2,  1  1, 2 183 173
(a)  (b)
4 16
sin2 x
 n cosec 2 x 
72. lim  r   81
x 0
 r 1  (c)  (d) Data not sufficient
4
(a) 0 (b) 

75. The position vector of a point P is r  xiˆ  yjˆ  zkˆ ,
1
(c) n (d)  
n when x, y, z  N and a  ˆi  ˆj  kˆ . If r·a  10 , the
number of possible position of P is________

ANSWERS
1. (d) 2. (d) 3. (c) 4. (b) 5. (a) 6. (c) 7. (d) 8. (480K) 9. (b) 10. (d)
11. (b) 12. (49) 13. (1m) 14. (140°C) 15. (c) 16. (c) 17. (b) 18. (a) 19. (c) 20. (a)
21. (b) 22. (a) 23. (200 m/s) 24. (a) 25. (b) 26. (3 atm) 27. (b) 28. (b) 29. (c) 30. (+6)
31. (c) 32. (a) 33. (d) 34. (16 atm) 35. (d) 36. (a) 37. (c) 38. (d) 39. (a) 40. (c)
41. (c) 42. (a) 43. (a) 44. (c) 45. (b) 46. (c) 47. (b) 48. (c) 49. (3) 50. (49.44 kg)
51. (b) 52. (c) 53. (d) 54. (d) 55. (a) 56. (c) 57. (a) 58. (2) 59. (d) 60. (c)
61. (0) 62. (d) 63. (c) 64. (1) 65. (1875) 66. (d) 67. (a) 68. (d) 69. (c) 70. (a)
71. (d) 72. (c) 73. (c) 74. (c) 75. (a)
8 MOCK TEST 8

EXPLANATIONS
1. T  2 I . V2 4E2 4E2
mgd P , P3  , P6 
R 121  3 121  6
P P
2. V  r V . 81E 2 81E2
P12  P36 
121  12 121  36
V V
3.  .
2L1 4L 2 Hence P12 is maximum.
4. Buoyant Force = Weight 16. As the sphere is earthed the net potential on it must
5. Use phase relationship. be zero. To make potential zero on the sphere some
electrons will flow from earth to sphere.
6. B = mg (in all three cases)
 V  V0  B
7. n  n0   Q
 V   Vs  A q

n1T1  n2T2
8. T r
n1  n2

3l l l l R
9. k  k  k  k
eg 1 2 3

10. t  1  T  (Vnet )A  0
t 2
1 q 1 Q
1  (VA )r  (VA )R  0   0
11. mv 2  4t 2 40 r 4 0 R
2
v = kt [Potential due to Q on shell and on sphere will be
same]
dv
 k  constant
dt Qr
 q
Hence force is constant. R
IC 98
12.   17.
IE 100
if IE = 100 IC = 98 IB = 2
IC 98 CM
   49 R
IB 2
 
13. v  2iˆ a  2iˆ  4jˆ R–2R/

v2 4 4
ar   ; r  4  1m
r r
  2R  
 PEmax  mgR  mg  R 
14. R  R R
    
200°C B C 20°C
 200      20  2R 
 mgR  mgR  mg  
R 2R   
400  2    20   140C
 2R 
 PEmax  mg  
15. 3 12   

18. Fractional error in current is

6 36 l  V R 
  
l  V R 
E
 0.0001 0.001
or    
3 & 6  in parallel = 2  0.2514 0.1 
12 & 36 in parallel = 9
  3.977  10 4  0.01
 
E 2E 9E
i V2  , V9 
11 11 11   0.0103977
 MOCK TEST 8 9
Percentage of uncertainty in the measurement of
 0i 0iR2
21. Bcenter  & Bdistance 
l 3

 
 100  0.0103977  100 2R  2

2
current i.e., l 2  R2  2 2R 
 

l
 100  1.039%  1.04% 22. 5.5  1  ig  120  ig  0.045A
l
where ig is the maximum deflection current
19.
Rough  100 92
23. v   or  200ms1
surface k 0.5 0.46

 dE1
24. Force of one dipole on the other: F  p2 , where
h1 dr
v
E1 is the electric field of dipole of dipole moment p1.
k·2p1
A ball rolls for rough surface, the linear and angular Also, E1 
r3
both the velocities reduce and at the highest point
ball will come at momentarily rest. dE1 6kp
 41
and
dr r
So, 1 mv 2  1 T2  mgh1 ...(i)
2 2 6p1p2
F
40r 4
For plane surface, only the linear velocity of the ball
will become zero due to ‘mg sin’ at the highest
point. 25. CP  monoatomic   5R , CP  diaatomic   7R
2 2

 CP  polyatomic   4R neglecting vibrational dof 

Plane The slope of the graph is proportional to CP

surface
26. PV = P1V1 + P2V2
 P × 5V = 1.5 × 2V + 4 × 3V
h2
v P = 3 atm.
27. HCl + NaOH  NaCl + H2O
1 mole 1 mol 1 mol H = – 13.7
1
So, 2 mv 2  mgh2 ...(ii) When this heat is used to increase the temperature
of 2 L solution, temperature was x°C. Now, if we add
So, from Eqs. (i) and (ii), we get
500 ml each of 1 M H2SO4 and 1 M Ba(OH)2.
h1 > h2
H+ + OH–  H 2O
20. Let say object moves with speed u image l1 moves
1 mol 1 mol 1 mol
with same speed u towards mirror. Image I2 will move
horizontally with object with same speed in same (From H2SO4) (from Ba(OH)2) H = – 13.7
direction. As we know that during that image forma- This heat is used to increase the temperature of 1 L
tion all four (images and object) will lie on the cor- solution, hence temperature should be double,
ners of a rectangle so like other three points, fourth y = 2x.
point will have to move with same speed so speed of 28. Since at constant volume
image I3 will be equal to object.
dV = 0, w = P dV = 0
I2 I3  E = q + w
 E = q
29. Let us take the Vanderwaal’s gas equation for 1 mole.
 a 
 P  2  (V  b)  RT . So, at high temperature and low
 V 
O v I1
pressure the correction factors will be negligible.
10 MOCK TEST 8
30. The given compound is H2S2O8 or Perdisulphuric acid. 38. I2  2Br   2I  Br2
Let the oxidation state of S in H2S2O8 be A. (assuming
oxidation state of each oxygen). E0cell  0.54  1.09  0.55

2(+1) + 2A + 8(–2) = 0 E0cell   ve (Reaction is non spontaneous)

2A = 14
39. By adding all equations
A = +7
H2  S  2O2  H2SO4
Although it looks +7. But it is wrong because the
oxidation state of an element can not exceed the H  H1  H2  H3  H4  754.4 kJ
valence electrons. So, there is a peroxide linkage.
Hence the oxidation state of S in H2S2O8 is +6. 40. Rate  K  A 2 x By
O O R2
 2  2x  x  1
H – O – S – O – O – S – OH R1
O O
R3 1
 2  4y  y 
31. For 4f R2 2
n = 4, I = 3 and m can be – 3 to 3.
41. As we move down the group, the acidic strength of
32. Equivalents of KMnO4 = equivalent of FeSO4 + oxyacid decreases.
equivalents of FeC2O4.
42. CuSO4 reacts with KI to give Cu2I2 (white ppt.) but
x × 5 = 1 × 1 + 1 × 3, where x is the number of moles not with KCl.
of KMnO4.
Fehling solution mainly contains CuSO4 and NaOH.
4 When warmed with glucose (with – CHO group) gives
x= mole.
5 red ppt. of Cu2O
CuSO4 on heating gives CuO.
33. E1  3  W RT1
2 16 43. [Mn(H2O)6]2+ : Octahedral; Five unpaired electrons
– paramagnetic
3 W E 30T1 T1 8
E2   RT  1    . [Cu(H2O)6]3+ : Octahedral; Two unpaired electrons –
2 30 2 E2 16T2 T2 5
paramagnetic
[Co(H2O)6]3+ : Octahedral; No unpaired electron –
34. 

C(s)  CO2 (g) 
 2CO(g)
diamagnetic
Moles at t  0 1 0
1 1 [Co(H2O)6]2+: Octahedral; Three unpaired electrons
Moles at equilib. 1 2
2 2 – paramagnetic
Mn2+(Z = 25) : [Ar]183d5;
 1 
2
Cu3+(Z = 29) : [Ar]183d8;
(PCO)  3 / 2  12 
2 2
Kp      8  16 atm. Co3+(Z = 27) : [Ar]183d6;
PCO2  1/ 2  4
  12  Co2+(Z = 27) : [Ar]183d7;
3/2 
44. Ni(CO)4 : Tetrahedral
35. Let the volume of KOH and H2SO4 used is x mol and
Ni2+(Z = 28) : [Ar]183d8
y ml respectively, then from law of equivalence x × 1
= y × 0.5 × 2 In [Ni(PPh3)2Cl2] both the ligands PPh3 and Cl are
weak and as such cannot pair up the d-electrons.
[  n-factor for H2SO4 = 2]
Thus hybridisation is sp3 and shape is tetrahedral.
x=y
46. Due to low electronegativity of N in compound C
Again x + y = 100  x = y = 50 ml. basic character decreases. Due to umbrella effect,
37. P = 180 XA + 90 A is least reactive.
 If XA = 1 P  PA0  PA0  180  90  270 47. Non super imposable mirror image.
48. Due to cyclopropyl unique stability.
If XA| = 0 P  PB0  PB0  180  90  90
49. Each ring contributes 1DBE.
PA0 270 3 50. Total energy required per day
 
PB0 90 1 = 100 × 20,000 kJ = 2 × 106 kJ
 MOCK TEST 8 11

Now 809 kJ is produced by burning 16 g CH4 3

dx 3
58. Given limit    2 1 x  2
 2× 106 kJ is produced by burning 0
1 x 0

16  2  106 16  2  103 59. I   sin x dx

 g CH4  kg = 39.555 kg.
809 809 sin 4x

Gobar gas required to be produced per day 1 dx

4  cos.cos2x


39.555  100
 kg = 49.44 kg 1 cos x
4  (1  sin2 x)(1  2 sin2 x)
80  dx

1 2  3  .... n n(n 1) n 1 Putting t = sinx, dt = cosx.dx,

51. G.M.  (3.32.33......3n )1/ n  (3) n 3 2n 3 2
1 dt
4  (1  t 2 )(1  2t 2 )
I
52. For y = sinx; x  (0,  / 2)
tangent drawn to it at any point lies completely above 1  2 1 
4   1  2t 2 1  t 2 
  dt
the graph of y = sinx,
1 dt 1 dt
Thus, sin A  sinB  sin  A  B   sin  
4  1  t2 4  1  t2

2  2  4
2
 sinA + sinB  2 . 1
t
1 1 1 1 t
 . ln 2  ln C
53. S  1  1  1    1  1    1  1   .......  1 4 2 1
t 8 1 t
4  3 7   7 11   11 15   12 2

   1
54. | z |  |  1 , arg  z    
z
i 60. a  (a  b)  2 b
 2 
      
z  (a. b)a  (a. a)b  1 b
  1  | z | |  |  1 2

    1
a. b  0, a. a   (which is not possible)
z  z 2
arg       is purely imaginary
 2  Thus information are inconsistent.
z z z 61. As z1,z2,...,z3 lie on the circle z  2 , zi  2
   0; z  z  0  z   z  
  
2
 zi 4
 z  i |  |2  i.

i  zi zi  4 for i = 1, 2, 3, ..., n
55. ee  e(cos  isin )  ecos .eisin 
1 1
 ecos  [cos(sin )  isin(sin )] Thus,  z1 for i = 1, 2, ..., n
zi 4

56. (2x  10y3 ) dy  y  0  E  z1  z 2  ...  zn  4

1 1 1
z1  z2  ...  zn
dx 4 4 4
 2xdy + ydx = 10y3dy  z1  z2  ...  zn  z1  z2  ...  zn
 2xydy + y2dx = 10y4dy
 d(y2.x) = 10y4dy  z1  z2  ...  zn  z1  z 2  ...  zn

 xy2 = 2y5 + C  z  z 

=0
57. Required area,
62. Put x  1  t or x  t2  1 so that the given equation
 5 / 4 3 / 2 2
becomes
  sin xdx   sin xdx   cos xdx   cos xdx
/ 4  5 / 4 3 / 2
t 2  4  4t  t 2  9  6t  1
 5 / 4 3 / 2 2
  cos x  / 4  cos x   sin x 5  / 4  sin x 3  / 2
or  t  2 2   t  32 1

(4 2  1) or t  2  t  3  1
 sq. units.
2
12 MOCK TEST 8
63. We have 67. Altitude are AA1, BB1 and CC1.
A
1 1 1 1
x  ,y 
1  sin2  cos 2  1  cos2  sin2 

1 1
Also, cos     cos      cos2   sin2   
x y C1 B1

As 0  cos2   1, 0  sin2   1,  1  cos2   sin2   1

1 1
 1   1 B C
x y
A1

 n 1 1 1
1 1 1 xy  AA1(a)  (BB1 )b  (CC1)c
Thus, z   x  y  
 1 1

xy  y  x 2 2 2
n 0
1   
 x y
2 2 2
 AA1  , BB1  , CC1 
a b c
 z  xy  y  x   xy or xyz  xy  yz  xz
Since, sinA, sinB, sinC are in A.P., therefore
64. We have
Since, a, b, c are in A.P.,
log2 18 1  2log2 3
a  log12 18   and 1 1 1
log2 12 2  log2 3  , , are in H.P..
a b c
2 2 2
log2 54 1  3log2 3  AA1  , BB1  , CC1 
b  log24 54   a b c
log2 24 3  log2 3
Since, sinA, sinB, sinC are in A.P., therefore
Putting x = log23, we have
Sinc, a, b, c are in A.P.,
1  2x 1  3x  1  2x 1  3x 
ab  5  a  b    5   1 1 1
2 x 3 x  2 x 3x  , , areinH.P.
a b c


6x 2  5x  1  5  x 2  1   
x 2  5x  6
1 2 2 2
 x  2 x  3  x  2 x  3  , , are in H.P..
a b c
65. Using prime-factorization of 1050, we can write the  AA1, BB1, CC1 are in H.P..
given equation as
68. x2 + ax + bc = 0 ...(i)
x1 x 2 x 3 x 4 x5  2  3  52  7 x2 + bx + ca = 0 ...(ii)
We can assign 2, 3 or 7 to any of 5 variables. We x2 + cx + ab = C ...(iii)
can assign entire 52 to just one variable in 5 ways or From (i) – (ii), we get
can assign 52 = 5 × 5 to two variables in 2C2 ways.
x(a – b) + c(b – a) = 0
Thus, 52 can be assigned in
 x=c
5
C1  5C2  5  10  15 ways
From (ii) – (iii), we get
Hence, required number of solutions x(b – c) + a(c – b) = 0
= 5 × 5 × 5 × 15 = 1875  x=a
66. a3x2 – 2hxy + b3y3 = 0 From (i) – (iii), we get
Let the slope of lines be m1 and m2 x(a – c) + b(c – a) = 0
3  x=b
Then m1 + m2  2h3 , and m1m2  a3
b b Thus sum of common roots = a + b + c.
69. For the first key, maximum number of trials needed is
Let m22  m1
n. For second key it will be (n – 1). In general for rth
a3 a 2h key, maximum number of needed trials is (n – r + 1).
 m32   m2  and m22  m2  3
b3 b b Thus required answeres = n + (n – 1) + ...... + 1
2
2h a a 2h
    ab  a2  n(n  1) n1
b3 b b2 b   C2
2
 2h = a2b + ab2 = ab(a + b)
 MOCK TEST 8 13

70. Total functions = 3n 73. Differentiating given equation we get

Functions in which one of the elements of B has no e x ·f 1  x   e x ·f  x   1  x 4
pre image = 3C1.2n.
Functions in which two elements of B has no pre Since (g of)(x) = x·as ‘g’ is inverse of f.
image = 3C2 = 1.  g  f  x    x
Thus total number of onto functions
 g1  f  x  ·f 1  x   1
= 3n – 3C1, 2n + 3C2.1n = 3n – 3.2n + 3
1
 g1  f  0   
 x 2
 f 1 0
71. f  x   sin 1  log 2     R
 
  2   g1  2  
1
f 1 0

 x2  (Here f(0) = 2 observe from hyphthesis)

  1  log 2    1
 2  Put x = 0 in (1) we get f1(0) = 3.
74. Let ,  be roots of x 2  bx  c  0 ,
1 x2 x2
   2  1 2 Then     b
2 2 2
 one of the roots is ‘2’ (since ,  are primes and
 1  x 2  4  x    2,  1  1, 2  b is odd positive integer)
 f  2   0  2b  c  4 and b + c = 35
 
2 2 2 sin2 n
72. L  lim 1cosec n  2cosec n  ....  ncosec n
x0
 b  13, c  22

sin n
  1 cosec b  2 cosec n 
Minimum value = f  13    81 .
cosec n
 n  1
lim       ....     1 ·n  2  4
x0  n 
  n  n  
75. r ·a  10
  0  0  0  ...  1 ·n  n
 x  y  z  10, x, y, z  N

Number of solutions = 10 1
C3 1  36
 MOCK TEST – 9
5. Interference fringes are obtained in Young's double-
PHYSICS (SECTION – A)
slit experiment on a screen. Which of the following
1. A wire of negligible mass elongates by l mm when a statements will be incorrect about the effect of
load W is hanged from it. If the wire goes over a introducing a thin transparent plate in the path of
pulley and two weights W each are hung at the two one of the two interfering beams.
ends, the elongation of the wire will be (in mm) (a) The separation between fringes remain unaffected.
(a) l (b) 2l (b) The entire fringe system shifts towards the side
on which plate is placed
l
(c) zero (d) (c) The conditions for maxima and minima are
2

2. A gas mixture consists of 2 moles of oxygen and 4 reversed i.e., maxima for odd multiple of and
moles of argon at temperature T. Neglecting all 2
vibrational modes, the total internal energy of the 
system is minima for even multiple of .
2
(a) 4RT (b) 15RT (d) Shape of the fringe also remains unaffected.
(c) 9RT (d) 11RT 6. According to the Bohr theory of the hydrogen atom,
3. A cyclic process ABCA is shown in PT diagram. When electrons starting in the 4th energy level and eventually
presented on PV, it would ending in the ground state could produce a total of
how many lines in the hydrogen spectra?
P B
A 7. An object was placed upright 25 cm in front of a
converging lens with a focal length of 20 cm. A
C concave mirror with a focal length of 15 cm was
T
placed 120 cm behind the lens. Which of these
describes the final image?
P B P B
A A (a) real, enlarged (b) virtual, upright
(a) (b) (c) virtual, inverted (d) inverted, diminished
C C
V V 8. A radioactive source has a half life of 20 days. During
a period of 60 days fraction of the atoms that have
P P decayed would be
B A B A
(a) 100% (b) 87.5%
(c) C (d) C
V V (c) 64% (d) 50%
9. A current I flows along a wire frame having the shape
4. In the figure shown the angle made by the light ray shown total of six straight wires of length L each,
with the normal in the medium of refractive index 1 soldered to form two perpendicular square shapes.
is: The magnetic moment of this wire frame is

30°
n1 = 3
n2 = 2
n3 = 1
n4 = 2
n5 = 1.6 (a) IL2 2 (b) 2IL2 2

(a) 30° (b) 60° IL2

(c) (d) None
(c) 90° (d) None of these 2
2 MOCK TEST 9

10. In the circuit shown in figure switch S is closed at 15. A homogeneous chain rests on a rough horizontal
time t = 0, current through inductor after long time of
table, the coefficient of friction between the chain &
closing of switch.
the table is 0.5. The maximum fraction of the length
L of the chain that can hang over the table without
slipping is
R
1 1
R S (a) (b)
2 4
E
1 1
(c) (d)
E E 3 6
(a) (b)
R 2R
16. The spring mass system inside frictionless tube
(c) zero (d) none rotating with constant  as given. Find angular
11. In a meter bridge experiment, null point is attained frequency n of mass SHM about its mean position.
at 20 cm from one end to the wire when resistance
X is balanced against another resistance Y. If X < Y, 
then the new position of null point from same end, if
one decides to balance a resistance of 4X against
Y will be__________(cm)
12. When a metallic surface is illuminated with light of k
wavelength  , the stopping potential is V, when the m
same surface is illuminated by light of wavelength
V
2  , the stopping potential is . The threshold
3
wavelength is
k
4 (a) (b) 
(a) (b) 4 m
3

8 k 
(c) 6 (d) (c)  2 (d)
3 m 2k
13. A particle is released from rest from a tower of height
17. An optical system consists of a diverging and
3h. The ratio of times to fall equal heights h i.e.
converging lens. Focal length of lens is 40 cm. Object
t1 : t2 : t3 is
is at a distance of 80 cm in front of converging lens.
(a) 5 : 3 : 1
Distance of image from converging lens is
(b) 3 : 2 : 1
(c) 9 : 4 : 1

(d) 1 :   
2 1 : 3 2 
14. An LC resonant circuit contains 400 pF capacitor &
100 H inductor. It is set into oscillation coupled to O
an antenna, the wavelength of the radiated
electromagentic waves is
80 cm Very small
(a) 377 mm
(b) 377 m
(c) 377 cm (a) 40 cm (b) 100 cm
(d) 3.77 cm (c) 120 cm (d) 80 cm
 MOCK TEST 9 3
18. Two equal point charges are fixed at x = –a and (a) Statement 1 is true and Statement 2 is false.
x = +a on the x-axis. Another point charge Q is placed (b) Statement 1 and Statement 2 both are true. But
at origin. The change in electrostatic potential energy Statement 2 is not the correct explanation of
of the system when Q is displaced by a small distance Statement 1.
x along the x-axis is approximately proportional to (c) Statement 1 and Statement 2 both are true. But
(a) x (b) x2 Statement 2 is the correct explanation of
Statement 1.
1
(c) x3 (d) (d) Statement 1 is false and Statement 2 is true.
x
23. When a metallic surface is illuminated by a light of
19. Two springs of force constants 300 N/m (Spring A)
frequency 8 × 1014 Hz, photoelectron of maximum
and 400 N/m (Spring B) are joined together in series.
energy 0.5 eV is emitted. When the same surface is
The combination is compressed by 8.75 cm. The
illuminated by light of frequency 12 × 10 14 Hz,
EA E photoelectron of maximum energy 2 eV is emitted.
ratio of energy stored in A and B is . Then A
EB EB The work function is__________(eV)
is equal to:
24. Difference between nth and (n + 1)th Bohr's radius of
4 16 hydrogen atom is equal to (n –1)th Bohr's radius.
(a) (b)
3 9 The value of n is__________
3 9 25. The binding energies per nucleon of deuteron (1H2)
(c) (d) and helium (2He4) atoms are 1.1 MeV and 7 MeV. If
4 16
 two deuteron atoms react to form a single helium
20. A uniform electric field E exists between the plates atom, then the energy released is__________(MeV)
of a charged condenser. A charged particle enters
the space between the plates and perpendicular to CHEMISTRY (SECTION – B)

E . The path of the particle between the plates is a: 26. Alkene(s) that would give the following alcohol by
(a) parabola (b) hyperbola oxymercuration-demercuration reaction is
(c) circle (d) straight line CH3
21. An engine approaches a hill with a constant speed. OH
When it is at a distance of 0.9 km, it blows a whistle
whose echo is heard by the driver after 5 seconds. If
CH3 CH2
the speed of sound in air is 330 m/s, then the speed
of the engine is : (a) (b)
(a) 32 m/s (b) 27.5 m/s
(c) 30 m/s (d) 60 m/s
(c) (d) both (a) and (b)
22. Chamber I Chamber II
ideal real
gas gas CH3
1 2 3 4
27. A 0.01 M solution of glucose in water freezes
There are two identical chambers, completely at – 0.0186°C. A 0.01 M solution of KNO 3 in water
thermally insulated from surroundings. Both will freeze at
chambers have a partition wall divinding the chambers
in two compartments. Compartment 1 is filled with (a) – 0.0093°C (b) – 0.0372°C
an ideal gas and Compartment 3 is filled with real (c) – 0.0186°C (d) – 0.093°C
gas. Compartments 2 and 4 are vacuum. A small 28. 20 ml of HCl having a certain normality neutralises
hole (orifice) is made in the partition walls and the exactly 1.0 g CaCO 3 . The normality of acid
gases are allowed to expand in vacuum. is__________(N)
Statement 1 :No change in the temperature of the 29. For the cell reaction, Cu(s)|Cu 2+(aq)||Ag+|Ag(s), if
gas takes place when ideal gas expands in vacuum.
However, the temperature of real gas goes down E = +0.34 V and E = 0.80 V and
Cu2  / Cu Ag / Ag
(cooling) when it expands in vacuum.
Statement 2 :The internal energy of an ideal gas is [Cu+2] = 0.01 and [Ag+] = 1.0 mol dm –3 the emf of
only kinetic. The internal energy of a real gas is the cell is__________(V)
kinetic as well as potential.
4 MOCK TEST 9

30. A radioactive isotope having t 0.5 = 3 days was 39. The end product 'C' in the following sequence of
received after 12 days. If 3 g of isotope is left in chemical reactions is
the c ontainer, what was the initial wt. of
CaCO  NH OH
isotope__________(g) CH3 COOH 
3
 A  B 
2 C
31. Keeping in mind that the EAN = 36, Co 2(CO) x will
be (a) acetaldehyde oxime
(a) Co2(CO)5 (b) Co2(CO)7 (b) formaldehyde
(c) Co2(CO)9 (d) Co2(CO)8 (c) methyl nitrate
32. Action of caustic soda on Al(OH) 3 gives a (d) acetoxime
compound having formula 40. A sample of wusitite FexO contains one Fe(III) for
(a) Na3AlO3 (b) NaAlO2 every three Fe(II). Calculate the value of x__________
(c) Na2Al(OH)4 (d) Al2(OH)4 41. -D-glucose and -D-glucose have a specific rotation
33. In the borax bead test of Co 2+, the blue colour of of +112° and +19° respectively. In aqueous solution
bead is due to the formation of the rotation becomes +52°. This process is called
(a) B2O3 (b) Co3B2 (a) Inversion (b) Racemisation
(c) Co(BO2)2 (d) CoO (c) Mutarotation (d) Enolisation
34. Correct formula of the complex formed in the brown 42. In chlorobenzene solutions, the basic strength of
ring test for nitrates is amines increases in the order
(a) FeSO4NO (b) [Fe(H2O)5NO]2+ (a) (C2H5)3N < (C2H5)2NH < C2H5NH2
(c) [Fe(H2O)5NO]+ (d) [Fe(H2O)5NO]3+ (b) C2H5NH2 < (C2H5)2NH < (C2H5)3N
35. Which of the following gives blood red colour with (c) (C2H5)2NH < C2H5NH2 < (C2H5)3N
KCNS?
(d) (C2H5)3N < (C2H5)NH2 < (C2H5)2NH
(a) Cu2+ (b) Fe3+
43. The correct order of increasing boiling points of the
(c) Al3+ (d) Zn2+ following compounds is
36. Which of the following statement is incorrect?
(a) Calcium carbide when heated with N2 produces O O
calcium cyanamide. C , C ,
(b) Water gas is a mixture of CO and H 2 . CH3 NH2 CH3 Cl
(c) Producer gas is a mixture of CO 2 and N2. I II
(d) SiCl4 on hydrolysis produces silicic acid.
37. Optical isomerism is not shown by complex. O O
(a) [Cr(OX)3]3 – C , C
(b) [Co(en)2Cl2]+ (Cis -form) CH3 OCH3 CH3 OCOCH3
(c) [Co(en)2Cl2]+ (Trans -form) III IV
(d) [Cr(en)3]3+
(a) I < II < III < IV
O O
(b) II < III < IV < I
O3/Zn
38. (A) . (c) II < IV < III < I
H2O H3C H
(A) is (d) II < III < I < IV
44. Certain ketone A (capable of showing iodoform test
positive) on reduction gives B. B on acidic dehydration
(a) (b)
at 443K gives C. C on reductive ozonolysis gives
CH
H3 only MeCHO. A and C in the above sequence are
CH3
respectively
CH3
(a) CH3COCH3 and CH3CH = CH2
CH3 (b) CH3COC2H5 and CH3CH2CH = CH2
(c) (d)
(c) CH3COC2H5 and CH3CH = CH – CH3
CH3 (d) CH3COC2H5 and CH3CH2 – CH(OH)CH3
 MOCK TEST 9 5
45. The major product formed in the following reaction is O
CH3OH(excess) Mg / ether
(i) Hg(OAc) , THFH O (a)    
CH = CHCH3 
2
(ii) NaBH
2  H SO 2 4
4
H2O / H O
 3
OH
O
(a) CH – CH2 – CH3 H2O / H O
Mg / ether
( b)   
3

OH OH CH OH / H

3 

(b) CH2 – CH – CH2
O
Mg / ether CH3OH(excess)
(c) CH2 – CH2 – CH2OH
( c)   –
OH
H2O / H O
 3
(d) HO CH2 – CH2 – CH3
2 H O / H O
CH3OH(excess)
46. Iso-electric point of alanine is (pH = 6). At which pH, (d) 
3
 Mg / ether
  
H SO 2 4
maximum concentration of zwitter ion of alanine will O
be present__________
47. Which of the following orders regarding thermal
stability of hydrides MH3 of group 15 is correct?
MATHEMATICS (SECTION – C)
(a) NH3 > PH3 > AsH3 (b) NH3 < PH3 < AsH3
(c) NH3 > PH3 < AsH3 (d) NH3 < PH3 > AsH3 x 1 x2  2 x(x  1)
+ +
51. If   x(x  1) x 1 x(x 2  2)
48. (y)H3N NH3(z)
x2  2 x(x  1) x 1
COOH
(x)  p0 x 6  p1x 5  p2 x 4  p3 x 3  p4 x 2  p5 x  p6 ,
The order of decreasing acidity of these acidic
then (p5, p6) =
sites is:
(a) (– 3, – 9) (b) (1, 7)
(a) x > z > y (b) z > x > y
(c) (– 3, – 5) (d) (3, – 9)
(c) x > y > z (d) y > x > z
52. The number of points with integral coordinates that
49. Solution of NH 4Cl and NaCl are taken in two test
are interior to the circle x2 + y2 = 16 is__________
tubes A and B. What will happen when precipitate
53. The term independent of x in the expansion of
of Mg(OH2) is added to both the test tubes?
n
 1
(a) Precipitation will occur in A and B. (1  x)n  1   is
 x
(b) T here will be a clear solution in A and
precipitation will occur in B. (a) 1 (b) (n + 1) Cn2n
(c) There will be clear solutions in both A and B.
(d) T here will be a clear solution in B and (c) Cn2n (d) None of these
precipitation will occur in A. 54. The median AD of the triangle ABC is bisected at E,
50. Give the correct sequence of reagents for the BE meets AC in F. Then AF : AC =
following conversion:
3 1
O (a) (b)
4 3
Br ?
C CH3 HO 1 1
(c) (d)
2 4
O 55. If the circle x2 + y2 = 4 bisects the circumference of
CH2 CH2 C CH3 the circle x 2 + y2 – 2x + 6y + a = 0, then a
equals__________
6 MOCK TEST 9

56. If two distinct chords, drawn from the point P(a, b)

 
2n 2
61. If for n  N,   1
k 2n
on the circle x2 + y2 – ax + by = 0 Ck  A , then value of
k 0
where ab  0, are bisected by the y-axis, then

  1 k  2n  2n Ck 
2n
(a) a2 > 8b2 (b) b2 > 8a2 k 2
is
(c) a2 > 4b2 (d) b2 > 4a2 k 0

57. Equation of parabola having the extremities of it's (a) nA (b) –nA
latus rectum as (3, 4) and (4, 3) is (c) 0 (d) none of these
 1 0
2
xy6
2 2 62. If A   , then A100 is equal to
(a)  x     y    
7 7
  1/ 2 1
 2  2  2 
 1 0
(a)  50 1
2 2 2
x y8
(b)  x     y    
7 7
  1 0
 2   2   2 
(b)  
 1/ 2
100
1
2 2 2
xy4
(c)  x     y    
7 7
  1 0
 2  2  2  (c) 
(d) None of these  25 0
58. The line y = mx + c, will be a normal to the ellipse (d) none of these

x2 y2 x 1 5x 7
  1, if
2 2
a b 63. If x 2  1 x  1 8  ax 3  bx 2  cx  d then value
2x 3x 0
a2 (b2  a2 )2
(a)  b2  of c is given by
m2 c2
(a) –1 (b) 12
2 2 2 2
c (b  a ) (c) 15 (d) 17
(b)  b2 
2 2 64. A group of 6 boys and 6 girls is randomly divided
m a
into two equal groups. The probability that each group
b2 (b2  a2 )2 contains 3 boys and 3 girls is
(c) a2  
m2 c2 10 5
(a) (b)
231 531
b2 (b2  a2 )2
(d) c 2   90 100
m2 a2 (c) (d)
231 231
 3 5 65. If the value of
59. The numerical value cos  cos  cos is equal
7 7 7  3 5 7 9 11 13
to sin sin sin sin sin sin sin is
14 14 14 14 14 14 14
1 3 equal to
(a)  (b)
2 2 1 1
(a) – (b)
16 8
3 1
(c)  (d) 1
2 2 (c) (d) 1
64
60. If f(x) = sin x + cos x, then range of f(x) is
6 6

66. If f1(x) = ex, f2(x) = e–x and f3(x) = f2(f1(x)), then f3 (0)
1  1 3 is equal to
(a)  , 1 (b)  , 
4  4 4
1
(a) – e (b) 
3  e
(c)  , 1 (d) None of these
4  (c) –1 (d) None of these
 MOCK TEST 9 7

67. n  N, n  1 such that 8n + 1 is a perfect square, 71. The point (1, 2) is one extremity of focal chord of
then parabola y2 = 4x. The length of this focal chord is
(a) n must be odd (a) 2 (b) 4
(b) n can't be perfect square (c) 6 (d) none of these
(c) n must be prime number 72. If a and b are chosen randomly from the set
(d) 2n can't be a perfect square consisting of number 1, 2, 3, 4, 5, 6 with
replacement. Then probability that
68. Locus of complex number satisfying
2x
 z  5  4i    ax  bx 
 z  3  2i   3 , is the arc of a circle whose radius lim    6 is
  x 0
 2 
is equal to
1 1
10 (a) (b)
(a) 5 2 (b) 3 4
3
1 2
5 (c) (d)
9 9
(c) 5 3 (d)
3
73. The number of solutions of the equation
69. AB is any focal chord of y2 = 4ax, locus of mid point
of AB is a parabola whose directrix is  
16 sin5 x  cos5 x  11 sin x  cos x  in the interval

3a a 0, 2 is__________

(a) x  (b) x  
2 2 74. The number of real solutions of
a 
(c) x  (d) None of these tan1 x  x  1  sin1 x 2  x  1  is _____
2 2
70. Tangents OA and OB are drawn from O(0, 0) to the 75. If z1 and z2 are unimodular complex number that
circle (x – 1)2 + (y – 1)2 = 1. Equation of circumcircle
of triangle OAB is satisfy z12  z22  4 and then (z1  z1)2  (z 2  z 2 )2
(a) x2 + y2 + x + y = 0 (b) x2 + y2 – x + y = 0 is equal to__________
(c) x + y + x – y = 0 (d) x + y – x – y = 0
2 2 2 2

ANSWERS
1. (a) 2. (d) 3. (c) 4. (b) 5. (c) 6. (6) 7. (a) 8. (b) 9. (a) 10. (a)
11. (50 cm) 12. (b) 13. (d) 14. (b) 15. (c) 16. (b) 17. (b) 18. (b) 19. (a) 20. (a)
21. (c) 22. (b) 23. (2.5 eV) 24. (4) 25. (23.9 MeV) 26. (d) 27. (b) 28. (1.0 N)
29. (0.52 V) 30. (48 g) 31. (d) 32. (b) 33. (c) 34. (b) 35. (b) 36. (c) 37. (c)
38. (a) 39. (d) 40. (8/9) 41. (c) 42. (b) 43. (b) 44. (b) 45. (a) 46. (pH = 6) 47. (a)
48. (c) 49. (b) 50. (a) 51. (b) 52. (45) 53. (c) 54. (b) 55. (16) 56. (b) 57. (b)
58. (a) 59. (d) 60. (a) 61. (b) 62. (a) 63. (d) 64. (d) 65. (c) 66. (b) 67. (d)
68. (b) 69. (c) 70. (d) 71. (b) 72. (c) 73. (6) 74. (2) 75. (12)
8 MOCK TEST 9

EXPLANATIONS
1. Tension remains equal to W.
t1  t1  
2  1  t 3  t1 3
 n Cv  n2Cv 2 
2. U   1 1
 n1  n2
T .
 t3   3  2 t1 
3. PV = nRT
4. Use Snell’s law.
 t1 : t 2 : t 3  1:  2 1 :  3 2 
5. Optical path becomes non-zero at the centre.
1 C
14. f  
n(n  1) 2 LC 
6.
2
7. The image formed by the lens acts as an object for the mirror.   2  3  108  4  10 10  104

1 1 1 1 1 1   377 m
   
v1 u1 f1 ; v 2 (v1 120) f2
mg m  l  x  g
15. x
1 l l
8. In three half lives, th remains.
8
(l – x)
9. Meff  M2  M2

10. After a long time, the inductor behaves as a wire thus

x
shorting the resistance in parallel.

