Professional Documents
Culture Documents
No.182
Opening Interview
Technological Development for Solving Social Issues 1
General Overview
Development and Demonstration toward Hydrogen Energy Introduction Essential
for Establishing a Decarbonized Society 3
Technical Description
Hydrogen Production
— Development of Hydrogen Production Technologies 17
Hydrogen Production
— Development of Hydrogen Liquefaction Systems 23
Hydrogen Storage
— Development of Liquefied Hydrogen Terminal 29
Hydrogen Transportation
— Development of Liquefied Hydrogen Carrier 35
Hydrogen Utilization
— Development of Hydrogen Fueled Power Generation Technologies 41
Hiroshi Nakatani
Director, Managing Executive Officer
General Manager, Corporate Technology Division
1
gained from past projects to other projects, and technology, we aim to solve some of the issues we
produce synergistic effects as a comprehensive heavy will face, such as labor shortages and environmental
industry manufacturer that transcends business problems.
boundaries, such as through the development of Furthermore, we are focusing our strengths on
motorcycles that integrate gas turbine technologies. promoting the creation of a hydrogen-based society as
Furthermore, by envisioning the near future of our a new business opportunity to solve the two problems
business segments, we propose products and of global warming and resource depletion in the
services that solve the problems surrounding society future.
and create technologies that will support future
generations.
What is your efforts to
achieve a hydrogen-based
What are some business society?
sectors you are focusing on
Utilizing our proprietary cryogenic technology,
for the future?
which makes large-volume transportation of hydrogen
We are focusing on market development for new possible by liquefying hydrogen, we began leading the
fields in the robotics business as a business way in efforts to achieve a hydrogen-based society
opportunity to address social issues such as the about 10 years ago, ahead of our competitors.
declining birthrate and aging population, as well as the Specifically, we have been developing technologies
shrinking working population. In order to address the and products that are used in each step along the
problem of our rapidly aging society and to respond to hydrogen energy supply chain, which include
its needs, we will develop medical robots in production, transportation, storage, and utilization. To
cooperation with other companies to provide achieve a hydrogen-based society, we also need an
advanced medical care to as many patients as environment where hydrogen energy can be widely
possible. To address the problem surrounding the used by everyone. To achieve this, it is important to
decline in the working population, we are developing establish standards and rules for handling hydrogen,
technologies to enable the use of robots in a wide and we are the leading company involved in the
range of fields, such as duAro, a robot that is capable development of these standards and rules. We believe
of working in collaboration with humans, and that establishing these rules will make it easier to use
Successor, a robot that learns and reproduces human hydrogen energy around the world, and will also
skills. create opportunities and markets for our products and
In addition, we are currently working to provide services to spread worldwide.
services that offer added value by optimizing
operations and maintenance tasks as our initial efforts
Closing comments
to develop service-based businesses. Some examples
of these efforts include our remote monitoring service We believe that our various technological
for railroad tracks, which is currently under developments aimed at solving social issues will
development for commercialization, and our remote contribute to the sustainable management of our
monitoring system for gas turbines and gas engines, company. We will continue to make the utmost efforts
By combining hardware knowledge and digital in achieving our goals.
3
2,000
1,800
habitable land〔MWh/km2〕
1,400
Japan
1,200
1,000
Germany
800
Norway
600
400
World
China
200
U.S.
0 Australia
1980 1985 1990 1995 2000 2005 2010 2015
Time〔year〕
5. 0
4. 5
Japan
Annual primary energy consumption/
4. 0
habitable land〔ktoe/km2〕
3. 5
3. 0
2. 5
China
2. 0
Germany
1. 5
1. 0
EU
0. 5
U.S.
Norway
0. 0
2008 2013 Australia 2018
Time〔year〕
targets.
2 Japan’s strategy on hydrogen
The Strategic Energy Plan, which is the basis of Japan’s
The Council for a Strategy for Hydrogen and Fuel Cells energy policy, starts covering hydrogen in its fourth edition
was established in December 2013 gathering experts from released in April 2014. While hydrogen has been
industry, government, and academia as part of an initiative incorporated into the nation’s policies in this way, in
by the Ministry of Economy, Trade and Industry. The council December 2017 the Basic Hydrogen Strategy was
released the Strategic Roadmap for Hydrogen and Fuel formulated and released through cross-ministerial
Cells in June 2014. The roadmap was renewed in 2016 and cooperation. The strategy aims to commercialize hydrogen
2019, and the latter clarifies the cost target for hydrogen fueled power generation and a hydrogen energy supply
and the performance target for key equipment and chain early in the 2030s, and it presents a vision that the
systems toward social implementation of hydrogen and capacity of future hydrogen fueled power generation will
fuel cells, and defines action plans to achieve these reach 30 GW.
* Data source: Website of US Energy Information Administration, Kawasaki Technical Review No.182 4
and BP Statistical Review of World Energy (2019) February 2021
General Overview
While promoting hydrogen policies ahead of the rest of China, South Korea, and more have released or are
the world, Japan hosted Hydrogen Energy Ministerial formulating their roadmap.
Meetings in Tokyo in September 2018 and 2019 attended Considering such global movement, some predict that a
by related ministers from around the world. hydrogen-based society will come earlier than the previous
forecast.
5
Australia Japan
Hydrogen Loading of
Gas Hydrogen Liquefied hydrogen Liquefied hydrogen
Brown-coal Gasification land liquefied
refining liquefaction marine transportation unloading
transportation hydrogen
LH2
H2 LH2
Mining site facility 150km Port site facility 9, 000km Kobe Airport Island
(Latrobe Valley) (Hastings)
Corporation, Shell Japan Ltd., and Electric Power State governments is part of that. In April 2018, a subsidy-
Development Co., Ltd. (J-POWER), came together to form awarding ceremony for this project was held in Latrobe
the CO2-free Hydrogen Energy Supply-chain Technology Valley, where a brown-coal mining site is located. The
Research Association (HySTRA)—which was later joined by construction of facilities is proceeding in Australia as well.
Marubeni Corporation, ENEOS Corporation, and Kawasaki These Japan-Australia pilot demonstrations have entered
Kisen Kaisha, Ltd.—and has been carrying out technology the operational phase that started in fiscal 2020.
development to establish a hydrogen energy supply chain Ahead of this, in fiscal 2018, as a grant project by
for the purpose of economical, stable procurement of a NEDO, called the Smart Community Technology
large amount of hydrogen with the support of the New Development Project Utilizing Hydrogen Cogeneration
Energy and Industrial Technology Development Systems, under the coordination of Obayashi Corporation,
Organization (NEDO) (a grant project by NEDO called the in cooperation with Kobe City, the Kansai Electric Power
Demonstration Project for Establishment of Mass Co., Inc., Iwatani Corporation, and others, Kawasaki
Hydrogen Marine Transportation Supply Chain Derived from successfully conducted a technological demonstration of
Unused Brown Coal). We are now commissioning a gas turbine cogeneration, the key to hydrogen utilization, in
liquefied hydrogen carrier, a liquefied hydrogen unloading a city area. We installed our 1 MW gas turbine (Fig. 5) on
terminal in Kobe, and brown-coal gasification facilities in Kobe Port Island, and it successfully supplied heat and
Australia. electricity to neighboring public facilities. This is the first
Since Kawasaki, Iwatani, J-POWER, Marubeni, and AGL time in the world that a hydrogen fueled gas turbine was
Loy Yang Pty Ltd formed a consortium in 2018, we have operated in a city area.
been constructing and commissioning gas refining facilities As the proportion of renewable energy gets larger in
and a hydrogen liquefaction and loading terminal with a the future, problems will be revealed, such as unstable
subsidy from the Australian government and the Victoria power supply caused from fluctuating renewable energy
State government. sources and mismatches between electricity supply and
The construction of a liquefied hydrogen carrier and the demand. A way to solve this mismatch is power-to-gas
facilities at each of the sites is well on track. In regard to technology, which is the idea of supplying surplus
our liquefied hydrogen carrier, a naming and launching electricity generated from renewable energy to a water
ceremony was held in December 2019 (Fig. 4). The carrier electrolysis, producing and storing hydrogen, and utilizing
was named SUISO FRONTIER and the ceremony was the stored hydrogen as energy.
