Class___Index No. Candidate Name: jut sam) ~© FUHUA SECONDARY SCHOOL Secondary Four Express 4. E Ld Preliminary Examinations 2019 au Sed ba Scary Pa Seay Pa Sram us eva fab Siang Pl Sambar as saan Pb Semdty Fa Seon Fb Sela Pe Sent uae roan Pu Srmdny ts Sey Fab Soma Fa Send a Se) ad Seay Fal Sry Ps Sndaty us Senda Pa Stn sua Pala Seca Pla Satya Seay a Seony Fa Senda Pe Sen ue edn Pala Sern Ss Sey Sa Seconay Pla Sad ub Sey CHEMISTRY 6092/01 Paper 4 Multiple Choice 2 September 2019 0755-0855 1 hour READ THESE INSTRUCTIONS FIRST INSTRUCTIONS TO CANDIDATES Write in soft pencil Write your name and index number on the Answer Sheet in the spaces provided unless this has been ‘done for you. ‘There are forty questions on this paper. Answer all questions. For each question there are four possible answers A, B, C and D. Choose the one you consider correct and record your choice in soft pencil on the separate Answer Sheet Provided, Each correct answer will score one mark. A mark will not be deducted for a wrong answer. ‘Any rough working should be done in this booklet, A.copy of the Periodic Table is printed on page 13, ‘The use of an approved scientific calculator is expected, where appropriate. PARENT'S SIGNATURE. FOR EXAMINER'S USE 140 Setter. Mdm Hla Soo Ching Vetter: Mr Elton Tan This question paper consists of 13 printed pages including this page. www.KiasuExamPaper.com 173Multiple Choice Questions [40 marks] ‘Answer all questions and shade your answers on the OMR sheet provided. The graphs (not drawn to scale) show the heating curves of oxygen and nitrogen over a period of time. temperature / °C. ‘ime / minutes Ne 183; ~196 210 218 Which of the following statements about a mixture of oxygen and nitrogen is correct? A At-190°C, both oxygen and nitrogen exist as a liquid. B At-200°C, both oxygen and nitrogen exist in the same state © At -215°C, both nitrogen and oxygen molecules are vibrating about fixed positions, D_At-185°C, both oxygen and ogen molecules move rapidly in all directions. Refer to the following setup. filter funnel mixture evaporating dish t heat Which of the following mixtures can be separated into its components using this setup? A ammonium chloride and iodine B_copper(|l) sulfate and sodium chloride € potassium iodide and copper(II) sulfate D__ sodium chloride and ammonium chloride Which of the following substances does not contain atoms bonded to other atoms by four covalent bonds? graphite Polypropene silicon dioxide terylene voup 2 www.KiasuExamPaper.com 174The diagram shows the start of experiment 1 and 2 using gas jars of carbon monoxide and oxygen arranged in two different orientations. All other conditions are kept constant. carbon monoxide tia x carbon lid monoxide oxygen \ oxygen experiment 1 experiment 2 The lids are removed and the gases are allowed to mix Which of the following observations would you expect for the experiments? A. The rate of oxygen diffusing is much faster than rate of carbon monoxide diffusing in both experiments. B The rate of carbon monoxide diffusing is much faster in experiment 1 than in experiment 2 © Inexperiment 2, the final concentration of carbon monoxide in the top jar will be less than its original concentration. D__ The final concentration of carbon monoxide in the left jar in experiment 1 is the same as the final concentration of carbon monoxide in the top jar in experiment 2 A salt, P, on warming with aqueous sodium hydroxide, showed no visible reaction, When aluminium powder was added, a gas that turned damp red litmus paper blue evolved. What is salt P? A Ca(NOs)2 B KNOs C NH«Ci D NHsNO3 Tritium is an isotope of hydrogen and has the symbol T. \correct for a tritium compound? 3 www.KiasuExamPaper.com 17510 ‘Compound X contains two elements, metal Y and non-metal, Z. X consists of a lattice of positive and negative ions. Each positive ion is surrounded by eight anions and each negative ion is surrounded by four cations. What ions are present in, and what is the formula of, compound X? Tons present formula A YZ Yo B Yez- YZ2 c zye ZY Lo. ZY | 2Y2 Which of the following substances contain delocalised electrons? 1 iron 2 steel 3. diamond 4° graphite 1 and 2 2and 4 1,2 and4 2,3and 4 vom> Aqueous lead({I) nitrate can be distinguished from aqueous zinc nitrate by adding any of the following solution except A aqueous potassium chloride B_ aqueous sodium sulfate. C dilute sutfuric acia, D__ sodium hydroxide solution. 