X 20 1
11.  
Y 80 4

Y  4X x  0.5 1
x   l  x  ;   
l   1 1.5 3
4X l
Now,  16. The free body diagram of system at x displacement from
Y 100  l
mean position.
 l = 50 cm
x
hc
12. eV   m (L + x)
2

 m

eV hc 2 hc L
   or eV   2 NL Mean position
3 2 3 
At mean position,
2  hc  hc
      2
3    m2L  k

hc 4 hc hc At x displacement,
  or   
3 3 4 0
ma  k(   x)  m2 (L  x)  (k  m2 )x
 0  4
k
So, n   2
1 1 m
13. h  gt12 ; 2h  g  t1  t 2 
2
2 2 17. Image formation from 1st lens

2h h 1 1 1
 t1  t1  t 2  2  
g 9 v u f

1 1 1
 
t2 
h
g
 
2  2  t1  2 1  v 80 40

80
 v cm
1
and 3h  g  t1  t 2  t 3  3
2
2
For second lens,

6h 1 1 1
t1  t 2  t 3   3t1  
g v u f
 MOCK TEST 9 9

  
1 1 1  K  NO3
27. KNO3 ionises as, KNO3 
 
v 80 / 3 40  Concentration in solution = 2 × 0.01 = 0.02
v = –80 cm Tf = Tf – T° = kf × m for glucose

Tf 0.018
1 2Qq q2  kf    1.86 m–1
18. Ui   m 0.01
40 a 4 0  2a
Tf for KNO3 = 1.86 × 0.02 = 0.0372°C
1 Qq 1 Qq q 2 Tf = T° – Tf = 0.0000 – 0.0372 = – 0.0372°C
Uf   
40 a  x 40 a  x 40  2a 28. CaCO3 + 2HCl  CaCl2 + H2O + CO2 is
(100 g) (73 g)
1
1 2Qqa q 2
2qQ  x 
2
q2 100 g of CaCO3 is neutralised exactly by 73 g of HCl
    1  2  
4 0 a 2  x 2 4 0  2a 4 0a  a  40  2a 1g of CaCO3 shall be neutralised by

73
 2qQ  2  0.73 g HCl
 U  Uf  Ui   100
x
 40a   1N HCl is required.

19. We can write : F  k1x1 & F  k 2 x 2 . Equivalent spring con-

0.059 [Ag ]
29. Ecell  Ecell  log
k1k 2 1200
2 [Cu2 ]
stant, k   Nm1
k1  k 2 7
0.059 (1.0)2
 0.80  0.34  log
F kx  1200   8.75 
2 0.01
Now, x1      5cm
k 1 x1  7   300 
0.059
 0.46   2  0.46  0.059 = 0.52 V
2
 x 2  8.75  5  3.75 cm
N0
30. N  [n = no. of half lives]
E A E1 k1x12 Fx1 5 4 2n
    
EB E2 k 2 x 22 Fx 2 3.75 3
or N0 = N × 2n = 3 × (2)4 = 48 g
20. Velocity is constant in one direction, whereas it is varying 31. In the cobalt carbonyl there are two Co atoms joined by Metal –
with constant acceleration in a perpendicular direction. Metal bond. Each cobalt has 27 + 1 = 28 electrons on it. Since
8 more electrons (4 pairs) are needed by each cobalt atom, the
900 900  5v
21. 5    v  30ms1 Co atoms are linked to 4 carbonyl groups each.
330 330
22. Temperature and pressure of real gases decreases during OC CO On each cobalt atom
free expansion. Also, due to intermolecular forces, the internal OC CO Co = 27 electron
Co – Co
OC CO from Co – Co bond = 1 electron
energy of a real gas has some contribution of potential energy.
OC CO 4 four CO group = 8 electrons
23. 8 × 1014h = 0 + 0.5
Total = 36 electrons
12 × 1014h = 0 + 2

12  2 32. Al(OH)3  NaOH  NaAlO2  2H2O

Dividing, we get  0
8 0  0.5
33. CoO  B2O3  Co(BO2 )2
Blue bead
3  2
 0
2 0  0.5 34. Correct formula of complex ion is [Fe(H2O)5NO]2+.

30 + 1.5 = 20 + 4 or 0 = 2.5 eV

35. Fe3   3KCNS  Fe(CNS)3  3K 
24. We know, rn  n2 Blood red colour

So, (n + 1)2 – n2 = (n – 1)2  n = 4 36. Producer gas is a mixture of CO and N2.

25. Total binding energy of helium atom (2He4) 40. Let there be 1 mole of Iron atom:
= 4 × 7 = 28 MeV
1
Total binding energy of deuteron 1H2(1p + 1n) We will have amount of Fe (III) = mol
4
= 2 × 1.1 = 2.2 MeV
Hence, binding energy of 2 deuterons 3
amount of Fe (II) = mol
= 2 × 2.2 = 4.4 MeV 4
So, the energy released in forming helium nucleus from two
1 3 9
deuterons is Total positive charge due to 1 mole =  3   2 
4 4 4
28 – 4.4 MeV = 23.6 MeV
10 MOCK TEST 9

9 x 1 x2  2 x(x  1)
Total positive charge due to x mole = x
4 2
+ x(x  1) x  1 x(x  2)
Total +ve charge = Total –ve charge 2x 2x  1 1

9 8
x2 x
4 9  6p0 x 5  5p1x 4  4p 2 x 3  3p3 x 2  2p 4 x  p 5

Putting x = 0 both sides, we get p5 = 7;

Fe8 O
9
52. The points satisfying x2  y 2  16 , lie on 3  x  3,
42. In chlorobenzene solution, the basic strength of aliphatic amines
is decided on the basis of +I effect. Hence the order of basicity 3  y 3.
is 3° > 2° > 1°. The number of selections of values of x is 7, namely – 3, – 2, –
1, 0, 1, 2, 3. The same is true for y. So the number of ordered
43. CH3COCl < CH3CO2CH3 < (CH3CO)2O
pairs (x, y) is 7 × 7. But (3, 3), (3, –3), (–3, 3), (–3, –3) are
Absence of Higher rejected. So the number of points is 45.
hydrogen molecular mass
bonding and more surface area
53. (1  x)n nC0 nC1x1  nC2 x 2  ..........  nCn xn

< CH3CONH2 n
Extensive  1 n n 1 n 1 n 1
 1  x   C0  C1 1  C2 2  .....  Cn n
intermolecular   x x x
hydrogen bonding
the term independent of x will be
OH n
C0 .nC0 nC1nC1  .....  nCn .nCn  C02  C12  .......  Cn2  Cn2n
Reduction
44. CH3COC2H5   CH3 – CHCH2CH3
LiAlH4 54.
(A) (B)
A (a)
H2 SO4
  CH3CH  CH  CH3 
443K
(C) 1 F
45. In oxymercuration demercuration reaction, the product formed  E
is same as in case of acid catalysed addition of water to 1
carbon-carbon double bond but it is without any rearrangement.
(0) (c)
It is believed to be due to the formation of cyclic mercurim ion B D C
which do not allow any rearrangement. However, the final
1
product formed corresponds to the most stable intermediate c
2
carbocation.
46. Aniline is c
a+
NH 2
Position vector of E = 2 =a+c
H3C C COOH
2 2 4
H Let AF : FC =  : 1 and BE : EF   : 1
47. Bond strength  thermal stability
 c  a 
49. On adding Mg(OH)2 in test tube A, NH4OH will be formed which    1.0
is weak electorlyte. Thus concentration of OH–1 will decrease λc + a  1  
Position vector of F = and of E =
and value of solubility product will be more than the ionic 1+ λ  1
product. Therefore, a clear solution will be obtained. In test
tube B, NaCl will form NaOH gets highly ionised. Thus a c  
  a c
concentration of OH–1 ions will increase, due to which product 2 4 (1   )(1   ) (1   )(1  )
of ionic concentrations will be more than its solubility product
and it will remain in precipitated state. 1  1 
  and 
2 (1   )(1   ) 4 (1   )(1   )
1 2 0
51. Putting x = 0 in both sides, we get, 0 1 0  p6
1
2 0 1 1 AF AF  1
  ;    2  .
2 AC AF  FC 1   3 3
 p6 = 1 by expansion. 2
p5 is the coefficient of x or constant term in the differentiation 55. The common chord of given circles is
of determinant.
S1 – S2 = 0  2x – 6y – 4 – a = 0
Differentiate both sides,
which passes through the centre of second circle, a = 16
1 2x 2x  1 x 1 x 22
x(x  1) 56. Let the chord get bisected at P(0, ), then other extremely of
the chord is (–a, 2 – b). It must lie on the circle, thus
x(x  1) x 1 x(x 2  2) + 2x  1 1 3x 2  2
a2 + (2 – b)2 = – a2 + b(2 – b)
x2  2 x(x  1) x 1 x 2  2 x(x  1) x 1
 42 – 6b + 2b2 + 2a2 = 0
 MOCK TEST 9 11
This equation should have distinct and real roots Writing the terms in S in the reverse order, we get
 36b > 16(2b + 2a )
2 2 2

 
2n 2
S     1 k
k 2n
 9b2 > 8b2 + 8a2 Ck … (2)
k 0
 b > 8a
2 2
Adding (1) and (2) we get
7 7
 
2n
57. Focus is  ,  and it’s axis is the line y = x. Corresponding 2
2S  2n   1
k 2n
2 2 Ck  2nA
k0

1 2  S  nA
value 'a '  ( 1  1)  . Let the equation of it’s directrix be
4 4
 1 0  1 0   1 0
y + x +  = 0. 62. A 2   
 1 2 1  1 2 1  2 1 2 1
|3 4| 2
  2.  1 0  1 0  1 0
2 4 A3  A 2A      
   
2 1 2 1  1 2 1    1
3 1 2
  = – 6, – 8
Continuning in this way, we get
Thus equation of parabola is
 1 0  1 0
2
(x  y  6)2
2 A100   
  100 1 2 1  50 1
7  7
x  2  y  2 
    2
63. Differentiating both the sides of (1), we get
2 2 2
or  x  7    x  7   (x  y  8) x 1 5 0 x  1 5x 7 x  1 5x 7
 2  2 2
x 2  1 x  1 8  2x 1 0  x2  1 x  1 8
58. Let the foot of normal is (a cos, b sin),
2x 3x 0 2x 3x 0 2 3 0
ax by
then   a2  b2  3ax 2  2bx  c
cos  sin 
and the given lines will be identical. Putting x = 0, we get

mcos  sin  c 1 5 0 1 0 7 1 0 7
Thus,   2
a b (b  a 2 ) c  1 1 8  0 1 0  1 1 8
0 0 0 0 0 0 2 3 0
ac
 cos   ,
m(b2  a2 )  c  0  0  17  17
bc 64. The number of ways of choosing 6 persons out of 12 for a
sin   group is 12C6.
(b2  a2 )
a2 (b2  a2 )2 The number of ways in which this group can contain 3 boys
  b2 
m 2
c 2
and 3 girls is  6
C3  6
C3 . 
  3  1 2 
cos  
    100
.

59. cos  cos
3
 cos
5 7 2 7  3 6
C3 6
C3
 .sin Therefore required probability 
7 7 7  7 12
231
sin C6
7
65. The given expression can be written as
 3   3  6
cos   .sin   sin  3 5    5 
  7   7   7 sin sin sin sin   sin    
  14 14 14  2  14 
sin 2.sin
7 7  3    2
sin     sin      k
 14  14

sin
 7 1  3 5
 2 where k  sin sin sin
2.sin 14 14 14
7
60. f(x) = cos6x + sin6x = (cos2x + sin2x)      3    5 
 cos    cos   cos  
(sin4x + cos4x – cos2x.sin2x)  2 14   2 14   2 14 
= ((sin2 + cos2)2 – 3sin2x.cos2x) 3 2 
 cos cos cos
3 2 7 7 7
= 1 sin 2x
4 1   2 4
  2 sin cos cos cos
 7 7 7 7
 f(x)   , 1
1 2 sin
7
4 
1 4 4
 sin cos
 
2n 2 
  1 k  2n 7 7
k 2n
61. Let S  Ck ...(1) 4 sin
k 0 7
1 8 1
 2n  k   2n C2n k 
2n 2   sin 
S     1
2n  k
  7 8
k 0
8 sin
7
12 MOCK TEST 9
x 71.
66. f3(x) = f2(f1(x)) = e f1(x)  e e Y
A(1, 2)
x
 f3 (x)  e  e , e x

0 1 S(1, 0) X
 f3 (0)  e e ,  e0  
e
67. 8n + 1 is clearly odd. B

Let 8n + 1 = (2 + 1)2,   1 The parabola y2 = 4x, here a = 1 and focus is (1, 0)
 8n = 42 + 4 The focal chord is ASB. This is clearly latus rectum of
parabola, its value = 4
 2n = ( + 1)
2x
Thus 2n is the product of two consecutive integer, hence 2n  a x  bx 
can’t be a perfect square. 72. lim   6
 2 
x 0

(as 2 < ( + 1) < (+ 1)2

68. Let A = –3 + 2i, B = 5 – 4i  a x 1   b x 1 
lim   
x 0    
 x   x 
 z B   e 6
We have, arg  
zA 3
 elog a  log b  6
2 ab = 6
Clearly chord joining A and B will subtend an angle at the
3
center of the arc.  a, b   1, 6  ,  6, 1 ,  2, 3 , 3,2 
AB | 3  2i  5  4i | 64  36  10 4 1
Required probability  
If center be ‘C’ and radius be equal to ‘r’, then 66 9
2
AB2  CA 2  CB2  2CA.CB cos
3  
73. 16 sin5 x  cos5 x  11 sin x  cos x   0

1
 100  r 2  r 2  2r 2 .    sin4 x  sin3 x cos x  sin2 x cos2 x  
2   sin x  cos x  16    11  0
  sin x cos3 x  cos 4 x
100 10    
 r2  r 
3 3

69. Let A  (a t12 ,2a t1),B  (a t 22 ,2 at 2 )

 
  sin x  cos x  16 1  sin2 x cos2 x  sin x cos x  11  0  
Then t1 t2 = –1   sin x  cos x  4 sin x cos x  1 4 sin x cos x  5   0
y
y2 = 4ax As 4sin x cos x  5  0 , we have
A
sin x  cos x  0, 4 sin x cos x  1  0

x The required values are

O
 12, 5  12, 9  12, 13 12, 17  12, 21 12, 
B
They are 6 solutions on 0, 2  .
If P(h, k) is the mid point of AB, then
1 
74. cos1  sin1 x 2  x  1 
2h  a(t12  t 22 ) x2  x  1 2
= a[(t1 + t)2 – 2t1t2] = a[(t1 + t2)2 + 2]
 x2  x  1  1
and, 2k = 2a(t1 + t2)
 k2  75.  z12  z 22  4  z12  z22  4
k
 t1  t 2   2h  a  2  2 
a  a 
  z1  z1    z2  z2 
2 2
Thus locus of ‘P’ is
y2 = 2ax – 2a2 = 2a(x – a). It’s directrix is,  z12  z12  2z1z1  z 22  z22  2z 2 z 2
a a
x–a– x
2 2   
 z12  z22  z12  z22  4  12. 
70. Clearly, the tangents drawn from (0, 0) will be x-axis and
y-axis respectively and the corresponding points of contact
are (1, 0) and (0, 1) respectively.
Thus, equation of required circumcircle is
x(x – 1) + y(y – 1) = 0
 x2 + y2 – x – y = 0
 MOCK TEST – 10
PHYSICS (SECTION – A)
1. A ray of light is incident normally on the first refracting 3. A circuit consists of a battery, resistor R and two
face of the isosceles prism of refracting angle A. The light bulbs A and B as shown:
ray of light comes out at grazing emergence. If one
half of the prism (shaded position) is knocked off, R
the same ray will

90° A B

If the filament in lightbulb A burns out, then the

following is true for light bulb B:
(a) emerge at an angle of emergence (a) it is turned off
1  (b) its brightness does not change
sin–1  sec A / 2 
2  (c) it gets dimmer
(b) not emerge out of the prism (d) it gets brighter
(c) emerge at an angle of emergence 4. The central maximum normally occurs at a spot on
the screen midway between the two slits at room
1 
sin–1  sec A / 4  temperature. On insertion of the transparent plate:
2 
(a) this spot will still be a maxima
(d) None of these
(b) this spot will now become a minima
2. A distribution of charges is held fixed by rigid
insulators as shown in figure. A charge Q at (– a, 0, (c) the spot will be neither a minima nor a maxima
0) and at (a, 0, 0) and a charge – 2Q at (0, 0, 0). (d) this spot may be either a minima or maxima
Which of the following electric fields will cause a net 5. For the arrangement of the potentiometer shown in
torque to be exerted on the system of charges. the figure, the balance point is obtained at a distance
75 cm from A when the key k is open. The second
Z balance point is obtained at 60 cm from A when the
key k is closed. Find the internal resistance (in )
+Q of the battery E1___________.
O
Y
–2Q
+Q E0 = 2V
X
 A B
(a) E  (cons tan t)jˆ
 E1= 1.5V G
(b) E  (E0 x  cons tan t)iˆ
 r
(c) E  (E0 x  cons tan t)kˆ k
6

(d) E  E0 | x | ˆi
2 MOCK TEST 10

6. A block of mass m is at rest with respect to a rough 12. The relation between U, P and V for an ideal gas
incline kept in elevator moving up with acceleration in adiabatic process is given by U = a + bPV.
Find the value of adiabatic exponent    of the
a. Which of following statement is correct?
a gas
b 1 b 1
(a) (b)
b a

(a) The contact force between block & incline is a 1 a
(c) (d)
parallel to the incline. a ab
(b) The contact force between block & incline is of 13. The ratio of energy stored in 5 F capacitor to 4 F
magnitude m(g + a). capacitor in the above circuits is___________
(c) The contact force between block & incline is
perpendicular to the incline. 4 5 F
(d) The contact force is of magnitude mg cos.
7. A particle is constrained to move in a circle with a
2
10-meter radius. At one instant, the particle's speed
is 10 m/s and is increasing at a rate of 10 m/s2. The 4
angle between the particle's velocity and acceleration 4 F
vectors is___________
10V
8. A particle is projected at angle 53° to the horizontal
at speed of 10 m/s. Find its tangetial acceleration at 14. A closed organ pipe & an open organ pipe of same
t = 1.4 sec. length produce 2 beats when they are set into
(a) 5 m/s2 (b) 5 2 m / s2 vibrations simultaneously in their fundamental mode.
The length of open organ pipe is now halved and of
(c) 10 2 m / s2 (d) 10 m/s2 closed organ pipe is doubled, the no. of beats
9. A small particle is placed on top of a fixed hemisphere. produced is___________
15. Ratio of magnetic field at the centre of a current
Particle is projected with a speed v  2gR . What
carrying coil of radius R & at a distance of 3R on its
is the radius of curvature of the path of the particle at axis is
the given instant is nR. Then 'n' is ___________
v = 2gR (a) 20 10 (b) 2 10

(c) 10 (d) 10 10
16. A thin flexible wire of length L is connected to two
fixed points and carries a current I in the clockwise
10. The potential across a 3 F capacitor is 12V when it
direction as shown in the figure. When the system
is not connected to anything. It is then connected in
is put in a uniform magnetic field of strength B going
parallel with an uncharged 6 F capacitor. At
into the plane of the paper, the wire takes the shape
equilibrium, the charge q on the 3 F capacitor and
of a circle. The tension in the wire is
the potential difference V across it are
(a) q = 12C, V = 4V (b) q = 24C, V = 8 V
(c) q = 36C, V = 12 V(d) q = 12C, V = 6V
11. There is a concentric hole of radius R in a solid
sphere of radius 2R. Mass of remaining portion
is M. W hat is the gravitation potential at the
centre ?
IBL IBL
5 GM 5 GM (a) (b)
(a)  (b)  16 
7 R 14 R
IBL IBL
(c) (d)
3 GM 9 GM 2 4
(c)  (d) 
7 R 14

17. A glass prism of refractive index 1.5 is immersed in
water (refractive index is 4/3). A light beam incident
normally on the face AB is totally reflected to reach
the face BC if
B A

MOCK TEST 10 3
20. A small block is shot into each of the four tracks as
shown in the figure below. Each of the tracks rises
to the same height. The speed with which the block
enters the track is the same in all cases. At the
highest point of the track, the normal reaction is
maximum in
(a) (b)

C (c) (d)

8 2 8
(a) sin   (b)  sin   21. On a linear temperature scale Y, water freezes at –
9 3 9 160°Y and boils at – 50°Y. On this Y scale, a tem-
2 perature of 340 K would be read as: (water freezes
(c) sin   (d) None of these
8 at 273 K and boils at 373 K)
18. The variation of induced emf (e) with time (t) in a coil (a) – 86.3°Y (b) – 233.7°Y
if a short bar magnet is moved along its axis with a (c) – 106.3°Y (d) – 73.7°Y
constant velocity is best represented as 22. The gravitational field, due to the 'left over part' of a
uniform sphere (from which a part as shown, has
been 'removed out'), at a very far off point, P, located
as shown, would be (nearly):
e e
Mass of compete
Removed sphere = M
Part
P
(a) (b) R R
x
e e
8 GM 6 GM
(a) (b)
9 x2 7 x2
(c) (d) 5 GM 7 GM
(c) 2 (d)
6 x 8 x2
23. Photons of an electromagnetic radiation has an
19. A uniform ring of mass m is lying at a distance energy 11 keV each. To which region of
3a from centre of a sphere of mass M just over the electromagnetic spectrum does it belong?
sphere where a is the radius of ring as well as that of (a) Ultra violet region (b) Infrared region
sphere. Then, gravitational force exerted is (c) visible region (d) X-ray region
24. A uniform sphere of weight W and radius 5 cm is
being held by a string as shown in the figure. The
tension in the string will be:
3a
8 cm

GMm GMm
(a) (b) W W
8a 2
3a2 (a) 13 (b) 12
5 5
3GMm 3GMm W W
(c) (d) 2 (c) 13 (d) 5
2 8a
a 12 12
4 MOCK TEST 10

25. This question has Statement-1 and Statement-2. 29. Arrange the following ions in order of decreasing
of the four choices given after the Statements, X – O bond length where X is the central atom
choose the one that best describes the two
(a) ClO4 , SO24 ,PO34 , SiO44
Statements.
Statement-1 :A capillary is dipped in a liquid and (b) SiO44  , PO34 ,ClO4 , SO24
liquid rises to a height h in it. As the temperature of
the liquid is raised, the height h increases (if the (c) SiO44  , SO24 ,PO34 , ClO4
density of the liquid and the angle of contact remain
(d) SiO44  , PO34 ,SO24 , ClO4
the same)
30. On the basis of the information available for the
Statement-2 :Surface tension of a liquid decreases
reaction:
with the rise in its temperature.
4 2
(a) Statement 1 is false and Statement 2 is true. Al  O2  Al2O3 , G  827KJ mol1 the
3 3
(b) Statement 1 and Statement 2 both are true, minimum magnitude of e.m.f. required to carry
Statement 2 is not the correct explanation of out electrolysis of Al2O3 is (F = 96500 C mol–1)
Statement 1. (a) 8.56 V (b) – 4.28 V
(c) Statement 1 and Statement 2 both are true, (c) – 2.14 V (d) 6.42 V
Statement 2 is the correct explanation of
31. A substance C 4H10O yields on oxidation a com-
Statement 1.
pound C4H8O which gives an oxime and a positive
(d) Statement 1 is true and Statement 2 is false. iodoform test. The original substance on treatment
with conc. H2SO 4 gives C4H8. The structure of the
CHEMISTRY (SECTION – B) compound is
26. The reaction X  Product follows first order
(a) CH3CH2CH2CH2OH
Kinetics. In 40 minutes, the concentration of X
changes from 0.1 M to 0.025 M. Then the rate of (b) CH3CH(OH)CH2CH3
reaction when concentration of X is 0.01 M (c) (CH3)3COH
(a) 1.73 × 10–4 M min–1 (d) CH3CH2 – O – CH2CH3
(b) 3.47 × 10–5 M min–1 32. The most reactive compound towards formation
(c) 3.47 × 10 M min
–4 –1 of cyanohydrin on treatment with KCN followed
by acidification is
(d) 1.73 × 10–5 M min–1
(a) Benzaldehyde
27. Equal volum es of the f ollowing Ca 2+ and
F– solutions are mixed. In which of the following (b) P-Nitrobenzaldehyde
will precipitation occur? (c) Phenyl acetaldehyde
[Given KSP of CaF2 = 1.7 × 10 –10
] (d) p-Hydroxybenzaldehyde
(A) 10 MCa + 10 MF
–2 2+ –5 – 33. If N and S elements are present in organic
(B) 10 MCa + 10 MF
–3 2+ –4 – compound, then during Lassaigne's test both
change into
(C) 10–4 MCa2+ + 10–2 MF–
(a) Na2S and NaCN
(D) 10–2 MCa2+ + 10–3 M F–
(b) NaSCN
Select the correct answer:
(c) Na2SO3 and Na2CO3
(a) In (D) only
(d) Na2S and NaCNO
(b) In A and B
34. A compound A has a molecular formula C 7H7NO.
(c) In (C) and (D) On treatment with Br2 and KOH, A gives an amine
(d) In (B), (C) and (D) B whic h gives c ar bylam ine tes t. B upon
28. The heat liberated when 1.89 g of benzoic acid is diazotisation and coupling with phenol gives as
burnt in a bomb calorimeter at 25°C increases the azodye. A can be
temperature of 18.94 kg of water by 0.632°C. If (a) C6H5CONHCH3
the specific heat of water at 25°C is 0.998 cal/g
(b) C6H5CONH2
deg., the value of the heat of combustion of ben-
zoic acid is___________(kcal/mole) (c) C6H5NO
(d) o, m- or p-C6H4(NH2)CHO
 MOCK TEST 10 5
35. Dye test can be used to distinguish between (c) Significant p – p interaction between B and F
(a) Ethylamine and acetamide in BF3 whereas there is no possibility of such
(b) Ethylamine and aniline interaction between C and F in CF4
(c) Urea and acetamide (d) Lower degree of p – p interaction between B
(d) Methylamine and ethylamine and F in BF3 than that between C and F in CF4.
36. Among the following, which exhibits aromaticity? 43. The decreasing order of C–N bond length in the
(a) Cyclopentadienyl cation following compounds:
(b) Cyclopentadienyl radical OMe
MeO OMe
(c) Cycloheptatrienyl radical
(d) Cycloheptatrienyl cation
MeO OMe
37. The solubility product of A2X3 is 1.08 × 10–23. Its
NO2 NO2 NO2 NO2
solubility will be
(a) 1 × 10–3 (b) 1 × 10–6 (a) (IV) > (III) > (II) > (I)(b) (IV) > (II) > (III) > (I)
(c) (III) > (II) > (I) > (IV)(d) (III) > (I) > (II) > (IV)
(c) 1 × 10–4 (d) 1 × 10–5
44. How many unit cells are present in a cube shaped
x ideal crystal of NaCl of mass 1.0g?
38. Graph between log and log P is a straight line
m (a) 1.28 × 1021 (b) 1.71 × 1021
inclined at an angle q = 45°. When pressure of 0.5 (c) 5.14 × 1021 (d) 2.57 × 1021
atm and log k = 0.699, the amount of solute adsorbed
45. A gaseous mixture of three gases A, B and C has a
per gram of adsorbent will be___________
pressure of 10 atm. The total number of moles of all
(log k = intercept)
the gases is 10. If the partial pressures of A and B
39. Phenol is heated with chloroform and alcoholic KOH are 3.0 and 1.0 atm respectively and if C has a
when salicyladehyde is produced. This reaction is mol/wt. of 2.0. What is the weight of C in g present
known as in the mixture___________
(a) Fridel-Crafts reaction
(b) Reimer-Tiemann reaction 46. The C.FS.E of Co NH3 6  Cl3 is
(c) Rosenmund reaction (a) 7.2 0 (b) 0.4 0
(d) Sommelet reaction
40. A compound 'X' having molecular formula, (c) 2.4 0 (d) 3.6 0
C4H10O gave on oxidation a ketone (C 4H8O). 47. In the extraction of copper, metal is formed in the
Which of the following is the structure of 'X'? Bessemer converter due to reaction.
(a) CH3   CH2 3  OH (a) Cu2S + 2Cu2O  6Cu + SO2
(b) Cu2S  2Cu + S
(b)  CH3  2 CHCH2  OH
(c) Fe + Cu2O  2Cu + FeO
(c) CH3  CH  OH CH2  CH3 (d) 2Cu2O  4Cu + O2
(d)  CH3 3 C  OH 48. Which of the following curve represents the Henry's
law ?
41. 60g CH3COOH and 46g C2H5OH react in 5L flask to
form 44g CH3COOC2H5 at equilibrium. On taking 120g
CH3COOH and 46g C2H5OH, CH3COOC2H5 formed
log P log P
at equilibrium is___________(g)
(a) (b)
42. The bond dissociation energy of B–F in BF3 is 646
kJ mol–1 where as that of C–F in CF4 is 515 kJ log x log x
mol–1. The correct reason for higher B–F bond
dissociation energy as compared to that of C–F is
log P log P
(a) Smaller size of B–atom as compared to that of C
atom (c) (d)
(b) Stronger the bond between B and F in BF3 as log x log x
compared to C – F in CF4
6 MOCK TEST 10

49. When two half-cells of electrode potential of E1 and n

(c) (n  1) when n is even
E2 are combined to form a cell of electrode E3, then 2
(where n1, n2 and n3 are number of electrons n(n  1)
exchanged in first, second and combined half cells): (d)  when n is odd
2
E1n1  E2n2 55. f : N  N where f(x) = x – (–1)x, then f is
(a) E3 = E2 – E1 (b) E3 
n3 (a) One one and into
E n E n (b) Many one and into
(c) E3  1 1 2 2 2 (d) E3 = E1 + E2
n3 (c) One one and onto
50. For a first order homogeneous gaseous reaction A (d) Many one and onto
 2B + C then initial pressure was Pi while total
pressure after time t was Pt. Then expression for 56. Range of f(x) = [|sinx| + |cosx|], where [.] denotes
rate constants K in terms Pi, Pt and t is. the greatest integer function, is
(a) {0} (b) {0, 1}
2.303  2Pi 
(a) K  log   (c) {1} (d) None of these
t  3Pi  Pt  57. Which of the following functions is non-periodic, here
2.303  2Pi 
(b) K  log   [.] and {.} denotes the greatest integer function and
t  2Pt  Pi  fractional part respectively?
2.303  Pi  2x
(c) K  log   (a) (b) sin–1({x})
t  Pi  Pt  2[x]
(d) None of these 1
(c) sin1( cos x )
2
(d) sin (cos(x ))
MATHEMATICS (SECTION – C)
  x2 
51. The focus of the parabola 4y2 – 6x – 4y = 5 is 58. Domain of f(x)  sin1 log2    , where [.]
  2 
 8   5 1   
(a)  , 2  (b)  ,  denotes the greatest integer functions, is
 5   8 2
1 5  6 1  (a)   8, 8  (b) [ 8,  1)  (1, 8]
(c)  ,  (d)  , 
2 8 8 2  (c) [–1, –1] (d) (  8,  1]  [1, 8)
52. The locus of the middle point of the intercept of the
tangents drawn from an external point to the ellipse 59. lim (x  1){x} , where {.} denotes the fractional part,
x 1
x2 + 2y2 = 2 between the coordinate axes, is is equal to
1 1 1 1 (a) 1 (b) 0
(a)  1 (b)  1
x2 2y 2 4x 2 2y 2 (c) doesn't exist (d) None of these
1 1 1 1
(c)  1 (d)  1  x2  x
2x 2 4y 2 2x 2 y 2 , x  0 is differentiable at x = 0,
60. If f(x)  e
53. Let an = product of first n natural numbers. Then for ax  b, x  0
all n  N
n
then
 n  1
  an
n (a) a = 1, b = – 1 (b) a = – 1, b = 1
(a) n  an (b) 
 2 
(c) a = 1, b = 1 (d) a = –1, b = –1
(c) nn  an1 (d) None of these 61. If the product of the perpendicular drawn from the
1 x n 1 point (1, 1) on the lines ax2 + 2hxy + by2 = 0 is 1,
54. Let f(x)  and then
1 x
2 3 n 1 (a) h(a – b) + ab = 0 (b) h(a + b) – ab = 0
g(x)  1    ....  ( 1)n .
x x2 xn (c) h(a + b) + ab = 0 (d) h(a – b) – ab = 0
Then the constant term in f(x) × g(x) is equal to 62. The locus of the points of intersection of the tangents
2
n(n  1) at the extremities of the chords of the ellipse
(a) when n is even x2+ 2y2 = 6 which touch the ellipse x2 + 4y2 = 4 is
6
n(n  1) (a) x2 + y2 = 4 (b) x2 + y2 = 6
(b) when n is odd (c) x2 + y2 = 9 (d) none of these
2
 MOCK TEST 10 7

63. Let P  a sec , b tan  and Q  a sec , b tan  where

68. If S(n) denotes the sum of first 'n' term of certain A.P.
with common difference equal to 5, then
 S(3n)
  , be two points on the hyperbola is always equal to___________
2 S(2n)  S(n)
x2 y2
  1 . If (h, k) is the point of intersection of n
a2 b2 69.  r(n Cr  n Cr 1) is equal to
normals at P and Q, then k is equal to r 1

 a2  b 2  (a) 2n + n + 1 (b) 2n – n + 1
a2  b2
(a) (b)    (c) n – 2n + 1 (d) n – 2n – 1
a  a  

70. Let a  ˆi  ˆj, b  2iˆ – k.
ˆ Then the position vector of
a2  b2  a2  b 2 
(c) 
(d)  b     
b   the point of intersection of the lines r  a  b  a
   
64. If  is the angle between the line and r  b  a  b is


r  2iˆ  3ˆj  kˆ  ˆi  ˆj  kˆ t and the plane (a) 3iˆ  ˆj  kˆ (b) 3iˆ  ˆj  kˆ

 
r· 3iˆ  4 ˆj  5kˆ  q , then (c) 3iˆ  ˆj  kˆ (d) None of these

71. How many tangents to the circle x 2  y 2  3 are

2 6 2 6
(a) cos   (b) sin   there which are normal to the ellipse
15 15
x2 y 2
  1___________
11 7 11 7 9 4
(c) cos    (d) sin   
70 70
72. The length of the transverse axis of the hyperbola
65. Equation of the line of shortest distance between
9x 2  16y 2  18x  32y  151  0 is___________
x y z x  2 y 1 z  2
the lines   and   is 73. The mean of 10 observations is 16.3 by an error one
2 3 1 3 5 2 observation is registered as 32 instead of 23. Then
the correct mean is
(a) 3  x  21  3y  92  3z  32
(a) 15.6 (b) 15.4
x   62 3 y  31 z   31 3 (c) 15.7 (d) 15.8
(b)  
13 13 13 74. AB is a vertical pole with B at the ground level and A
at the top. A man finds that the angle of elevation of
the point A from a certain point C on the ground is
x  21 y   93 3 z   32 3
(c)   60°. He moves away from the pole along the line BC
13 13 13 to a point D such that CD = 7 m. From D the angle
of elevation of the point A is 45°. Then the height of
x  2 y  3 z 1 the pole is
(d) 1 3  1 3  1 3

66. If n  N > 1, then sum of real part of roots of zn = (z (a)

7 3
2
 3 1 m  (b)
7 3
2
 3 1 m 
+ 1)n is equal to

n (n  1) 7 3 1 7 3 1
(a) (b) (c) m (d) m
2 2 2 3 1 2 3 1

n (1  n) 75. If a, b, c are positive number such that

(c)  (d)
2 2 alog3 7  27, blog7 11  49, c log11 25  11 , then sum
67. Total number of positive integral solutions of x1 + x2
2 2 2
of digits of S  a
log3 7 
 b
log7 11
 c
log11 25 
+ x3 = 24 and x12  x 22  x 32 is equal to___________
is___________
8 MOCK TEST 10

ANSWERS
1. (a) 2. (c) 3. (d) 4. (d) 5. (1.5) 6. (b) 7. (45°) 8. (b) 9. (2R) 10. (a)
11. (d) 12. (a) 13. (1.25) 14. (7) 15. (d) 16. (b) 17. (b) 18. (b) 19. (d) 20. (b)
21. (a) 22. (d) 23. (d) 24. (c) 25. (a) 26. (c) 27. (c) 28. (771.4 kcal.mole) 29. (d)
30. (c) 31. (b) 32. (b) 33. (b) 34. (b) 35. (b) 36. (d) 37. (d)
38. (2.5 g/g adsorbent) 39. (b) 40. (c) 41. (58.66g) 42. (c) 43. (a) 44. (d) 45. (12) 46. (c)
47. (a) 48. (a) 49. (b) 50. (a) 51. (b) 52. (c) 53. (b) 54. (b) 55. (c) 56. (c)
57. (d) 58. (d) 59. (b) 60. (c) 61. (c) 62. (c) 63. (d) 64. (b) 65. (a) 66. (d)
67. (2) 68. (3) 69. (c) 70. (a) 71. (0) 72. (8) 73. (b) 74. (a) 75. (19)

EXPLANATIONS
10
1. Angle of incidence becomes A . 13. i   1A
10
2
   . V5  6V V4  6V
2.   PE
1
3. Voltage across B increases. E5 2  5  36
   1.25
4. May be a maxima or a minima. E4 1
 4  36
2
5. E  75  R  E  60 . v v
100 R  r 100 14. f0  fC 
2l 4l
6. contact force = friction + normal reaction
   v
7. atotal  ac  at f0  fC   2 beats
4l
2 v v
8. at  Now f '0  f 'C 
R l 8l
9. The particle loses contact. 7v
2
f '0  f 'C   7 beats
V 8l
g
R  0i
15. Bc 
C V  C2 V2 2R
10. V 1 1
C1  C2
 0iR2
B
M 3M
 
32
11. P   2 R 2  9R2
4
3 
  2R  R 3
3

28 R3
BC
 10  10 10
32

4  8 B
M1  P    2R   M
3
3  7 16. Consider a small arc as below
Vrem  Vwhole  Vhole Fm
3 GM1 3 GM2
 