attended by 4,000 guests. In 2018, under the coordination of Toyota Tsusho
The governments of Japan and Australia cooperate in Corporation, Kawasaki conducted a power to gas
supporting the establishment of a hydrogen energy supply demonstration commissioned by NEDO, called the
chain derived from brown-coal, and in a Japan-Australia Research and Development of Technologies for
summit meeting usually held at the end or beginning of the Stabilization, Storage and Use in Converting Unstable
year, their cooperation on this project was announced in Electric Power Derived from Renewable Energies into
official documentation. The significant support for our Hydrogen in Hokkaido, in which we connected a water
consortium from the Australian federal and the Victoria electrolysis system to a wind power generation facility in
Fig. 5 Demonstration facility for hydrogen fueled gas turbine cogeneration (in Kobe City)
Tomamae, Hokkaido and successfully produced hydrogen. self-sufficiency rate. This technology will be important
Figure 6 shows the hydrogen production facilities. Such when hydrogen is produced using inexpensive renewable
hydrogen derived from renewable energy is essential to energies of other countries, which also offers hope that a
establishing a sustainable energy-based society, and is large market will form.
needed to some extent even when considering the energy
7
(a) External appearance
9
(2) Followers around the world Medium-Term Business Plan in 2010, and ever since, we
Hydrogen energy utilization is gathering momentum all have been working on technology demonstrations toward
over the world. The Hydrogen Council 4), which was commercialization and the establishment of a cooperative
established in January 2017 by 13 global companies from consortium as well as technology and product
areas such as energy and resources, plants, industrial development to achieve that .
gases, and transportation equipment, aims to achieve a Figure 1 shows the concept of CO 2-free Hydrogen
hydrogen-based society as quickly as possible and has 92 Chains in which hydrogen is produced by gasifying and
member companies as of the end of July in 2020, refining brown-coal in Latrobe Valley, Victoria State,
increasing by a factor of six times in the four years since its Australia, liquefied and then shipped to Japan in a liquefied
foundation. In addition, 70% of G20 countries have hydrogen carrier. Brown-coal is low in transport efficiency
incorporated hydrogen utilization into their policies. In this due to its high moisture content and the spontaneous
way, there is a rapidly growing likelihood of realizing ignition that can occur when it dries. Because of this, it has
hydrogen utilization and its market expansion. only been used locally for power generation in the vicinity
of the mine. Half of all the coal reserves in the world are
brown-coal. Among them, Victoria State in Australia has a
2 Concept of a CO2-free hydrogen vast amount of those reserves, and the brown-coal
energy supply chain reserves in the Latrobe Valley area alone are equivalent to
We made our Concept of a CO2-free Hydrogen Energy 240 years' worth of electric power generation in Japan. The
Supply Chain (CO2-free Hydrogen Chains) public in our Loy Yang Coal Field shown in Fig. 2, which is said to be the
Latrobe Valley
Brown-coal
thermal power plant
largest in the Southern Hemisphere, is an open-cut mine hydrogen produced in Latrobe Valley is compressed and
that boasts an astounding 14 km perimeter. transported through gas pipelines, and then liquefied in a
Hydrogen can be produced by gasifying and refining hydrogen liquefier installed near a port. After being stored
any fossil fuel, not just brown-coal, but in the refining in a storage tank, the liquefied hydrogen is loaded onto a
process CO2 is coproduced as well. By implementing liquefied hydrogen carrier and shipped to Japan. This scale
carbon dioxide capture and storage (CCS) to capture the is equal to the liquefied natural gas (LNG) chain
CO 2 byproduct at the site and store it underground, commercialized in the 1960s.
hydrogen can be obtained without releasing any CO2 into In order to evaluate the basic feasibility of this concept, we
the atmosphere (CO2-free hydrogen). The Australian federal conducted conceptual design based on commercialization
and the Victoria State governments are collaborating on a with the specifications shown in Table 1 and the core
CCS project called CarbonNet, which makes Victoria State facilities shown in Fig. 3, and evaluated economic
a good place to put both brown-coal and CCS to use 5). The efficiency by estimating the cost of equipment and
Brown-coal consumption〔Mton/year〕 4. 74
CO2 storage〔Mton/year〕 4. 39
Brown-coal gasifier
Hydrogen
liquefaction Hydrogen
facility storage facility
Hydrogen
liquefaction facility
11
Cost of hydrogen (CIF) interrupted and we will not be able to say we have put
29.8 yen/Nm3 hydrogen into practical use. In addition, if a foreign product
Hydrogen carrier 2.6 is needed anywhere in the supply chain, extra efforts and
Loading terminal 3.2 cost will be required to conform to standards and
specifications.
Hydrogen liquefaction 9.8 “Ready-to-use” means the state in which not only the
necessary technologies and products exist but also the
Hydrogen pipeline 0.5 rules and regulations required for operation and safety have
been established. This is why technology development and
Hydrogen production 8.5
rule establishment must proceed at the same time to
CCS 2.9 realize the world’s first CO 2 -free Hydrogen Chain.
Brown-coal fuel 2.3 Additionally, we must acquire intellectual properties at the
same time to do business from an advantageous position.
Fig. 4 Cost structure of CO2-free hydrogen
Therefore, we have been collaborating with stakeholders to
work on technology development and the establishment of
rules and standards for a liquefied hydrogen carrier, a
operation. The commercialized hydrogen supply is loading arm for liquefied hydrogen, and so on.
equivalent to the amount consumed by three million fuel One of our strengths in realizing a hydrogen energy
cell vehicles or a single one-million-kilowatt hydrogen gas supply chain is our technologies related to cryogenic
turbine combined cycle power plant. As shown in Fig. 4, the liquefied gas that we have cultivated for many years, such
Cost Insurance and Freight (CIF) for delivery to Japan was as LNG carriers and the liquefied hydrogen storage tank
estimated to be approximately 30 yen/Nm3 (334 yen/kg), of and supply facilities at the Tanegashima Space Center.
which the costs of raw brown-coal and CCS account for There are many different ways to carry hydrogen such as
approximately 17%. liquefied hydrogen and putting it in tanks, compressing
The CO 2 -free Hydrogen Chains concept has the hydrogen and putting it in gas canisters, and using
following features: absorbing alloys or organic compound media, but among
・Stable, large volume supply: hydrogen production from them, liquefied hydrogen is already at the level of
unused resources commercialization and is suitable for large-volume
・Good for the environment: on-site capturing and storing transportation and storage, and, it does not need any
of CO2 byproduct energy to convert it into ready-to-use hydrogen gas.
・Enhance industrial competitiveness: technological and Liquefied hydrogen is 70.8 kg/m3 in density, lower than the
industrial ability sufficient for handling hydrogen required 443 kg/m3 of LNG, but has high volumetric efficiency.
・Restrain outflow of national wealth: does not result in Specifically, it is approximately 800 times higher than
just purchasing expensive resources atmospheric-pressure hydrogen gas. Also, it has a boiling
As you can see from the above, CO2-free hydrogen meets point of 20.3 K, approximately 90 K lower than the 112 K of
the conditions required for future energy, that is, energy LNG, and low latent heat per volume, which requires high-
security, economic efficiency, environment and safety efficiency liquefaction technology and high-performance
(3E+S). insulation technology.
This economic efficiency evaluation was conducted as Major advantages of liquefied hydrogen are as follows:
an international project of the New Energy and Industrial ・Already in practical use as transport media for industrial
Technology Development Organization (NEDO) and the use and rocket fuel
outcomes have been recognized by both the Australian and ・Highly efficient transport because no additional weight
Japanese governments. needs to be transported as it is not absorbed into or
combined with any transport media such as metals and
organic solvents
3 Kawasaki’s development of core ・Able to be evaporated at normal temperature on-site
technologies and products (energy is not needed)
In order to realize CO2-free Hydrogen Chains, we need ・Once gasified, it is able to be supplied to a fuel cell
to make it “ready-to-use.” The core technologies and without having to be refined, due to its high purity
products to produce, transport, store, and utilize hydrogen ・Able to be liquefied using less-expensive local energy
must be available to seamlessly operate from the when the supply site is located in an energy rich foreign
beginning to the end of the supply chain. If even a single country
core product is missing, the supply chain will be ・Able to contribute to cold energy power generation and
other purposes on-site by using the cold energy Supply Chain Derived from Unused Brown Coal, and the
produced, because the energy when liquefied is not lost Australian portion, which is a grant project by Australian
but converted into cold energy (-253°C) federal and Victorian state governments.