5g of element X reacted completely with 8 g of element Y to form a compound with the formula XY2 Given that the relative atomic mass of Y is 80, what is the relative atomic mass of x? 4 www.KiasuExamPaper.com 176"1 12 13 14 In an experiment, 8.0 cm? of 1.00 mol/dm? aqueous barium chloride was mixed with 8,0 cm? of 1.00 mol/dm? of aqueous silver nitrate. Which of the following ions are present in the solution produced? Batt cr vom> bw 8 a = Solutions P and Q were tested with a few drops of Universal Indicator. Solution P turned the indicator red while solution Q turned the indicator yellow. It can be deduced that Solution P has a higher pH than solution Q. Solution Q is more alkaline than solution P. Solution Q reacts with calcium carbonate to give carbon dioxide gas. The concentration of hydrogen ions in Q is higher than the concentration of hydrogen ions in solution P. vom> ‘Substance Y was added bit by bit, with stirring, to aqueous solution Z. The changes in pH of the mixture are shown in the graph 0” amount of substance ¥ added What could Y and Z be? Y Z A aluminium oxide hydrochloric acid B calcium oxide nitric acid Cc sodium oxide ethanoic acid [o_| zinc oxide propanoic acid An element bums in air to form a compound which does not react with both acids and alkalis. Which element could it be? aluminium ‘carbon iron phosphorus vom> 5 www.KiasuExamPaper.com 17715 16 17 18 19 Which of the following properties shows that a certain substance, M, is alkaline? A. Solution M dissolves copper(tl) oxide. B On adding dilute hydrochloric acid to solution M, carbon dioxide is given off. Solution M when warmed with aqueous ammonium chloride gives off ammonia gas, D_ Solution M forms brown precipitate when reacted with iron(lll) chloride solution. In which of the following experiments will a redox reaction occur? A Adding nitric acid to aqueous ammonia B Adding copper turnings to aqueous silver nitrate © Adding chlorine water to aqueous potassium fluoride. D_ Adding aqueous sodium hydroxide to aqueous copper(|) nitrate. In which of the following does vanadium have the lowest oxidation number? vr vor NH«VOs V20s com> In an experiment, two different metal rods, X and Y, were dipped in dilute sulfuric acid, with their top ends touching. A gas was collected around rod Y. rod X rod ¥ sulfuric acid Which of the following can you conclude about this experiment? A B c D Electrons flow from rod Y to X Rod X is more reactive than rod Y. Rod Y reacts with acid to produce hydrogen gas. lons of Y can be found in the solution but not ions of x Which of the following reactions is not involved in the manufacture of iron from the blast furnace? Coke burns in air to form carbon dioxide. Acidic impurities are removed by calcium oxide. Limestone is decomposed to form calcium oxide. Haematite is reduced by carbon dioxide to form iron vom> 6 www.KiasuExamPaper.com 17820 24 22 23 W, X, Y and Z are four metals which form cations W*, X2*, Y* and Z2 The following are information on some of the reactions that the metals undergo, X**(aq) + W(s) > no reaction Z2*(aq) + 2W(s) -» 2W*(aq) + Z(s) Y2C0s(8) ““ no reaction Z(s) + 2H'(aq) > Zag) + H2(9) The order of decreasing reactivity of the metals are A X,W.ZY. B XY,Z,W. c Y,X,W,Z. D ZWXY. Which of the following method is most likely used to extract an element with an electronic structure of 2.8.8.2? electrolysis of its aqueous chloride electrolysis of its molten ore reduction with carbon reduction with hydrogen voup Part of the Periodic Table is shown below. Elements W, X and Y have high melting points. Y is less reactive than W. Z can form both ionic and covalent compounds. X and Y form compounds that are coloured. RON Which of the following statements are correct? A 23 B 12,3 Cc 23,4 Do 1,2,4 Which statement is most likely to be true for astatine, which is in Group VII of the Periodic Table? A Astatine is a stronger oxidising agent than chlorine. B__ Astatine reacts with hydrogen to form a compound with formula HAtz Aqueous potassium astatide reacts with aqueous silver nitrate to form aqueous silver astatide. D__ Sodium astatide is less stable than sodium chloride. 7 www.KiasuExamPaper.com 17924 25 26 27 Which of the following reactions is endothermic? 2H > He H20() > H20(g) 2H + O2 > 2H20 ‘CeH120s + 602 >» 6CO2 + 6H20 vouD> What are the effects of temperature of reactants and use of a catalyst on the activation energy and enthalpy change of a reaction? effect of temperature effect of catalyst activation energy | enthalpy change | activation energy | enthalpy change A decreases no change decreases no change B decreases decreases no change no change c no change no change decreases no change D nochange | nochange _| __ nochange _| __no change In the reaction between calcium carbonate and ethanoic acid, the following changes could be made to the conditions. 1 Increase the concentration of ethanoic acid 2 Increase the particle size of calcium carbonate. 3. Increase the temperature of the system. 