2 2 2 R d d
3G  1 8M M  9GM
    
2R  2 7 7 14R T
12. U = a b PV = a + b nRT
dU = bnRdT
but dU = nCVdT
CV = bR
d d
CP = CV + R = (b + 1)R
CP b  1
Y 
CV b
 MOCK TEST 10 9
Clearly, net force 2Tsin(d) will be by magnetic
mv 20
force on the wire hence, Nmax   mg
Rminm
2Tsin(d) = Fm = l dLB sin90°
R is minimum for first case hence (b) is correct.
2T(d)  l dLB

ldLB L
T  lB  lBR  lB  ( L  2R) Y   160  50   160 
2d 2 21. 
X  273 373   273 
lBL
T
2 11
 Y  160   X  273 
17. Consider the diagram below 10
For X = 340, Y = – 86.3°Y
A B M
G 
 GM  8   GM  1  1   7 GM
22. Ig  2   x 2 8x 2  8 x 2
x R   
i   x
2 
i=


23. conceptual
24. T cos   mg .... for vertical equilibrium &

12 .... from the figure

cos  
13
C

Clearly, the angle of incident the face BC will also be Hence, T  13 mg or 13W
12 12
 as shown in above diagram.
18. When the bar magnet is entering and leaving the 2Scos 
25. h , which decreases with increase in
coil, the polarity of emf should be opposite in two rg
cases. Only in option (b) polarity is different. temperature as surface tension-S decreases,
19. For all point out the sphere we can treat it as point density (  ) and angle of contact (  )remain
mass at its centre so, effectively it will be the force constant.
between ring and point mass.
26. K  2.303 log 0.1  2.303  0.6021
Gravitation field at x  3a on axis of ring is 40 0.025 40

Gmx Gm( 3a) 2.303  0.6021  10 2

E  Now Rate = K[X] 
(R2  x 2 )3 / 2 [a2  3a2 ]3 / 2 40
3Gm = 3.47 × 10–4 M min–1

8a2
27. In case of (C) and (D)
3GMm
F  ME   [C]  Ionic product of CaF2 = (0.5 × 10–4) (0.5 ×
8a2
10–2)2= 1.25 × 10–9
 20. As the block rises to same height in all cases, hence
speed of the highest point will be same at all points so Ki > KSP
according to conservation of energy. [D]  Ionic product of CaF2 = (0.5 × 10–2) (0.5 ×
We can write 10–3)2= 1.25 × 10–9
so again Ki > KSP
v
28. Q = mcT = 18940g × 0.998 × 0.632 = 11946.14
0

calorie
Now, 1.89g of acid liberates heat = 11946.14 calories
mg
so heat liberated by 122g of acid (1 mol)
N
11946.14  122
 = 771126.5 calorie = 771.12 kcalorie
mv 02 1.89
N  mg 
R 29. Greater the bond order, shorter is bond length. Bond
order of
mv 02
N  mg ClO 4  1.75, SO24  1.5, PO34  1.25, SiO 44   1
R
10 MOCK TEST 10
30. For the reverse reaction OH O
[O]
2 4 40. CH3 – CH – CH2 – CH3 CH3 – C – CH2 – CH3
Al O  Al  O2, (G = 872 × 103 J mol–1)
3 2 3 3
41. Molar mass of CH3COOH = 60g mol–1
4 3 4
Al  4e  Al so n = 4 Molar mass of C2H5OH = 46g mol–1
3 3
1
Molar mass of CH3COOC2H5 = 88g mol–1
Now, E   G  827000 J mol 1  2.14 V 0
nF 4  96500 C mol  [CH3COOH]Initial   0.2 mol L–1
60  5
conc.H SO
31. CH3CH(OH)CH2CH3 
2 4  CH CH  CHCH
3 3 46
(C4H10 O) (C4H8 ) [C2H5OH]Initial   0.2 mol L–1
46  5
[O]
CH3CHOHCH2CH3 
 CH3COCH2CH3 44 1
2 Bu tanol Bu tanone [CH3COOC2H5 ]eqm    0.1 mol L–1
88 5
Butanone gives both an oxime and positive iodoform
test, therefore, the original compound is 2-butanol. CH3COOH + C2H5OH   CH3COOC2H5 + H2O
32. Due to electron withdrawing nature of NO2 group, the Initial
partial +ve charge on the carbon atom of the > C = O
0.2 M 0.2 M
group in p-nitrobenzaldehyde increases and hence
becomes more susceptible to nucleophilic attack by At eqm.
CN– ion. (0.2 – 0.1)M (0.2 – 0.1) M 0.1 M 0.1 M
O [CH3COOC2H5 ][H2O] 0.1 0.1
K   1
Br2 + KOH [CH3COOH][C2H5OH] 0.1 0.1
C NH2 NH2
34. In second case,
[CH3COOH]initial = 0.4 M
Benzamide [C2H5OH]initial = 0.2 M
(A) (B)
If x is the amount of acid and alcohol reacted
NaNO2/HCl
N2Cl– Phenol [CH3COOH]eqm. = (0.4 – x] M
+

ice cold
[C2H5OH]eqm.= [0.2 – x] M
[CH3COOC2H5]eqm. = [H2O]eqm. = x M
N=N OH
(Azodye) x2
 K 1
35. Aniline (aromatic amine) give dye test whereas (0.4 – x)(0.2 – x)
ethylamine (aliphatic amine) does not.  x2 = (0.4 – x)(0.2 – x)
x2 = 0.08 + x2 – 0.6x
36. cyclopeptatrienyl cation 0.6x = 0.08
8
( ) x M
60
 4x  2 e  (where x = 1) 8 2
 Moles of ethyl acetate produced  5 
37. A2X3 is 2 : 3 type electrolyte 60 3

1.08  10 23 
5
K sp  108 S 108S
5
2
Mass of ethyl acetate produced   88  58.66g.
3
S5  10 25 S = 1 × 10–5
42. In BF3 there is considerable p – p interaction
x 1
38. KP n between unfilled p-orbital (having no electron) over
m
boron and the lone pair of electrons over fluorine in
x 1
log  log P  log K 2p orbital
m n
1 F F + F+
slope   tan   tan45 B F B F B F
x F F F
x
log  log0.5  0.699
m F
B F
x +F
 log0.5  log5 log  log2.5
m 43. Decreasing order of C–N bond length will be (IV) (Due
x to steric inhibition of resonance) > (III) (Due to cross
 2.5
m conjugation) > (II) > (I) (Due to extended conjugation)
 MOCK TEST 10 11

44. Mass of one unit cell = a3 × d Point of contact be R  ( 2 cos ,sin )

MZ MZ 58.5  4
= a3 ×   grams
Noa3 No 6.02  1023 Equation of tangent AB is x cos   y sin   1
2
23
Number of unit cells in 1gm  6.02  10  2.57  1021
58.5  4  A  ( 2 sec ,0); B  (0,coses)
45. Total pressure of mixture of gases A, B and C Let the middle point Q of AB be (h, k).
= 10 atm.
 h  sec  ,k  cosec  cos  
1 1
,sin  
Number of total moles = 10 2 2 h 2 2k

Partial pressure of A 
Number of moles of A
 10  12  12  1
10 2h 4k
 3 = Number of moles of A. 53. We have an  1.2.3.............n  n! , nn  n.n.n........ to n
Number of moles of B times
 Partial pressure of B   10
10
 nn  n.(n  1)(n  2)....{n  (n  1)}
= Number of moles of B.
 nn  n.(n  1)(n  2).........2.1
 Number of moles of C = 10 – (3 + 1) = 6.
Now 1 mole of C = 2g  nn  n!  nn  an . So (a) is false nn  (n  1)!
 6 mol of C = 2 × 6 = 12 g.
 nn  an  1 . So (c) is false
46. Due to strong ligand t 62geg0
1  2  3  .....  n
47. Self reduction  (1.2.3......n)1/ n
n
Cu2S + 2Cu2O  6Cu + SO2
 n(n  1)  (n!)1/ n  n  1  (n!)1/ n .
48. P = KH x 2n 2
log P = logKH + log X n
  n  1   n! . So (b) is true.
49. Electraode potential is intensive property while gibb’s  2 
free energy is extensive. 54. f(x)  1  x  x 2  .......  xn
50. A  2B  C
Pi 0 0 Pressure at t = 0 f (x)  1  2x  3x 2  ......  n xn 1
Pi  P 2P P Pressure at any t f (x).g(x)  (1  2x  3x2  ....  n xn 1 ) 
Pt  Pi
 Pt  Pi  2P or P   2 3 n n  1
2  1  x  2  ......  ( 1) 
 x xn 
2.303  Pi 
K  log   constant term in f (x)  g(x) is
t  Pi  P 
  c  12  22  32  42  .......  n2 ( 1)n 1
2.303  Pi  When n is odd,
 log    2.303 log  2Pi 
t  P  t  Pi
P  t  3P  P 
 i t 
 i  2
c  [12  22  .....  n2 ]  2[22  42  6 2  ......  (n  1) ]
 2 
2
 n(n  1)(2n  1)  n  1 
51.  y  1   3 (x  1)   Y 2  3 X 
2
=   2.22 [12  22  32  ......    
 2  2 2    2  

6

where, 1
Y  y  ,X  x  1 n(n  1) n(n  1)
2  (2n  1  2(n  1)) 
6 2
1 1
Focus (X = a, Y = 0);  x  3  1   5 ; y  0   x  1, x  even
8 8 2 2 55. f(x)  
x  1, x  odd
  5 1
 Focus =   , 
8 2   which is clearly one one and onto.
52. Y 56. y  | sin x |  | cos x |
B  y 2  1 | sin 2x |
Q(h, k)
R  1  y2  2
X X
O A  y  [1, 2]
P
 f(x)  1  x  R
Y
12 MOCK TEST 10
Equation of a tangent to the ellipse (i) is
2x
57. Period of is 1.
2[x] x
cos   y sin   1
2
… (ii)
Period of sin {x} is 1. –1

Period of sin1( cos x ) is 2, whereas sin–1(cosx2) is Equation of the ellipse x2  2y2  6 can be written as
non-periodic. x2 y2
 1 … (iii)
  x2  6 3
58. We must have 1  log2     1
 2 
   Suppose (ii) meets the ellipse (iii) at P and Q and
the tangents at P and Q to the ellipse (iii) intersect
 x2 
 1  log2    2 at (h, k), then (ii) is the chord of contact of (h, k)
 2 
  with respect to the ellipse (iii) and thus its equation
1  x2  is
  4
2  2 
hx ky
 1  x2 < 8  1 … (iv)
6 3
 x  ( 8,  1]  [1, 8) Since (ii) and (iv) represent the same line
59. lim(x  1){x}  0 as lim(x  1)  0 h6 k3
x 1 x 1  1
 cos  2 sin 
and lim {x}  0, lim {x}  0.
x 1 x 1  h  3 cos , k  3 sin 
f(h)  f(0) and the locus of (h, k) is x2 + y2 = 9
60. f (0  0)  hlim
0 h 63. Equations of the normal at P is
2 h
 lim
h 0
eh
h
b 
ax  by  cosec  a2  b2 sec   … (i)

(eh
2 h
 1  (1  b))(h2  h)
and the equation of the normal at Q  a sec , b sec  is
 lim ,
h0 h(h2  h)

ax  by cosec  a2  b2 sec   … (ii)
= 1, provided b = 1
Subtracting (ii) from (i) we get
ah  b  b
f(0 – 0)  lim h
a
h0 a2  b 2 sec   sec 
y 
Thus for f(x) to be differentiable, at x = 0, b cosec  cosec

a = b = 1.
a2  b2 sec   sec   2  
61. Let the lines represented by the given equation be y So that k  y 
b cosec  cosec   2   
= m1 x and y = m2 x then m1 + m 2 = –2h/b, m1m2
= a/b       2
The product of the perpendicular from (1, 1) to these
a 2  b2 sec   cosec  a 2  b2 
lines is    
b cosec   sec   b 
1  m1 1  m2
 1 (given)
1  m12 1  m2 64. The line is parallel to the vector ˆi  ˆj  kˆ and the normal
to the plane is 3iˆ  4ˆj  5kˆ , so that the angle between
 1   m1  m2   m1m2   1  m1  m 2  m1 m2
2 2 2 2 2
  these vectors is  2 .

 ˆi  ˆj  kˆ · 3iˆ  4ˆj  5kˆ 

2
 b  2h  a  4h2 a a2
    1 2  2 b  2
 b  b b cos   2    
1  1  1 3 2  42  5 2
  a  b  2h   a  b  4h2
2 2

345 2 6
 sin   
  a  b2  4h  a  b   a  b2  0 3 50 15

 4ab  4h  a  b  0 65. Let P  2r1,  3r1, r1 and Q  3r2  2,  5r2  1, 2r2  2 be the
 h  a  b  ab  0 points on the given lines so that PQ is the line of
shortest distance between the given lines. Now
62. We can write x2  4y2  4 as direction ratios of PQ are
x2 y2 2r1  3r2  2,  3r1  5r2  1, r1  2r2  2
 1 … (i)
4 1
Since it is perpendicular to the given lines
 MOCK TEST 10 13

2  2r1  3r2  2   3  3r1  5r2  1   r1  2r2  2   0 n 1

 n.2n 1   k. nCk  (2n  1)
and 3  2r1  3r2  2  3  3r1  5r2  1  2  r`  2r2  2  0 k 0

= n.2n–1 – (n.2n–1 – n.nCn) – (2n – 1)

 14r1  23r2  1  0, 23r1  38r2  0
= n – 2n + 1
 r1  31 3, r2  19 3    
70. r a  ba
 P is (62/3, –31, 31/3) and Q(21, –92/3, 32/3)    
 (r  b)  a  0
and direction ratios of PQ are 1/3, 1/3, 1/3.   
Hence, equations of PQ as it passes through Q are  r  b  1a  2iˆ  kˆ  1(iˆ  ˆj)
     
x  21 y  92 3 z  32 3 r  b  a  b  r  a   2b  (iˆ  ˆj)   2 (2iˆ  k)
ˆ
 
13 13 13 At the point of intersection;
 3  x  21  3y  92  3z  32 2iˆ  kˆ  1(iˆ  ˆj)  (iˆ  ˆj)  2 (2iˆ  k)
ˆ
66. zn= (z + 1)n, this equation will have exactly (n – 1)
 2  1  1  22, 1  1, 2  1
roots.
n
 1  1, 2  1
 z  1 z 1
We have,  z  1  1  |z + 1| = |z| Thus P.V. of point of intersection is
  z

 ‘z’ lies on the right bisector of the segment r  (2iˆ  k)
ˆ  (iˆ  ˆj)  3iˆ  ˆj  kˆ

connecting the points (0, 0) and (–1, 0)

71. Equation of normal at p  3 cos , 2 sin   is
1
Thus, Re(z) =  . Hence roots are collinear and will 3x sec   2y cosec  5
2

1 5
their real part equal to  .  3
2 9 sec 2   4 cosec 2
1
Hence sum of real parts of roots   (n  1). But Min. of 9sec 2   4 cosec 2  25
2

67. x12  x 22  x 32 and x1 + x2 + x3 = 24  no such  1 exists.

These given informations give us the idea that x1, x2  x  1  y  1

2 2

and x3 can be treated as the sides of a right angled 72. Given hyperbola is  1
16 9
triangle whose hypotenuse is x3 and perimeter is
24. The obvious solution is x1 = 8, x2 = 6, x3 = 10 or Length of the transverse axis is 2a = 8
x1 = 6, x2 = 8, x3 = 10. 74. a x  hcot 60  h 3
Thus there are two sets of positive integral solutions.
68. Let the first term be ‘a’. Then x  7  hcot 45  h  h  h 3 7

3n 7 3
S(3n)  (2a  (3n  1)5)  h
2 3 1
A
2n
S(2n)  (2a  (2n  1)5)
2

n
S(n)  (2a  (n  1)5) h
2

n
 S(2n)  S(n)  (2a  5(4n  2  n  1)) 45° 60°
2
D 7 C x B
n
 (2a  (3n  1)5) 
S(3n) S(3n) 75. The given expression can be written as
 3
2 3 S(2n)  S(n)
log3 7
S  (alog3 7 )  (blog7 11)log7 11  (c log11 25 )log11 25
n n n
69.  r.(n Cr  n Cr 1)   r. nCr   (r  1  1) nCr 1
 11
log11 25
r 1 r 1 r 1
 27log3 7  49log7 11  = 73 + 11
12 + 5 = 469
n n n
=  r. Cr  (r  1) Cr 1   Cr 1  Sum of digits = 19.
n n n

r 1 r 1 r 1
 MOCK TEST – 11
(c) The electron beams do not produce magnetic
PHYSICS (SECTION – A) fields on each other
1. Somewhere in a circuir is a resistor. A constant (d) The magnetic forces caused by the electron
current is flowing in the direction as indicated in the beams on each other are weaker than the
B   electrostatic forces between them
figure. In going from A to B, we measure  E.d l . 5. The mobile side of the triangular conducting frame
A
What do we find? made of uniform wire as shown in the figure is slid
symmetrically at a uniform speed of v = 0.1 m/s along
the two other sides. The horizontal frame is in a
A B
vertical homogeneous magnetic field with an induction
(a) a positive value of B = 0.4T. At a certain instant, the length of each
(b) a negative value side is l = 1 m and combined resistance of all three
(c) zero sides is 1.
(d) we do not have enough information to answer
2. Two straight wires are perpendicular to the plane of
this page.
One, located at point M, carries a positive current
B
into the page.
v
One, located at point N, carries a positive current
out of the page.
The vector that best represents the resultant magnetic
field at point P is____________
2
How much is the electromotive force induced in the
P circuit at the moment shown?
1 3
(a) 0.04 V (b) 0.12 V (c) 0.06 V(d) None of these
4 6. In a Young's double-slit experiment, if the slits are of
X unequal width,
M N (a) fringes will not be formed
3. In a coaxial cable, a thin straight conductor is fixed (b) the positions of minimum intensity will not be
along the axis of an outer hollow conductor. The two completely dark
carry equal currents flowing in opposite directions.
(c) bright fringe will not be formed at the centre of the
Let X denote the region between the two conductors,
screen
and Y denote the region outside the outer conductor.
The magnetic field is zero in (d) distance between two consecutive bright fringes
will not be equal to the distance between two
(a) Y but not in X (b) X but not in Y
consecutive dark fringes
(c) both X and Y (d) Neither X nor Y
7. A small sphere A of mass m and radius r rolls without
4. Two parallel conductors carrying current in the same slipping inside a large fixed hemispherical bowl of
direction attract each other, while two parallel beams radius R(>>r) as shown in figure. If the sphere starts
of electrons moving in the same direction repel each from rest at the top point of the hemisphere find the
other. Which of the following statements cannot be normal force exerted by the small sphere on the
the reason for this? hemisphere when it is at the bottom B of the
(a) The conductors are electrically neutral hemisphere.
(b) The conductors produce magnetic fields on each
other
2 MOCK TEST 11
A 13. The pressure at the bottom of an open tank of
water is 3P where P is the atmospheric pressure.
R If water is drawn out till the level of water remains
one fifth, the pressure at the bottom will be
B
13
10 17 (a) 2P (b) P
(a) mg (b) mg 5
7 7
4 7
5 7 (c) P (d) P
(c) mg (d) mg 5 5
7 5
8. A glass (R.I. = 1.5) slab having thickness 6 cm is 14. A radioactive element X converts into a stable
placed infront of a concave mirror of focal length element Y. Half-life of X is 2 hours. Initially only X is
20 cm as shown a point object O is placed on the present. After time t, the ratio of atoms of X and Y is
axis of mirror at a distance of 27 cm from the pole.
found to be 1 : 4, then t is
(a) 2 hours
(b) 4 hours
O P
(c) between 4 & 6 hours
(d) 6 hours
Find the distance (in cm) of final image from
P____________ 15. Two trains move towards each other with same speed.
Speed of sound is 340 m/s. If the frequency of tone
9. A particle performs uniform circular motion with an
angular momentum L. If the frequency of particle's 9
motion is doubled and its kinetic energy is halved, of whistle of one heard by other changes by times
8
the angular momentum becomes
as they cross each other, then the speed of each
(a) 2L (b) 4L
train is____________(m/s)
L L
(c) (d) 16. Two coherent light source radiate in phase. The
2 4
10. A solid sphere, a hollow sphere and a disc, all having d
distance between sources is d, where is the
same mass and radius, are placed at the top of an 4
incline plane and released. The friction coefficients wavelength of light produced. The angles are
between the objects and the incline are same but measured from the line connecting the two sources.
not sufficient to allow pure rolling in any of three cases. The distance from source to point of observation is
Least time will be taken in reaching the bottom by significantly larger than wavelength, then
(a) the solid sphere P
(b) the hollow sphere
(c) the disc
S1
(d) all will take same time
d/2 
11. Young's double slit experiment is made in a liquid.
The 10th bright fringe in liquid lies where 6th dark d/2
fringe lies in vacuum. The refractive index of liquid S2
is____________
(a) at  = 60°, maxima at P
12. The maximum tension in the string of pendulum
(b) at  = 30°, minima at P
is two times the minimum tension. Let 0 be
(c) at  = 60°, minima at P
the angular amplitude. Then, cos 0 is (d) at  = 30°, maxima at P
17. The initial state of an ideal gas is represented by the
1 3 point a on the p-V diagram and its final state by the
(a) (b)
2 4 point e. The gas goes from the state a to the state e
by three quasi stationary processes represented by
2 3 (i) abe (ii) ace (iii) ade. The heat absorbed by the
(c) (d) gas is
3 5
 MOCK TEST 11 3

e  u  u2  gdsin2 
pressure (p) (c) tmin   
 g tan  
 
b d c

 u  u2  gdcos 2 
a (d) tmin   
 gcos  
 
volume (V)
21. Two balls of same mass and carrying equal charge
(a) the same in all the processes
are hung from a fixed support of length l. At
(b) the same in processes (i) and (ii) electrostatic equilibrium, assuming that angles made
(c) greater in process (i) than in (iii) by each thread is small, the separation, x between
(d) less in process (ii) than in (iii) the balls is proportional to:
18. Time period of small oscillation of plate of mass m (a) l 2 (b) l
and given dimension is
(c) l 1 3 (d) l 2 3
22. A person lives in a high-rise building on the bank of
k
a river 50 m wide. Across the river is a well lit tower
of height 40 m. When the person, who is at a height
of 10 m, looks through a polarizer at an appropriate
angle at light of the tower reflecting from the river
b
surface, he notes that intensity of light coming from
distance X from his building is the least and t h i s
corresponds to the light coming from light bulbs at
a
height 'Y' on the tower. The values of X and Y are
m m(a2  b2 ) respectively close to (refractive index of water  4 3 )
(a) 2 (b) 2
k 3ka2
ma L
(c) 2 (d) None of these
kb
40m
19. A particle moves with simple harmonic motion in
straight line. In 1st second, it covers d1 and in 2nd 10m Y
second, it covers d2. What will be the amplitude of X
SHM (particle start from rest)? 50 m
(a) 22 m, 13 m (b) 17 m, 20 m
d1
(a) d1d2 (b) (c) 25 m, 10 m (d) 13 m, 27 m
d2
23. A letter 'A' is constructed of a uniform wire with
d12 2d12 resistance 1.0  per cm. The sides of the letter are
(c) (d)
2d1  d2 3d1  d2 20 cm and the cross piece in the middle is 10 cm
20. A projectile is fired with velocity u at an angle , so long. The apex angle is 60°. The resistance between
to strike a point on the inclined plane at an angle  the ends of the legs is close to____________()
with the horizontal. The point of projection is at a 24. A bullet of mass 10 g and speed 500 m/s is fired
distance d from the inclined plane on the ground. into a door and gets embedded exactly at the centre
The angle  is adjusted in such a way, so that the of the door. The door is 1.0 m wide and weighs
projectile can strike the inclined plane in minimum 12 kg. It is hinged at one end and rotates about a
time, find that minimum time. vertical axis practically without friction. The angular
speed of the door just after the bullet embeds into it
 u  u2  gdtan2  will be:
(a) tmin    (a) 6.25 rad/sec
 gtan  
  (b) 0.335 rad/sec
 u  u2  gdsin2  (c) 3.35 rad/sec
(b) tmin   
 gcos   (d) 0.625 rad/sec
 
4 MOCK TEST 11
25. A ray of light of intensity I is incident on a parallel O
glass slab at point A as shown in diagram. It
undergoes partial reflection and refraction. At each (c) CH3 C C CH3
reflection, 25% of incident energy is reflected. The N OH
rays AB and A'B' undergo interference. The ratio Imax (d) CH3CH2 C CH3
and Imin is:
N OH
B B’ 30. In order to refine "blister copper", it is melted in a
A’ furance and is stirred with green logs of wood.
A The purpose is:
(a) To expel the dissolved gases in the blister
copper.
(b) To bring the impurities to surface and oxidise
C C’
them.
(a) 7 : 1 (b) 8 : 1 (c) To increase the carbon content of copper.
(c) 49 : 1 (d) 4 : 1 (d) To reduce the metallic oxide impurites with
hydrocarbon gases liberated from the wood.
CHEMISTRY (SECTION – B) 31. The reaction of hydrogen and iodine mono chloride
26. How many moles of BH 3 are needed to react is given as H2(g) + 2ICl(g)  2HCl(g) + I2(g)
c om pletely with 2 m ole of 1–Pentene in This reaction is of first order with respect to H 2(g)
hydroboration-Oxidation reaction: and ICl(g), following mechanisms (given below)
2 were proposed
(a) mole (b) 2 mole
3 Mechanism I
3 H2(g) + 2ICl(g)  2HCl(g) + I2(g)
(c) mole (d) 3 mole
2 Mechanism II
27. The compound which undergoes SN1 reaction most H2(g) + ICl(g)  HCl(g) + HI(g) : slow
rapidly is: HI(g) + ICl(g)  HCl(g) + I2(g) : fast
W hich of the above mechanism(s) can be
(a) Br (b) Br consistent with the information about the reaction?
(a) I only (b) II only
(c) CH2Br (d) Br (c) I and II both (d) neither I nor II
32. The energies of activation for the forward and
NHCH2CH3

reverse reactions for A2 + B2  2AB are 180kJ
28. + CH3I (excess)  Product, The
mol and 200 kJ mol respectively. The presence
–1 –1

product is : of a catalyst lowers the activation energy of both

(a) a primary amine (forward and reverse) reactions by 100 kJ mol–1.
(b) a secondary amine The enthalpy change of the reaction A 2 + B 2
(c) a tertiary amine  
  2AB in the presence of catalyst will be (in
(d) a quarternary ammonium kJ mol–1)
O (a) 20 (b) 300
NaNO2
29. CH3CH2 C CH3 A (Major Product) (c) 120 (d) 280
HCl
A will be: 33. The difference between the boiling point and
O freezing point of an aqueous solution containing
sucrose (Molecular mass = 342 g mol–1) in 100 g
(a) CH3 CH C CH3 of water is 105.0C. If Kf and Kb of water are 1.86
NO and 0.51 K kg mol–1 respectively, the weight of
O sucrose in the solution is about
(b) CH3CH2 C CH = N OH (a) 34.2 g (b) 342 g
(c) 7.2 g (d) 72 g
 MOCK TEST 11 5
34. The half cell reactions for rusting of iron are 40. Which of the following curves may represent the
speed of the electron in a hydrogen atom as a
1
2H  O2  2e  H2O, E  1.23V function of the principal quantum ‘n’
2

Fe2   e   Fe(s), E  0.44V a

G° (in kJ) for the reaction is b d
(a) – 76 (b) – 322 V c
(c) – 122 (d) – 176
35. 4.5 g of Aluminium (at. mass 27 amu) is deposited
at cathode from Al3+ solution by a certain quantity
of electric charge. The volume of hydrogen n
produced at STP from H + ions in solution by the (a) a (b) b
same quantity of electric charge will be (c) c (d) d
41. The t0.5 of a radioactive isotope is 1.5 hours. How
(a) 44.8 L (b) 11.2 L
1
(c) 22.4 L (d) 5.6 L long will it take for its activity to be reduced to of
16
+
BH3/THF H2O its original value?
36. B CH2 A
H2O/OH (a) 3.0 h (b) 360 min
A and B are respectively: (c) 4.5 h (d) 600 min
42. At a given temperature, total vapour pressure (in Torr)
(a) both CH2OH of a mixture of volatile components A and B is given
by P = 120 – 75 XB hence vapour pressures of pure
A and B respectively (in Torr) are
(b) both CH3
(a) 120, 75 (b) 120, 195
OH
(c) 120, 45 (d) 75, 45
(c) CH2OH , CH3 43. Depression in freezing point of 0.01 m CH3COOH
OH solution in urea is 0.2046K. If kf for urea is 1.86,
then calculate pH of CH3COOH solution:
(d) CH3 , CH2OH (a) 2 (b) 3
OH (c) 3.2 (d) 4.2
37. A sample of 1.79 mg of a compound of molar mass 44. K4[Fe(CN)6] can be used to detect which of the
90g mol–1 when treated with CH3MgI releases 1.34 following ions: Fe2+, Fe3+, Zn2+, Cu2+, Ca2+?
ml of a gas at STP. The number of active hydrogen (a) Fe2+ and Fe3+ only (b) Fe3+, Zn2+ and Cu2+ only
in the molecule is____________ (c) All but not Ca2+ (d) All of these ions
38. When phenol reacts with benzene diazonium chloride, 45. The haemoglobin from red blood corpuscles of most
the product obtained is? mammals contain approximately 0.33% of iron by
(a) Phenyl hydrazine mass. The molecular mass of haemoglobin is 67200.
(b) p-amino azobenzene The number of gram atoms of iron in each mole of
haemoglobin is____________
(c) phenol hydroxylamine
46. The solubility of AgBr in water and 0.01 M CaBr2,
(d) p-hydroxy azobenzene
0.01M KBr, and 0.05M AgNO3 be S1, S2, S3 and S4
39. A mixture of 50.0 mL of NH3 and 60.0 mL of O2 gas respectively, give the relation of solubilities.
reacts as
(a) S1 > S2 > S3 > S4 (b) S1 > S3 > S2 > S4
4NH3 (g)  5O2 (g) 
 4NO  6H2 O (g) (c) S2 > S1 > S3 > S4 (d) S4 > S3 > S1 > S2
47. Which of the following traids have approximately
If all the gases are at the same temperature and
equal size ?
pressure and the reaction continues until one of the
gases is completely consumed, what volume of water (a) Na  ,Mg2  , Al3  (isoelectronic)
vapour is produced : (b) F  , Ne, O 2  (isoelectronic)
(a) 48 mL (b) 60 mL (c) Fe, Co, Ni
(c) 72 mL (d) 75 mL (d) Mn2  , Fe2  , Cr (isoelectronic)
6 MOCK TEST 11

48. The rate of a gaseous reaction is given by the

 x
expression k[A] [B]. If the volume of the reaction cos , x  0
vessel is suddenly reduced to 1/4th of the original 58. Let f(x)   2 . Then x = 0 will be a point
 x  a, x  0
volume, the reaction rate relating to the original
rate would be how much times____________ of local maxima for f(x) if
49. The vapour pressure decreases by 10 mm of Hg when
solute's mole fraction in a solution is 0.2. If the vapour (a) a  ( 1, 1) (b) a  (0, 1)
pressure decrease is 20 mm of Hg, then the mole (c) a  0 (d) a  1
fraction of solute will be____________
59. Point on y2 = 4x that is nearest to the circle x2 + (y –
50. When 40 cc of slightly moist hydrogen chloride 12)2 = 1, is
gas is mixed with 20 cc ammonia gas, then final
(a) (4, – 4) (b) (4, 4)
volume of gas at the same temperature and
pressure will be____________(cc) (c) (9, 6) (d) (9, – 6)

dx
MATHEMATICS (SECTION – C) 60.  x 2 / 3 (1  x 2 / 3 ) is equal to
51. If y = 3[x] + 1 = 4[x – 1] – 10, where [.] denotes the
greatest integer function, then [x + 2y] is equal 1
to____________ (a) tan1(x1/ 3 )  C
3
52. Let f(x) = 1  x 2 , then
(b) 3 tan1(x1/ 3 )  C
(a) f(xy) = f(x).f(y) (b) f(xy)  f(x).f(y)
(c) f(xy)  f(x).f(y) (d) None of these 17
(c) sin1(x1/ 3 )  C
53. Total number of values of 'x' where the function 88

f(x)  cos x  cos 2x attains it's maximum value (d) 3 sin1(x1/ 3 )  C

is/are____________
54. If the line ax + by + c = 0 is a tangent to the curve xy
+ 2 = 0, then
61. The graph of the function f  x   loga x  x  1
2
 
is symmetric about
(a) a > 0, b > 0 (b) a > 0, b < 0
(a) x-axis (b) origin
(c) a > 0, c > 0 (d) a > 0, c< 0
(c) y-axis (d) the line y = x
x  1 x 
55.  e 
 (1  x)3 
dx is equal to
sin1 x  tan1 x
  62. lim is equal to
x0 x3
ex ex
(a)  C (b)  C (a) 2 (b) 1
(1  x)3 / 2 (1  x)2
1
ex ex (c) –1 (d)
(c) C (d) C 2
(1  x)3 / 2 (1  x)2

63. The value of lim


1  cos ax 2  bx  c  where
56. Total number of parallel tangents of f1(x) = x – x + 1 2

and f2(x) = x3 – x2 – 2x + 1 is equal to

x 
 x   2

(a) 2 (b) 3 ,  are the distinct roots of ax 2  bx  c  0

(c) 4 (d) None of these
57. Tangents are drawn to y = cosx from the point P(0,     2
(a)     
2
(b)
0). Points of contact of these tangents will always 2
lie on
2
1 1 1 1  a     2 
(a)  1 (b)  1
x2 y2 x2 y2 (c)   (d) None of these
 2 

(c) x 2  y 2  1 (d) x2 – y2 = 1
 MOCK TEST 11 7
70. If the tangent to the curve xy + ax + by = 0 at (1, 1)
 x  y 1
64. Let f    f  x   f  y   for real x and y. If f'(0)
 2  2  ab
makes an angle tan–1(2) with x-axis, then is
ab
exists and equals –1 and f(0) = 1 then the value of
f(2) is equal to
(a) 1 (b) –1 1 1
(a) (b) 
2 2
1 (c) 1 (d) –1
(c) (d) 2
2 71. The orthocentre of the triangle formed by the lines x
65. The equation of the common tangent to the curves + y = 1, 2x + 3y = 6 and 4x – y + 4 = 0 lies in
y2 = 8x and xy = –1 is (a) I quadrant (b) II quadrant
(a) 3y = 9x + 2 (b) y = 2x + 1 (c) III quadrant (d) IV quadrant
(c) 2y = x + 8 (d) y = x + 2 72. The ratio of sum of first three terms of a G.P. to the
66. Range of f(x) = [cos–1{x}], where [.] and {.} denotes sum of first six terms is 64 : 91, the common ratio
the greatest integer function and fractional part of G.P. is
respectively, is
1 3
(a) {0, 1} (b) {0, 1, 2} (a) (b)
4 4
(c) {0, 1, 2, 3} (d) None of these 5 7
67. If f(x + f(y)) = f(x) + y  x, y  R and f(0) = 1, then (c) (d) 4
4
value of f(7) is____________ 73. The coefficient of the term independent of x in the
68. f(x) = [x2] – {x}2, where [.] and {.} denote the greatest 10
 x 1 x 1 
integer function and fractional part respectively, is expansion of  23  
x  x  1 x  x1 2 
13
(a) Continuous at x = 1, – 1 ____________
(b) Continuous at x = – 1 but not at x = 1 74. The complex number 3 + 4i is rotated about origin
(c) Continuous at x = 1 but not at x = – 1 by an angle of  4 and then stretched 2-times. The
(d) Discontinuous at x = 1 and x = – 1 complex number corresponding to new position is
69. Domain of definition of f(x), where f(x) = maximum
(a) 2  3  4i (b) 2  1  7i
{x, 1, x2}  x  R, is
(c) 2  3  4i (d) 2  1  7i
(a) R ~ {–1, 0, 1} (b) R ~ {0, 1}
(c) R ~ {–1, 0} (d) R ~ {–1, 1} 75. ( 2  1)6   ( 3  1)6   ([·] denotes greatest
   
integer function) ____________

ANSWERS
1. (a) 2. (4) 3. (a) 4. (c) 5. (a) 6. (b) 7. (b) 8. (102) 9. (d) 10. (d)
11. (1.8) 12. (b) 13. (d) 14. (c) 15. (20 m/s) 16. (a) 17. (c) 18. (b) 19. (d) 20. (b)
21. (c) 22. (d) 23. (26.7 ) 24. (d) 25. (c)
26. (a) 27. (b) 28. (d) 29. (c) 30. (d) 31. (b) 32. (a) 33. (d) 34. (b) 35. (d)
36. (d) 37. (3) 38. (d) 39. (c) 40. (c) 41. (b) 42. (c) 43. (b) 44. (a) 45. (4)
46. (b) 47. (c) 48. (16) 49. (0.4) 50. (20 cc)
51. (107) 52. (c) 53. (1) 54. (b) 55. (d) 56. (d) 57. (b) 58. (d) 59. (b) 60. (b)
61. (b) 62. (d) 63. (d) 64. (b) 65. (d) 66. (a) 67. (1) 68. (d) 69. (d) 70. (a)
71. (a) 72. (b) 73. (210) 74. (b) 75. (612)
8 MOCK TEST 11

EXPLANATIONS
B 13. P  pg 5h  3P
1. V    E.dl .
A pg  5h  2P

2. Use Biot Savart’s law. 2P

pgh 
3. Use Ampere’s law. 5
4. Moving charge produces Magnetic field.
P  2P 7P
p'  P  pgh  
5. E = Bul. 3 5
6. For slits of unequal width, I1  I2 14. at t = 4 hours
N0 3N0
mv 2 Nx  Ny 
7. At the bottom, N  mg  4 4
r
Nx 1
 
 1 Ny 3
8. The slab produces a shift d = t  1  
 
at t = 6 hours
9. I11 = I22 N0 7N0
Nx  Ny 
10. All have the same acceleration while sliding. 8 8

11 Nx 1
11. 6th dark fringe lies at 
2 Ny 7

C   1 1 1
  , '  lies between &
V '  4 3 7

10  t lies between 4 & 6 hours

10th bright in liquid = 10 ' 