・Clean and sustainable as it is non-toxic and has zero The NEDO portion is being conducted under the
global warming potential (GWP) initiative of the CO2-free Hydrogen Energy Supply-chain
Technology Research Association (HySTRA), which was
We have been developing hydrogen technologies and established in 2016 and is headed by us. The HySTRA’s
products for its production, liquefaction, transportation, members are: Kawasaki Heavy Industries, Ltd., Iwatani
storage, and utilization, while advancing our cryogenic Corporation, Electric Power Development Co., Ltd.
technology. (J-POWER), Shell Japan Ltd., Marubeni Corporation,
ENEOS Corporation, and Kawasaki Kisen Kaisha, Ltd.
The Australian portion is conducted where Hydrogen
4 Progress of the project Engineering Australia Pty Ltd (HEA), Kawasaki's subsidiary,
To implement hydrogen energy in our society, all the serves as the main contact to the Australian governments.
core technologies from the supply side to the demand side The participants are: Kawasaki, Iwatani, J-POWER and its
should be seamlessly developed and linked, just like LNG. subsidiary J-Power Latrobe Valley Pty Ltd (JPLV), Marubeni,
We have thus been engaged in hydrogen supply from AGL Loy Yang Pty Ltd, and Sumitomo Corporation.
overseas as part of the Japan-Australia pilot demonstration In Japan-Australia pilot demonstration projects,
projects and in hydrogen utilization as part of the hydrogen Kawasaki is responsible for project coordination and the
gas turbine cogeneration demonstration project. development and supply of technologies and device
systems in each process.
(1) Japan-Australia pilot demonstration projects ( i ) Gasification and gas refining
Toward the implementation of hydrogen energy in our Figure 6 shows the brown-coal gasification and
society, we started conducting hydrogen energy supply hydrogen refining facility. We delivered the following to
chain technology demonstrations (Japan-Australia pilot JPLV: a preprocess facility to dehumidify and pulverize
demonstration projects) on a pilot scale (approximately brown-coal to prepare it to be sent to a gasifier, and a
1/120 of commercial scale by carrier capacity) in fiscal facility to compress refined gaseous hydrogen and load it
2020, including the world’s first long-distance large-volume into land transport container trailers for delivery.
marine transportation of liquefied hydrogen produced from ( ii ) Liquefaction of hydrogen and loading of liquefied
brown-coal-derived hydrogen. As shown in Fig. 5, this pilot hydrogen
project covers the whole hydrogen energy supply chain A site to liquefy high-pressure gaseous hydrogen has
from the brown-coal gasification and hydrogen refining been constructed at the Port of Hastings. The liquefied
facility in Latrobe Valley through to the liquefied hydrogen hydrogen is loaded into container trailers made by
unloading terminal at Kobe Airport Island, and will identify Kawasaki, carried to the pier, and then loaded into a
issues in technology, safety, operation, and social liquefied hydrogen carrier. Figure 7 shows the hydrogen
acceptance. It consists of the NEDO portion, which is a liquefaction terminal.
NEDO grant project called the Demonstration Project for ( iii ) Liquefied hydrogen carrier
Establishment of Mass Hydrogen Marine Transportation As a liquefied hydrogen carrier had never been built
Australia Japan
13
Source: HySTRA
anywhere in the world, we designed one based on the IGC in November 2016, which were a joint proposal by the two
Code of the International Maritime Organization (IMO), countries 6) . This became a steady step toward the
namely, the International Code of the Construction and realization of large-volume marine transportation of
Equipment of Ships Carrying Liquefied Gases in Bulk, liquefied hydrogen.
which applies to LNG ships. The pilot demonstration carrier has a vacuum insulated
At the end of 2013, approval, in principle, was provided storage tank (1,250 m 3 in capacity) with a pressure-
from Class NK for the cargo containment system installed accumulation cylinder structure, which can store boil-off
in the liquefied hydrogen carrier (pilot demonstration gas internally, like a coastal LNG carrier. After the basic
carrier) for the Japan-Australia pilot demonstration projects. design was completed in fiscal 2016, then detail design
To get this approval, we proposed requirements for hull, was conducted and construction began. The naming and
materials, safety standards, and so on, taking account of launching ceremony took place at Kobe Works in
the properties of liquefied hydrogen, as well as IGC code. December 2019. The storage tank was installed into the
Also, we conducted risk assessment by HAZID analysis. carrier in March 2020, it was outfit as shown in Fig. 8, and
To operate this liquefied hydrogen carrier, maritime the operation started in the fall of 2020.
authorities of Japan and Australia started discussions on ( iv ) Kobe unloading terminal
safety standards in 2014, and the IMO approved interim Constructing and operating a liquefied hydrogen
recommendations for carriage of liquefied hydrogen in bulk loading/unloading terminal for bulk carriers will also be a
world’s first, just like the liquefied hydrogen carrier. We are use electricity, heat and hydrogen energy on a community
constructing an unloading terminal in an approximately 100 level by using a heat and electricity supply system
ha area rented from Kobe City in the northeast part of Kobe (hydrogen cogeneration system) which has a 1 MW-class
Airport Island. Figure 9 shows how the terminal. gas turbine fueled by hydrogen and natural gas at its core.
The onshore liquefied hydrogen storage tank has a Obayashi Corporation served as the project organizer of the
2,500 m3 capacity, which is the largest in Japan. The NEDO grant project, called the Smart Community
world’s first loading arm system (LAS) for liquefied Technology Development Project Utilizing Hydrogen
hydrogen adopts the method of suspending a stainless- Cogeneration Systems, and installed and operated an
steel double-wall vacuum flexible hose from a trellis frame. integrated EMS and a heat supply system, and Kawasaki
The tip of the LAS is equipped with an emergency release delivered a hydrogen cogeneration system. This was a joint
system to safely block liquefied hydrogen leaks when a project by Kobe City, the Kansai Electric Power Co., Inc.,
carrier leaves the port in an emergency. Iwatani Corporation, Kanden Energy Solution Co., Inc., and
The terminal construction was completed in May 2020, Osaka University.
and after some test runs, full operation of the terminal One of the pieces of equipment used in this technology
started in the fall of 2020. demonstration is shown in Fig. 10. The facility is installed
in an urban area, and it supplied heat and electricity to
(2) Hydrogen gas turbine cogeneration demonstration neighboring public facilities, namely, an international
project exhibition hall, a sports center, a central city hospital, and a
We conducted technology development and sewage treatment plant. The operation of a 100%
demonstration of a new energy management system hydrogen-fueled gas turbine cogeneration system installed
(EMS) on Port Island in Kobe City, which aims to efficiently in a city area was a first-ever attempt in the world, and
Vent stack
BOG warmer
Self-pressurizing
evaporator
15
Doctor of Engineering
Motohiko Nishimura
Hydrogen Project Development Center,
Corporate Technology Division
Kenjiro Shindo
Project Promotion Department,
Hydrogen Project Development Center,
Corporate Technology Division
Hydrogen Production
— Development of Hydrogen Production Technologies
2 Development overview
1 Background Brown-coal is an early stage coal with high water
The current major methods of hydrogen production in content, which makes worse transport efficiency, and it
industry are by-product hydrogen from petrochemical can easily cause self-ignition when it dries. It has thus only
plants and steelworks, and natural gas reforming. There are been used for power generation near mining sites, but
some facilities producing hydrogen through biomass gas Kawasaki is focusing on potential in brown-coal and has
reforming, but not on a big scale. worked on developing hydrogen production technologies to
By-product hydrogen may require additional facilities to utilize it further. As shown in Fig. 1, one method is to burn
increase its purity because some impurities can get mixed brown-coal in a gasifier and then only extract the hydrogen
in depending on the production process. Above all, the gas from the generated gases. We have tried to develop
amount of production depends on the amount produced of the gasification technology and the gas refining technology
the original product and thus by-product hydrogen is not to extract high purity hydrogen gas, and to verify the
suitable for stable mass production. Since natural gas technologies at a bench scale test facility built in one of our
reforming is affected by the amount produced and cost of factories.