4 Increase the pressure of the system. What changes would increase the rate of reaction? A tand2 B tand3 c 2and3 D 1,2,3and4 Refer to the following bond energy table bond bond energy /kJ mol F-F 158 H-H 436 HF 556. It can be deduced that the bonds in fluorine is the strongest. fluorine gas is more reactive than hydrogen gas hydrogen fluoride molecules are the least stable. the energy produced when forming 1 mole of hydrogen fluoride molecules from its elements is 518 kJ. com> 8 www.KiasuExamPaper.com 18028 Which statement is true for both simple and electrolytic cells, simple cell electrolytic cell A Treonvers electrical energy into Teconverts chemical energy into chemical energy. electrical energy. B | Oxidation occurs at negative electrode. Oxidation occurs at positive electrode ¢ | Electrons flow from the cathode to the | Electrons flow from the cathode to anode. the anode. D_|__ Mass of the anode will decrease. __|_Mass of the anode may increase. _| 29 Refer to the following electrolytic setup. All electrodes used are graphite. 30 molten zine bromide What could be observed after a few minutes? A Asilvery solid is formed at electrode W. A.red brown liquid is formed at electrode X. Apale yellow gas is formed at electrode Y A.colourless and odourless gas is formed at electrode Z D dilute sulfuric acid In electroplating a silver spoon with copper, which combination of anode, cathode and electrolyte is the most suitable? www.KiasuExamPaper.com 181 anode cathode electrolyte A copper silver spoon copper(ll) nitrate solution B copper silver spoon silver nitrate solution c silver spoon copper copper(ll) nitrate solution bd | silver spoon copper silver nitrate solution | 931 Some properties of substances P, Q, R and S are given in the table below. 32 33 34 substance | percentage electrical effect of heat composition by | conductivity when mass solid P constant yes ‘solid burns in air to form an oxide. a varies no liquid burns to form carbon dioxide and water. R constant no Solid decomposes to form two products, s varies yes solid melts Which classification of the substances as an element, a mixture or a compound is correct? element mixture ‘compound a P Ss QR B s Q PLR c R s P,Q D P as I R ‘Ammonium nitrate, NH4NOs, ammonium sulfate, (NHs)2SOx, urea, (NH2)2CO and ammonium phosphate, (NH4)2POs are all fertilisers that can be produced from ammonia. Which of these contains the most nitrogen per kilogram of fertiliser? ammonium nitrate ammonium sulfate ammonium phosphate urea voup The Haber process is a reversible reaction as some of the ammonia formed is unstable as it decomposes readily back into its reactants Which of the following method is used to prevent this from happening? ‘A Adding water to dissolve ammonia B Cooling the mixture to liquefy ammonia C Filter the mixture to remove ammonia D Fractional distil the mixture to separate ammonia gas. What is the volume of air required for a mixture of 20 cm? of methane and 40 cm? of carbon monoxide to burn completely? 60 cms 80 cm® 300 cm? 400 cm? com> 10 www.KiasuExamPaper.com 18235 Which of the following reagents could be used to distinguish between samples of 36 ethanol and ethanoic acid? 1 aqueous bromine 2 sodium carbonate 3 aqueous sodium chloride 4 litmus solution A tand2 B 2and3 © 2and4 D 1,2and4 How does the number of carbon, hydrogen and oxygen atoms in an ester differ from the total number of carbon, hydrogen and oxygen atoms in the alcohol and ‘carboxylic acid from which the ester was derived? carbon atoms hydrogen atoms oxygen atoms a same same same B less same less c same less less {o_| less | less less 37 Which of the following tests can be used to distinguish the following organic 38 compounds, |, II and Ill separately from each other. 1_|Adding aqueous bromine. test |2__[ Adding powdered magnesium. |___ [3 [Warming with acidified potassium manganate(Vil. A 1only B 2only © tand2 D 1,2and3 The chemical equation for a reaction is shown below. CHsCOOH + Brz CH2BrCOOH + HBr This reaction is an example of a/an A _ addition reaction. B condensation reaction. esterification reaction D substitution reaction. "1 www.KiasuExamPaper.com 18339 Asection of a polymer is shown below. 4 4 Which of the following shows a monomer involved in the formation of the above polymer? A oh Oo 5 rege wt t_ton 4 oft St wo-Lt{) ton > RR witb on 4 40 Three metal oxides each have the formula G2Os Which statements about these oxides are correct? 1 If the relative molecular mass for the oxide is 152, metal G is a transition element. 2 If the relative molecular mass for the oxide is 160, the oxide of metal G can react with both acid and alkali 3. If the relative molecular mass for the oxide is 102, the oxide of G is formed when metal G reacts with steam. A tand2 B 2and3 © 1and3 D 4,2and3 End of Paper 12 www.KiasuExamPaper.com 184