9  340  v 
15. f'  f  f
8  340  v 
10  11

 2 v = 20 m/s


20
 1.8 16. i.e.,   d
11 4

As  is large in comparison with d so only assumption

12. Tmin  mg cos 0
of YDSE is valid, so x of any point
x = d sin = 4 sin
T

For  = 60°, x = 4  3  2 3
T 2
mg Neither maxima nor minima.
mg
1
For  = 30°, x  4   2 maxima at P..
mv 2 2
Tmax  mg 
R 17. As initial and final condition is same that’s why U
will be same for all three.
1
mv 2  mgR 1  cos 0 
2 For abe, Q = U + W
Overall work done is positive as we can see that in
mv 2
 2mg  2mgcos 0 upper part of graph, net volume increases.
R
So, Q will be sum of U(>0) and W(>0).
Tmax  mg  2mg  2mgcos 0
In ae part, W = 0 so Q = U
2cos 0  3  2cos 0 In ade part, W < 0, Q = U – W
So, heat absorbed by gas is greater in process (i)
3
cos 0  than process (iii).
4
 MOCK TEST 11 9
18. For small value of , spring force will be = K(a) 21. For equilibrium:
Restoring torque about hinge  = (ka)a = (ka2) mgsin   qEcos 

kq2
 tan  
k mgx 2

 x kq2
a  
2l mgx 2

 2kq2 
 x 3    l  x  l 3
1

 mg 

22. Using Brewster’s Law:

4 x 50  x
  tanib   
So, tension on spring T  2 IH 3 10 y
ka2
Solving x  13 and y  27
IH = Moment of inertia about hinge
2
 a2  b2 
IH  ICOM  m   ib ib y
 2  10
  x 50-x
m(a2  b2 ) m(a2  b2 ) m(a2  b2 )
  
12 4 3 23. Req  10  20  10  26.7
3
m(a2  b2 )
T  2  24. Applying Angular Momentum Conservation:
3ka2
19. By general equation of SHM with  frequency mvr  I 
10
 500  0.5 
12  12

x = Acos(t) 1000 3

At t = 1sx = A – d1    0.625 rad/s

At t = 2sx = A – d1 – d2 25. Let the original intensity be I0 , then
From equation,
and IA 'B '  0.75  0.25  0.75IO   0.75  IAB
2
IAB  0.25IO
A – d1 = A cos()
A – d1 – d2 = A cos(2) = A[2cos2 – 1]
 
2

Imax IAB  IA ' B '

  A  d 2  Now,   49
 
2
Imin IAB  IA ' B '
A  d1  d2  A 2  1
  1
  A  

2d12 26. 3 mole of alkene reacts with = 1 mole of BH3

A
3d1  d2
2
20. Suppose the coordinate of the point where projectile  2 mole of alkene reacts with = mole of BH3
3
strikes the inclined plane is (x, y).
27. Rate of SN1  stability of carbocation.
1
Now, y  (usin )t  2 gt2 ... (i)
and x = (cos)t ...(ii) 28. NHCH2CH3 Salt
CH3
From the geometry of the figure, CH3 – I
H3C N CH2 CH3
d = x + y cot ...(iii) 2 mole +
From Eqs. (i), (ii) and (iii)
 1 
d  (ucos )t   (ucos )t  gt 2  cot  ...(iv)
 2  OH O

For tmin, dt  0 which, gives tan = cot 29. CH3 CH C CH3 CH3 CH C CH3
d
O N N O
    +
2 CH3
Now, substituting this value of  in Eq. (iv) CH3 C C
 u  u2  gdsin2  O
N (Major)
tmin    O
H
 gcos  
 
10 MOCK TEST 11
31. Since the given reaction is first order with respect to +
38. HO + N2 Cl ¯
H2 and ICl, the slow step should involve 1 molecule
of H2 and 1 molecule of ICl. Hence II is the correct
HO N N
mechanism.
32. The presence of catalyst does not affect the enthalpy 39. Limiting reagent is O2
change of the reaction. ACC to equation5 moles O2 gives 6 moles H2O
H = 180 – 200 = – 20 kJ mol –1
60 moles O2 gives 72 moles H2O
33. Tb = Kb × m and Tf = Kf × m 0.693 0.693
41.   hours 1 = 0.462 hr–1
t1/ 2 1.5
 Tb + Tf = (Kb + Kf)m
Now, Tb – Tf = (T°b + Tb) – (T°f – Tf) N0 = 1; N  1
16
105 = (Tb + Tf) + (T°b – T°f)
2.303 N 2.303
105 = (Tb + Tf) + 100 t log 0  log 16  6hr  360min
 N 0.462
 Tb + Tf = 5 42. P = P°A XA + P°BXB
Tb  Tf 5 5 P = P°A(1 – XB) + P°BXB
 m    2.11
Kb  K f 1.86  0.51 2.37 P = P°A – (P°A – P°B)XB
Moles of solute But P = 120 – 75 XB
Molality 
Mass of solvent(kg)  P°A = 120 Torr

 Moles of solute = 2.11 × 0.1 = 0.211 P°A – P°B = 75

 Mass of solute = 0.211 × 342 = 72.16 g P°B = P°A – 75 = 120 – 75 = 45 Torr
34. For e.m.f. to be +ve, oxidation should occur at iron 43. Kf = 1.86 m–1
electrode. Ecell = 1.23 + 0.44 = 1.67 V Tf  iK f m

G  nFEcell  2  96500  1.67  322 kJ. 0.02046 = i × 1.86 × 0.01

2.046
35. Al3   3e  Al i  1.1
1.86
27 g of Al are deposited by a charge = 3F
 CH3COO– + H+
H2O
CH3COOH 
1 0 0
4.5 g of Al are deposited by a charge  3  4.5 F  0.5 F
27  
1 

2H  2e   H2 i = 1 +  , 1 +  = 1.1 or  = 10–1

 [H+] = C  = 10–2 × 10–1 = 10–3
2F produce H2 = 22.4 L at STP
pH = 3
22.4
 0.5 F will produce H2 =  0.5  5.6 L 44. Fe2+ + [Fe(CN)6]4–  Fe[Fe(CN)6]2–  (white)
2
Fe3+ + [Fe(CN)6]4–  Fe4[Fe(CN)6]3  (Prussian
36. HO
O – CH2 CH2 Blue)
45. 100g haemoglobin has = 0.33g Fe
H3O
+ CH3
0.33
OH 67200g haemoglobin has Fe   67200  221.76g
100
37.  A   CH3MgI  CH4  1 mole or N0 molecules of haemoglobin has
If total no of active hydrogen are ‘x’ in compound ‘A’ 221.76
 g atom of Fe = 3.96 g-atom of Fe
then x no of moles of CH4 forms 56

1.79  10 3
= 4.0g atoms
no of moles of (A)   2  10 5 moles
90 Br      
46.   CaBr2  0.01  2, Br  KBr  0.01  Ag  AgNO3  0.05
1.34
no of moles of CH4   6  10 5 moles Both Br  and Ag ions act as common ions, so
22400

3 active hydrogen are present larger the conc. of Br  and Ag more is the
suppression of ionization of gBr
 MOCK TEST 11 11

47. Because shielding effect and increase in effective x

 1 x 
e (x  1)
nuclear charge are cancelled. 55.  e x   dx    dx
(1  x)3  (x  1)3

48. rate = k[A].[B]

When volume is reduced to 1 th of its original volume, e x (x  1  2) x 1 2 

  dx    e    dx
4 (x  1)3  (x  1)2
(x  1)3 
pressure increases to four times; then A and B
becomes 4A and 4B.  ex 2e x 2e x  ex
 rate = k × 4 × 4 = 16 k
 
 (1  x)2
  (1  x)3
dx   (1  x)3
dx 

 C 
(1  x)2
C
 
49. According to Raoult’s law,
P° – P = P° X 56. f1(x1)  2x1  1, f2 (x 2 )  3x 22  2x 2  2.

 10 = P° × 0.2 ... (i) Let tangents drawn to the curves y = f1(x)

and 20 = P° × X2 ... (ii) and y = f2(x) at (x1, f(x1)) and (x2, f(x2)) are parallel,
Hence, P° is same
then 2x1 – 1 = 3x 22  2x 2  2,
Equating equations (i) and (ii),
which is possible for infinite number of ordered pair
10 20 20  0.2
 or X2   0.4 (x1, x2).
0.2 X2 10

Hence mole fraction of solute is 0.4 when vapour 57. For y = cosx, dy   sin x.
dx
pressure decreases to 20 mm Hg.
50. 20 ml ammonia gas will neutralize with 20 ml Let the point of contact be (x0, cosx0).
hydrogen chloride gas and form ammonium chloride. Equation of tangent to y = cosx at this point is
So, at same temperature and pressure, the volume
(y – cosx0) = sinx0(x0 – x).
of gaseous mixture will be 20 ml
NH3(g) + HCl(g)  NH4Cl. It must pass through (0, 0).

51. cy = 3[x] + 1 = 4[x – 1] – 10 = 4[x] – 14 Thus, x0 = – cotx0.

 [x] = 15 and y = 3.15 + 1 = 46 We also have y0 = cosx0
 [x + 2y] = 2y + [x] = 2.46 + 15 = 107 1 1
   1.
2 2
y20 x02
52. f(xy)  1  x y
58. Clearly, f(x) is increasing before x = 0
 f(x).f(y) = (1  x2 )(1  y2 )
and starts decreasing after x = 0. f(0) = a.

= 1  x 2 y2  x 2  y 2 )  1  x 2 y 2 For x = 0 to be the point of local maxima

f(0)  lim f(x)
 f(xy)  f(x).f(y) x 0  0

53. Maximum value of f(x)  cos x  cos 2x is clearly equal  a 1

to two and it occurs when cosx = 1,
i.e. x = 2n1, 2x  2n2 ,
where n1 and n2 are integers.
 x = 0 is the only possibility.
54. For xy = – 2,
cos 2x  1 , 59. Shortest distance between two curves always occur
along the common normal. That means if ‘P’ is the
required point then PA becomes the common nor-
mal.
2 2
x + (y - 12) = 1

dy 2 A
 , which is always positive.
dx x 2
y2 = 4x
P
Thus, a  0 or signs of ‘a’ and ‘b’ must be opposite.
b O
12 MOCK TEST 11

Let P  (t 2 , 2t). ax 2  bx  c
63. xlim

1  cos ax 2  bx  c   lim 2sin 2
2
Equation of normal at ‘P’ is 
 x   2 x 
 x   2
y = – tx + 2t + t , 3

it should pass through (0, 12). a  x    x  

sin2 a2     
2
a2
2  x   
2
Thus t + 2t – 12 = 0
3  lim 
x   a  x    x     2 2
 t = 2.  2 

Hence, P  (4, 4).

64. Putting y = 0 in the given functional equation, we
dx get
60. I  x 2 / 3 (1  x2 / 3 ) ,
f  x   f  0 1
f  x 2   1  f  x    f  0   1
Let t3 = x 2 2

 dx = 3t2dt  f  x   2f  x 2  1 … (i)
2 f  0  h  f  0 
 I    23t dt2  3  dt 2 Since f '  0   1 we get lim  1
t (1  t ) 1 t h 0 h

f  h  1
 3 tan1(t)  C = 3tan–1(x1/3) + C  lim  1
h0 h

 x   1 Let x R , then
61. f  x   loga x 2  1  loga
2
x  x 1
f  2x   f  2h

  log x  x 2  1   f  x   f '  x   lim
h 0
f  x  h  f  x 
h
 lim
h0
2
h
 f  x

Hence f is an odd function, therefore, the graph of f 11 

is symmetric about origin. Since  lim  2 2f  x   1  2f  h  1  f  x   [using (i)]
h 0 h  

ax  a x f  h  1
f 1  x   , so graph of f, cannot by symmetric  lim
1
 f  x   1  f  h  f  x    lim  1
2 h 0 h h 0 h
about the line y = x. Non-symmetry about x-axis
Thus f '  x   1 , so we get f(x) = –x + C
and y-axis is clear.
But f(0) = 1, therefore, 1 = f(0) = –0 + C
sin1 x  tan1 x  0 
62. lim  form  C1
x0 x3 0
Thus f(x) = 1 – x, in particular
1 1 f(2) = 1 – 2 = –1
 2
 lim 1  x2 1  x
2
65. Differentiating the given curve w.r.t. x, we get
x 0 3x
(L Hospital rule) dy dy dy 2x
3y 2  6x  12   2
dx dx dx y 4
 
1 1 1  x 2  1  x2 
 lim 2  dy
 
3 x 0 x  1  x 2 1  x 2 
  At point where the tangent(s) is (are) vertical,
dx
is
not defined, i.e. at those points.
1

1 1 x
 lim 2 
2 2

 1  x2
·
  1

  y 2  4  0  y  2
3 x 0 x
 1  x 2
1  x 2
 1  x 2
 1  x 2
   when y = 2, 8 + 3x2 = 12(2)  3x2 = 16
4
x= 
1
 lim
x2 3  x2

 1  
3
 
3 x 0 x2 1  x 2 1  x 2 1  x 2  1  x 2   When y = –2, –8 + 3x2 = –24  3x2 = –16 .
This is not possible.
1  3 1
   
3  2 2 Thus, the required points are   4 3 , 2 .
 MOCK TEST 11 13

  k4
66. Range of cos–1{x} is  0,   4  1
 2 h3

 Range of [cos–1{x}] is {0, 1}  4k  16  h  3

67. f(x + f(y)) = f(x) + y, f(0) = 1  h  4k  13 ...(i)

Putting y = 0, we get and slope of PB × slope of AC = –1

f(x + f(0)) = f(x) + 0 8
k
 f(x + 1) = f(x)  x  R  5   2  1
3 3
Thus f(x) is periodic with 1 as one of it’s period. h
5
Thus f(7) = f(6) = f(5) = ...... = f(1) = f(0) = 1
68. f(x) = [x2] – {x}2 5k  8 2
  1
5h  3 3
f(–1) = 1, f(– 1 – 0) = 0 – 1 = – 1
 10k  16  15h  9
f(1) = 1, f(1 + 0) = 1 + 0 = 1
f(1 – 0) = 0 – 1 = – 1  15h  10k  25  0

Thus f(x) is discontinuous at x = 1, – 1  3h  2k  5  0 ...(ii)

69. Bold line represents the graph of f(x). 3 22

Solving Eqs. (i) and (ii), we get h  , k 
Clearly, f(x) is non-differentiable at x = –1, 1 7 7

y=x
2
y y=x Hence, orthocentre lies in I quadrant.

y=1

72. Given
S3 64 a r  1
 
3
 
S6 91 a r 6  1  
x
–1 1


r 3
1  
64
70. xy + ax + by = 0, (1, 1) lies on it, r 3

 1 r3  1  91

 a+b+1=0
27 3
Also, x. dy  y  a  b dy  0  r3 
64
r 
4
dx dx
dy (y  a)
 
dx (x  b)
73. Given expression 
 x   1
13 3


 x  1
dy

(1  a)
 2 (given)
x 23
x13
1 x 12
x 12

1
dx 1, 1 1 b
 –1 – a = 2 + 2b

x 13

 1 x 2 3  x1 3  1   x 12

 1 x1 2  1 
3+b+b+a=0

b = – 2, a = 1
 x 23
x 13
1  x 12
 x1 2  1 

a  b 1 1

ab
 
2 2
  
 x1 3  1  1  x 1 2  x1 3  x 1 2 
 3 8
71. Coordinates of A and B are (– 3, 4) and   ,  if  x 1 x 1 
10

 5 5   23  12 
 x  x 1 x  x 
13
orthocentre p(h, k)
y
=0

10
 x 1 x 1 
4

 23  12 
y+

 x  x 1 x  x 
13
+
4x

A C
2x
 
10
+  x1 3  x 1 2
B 3y
= 6
 
10
O x Tr 1 in x1 3  x 1 2 is

Then, (slope of PA) × (slope of BC) = –1

14 MOCK TEST 11
= 2(8 + 15 × 4 + 15 × 2 + 1) = 198
  · 1 · x 
10  r r r
10 1 2
Cr x 1 3
 As [F1] = 0, F1  {F1}  1  {I1}
 10  r r 
  
  1 which is independent of x  I1  1  {I1}  198  [I1]  197
r 10
 3 2
Cr x

I2  ( 3  1)6,F2  ( 3  1)6
 10  r r 
If   0r 4
 3 2
I2  F2  ( 3  1)6  ( 3  1)6

Hence, required coefficient  10C4  1  210

 
4

 2 6C0 ( 3)6  6C2 ( 3)4  6C4 ( 3)2  6C6

i 4
74. The new complex number is 2 3  4i e  2  1  7i = 2(27 + 15 × 9 + 15 × 3 + 1) = 416

75. I1  ( 2  1)6 , F1  ( 2  1)6  F2  {F2 }  1  {I2 }

[I2 ]  415
I1  F1  ( 2  1)6  ( 2  1)6
[I1]  [I2 ]  197  415  612

 2 6C0 ( 2)6  6C2 ( 2)4  6C4 ( 2)2  6C6 ( 2)0 
 MOCK TEST – 12
PHYSICS (SECTION – A) P
1. A bulb and a capacitor are connected in series to a 6P0 B
source of alternating current. If its frequency is
increased, while keeping the voltage of the source 3P0
constant, then A
(a) bulb will give more intense light V
P V0 5V0
(b) bulb will give less intense light 3R 13R
(c) bulb will give light of same intensity as before (a) (b)
2 6
(d) bulb will stop radiating light 5R
2. 110 volts (rms) is applied across a series circuit (c) (d) 2R
2
having resistance 11 and impedance 22. The 8. A particle of mass m and charge q is attached to a
power consumed is____________() light rod of length L. The rod can rotate freely in the
3. Suppose the potential energy between electron and proton plane of paper about the other end, which is hinged
at P. The entire assembly lies in a uniform electric
ke2 field E also acting in the plane of paper as shown.
at a distance r is given by  . Application of Bohr's
3r 3 The rod is released from rest when it makes an angle
theory to hydrogen atom in this case show that  with the electric field direction. Determine the speed
of the particle when the rod is parallel to the electric
(a) Energy in the nth orbit is proportional to n6
field.
(b) Energy is proportional to m–3 (m : mass of electron)
m, q
(c) both (a) and (b) are correct
(d) none are correct E
L
4. The half-life of the radioactive Radon is 3.8 days.
1 
The time, at the end of which th of the Radon
20 P
sample will remain undecayed, is (given log 10e 1 1
= 0.4343)  2qEL(1  cos )  2  2qEL(1  sin )  2
(a) 3.8 days (b) 16.5 days (a)   (b)  
 m   m 
(c) 33 days (d) 76 days
5. A radioactive element is disintegrating having half 1 1
life 6.92 sec. The fractional change in number of  qEL(1  cos )  2  2qEL cos   2
(c)   (d)  
nuclei of the radioactive element during 10 sec is:  2m   m 
(a) 0.37 (b) 0.63 9. A biconvex lens of focal length 15 cm is in front of a
(c) 0.25 (d) 0.50 plane mirror. The distance between the lens and the
6. A series combination of resistor and capacitor is mirror is 10 cm. A small object is kept at a distance
connected across with an applied AC voltage of 30 cm from the lens. The final image is
source. Separate voltmeter reading across the (a) virtual and at a distance of 16 cm from the mirror
resistor and capacitor give values of 50 V (rms) and (b) real and at a distance of 16 cm from the mirror
75 V (rms) respectively. The effective (rms) voltage (c) virtual and at a distance of 20 cm from the mirror
of the source, is nearly____________(V) (d) real and at a distance of 20 cm from the mirror
7. One mole of a monoatomic ideal gas undergoes the 10. A point source S is placed at the bottom of different
process A  B
layers as shown in the figure. The refractive index of
in the given P-V diagram. The specific heat for this bottom most layer is m0. The refractive index of any
process is 0
other upper layer is 0  where n = 1, 2,
4n  18
2 MOCK TEST 12

..... A ray of light with angle i slightly more than 30° 16. Imagine an atom made up of a proton and a
starts from the source S. Total internal reflection hypothetical particle of double the mass of the
takes place at the upper surface of a layer having n electron but having the same charge as the electron.
The wavelength of the radiation that will be emitted
equal to____________
when this particles jumps from first excited state to
ground state (in terms of the Rydberg constant R for
the hydrogen atom) is equal to
=3
=2 2 1
(a) (b)
=1 3R 3R
0
1
S (c) (d) None of these
2R
11. Capacity of an isolated sphere is increased n times
17. Let  be the angular velocity of earth's rotation about
when it is enclosed by an earthed concentric sphere.
its axis. Assume that the acceleration due to gravity
The ratio of their radius is on earth's surface has value at equator and the poles.
n2 n An object weighed at the equator gives same reading
(a) (b) as taken at depth d below surface at pole (d << R).
n 1 n 1
The value of d is
2n 2n  1
(c) (d) 2R2 2R2
n1 n 1 (a) (b)
12. Magnetic moment of an electron in the nth orbit of g 2g
hydrogen atom is (m = mass of electron, h = Planck's
22R2 R
constant) (c) (d)
g g
neh neh
(a) (b) 18. The potential difference between the points A and B
m 4m is +40 V. If the electric field is uniform then the value
meh meh of electric field at B
(c) (d)
2n 4n 2 cm
A B
13. In a series L-R growth circuit, if maximum current
(a) must be equal to 20 V/cm
and maximum voltage across inductor of inductance
3mH are 2A and 6V, then the time constant of the (b) may be less than 20 V/cm
circuit is____________(ms) (c) Both (a) and (b) are correct
14. The combination of gates shown in figure produces (d) Both (a) and (b) are not correct
19. Figure (a), shows a parallel-plate capacitor having
A
square plates of edge a and plate-separation d. The
Y gap between the plates is filled with a dielectric of
B dielectric constant K which varies parallel to an edge
a, where K and  are constant and x is the distance
(a) NOR gate (b) NAND gate
from the left end.
(c) AND gate (d) OR gate
K = K0 + x
15. Time taken by the projectile to reach from A to B is
Calculate the capacitance?
t. Then, the distance AB is equal to
u a

K
B
x
° dx
60
30° (a) (b)
A
(a) ut 3 (b) 2ut 0 a 2  a  0 2a2  a 
(a) K 0  2  (b) 3K 0  2 
ut  3 d   d  
(c) (d) ut  
3  2  3 0 a 2  a  0 a 2  a 
(c) 3K 0  4  (d) K 0  2 
4d   6d  
 MOCK TEST 12 3
20. A rigid body oscillates angularly about point O. 24. In the circuit shown here, the voltage across L and
Distance between O and center of gravity is L and C are respectively 300 V and 400 V. The voltage E
radius of gyration is K, then what will be equivalent of ac source is :
length? L
K K2
(a) (b)
L L C
2 2
L K
(c) L  (d) L 
L L E
21. Two coils, X and Y, are kept in close vicinity of each (a) 100 Volt (b) 400 Volt
other. When a varying current, I(t), flows through (c) 500 Volt (d) 700 Volt
coil X, the induced emf (V(t)) in coil Y, varies in the 25. Two simple pendulums of length 1 m and 4 m
manner shown here. The variation of I(t), with time, respectively are both given small displacement in
can then be represented by the graph labelled as
the same direction at the same istant. They will be
graph:
again in phase after the shorter pendulum has
completed number of oscillations equal
V(t) to____________
t
CHEMISTRY (SECTION B)
26. When MnO 2 is fused with KOH in the presence of
I(t) I(t) air, a coloured compound is formed, the product
(A) t (B) t and its colour is:
(a) K2MnO 4, dark green (b) KMnO4, purple
(c) Mn2O 3, brown (d) Mn3O 4, black
I(t) I(t) 27. Which of the following will not show geometrical
(C) t (D) t isomerism?
(a) [CO(NH3)5 NO2] Cl2 (b) [Cr(NH3)4Cl2] Cl
(a) A (b) C (c) [CO(en)2Cl2]Cl (d) [Pt(NH3)2Cl2]
(c) B (d) D 28. A white salt turns yellow on heating but becomes
22. If a carrier wave c  t   A sin c t , were to be white on cooling. It may be a salt of :
amplitude modulated by a modulating signal (a) Fe (b) Pb
(c) Al (d) Zn
m  t   A sin m t , the equation representing the
29. The configuration at C – 2 and C – 3 of the
modulated signal Cm  t  , and its modulation compound given:
index, would be respectively: CH3
H Cl
(a) Cm  t   A 1  sin c t  sin m t and 2 Cl H
(b) Cm  t   A 1  sin c t  sin m t and 1 C2H5
(a) 2R, 3S (b) 2S, 3R
(c) Cm  t   A 1  sin m t  sin c t and 1 (c) 2S, 3S (d) 2R, 3R
(d) Cm  t   A 1  sin m t  sin c t and 2 30. The principle product of the reaction between
methyl butanoate and 2 moles of CH 3MgBr after
23. When Uranium is bombarded with neutrons, it
hydrolysis is:
undergoes fission. The fission reaction can be
written as : OH

92 U235  0n1  56Ba141  36 Kr 92  3x  Q  energy  (a) C3H7COCH3 (b) C3H7 C CH3

where three particles named x are produced and CH3
energy Q is released. What is the name of the O H
particle x?
(a) neutron (b)  -particle (c) C3H7CHOHCH3 (d) C3H7 C C CH3
(c) neutrino (d) electron CH3
4 MOCK TEST 12

31. 50 mL of 0.1M of H 3CCOOH is titrated against 41. The rate of the reaction
0.1M NaOH solution. _________will be the pH of 2NO + Cl2 2NOCl is given by
the solution when 25 mL of NaOH is added?
[Given: Ka of H3C–COOH = 2 × 10–5; log 2 = 0.3] the rate = k[NO]2 [Cl2]
32. The decomposition of a certain mass of CaCO 3 The value of the rate constant can be increased by
gave 11.2 dm 3 of a CO 2 at S.T.P. The mass of (a) increasing the temperature
KOH required to completely neutralize the gas (b) increasing the concentration of NO
is__________(g) (c) increasing the concentration of Cl2
33. The compound that is both paramagnetic and (d) doing all three
coloured is
42. At low pressure, the compressibility factor can be
(a) CuF 2 (b) K3[Cu(CN) 4] expressed by:
(c) K2[TiCl6] (d) K2CrO4
 a   RTV 
34. The equivalent weight of MnO 2 is equal to its mo- (a)  1   (b)  1 
 RTV   a 
lecular weight when it is converted to
(a) Mn2O 3 (b) MnO  a   RTV 
(c)  1   (d)  1 
(c) MnO24 (d) MnO4  RTV   a 

35. The complex having the highest magnetic moment 43. 2L of SO2 gas at 760 mm Hg are transferred to 10L
is flask containing oxygen at a particular temperature,
the partial pressure of SO 2 in the flask
(a) [Zn(H2O)6]2+ (b) [Cr(H2O)6]2+
is____________(mm Hg)
(c) [Mn(H2O)6]2+ (d) [Cu(H2O)6]2+
44. What is the solubility of PbSO4 in 0.01 M Na2SO4
36. Which of the following molecules is T- shaped? solution if Ksp for PbSO4 is 1.25 × 10–9?
(a) PCl3 (b) BCl3
(a) 1.25 × 10–7 mol L–1
(c) NH3 (d) CIF3
(b) 1.25 × 10–9 mol L–1
37. On heating a mixture of NaCl, K2Cr2O7 and conc.
H2SO4, which of the following is formed? (c) 1.25 × 10–10 mol L–1

(a) CrCl3 (b) CrO2Cl2 (d) 0.10 mol L–1

(c) Cl2 (d) NaClO2 45. The stability of hydrophobic sol is due to
38. Which of the following statements about the complex (a) solvation of colloidal particles
[CoF6 ]3  which is paramagnetic in nature is (b) the charge on the colloidal particles
correct? (c) the size of the particles
(d) none of the above
(a) Cobalt involves d2sp3 hybridisation
46. n-factor for HCl in reaction K2Cr2O7 + HCl  KCl +
3 2
(b) Cobalt involves sp d hybridisation CrCl3 + Cl2

(c) F is in zero oxidation state 5 3

(a) (b)
(d) the oxidation state of cobalt is +2 7 7
39. The edge length of unit cell of sodium chloride is 7 7
564 pm. If the size of Cl– ion is 181 pm, the size of (c) (d)
3 5
Na+ ion would be____________(pm)

40. Among LiCl, BeCl2 , MgCl2 and RbCl, the CH 3

compound with greatest and least ionic character, Br2/hv
respectively are 47. Monobromoderivatives

(a) LiCl and RbCl (b) RbCl and BeCl2

The number of possible monobromo products is
(c) RbCl and MgCl2 (d) MgCl2 and BeCl2
excluding stero isomers____________
 MOCK TEST 12 5

48. If E0cell for a given reaction is negative which gives 52. The order of the differential equation whose general
solution is y = c1 cos2x + c2 cos2x + c3 sin2x + c4,
the correct relationship for the value of G0 and keq is____________
? 53. Value of positive real parameter 'a' such that the area
of the region bounded by the parabolas y = x – ax2,
(a) G0  0, k eq  1 (b) G0  0, k eq  1 ay = x 2 attains it's maximum value, is equal
to____________
(c) G0  0, k eq  1 (d) G0  0, k eq  1
54. Total number of points of discontinuity of f(x) = [3 + 4
49. Equivalent conductance of Ba 2+ and Cl– ions are sinx], where [.] denotes the greatest integer function,
127 and 76 ohm –1 cm –1 eq –1 respectively. in [, 2] is equal to____________
Equivalent conductance of BaCl 2 at infinite
dilution is 1  2 1  1  2 1 
55. Range of f(x) = sin  x    cos  x   ,
(a) 132.4 (b) 101.5  2   2
(c) 139.5 (d) 204.5 where [.] denotes the greatest integer function, is
50.
 
(a)  ,   (b) {}
(X) NaBH4 Conc.HBr 2 
Y Z W
N2H4/OH 1. Mg, ether 
NBS 2. CO2 (c)   (d) None of these
M 3. H3O + 2
56. If both the roots of x2 – ax + a = 0 are greater than 2,
Ph CH C2H5
then
COOH
(a) a  ( , 4) (b) a  (0, 2)
Which is not correctly matched? (c) a  (4,  ) (d) None of these
Cl
(a) (X) is 57. If x3 + ax + 1 = 0 and x4 + ax2 + 1 = 0 have a common
+ AlCl3 root, then complete set of values of a is
O
OH (a) ( ,  2) (b) {2}

(b) (Y) is Ph (c) [ 2,  ) (d) None of these

CH CH3
Br n
58.  r.((r)!) is equal to
r 1
(c) W is
(a) n! – 1
(b) (n – 1)! – 1
(d) M is (c) (n + 1)! – 1
(d) None of these
59. H1 is the H.M. and G1 is the G.M. of positive real
MATHEMATICS (SECTION C) numbers 'a' and 'b'. If H1 : G1 = 4 : 5 then a : b is
(a) 5 : 4 (b) 1 : 4
1
51.  tan xdx is equal to (c) 1 : 5 (d) None of these

(a) (x  1) tan1 x  x  C (i)

60. If Z  (i)(i) , where i  1, then |z| is equal to
(b) x.tan1 x  x  C
(a) 1 (b) e  / 2
1
(c) x  x tan x C
(c) e  (d) None of these
1
(d) x  (x  1) tan x C
6 MOCK TEST 12
61. The set of all values of a for which the function 66. The exhaustive set of values of 'a' such that x2 + ax
+ sin–1(x2 – 4x + 5) + cos–1(x2 – 4x + 5) = 0 has
 a4  5
f  x    1 x  3x  log5 decreases for all atleast one solution is
 1 a  
  
(a)  2   (b)  ,  2  
real x is  4   4

 5  27      
(a)  3,   2,   (c)  ,  2   (d)  2  ,  
 2   4   4 
67. In acute angled triangle ABC, r = r2 + r3 – r1 and
 3  21   ac
B 
  1,  
(b)  4, , then exhaustive range of is (r1, r2,
2  3 b
 r1, r and s have usual meanings)
(c)  ,   1   1 1
(a)  , 1 (b)  , 
2   4 2
(d) 1,  
1  1 
(c)  , 1 (d)  , 1
2
x 1  4  3 
62. If I   x4
dx , then I equals
68. The side of a triangle ABC are in A.P. (order being a,
2! 2! 1 8a
     , then the
32
2 b, c) and satisfy,
1 x 1
 
1 2 1!9! 3!7! 5!5! (2b)!
(a)  C 3 2
(b) x x  1 C value of cosA + cosB is
3 x3
12 13
1 x 
2
32 (a) (b)
x 12 1 7 7
(c) C (d)  C
x2 3 x2 11 10
(c) (d)
7 7
 3x 2  3x   x  1 cos  x  1  dx , then
0
2  x
3
63. If I  69. The combined equation of straight lines that can be
I equals obtained by reflecting the lines y = |x – 2| in the
y-axis, is
(a) –4 (b) –3
(a) y2 + x2 + 4x + 4 = 0 (b) y2 + x2 – 4x + 4 = 0
(c) –2 (d) –1
(c) y2 – x2 + 4x – 4 = 0 (d) y2 – x2 – 4x – 4 = 0
dy 3x  4y  2 70. Tangent drawn to x2 + y2 = 25 at the point P(3, 4)
64. The solution of the equation  is
dx 3x  4y  3 meets the circle x2 + y2 = 81 at the points A and B.
If the tangents drawn to x2 + y2 = 81 at the points A
and B intersect at C, then co-ordinates of 'C' is
(a)  x  y 2  C  log  3x  4  1
 243 81   243 81 
(b) x  y  C  log  3x  4y  4 (a)  ,  (b)  , 
 25 25   25 5 
(c) x  y  C  log  3x  4y  3
 243 81 
(c)  ,  (d) None of these
(d) x  y  C  log  3x  4y  1  5 25 

65. If p, q, r are three mutually perpendicular vectors  x cos3 x  sin x 

e
sin x
71.   dx is equal to
of the same magnitude and if a vector x satisfies  cos2 x 
the equation
p    x  q  p   q    x  r   q  r    x  p   r   0 ,
(a) esin x  tan x  x   C

then vector the x is (b) esin x  x  sec x   C

(a) 1 2  p  q  2r  (b) 1 2  p  q  r 
(c) esin x  sec x  tan x   C
(c) 1 3  p  q  r  (d) 1 3  2p  q  r  (d) none of these
 MOCK TEST 12 7

72. The area of a smaller portion enclosed by the curves

74. Let f be a function such that f  x  y   f  x   f  y 
x2 + y2 = 9 and y2 = 8x is

2 9 9

 1
 sin1  
 
for all x and y and f  x   2x 2  3x g  x  for all x
(a)
3 4 2 3
where g(x) is continuous and g(0) = 9 then f '  x  is
 2 9 9 1  1   ____________
(b) 2    sin   
 3 4 2  3   75. Let f : R  R be given by
 2 9 9 1  1  
(c) 2    sin     x   x  ,When  x  is odd
 3 4 2  3  
 f(x)   W here [.]
 x   x   1,When  x  is even
2 9 9  1
(d)   sin1  
3 4 2 3 4
denotes the greatest integer function, then  f  x dx
 f y x  4
73. Solution of the equation xdy   y  x  dx

 f '  y x   is equal to____________
x y
(a) f    cy (b) f    cx
y x

y y
(c) f    cxy (d) f    0
x x

ANSWERS
1. (a) 2. (275) 3. (c) 4. (b) 5. (b) 6. (90V) 7. (b) 8. (a) 9. (b) 10. (4)
11. (b) 12. (b) 13. (1 ms) 14. (d) 15. (c) 16. (a) 17. (a) 18. (d) 19. (a) 20. (d)
21. (a) 22. (c) 23. (a) 24. (a) 25. (2) 26. (a) 27. (a) 28. (d) 29. (c) 30. (b)
31. (4.70) 32. (56 g) 33. (a) 34. (a) 35. (c) 36. (d) 37. (b) 38. (b) 39. (101 pm) 40. (b)
41. (a) 42. (a) 43. (152 mm Hg) 44. (a) 45. (b) 46. (b) 47. (5) 48. (a) 49. (c)
50. (b) 51. (a) 52. (2) 53. (1) 54. (8) 55. (b) 56. (d) 57. (b) 58. (c) 59. (b)
60. (a) 61. (b) 62. (a) 63. (a) 64. (d) 65. (b) 66. (a) 67. (d) 68. (a) 69. (d)
70. (a) 71. (b) 72. (b) 73. (b) 74. (27) 75. (4)
8 MOCK TEST 12

EXPLANATIONS
1. Impedance decreases.
2. P = I2R 16. i.e., 1  RZ2  12  12 
 n m 

3. F   du where, R is Rydberg constant and Z is atomic

dr number.
  E = Energy exchanged between states × me
4. log  N   t .
N
 
1   1 1 
5. N 
N  N
.  2 RZ 2  2  2    2R(1)2 1  1   3R
    1 4 
N  n1 n2     2

6.
Veff  VR2  VC2
  2
Q 3R
7. C
T 17. At equator g = g – 2R
1 2
8. Work done by electric field = 2
mv  d
At depth, d on the pole g = g 1  
9. The mirror reflects the ray coming from the lens. R  
raser Both should be equal, then
10. For T.I.R, sin  
 denser
g  g
11. C1  4 0 R1
 RR   2R   d
C2  4  0  1 2   nC1 g 1    g 1  
 g   R
 R2  R1  
R2 n
  2R2
R1 n  1 So, the value of d = g
Magnetic momentum q 2
12. Angular momentum  2m  2m 18. So, every one must understand the relation between
V and E.
e nh neh
 Magnetic moment   
2m 2 4m V
E
Vmax 6 r
13. R   3
imax 2 Two cases are possible
L = 3mH Case-1
  L R  1ms

14. A ·B  A B E
A B
2 cm
A B A B A·B A ·B A B
0 0 1 1 1 0 0
1 0 0 1 0 1 1
0 1 1 0 0 1 1 For this case, E  20V along A  B
1 1 0 0 0 1 1 cm

u Case-2
15.