natural gas, which is a primary source, from the viewpoint In hydrogen production by renewable energy, as shown
of energy security as diversification of the energy source, it in Fig. 2, hydrogen gas is produced by water electrolysis
would be better to produce hydrogen from other raw using electricity generated from wind power and
materials and energy resources. photovoltaics. We have developed unique technologies to
Brown-coal is not being effectively used as an energy enable high efficiency hydrogen production, and along with
resource even though there is so much reserves of it all this, we have conducted demonstration tests to verify the
over the world, especially Australia. That is why Kawasaki technologies attaching a small-scale prototype electrolyzer
focused on the use of brown-coal as a method of hydrogen to a wind generation facility in Hokkaido.
production and has worked on establishing technologies
that use it to produce a large amount of inexpensive
17
Brown-coal
Gasification Gas refining Hydrogen gas
Electricity
Hydrogen gas
Water electrolyzer
Liquid Brown-coal
oxygen slurry
Hydrogen
Shift CO2
reactor
Pressurized
gasifier
Absorber Stripper
Scrubber
( ii ) Gas refining process time, which gave us a reason to adopt the wet feed
In the gas refining process, the shift reaction and CO2 method.
separation and capture are conducted. Gasification
Shift reaction We developed a gasifier ourselves to understand the
In the shift reaction process, carbon monoxide, which brown-coal gasification characteristic and optimize the
makes up approximately 10 to 20% of the syngas, is downstream gas refining process. This gasifier has its
reacted with water vapor via a catalyst to produce slurry burner installed at the top where it gasifies
hydrogen and carbon dioxide, which improves the yield brown-coal slurry, its wall has a fireproof heat-insulation
of hydrogen. There are two kinds of shift reaction: the structure, and at the bottom it has a function to directly
sour shift reaction that requires sulfur, and the sweet cool the syngas. The gasifier can conduct oxygen-blown
shift reaction that does not. gasification in a 0.4 MPa pressurized environment, and
CO2 separation and capture each part is sealed with gas (CO2) to raise the hydrogen
The method of CO2 separation and capture is selected content.
according to the type, pressure, amount, and purity of ( ii ) Gas Refining Process
the target gas which could be combustion emission gas Shift Reaction
or gasification gas, for example. Major methods include As brown-coal contains sulfur, the syngas generated
chemical absorption, in which CO2 reacts with a liquid by gasification contains sulfuric gases such as hydrogen
absorbent; physical absorption, in which CO 2 is sulfide as impurities. We thus adopted the sour shift
dissolved in a liquid absorbent under high pressure and reaction method, which does not require the removal of
low temperature; adsorption, in which CO2 is adsorbed the sulfur content, can utilize sulfur as a catalytic
by activated carbon or zeolite; and membrane separation activator, and is an easier system to operate.
in which CO 2 is separated out with a polymer CO2 separation and capture
membrane. For commercial use, the physical absorption method,
which uses the pressure of a gasifier’s highly
(2) Technology development pressurized gas, has a stronger track record, but
( i ) Gasification process because the syngas pressure supplied from the gasifier
Brown-coal pretreatment was not high enough at 0.3 MPa in our bench scale test,
Although brown-coal has high water content at around we adopted the chemical absorption method. Also, as a
60%, we set a target of having at least 53% brown-coal new technology, we developed a new adsorption
in the slurry (i.e., 47% or less water content) from the method that uses an adsorbent with a liquid chemical
standpoint of economic feasibility. In order to decrease absorbent supported on carrier. This method enables us
the water content in the powdery brown-coal when to separate and capture CO2 at a lower temperature
mined and make the brown-coal into a highly than with the normal chemical absorption method.
concentrated, less viscous liquid, the surface structure
had to be changed to prevent dried brown-coal from (3) Technology verification through a bench scale test
reabsorbing moisture, which is known as reforming As shown in Fig. 5, we attached a gas refining facility
treatment. In this project, we developed brown-coal to a pressurized gasifier in our Akashi Works, and
pretreatment technologies that can dry and perform the conducted a demonstration test for bench-scale hydrogen
reforming treatment on the brown-coal at the same production from September 2012 to February 2013.
19
Fig. 5 Overall view of bench scale test facility
( i ) Test objectives converted in the shift reactor; almost 100% of the carbon
Shift reaction equipment and CO 2 separation and dioxide was captured in the absorber; and a hydrogen
capture equipment need to be combined in multiple stages concentration of approximately 86% was achieved. Each
to make a complete process that can be successfully item met the designed value.
established for business purposes. In our bench scale test, In addition, when we refined the gas with the shift
we tested hydrogen production from brown-coal by reaction and adsorption methods we developed as new
verifying each piece of equipment to meet capacity technologies, the hydrogen concentration at the adsorption
requirements in a single step. outlet was over 80% and both methods met the designed
( ii ) Test results value. In this way, we have successfully verified that
Figure 6 shows the results of the test where we hydrogen can be produced from brown-coal.
refined syngas generated from brown-coal in the
pressurized gasifier with the shift reaction method and
chemical absorption method. The amount of gas at the
4 Hydrogen production technology by
shift reactor outlet increased because water vapor was
water electrolysis
added, and the amount of gas at the absorber outlet (1) Hydrogen production by alkaline water electrolysis
decreased because CO2 was removed. The test results Hydrogen production methods by water electrolysis
were that approximately 83% of the carbon monoxide was can be classified into three major types: alkaline water
1.4
4.3% N 2 and other gases
1.2
CO2
3.3%
CO
1.0
Composition (dry)〔-〕
49.5% H2
0.8 40.9%
7.7%
3.2%
0.6
6.3%
21.8%
0.4
43.0% 86.0%
0.2 34.0%
0.0
Shift reactor inlet Shift reactor outlet Absorber outlet
Oxygen vent
Supply to hydrogen
utilization facilities
Dehumidifying and
refining device
Hydrogen Compressor
Water
electrolyzer
Gas holder
Fig. 8 Schematic image of demonstration plant (only within the scope of Kawasaki Heavy Industries, Ltd.)
21
Development on Stabilization, Storage and Utilization of
Unstable Renewable Electricity In Hokkaido Using Hydrogen- Mitsugu Ashikaga
Project Control Department,
Based Technologies,” commissioned by the New Energy and Hydrogen Project Development Center,
Industrial Technology Development Organization (NEDO) 2). In Corporate Technology Division
this project we attached a water electrolyzer to wind power
generation facilities (a renewable energy), produced
hydrogen by using part of the electricity generated there, and Norihiko Kumada
then demonstrated a system supplying the optimum Project Control Department,
Hydrogen Project Development Center,
quantity of electricity and hydrogen on demand.
Corporate Technology Division
Our main scope was hydrogen production using the
alkaline water electrolyzer, in this system hydrogen gas
produced by the electrolyzer was pressurized to 0.9 MPaG
with a compressor, refined the compressed gas with a Toshinori Muraoka
Analysis Technology Department,
dehumidifying and refining device, and then supplied the gas Engineering Solution Division,
to hydrogen utilization facilities (scope of one of Kawasaki Technology Co., Ltd.
co-implementers), as shown in Fig. 8.
The result of our demonstration, under the severe
operating condition, which was a current density of 6.4 kA/ Yugo Ohata
m2, was that electricity was provided into the alkaline water Systems Engineering Department,
System Technology Development Center,
electrolyzer, but it achieved very high electrolysis efficiency
Corporate Technology Division
(in high calorific value) exceeding 84% at best. We also
obtained excellent results on the purity of the hydrogen gas
produced in that the hydrogen gas contained less than 0.1
vol% oxygen (in dry base), verifying the high gas-separation
Tatsuya Taniguchi
Environmental System Research Department,
ability of the diaphragm we developed. Technical Institute,
Water electrolysis technologies are becoming more Corporate Technology Division
important for further promotion of renewable energy and
establishment of a hydrogen-based society in the future.