° C
60
30°
A C E
r x B
u
uH  ucos 60  A Ex x
2

ut
AC 
2
In this case r < x, so Ex < E
AC ut 2 ut
AB   
cos 30 3 2 3  E  20V .
cm
 MOCK TEST 12 9
19. Consider a small strip of width dx at a separation x
31. CH3COOH  NaOH  CH3COONa  H2O
from the left as figure (b).
Millimoles t  0 5 2.5 0 0
This strip form a small capacitor of plate area xdx. Millimoles t  t  2.5 0 2.5
Its capacitance is
Here, millimoles of CH3COOH and CH3COONa are
(K  x)0adx same.
dC  0
d
Together they constitute acidic buffer and for acidic
The given capacitor may be divided into such strips buffer
with x varying from 0 to a.
[salt]
All these strips are connected in parallel. The pH  pKa  log
[acid]
capacitance of the given capacitor is,
because [salt] = [acid], so
a
(K  ax)0adx  a2  a  pH = pKa
C 0  0 K 0 
d d  2 
0 pH = – log 2 × 10–5
20. Consider rigid body oscillates about O. Torques due pH = 4.7
to gravity   mgL sin  33. CuF2(d9, Cu2+) is coloured and paramagnetic
For small  K3[Cu(CN)4] is colourless; Cu+, d10, diamagnetic
  (mgL) K2[TiCl6] is colourless; Ti+4, d0, diamagnetic
K2CrO4 is yellow; Cr+6, d0, diamagnetic. It is coloured
O
due to charge transfer.
 4 3
34. MnO2 Mn2O3


In the above reaction change in the oxidation state
is 1. Hence the equivalent weight of MnO2 is the
mg same as its molecular weight.
So, time period Molecular weight
Equivalent weight 
Number of electrons transferred
I0
T  2
mgL Molecular weight
= 1
where, I0 is moment of inertia about O
I0 = ICOM + mL2 35. [Zn(H2O)6]2+:
= mK2 + mL2 3d 4s 4p 4d
x x x x x x

K2 [Cr(H2O)6]2+:
L
T  2 L x x x x x x
g
[Mn(H2O)6] : 2+

2 x x x x x x
So, Leq  K L
L [Cu(H2O)6] : 2+

d di x x x x x x
21. Use     M
dt dt
36. F
22. Conceptual. Refer “Communication System” from
NCERT book. Cl F
23. Conceptual F
24. As VL & VC are having a phase difference of 180°. 37. K2Cr2O7 + 4 NaCl + 6H2SO4  2KHSO4 + CrO2Cl2
25. 2Tshort  Tlong + 4NaHSO4
(Chromyl chloride test)
26. 2MnO2 + 2KOH + O2  2K2MnO4 + 2H2O.
27. Octahederal complex of type (MA5B) do not show a
39. rNa  rCl  r   282  181  101 pm
geometrical isomerism. 2 Na

28. ZnO turns yellow on heating but becomes white on 40. Rb+ is large cation
cooling. Be2+ is smaller cation
10 MOCK TEST 12
41. The rate constant of a reaction depends only on
c c   c c 
temperature and does not depend on the   2  3  c 4    c1  2  3  cos 2x = A + B cos2x
 2 2   2 2 
concentration of the reactants. It increases with
increase in temperature. That means there are two effective parameters. Thus
the order of differential equation will be 2.
42.  P  a2  V  RT
 V  x2
53. At point A,  x  ax 2
a PV a a
PV   RT ;  1
V RT VRT
2
ay = x
a
Z  1
VRT
P  V 760  2000 A
43. pSO2    152 mm Hg
VTotal 10,000

44. [SO24  ]  0.01 mol L–1; O

2
K sp  [Pb ][SO24 ]
y = x – ax2
9
1.25  10
or [Pb2  ]  K sp /[SO 24 ]   x = 0, x  a
0.01
1  a2
46. K2Cr2O7 + 14HCl  2KCl + 2CrCl3 + 3Cl2 + 7H2O
a /1 a2 
6 3 x2 
Area bounded,   
2
n-factor of HCl    x  ax   dx
14 7 0  a 

CH 2 Br CH 3 CH 3
Br a /1 a2 
Br d x2  d  a 
 
2
   x  2  dx  0.  
47. (i) (ii) (iii) da 0  a  da  1  a2 

CH 3 CH 3 a /1 a2
(1  a2 ) a(1  a2 ) a(1  a)(1  a)
= x3  
3a 2
3(1  a2 )3 (1  a2 )3
(iv) (v) 0

Br
Br  d  0  a  (0, 1) and, d  0  a  (1, )
da da
48. G  0.059logk  nFE0cell
Thus, a = 1 is the point of maxima for .
 k  1, G  0
54. f(x) = 3 + [4 sinx].
1 127 Clearly, f(x) is non-differentiable at all these points
49. BaCl2   Ba2  Cl   76
2 2 where g(x) = [4 sinx] is non-differentiable.
= 139.5 ohm–1 cm–1 eq–1. In [, 2] g(x) is clearly non-differentiable at eight
points. It should be noted that g(x) is differentiable
51. I   tan1 xdx
at x = 3 .
1 1 1 x 2
 x.tan1 x  . .x dx  x.tan1 x   dx
1 x 2 x 2 1 x
 2
x
1
Now putting x t i.e., dx  dt –1
2 x
–2 y = [4 sinx]
 dx = 2t dt, we get I  x.tan1 x  1  t 2 2t dt
2 1 t –3

t2  1  1 –4
1
 x.tan1 x   dt  x.tan x  t  tan1 t  C
2
1 t
55.  x 2  1    x 2  1  1  1   x 2  1  .
1 1  2  2   2
 x.tan x  x  tan x C
52. y = c1 cos2x + c2 cos2x + c3 sin2x + c4, Thus for domain point of view.
 2 1
 c1 cos 2x 
c2 c
(1  cos2x)  3 (1  cos 2x)  c 4  x  2   0, 1   x 2  1   1, 0
2 2    2
 MOCK TEST 12 11

 f(x) = sin–1(1) + cos–1(0) For f(x) to be decreasing for all x, we must have
or sin–1(0) + cos–1(–1) f’(x) < 0 for all x.
 f(x) = {}
 a4  4 3
56. x2 – ax + a = 0   1  a  1 x  5 x
 
 D = a2 – 4a  0
 a  ( , 0]  [4, ) This is possible only if
a4
 1 0
1 a
Both roots are greater than 2, if f(2) > 0
 a  ( , 4) This inequality is always true if a > 1, i.e. a  1,  .
Moreover, we must have a  4 for a4 to be real.
and a  2,
2 a4
Therefore, we have  1  a  4  1  a [ we
 a > 4. 1 a

Hence no such ‘a’ can be obtained. consider only a < 1]

57. x3 + ax + 1 = 0,  a  4  1  a2  2a  0  a2  3a  3
x4 + ax2 + 1 = 0 have a common root.
3  21
Clearly this common root can’t be equal to zero.  a
2
Multiplying first equation by x, we get x4 + ax2 + x = 0.
Solving it with second equation we get x = 1.  3  21
Thus a  4,   1, 
Thus x = 1 is the common root.  2 

1+a+1=0
62. Put x = tan  so that x 2  1  sec  , dx  sec 2 d
a=–2
58. r((r)!) = (r + 1 – 1) (r!) sec  sec 2  cos 
 I d   d
= (r + 1)! – r! tan4  sin4 

= V(r) – V(r – 1)
 
2 32
n 1 1 1 sec 3  1 x 1
       C
  r(r!)  V(n)  V(0) = (n + 1)! – 1 3 sin3 
C 3
3 tan 
C
3 x3
r 1

63. We can write

59. H1  2ab , G1  ab
ab
I    x 2  3x 2  3x   x  1 cos  x  1  dx
0

H1 2ab 2 ab 4 2 ab 2
    
G1 (a  b) ab a  b 5 a  b
Put x + 1 = t, so that
9 ( a  b )2 1 ( a  b )2
  ,  I
1
1  t
3
 1  t cos t  dt
5 ab 5 ab
2
 9  ( a  b )2 
1
 1 dt   t 11  2
( a  b) 1

a b
as t3 + t cos t is an odd function.
 3
a b
dy dX
64. Put 3x  4y  X  3  4 
 a:b=1:4 dx dx

i
(i)  dy 1  dX 
60. z  (i)(i)  (e 2)   3  
dx 4  dx 

 |z| = 1 Therefore the given equation is reduced to

61. Differentiating, we get
3 1 dX X  2
 
4 4 dx X  3
 a4 
f '  x    1 5x 4  3
 1 a  1 dX 4X  8  3  X  3
 
4 dx 4  X  3
12 MOCK TEST 12

(s  a)(s  c) a  c
X3  4   
  dX  dx    1   dX  dx s(s  b) b
X1  X  1
B ac
 tan2  .
  X  4log  X  1  x  cons tan t 2 b
B  
4log  3x  4y  1  x  3x  4y  cons tan t Since B    ,   , therefore  ,

3 2 2  6 4 

 log  3x  4y  1  x  y  C 
ac 1 
  , 1
b 3 
65. p   x  q   p    p · p  x  q    p ·  x  q  p 2! 2 1
68.  
1!9! 3!7! 5!5!
 p  x  q   p·x  p  p · q  0 2 10 2 10 1 10
 ( C1)  ( C3 )  ( C5 )
10! 10! 10!
Similarly, q   x  r   q  q  x  r    q · x  q
2
1 10
 ( C1  10 C9  10 C3  10 C7  10 C5 )
10!
and r   x  p   r   r  x  p    r · x  r
2

1 10 1 29 8a
 (2 )   (given).
without loss of generality we can assume that 10! 10! (2b)!
 3a = 9, 2b = 10
p  p ˆi,q  p ˆj r  p kˆ p  q  r 
 a = 3, b = 5
Therefore, L.H.S. of the given expression
Also a, b, c are in A.P.
2
3p x p
2
p  q  r   2
      
p  ˆi · x ˆi  ˆj · x ˆj  b · x kˆ 

 c = 7.

b2  c 2  a2 25  49  9 13
2
3p x p
2
p  q  r   2
p x cos A   
2bc 2.5.7 14
2
2p x p
2
p  q  r 
a2  c 2  b2 9  49  25 11
cosB   
This expression will be equal to 0 if 2ac 2.3.7 14

1 13  11 24 12
x p  q  r   cos A  cosB   
2 14 14 7

66. We must have 69. If we reflect y = |x – 2| in y-axis, it will become

y = |– x – 2| = |x + 2|
1  x2  4x  5  1
Hence, reflected lines are
If x 2  4x  5  1, then y = x + 2, y = – x – 2
x2  4x  4  0 Their combined equation is
(y – x – 2) (y + x + 2) = 0
 (x  2)2  0
 y2 – x2 – 4x – 4 = 0
 x=2 70. Equation of tangent at ‘P’ is
If x2 + 4x + 5  –1, then 3x + 4y = 25 ... (i)
x2 – 4x + 6  0 Let C be (h, k) then AB is chord of contact of ‘C’.
 x  R.
C(h, k)
Thus x = 2 is the only solution.
 
 4  2a   0, a    2 A
2 4
67. r = r2 + r3 – r1
P
   
   
s sb sc sa
1 1 1 1 B
   
s sb sc sa

b sasc c a
  
s(s  b) (s  c)(s  a) (s  c)(s  a)
x2 + y2 = 25 x2 + y2 = 81
 MOCK TEST 12 13

This equation of AB is,

73. We have, xdy   y     dx
 xf y x 
hx + ky = 81 ... (ii) 
 f '  y x  
(i) and (ii) are equations of same line
dy y f  y x 
   which is homogenous
h k 81 dx x f '  y x 
  
3 5 25
dy dv
Putting y  yx  vx ,
243 81 dx dx
 h ,k 
25 5
dv f v f ' v  dx
71. We have we obtain vx v  dv 
dx f ' v  f v x
 x cos3 x  sin x 
I   e sin x   dx Integrating, we get log f  v   log x  logc
 cos2 x 

y
  xe sin x cos xdx   esin x  sec x tan x  dx  logf  v   logcx  f    cx
x

  xesin x   esin x dx    esin x sec x   esin x dx 

    f  x  h  f  x  f  x   f h   f  x 
74. f '  x   lim  lim
h 0 h h0 h
 e sin x  x  sec x   C

 lim
 2h 2

 3h g  h 
 lim  2h  3  g  h 
h0
72. h0 h
(0, 3)

 3g  0   3.9  27

75.  f(x)  
O {x}, [x] is odd
(-3, 0) (3, 0)
1  {x}, [x]is even

(0, -3)  The graph of f(x) is

1
x 2  y 2  9 , x 2  8x  9  0

8  64  36 –4 –3 –2 –1 0 1 3
x 2 4
2

8  10 4 1
x  9, 1 x =1
2 

4

f(x)dx  8 f(x)dx  4
Area enclosed 0

 2   2 2xdx   9  x 2 dx   2  2 2  xdx   9  x 2 dx 
1 3 1 3

 0 1   0 1 

On simplifying we get

 2 9 9  1 
 2   sin1   
 3 4 2  3  
 MOCK TEST – 13

PHYSICS (SECTION – A)
1. A radioactive substance is being produced at a constant
mg mg
rate of 200 nuclei/s. The decay constant of the (a) (b)
substance is 1 s –1. After what time the number of r B  B
2
x
2
z rB z
radioactive nuclei will become 100. Initially there are mg mg
no nuclei present (c) (d)
rB x r B x B z
1 6. Equal volumes of two immiscible liquids of densities
(a) 1s (b) s
ln  2   and 2 are filled in a vessel as shown in figure.
(c) ln (2) s (d) 2 s h 3h
2. When an electron in the hydrogen atom in ground state Two small holes are punched at depth and
2 2
absorbs a photon of energy 12.1 eV, its angular from the surface of lighter liquid.
momentum:
(a) decreases by 2.11 × 10–34 J–s
(b) decreases by 1.055 × 10–34 J–s h  v1
(c) increases by 2.11 × 10 J–s
–34

(d) increases by 1.055 × 10–34 J–s

h 2 v2
3. A series circuit has an impedence of 50.0 and a power
factor of 0.63 at 60 Hz. The voltage lags the current. To
raise the power factor of the circuit: If v1 and v 2 are the velocities of efflux at these two
(a) an inductor should be placed in series v
holes, then 1 is:
(b) a capacitor should be placed in series v2
(c) a resistance should be placed in series 1
1
(d) an inductor or a resistance should be placed in (a) (b)
2 2 2
series
1 1
4. A conducting circular loop of radius 'a' and resistance (c) (d)
R is kept on a horizontal plane. A vertical time varying 4 2
magnetic field B = 2t is switched on at time t = 0. Then 7. A block is submerged in a vessel filled with water by
: a spring attached to the bottom of the vessel. In
(a) power generated in the coil at any time t is constant equilibrium the spring is compressed. The vessel
now moves
(b) flow of charge per unit time from any section of the
coil is constant
(c) total charge passed through any section between

 4a2 
time t = 0 to t = 2 is  R 
 
(d) all of the above
5. A rigid circular loop of radius r and mass m lies in the x-
y plane on a flat table and has a current i flowing in it. At downwards with an acceleration a (< g). The spring
this particular place, the earth’s magnetic field is length:
 (a) will become zero
B  B x i  Bz k.
 The value of i so that one edge of the
(b) may increase, decrease or remain constant
loop lifts from the table is: (c) will decrease
(d) will increase
2 MOCK TEST 13

8. The potential energy of a particle of mass 1 kg is, U = 13. In the circuit shown find the charge stored in the 5F
10 + (x – 2)2. Here, U is in joule and x in metres. On
capacitor.
the positive x-axis particle travels upto x = + 6 m.
Choose the wrong statement:
2F 2F 3F 5F 3F 4F
(a) On negative x-axis particle travels upto x = – 2m
(b) The maximum kinetic energy of the particle is 16 J
(c) The period of oscillation of the particle
is 2 seconds
(d) None of the above 100V
9. Frequency of a particle executing SHM is 10 Hz. The
(a) 60 C (b) 20 C
particle is suspended from a vertical spring. At the
highest point of its oscillation the spring is (c) 30 C (d) zero
unstretched. Maximum speed of the particle is : (g =
14. Photons with energy 5eV are incident on a cathode
10 m /s2)
C on a photoelectric cell. The maximum energy of
(a) 2 m / s (b)  m / s the emitted photoelectrons is 2 eV. When photons of
energy 6 eV are incident on C, no photoelectrons
1 1 willl reach the anode A if the stopping potential of A
(c) m/s (d) m/s
 2 relative to C is
10. A satellite S is moving in an elliptical orbit around the (a) –3 V (b) 3 V
earth. The mass of the satellite is very small (c) –1 V (d) 4 V
compared to the mass of the earth: 15. The modulating frequency is 5 kHz and the carrier
(a) the acceleration of S always directed towards the frequency is 100 kHz. What is the bandwidth of AM
centre of the earth transmission___________ (kHz)
(b) the angular momentum of S about the centre of 16. Two coils A and B have coefficient of mutual
the earth changes in direction, but its magnitude inductance M = 2H. The magnetic flux passing
remains constant through coil A changes by 4 Wb in 10 s due to the
(c) the total mechanical energy of S varies change in current in B. Then:
periodically with time (a) change in current in B in this time interval is 0.5 A
(d) the linear momentum of S remains constant in (b) the change in current in B in this time interval is 2
magnitude A
11. An ideal gas    1.5  is expanded adiabatically.. (c) the change in current in B in this time interval is 8
A
How many times has the gas to be expanded to
(d) a change in current of 1A in coil A will produce a
reduce the root mean square velocity of molecules
change in flux passing through B by 4 Wb
two times?
17. The horizontal range and maximum height attained
(a) 4 times (b) 16 times
by a projectile are R and H respectively. If a constant
(c) 8 times (d) 2 times
12. An impulse J is applied on a ring of mass m along a g
horizontal acceleration a  is imparted to the
line passing through its centre O. The ring is placed 4
on a rough horizontal surface. The linear velocity of projectile due to wind, then its horiztontal range and
centre of ring once it starts rolling without slipping is maximum height will be:

O H  H
J (a) (R  H), (b)  R   , 2H
2 2
J J (c) (R  2H), H (d) (R  H), H
(a) (b)
m 2m
18. A 1.5 kg block is initially at rest on a horizontal
J J frictionless surface when a horizontal force in the
(c) (d) positive direction of x-axis is applied to the block.
4m 3m
 MOCK TEST 13 3
24. In the fission reaction of 92U there is a mass defect
235

 

2 ˆi N, where x is in of 0.7 u (a.m.u)___________(kg) uranium fuel will be
The force is given by F  4 – X
needed by a nuclear plant having capacity of
metre and the initial position of the block is 100 MW in a month of 30 days.
x = 0. The maximum kinetic energy of the block 25. When two tuning forks (fork 1 and fork 2) are sounded
between x = 0 and x = 2.0 m is : simultaneously, 4 beats per second are heard. Now,
(a) 2.33 J (b) 8.67 J some tape is attached on the prong of the fork 2.
(c) 5.33 J (d) 6.67 J When the tuning forks are sounded again, 6 beats
per second are heard. If the frequency of fork 1 is
d 200 Hz, then ___________(Hz) Was the original fre-
19. In Young’s double slit experiment =  10 4 (d =
D quency of fork 2.
distance between slits, D = distance of screen from
the slits). At a point P on the screen resulting intensity CHEMISTRY (SECTION – B)
is equal to the intensity due to individual slit I0. Then
the distance of point P from the central maximum is 26. Which one of the following has S° greater than
zero?
: (   6000Å)


(a) CaO(s) + CO 2(g) 
 CaCO3(s)
(a) 2 mm (b) 1 mm
(c) 0.5 mm (d) 4 mm 

(b) NaCl(aq) 
 NaCl(s)
20. An AC source producing emf V = V0 [sin  t + sin


 Na+(aq) + NO3 (aq)
(c) NaNO 3(s) 
2  t] is connected in series with a capacitor and a
resistor. The current found in the circuit is i = i1 sin 

(d) N2(g) + 3H2(g) 
 2NH3(g)
(  t + 1 ) + i2sin(2  t + 2 ). Then:
27. If the heat of neutralisation for a strong acid-base
(a) i1 = i2 reaction is -57.1 kJ/mole ___________(kJ) would
(b) i1 < i2 be the heat released when 350 cm3 of 0.20 M H2SO4
(c) i1 > i2 is mixed with 650 cm 3 of 0.10 M NaOH.
(d) i1 may be less than, equal to or greater than i2 28. The vapour density of N2O4 at a certain temperature
21. Two bodies of masses m1 and m2 are initially at rest is 30. What is the percentage dissociation of N 2O4
at infinite distance apart. They are then allowed to at this temperature?
move towards each other under mutual gravitational (a) 53.3% (b) 106.6%
attraction. Their relative velocity of approach at a (c) 26.7% (d) None
seperation distance r is 29. Both HCOOH and CH3COOH solutions have equal
K1
 m1  m2  
12
  2G
12

m1  m2 
pH. If (ratio of acid ionisation constants) of
(a) 2G  (b)  K2
 r   r 
these acids is 4, their molar concentration ratio
12
will be___________
 r   2G 
12
30. The values of van der Waal's constant 'a' for the
(c)   (d)  m1m2 
 2G  m1m2    r  gases O2, N2, NH3 and CH4 are 1.360, 1.390, 4.170
and 2.253 L atm.mol–2 respectively. The gas which
22. A person is running towards a large concave mirror can most easily be liquefied is
of radius of curvature 10 m. At some point of time (a) O2 (b) N2
he is 30 m away from the mirror and is running with
(c) NH3 (d) CH4
1 m/s. ___________(m/s) will be the relative velocity
of his image with respect to him. 31. On the basis of the information available for the
23. A vessel contains two immsicible transperent liquids 4 2
reaction Al  O2 
 Al2O3 , G = – 827 kJ
of refractive index 1.5 and 1.2 respectively they are 3 3
having depths of 1.5 and 1.2 respectively they are mol–1 of the minimum e.m.f. required to carry out
having depths of 15 cm and 12 cm respectively. electrolysis of Al2O3 is___________.
___________(cm) will be the apparent depth of the (F = 96500 C mol–1)
bottom of the vessel on seeing it from above.
4 MOCK TEST 13

32. For the redox reaction, Zn(s) + Cu2+(0.1 M) 

x
40. Graph between log   vs log p is provided for ab-
Zn2+(1 M) + Cu(s) taking place in a cell, Ecell is m
1.10 volt. Ecell for the cell will be___________(volt) sorption of NH3 gas on metal surface. Calculate
 RT  weight of NH3 gas absorbed by 50 gm of metal sur-
 2.303 F  0.0591 face of 2 atm pressure___________(gm)
 
33. Adsorption is accompanied by
(a) decrease in enthalpy and increase in entropy
(b) increase in enthalpy and increase in entropy
log(x/m) 45°
(c) decrease in enthalpy and decrease in entropy A
(d) no change in enthalpy and entropy 0.3

34. During transformation of a

c X to b
d Y by  and - O log p
decay, the number of -particles emitted are
41. The equilibrium constant for the reversible reaction,
ab ab
(a) (b) d  c N + 3H   2NH is K and for the reaction
4 2 2 2 3

a  b  1 3
 
(c) d   c (d) 2c – d + a – b N2  H2   NH3 , the equilibrium constant is K'.
 2  2 2
35. For a zero order reaction, a plot of rate (along Y- K and K' will be related as
axis) and concentration (along X-axis) is (a) K = K' (b) K   K
(a) a rectangular parabola
(b) a line with –ve slope and zero Y-intercept (c) K  K  (d) K × K' = 1
(c) a line with +ve slope and a non-zero Y-intercept 42. Which of these series of elements listed would have
(d) a line with zero slope and a positive Y-intercept nearly the same atomic radii?
36. 50% neutralisation of solution of formic acid (Ka = 2 (a) Fe, Co, Ni (b) Na, K, Rb
× 10-4) with NaOH would result in a solution having (c) F, Cl, Br (d) Li, Be, B
hydrogen ion concentration of 43. Which is a pair of geometrical isomers
(a) 2 × 10-4 (b) 3.7 Cl CH2CH3
(c) 2.7 (d) 1.85 I. C=C
37. H Br

4r 2 r2

r
This radial probability distribution graph can
represent the orbital
(a) 5s (b) 5d
(c) 4p (d) 6d (a) I and II (b) I and III
38. Which of the following molecule or ion has highest (c) II and IV (d) III and IV
number of total electrons in antibonding molecular 44. Which is the decreasing order of strength of bases:
orbitals
OH , NH2 , HC  C  and CH3 CH2 ?
(a) O2 (b) N2
2 (a) CH3 CH2  NH2  HC  C   OH
(c) N2 (d) O2
39. Which of the following combination of gases is most (b) OH  NH2  HC  C   CH3 CH2
easiest to separate
(c) OH  NH2  CH3 CH2  HC  C 
(a) H2 and He (b) CO 2 and N2O
235 238
(c) U F6 and U F6 (d) C3H8 and C3H6 (d) NH2  HC  C   OH  CH3 CH2
 MOCK TEST 13 5
45. The reaction of propane with HOCl proceeds via the MATHEMATICS (SECTION – C)
addition of
(a) H+ in the first step 51. If n  N > 1, then sum of real part of roots of
(b) Cl+ in the first step zn = (z + 1)n is equal to
(c) OH– in the first step
n n  1
(d) Cl+ and OH– in a single step (a) (b)
2 2
46. Which of the following is a condensation homopolyme
(a) Nylon-6,6 n 1  n
(b) Nylon-6 (c)  (d)
2 2
(c) Nylon-6,10 52. Total number of positive integral solutions of
(d) Da cron
x 1 + x 2 + x 3 = 24 and x 21  x 22  x 32 is equal
47. At a particular temperature, the vapour pressures of
the two ligands A and B are respectively. 120 mm to___________
and 180 mm of mercury. If 2 moles of A and 3 moles 53. If S(n) denotes the sum of first ‘n’ term of certain A.P.
of B are mixed to form an ideal solution. The mole with common difference equal to 5, then
fraction of B in vapour phase will be
S  3n 
(a) 4/13
S  2n   S  n  is always equal to___________
(b) 2/5
(c) 9/13 54. The number of divisors of 9600 including 1 and 9600
(d) None of these are ___________
48. Which type of linkage is present in starch ? n

(a) C1-C4 glucosidic linkage 55. r 

r 1
n

Cr  nCr 1 is equal to

(b) C1-C6 glucosidic linkage

(a) 2n + n + 1
(c) Both (a) and (b)
(b) 2n – n + 1
(d) amide linkage
(c) n – 2n + 1
49. The correct statement related to IUPAC nomencla-
(d) n – 2n – 1
ture is
56. A real valued function f(x) satisfies the functional
(a) If 2 or more chains of equal length are seen in the
equation f(x – y) = f(x) f(y) – f(a – x) f(a + y) where a
compound then the chain with minimum number
is a given constant and f(0) = 1, f(2a – x) is equal to
of side chain is preferred.
(a) f(–x) (b) f(a) + f(a – x)
(b) If double and triple bonds are at symmetrical
positions in a compound then triple bond gets (c) f(x) (d) –f(x)
lower preference. x
 1 1
(c) Correct IUPAC name of CH3COC2H5 is ethylmethyl 57. lim  sin  cos  is
ketone.
x 
 x x

(d) As far as possible, the IUPAC name of a (a) e (b) e2

compound is written as a single word.
1
(c) (d) does not exist
e
(B) H H (A)
¯OH 58. Let f : R  R be a function such that
50. R CH C CH2
slow  x  y  f(x)  f(y)
O
f  , f(0) = 0 and f(0) = 3, then
 3  3
which is correct?
f(x)
(a) A is more reactive than B (a) is not differentiable in R
x
(b) B is more reactive than A (b) f(x) is continuous but not differentiable in R
(c) both are of same reactivity (c) f(x) is continuous in R
(d) H can't release (d) f(x) is bounded in R
6 MOCK TEST 13

dy 67. The number log27 is

59. If y = sin–1  x 1  x  x 1  x 2  and
  dx (a) an integer (b) a rational number
(c) an irrational number (d) a prime number
1
=  p, then p =
2 x(1  x) 68. If ,  be the roots of 4x2 – 16x +  = 0, where
1   R such that 1 <  < 2 and 2 <  < 3, then the
(a) 0 (b)
1 x
number of integral solutions of  is___________
–1 1
(c) sin x (d) 69. The least value of expression x2 + 2xy + 2y2 + 4y + 7 is
1  x2 (a) –1 (b) 1
60. f(x) = 1 + 2x2 + 4x4 + 6x6 + ............... + 100x100 is (c) 3 (d) 7
polynomial in a real variable x, the f(x) has
70. The value of a for which the sum of the squares of the
(a) neither a maximum nor a minimum roots of the equation x2 – (a – 2)x – a – 1 = 0 assume
(b) only one maximum the least value is
(c) only one minimum (a) 2 (b) 3
(d) one maximum and one minimum (c) 0 (d) 1
1

2
61. dx  71. Point A lie on the curve y  e  x and has the
sin x  cos4 x
4

1  tan2 x  1 
tan1  c
coordinates  x,e  where x > 0. Point B has
x 2

(a)
2  tan x  coordinates (x, 0). If 'O' is the origin then the
 
maximum area of the triangle AOB is
 2
1 tan x  1
 1 1
(b) tan    c
(a) (b)
 2 tan x  2e 4e
1  tan2 x  1  1 1
tan1  c
(c)
2  2 tan x  (c)
e
(d)
8e
 
1  tan2 x  1  72. If f  x   4x3  x 2  2x  1 and
1
tan  c
(d)
2  2 tan x  min f  t  : 0  t  x; 0  x  1
  g x  
62. If A = {a, b, c, d} and B = {1, 2, 3}, then the number of  3  x ; 1 x  2
on-to function possible from A to B satisfying f(a) = 1 is Then, g 1 4   g  3 4   g  5 4  
(a) 8 (b) 10 7 9
(a) (b)
(c) 12 (d) 16 4 4
63. The value of ‘a’ if the line 3x + 4y + a = 0 is a tangent 13 5
(c) (d)
to the circle x2 + y2 – 4x + 6y + 9 = 0 is 4 2
(a) 4 (b) –16 73. The line which is parallel to x-axis and

5 crosses the curve y  x at angle of is
(c) 16 (d) 4
2
1 1
64. If eccentricity of a given hyperbola is 3/2, then then (a) y  (b) x 
2 2
eccentricity of its conjugate hyperbola is
1 1
4 (c) y  (d) y 
(a) (b) 3 4 2
3 74. Number of solutions of the equation 3 tanx + x 3
3  
(c) (d) 2 = 2 in  0,  is
5  4
65. If the equation of a given hyperbola is xy – 3x + 4y – (a) 0 (b) 1
6 = 0, then the equation of its conjugate hyperbola is (c) 2 (d) 3
(a) xy – 3x + 4y – 18 = 0(b) xy – 3x + 4y = 0
75. xdy  ydx  y 2 dy, y  0 and y(1) = 1 then (–3) =
(c) xy – 3x + 4y + 6 = 0 (d) xy – 3y + 4y –12 = 0
(a) 2 (b) 3
66. The number of real roots of the equation |x|2 – 3|x| + 2
(c) 4 (d) 5
= 0 is___________
 MOCK TEST 13 7

ANSWERS
1. (c) 2. (c) 3. (d) 4. (d) 5. (c) 6. (d) 7. (d) 8. (d) 9. (d) 10. (a)
11. (b) 12. (b) 13. (d) 14. (a) 15. (10 kHz) 16. (b) 17. (d) 18. (c) 19. (a)
20. (b) 21. (b) 22. (1.04 m/s) 23. (20 cm) 24. (115 kg) 25. (196 Hz)
26. (c) 27. (3.71 kJ) 28. (a) 29. (0.25) 30. (c) 31. (2.14 V)
32. (1.07 volt) 33. (c) 34. (c) 35. (d) 36. (a) 37. (d) 38. (d) 39. (a) 40. (200 gm)
41. (b) 42. (a) 43. (c) 44. (a) 45. (b) 46. (b) 47. (c) 48. (c) 49. (d) 50. (a)
51. (d) 52. (2) 53. (3) 54. (48) 55. (c) 56. (d) 57. (a) 58. (c) 59. (d) 60. (c)
61. (d) 62. (c) 63. (c) 64. (c) 65. (a) 66. (4) 67. (c) 68. (3) 69. (c) 70. (d)
71. (d) 72. (d) 73. (d) 74. (b) 75. (b)

EXPLANATIONS
1. Let N be the number of nuclei at any time t. dB
Then 4. e = (a2) dt =(a2)(2);  Induced emf e = 2a2

 Induced current or flow of charge per unit time

N t

  dt
dN dN
 200  N ;   or
dt 200  N through any section of the coil is
0 0

N
200


1  e t  i
e
or
 2a 2
i  

 = constant
R  R 
Given that N = 100 and  = 1s–1
t  1  Charge passed through any section between
 100 = 200(1 – e–t) or e   2  ;  t = 1n (2) sec. t = 0 and t = 2s is
 
2. After absorbing a photon of energy 12.1 eV  2a2   4 a 2 
electron jumps from ground state (n = 1) to q  it     2  or q   
 R   R 
second excited state (n = 3). Therefore change
in angular momentum Further P = i2R = constant (as i is constant)
 h  h h 5. The torque on the loop must be equal to the
L = L3 – L1  3  2   2   gravitational torque exerted about an axis tangent to
 
the loop.
6.6  10 34
 Js = 2.11 × 10–34 J-s The gravitational torque:
3.14
3. Voltage lags the current. 1 = mgr ...(1)
Hence, XC > XL Only Bx, causes a torque. Therefore torque to the
Further magnetic field
 
cos  
R

R

1 2 | M  B | = MB sin 90° = r2iBx ...(2)
Z
 
2 2
R  XC  XL
2
 X  XL 
1   C  mg
 R  Eqs. (1) and (2), we get, i
rB x
To raise the power factor, the denominater
should decrease. For this either R should
increase or XC – XL should decrease. If a h
6. v1  2g  2   gh
resistance is added in series, the denominater  
1 From Bernoulli’s theorem
will decrease. X C – X L or  L can be
C
decreased either by increasing C or L. If we h 1
gh  2g     2  v 22
put a capacitor in series the equivalent 2 2
 C1C2 
capacitance    of the circuit will v1 1
 C1  C2   v 2  2gh ;  
v2 2
decrease. Hence, either a resistance or an
inductor should be put in series to raise the
power factor.
8 MOCK TEST 13

7. When the vessel was at rest. Equilibrium of block m 1

 
gives Weight = kx + upthrust k 400 2
or W = kx + F  (i) Therefore, the maximum speed of particle will be:
As the spring moves downwards with acceleration  g  1
vmax  A   2
 20   m / s
a(<g) upthrust is reduced.  400   2 

Not let x be the new compression. Then 10. Force on satellite is always towards earth, therefore,
W – kx – F = ma acceleration of satellite S is always directed towards
centre of the earth. Net torque of this gravitational
or W  kx   g  a  F  W a force F about centre of earth is zero. Therefore,
 g  g
angular momentum (both in magnitude and direction)
a a of S about centre of earth is constant throughout.
or  W  F   kx  F  W
g g Since, the force F is conservative in nature, therefore
or kx  kx  a F  W a mechanical energy of satellite remains constant.
g g Speed of S is maximum when it is nearest to earth
and minimum when it is farthest.
or x  x  F  W  a
gx
kx upthrust = F kx F 11. Vrms  3RT
M
V1
if V2  then T2  T1
2 4
a
also, T1V1 1  T2 V2 1

T1
T1 V1  V2
Weight = W W 4
Now since, V2  16V1
F<W
12. V = J/m
x < x
By coservation of L about point of contact
Therefore, length of spring will increase.
mvr = mvr + I
8. U(6 m) = 10 + (6 – 2)2 = 26 J
U(–2 m) = 10 + (– 2 – 2)2 = 26 J mvr  mv 'r  mr 2   vr '
As U(6 m) = U(– 2 m), mvr  2mv 'r
On negative x-axis particle travels upto J
v'  v 2 
x=–2m 2m
Mean position of the particle is x = 2 m 13. 5F capacitor is short circuited, hence zero charge
U(2 m) = 10 J
14. K max  hc  
 K(2 m) = (26 – 10)J = 16J = Kmax 
Put x – 2 = X 2eV  5eV  
U = 10 + X2
  3eV
dU
F  2X Now, Kmax  6eV  3eV  3eV
dX
F  V0  3V
a  2X (m = 1 kg)
m
15. Bandwidth = 5 + 5 = 10 kHz
2
 2 
T 16.   Mi
 T  2 d 4
 d  M(di) or (di)    2A
mg M 2
9. Mean position of the particle is distance below
k Further d  M(di) = (2) (1) = 2Wb
the unstretched position of spring. Therefore,
2uy u2y
amplitude of oscillation is 17. T ,H  and R = uxT
g 2g
mg
A where, T = time of flight of the projectile and ux and uy
k
are respectively the horizontal and vertical
k
  2f  20 (f = 10 Hz) components of initial velocity.
m
 MOCK TEST 13 9
When a horizontal acceleration is also given to the 22. The mirror formula is
projectile uy and hence T and H will remain un- 1 1 1
 
changed while the range will become v u f
 2 Differentiating it with respect to time, we have
1 2  R  1  g   4uy 
R  ux T  aT    2  =R+H 1 dv 1 du
2 2 4  g    0
v 2 dt u2 dt
18. From work-energy theorem kinetic energy of block at
u2 du dt
x = x is;   ...(i)
v2 dv dt
3
x x u = –30, f = –5m, v = ?
K   (4  x 2 ).dx or K  4x 
0 3
1 1 1
dK  
For K to be maximum 0 v 30 5
dx
1 1 1 1 6
or 4 – x2 = 0 or x =  2m    
v 30 5 30
At x = +2m is negative 30
v  6
i.e., kinetic energy (K) is maximum. 5
(2)3 16 Putting it in Eq. (i)
Kmax = (4)(2) –  J  5.33 J
3 3 30  30 1
 
2   2   66 x
19. I  4I0 cos   ; I0  4I0 cos  
 2  2
66 1
x   0.04 m / s
  1   30  30 25
 cos  2   2 or 
2 3 Velocity of image = 0.04 m/s in opposite
1  1 d  yd  direction, so relative velocity = 1 + 0.04
or    y.  x  
3   D D = 1.04 m/s
 6  107 23. For the lower layer of liquid,
 y  = 2 × 10–3 m = 2 mm
3
d 3  104
D
V0 V0 12 cm 1.2 (x)
20. i1  and i2 
Z1 Z2
15 cm 1.5 (y)
2 2
 1 
2  1 
2
Here, Z1  R   and Z2  R  
 C   2C  Re al depth 1.5
 xwy 
As Z2 < Z1 ;  i1 < i2 Apparent depth 1.2
21. Let velocities of their masses at distance r from each
15 15
other be v1 and v2, respectively. 
d1 12
By conservation of momentum,
 d1 = 12 cm
m1v1  m2v 2  0
For upper layer of liquid,
m1v1  m2v 2 ...(i) Re al depth
 w a x  1.2
By conservation of energy, Apparent depth

Change in potential energy = Change in kinetic energy

12
 1.2
Gm1m2 1 1 d2
 m1v12  m2 v 22
r 2 2
 d2 = 10 cm
m1v12 m2 v 22 Gm1m2
   ...(ii) Total appernt depth = d1 + d2 = 12 + 10 = 22 cm
2 2 r2
On solving Eqn. (i) and (ii), we get 24. Energy generated per fission
= 0.7 × 1.67 × 10-27 × 9 × 1016 J
2Gm22
v1  = 10.5 × 10-11 J
r  m1  m2 
Total energy required to be generated in one month
2Gm12
v2  = 1000 × 106 × 60 × 60 × 24 × 360 J
r  m1  m2 
= 1012 × 36 × 36 × 24 = 3.11 × 1016 J
 Relative velocity of approach,
Number of molecules of U-235 required
2G
v app  v1  v 2 
r
m1  m2 
10 MOCK TEST 13

4 3 4
3.11 1016 Al  4e  Al
  0.296  1027 3 3
10.5  1011
n=4
0.296  1027
Number of moles of U-235   0.49 × Here G = –nE°F
6.02  1026
kg-mole G 827000 J mol1
E    = – 2.14 V
nF 4  96500 C mol1
Mass in kg = 0.49 × 235 kg = 115.15 kg
25. Let the two frequencies be v1 and v2. v2 may be Thus minimum e.m.f. required = 2.14 V
either 204 Hz or 196 Hz. 0.0591 [Zn2  ]
32. E = E° – log [Here n = 2]
2 [Cu2  ]
+ 4 Hz 204 Hz
(v2)
E = 1.1 V – 0.0591 V log 1
200 Hz 2 0.1
(v1)
= (1.1 – 0.02955)V = 1.07045V  1.07 V
– 4 Hz 196 Hz
(v2) 33. Adsorption is accompanied by decrease in enthalpy
(H =–ve) and decrease in entropy (S = –ve).
As mass of second fork increases, v2 decreases.
34. a
c X  bdY  x 24He  y 1
If v2 = 204 Hz, a decrease in v2 decreases beats/
sec. But this is not given in question. Here x = -particles emitted and y = -particles emit-
If v2 = 196 Hz, a decrease in v 2 increases beats/ ted.
sec. a = b + 4x
This is given in the question when beats increase ab
to 6 x= 4
 Original frequency of second fork = 196 Hz. c = d + 2x – y
27. Amount of H2SO4 = M × V = 0.20 × 350 = 70 m mol y = d – c + 2x
 Amount of H+ ions = 2 × 70 = 140 m mol
Amount of NaOH = M × V = 0.10 × 650 = 65 m mol y = d – c + ab
2
 Amount of OH– ions = 65 m mol
a  b
Thus NaOH is the limiting reactant. As such 65 m y = d + – c
 2 
mol of OH– ions will react with 65 m mol of H+ ions to
give 65 m mol of water. 35. For a zero order reaction the graph between rate and
1 mol of H+ ions react with 1 mol of OH– ions to give concentration is a straight line with zero slope and
+ve Y-intercept.
1 mol of H2O and in the process 57.1 kJ of heat is
produced. 36. 2 × 10-4
So, the heat produced = 57.1 × 65 × 10–3 = 3.71 kJ
pH  pK a  log
salt 
29. As pH of HCOOH sol. = pH of CH3COOH sol. acid
 [H+] in HCOOH sol. = [H+] in CH3COOH sol.
salt   acid
[HCOO  ][H ] [H ]2
K1  
[HCOOH] [HCOOH] pH = pKa; [H+] = Ka = 2 × 10-4
[CH3COO ][H ]
37. 6d
[H ]2
K2  
[CH3COOH] [CH3COOH] 38. O22
K1[HCOOH] = K2[CH3COOH];
rH2 4
[HCOOH] K 1 39.   2
 2   0.25 rHe 2
[CH3COOH] K1 4
x
31. For the reverse reaction 40. m  kp1 n
2 4
Al2O3  Al  O2 logk  0.3 ; n=1
3 3

G = 827 × 103 J mol–1 x

So  2p  2P  x  200gm
m
 MOCK TEST 13 11

41. As reaction is divided by 2, n n n

 r. C  C    r.  r  1  1 C
K  K
55.
n
r
n
r 1
n
Cr  n
r 1
42. Fe, Co, Ni have nearly the same atomic radii because r 1 r 1 r 1

the contractive effect of the increased nuclear charge n n n

is counter balanced by the increase in size due to  r. C   r  1 C   C

r 1
n
r
r 1
n
r 1
r 1
n
r 1

increasing shielding effect of the inner electrons.

n 1
44. Corresponding conjugate Lewis acids are = n.2n–1 –  k. C   2  1
n
k
n

H2O, NH3, HC  CH, CH3CH3 k 0

Increasing order of acid strength of these Lewis = n.2n–1 – (n.2n–1 – n.nCn) – (2n – 1) = n – 2n + 1
acids is 56. f(x – y) = f(x) f(y) – f(a – x) f(a + y) ( f(0) = 1)
CH3CH3 < NH3 < HC  CH < H2O put y = 0
45. HO – Cl  OH– + Cl+ f(x) = f(x) f(0) – f(a – x) f(a)  f(a – x) f(a) = 0 ... (1)
 put x = a, y = a – x
CH3  CH  CH2 
Cl

Pr opene  f(x) = f(a – x) f(a) – f(0).f(2a – x)
46. Nylon - 6  f(x) = 0 – f(2a – x)  f(2a – x) = –f(x)
180  3 5
47. xa   9 13 57. 1 From
2 3
120    180  
5 5  1 1 
l  lim x  sin  cos  1
50. A is more reactive than B x 
 x x 
51. zn = (z + 1)n, this equation will have exactly (n – 1)
1
roots. put x = t
n
 z  1 z 1
We have,   1  z 1  |z + 1| = |z| 1   1 t t t
 z  = lim [sin t  cos t  1] = lim 2 sin cos  2 sin2 
t 0 t 
t 0 t  2 2 2
 ‘z’ lies on the right bisector of the segment
connecting the points (0, 0) and (–1, 0) 
1  t t 1
= lim 2 sin cos  sin  = 1 = e1
t 0 t 2 2 2
1
Thus, Re(z) =  . Hence roots are collinear and will
2
1
58. Put y = 0  f  x   f(x)  f(3x) = 3f(x)
their real part equal to  . 3 3  
2
f(3x)  f(3h)
1 f(x  h)  f(x)  f(x)
Hence, sum of real parts of roots  
2
n  1. f(x) = hlim
0 h
= hlim
0
3
h
52. x 21  x 22  x 32 and x1 + x2 + x3 = 24 8f(x)  3f(x)
 f(x) f(h)  f(0)
= hlim 3 = hlim  f (0)
These given informations give us the idea that x1, x2 0 h 0 h
and x3 can be treated as the sides of a right angled f(x) = 3
triangle whose hypotenuse is x3 and perimeter is 24.  f(x) = 3x + c
The obvious solution is x1 = 8, x2 = 6, x3 = 10 or x1 =  f(x) = 3x
6, x2 = 8, x3 = 10. 59. y  sin –1(x 1  x  x 1  x 2 )
Thus there are two sets of positive integral solutions. dy 1

53. Let the first term be ‘a’. dx 2 x(1  x)  p
3n
Then, S(3n) = (2a + (3n – 1)5) y = sin–1(x) + sin–1 ( x )
2
dy 1 1
2n n  
S(2n) = (2a + (2n – 1)5); S(n) = (2a + (n – 1)5) dx 1  x2 2 x 1  x
2 2
n 60. f(x) = 1 + 2x2 + 4x4 + 6x6 + ... + 100x100
 S(2n) – S(n) = (2a + 5(4n – 2 – n + 1))
2 f(x) = 4x + 16x3 + 36x5 + ... + (100)2 x99
n S  3n  S  3n  f(x) = x(4 + 16x2 + 36x4 + ...+ (100)2 x98)
(2a + (3n – 1)5)   3
=
2 3 S  2n   S n  f(x) = 0
54. Since 9600 = 27 × 31 × 52  x=0
Hence number of divisors = (7 + 1)(1 + 1)(2 + 1)
x = 0 is minima point
= 48. 0
12 MOCK TEST 13

1 sec 4 x
61.  sin 4
x  cos4 x
dx  
tan4 x  1
dx

Let tan x  t
1
1  t  dt 
2 1
t 2 dt
 t4  1 2 1
t  2 69. x2 + 2xy + 2y2 + 4y + 7 = x2 + 2xy + y2 + y2 + 4y + 7
t
= (x + y)2 + y2 + 4y + 7 = (x + y)2 + (y + 2)2 + 3
Let t  1  z least value of (x + y)2 is 0 when y = – x
t
least value of (y + 2)2 is 0 when y = – 2
dt 1  z 
  tan1  c  least value is = 0 + 0 + 3 = 3
t2  2 2  2 
1  t2  1 70. x2 – (a – 2)x – a – 1 = 0
 tan1  c
2  2t 

 2  2        2
2
62. No of function = 33  2 C1·23  2 C2·13  12
63. Distance from centre to the line should be equal to = (a – 2)2 + 2(a + 1) = a2 – 2a + 6

Min   2  2  at 2A  2  1  a = 1
radius 8 2

6  12  a 2
d  2 xe  x 1 2 2 
5 71. A Area =  A '   e  x  2x 2e  x 
2 2 
 a  6  10  a  6  10 1
A'  0  x  gives A max
 a  16 or  4 2

e 1 2 1
1 1 4 1 A max  
64.  1   2 1 2 2 8e
e12 e 22 9 e2
72.
9 3
 e22   e2 
5 5

65. Equation of pair of asymptops is given by 0 1/2 1

s+l=0 f '  x   12x  2x  2  2  3x  1 2x  1
2

 xy  3x  4y  18  0
 f  x , 0  x  1 2
for the above equation to represent a pair of lines 
g  x   f 1 2  , 1 2  x  1
l = -6 
 3  x, 1 x  2
 equation of conjugate hyperbola is
73. y  x and y = c  x = c 2
s + 2l = 0
dy 1
xy – 3x + 4y – 18 = 0 y  x; 
dx 2 x
66. |x|2 – 3|x| + 2 = 0 (|x| – 2) (|x| – 1) = 0 dy 1 1
  1 c 
 x  1,  2 dx P 2c 2

 number ofreal roots is 4. 1

 eqn y  2
67. log27  log24 < log27 < log28
 2 < log27 < 3 i.e. not integer 74. f  x   3 tan x  x3  f '  x   3 sec 2 x  3x 2  0
f(x) is increasing
Let logz 7  P (where p and q are co-prime)
q thus f(a) assume the value 2 exactly once
 2p/q = 7  2p = 7q Also f(0) = 0, f(  /4) > 2
which is not possible so log27 an irrational number. By intermediate value theorem f(c) = 2 for c   0,  
4  
68. 4x2 – 16x +  = 0,  R d y x
 dy  1  y  c
1<  <2&2< <3 75.
 y x 2 y
f(1) f(2) < 0 & f(2) f(3) < 0 x
y(1) = 1  c = -2   y2
(–12 +  ) (–16 +  ) & (–16 +  ) (–12 +  ) = 0 y

12 <  < 16 (Integer  ) = 13, 14, 15 three value 3

y  3    y2 y 3
y
 MOCK TEST – 14
PHYSICS (SECTION – A) U U
1. A particle of specific charge (charge/mass)  starts
moving from the origin under the action of an electric (a) (b)
 
field E  E0 i and magnetic field B  B0 k.
 Its velocity
x O x -x O x
 
at (x0, 0, 0) is 4iˆ  3ˆj . The value of x0 is:
U
U
13 E0 16 B0
(a) (b) (c) (d)
2 B0 E0

25 5 x O x x O x
(c) (d)
2 E0 2B0
5. n identical cells are joined in series with two cells A
2. A hollow sphere of radius 2R is charged to V volts and B with reversed polarities. EMF of each cell is E
and another smaller sphere of radius R is charged to and internal resistance is r. Potential difference
across cell A or B is (n > 4) :
V
volts. Now the smaller sphere is placed inside
2 2E  1
(a) (b) 2E  1  
the bigger sphere without changing the net charge n  n
on each sphere. The potential difference between
the two spheres would be:  2
4E
(c) (d) 2E  1  
3V V n  n 
(a) (b)
2 4 6. A ring consisting of two parts ADB and ACB of same
conductivity K carries an amount of heat H.
V
(c) (d) V The ADB part is now replaced with another metal
2 keeping the temperatures T 1 and T 2 constant.
3. In the circuit shown in figure potential difference The heat carried increases to 2H. What should be
between A and B is_____________ the conductivity of the new ADB part?
E = 190V  ACB 
 Given ADB  3 
 
C 3C C

A
B
C 3C
A B T
4. Four equal charges of magnitude q each are placed T1 2

at four corners of a square with its centre at origin D

and lying in y-z plane. A fifth charge +Q is moved
7
along x-axis. The electrostatic potential energy (U) (a) K (b) 2 K
3
varies on x-axis as:
5
(c) K (d) 3 K
2
2 MOCK TEST 14
7. Pressure versus density graph of an ideal gas is 13. Two coherent point sources S1 and S2 vibrating in
shown in figure: phase emit light of wavelength  . The seperation
P between them is 2 . Find the smallest distance
C from S 2 on a line passing through S 2 and
perpendicular to S 1 S 2 , where a minimum of
B intensity occurs.
7 15
D (a) (b)
A 12 4

 3
(a) during the process AB work done by the gas is (c) (d)
positive 2 4
(b) during the process AB work done by the gas is 14. The gravitational field in a region is given by

negative
(c) during the process BC internal energy of the gas
 
E  4iˆ  ˆj N/kg work done by this field is zero
is increasing when a particle is moved along the line
(d) none of the above (a) y + 4x = 2 (b) 4y + x = 6
8. A string of mass 0.2 kg/m and length l = 0.6 m is fixed (c) x + y = 5 (d) all of these
at both ends and stretched such that it has a tension 15. Maximum speed of a particle in SHM is v max.
of 80 N. The string vibrates in 3 segments with Then the average speed of this particle in one time
maximum amplitude of 0.5 cm. The maximum period is equal to
transverse velocity amplitude is_____________(m/s)
v max v max
9. An organ pipe P1 closed at one end is vibrating in its (a) (b)
first harmonic and another pipe P2 open at both ends 2 
is vibrating in its third harmonic, are in resonance v max 2v max
with a given tuning fork. The ratio of the lengths of P1 (c) (d)
2 
and P2 is:
16. The fundamental frequency of a sonometer wire of
8 3 length l is f0. A bridge is now introduced at a distance
(a) (b)
3 8 of  l from the centre of the wire (  l <<l).
The number of beats heard if both sides of the bridge
1 1
(c) (d) are set into vibration in their fundamental modes are:
6 3
8f0 l f0 l
10. If  represents the coefficient of viscosity and T the (a) (b)
l l
T
surface tension, then the dimensions of are same 2f0 l 4f0 l
 (c) (d)
l l
as that of :
(a) length 17. A detector is released from rest over a source of sound
(b) mass of frequency f0 = 103Hz. The frequency observed by
(c) time the detector at time t is plotted in the graph. The speed
of sound in air is_____________(m/s)
(d) speed
11. 70 cal of heat is required to raise the temperature of (g = 10 m/s2)
2 moles of an ideal gas at constant pressure from
40°C to 45°C (R = 2 cal/mol°C). The gas may be
(a) H2 (b) He
(c) CO2 (d) NH3
12. A particle of mass m begins to slide down a fixed
smooth sphere from the top. What is its tangential
acceleration when it breaks off the sphere?
2g 5
(a) (b) g
3 3

g
(c) g (d)
3
 MOCK TEST 14 3
18. An ionized gas contains both positive and negative 25. A cubical block of side 30 cm is moving with
ions. If it is subjected simultaneously to an electric velocity 2 m s–1 on a smooth horizontal surface.
field along the +x-direction and a magnetic field along The surface has a bump at a point O as shown in
the +z-direction, then: figure. The angular velocity (in rad/s) of the block
immediately after it hits the bump is_____________
(a) positive ions deflect towards +y-direction and
negative ions towards –y-direction a = 30 cm
(b) all ions deflect towards +y-direction
(c) all ions deflect towards –y-direction
(d) positive ions deflect towards –y-direction and O
negative ions towards +y-direction
19. The binding energies of nuclei X and Y are E1 and E2 CHEMISTRY (SECTION – B)
respectively. Two atoms of X fuse to give one atom of 26. Potassium fluoride KF has NaCl structure.
Y and an energy Q is released. Then: Its density is 248 g cm –3 and its molar mass is 58
(a) Q = 2E1 – E2 g mol–1. The distance between K + and F – ions in
KF is _____________(pm)
(b) Q = E2 – 2E1
27. The reaction, X  Product follows first order
(c) Q < 2E1 – E2
kinetics. In 40 minutes the concentration of X
(d) Q > E2 – 2E1 changes from 0.1 M to 0.025 M. Then the rate of
20. Which of the following about hysteresis loss is reaction when concentration of X is 0.01 M
correct? (a) 1.73 × 10–4 M min–1 (b) 3.47 × 10–5 M min–1
(a) It is more in case of soft iron (c) 3.47 × 10–4 M min–1 (d) 1.73 × 10–5 M min–1
(b) It is more in case of steel 28. Which is deliquescent?
(c) It is equal in both the cases (a) MgCl2 (b) NaOH
(d) There is no hysteresis loss in both iron and (c) CaCl2 (d) All
steel 29. Non combustible hydride is
21. When a disc is rolling up an inclined plane, (a) NH3 (b) PH3
its speed decreases gradually. What is the (c) AsH3 (d) SbH3
direction of friction force acting on it? 30. T he c or r ec t produc t of m ono- nitr ation of
(a) In upward direction parallel to inclined plane
(b) In downward direction parallel to inclined plane CH2–COO is
(c) No friction at all as there is perfect rolling
(d) None of the above
22. In an AC generator, armature is perpendicular (a) CH2–COO
to magnetic field and is rotating with angular
velocity of 50 cycle per second. Find the
NO2
time at which current will be 1 2 times the
maximum current for the first time.
(b) CH2COO
(a) 2.5 ms (b) 5 ms
(c) 7.5 ms (d) 10 ms
NO2
23. The ratio of wavelength of the last line of Balmer
series and the last line of Lyman series is (c) NO2 CH2COO
(a) 1 (b) 4
(c) 0.5 (d) 2
24. According to Bohr's theory, the time averaged (d) CH2COO NO2
magnetic field at the centre (i.e., nucleus) of a
hydrogen atom due to the motion of electrons in the 31. Glucose is
nth orbit is proportional to (n = principal quantum (a) Aldopentose (b) Aldohexose
number) n–x, then x is _____________
(c) Ketopentose (d) Ketohexose
4 MOCK TEST 14

32. If K a1 and K a2 are the ionization constants of 39. Which of the following will not produces aromatic
major product
H3N+CHICOOH and H3N+CHICOO –, respectively,
the pH of the solution at the isoelectric point is Red hot
(a) Me C CH
(a) pH  pK a1  pK a2 (b) pH  pK a1  pK a2 Fe tube

1 (pK a1  pK a2 ) Al2O3
(c) pH  (pK a1  pK a2 ) 2 (d) pH  (b) n-Hexane
2 CO2O3/
33. Carbohydrates which differ in configuration at the
glycosidic carbon (i.e. C 1 in aldose and C 2 in CHCl3
ketoses) are called (c)
(a) Anomers (b) Epimers KOH
(c) Diastereomers (d) Enantiomers Cl
Cl Cl
34. NH3  I2  ' A ' HI ; Alc. KOH
(d)
' A ' 
Rubbed
 'B '  N2  NH4I
Cl Cl
A and B are
Cl
(a) NH2NI4 and I2 (b) NH3NI3 and H2
40. Two liquid A and B form an ideal solution. When
(c) NH3NI3 and I2 (d) NH2NI4 and H2 total pressure of above solution is 600 torr, the
35. When iodine reacts with NaF, NaBr and NaCl: amount fraction of A in the vapour phase is 0.35 and
(a) It gives mixture of F 2, Cl2 and Br2 in liquid phase is 0.70. The vapour pressure of pure
(b) It gives chlorine A is_____________(torr)
(c) It gives bromine 41. In which case formation of butane nitrile is possible?
(d) None of the above
(a) C3H7Br + KCN (b) C4H9Br + KCN
36. For reaction X2(g) + y2(g)  2XY(g) (c) C3H7OH + KCN (d) C4H9OH + KCN
The following data are observed 42. Increasing order of reactivity of the following alkyl
[X2] [Y2] Rate of appearance of XY (M/sec) halides in the Williamson’s synthesis is
0.1 0.1 5 × 10
-6 CH2 = CHCH2Cl, CH3CH2CH2Br,
-5
I II
0.2 0.1 10 (CH3)3CCH2Br, CH3CH2CH2Cl
-5
0.2 0.2 4 × 10 III IV
Rate constant of reaction will (in M1-n sec-1) where 'n' (a) II < III < IV < I (b) III < II < IV < I
is order of reaction. (c) IV < III < I < II (d) III < IV < II < I
(a) 2.5 × 10-4 (b) 5 × 10-3
(c) 2.5 × 10-3 (d) 5 × 10-4 43.
37. Which of the following will give -ve Tollen's but +ve
The product A is
iodoform test-
(a) methanal (b) ethanal
(c) pentan-3-one (d) 2, 3-pentanedione (a)
38. Br

HBr (b)
P1 + P 2

P1 & P2 are major dibromo products. What is the

relationship between P1 & P2
(a) Diastereomer (c)
(b) Enantiomers
(c) Configurational isomer
(d) Constitutional isomer (d)
 MOCK TEST 14 5
44. The appropriate reagent for the transformation

(a) Zn(Hg), HCl (b) NH2NH2, OH–

(c) H2/Ni (d) NaBH4
45. The major product of the following reaction is:

Na/ether Br2/hu C2H5O /C2H5OH1D

Br Cl
(1) (2) (3)

(b) Statement-I is True, Statement-II is True;

Statement-II is NOT a correct explanation for
(a) (b) Statement-I
(c) Statement-I is True, Statement-II is False.
(d) Statement-I is False, Statement-II is True.
H O
(c) (d) AgCN
50. Bromoethane   A 
3
Formic acid
+B
46. The de Broglie wavelength of neutron at 27°C CHCl Reduction
B 
KOH
3
 A 
 C

is  . The wavelength at 927°C will be , A, B and C in the above sequence of reactions are
n
then n is_____________ (a) Ethanamine, Ethane nitrile and diethyl amine
(b) Ethanamine, Ethyl isocyanide and ethyl methyl
47. A gaseous mixture of H2 and CO2 gas contains 66
amine
mass% of CO2. The vapour density of mixture is
_____________ (c) Ethyl isocyanide, Ethyl amine and methyl
isocyanate
48. What is the product of the following reactions ?
(d) Ethyl isocyanide, Ethanamine and ethyl methyl
amine
Br (i) Mg, Et2O, (ii) CO2, Et2O

(iii) H3O+, H2O, (iv) SOCl2, pyridine MATHEMATICS (SECTION – C)

(v) NH3 (solvent)  
51. Let a  ˆi  ˆj, b  2iˆ  k.
ˆ Then the position vector of
   
Cl . the point of intersection of the lines r  a  b  a and
   
(a) (b) r  b  a  b is
NH NH
(a) 3iˆ  ˆj  kˆ (b) 3iˆ  ˆj  kˆ
O
NH2
(c) (d) (c) 3iˆ  ˆj  kˆ (d) None of these
NH2  
52. a,b are two mutually perpendicular unit vectors and
49. Statement-I : Redox titrations, involving KMnO4 in 
acid medium, can not be done in presence of c be a unit vector that is inclined at an angle  to
      
 
hydrochloric acid.
both a and b. If c  x1a  x 2b  x 3 a  b , then
Statement-II : Hydrochloric acid does not provide
enough H+ ions for the reaction. (a) x1 = x2 + 1 (b) x 22   cos 
(a) Statement-I is True, Statement-II is True;
Statement-II is a correct explanation for (c) x32  1  2x12 (d) x 22  1  2x 23
Statement-I
6 MOCK TEST 14
53. Range of f(x) = [cos–1{x}], where [.] and {.} denotes 10 2 2 2 2

the greatest integer function and fractional part

65. C0 10 C1 10 C2  ... 10 C10 
respectively, is (a) 2020 (b) 20!
(a) {0, 1} (b) {0, 1, 2} 20
(c) C10 (d) (10!)2
(c) {0, 1, 2, 3} (d) None of these
54. If f(x + f(y)) = f(x) + y  x, y  R and f(0) = 1, 66. The locus of a point such that two tangents drawn
from it to the parabola y2 = 4ax are such that the
then value of f(7) is
slope of one is double the other is
(a) 1 (b) 7
(c) 6 (d) 8 2 9
(a) y – ax (b) y = ax
55. f(x) = [x ] – {x} , where [.] and {.} denote the greatest
2 2 4
integer function and fractional part respectively, is (c) y2 = 9ax (d) x2 = 4ay
(a) Continuous at x = 1, –1 67. The value of ‘k’ for which the set of equations
(b) Continuous at x = –1 but not at x = 1 3x + ky – 2z = 0, x + ky + 3z = 0, 2x + 3y – 4z
= 0 has a non-trivial solution over the set of rational
(c) Continuous at x = 1 but not at x = –1
number is
(d) Discontinuous at x = 1 and x = –1
33 31
56. If a1, a2...an are in A.P. with common difference d  0, (a) (b)
2 2
then the sum of the series (sin d) [cosec a1 cosec a2
+ cosec a2 cosec a3 + ...+ cosec an–1 cosec an] (c) 16 (d) 15
(a) sec a1 – sec an (b) cosec a1 – cosec an n
(c) cot a1 – cot an (d) tan a1 – tan an  [x]dx
57. If two roots of the equation x3 – px2 + qx – r = 0 are 68. The expression
0
n is equal to
equal in magnitude but opposite in sign, then
(a) pr = q (b) qr = p
 {x}dx
0

(c) pq = r (d) None of these

58. If coefficients of the equation ax 2 + bx + c = 0, (n  1) n
(a) (b)
2 2
a  0 are real and roots of the equation are non-real
complex and a + c + b < 0, then (c) n (d) (n – 1)
(a) 4a + c > 2b (b) 4a + c < 2b   
69. Vector x satisfying the relation A.x  c and
(c) 4a + c = 2b (d) None of these   
59. The last two digits of the number 3400 are A  x  B is
(a) 81 (b) 43      
cA  (A  B) cA  (A  B)
(c) 29 (d) 01 (a)  (b) 
|A| | A |2
n r
60. If  nk Cr  x Cy then   
cA  (A  B)
  
cA  2(A  B)
k 1
(c)  (d) 
(a) x = n + 1; y = r (b) x = n; y = r + 1 | A |2 | A |2
(c) x = n; y = r (d) x = n + 1; y = r + 1 70. If a circle of constant radius 3 k passes through the

61. If a, b, c  R and a  b  c  6 , then the origin ‘O’ and meets co-ordinate axes at A and B
then the locus of the centroid of the triangle OAB is
maximum value of a·b2 ·c 3 is_____________
(a) x2 + y2 = (2k)2 (b) x2 + y2 = (3k)2
62. The set of values ‘a’ if the roots of the equation
ax2 + (3a - 2)x + (a - 3) = 0 are opposite in sign is (c) x2 + y2 = (4k)2 (d) x2 + y2 = (6k)2
(a) (0, 3) (b) (3,  )
sin2x a  bcos x
(c) (  , 0) (d) [0, 3] 71. If
  3  4cos x  3
dx 
c  3  4cos x 
d
 e where 'e' is
63. The number of 4 digit numbers in which the digits
are in ascending order is_____________ an arbitrary constant and a, b, c, d are the
64. Number of 4 digit numbers that are divisible by 2 if integers then minimum value of a + b + c + d
repetition of digits is not allowed is_____________ =_____________
 MOCK TEST 14 7

x 4 3
 sin t dt (a) ln (b) ln
2
3 4
72. lim 0

x 0 x 1  cos x  3
(c) ln (d) 0
1 2
(a) (b) -2
3 74. Set of real values of K for which the lines x + 3y + 1
2 = 0, Kx + 2y - 2 = 0 and 2x - y + 3 = 0 form a triangle
(c) 2 (d) is_____________
3

73. If I1  lim
2n

r 2
n
2
and

75. Range of f  x   ln x  3 x  2
2
 is, (where {x}
n 
r 1  3rn  2n represents fractional part of x)
n

 2r
n (a) [2, 6) (b) (ln2, ln6)
I2  lim 2 2
, then the value of
n   3rn  n
r 1
2I1  I2 is equal to
(c) [ln2, ln6) (d)  ,ln2

ANSWERS
1. (c) 2. (b) 3. (10 V) 4. (b) 5. (d) 6. (a) 7. (d) 8. (1.57 m/s) 9. (c) 10. (d)
11. (a) 12. (b) 13. (a) 14. (a) 15. (d) 16. (a) 17. (300 m/s) 18. (c) 19. (b)
20. (b) 21. (a) 22. (a) 23. (b) 24. (n )
–5
25. (5.0) 26. (268.7 pm) 27. (c) 28. (d)
29. (a) 30. (d) 31. (b) 32. (d) 33. (a) 34. (c) 35. (d) 36. (b) 37. (d) 38. (a)

39. (d) 40. (300 torr) 41. (a) 42. (d) 43. (c) 44. (b) 45. (b) 46. ( ) 47. (2.7) 48. (d)
2
49. (c) 50. (d) 51. (a) 52. (c) 53. (a) 54. (a) 55. (d) 56. (c) 57. (c) 58. (b)
59. (d) 60. (b) 61. (108) 62. (a) 63. (126) 64. (2296) 65. (c) 66. (a) 67. (a) 68. (d)

69. (b) 70. (b) 71. (29) 72. (d) 73. (c) 74. ( R  2 3, 4, 6 5 ) 75. (c)
8 MOCK TEST 14

EXPLANATIONS
1. Let q be the charge and m the mass of the particle.
8. l  3
At (x0, 0, 0) speed of the particle is 5 units. 2
Applying work-energy theorem 2l  2  0.6 
   m  0.4m
3 3
1 25 25m 25
qE0 x 0  mv 2  m ;  x0   T 80
2 2 2qE 2  E0 v   20m / s
0
 0.2
V 40RV N N N N
2. Charge on smaller sphere q  C  2  
  2

q 1 1   VR  1  V
Potential difference = 4  R  2R    2  2R   4 3
0      l=
2
E = 190V E = 190V
3. v 20
f   Hz  50 Hz
 0.4
C 3C  
C 3C
Vmax   amax  

A
B B
 
 0.5  102 m  2  50  m / s 

2
m/s = 1.57 m/s
C 3C 3 9. First harmonic of closed = Third harmonic of open
C
4
V  v  l1 1
E = 190V   3  ;  
4l2  2l2  l2 6
15
C  T   MT 2  1
     1 1   LT 
C 4 10.
   ML T 

V1 V2 11.  Q P  nCP T  70

 15  7
CP  7  R
 4  C 15  4  2
V1
   ;  V2    190   40V
V2 C 4  19   Gas is diatomic (H2)
12.
3 v
Now this 40V is distributed in C and 3C in the ratio of 
1
mg
 VAB = 10 V
4. At the centre of square net force on +Q is zero. But
at x = 0, it is in unstable equilibrium position i.e., 2
1 mv
potential energy is maximum. mv 2  mgR 1  cos   & mgcos  
2 R

i
n  4E . 2
5. Current in the circuit will be  cos  
nr 3
Hence, potential difference across A and B is
g 5
n  4  E r  2E  1  2  Tangential acceleration  gsin  
V = E + ir = E +   3
nr  n
13.
KA  T1  T2  KA  T1  T2  4
6. H1 + H2    KA  T1  T2  P
3l l 3l x 2  4 2
x
In later case
7KA KA 7 S1 S2
H2 = 2H – H1  3l  T1  T2   l  T1  T2   K   3 K 2

3
x  x 2  4 2  x 
PM 1 2
7.  and  
RT V
3 2
During AB,  and hence V is constant. x 2  4 2  x 2    3x
4
Therefore, work done is zero.
7
During BC, P   i.e, T x
12
and hence, U is constant.
 MOCK TEST 14 9
  19. During fusion, binding energy of daughter nucleus is
14. E·dr  0 or 4dx + dy = 0
always greater than the total binding energy of the
 line is 4x + y = 2 parent nuclei. The difference of binding energies is
15. vmax  A released. Hence, Q = E2 – 2E1
20.
4A 4A
v avg   I I
T 2

2
v avg  v max B B


v
16. f0 
2l
Hysteresis curve of Hysteresis curve of
Now beat frequency = f1 – f2 steel soft iron
Hysteresis curve shows the pattern of change in I
  vis-a-vis by change in B. The area under hysteresis
v v
  v 1 1 
l  l   2 l   loop represents loss of energy in one complete cycle
2   l 2   l
2  2    l l  l  of magnetising and demagnetising of a magnetic
 2 2 
material from the figure above it is clear that in case
 l  2 l  l  2l 
of steel hysteresis loss is more.
 2 2 
 (f0l)     2f0l  l2  4( l)2  21.
 l  2 l l  2 l   

 4 l  8f l Force of friction
 2f0l  2   0
 l  l

 v  v0  f v
17. f   f0  f0  0 0
v  v In the figure above movement of rolling disc is shown.
It is clear that the point on the disc in touch with the
0  f g inclined plane tends to go down. So, force of friction
v0 = gt;  f  f0   v  t will act in upward direction parallel to the surface.
22. emf generated according to equation,
f g
i.e., f–t graph is a straight line of slope 0v e  e0 sin t

e0
 e0 sin t 
f0g f0 g (103 )(10) sin t  sin
or  slope or v    300 m / s 2 4
v slope  103 
 30  
  t 
4
   1
18. We can write E  Ei and B  Bi
2 
 t  n  T 
T 4  

Velocity of the particle will be along q.E direction. 
2nt 
Therefore, we can write 4
1 1
 t 
V  Aq Ei 8n 8  50
   1000
In E, B and V , A, E and B are positive constants
s t ms  2.5 ms
8  50
while q can be positive or negative.
23. The wavelength of last line of Balmer series
Now, magnetic force on the particle will be
1  1 1  R
 R 2  2 
B 2   4
The wavelength of last line of Lyman series
 1  1 1 
Since, Fm is along negative y-axis, no matter what  R 2  2   R
L  1  
is the sign of charge q. Therefore, all ions will deflect
towards negative y-direction. B 4
  4
L 1
 36. From given data rate = K[1/2]1 [1/2]2
 0I
24. Magnetic field at the centre, Bn 
5  10 6  K 0.1 0.1
2rn 2

For a hydrogen atom, radius of nth orbit is given by

5  10 6  K 1  103
 n2   h  40
rn     rn  n2 k = 5 × 10 -3
m   2  e2
 
37. 2, 3- pentanedione
e e evn
I   38. Diastereoers
T 2rn v n 2rn
40. Ptotal = 600 torr
Also, vn  n1  I  n3 PA = P  XA . . . . . .(i)
(P = total pressure)
Hence, Bn  n5
XA = mole fraction of A in vapour pressure
25. Since no exernal torque acts on the system, there- YA = mole fraction of A in liquid solution
fore total angular momentum of the system about
point O remains constant. PA = PA0  YA . . .. . . (ii)
a PA = vapour pressure of pure A
Before hitting, Li  mv
2
from Eq. (1) and (2)
After hitting, Lf  I 0
PA  YA = Ptotal  X A
a mva
 mv  I or  
2 2I PA0  0.70  600  0.35

Here I = moment of inertia of cube about its edge

0.35 600
PA0  600   = 300 torr
2 0.70 2
a2  2a  ma2 ma 2ma 2
m  m   6  2  3
6  2  42. CH 2 = CH – CH 2 – Cl (Aliylic and 1°) >
CH3CH2CH2 – Br (1° and C – Br bond) >
mva  3 3v 32
     5 rad s –1 CH3CH2CH2 – Cl (1° and C – Cl bond) >
2  2ma2 4a 4  0.3
(CH3)3CCH2Br (Neopentyl bromide, a sterically
26. Since NaCl has f.c.c. structure, KF has also fcc hindered R – C)
structure and Z = 4.
Further in a face centred cubic lattice the distance
between the cation and anion is equal to the sum of 43.
their radii which is equal to half of the edge length of
a
the unit cell i.e., r+ + r– = 2 .
In this ester benzene ring A is bonded to oxygen
ZM
atom
Now edge length a 3 =   N (an activating group and 0 – and p-directing) while
A

4  58
ring B is bonded to group (a deactivating
  155.318  10  24 cm3
2.48  6.023  10 23 and m-directing group) p-nitro group on ring A will
 a = 5.375 × 10–8 cm = 5.375 × 10 –10 m be sterically most stable.
= 537.5 × 10 –12 = 537.5 pm 44. Both Zn(Hg), HCl and NH2NH2, OH– can reduce –
COCH3 group to –CH2–CH 3 group, but HCl will also
a 537.5
Now r+ + r – = 2 =  268.7 pm bring about dehydration of alcohol to form alkene.
2
Therefore, appropriate reagent for the conversion is
2.303 0.1 2.303 2.303  0.6021 NH 2NH2, OH– (B).
27. k  40 min log 0.025  40 min log 4  40
min–1
45.
2.303  0.6021
Rate = k[X]   10 2 Mmin –1
40

2.303  6.021
  10 4 Mmin–1 = 3.47 × 10 –4 M min–1
4
28. Because MgCl3, NaOH and CaCl2 all absorbs water
from the atmosphere moisture. h 1 T2
46.   and v T  
mv 2 T1
47. Let the mass of mixture = 100 gm 56. d = (a2 – a1) = (a3 – a2) = ... = (an – an–1  0)
w CO2  66gm , w H2  34gm sind[cosec a1 cosec a2 + coseca2 cosec a3 + ...
+ cosec a n–1 cosec an]
nCO2  1.5 nH2  17
sind sind sin d
=   .. 
100 sina1 sina2 sina2 sina3 sin an 1 sinan
M.wtmix   5.4
18.5
n 
V.D. = 2.7 n
sin(a  ar 1) sin(ar  cosar 1 cosar sinr 1 
  sina r    
 sin ar r2 
sina 1 sin ar sinar 1 sin ar 
51. r  a  b  a r2 r 1 r

       n
 r  b  a  0  r  b  1 a  2iˆ  kˆ  1 ˆi  ˆj   (cot ar 1  cot ar )  cot a1  cot an
r2
      ˆ ˆ ˆ ˆ 57. x – px 2 + qx – r = 0
3
r  b  a  b  r  a  2b  i  j   2 2i  k
p  Satisfy given equation
At the point of intersection;
p3 – p3 + pq – r = 0
2iˆ  kˆ  1 ˆi  ˆj  ˆi  ˆj   2 2iˆ  kˆ pq = r
 2 + 1 = 1 + 22 + 1 = 1, 2 = 1  1 = 1, 2 = 1 58. ax2 + bx + c = 0, a  0,

Thus P.V. of point of intersection is Given

 a+b+c<0 &D<0
i  2iˆ  kˆ  ˆi  ˆj  3iˆ  ˆj  kˆ
 f(x) < 0 x  R  f(–2) < 0
     
52. a. b  0 , a . c  b . c  cos   4a – 2b + c < 0  4a + c < 2b
       59. 3400 = (3 2)200 = (9) 200 = (10 – 1)200
c  x1a  x 2b  x 3 a  b  c.a  x1a.a  x1  cos 
= 200C0 10200 + 200C1 10199 + 200C2 10198 + ...+ 200C199
101 + 200C200 100 – 100[200C010198 + 200C110197 +
Also, 200C 10196 + ...+ 200C
2 198]
    + 200C199101 + 200C2001000
 c  a  b cos   x 3 a  b
= (k)100 + 200(10) + 1(1)
     = (k + 20)100 + 01
Now, | c |2  a  b cos   x 3 a  b
So, last two digits is 01.
   