Kawasaki will continue to work on further improvement of Nanase Ishikawa
durability and further cost reduction for key components Material Research Department,
Technical Institute,
such as electrodes and diaphragms, as well as studies on Corporate Technology Division
future commercialization.
Conclusion
Kawasaki believes that, through such technology
development, we came to recognize what technologies
Reference
were required to produce a large amount of inexpensive
hydrogen and established the fundamental technologies 1) Khan,M.A., Zhao,H., Zou,W., Chen,Z., Cao,W., Fang,J.,
for building a hydrogen energy supply chain in the future. Xu,J., Zhang,L., & Zhang,J.: “Recent Progresses in
For the hydrogen production technologies by water Electrocatalysts for Water Electrolysis,” Vol. 1, No. 4,
electrolysis in the project in Hokkaido, we received pp. 483–530 (2018)
tremendous support from NEDO, who commissioned the 2) Toyota Tsusho Corporation et al: “Power to Gas
project, and co-implementers including Toyota Tsusho Demonstration to Start in Hokkaido,” NEDO News List,
Corporation. We would like to sincerely thank everyone for https://www.nedo.go.jp/english/news/AA5en_100291.
their help. html (2017)
Hydrogen Production
— Development of Hydrogen Liquefaction Systems
23
facility consists of a hydrogen liquefier as well as
3 Hydrogen Liquefaction System and equipment such as liquefied hydrogen storage tanks, liquid
Kawasaki’s Development Challenges nitrogen storage tanks, which is used for precooling, and
(1) Hydrogen liquefaction system hydrogen compressors.
A schematic diagram of our demonstration facility for a The schematic process flow of the hydrogen
hydrogen liquefaction system is shown in Fig. 1. The liquefaction system is shown in Fig. 2. hydrogen feed gas
Hydrogen liquefier
(designed/manufactured by Kawasaki)
Fig. 1 Schematic diagram of hydrogen liquefaction system (demonstration facility in Harima Works)
OUT IN
Liquefied IN Hydrogen compressor
hydrogen Hydrogen gas
(For precooling)
(Refrigeration cycle)
Heat
exchanger
Expansion turbine
Expansion valve
Heat
exchanger
Heat
exchanger
Hydrogen liquefier
compressed by the hydrogen compressor is cooled to (ii) Structure, insulation, and sealing
almost -200°C by liquid nitrogen for precooling, it is cooled When designing the hydrogen liquefier’s structure, we
again by a few dozen degrees using the cold energy from a took into consideration standards and regulations of
refrigeration cycle, and then it is liquefied through adiabatic seismic design, referring to a helium liquefier we had
expansion through an expansion valve. This refrigeration developed. To prevent heat input from the outside of the
cycle adopts a hydrogen Claude cycle (a refrigeration cycle hydrogen liquefier, we also insulated the support of the
combining expansion turbines and an expansion valve), internal equipment.
which means the system uses hydrogen to cool hydrogen. In order to make the hydrogen liquefier vacuum-
insulated, we needed to maintain a high vacuum on the
(2) Development challenges inside. Consequently, welded parts and sealed flanges
There was a wide range of development challenges as required extremely tight seals. Making the most of our
we had never developed a hydrogen liquefier before and high precision manufacturing and extremely tight sealing,
needed to design it on a large scale. Major challenges we were able to pass a helium leak test. For the insulating
were: materials applied to the surfaces of the internal equipment,
Process design we applied our cumulated know-how on design and
Structure, insulation, and sealing of hydrogen liquefiers construction.
Expansion turbine (iii) Expansion turbine
Operation control for start-and-stop, load change, and The expansion turbine, shown in Fig. 3, is a key piece
other operations of hardware used to generate the cold heat required for
Gas purity management liquefaction. In designing the optimal process, the turbine
Facility/operation safety needed to be much smaller than the hydrogen liquefier
For a new liquefier, there are other challenges, such as (approximately four meters in diameter, and twelve meters
further improvement of its efficiency and reliability high), and rotate at a speed of more than 100,000
demonstration for future commercialization. revolutions per minute. So, we developed a new gas
And as we are an equipment manufacturer and did not bearing using hydrogen gas to support the rotating shaft,
have sufficient expertise on liquefaction plant operation instead of using the typical oil or ball bearing. This gas
including facility operation/maintenance or organizations for bearing also offers benefits such as significant reduction of
such operations, establishing each of these toward friction loss due to the bearing and prevention of system oil
demonstration operation was another big challenge for us. contamination. Lastly, in designing aerodynamics and rotor
dynamics, we applied our high-speed rotating machinery
technology for gas turbines and jet engines.
4 Prototype liquefier (iv) Operation control
(1) Design and manufacturing As the behavior of a hydrogen liquefaction system is
Our prototype liquefier and its surroundings are shown very complicated, we used simulations to design the
in the picture at the beginning of this chapter. Because we control logic. There were some parts that had to be
have experience manufacturing large-scale structures and adjusted step by step during the actual operation, and we
cryogenic-related equipment including LNG storage tanks, continued making slight improvements based on the data
we successfully manufactured the hydrogen liquefier and obtained from the demonstration operation.
the liquefied hydrogen storage tank we developed this (v) Purity management
time without installing any new infrastructure. In a -253°C environment where hydrogen gets
Although this system was built for the purpose of liquefied, every substance except helium and hydrogen
technology development, in order to obtain and freezes and turns into a solid, which means that any
demonstrate commercial-scale liquefaction technologies, impurities in the hydrogen gas may clog the system. That
we built it on a commercial scale, which can produce is why hydrogen gas purity management is so important,
approximately five tons of liquefied hydrogen per day. and why we monitored an analyzer to make sure that the
( i ) Process design level of impurities was always less than a ppm. This
We designed the process ourselves and optimized the allowed us to produce liquefied hydrogen with purity
compressor arrangement, the number of stages of the higher than 99.999%, meaning that once gasified, you can
expansion turbines and their load distribution, and the use it directly for a fuel cell, as mentioned above.
pressure in each line. We also conducted element tests (vi) Safety
such as the pressure drop characteristics of an adsorber to To ensure safe facility design, we conducted HAZOP
adsorb impurities, and then reflected those results in the and FMEA ourselves, which are system engineering
design. methods of analyzing the reliability and safety of plant
25
Fig. 3 Hydrogen liquefier (upper part) and expansion turbine
facilities, and we had several independent organizations to improve liquefaction efficiency, and increased the
review the level of safety. For our facility demonstration design accuracy by using the data of the prototype
operation, we put an organization and system in place for liquefier. To improve its efficiency even further, we added
operation and maintenance, communicated closely with an ejector that collects boil-off gas in the liquefied
relevant administrative authorities, and proceeded with hydrogen storage tank along with the cold heat. We
operations while preventing any safety issues from adopted almost the same expansion turbine as the
occurring. prototype’s, valuing the performance it demonstrated. To
make the liquefier smaller, we reconsidered the layout of
(2) Demonstration operation the internal equipment, and made it 0.5 meters smaller
In September 2014 we successfully liquefied hydrogen than the prototype in diameter and height, as shown in
for the first time. After that, we verified our process design Fig. 4. This reduced the weight by 30% from the prototype
for this prototype liquefier, and tested the performance of and contributed to cost reduction.
the expansion turbines, the controllability, and the After completing the prototype demonstration
adsorber, among other things. We also measured the operation, we worked on the design and manufacture of a
vibration and stress of the internal piping and confirmed its new liquefier, and replaced the prototype with the new one
soundness. in March 2019 as shown in Fig. 5. After that, we adjusted
After that, we continued to update the facility and the the peripheral equipment in accordance with the new
control software to improve the performance and reliability liquefier and started trial operation in August 2019.