. a  b cos   x 3 a  b n r
60.  n k Cr  x Cy
k 1
       2
 | a |2  | b |2  2a . b cos 2   x 23  1  a . b  n–1C n – 2C n–3C
  L.H.S = r+ r + r + ... + rCr
= rCr + r+1Cr +...n–2Cr + n–1Cr
 1 = 2 cos2  + x 32  x 23 = 1 – 2 cos 2 = 1 – 2 x12
= r+1Cr+1 + r+1Cr +...+ r+2Cr + ...+ n–1Cr
  = r+2Cr+1 + r+2Cr +...+ n–1Cr
53. Range of cos–1{x} is  0, 2   Range of [cos –1{x}] is
  = r+2Cr+1 +...+ n–1Cr
{0, 1} = n–1Cr+1 + n–1Cr
54. f(x + f(y)) = f(x) + y, f(0) = 1 = nCr+1 = xCy  x = n, y = r + 1
Putting y = 0, we get
f(x + f(0)) = f(x) + 0  f(x + 1) = f(x)  x  R 61. Apply A.M.  G.M. for the forms as a, b , b , c , c , c
2 2 3 3 3
Thus f(x) is periodic with 1 as one of it’s period.
b c 
a  2   3   1
Thus f(7) = f(6) = f(5) = .......= f(1) = f(0) = 1  3    a  b  · c  
2 3 6
 2
     
55. f(x) = [x 2] – {x}2 b   2   3  
f(–1) = 1, f(–1 – 0) = 0 – 1 = –1  ab2c 3  108
f(1) = 1, f(1 + 0) = 1 + 0 = 1 62. For roots to be of opposite sign
f(1 – 0) = 0 – 1 = – 1
c a 3
Thus f(x) is discontinuous at x = 1, –1 0  0  a  0,3
a a
63. By selecting any 4 digits out of 1 to 9 in 9 C4
ways, we can arrange them only in one way. Ans
9
68.
C4

64. If units place is ‘o’ then no of ways is 9 × 8 × 7

otherwise 8 × 8 × 7 × 4
 total possibilities = 9 × 8 × 7 + 8 × 8 × 7 × 4 = 56
× 41 = 2296
n2 2 2 2
65. C0 n C1 n C2  ... n Cn  2n Cn
 
20
C10
69. A.X  C
  
AXB
1
66. y2 = 4ax; Slope = 
t take cross with A
    
A  A X  A B

  
 CA – A  B
X 
| A |2

70. Let centre (a, b)

AB2 = (6k)2 = (2a)2 + (–2b) 2
 a2 + b2 = 9k 2
2t
1 2

71. cos x  t 
 3  4t 3
dt

t1 t2
 
1 
  dt
 t2 = 2t1 ... (1) 1 3
 

2  3  4t 2 3 
R[at1t2, a(t1 + t2)]  3  4t 

h = at1t2, k = a(t1 + t2)  

1  1 3 e  3  8t
  e

8  3  4t 2 3  4t 
2  16 3  4t
2
k = 3at1  t1  k  
33
x x
h  2at12 72.
0
 sin t 2dt
 sin t dt
2

lim  lim 0
k2 9 x  0 3 1  cos x x 0 x3
h  2a 2  k  ah 2
x
9a 2 2
x

sin x 2 2
2 lim 
x  0 3x 2 3
67. 3x + ky – 2z = 0 2

x
x + ky + 3z = 0 1
73. I1  2
dx  ln3 2
2x + 3y – 4z = 0  3x  2
0
D=0 1

 2x
1
I2  dx  ln3 2
2
 3x  1
0
74. Three lines forms a triangle if they are non-concurrent
3(– 4k – a) – k(– 4 – 6) – 2(3 – 2k) = 0 and so two lines are parallel answer  R  2 3, 4, 6 5
– 12k – 27 + 4k + 6k – 6 + 43k = 0
75. ln is increasing
2k = 33; min at n = 0
max at n = 1  Range [ln2, ln6)
 MOCK TEST – 15
PHYSICS (SECTION – A) immersed in a liquid of refractive index 1.5 the
corresponding y coordinates will be:
1. A steady current flows in a metallic conductor of non- (a) 2 cm, 7.5 cm (b) 3 cm, 6 cm
uniform cross section. The quantity/quantities which
4 10
remain constant along the length of the conductor (c) 2 cm, 4 cm (d)
cm, cm
is/are: 3 3
6. The maximum intensity in Young's double slit
(a) current, electric field and drift speed experiment is I0. Distance between the slits is
(b) drift speed only1 d  5, where  is the wavelength of
(c) current and drift speed monochromatic light used in the experiment. What
(d) current only will be the intensity of light in front of one of the slits
on a screen at a distance D = 10d?
2. A real image is formed by a convex lens, then it is
connected with a concave lens and again a real image I0 3
(a) (b) I0
is formed. This image will: 2 4
(a) shift towards the lens system I0
(c) I0 (d)
4
(b) shift away from the lens system
7. A spherical surface of radius of curvature R,
(c) remain in its original position separates air from glass. The centre of curvature is
(d) shift to infinity in the glass. A point object P placed in air is found to
have a real image Q in the glass. The line PQ cuts
3. Refraction takes place at a concave spherical
the surface at a point O and PO = OQ. The distance
boundary separating glass air medium. For the image
PO is equal to m R, then ‘m’ is ___________
 3 8. A capacitor of capacity 6F and initial charge 160C
to be real, the object distance   g   :
 2
is connected with a key S and resistance as shown
(a) should be greater than three times the radius of in figure. Point M is earthed. If key is closed at t = 0;
curvature of the refracting surface then the current through resistance R   1  at t =
(b) should be greater than two times the radius of 16 s is:
curvature of the refracting surface
2 N 1
(c) should be greater than the radius of curvature of
the refracting surface S
+
(d) is independent of the radius of curvature of the 2 C R 1
refracting surface

d 4 M 2
4. In Young’s double slit experiment  10 4
D
10 10
(d = distance between slits, D = distance of screen (a) A (b) A
from the slits). At a point P on the screen resulting 3e e
intensity is equal to the intensity due to individual 20
(c) A (d) none of these
slit I0. Then the distance of point P from the central 3e
maximum is___________(mm)    6000 Å  9. A 100 W bulb B1, and two 60 W bulbs B2 and B3, are
connected to a 250 V source, as shown in the figure.
5. In Young’s double slit experiment the y co-ordinates Now, W 1, W 2 and W 3 are the output powers of the
of central maxima and 10th maxima are 2 cm and bulbs B1, B2 and B3 respectively. Then:
5 cm respectively. When the YDSE appratus is
2 MOCK TEST 15

B1 B2 1 1
(a) (b)
4 8
1 1
(c) (d)
B3 3 6
15. A 120 V, 60 W lamp is run from a 240 V, 50 Hz
250 V mains supply using a capacitor in series. Find the
capacitance required to operate the lamp at its
normal rating___________(F)
(a) W 1 > W 2 = W 3 (b) W 1 > W 2 > W 3
16. A hollow sphere of radius 2R is charged to V volts
(c) W 1 < W 2 = W 3 (d) W 1 < W 2 < W 3 and another smaller sphere of radius R is charged
10. A point charge q is placed at a distance of r from the
V
centre of an uncharged conducting sphere of radius to volts. Now the smaller sphere is placed inside
2
R(< r). The potential at any point on the sphere is:
the bigger sphere without changing the net charge
1 q on each sphere. The potential difference between
(a) zero (b) .
40 r v
the two spheres would be , then x is ___________
x
1 qR 1 qr 2
(c) . (d) .
40 r 2 4 0 R 17. The dimensions of b 4 (  = Stefan’s constant and
b = Wein’s constant) are :
11. A tiny sphere of mass m and density  is dropped
(a) [M0L0T0] (b) [ML4T–3]
in a tall jar of glycerine of density  . When the
(c) [ML–2T] (d) [ML6T–3]
sphere acquires terminal velocity, the magnitude of
viscous force is 18. Two bodies of mass m and 4 m are attached with
string as shown in the figure. The body of mass m
mg mg hanging from a string of length l is executing
(a) (b)
  oscillations of angular amplitude while the other
body is at rest. The minimum coefficient of friction
    between the mass 4m and the horizontal surface
(c)  1   mg (d) mg  1   should be:
   

12. The ratio of Planck's constant and moment of inertia

has the same dimensions as
(a) frequency
(b) velocity
(c) Angular momentum
(d) time
13. Two objects moving along the same straight line are  2  cos 0  2  0 
(a)   (b) 2cos  
leaving point A with acceleration a, 2a and velocity 3 2
2u, u respectively at t = 0. The distance moved by  1  cos 0   3  2cos 0 
objects with respect to point A when one object (c)   (d)  
2 4
overtakes the other is
19. Two particles of masses m1 and m2 in projectile motion
6u2 2u2  
(a) (b) have velocities v1 and v 2 , respectively at time
a a
t = 0. They collide at time t0. Their velocities become
4u2 8u2  
(c) (d) v1 and v2 at time 2t0, while still moving in air. The
a a  
14. Half life of a radioactive substance A is two times value of (m1v1  m2 v 2 )  (m1v1  m2 v 2 ) is:
the half life of another radioactive substance B. (a) zero (b) (m1 + m2)gt0
Initially the number of nuclei of A and B are NA and
NB. After three half lives of A the number of nuclei of 1
(c) 2(m1 + m2)gt0 (d) (m1  m2 )gt0
both are equal, Then the ratio NA/NB is 2
 MOCK TEST 15 3
20. Two identical balls A and B are released from the Bead enters curved part at A and leaves at B.
positions shown in figure. They collide elastically on Magnitude of average force exerted by bead over
horizontal portion MN. The ratio of heights attained the wire as it passes from A to B is
by A and B after collision will be: (neglect friction)
5mv 2 4mv 2
(a) (b)
d d

2mv 2
(c) 0 (d)
d
25. In a series resonant LCR circuit, the voltage across
R is 100 volts and R  1 k with C  2F. The
resonant frequency  is 200 rad/s. At resonance
the voltage across L is___________(V)

CHEMISTRY (SECTION – B)
(a) 1 : 4 (b) 2 : 1
(c) 4 : 13 (d) 2 : 5 26. The ionization constant of HCO 2H is 1.8 × 10 –4.
W hat is the percent ionization of a 0.001 M
1 solution___________(%)
21. The dimension of 0E2 ( 0 : Permittivity of free
2 27. Coupling of diazonium salts of following takes
space, E : Electric field) is place in the order

(a) MLT  (b) ML T 

1 2 2
O– OH NH2 +NH3

(c) ML T  (d) ML T 

1 2 2 1

22. A plate has length 5  0.1 cm and breadth 2 

0.01 cm. The area of plate is
I II III IV
(a) 10  0.1 cm2 (b) 10  0.01 cm2
(a) IV < II < III < I
(c) 10  0.001 cm2 (d) 10  0.25 cm2
(b) IV > III < II < I
23. For a body angular velocity is   ˆi  2ˆj  3kˆ and a (c) II < IV < I < III
point on it has a radius vector r  ˆi  ˆj  kˆ , then (d) I < II < III < IV
28. Aniline when diazotized and then treated with
what is the linear velocity of point
dimethyl aniline gives a coloured product. Its
(a) 5iˆ  2ˆj  3kˆ structure would be

(b) 5iˆ  2ˆj  3kˆ

(a) (CH3)2N N=N
(c) 5iˆ  2ˆj  3kˆ

(d) 5iˆ  2ˆj  3kˆ

(b) (CH3)2N NH
24. A bead of mass m moving with speed v is moving
over a U-shaded wire as shown.

v A (c) CH3NH N=N NHCH3

m
d
(d) CH3 N=N NH2
B
4 MOCK TEST 15

OH 33. Consider the reaction

29. 
I2 , NaHCO3
 Major product:
O G CH2 – Br + 
Acetone
SN 1


I N

+
(a) O G CH2 – N Br
–

O
The rate of the reaction depends on the nature
O
(b) O of G. The rate order for the reaction (where G is)
I (a)CH3 – > CH3 – CH2 – > (CH3)2CH – > (CH3)3C
– due to hyperconjugation
I
– + (b)CH3 – > CH3 – CH2 – > (CH3)2CH – > (CH3)3C
COONa – due to steric acceleration
(c)
I (c) (CH3)3C – > (CH 3)2CH – > CH 3CH2 – > CH 3 –
due to inductive and steric effects
OCOONa
(d)(CH3)3C – > (CH 3)2CH – > CH 3 – > CH3CH2 –
(d) COONa due to hyperconjugation
I 34. The correct order of basicity is
I II III IV
30. 
HCl
CCl4
 Major product: N
> > >
N N N
Cl Cl
H H
(a) (b)
Identify the correct statement.
Cl (a) In III, lone pair of electrons is involved in
delocalisation but not in II.
Cl (b) In IV, lone pair of electrons is involved in
(c) (d) delocalisation but not in III.
(c) I is more basic than II because six membered
31. The root mean square velocity of one mole of a ring is more stable than five membered ring.
monoatomic gas having molar mass M is U rms. (d) In III lone pair of electrons is present in sp orbital
The relation between the average kinetic energy but in I, II and IV lone pair of electrons is present
(E) of gas and Urms is in sp2 orbital.
35. The com pound with the structural formula
3E 2E
(a) Urms  (b) Urms 
2M 3M
is
2E E
(c) Urms  (d) Urms  (a) aromatic and non-polar
M 3M
(b) aromatic and polar with definite dipole moment
32. 'a' and 'b' are vander waal's constants for gases.
Chlorine is more easily liquified than ethane (c) non-aromatic and non-polar
because (d) non-aromatic and polar with definite dipole
(a) a and b for Cl2 < a and b for C2H6 moment
0
(b) a for Cl2 < a for C2H6 but b for Cl2 < b for C2H6 36. For strong electrolyte m  m  10 C . Then
(c) a for Cl2 > a for C2H6 but b for Cl2 < b for C2H6
calculate m at 0.01 M if its value at 0.16M is 200
(d) a and b for Cl2 > a and b for C2H6
Scm2mol-1___________(Scm2mol-1)
 MOCK TEST 15 5
37. Select the correct statement about [Mn(CO)4NO] 44. Identify the correct statement regarding a
which is diamagnetic spontaneous process
(a) It is diam agnetic because Mn metal is (a) Lowering of energy in the reaction process is the
diamagnetic in free state only criterion for spontaneity.
(b) It is diamagnetic because Mn is in +1 oxidation (b) For a spontaneous process in an isolated sys-
state in this complex tem, the change in entropy is positive.
(c) NO is present as positive ligand (c) Endothermic reaction are never spontaneous.
(d) All of these (d) Exothermic reactions are always spontaneous.
38. Which of the following reaction from N2O
45. The radioactive decay of 35
X88 by a  -emission
(a) NH4NO3  
produces an unstable nucleus which spontaneously
 emits a neutron. The final product is___________
(b) NH3 (excess) + Cl2  
46. Which of the following oxoacids of sulphur has more

(c) NH4NO2   than one oxidation state of oxygen?

(a) H2S2O3 (b) H2S2O4
(d) FeSO4 + HNO3  
(c) H2S2O6 (d) H2S2O8
39. Benzylamine & aniline can be distinguished by
47. 0.246 g of the organic compound gave 22.4 cm3 of
(a) Isocynide test (b) Musturd oil test nitrogen gas at STP as determined by Duma's
(c) Dye-azo test (d) Hinsberg test method. The percent of nitrogen in the compound
40. Which of the following reaction is not correctly is___________
matched with its products: 48. Assuming 100% ionization, the increasing order of
the freezing point of the solution will be
(a) P4 + 10SO2Cl2  4PCl3 + 10SO2
(a) 0.10 mol kg-1 Ba3 (PO4)2 < 0.10 mol kg-1 Na2SO4
(b) P4 + 8SOCl2  4PCl3 + 4SO2 + 2S2Cl2 < 0.10 mol kg-1 KCl
(c) 3CH3COOH + PCl3  3CH3COCl + H3PO3 (b) 0.10 mol kg-1 KCl < 0.10 mol kg-1 Na2SO4 < 0.10
mol kg-1 Ba3 (PO4)2
(d) Sn + PCl5  SnCl2 + PCl3
(c) 0.10 mol kg-1 Na2SO4 < 0.10 mol kg-1 Ba3 (PO4)2
41. Which of the following acids has the smallest < 0.10 mol kg-1 KCl
dissociation constant? (d) 0.10 mol kg-1 KCl < 0.10 mol kg-1 Ba3 (PO4)2 <
(a) CH3CHFCOOH (b) FCH2CH2COOH 0.10 mol kg-1 Na2SO4
(c) BrCH2CH2COOH (d) CH3CHBrCOOH 49. 2g of impure CaCO3 reacts with HCl to produce 410
42. The product of acid hydrolysis of P and Q can be ml of CO2 at 1 atmospheric pressure and 27°C.
distinguished by Calculate the percentage purity of the CaCO 3
used___________
is 50. In IF3 the bond angle of F-I-F is
(a) equal to 90° (b) less than 90°
(c) greater than 90° (d) None of these
is
MATHEMATICS (SECTION – C)
(a) Lucas reagent (b) 2, 4-DNP e1/ x 
2
, x0
(c) Fehling’s solution (d) NaHSO3 51. If (x) =  , then f(x) is
 0
, x0
43. The strongest base among the following is
(a) Differentiable at x = 0
(a) (b) (b) Continuous but not differentiable at x = 0
(c) Discontinuous at x = 0
(d) None of these
(c) (d)
6 MOCK TEST 15

52. The exhaustive set of values of ‘a’ such that 57.

x + ax + sin (x – 4x + 5) + cos (x – 4x + 5) = 0
2 –1 2 –1 2
 2 3 4 5 6
has atleast one solution is cos 0  cos  cos  cos  cos  cos  cos 
7 7 7 7 7 7

    1 1
(a)  2   (b)  , 2   (a) (b) 
 4  4 2 2
(c) 0 (d) 1
     58. Given the family of lines, a(3x + 4y + 6) + b(x + y +
(c)  , 2   (d)  2  ,  
 4  4  2) = 0. The line of the family situated at the greatest
distance from the point P(2, 3) has equation
53. The side of a triangle ABC are in A.P. (order being a,
(a) 4x + 3y + 8 = 0 (b) 5x + 3y + 10 = 0
2! 2! 1 8a (c) 15x + 8y + 30 = 0 (d) none
b, c) and satisfy, 1!9!  3!7!  5!5!  2b ! , then
  59. The greatest distance of the point P(10, 7) from the
circle x2 + y2 – 4x – 2y – 20 = 0 is
the value of cosA + cosB is
(a) 5 (b) 15
12 13 (c) 10 (d) none of these
(a) (b)
7 7 60. If (t2, 2t) is one end of a focal chord of the parabola y2
= 4x then the length of the focal chord will be
11 10
(c) (d) 2
 1
(a)  t  
7 7 1  2 1
(b)  t    t  t2 
 t  t  
54. The combined equation of straight lines that can be
obtained by reflecting the lines y = |x – 2| in the
1  1
y-axis, is (c)  t    t 2   (d) none
 t  t2 
(a) y2 + x2 + 4x + 4 = 0
(b) y2 + x2 – 4x + 4 = 0 61. The locus of z if z  i  z  i  4 is
(c) y2 – x2 + 4x – 4 = 0
(a) line segment
(d) y2 – x2 – 4x – 4 = 0 (b) ellipse
55. Tangent drawn to x2 + y2 = 25 at the point P(3, 4) (c) hyperbola
meets the circle x2 + y2 = 81 at the points A and B. (d) null set
If the tangents drawn to x2 + y2 = 81 at the points A
and B intersect at C, then co-ordinates of ‘C’ is 62. The period of the function y  f  x  if

f  x   f  x  2   2·f  x  1 is
 243 81   243 81
(a)  , (b)  ,
 25 25   25 5  (a) 2 (b) 4
(c) 8 (d) 12
 243 81  63. The set of values of ‘a’ if the function
(c)  , (d) None of these
 5 25   
y  cot 1  x 2  2x  a  ; R   0,  is an on-to
   2
  
56. If a, b, c are three non-coplanar non-zero vectors and
function is

r is any vector in space, then (a) {1} (b) (1,  )
           
(a  b)  (r  c)  (b  c)  (r  a)  (c  a)  (r  b) (c) 1,   (d) R
is equal to 64. The value of ‘a’ if the line 2x - 3y + a = 0 is a tangent
     to the parabola x2 = 8y
(a) 2[a b c]r (b) 3[a b c]r
(a) 9 (b) 3
  
(c) [a b c]r (d) None of these 8 8
(c) (d)
3 9
 MOCK TEST 15 7
65. The locus of point whose chord of contact subtends 71. If  is an imaginary cube root of unity then the
a right angle at the centre of the circle x2 + y2 = a2   10 
is value of cos 
225  r   r     is
 r 1 
(a) x2 + y2 = 2a2 (b) x2 - y2 = a2
1
(c) x2 + y2 = 4a2 (d) xy = a2 (a) –1 (b)
2
66. If ax = by = cz = dt and a, b, c, d are in G.P., then x, y,
z, t are in 1
(c) (d) 1
(a) A.P. (b) G.P. 2
(c) H.P. (d) None of these 72. If A = 5° then the value of
2
  sec A cosec A 
1    is___________
67. The sum  r2  1  1  4 sin A 4cos2 A  1 
2

r 2
73. The sum of series
3 84
C4  6· 84C5  15· 84C6  20· 84 C7  15· 84 C8  6· 84C9  84
C10
(a) 1 (b)
4 is equal to
88
4 (a) 86
(b) C10
(c) (d) None of these C10
3 90
(c) (d) 90
C10 C12
68. The last two digits of the number 3400 are___________
69. Number of terms free from radical sign in the 44
expansion of (1 + 31/3 + 71/7)10 is___________  cosn
n 1
70. The locus of the centers of the circles which cut the 74. Let x  44
find the greatest integer that
circles x2 + y2 + 4x – 6y + 9 = 0 and x2 + y2 – 5x + 4y
– 2 = 0 orthogonally is
 sinn
n 1

(a) 9x + 10y – 7 = 0 does not exceed 100x___________

(b) x – y + 2 = 0 75. Consider the sequence 2, 3, 5, 6, 7, 8, 10,
(c) 9x – 10y + 11 = 0 11, 12, 13, 14, 15, 17, ... of positive integers
that are not perfect squares. Determine the
(d) 9x + 10y + 7 = 0
2011th term of this sequence___________

ANSWERS
1. (d) 2. (b) 3. (a) 4. (2 mm) 5. (c) 6. (a) 7. (5R) 8. (c) 9. (d) 10. (b)

V
11. (c) 12. (a) 13. (a) 14. (b) 15. (7.7 F) 16. ( ) 17. (b) 18. (d) 19. (c) 20. (c)
4
21. (c) 22. (d) 23. (a) 24. (b) 25. (250 V) 26. (34%) 27. (a) 28. (a) 29. (c) 30. (a)
31. (c) 32. (c) 33. (a) 34. (b) 35. (b) 36. (203 Scm2mol–1) 37. (c) 38. (a) 39. (c)
40. (d) 41. (c) 42. (c) 43. (c) 44. (b) 45. (36X )87
46. (d) 47. (11.38) 48. (a) 49. (83.5)
50. (a) 51. (a) 52. (a) 53. (a) 54. (d) 55. (b) 56. (a) 57. (d) 58. (a) 59. (b)
60. (a) 61. (b) 62. (c) 63. (a) 64. (c) 65. (a) 66. (c) 67. (b) 68. (01) 69. (6)
70. (c) 71. (d) 72. (24) 73. (c) 74. (241) 75. (2056)
8 MOCK TEST 15

EXPLANATIONS
1. i  neAv d yd
6. Path difference x 
D
1 1
Drift speed, v d  
d 5
neA A
Here, y   (as d = 5  )
2 2
Therefore, for non-uniform cross-section (different
values of A) drift speed will be different at different and D = 10d = 50 
sections. Only current (or rate of flow of charge) will
be same. so x   5 

5  

 2  50  4
2. Power of concave lens should be less than that of
Corresponding phase difference will be
the convex lens to form a real image. So, net power
will decrease or focal length will increase. For real  2   2      
     x       or 
image v is positive, u is negative and f is positive.       4  2 2 4
From lens formula (substituting all values with sign),
  I
1 1 1  I  I0 cos2    I0 cos2    0
  2 4 2
v u f
7. Let us say PO = OQ = X
u is constant, f is increasing. So v will also increase.

3. Applying 2  1  2  1
2 v u R
1

 1= 1.0
Object 
P
O Q
 2 1  2  1
Applying,   +ve
v u R

1 1.5 1  (1.5) 1 3 1 Substituting the values with sign

  or  
v ( u) R v 2u 2R 1.5 1.0 1.5  1.0
 
X X R
1 3
For v to be positive 2R  2u or u > 3R (Distances are measured from O and are taken as
positive in the direction of ray of light)
   
4. I  4I0 cos2   ; I0  4I0 cos2   2.5 0.5
 2  2   ;  X = 5R
X R
  1   8. Resistance across capacitor
 cos    or 
 2 2 2 2
4  8 32
R  
2  2   1  1 d  yd  4  8 12
or      x or    y x  
3   3   D  D
c  CR  16s

 6  107
y    160 
3
d 3  10 4   t / 
D i  i0 e t / c   6  e t / c  10e c
 32 
 12 
 2  10 3 m  2 mm

5. Fringe width    . Therefore,  and hence w will After t  c , i  10 A

decrease 1.5 times when immersed in liquid. The e
distance between central maxima and 10th maxima This is distributed in inverse ratio of resistance.
is 3 cm in vacuum. When immersed in liquid it will
reduce to 2 cm. Position of central maxima will not 2  10  20
 i1  A A
3  e  3e
change while 10th maxima will be obtained at
y = 4 cm.
 MOCK TEST 15 9

V2 V2  1  240
2
9. P ; So, R z  R2  
R P  
 C  0.5

 R1 
V2
and R 2  R3 
V2  C  7.7 F
100 60
 V  4 0RV
16. Charge on smaller sphere q  C  
(250)2  2 2
Now, W1  .R1
(R1  R 2 )2
q 1 1   VR   1  V
2 2
Potential difference = 4  R  2R    2   2R   4
(250) 0
W2  .R2 and W3  (250)
(R1  R2 )2 R3
energy
17. mT  b or b4  m T and
4 4  T 4
W 1 : W 2 : W 3 = 15 : 25 : 64 or W 1 < W 2 < W 3 area  time

10. Since, potential V is same for all points of the sphere. energy
  energy  4
Therefore, we can calculate its value at the centre of or ;  b 4   
(area  time)T 4  area  time  m
the sphere.
[ML2 T 2 ]
 V
1 q
.  V
4
or [b ]  [L4 ]  [ML4 T 3 ]
40 r [L2 ][T]

V = potential at centre due to induced charges = 0

18.
(because net induced charge will be zero)
1 q
 V . .
40 r

11. F = mg - B

 
F  mg  1  
 

nh Maximum tension in the string is in its lowest

12. L  mvr  I  2
position.
h 2 h  l(1  cos 0 )
  frequency
I n
 Speed of mass m in its lowest position is
13. S1 = S2
V2 = 2gh=2gl(1 – cos 0 )
1 1
2ut  at 2  ut   2a  t 2
2 2 mv 2
Now, Tmax – mg =
l
2u
t
a
mv 2
or Tmax = mg  = mg + 2mg (1 – cos 0 )
l
 2u  a  4u 
2 2
 S1  S2  2u     2   6u
 a  2 a  a or Tmax = mg(3 – 2cos 0 )
14. 3 half lives of A  6 half lives of B. Block of mass 4m does not move


NA NB

NA

1  (4mg)  Tmax
;
23 26 NB 8
 3  2cos 0 
or 4mg  mg(3  2cos 0 ) or    
P 60  4
15. i   0.5A
V 120
   
19. | (m1v1  m2v 2 )  (m1v1  m2v 2 ) |
V 2
120  120
Rbulb    240  = |change in momentum of the two particle|
P 60
= |External force on the system| × time interval
Now, i  V = (m1 + m2)g(2t0) = 2(m1 + m2)gt0
z
10 MOCK TEST 15
20. After collision balls exchange their velocities E
25. Current I 
Z

where E  VR2   VL – VC 2

Z  R2   XL – XC 
2

At resonance, XL = XC
 Z =R
Again at resonance, VL = VC
 E = VR

VR 100
i.e., v A  2gh and vB  2g(4h)  2 2gh  I   0.1 A
R 1  103

v2 I 0.1
Height attained by A will be hA  2gA  h  VL  I L  
C (2  10 –6 )  (200)

But path of B will be first straight line and then  VL = 250 volt
parabolic as shown in figure.


 H+ + HCO2
26. HCO2H  

After calculation we can show that

0.001–x xx
13 hA 4
hB  h;  
hB 13
 is > 0.1 which means x is not ignorable.
4
x2
1  Ka = 1.8 × 10–4 =
21. The quantity 0E2 is the electrostatic energy 0.001  x
2
density, so it has dimensions of energy per unit Solving by quadratic, x = 3.4 × 10–4
volume, so it has dimensions ionized HCO2H
 % ionization = total HCO 2H
 100
ML2T 2 
    ML1T 2 
Energy
Volume L3    3.4  10 4
    100  34%
0.001
22. Area A = l × b = 5 × 2 = 10 cm2 Note: Check for 
A l b
  Ka
A l b = ;
c
 l b   0.1 0.01 
 A    ·A      10  0.25
 l b   5 2  1.8  10 4
=  0.42
23. Linear velocity 0.001

27. Electron releasing power:

  
v    r  ˆi  2jˆ  3kˆ  ˆi  ˆj  kˆ  – +
C6H5 – O > C6H5NH2 > C6H5OH > C6H5NH3

ˆi ˆj kˆ
 
 1 2 3  ˆi  2  1  3  1  ˆj 1 1  3  1  kˆ 1 1   2   1 28. NH2 
NaNO2
HCl, 273 K C6H5N2Cl
1 1 1

 5iˆ  2ˆj  3kˆ

N(CH3)2
24. p (bead) = pf  pi  2mv C6H5–N = N N(CH3)2

p wire = 2mv
31. For 1 mole of the gas
·d 2 d
t  
v 2v 1
PV = 3 Mu2
p 4mv 2
Average force =  3PV

3RT
t d or Ur.m.s. =
M M
 MOCK TEST 15 11

Kinetic energy, E  3 RT 40. Sn + PCl5  SnCl2 + PCl3

2
41. BrCH2CH2COOH is least acidic or has less Ka i.e.,
or 3 RT = 2E
dissociation constant. It is (a) due to lesser –I effect
2E of Br than F and (b) Br atom further away from –
 Ur.m.s. = .
M COOH group.
32. Van der waal’s constant ‘a’ signifies the attractive 42.
forces among molecules of the real gas. More the
value of ‘a’ more are the attractive forces a(Cl2) >
a(C2H6)
Vander waal’s constant ‘b’ is a measure of effective
size of gas molecule. It is four times the actual
volume of the gas molecule b(Cl2) < b(C2H6).
33. Methyl substituted benzyl bromide reacts faster and
isopropyl substituted compound reacts slower. The
tertiary butyl substituted compound reacts slower.
This rate order is explained by the hyperconjugative
effect.
34. IV is least basic because lone pair of electrons is
involved in delocalisation. In III, lone pair is present
in sp2 hybridised nitrogen but in I and II lone pair is Acetone and propanal can be distinguished by
present in sp3 hybridised nitrogen. Six membered Fehling solution
ring has greater +I effect than five membered ring.  1

45. X88  36 X
88

0n
 X87
35. The compound with the structural formula 35 36

46. H2S2O8
is aromatic and polar with definite 47. 11.38
 V 
% of Nitrogen =  22400  MN2   W 
N2  100 

dipole moment.  

 22.4   100 
   28     11.38
 22400   0.246 

+ PV 1 0.410
49. nCO2    0.0167mol
RT 0.082  300
–
0.0167 mol of CO2  1.67 g mol of CaCO3
The seven membered ring with positive charge and 1067
% of purity =  100 = 83.5 %
three alternate double bonds is aromatic. Similarly, 2
the five membered ring with negative charge and 50. F
alternate double bonds is aromatic. The molecule is
polar. I F

0 F
36. 200  m  10  0.40
2 2
e1/ h  0 e1/ h 1

51. f '    Lim

  lnh
0  Lim lnh  Lime h2
m  204 h0 h h  0 e h0

1
0
m  204  10  0.1  203 Scm2m1 as h  0, − ends to  at a much faster rate as
h2
37. NO is present as positive ligand 
1
 lnh
compared to –lnh    Lime h2 =0
 h0
38. NH4NO3  N2O  2H2O
Thus, f(x) is differentiable at x = 0
39. Dye-azo test
12 MOCK TEST 15
52. We must have, –1  x2 – 4x + 5  1            
56. (a  b)  (r  c)  (b  c)  (r  a)  (c  a)  (r  b)
  
If x2 – 4x + 5  1, then x2 – 4x + 4  0  (x – 2)2  0 P W V

x=2         
 P  (r  c)  W  (r  a)  (c  a)  V
If x2 + 4x + 5  –1, then x2 – 4x + 6  0  x  R.
            
Thus x = 2 is the only solution.  (P.c)r – (P.r )c  (W.a)r – (W.r )a  (c.V)a – (a.V)c
     
   [a b c]r  [a b r ]c  [b c a]r  [b c r ]a  [c r b]a  [a r b]c
 4  2a   0, a    2
2 4 
 2[a b c]r
2! 2
53. 1!9! + 3!7! + 5!5! 
10!
 10 C1   10!  10 C3   10!  10 C5 
1 2 2 1
57. cos0  cos   cos 2  cos 3  cos 4  cos 5  cos 6
7 7 7 7 7 7
 2 3  3   2 

1
10!
 10
C1  10C9  10C3  10C7  10C5   1  cos
7
 cos
7
 cos
7
 cos   
 7
  cos   
7


 
9 a  cos    
1 10 1  2  8  given .  7

10!
2  
10!  2b !
 