of the expansion turbines and plant controllability, which
enabled us to automatically start/stop the expansion (2) Demonstration operation of the new liquefier
turbines and automatically control the liquefaction We started full demonstration operation of the new
operation (constant loading and load change). The system liquefier in October 2019. Thanks to our achievement and
cleared multiple interlock tests without causing any trouble experience gained with the prototype liquefier, we
to the facility, fully confirming the safety of the system as successfully achieved liquefaction without facing any
well. This prototype liquefier demonstration operation was problems, even in the first operation. In the performance
completed at the end of fiscal 2016. test performed later, we confirmed that the liquefaction
efficiency was improved by approximately 20% from the
prototype. We also confirmed that the added ejector
5 New liquefier demonstrated the designed performance.
(1) Design and manufacturing As this new liquefier is the base for the commercialized
For our new liquefier, we improved the process in order one, stable performance, reliable controllability and facility
27
process that substantially increases liquefaction efficiency
will be required, as will making the system far larger. We Kozo Isano
Environmental System Research Department,
have already started technical studies to meet such Technical Institute,
requirements. Corporate Technology Division
Furthermore, we believe that what enabled us to have
continued accident- and injury-free demonstration
operation for the six years starting from the prototype Toshihiro Komiya
phase of hydrogen liquefiers was the high awareness of Industrial And Hydrogen Plant Department,
Industrial Plant Engineering Group,
safety of all the individuals involved and the fully safety-
Plant Engineering Business Division,
conscious system design. Energy System & Plant Engineering Company
We carried out the abovementioned development of
the hydrogen liquefaction system as one of our projects,
but the preparation and arrangement of the peripheral Yoshihiro Matsuda
Industrial And Hydrogen Plant Department,
equipment of the hydrogen liquefier was partially Industrial Plant Engineering Group,
subsidized by the Ministry of Economy, Trade and Industry. Plant Engineering Business Division,
Energy System & Plant Engineering Company
We would like to express our sincere gratitude for
supporting us.
Daisuke Kariya
Technology Development Department,
Reference Hydrogen Project Development Center,
Corporate Technology Division
1) Yoshiwa, Nakagawa, Kurosaki et al: “Development of an
Automated Helium Liquefier,” Kawasaki Technical
Review No. 101, pp. 1–8 (1988) (in Japanese)
Doctor of Engineering
2) Kamiya, Isano, Kariya et al: “Technologies of hydrogen P.E.Jp (Mechanical Engineering)
liquefaction, transport and storage — Paving the way to Shoji Kamiya
a hydrogen fueled future,” Kawasaki Technical Review Technology Development Department,
Hydrogen Project Development Center,
No. 176, pp. 51–58 (2016)
Corporate Technology Division
Hydrogen Storage
— Development of Liquefied Hydrogen Terminal
29
capacity tank, which will be the largest in Japan, and store
liquefied hydrogen transported by a liquefied hydrogen
3 Liquefied hydrogen terminal
carrier in the tank. The liquefied hydrogen terminal consists of a liquefied
Figure 1 is a rendering of a liquefied hydrogen loading/ hydrogen storage tank for storing liquefied hydrogen, a
unloading demonstration terminal in Kobe for verifying LAS to load/unload liquefied hydrogen between a carrier
loading/unloading technologies. The terminal is located on and the shore, and ancillary facilities. The ancillary facilities
the northeast shore of Kobe Airport Island. The site for handling hydrogen gas that we installed include a boil-
preparation and the installation of mooring facilities were off gas (BOG) compressor to compress hydrogen gas that
conducted by Kobe City in fiscal 2017. The construction of evaporates from the liquefied hydrogen storage tank, a
the terminal started in April 2018 and then its trial operation BOG holder to store the compressed hydrogen gas (Fig. 2),
was finished by the end of May 2020. We will complete and a vent stack to adequately release hydrogen gas that is
our demonstration of liquefied hydrogen marine generated while liquefied hydrogen is being loaded/
transportation between Australia and Japan before the end unloaded. The hydrogen gas stored in the BOG holder is
of fiscal 2020. used for gas replacement in the terminal facilities and as
Source:HySTRA
backup for unloading liquefied hydrogen from a carrier. The storage tank requires better thermal insulation than an
terminal has equipment for transferring liquefied hydrogen LNG storage tank. Because of this, we adopted a vacuum
from a liquefied hydrogen tank lorry to the liquefied insulation system. The largest liquefied hydrogen storage
hydrogen storage tank. tank in Japan was the 540 m3 tank at the Tanegashima
Space Center, but our storage tank will have at least four
(1) Liquefied hydrogen storage tank times the capacity. As shown in Fig. 4, we adopted a
The liquefied hydrogen storage tank, shown in Fig. 3, is perlite vacuum insulation system, enhancing the thermal
a spherical double-wall vacuum tank with a 2,500 m 3 insulation by filling the space between the inner and outer
nominal geometrical capacity. The tank receives and stores spherical tanks with perlite, a thermal insulation material,
liquefied hydrogen transported from Australia, and also and then creating a vacuum.
stores liquefied hydrogen transported by land from sites in To increase the size, we have been studying the most
Japan so it can be loaded into liquefied hydrogen carriers appropriate manufacturing method for welding thick plate
initially. materials at the construction site rather than at a factory
In order to store liquefied hydrogen for a long time and the optimum plate cutting plan to enhance
while keeping lowevaporation loss, a liquefied hydrogen construction efficiency. Through this process, we have
Insulation material
(Perlite)
31
bee n accu m u lati ng expertise wi th the aim of time, flexibility or mobility is also required for the system to
manufacturing such large tanks in the future. We have also follow the swaying movement caused by the waves. To
been studying the operation of large tanks like these, that end, we adopted a double-wall vacuum flexible hose
operations such as hydrogen gas replacement before for our LAS.
liquefied hydrogen is recharged and optimization of tank In order to move with the swaying movement of the
cooling, on which a demonstration will be conducted in liquefied hydrogen carrier, the LAS structure was designed
fiscal 2020. to hang the flexible hose with a crane-like arm. Figure 5 is
an image of a ship connected to the LAS. Figure 6 is the
(2) Loading arm system LAS for the demonstration project under construction at a
A loading arm system (LAS) is a facility that is installed factory. As we did not have experience making anything
on shore that connects to a liquefied hydrogen carrier like this arm structure for hanging a flexible hose even for
moored at sea to load and unload liquefied hydrogen. Once LNG applications,we conducted structure analysis studies
the carrier reaches the shore, the LAS is connected to the in many different arm positions. To confirm its durability
carrier’s manifold and it transports liquefied hydrogen while against repeated displacement in cryogenic conditions, we
following the swaying movement of the carrier due to the manufactured a prototype and conducted different
waves. performance tests using liquefied hydrogen.
A LAS that uses vacuum thermal insulation should be Not only is this LAS equipped with a system to follow
used for liquefied hydrogen as it requires better thermal swaying movements caused by waves but it also has an
insulation than existing LAS systems for LNG. At the same emergency release system (ERS) for the carrier to leave
Source:HySTRA
the shore safely and promptly in an emergency. If a carrier the hydraulic system controller.
displaces beyond tolerance, the ERS will automatically
activate to minimize liquefied hydrogen leak to the outside
as it detaches. In the event of an emergency such as a fire,
4 Future endeavors
the ERS can be started manually with the release switch. (1) Making larger liquefied hydrogen storage tanks
While the LAS for LNG does have an ERS, the LAS The spherical vacuum thermal insulated liquefied
structure for liquefied hydrogen has a different structure as hydrogen storage tank constructed in the pilot project
it adopts vacuum thermal insulation to increase the requires making its outer tank thicker to prevent buckling
thermal insulation properties, the same as the flexible caused by the internal vacuum pressure. In the case of a
hose, and in that it suppresses heat transfer from the valve storage tank that is tens of thousands of cubic meters in
that will be closed in an emergency. We used our thermal size, as would be needed at the commercial stage, the
stress analysis technology under cryogenic conditions for outer tank needs to be made very thick, which poses
this structure development. We developed these pieces of difficulties in obtaining and manufacturing plate materials.
equipment under the Cross-ministerial Strategic Innovation We are therefore developing a large-scale liquefied
Promotion Program (SIP) by the Japanese Cabinet Office, hydrogen storage tank with a new structure toward future
manufactured a prototype, and conducted tests such as a commercialization under a grant project by NEDO called
release test in which a tank was filled with liquefied the Development of Large-scale Equipment for the
hydrogen and a closing performance test after the ERS Transport and Storage of Liquefied Hydrogen and
disconnected 2). Equipment for Liquefied Hydrogen Unloading Terminals.
The term “LAS” covers all of the pieces of equipment One of the structures being studied is a flat-bottomed
that are part of the LAS system, including the double-wall cylinder, as shown in Fig. 7, which has higher volume
vacuum flexible hose, the crane-shaped arm, the ERS, and efficiency than the spherical shape used for large LNG
33
tanks. Using a non-vacuum structure with hydrogen gas at
Doctor of Engineering
atmospheric pressure between the inner and outer tanks
Akihiko Inomata
allows us to prevent buckling caused by vacuum pressure, Environmental System Research Department,
which would be a problem if a vacuum thermal insulation Technical Institute,
structure were used. We are also considering applying gas Corporate Technology Division
Hydrogen Transportation
— Development of Liquefied Hydrogen Carrier
35
issued interim recommendations 2) for Japan-Australia order to restrain the decline in transportation efficiency
marine transportation of liquefied hydrogen by approving a caused by gasification of the liquefied hydrogen on board,
Japan-Australia joint proposal. In addition, based on the eliminate the formation of a high-density oxygen
interim recommendations, and by setting more specific atmosphere generated by air liquefaction on the surface of
requirements on each of the items, Nippon Kaiji Kyokai the pipes, and eliminate any risk of damage to the carrier’s
(ClassNK) issued Guidelines for Liquefied Hydrogen structure from liquefied air droplets.
Carriers 3) to expand on the concepts involved in liquid In addition, as the piping is affected by tremendous
hydrogen transportation and the requirements against stress by thermal expansion and shrinkage while liquefied
various incident scenarios. We will ensure a high level of hydrogen is being loaded, and unlike on-land piping, by hull
safety by complying with this guideline as well. deformation, it must be protected from these.
Figure 1 is a rendering of the completed pilot
demonstration carrier. The shape of the hull is based on a (3) Cargo equipment
coastal LNG carrier that we built before, and it is equipped Liquefied hydrogen is very low temperature, 90°C
with a cargo tank specialized for liquefied hydrogen. As lower than LNG, which means that it requires cargo
liquefied hydrogen can be gasified by heat ingress more equipment with greater thermal-insulation performance
easily than LNG and may cause massive thermal shrinkage than cargo equipment used for LNG. Durability against
of the structure due to its cryogenic temperature, we have hydrogen’s physical properties must be confirmed and the
issues to resolve before we can put a liquefied hydrogen appropriate materials must be selected in terms of high
carrier into practical use. thermal-insulation performance and the prevention of
hydrogen leaks.
(1) Cargo containment system (CCS)
Regulations require that the pressure and temperature
of the cargo containment system (CCS) be controlled to
3 Development design and element
counteract heat ingress. When accumulating the boil-off
technology
gas produced by heat ingress instead of releasing it to (1) CCS
outside of the CCS, safe voyage to the destination must be CCS adopts a horizontal-cylinder pressure vessel that
ensured while maintaining the pressure. Also, heat ingress does not form part of the hull.This corresponds to a Type C
through the wall of the tank, pipes and the structure tank complying with pressure vessel standards defined in
supporting the CCS from the outside must be minimized. the IGC Code and ClassNK Rules and Guidance for the
In addition, the CCS must be structurally intact to Survey and Construction of Steel Ships 4) . The pilot
withstand the dynamic loads due to the ship’s motion demonstration carrier can install two 1,250 m3 CCSs, one
during a voyage. of which is installed in the foreside.
( i ) CCS thermal insulation system
(2) Cargo piping A CCS for liquefied hydrogen requires thermal
Cargo piping requires high level thermal insulation in insulation performance that is approximately ten times
Vent mast
higher than that for LNG. There are three modes of heat stably holds the inner vessel on the outer shell without
transfer, namely convection, conduction, and radiation. In letting them touch each other due to the ship motion
order to reduce heat ingress from the surface of the CCS during the voyage, cause more heat ingress, especially by
by heat convection and conduction, we adopted a double- heat conduction. So, to support the inner vessel we
shell structure consisting of inner vessel and outer shell, as adopted a saddle structure made with glass fiber
shown in Fig. 2. reinforced plastics (GFRP), which have excellent thermal
The supporting structure connecting the inner vessel insulation properties and strength. We studied various
and outer shell, the pipes, and the measuring instruments properties of the GFRP support structure in vacuum and
are a path of heat ingress by heat conduction. As a cryogenic temperature conditions, such as strength, heat
measure to reduce this, we adopted materials with low conduction, and outgas, and designed them to have the
heat conductivity, lessened the cross-sectional area of its required durability throughout the lifetime of the CCS.
structural materials, and made conduction paths longer. As The inside of the CCS is at an atmospheric temperature
a method to reduce heat radiation, we apply the double- during construction and regular inspections, but it is at a
shell vacuum insulation system with multi-layered cryogenic temperature when fully loaded. The temperature
insulation which is a metalized laminated film with high distribution inside of the CCS is even affected by the liquid
reflectivity. We designed the CCS with sufficient margin to level of the ballast and by loading and unloading. The inner
handle the temperature and pressure increase within the vessel shrinks and expands in line with temperature
CCS on a normal voyage, which enabled a Japan-Australia changes, while the outer shell remains at an atmospheric
voyage without releasing any boil-off gas to outside the temperature and thus the temperature difference between
CCS. Even when the inner vessel is full of liquefied the inner and outer shell causes a relative displacement.
hydrogen, the surface of the outer shell is kept at an For this reason, we designed it to have a structure in which
atmospheric temperature, generating neither liquefied two circular-arc saddle structures installed at the front and
atmosphere nor liquefied nitrogen. back of the inner vessel support it, and the saddles absorb
In addition, as a tool to ensure a safe voyage during the relative displacement by sliding on the inner surface of
transportation, the CCS is equipped with a Vacuum the outer vessel.
Insulation Performance Deterioration Monitoring System (iii) Tank dome
(VIPDM). Its purpose is to maintain the thermal insulation As the relative displacement between the inner vessel
performance and confirm the safety of a voyage by and outer shell due to temperature difference is large, we
continuously monitoring the deterioration rate of vacuum installed all pipes penetrating the CCS into a tank dome
and predicting any risk of thermal insulation performance placed at the top part of CCS. In the tank dome, we placed
deteriorating too quickly. cargo piping, conduit pipes, and an access hole.
(ii) CCS support structure (iv) CCS manufacturing technology
For the inner vessel and outer shell of the CCS, we Kawasaki has been manufacturing spherical liquefied
adopted austenite stainless steels, a material suitable for hydrogen storage tanks for rocket launch facilities as well
use in cryogenic conditions. The support structure, which as on-land liquefied hydrogen storage tanks and double-hull
Tank dome
Outer shell
Inner vessel Vacuum space
37
vacuum thermal insulation tanks for trailers. We have also terminal. Bayonet joints are commonly used as thermal-
manufactured a large-sized LNG storage tanks for ship. We insulated joints for liquefied hydrogen. Other cargo
manufactured the CCS by combining such technologies. handling equipment includes a compressor to compress
hydrogen gas, an evaporator to gasify liquefied hydrogen,
(2) Double-wall vacuum insulated piping and a heater to warm cryogenic hydrogen gas.