 2 3 3 3 2 
 1  cos  cos  cos   cos  cos  cos
 3a = 9, 2b = 10  a = 3, b = 5 7 7 7 7 7 7 7
=1
Also a, b, c are in A.P.
58. P(2, 3)
 c = 7.
b 2  c 2  a2 25  49  9 13 A
cos A   
2bc 2.5.7 14

a 2  c 2  b 2 9  49  25 11
cosB   
2ac 2.3.7 14
PM is maximum if required line  intersection of
13  11 24 12
 cosA + cosB =   3x + 4y + 6 = 0
14 14 7
 (–2, 0)
54. If we reflect y = |x – 2| in y-axis, it will become
x+y+2=0
y = |–x –2| = |x + 2|
30 3
mAP  
Hence, reflected lines are y = x + 2, y = –x – 2 22 4
Their combined equation is (y – x – 2)(y + x + 2) = 0 Slope m  –
4
3
 y2 – x2 – 4x – 4 = 0
4
55. Equation of tangent at ‘P’ is y  0  – (x  2)  4x  3y  8  0
3
3x + 4y = 25 ....(i) 59. x2 + y2 – 4x – 2y – 20 = O, P(10, 7)
Let C be (h, k) then AB is chord of contact of ‘C’. S1 = 100 + 49 – 40 – 14 – 20 > 0
P lies outside
C(h, k)
O(2, 1), r 4  1  20  r=5
A
greatest distance = PA = PO + OA
P 82  62  5  10  5  15
60. y2 = 4x a=1
B
P(t2, 2t) t1t2 = –1 For focal chord
1
2 2
x + y = 81 t2  –
x2 + y2 = 25 t
 1 2 
This equation of AB is, Q 2 , 
t t 
hx + ky = 81 ...(ii)
2 2
 1  2
(i) and (ii) are equations of same line PQ   t 2  2    2t  
 t   t
h k 81 243 81 2 2
   h , k   1  1  1
3 5 25 25 5  t   t    4  t  
 t  t  t
 MOCK TEST 15 13

61. If PA + PB = k, where k > AB, then locus of Z is 68. 3400 = (32)200 = (9)200 = (10 – 1)200
ellipse = 200C010200 + 200C110199 + 200C210198 + ……
62. f  x   f  x  2   2·f  x  1 200
C199101 + 200C200100 – [200C010198 + 200C110197
Substituting xx2 + 200C210196 + 200C198] + 200C199101 + 200C200100
f  x  2   f  x  4   2f  x  3  = (k)100 + 200(10) + 1(1) = (k + 20)100 + 01
Adding So last two digits is 01.
f  x   2f  x  2   f  x  4   2  f  x  1  f  x  3   69.
3
7 1
 2· 2f  x  2  0 0 10
3 0 7
 f  x   f  x  4  0
6 0 4
f  x  4  f  x  8  0 9 0 1
3 7 0
 f  x   f  x  8
0 7 3
63. For function to be onto range = co-domain
 no. of terms are 6
 
x 
2 2
 cot 1 2
 2x  a should take all values from  0, 2  70. Let centre (h, k) & circle; x + y + 2gx + 2fy + c = 0
 
h = –g, k = – f; For S : g = 2, f = – 3, c = 9,
 x 2  2x  a should take all values from 0,  1 1 1 1

5
 D  0  4  4a  0  a  1 For S : g =   2 , f = 2, c = – 2;  2.g.2 + 2.f(–3)
2 2 2 2
64. Equation of tangent to x 2  4ay will be in the form =c+9
 4g – 6f = c + 9 … (1)
y  mx  am2
 –5g + 4f = c – 2 … (2)
3
a 2 8 Subtract (2) from (1), – 9g + 10f = 11
  2    a 
3 3 3
 9x – 10y + 11 = 0
65. Let P(h, k) be a point in the locus
Equation of chord of constant is hx + ky = a2. 71. r  r    r   r    r  r  1
2 2
 
Pair of lines passing through origin & points of cotact 10 10

 hx  ky 
2
 (r  )(r  )   (r 2
 r  1)  450
is x y a 
2 2
2 
2
r 1 r 1
 a 
 10
As angle between pair of lines is 90° cos  (r  )(r  )  cos 2  1
225 r 1
 h2  k 2  2
 2  a2  4    2
 a   1

1   1 1 
  
   
72.  
 Locus is x2 + y2 = 2a2  cos A 4 cos2 A  3 sin A 3  4 sin2 A   cos3A sin3A 
 
x y z t
66. a = b = c = d = k(let)  2 2 2 2 
A  5      24
x log a = log k, y log b = log k  3 1 3  1 

z log c = log k, t log d = log k
73. 1  x 84  184C1 x  84C3 x2  84C3 x3  84C4 x4  84C5x5  84C6 x6  ....
a, b, c, d in G.P.
 log a, log b, log c, log d in A.P..  x  1
4
 x 6  6x 5  15x 4  20x 3  15x 2  6x  1
logk logk logk logk
 , , , in A.P.. 84
x y z t C 4  6· 84 C 5  15· 84 C 6  20· 84 C 7  15· 84 C8  6· 84 C9  84 C10  x10

1 1 1 1
 , , , in A.P.  x, y, z, t in H.P.. in 1  x   x  1  90C10
84 6
x y z t

1 
1 1 
 1 1  sin 22 
67.  r 2  2    r  1r  1  2   r  1  r  1 sin 1 2  
·cos 22.5 
1 2 1 2 1 2 cos1   cos 2   ...  cos 44 
74. x 
sin1   sin 2   ...  sin 44  sin 22 
1 1 1 1 1 1 1 1  ·sin 22.5 
 1            sin 1 2  
2 3 2 4 3 5 n 1 n 1 
1 
n   0 cot    2  1  2.414
n +1 8
1  1 3
 1 
2  2  4
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Solved Papers 2019
(January & April)
SOLVED PAPER
(JANUARY 2019)



 
 

×  
 

 

 
 ×

× × ×

× ×
× ×
 ° °

°
 °

NEt
Asn  Ser  (CH3CO)2 O 
3
P
(excess)

×
×
 


  
 






 


   

  

 



 


26.

31.

27. By colour coding,

R = 50 × 102 
I2 R = P
P
I= 20 mA
R
28.
Total = 12 GI.

H
32. S
T

T=

34. Total number of isotopes of hydrogen is 3 and no.

0.03 100 of radioactive isotopes among them is only 1.
Ycm from ground = 60 m
0.05 35. More polluted water has high biological oxygen
0.02 100 demand.
Vcm 40 m / s
0.05 36. Triclinic
2
37. Major product will be Due to

Height above building = 80 – 40 E2 elimination and extended conjugation

= 40 m Ea / RT
38. K = Ae
29. dM = di A
(i) is true but (ii) is false
dq (ii) should be
x2
2

( dx) x2
2

30.

39. Answer should be

3
FR = mR2 40. (Ph3P)3 RhCl
2
41. Density of DCM is higher than H2O.
42. Adipic acid will give unstable 7 membered
anhydride.
43. Electron withdrawing group enhances the rate of
55.
hydrolysis.
44. K.E = h – h, So (B) is not correct.
45. Combustion of coal 0.4 × 7 × 10 3 = YA × 104
46. Atomic & ionic radii decreases. YA = 0.28
47. Allylic radical will form in presence of sunlight.
YB = 1 -0.28 = 0.72.
48. 56. NaBH4 don’t reduce ester.
57. Be is used for making x-ray tube window.
58. Higher the Ka value lower the pKa value.
59. Hall-Herolut’s process is given by



 
  

At cathode:  

At anode: 
2C + 3O2  3CO2()
O CH2 OH
 
49. NH 2 – C  C  NH  CH  CO2 H 60.

CH2

CONH2
NEt
Asn  Ser  (CH3 CO)2 O 
3
P
excess
P is

     
50.
 
 
 

E.N. of Al = 1.5  Be(1.5)  

 
 
52. Lesser the SRP value higher the reducing power.
53. H2O2 act as oxidising agent and reducing agent in
acidic medium as well as basic medium
54. Ca(OH) 2 + Na2SO4  CaSO4 + 2NaOH
100 m mol 14 m mol — —
— — 14 m mol 28 m mol
  
 
 

  

 
      
    
  

   
    

 
     
      
     
  
  
     
     
   

   
 
 

        

   


     

 
 

   
 

     

   

   
 
   
   
    
   

  

    
    



  

  


  

 
    
 
 

     
 

 
  
  
 
  


 
 
 

       

     

       
            
 

  

  

  

   
 
 

  
 
 

  

   
    


    

  

 
  

       

 

      

 
  
   
   

   
    
        
   
    
   
  
  
  
     

  
 

      
  

       
   
   
  
     
   


   

   
  
 

   
 



 


 
    

  

    

     

  

     

          

 

 
  
 

    

      

       

    

  
 

    


  
 

   
          
   
  
 
  

  
 

 
 
       
 
       
 

 

     
 
   
   
 



 

     
 SOLVED PAPER
(APRIL 2019)
5. An alternating voltage (t) = 220 sin100 t volt is
applied to a purely resistive load of 50. The time
1. Four identical particles of mass M are located at taken for the current to rise from half of the peak
the corners of a square of side ‘a’. What should value to the peak value is:
be their speed if each of them revolves under the
(a) 7.2 ms (b) 5 ms
influence of others’ gravitational field in a circular
orbit circumscribing the square? (c) 2.2 ms (d) 3.3 ms
6. A boy’s catapult is made of rubber cord which is
42 cm long, with 6 mm diameter of cross-section
and of negligible mass. The boy keeps a stone
weighing 0.02 kg on it and stretches the cord by
20 cm by applying a constant force. When
released, the stone flies off with a velocity of
GM GM 20 ms–1. Neglect the change in the area of cross-
(a) 1.21 (b) 1.41
a a section of the cord while stretched. The Young's
GM GM modulus of rubber is closest to:
(c) 1.16 (d) 1.35 (a) 106 Nm–2 (b) 103 Nm –2
a a
2. Two particles move at right angle to each other. (c) 108 Nm–2 (d) 104 Nm –2
Their de Broglie wavelengths are 1 and  2 7. The reverse breakdown voltage of a Zener diode
respectively. The particles suffer perfectly is 5.6 V in the given circuit.
inelastic collision. The de Broglie wavelength ,
of the final particle, is given by:

(a) (b)
2

(c) (c)
The current Iz through the Zener is:
(a) 7mA (b) 15mA
3. In SI units, the dimensions of µ0 (c) 10mA (d) 17mA
3
(a) 2 (b) A–1T ML3 8. Two identical beakers A and B contain equal
(c) AT2 M–1L–1 (d) A2T3M–1L–2 volumes of two different liquids at 60°C each and
left to cool down. Liquid in A has density of
4. A particle moves in one dimension from rest under
the influence of a force that varies with the 8 × 102 kg/m3 and specific heat of 2000J kg–1 K–1
distance travelled by the particle as shown in the while liquid in B has density of 103 kg m–3 and
figure. The kinetic energy of the particle after it specific heat of 4000J kg –1 K –1. Which of the
has travelled 3 m is: following best describes their temperature versus
time graph schematically? (Assume the emissivity
of both the beakers to be the same)

(a)

(a) 5 J (b) 6.5 J

(c) 4 J (d) 2.5 J

(b)
(c)
(d)
9. A plane electromagnetic wave travels in free space
along the x-direction. The electric field component
of the wave at a particular point of space and time
is E = 6 Vm–1 along y-direction. Its corresponding
magnetic field component, B would be:
(a) 2 × 10–8 T along z-direction
(b) 6 × 10–8 T along z-direction
(c) 6 × 10 –8 T along x-direction
(d) 2 × 10 –8 T along y-direction
10. A wire of length 2L, is made by joining two wires
A and B of same length but different radii r and
2r and made of the same material. It is vibrating
at a frequency such that the joint of the two wires
forms a node. If the number of antinodes in wire
A is p and that in B is q then the ratio p : q is:
(a) 1 : 2 (b) 3 : 5
(c) 1 : 4 (d) 4 : 9
11. Radiation coming from transitions n = 2 to n = 1
of hydrogen atoms fall on He+ ions in n = 1 and
n = 2 states. The possible transition of helium
ions as they absorb energy from the radiation is:
(a) n = 2  n = 3 (b) n = 2  n = 4
(c) n = 2  n = 5 (d) n = 1  n = 4
12. For the circuit shown, with R1 = 1.0, R2 = 2.0 ,
E1 = 2V and E2 = E 3 = 4V, the potential difference
between the points ‘a’ and ‘b’ is approximately
(in V) :
(a) 3.3
(b) 2.7
(c) 3.7
(d) 2.3
13. Voltage rating of a parallel plate capacitor is
500 V. Its dielectric can withstand a maximum
electric field of 106 V/m. The plate area is 10–4 m2.
What is the dielectric constant if the capacitance
is 15 pF? (given 0 = 8.86 × 10–12 C2/Nm 2)
(a) 6.2 (b) 4.5
(c) 3.8 (d) 8.5
14. A solid conducting sphere, having a charge Q, is
surrounded by an uncharged conducting hollow
spherical shell. Let the potential difference
between the surface of the solid sphere and that
of the outer surface of the hollow shell be V. If
the shell is now given a charge of –4 Q, the new
potential difference between the same two
surfaces is :
(a) 4V (b) –2V
(c) 2V (d) V
15. A thin strip 10 cm long is on a U shaped wire of
negligible resistance and it is connected to a spring
of spring constant 0.5 Nm–1 (see figure). The
assembly is kept in a uniform magnetic field of
0.1 T. If the strip is pulled from its equilibrium
position and released, the number of oscillations
it performs before its amplitude decreases by a
factor of e is N. If the mass of the strip is 50 grams,
its resistance 10 and air drag negligible, N will
be close to :
(a) 5000
(b) 1000
(c) 50000
(d) 10000
16. An upright object is placed at a distance of 40 cm
in front of a convergent lens of focal length
20 cm. A convergent mirror of focal length 10 cm
is placed at a distance of 60 cm on the other side
of the lens. The position and size of the final
image will be:
(a) 40 cm from the convergent lens, twice the size
of the object
(b) 40 cm from the convergent mirror, same size
as the object
(c) 20 cm from the convergent mirror, twice the
size of the object
(d) 20 cm from the convergent mirror, same size
as the object
17. A steel wire having a radius of 2.0 mm, carrying 22. A circular coil having N turns and radius r carries
a load of 4 kg, is hanging from a ceiling. Given a current I. It is held in the XZ plane in a magnetic
that g = 3.1  ms–2 , what will be the tensile stress field Biˆ . The torque on the coil due to the
that would be developed in the wire?
magnetic field is:
(a) 5.2 × 10 6 Nm –2 (b) 4.8 × 10 6 Nm–2
(c) 6.2 × 10 6 Nm –2 (d) 3.1 × 10 6 Nm–2 Br 2I
(a) (b)
18. A thermally insulated vessel contains 150 g of water N
at 0°C. Then the air from the vessel is pumped (c) zero (d) Br2 IN
out adiabatically. A fraction of water turns into ice 23. If 1022 gas molecules each of mass 10 –26 kg collide
and the rest evaporates at 0°C itself. The mass of with a surface (perpendicular to it) elastically per
evaporated water will be closest to: (Latent heat
second over an area 1 m2 with a speed 104 m/s,
of vaporization of water = 2.10 × 106 J kg–1 and
the pressure exerted by the gas molecules will
Latent heat of fusion of water = 3.36 ×105 J kg–1)
be of the order of :
(a) 35 g (b) 20 g
(a) 1016 N/m2 (b) 103 N/m 2
(c) 130 g (d) 150 g
(c) 104 N/m 2 (d) 108 N/m 2
19. A thin circular plate of mass M and radius R has
its density varying as (r) = 0 r with 0 as constant 24. In figure, the optical fiber is l = 2 m long and has
and r is the distance from its center. The moment a diameter of d = 20µ m. If a ray of light is incident
of Inertia of the circular plate about an axis on one end of the fiber at angle 1= 40°, the
perpendicular to the plate and passing through number of reflections it makes before emerging
its edge is I = a MR 2 . The value of the coefficient from the other end is close to : (refractive index
a is: of fiber is 1.31 and sin 40° = 0.64)
3 3
(a) (b)
2 5
8 1
(c) (d)
5 2
20. A 20 Henry inductor coil is connected to a 10 ohm
resistance in series as shown in figure. The time (a) 45000 (b) 55000
at which rate of dissipation of energy (Joule’s heat)
across resistance is equal to the rate at which (c) 66000 (d) 57000
magnetic energy is stored in the inductor, is: 25. A 200 resistor has a certain color code. If one
2 replaces the red color by green in the code, the
(a) new resistance will be :
ln 2
1 (a) 300 (b) 100
(b) ln 2
2 (c) 400 (d) 500
(c) 2 ln 2 26. The bob of a simple pendulum has mass 2 g and a
(d) ln 2 charge of 5.0µC. It is at rest in a uniform
21. Four particles A, B, C and D with masses mA = m, horizontal electric field of intensity 2000 V/ m. At
mB = 2m, mC = 3m and mD = 4m are at the corners equilibrium, the angle that the pendulum makes
of a square. They have accelerations of equal with the vertical is (take g = 10 m/s2)
magnitude with directions as shown. The (a) tan–1 (2.0) (b) tan–1 (0.5)
acceleration of the centre of mass of the particles (c) tan–1 (0.2) (d) tan–1 (5.0)
is:
27. Ship A is sailing towards north-east with velocity
a
(a) where î points east and ˆj
5
north. Ship B is at a distance of 80 km east and
(b) Zero 150 km north of Ship A and is sailing towards
west at 10 km/hr. A will be at minimum distance
(c) from B in:
(a) 3.2 hr (b) 2.6 hr
a
(d) (c) 4.2 hr (d) 2.2 hr
5
28. In an interference experiment the ratio of
a1
amplitudes of coherent waves is The ratio
(c)
of maximum and minimum intensities of fringes
will be:
(a) 2 (b) 18
(c) 4 (d) 9
29. Water from a pipe is coming at a rate of 100 liters
per minute. If the radius of the pipe is 5 cm, the (d)
Reynolds number for the flow is of the order of :
(density of water = 1000 kg/m 3, coefficient of
viscosity of water = 1 mPa s)
33. If solubility product of Zr3 (PO4) 4 is denoted by
(a) 104 (b) 103 KSP and its molar solubility is denoted by S, then
(c) 102 (d) 106 which of the following relation between S and KSP
30. The wavelength of the carrier waves in a modern is correct?
optical fiber communication network is close to: 1 1
(a) 600 nm (b) 2400 nm (a) S (b) S
(c) 1500 nm (d) 900 nm
1 1

(c) S (d) S
31. For the reaction 2A + B  C, the values of
initial rate at different reactant concentrations 34. Maltose on treatment with dilute HCl gives:
are given in the table below. The rate law for the (a) D-Glucose and D-Fructose
reaction is:
(b) D-Glucose
Initial Rate (c) D-Fructose
(d) D-Galactose
0.05 0.05 0.045 35. The IUPAC name of the following compound is:
0.10 0.05 0.090 CH3 OH
0.20 0.10 0.72 | |

(a) Rate = k[A]2 [B]2 (b) Rate = k[A]2 [B]

(a) 3-Hydroxy-4-methylpentanoic acid
(c) Rate = k[A][B] (d) Rate = k[A][B]2
(b) 4,4-Dimethyl-3-hydroxybutanoic acid
32. The major product of the following reaction is:
(c) 4-Methyl-3-hydroxypentanoic acid
(d) 2-Methyl-3-hydroxypentan-5-oic acid
36. The quantum number of four electrons are given
below:

I. n = 4 I = 2 m1 = –2 ms

II. n = 3 I = 2 m 1 = 1 ms
(a)
III. n = 4 I = 1 m1 = 0 ms

IV. n = 3 I = 1 m1 = 1 ms

The correct order of their increasing energies

(b) will be:
(a) IV > III > II >I (b) I > II > III > IV
(c) I > III > II > IV (d) IV > II > III > I
37. Diborane (B2H6) reacts independently with O2 and
H2O to produce, respectively:
(a) B2O3 and H3BO3 (b) H3BO3 and B2O3 (c)
(c) B2O3 and [BH4]– (d) HBO2 and H3BO3
38. 100 mL of a water sample contains 0.81 g of
calcium bicarbonate and 0.73 g of magnesium
bicarbonate. The hardness of this water sample
expressed in terms of equivalents of CaCO 3 is: (d)
(molar mass of calcium bicarbonate is 162 g mol–1
and magnesium bicarbonate is 146 g mol –1 )
(a) 1,000ppm (b) 100 ppm
(c) 10,000 ppm (d) 5,000 ppm 43. Which of the following amines can be prepared
by Gabriel phthalimide reaction ?
39. The correct order of hydration enthalpies of alkali
metal ions is: (a) n- butylamine (b) neo-pentylamine
(a) Li+ > Na+ > K+ > Cs+ > Rb+ (c) t-butylamine (d) triethylamine
(b) Na+ > Li > K+ > Rb+ > Cs+ 44. Given that
(c) Na+ > Li+ > K+ > Cs+ > Rb+
(d) Li+ > Na+ > K+ > Rb+ > Cs+
40. For silver, C P(K–1 mol–1) = 23 + 0.01T. If the
temperature (T) of 3 moles of silver is raised from
300 K to 1000 K at 1 atm pressure, the value of
H will be close to :
The strongest oxidizing agent is:
(a) 21 kJ (b) 62 kJ
(a) Br2 (b) O2
(c) 16 kJ (d) 13 kJ
41. The correct order of the spin-only magnetic moment (c) Au3+ (d) S2 O82
of metal ions in the following low- spin complexes, 45. Assertion : Ozone is destroyed by CFCs in the
[V(CN) 6 ] 4– , [Fe(CN) 6 ] 4– , and upper stratosphere.
Reason : Ozone holes increase the amount of
is UV radiation reaching the earth.

(a) V2+ > Cr2+ > Ru3+ > Fe2+ (a) Assertion and reason are incorrect

(b) V2+ > Ru3+ > Cr2+ > Fe2+ (b) Assertion is false, but the reason is correct

(c) Cr2+ > V2+ > Ru3+ > Fe2+ (c) Assertion the reason is the correct explanation
for the assertion
(d) Cr2+ > Ru3+ > Fe2+ > V2+
(d) Assertion and reason are correct, but the
42. Coupling of benzene diazonium chloride with
reason is not the explanation for the assertion
1-naphthol in alkaline medium will give:
46. Adsorption of a gas follows Freundlich adsorption
isotherm. x is the mass of the gas adsorbed on
x
mass m of the adsorbent. The plot of log
m
(a) x
versus log p is shown in the given graph. is
m
proportional to :

3
(b)
(a) P 2 (b) P3
2
(c) P 2 (d) P 3
47. With respect to an ore, Ellingham diagram helps
to predict the feasibility of its
(a) Thermal reduction (b) Electrolysis
(c) Zone refining (d) Vapour phase refining
48. The major product of the following reaction is:
54. The major product of the following reaction is:
(a) (b)
53. The vapour pressures of pure liquids A and B are
400 and 600 mmHg, respectively at 298 K. On
mixing the two liquids, the sum of their initial
volumes is equal to the volume of the final
mixture. The mole fraction of liquid B is 0.5 in
the mixture. The vapour pressure of the final
solution, the mole fractions of components A and
B in vapour phase, respectively are:
(a) 500 mmHg, 0.4, 0.6
(b) 450 mmHg, 0.4, 0.6
(c) 500 mmHg, 0.5, 0.5
(d) 450 mmHg, 0.5, 0.5

(c) (d)
(a) (b)
49. In order to oxidise a mixture of one mole of each
of FeC2O4, Fe2(C2O4) 3, FeSO4 and Fe2(SO4)3 in
acidic medium, the number of moles of KMnO 4
required is:
(c) (d)
(a) 1.5 (b) 3
(c) 2 (d) 1
55. Element ‘B’ forms ccp structure and ‘A’ occupies
50. The following ligand is
half of the octahedral voids, while oxygen atoms
occupy all the tetrahedral voids. The structure of
bimetallic oxide is:
(a) AB2O4
(b) A2B2O
(c) A2BO4
(d) A4B2O
(a) tetradentate (b) bidentate
56. An organic compound neither reacts with
(c) hexadentate (d) teidentate neutral ferric chloride solution nor with Fehling
51. Which is wrong with respect to our responsibility solution. It however, reacts with Grignard reagent
as a human being to protect our environment ? and gives positive iodoform test. The compound
(a) Avoiding the use of floodlighted facilities is :
(b) Setting up compost tin in gardens
(c) Restricting the use of vehicles
(d) Using plastic bags (a) (b)
52. In the following compounds, the decreasing order
of basic strength will be:
(a) (C2H5) 2 NH > NH3 > C 2H5 NH2
(b) (C2H5) 2 NH > C2H5NH2 > NH3
(c) C2H5NH2 > NH3 > (C2H5)2 NH (c) (d)
(d) NH3 > C2H5 NH2 > (C2 H5) 2 NH
57. An organic compound ‘X’ showing the following 64. The sum of the series 2. 20C0 + 5. 20C1 + 8. 20C2 +
solubility profile is: ....... + 62. 20C20 is equal to
(a) 223 (b) 224
(c) 226 (d) 225
65. Let A and B be two non-null events such that
. Then, which of the following statements

(a)

(a) m – Cresol (b) Benzamide (b)

(c) Oleic acid (d) o-Toluidine (c)
58. The size of the iso-electronic species Cl–, Ar and (d)
Ca2+ is affected by: 66. The magnitude of the projection of the vector
(a) Nuclear charge
on the vector perpendicular to the plane
(b) Principal quantum number of valence shell
containing the vectors and is
(c) Azimuthal quantum number of valence shell
(d) Electron-electron interaction in the outer 3
orbitals (a) (b) 3 6
2
59. Which one of the following equations does
3
not corre ctly represent the first la w of (c) 6 (d)
thermodynamics for the given processes involving 2
an ideal gas? (Assume non-expansion work is zero) 67. The sum of all natural numbers ‘n’ such that
(a) Isothermal process: q = –w 100 < n < 200 and H.C.F. (91, n) > 1 is:
(b) Cyclic process: q = –w (a) 3303 (b) 3121
(c) Isochoric process: U = q (c) 3203 (d) 3221
(d) Adiabatic Process: U = –w 68. Let y = y(x) be the solution of the differential
60. The lanthanide ion that would show colour is : equation,
(a) Lu3+ (b) Sm3+ such that y(0) = 0.
(c) La3+ (d) Gd3+
If then the value of ‘a’ is:
1
(a) (b) 1
61. If then f is 4
equal to 1 1
(c) (d)
16 2
(a) 2f(x) (b) (f(x))2
69. The shortest distance between the line y = x and
(c) 2f(x2) (d) –2f(x)
the curve y2 = x – 2 is
62. All possible numbers are formed using the digits
1,1,2,2,2,2,3,4,4, taken all at a time. The number 11 7
(a) (b)
of such numbers in which the odd digits occupy 4 2 8
even places is:
7
(a) 160 (b) 162 (c) 2 (d)
4 2
(c) 175 (d) 180

63. If f x and g(x) = loge x, (x > 0) then 70. If and

then (2) is equal to

the value of the integral is 63 33

(a) (b)
16 52
(a) loge 3 (b) loge 1 63 21
(c) (d)
(c) loge 2 (d) loge e 52 16
 77. The sum of the co-efficient of all even degree
71. Let A , such that
6 6
32 is equal to:
A then a value of  is
(a) 32 (b) 24
(c) 29 (d) 26
(a) 0 (b)
32 78. If  and  be the roots of the equation x2 – 2x + 2 = 0,

(c) (d) then the least value of n for which = 1 is:

16 64
72. If S1 and S 2 are respectively the sets of local (a) 3 (b) 4
minimum and local maximum points of the (c) 2 (d) 5
function, f(x) = 9x4 + 12x3 – 36x2 – 25, x  R, then:
79. The equation of a plane containing the line
(a) of intersection of the planes 2x – y – 4 = 0 and
(b) y + 2z – 4 = 0 and passing through the point (1 , 1, 0) is:
(a) x – 3y –2z = –2 (b) x – y – z = 0
(c)
(c) 2x – z = 2 (d) x + 3y + z = 4
(d) 2
sin x
73. The mean and variance of seven observations are 80. lim equals:
8 and 16, respectively. If 5 of the observations
(a) 2 2 (b) 4
are 2,4,10,12,14, then the product of the
remaining two observations is: (c) 4 2 (d) 2
(a) 48 (b) 45 81.
(c) 40 (d) 49 (2, –1, 4) on the straight line, is:
74. A point on the straight line, 3x + 5y = 15 which is (a) Less than 2
equidistant from the coordinate axes will lie only
(b) Greater than 3 but less than 4
in
(c) Greater than 4
(a) 1st and 2nd quadrants
(d) Greater than 2 but less than 3
(b) 1st quadrant
82. Let O(0,0) and A(0,1) be two fixed points. Then
(c) 1st, 2nd and 4th quadrants
the locus of a point P such that the perimeter of
(d) 4th quadrant AOP is 4, is:
75. The sum of the squares of the lengths of the (a) 9x2 – 8y2 + 8y = 16 (b) 8x2 + 9y2 – 9y = 18
chords intercepted on the circle, x2 + y2 = 16 by
(c) 8x2 – 9y2 + 9y = 18 (d) 9x2 + 8y2 – 8y = 16
the lines, x + y = n, n  N, where N is the set of
all natural numbers, is: 83. The greatest value of c  R for which the system
of linear equations
(a) 210
x –c y – c z = 0
(b) 105
cx – y + c z = 0
(c) 160
cx + cy – z = 0 has non – trivial solution, is:
(d) 320
(a) –1 (b) 0
76. The contra positive of the statement “If you are
born in India then you are a citizen of India” is 1
(c) (d) 2
(a) If you are not born in India, then you are not 2
a citizen of India 84.
(b) If you are born in India, then you are not a
citizen of India
is
(c) If you are not a citizen of India then you are
59 53
not born in India (a) (b)
6 6
(d) If you are a citizen of India then you are born
26
in India (c) 8 (d)
3
85. If where
88. If then
 –  is equal to:
dy
is equal to:
(a) tan dx

(a) x (b)
(b) tan 3

(c) 2x (d)
6
(c) sin
89. If the tangents on the ellipse 4x 2 + y2 = 8 at the
points (1, 2) and (a, b) are perpendicular to each
(d) cos other, then a2 is equal to:
64 2
86. Let f:[0, 2]  R be a twice differentiable (a) (b)
17 17
function such that f (x) > 0, for all x (0, 2).
4 128
If (x) = f(x) + f(2 – x), then  is: (c) (d)
17 17
(a) Increasing on (0, 1) and decreasing on (1, 2)
5x
(b) Decreasing on (0, 1) and increasing on (1, 2)
90. dx is equal to:
(c) Decreasing on (0, 2)
(d) Increasing on (0, 2) 2
87. The sum of the solutions of the equation (Where c is a constant of integration)
(a) x + 2 sinx + 2 sin2x + c
is equal to:
(b) 2x + sinx + sin2x + c
(a) 10 (b) 4 (c) 2x + sinx + 2 sin2x + c
(c) 12 (d) 9 (d) x + 2 sinx + sin2x + c

1. (c) 2. (d) 3. (d) 4. (b) 5. (d) 6. (a) 7. (c) 8. (a) 9. (a) 10. (a)
11. (b) 12. (a) 13. (d) 14. (d) 15. (a) 16. (d) 17. (d) 18. (b) 19. (c) 20. (c)

21. (a) 22. (d) 23. (Bonus)24. (d) 25. (d) 26. (b) 27. (b) 28. (c) 29. (a) 30. (c)

31. (d) 32. (a) 33. (a) 34. (b) 35. (a) 36. (c) 37. (a) 38. (c) 39. (d) 40. (b)
41. (a) 42. (a) 43. (a) 44. (b) 45. (d) 46. (d) 47. (a) 48. (d) 49. (c) 50. (a)

51. (d) 52. (b) 53. (a) 54. (d) 55. (a) 56. (d) 57. (a) 58. (a) 59. (d) 60. (b)

61. (a) 62. (d) 63. (b) 64. (d) 65. (d) 66. (d) 67. (d) 68. (c) 69. (d) 70. (a)
71. (d) 72. (b) 73. (a) 74. (a) 75. (a) 76. (c) 77. (b) 78. (b) 79. (b) 80. (c)
81. (b) 82. (d) 83. (c) 84. (a) 85. (c) 86. (b) 87. (d) 88. (a) 89. (b) 90. (d)
 5.6
7. Current through 800  is
800
1. 3.4
a 2a Current through 200  is
200
Then current Iz is 10 mA.
8. We know,

GM
a 9.
   C
2.
Along z-direction
  
µ0

10.

Hence, p : q is 1 : 2

11. For hydrogen,

[1 and 2 are De-broglie wave lengths]

For He+,

Hence, transition is from n = 2  n = 4.


3. 12.
µ0 z

Hence, Dimension of µ 0 is
A2T3 M–1 L–2.

4.

Hence, Final K.E.=6.5 J

5. T

13.

6. We know, d

Hence, young’s modulus of rubber is closest to  K = 8.5

3 × 10 6 Nm –2
14. Initial :
M
3

Now, value of coefficient ‘a’ is

Final :

20.
dt

Hence, new potential difference between same L

two surfaces is V. T
15. Force on oscillating wire, is given by

20

t = T ln 2 = 2 ln 2

21. a cm
m
Time period T is
k
10
t
No. of oscillations is and t is given by t    
T

  
16. 22.


Hence, option ‘d’ is correct.

23.
17. Tensile stress is given by,
Pressure = 2Nm–2.
24. n1 sin1 = n2 sin 2.
1 × 0.64 = 1.31 sin 2.
18. mLv = (150 – m)Lf
m × 2.1 × 106 = (150 – m) (3.36 × 10 5) sin

tan
2 x
19.
d
x

No. of collisions
x
25. New resistance becomes 500.
2

26.
27. Velocity of A w.r.t B is CH3 OH
   | |
km/hr
35.
3-hydroxy-4-methylpentanoic acid
 
36. By aufbau rule.
IV < II< III< I
V
(3p)(3d) (4p) (4d)
I max
28. 37. Diborane burns in O2 forming B2O3.

29. Reynold number is given by,

Diborane hydrolyses in water producing H3BO3.

38. 162g of Ca(HCO3)2  100gCaCO3.

4
 Order of 4 100 ml sample contain 0.81g of Ca(HCO 3) i.e.,
6 equal to 5g of of CaCO3/lit and 0.73 g of Mg(HCO3)2
30. Wavelength used in modern optical fiber per 100ml is equal to 5g of CaCO 3 per lit. Total
communication is close to 1500nm. hardness is 10g per litre or 10,000 ppm
39. Hydration enthalpies of alkali metal ions decrease
down two group
31.
40. We know,
1000

r = 62KJmol–1.
41. V2+ has d 3 configuration of which all the 3 are
 a=1 unpaired electrons,
r Cr2+ has d4 configuration. On low spin the 4
electrons are arranged as one pair and 2 unpaired
electrons,
 b=2
Ru 3+ has d 5 configuration. In low spin the 5
Therefore, r = K[A] [B]2. electrons are arranged as 2 pairs and 1 electron
remain unpaired.
Fe2+ has d6 configuration. In low spin complex all
32. the six electrons are paired so no unpaired
electrons.
Hence, the corect order is given by first option.

42.

33. 



Let “s” be the solubility, then

Ksp = 6912 × s7
1

43. Only primary amine (n-butylamine) can be

prepared by Gabriel Pthalimide reaction with
34. D-glucose. better SN2.
44. Strongest oxidizing agent may have higher Formula of the compound
reduction potential in standard state. A2B4O8 i.e. AB2O4.
45. Ozone is destroyed by CFCs , due to which ozone Hence structure of Bimetallic oxide is AB2O4.
holes are formed. Through these holes the
amount ultraviolet radiation reaching the earth
increases
56.
46.
m m n

57.
47. Ellingham diagrams can be used for the thermal
reduction of ores.

58. Isoelectronic species contain same number of

48.
49. FeC2 O4 , Fe2 (C 2 O4 )3 , FeSO4 and Fe2 (SO4) 3
have valence factors as 3, 6,1 and 0 and that of
KMnO4 is 5. Therefore two moles of oxidizing
agent is required
50. Given ligand is tetradentate
51. Plastic bags are not biodegradable. So usage of
plastic bags causes much harm to environment
52. Basic strength in aq.solution:
shells so their size is effected by the nuclear charge.
59. For ideal gas
Isothermal process q = –w as U = 0
For isochoric process U = q, w = 0
For adiabatic processU = w, q = 0
60. La3+ (f0) ions are colourless ions.
61. By question,
e

53. A and B forms ideal mixture

of H8.
62. No. of ways = 4 C3
0
X A PA
YA
=

63.
YB = 1 – YA = 1 – 0.4 = 0.6

Given : f(x) = , g(x) = logex

54.

55. B forms Fcc lattice per unit cell

‘A’ occupies half the octahedral voids number of

octahedral voids 1 × 4 = 4
Per Unit cell 2 A atoms
Per unit cell 8 O atoms
64. A 32

65.
72. f’(x) = 36x3 + 36x2 – 72x
66. Magnitude of projection of vector is given by
= 36x (x2 + x – 2)
= 36x (x – 1) (x + 2)
 S1 = {–2, 1}, S2 = {0}
73. Let the remaining two observations are a,b
67. Given numbers are 101, 102, 103, …..199
Required value = sum of numbers divisible by – 64
7 + sum of numbers divisible by 13-sum of numbers
divisible by 91

74. Required point lies on y=x or x + y = 0

68. Required point is

dx

75.

76. If you are not a citizen of India then you are not
born in India
& y (0) 0  c = 0

77. 2

69. Equation of tangent to y2 = x – 2, which is parallel

Sum of coefficient of even powers of x
to y =x is y = x – 2 +
2

78. (x – 1)2 = –1 = i2  x = 1 ± i

70.
79. Equation of the line is

Equation of plane is

tan(2) = tan( +  +  – )

1 sin 2 x
80. lim

71. 2

A3
 86. f” (x) > 0  f’(x) is increasing in [0,2].
81.

(2, –1, 4)
For
Direction ratio’s

For

87. Here,

50
perpendicular distance = 3, 4
4
82. Given : O(0, 0) and A(0, 1) are two fixed points.
OP + AP + PA = 4  OP + AP = 3, locus of P is an
ellipse and equation to the locus is
88.
2
x

83. Given : x –c y – c z = 0, cx – y + c z = 0, cx + cy – 89. Equation of tangent at (1, 2) is 4x + 2y = 8

z=0

Equation of tangent (a, b) is

5x
1
84. 90. dx

2
85.
dx

= x + sin2 x + 2 sin x + c