We adopted the double-wall vacuum insulation system
for the cargo piping, similar to the CCS, to ensure high
thermal insulation performance. The inner pipe must be
4 Building and demonstration
stably supported by the outer pipe without letting them We started designing and manufacturing the CCS in
touch each other. Due to thermal expansion and shrinkage, fiscal 2017, started building the carrier hull in January 2019,
the inner and outer pipes become different in length. So, and launched the carrier in December 2019 (Fig. 4).
based on the double-wall vacuum pipe specifications we
applied to on-land hydrogen facilities before, we kept the (1) Carrier hull
thermal expansion and shrinkage during loading and An outline of the pilot demonstration carrier, such as
unloading and the carrier’s static/dynamic displacement in key dimensions, is shown in Table 1. As the carrier uses
mind as we developed a double-wall vacuum pipe for CCS of pressure vessel, we do not have to dispose of boil-
ships. For the valves for cryogenic use, we adopted off gas onboard during the voyage. We employed a diesel-
vacuum long bonnet valves with jackets, which have high electric propulsion system in which three main diesel
thermal insulation performance. generators supply electric power to two propulsion motors
and a propeller is driven through a reduction gear. The hull
(3) Cargo equipment is equipped with a bow thruster, a schilling rudder (a rudder
To ensure the durability of the cargo equipment against with high lift force and wide rudder angle), and a four-blade
the physical properties of hydrogen, based on marine controllable pitch propeller to improve operability when
equipment practically proven for LNG carriers and on-land berthing and unberthing.
equipment proven for hydrogen, we reviewed all materials
and specifications to cope with the properties of hydrogen (2) CCS
and the on-board utilization environment. For key The inside of the CCS (Fig. 5), which was completed in
equipment, we conducted tests using liquefied hydrogen March 2020, is equipped with submerged motor-driven
in the development phase, carried out operational risk pumps, a pipe support for fixing pipes, and equipment to
assessment, and took measures for identified issues. efficiently cool the inside of the CCS.
To enhance the thermal insulation properties and
reduce the risk of leaks, we adopted bayonet joints, as (3) Demonstration test
shown in Fig. 3, for the shore connection that connects to We will move to the demonstration phase after the
the loading arm system (LAS) of the loading/unloading liquefied hydrogen carrier is completed in 2020. In Phase I
warm sealing
cold sealing
Width〔m〕 19
Depth〔m〕 10. 6
39
of the demonstration, for the purpose of verifying the
Doctor of Philosophy
functions, performance, and safety of the CCS, piping, and
P.E.Jp (Marine & Ocean)
cargo equipment of the carrier, we will conduct each of the
Osamu Muragishi
following test items in the storing and loading/unloading R&D Department of Liquefied Hydrogen Carrier,
terminal that was constructed in the northeast area of Engineering Division,
Ship & Offshore Structure Company
Kobe Airport Island, which is located off the coast of Kobe
City: Shohei Inatsu
・Gas replacement in the CCS (efficient gas replacement R&D Department of Liquefied Hydrogen Carrier,
method) Engineering Division,
Ship & Offshore Structure Company
・Cool down of the CCS (efficient CCS cooling method)
・Loading of cargo liquid (filling the CCS with liquefied
hydrogen from the terminal)
・Operation of the cargo pump (operation under cryogenic Ryosuke Uraguchi
Project Control Department,
conditions) Hydrogen Project Development Center,
・Operation of other cargo equipment (function and Corporate Technology Division
performance)
・Confirmation of thermal insulation properties (thermal
insulation performance of the CCS and pipes) Kazuto Yamashiro
・Full load test (full load cruising and unloading procedure) Project Control Department,
Hydrogen Project Development Center,
In Phase II, we will demonstrate fully loaded marine
Corporate Technology Division
transportation between Japan and Australia.
Takumi Yoshida
References Ship Design Department,
Engineering Division,
1) Resolution MSC.370 (93) Amendments to the
Ship & Offshore Structure Company
International Code for the Construction and Equipment
of Ships Carrying Liquefied Gases in Bulk, IMO (IGC
Code) (2014)
2) Resolution MSC. 420 (97) Interim Recommendations
Takashi Koumoto
Manufacturing Engineering Department,
for Carriage of Liquefied Hydrogen in Bulk, IMO (2016) Production Division,
3) Guidelines for Liquefied Hydrogen Carriers, ClassNK Energy System & Plant Engineering Company
(2017)
4) Rules and Guidance for the Survey and Construction of
Steel Ships, Part N Ships Carrying Liquefied Gases in
Bulk, ClassNK (2019)
Hydrogen Utilization
— Development of Hydrogen Fueled Power
Generation Technologies
41
Combustor
Inlet air
Bearing
Exhaust air
Combustor liner
Pictures taken
in this direction
Fuel nozzle
Fuel nozzle
glowing red hot
using natural gas and hydrogen with a fuel nozzle for parts, making them so hot they glowed red.
natural gas. In the hydrogen combustion test, hydrogen Because there is a high-speed turbine rotation in the
flames and combustion gas got too close to the fuel nozzle stage after the combustor, if the combustor is damaged in
any way, such as a part falling off and entering the next NOx produced is also a major issue.
stage, the turbine may be broken and the engine will stop.
For this reason, it is important to take measures such as
giving combustor parts shapes that make it possible to
3 Development progress on hydrogen
maintain stable combustion even with hydrogen.
fueled gas turbines
There are mainly two types of combustion technologies
(2) Reduction of nitrogen oxides for NOx reduction in gas turbine. One is diffusion flame
Figure 3 shows images of a visualization combustor in combination with water injection that reduces NOx by
which part of the combustor was replaced with a quartz spraying water or steam into a combustor, which has high
glass cylinder to make it possible to research the flames combustion stability, and the other is dry low emission that
generated by igniting a hydrogen/natural gas mixture in the reduces NOx by other methods such as adjusting the way
combustor; and the appearance of the flames taken with a air and fuel are mixed together.
high speed camera. When the proportion of natural gas In the case of diffusion flame combustion in which fuel
was larger, as shown in Fig. 3 (b), the flames were formed gas is injected into the air and ignited, all that is required in
farther away from the fuel nozzle. On the other hand, order to accommodate hydrogen combustion is to take
when the proportion of hydrogen was larger, as shown in measures for the temperature rise of combustor parts.
Fig. 3 (c), the flames were formed closer to the fuel nozzle. Kawasaki adopted water injection to establish technologies
Due to this difference in reaction areas and the rise in local for the entire hydrogen fueled gas turbine power
flame temperature, when hydrogen is combusted in a gas generation system.
turbine combustor, nearly 2 to 2.5 times more NOx is However, with water injection, pure water production
produced than with natural gas. Reducing the amount of equipment must be installed to supply water and steam
Photographed area
(b) 80 vol% natural gas to 20 vol% hydrogen (c) 5 vol% natural gas to 95 vol% hydrogen
43
and so running costs will rise. That is why we are also any desired ratio.
implementing research and development on a new dry low Figure 4 is an overall view of our hydrogen gas turbine
emission combustor suited to hydrogen combustion. cogeneration system demonstration plant installed on Port
Island in Kobe City. After completion of the plant in
(1) Technology demonstration for hydrogen fueled gas December 2017, we carried out trial operation of the gas
turbine power generation turbine power generation system alone and operation tests
In a grant project by the New Energy and Industrial using natural gas, and then conducted demonstration tests
Technology Development Organization (NEDO), called the to supply both heat and power with a natural gas/hydrogen
Smart Community Technology Development Project blend and 100% hydrogen.
Utilizing Hydrogen Cogeneration Systems, Kawasaki In a demonstration test held on April 19 and 20, 2018,
worked on a hydrogen cogeneration system with a focus this system was fueled with 100% hydrogen at a rate of
on the development of hydrogen-fueled and natural gas approximately 2,200 Nm3/h, and it successfully supplied
and hydrogen mixture-fueled gas turbines1), 2). 2,800 kW of heat (steam) to two neighboring facilities and
In this project we employed a 1MW-class PUC17D 1,100 kW of electricity to four neighboring facilities at the
Generator for Ordinary Use, which is equipped with our same time, which is the world's first successful example
M1A-17D Gas Turbine Engine, which has a hydrogen of cogeneration using hydrogen fueled gas turbine power
combustion-compatible combustor. This generator has high generation in an urban area. Figure 5 is a picture of a
fuel flexibility to allow for operation with 100% hydrogen monitor for the operation monitoring system during this
fuel, natural gas, and natural gas/hydrogen blends mixed at demonstration test. We achieved NOx 50 ppm (O2-16%) by
water injection, which met the threshold of 70 ppm (O2- causes combustion instability like flash-back, it is very
16%) set by Japan’s Air Pollution Control Act. difficult to use dry low NOx combustion with it.
For this reason, Kawasaki has studied the application of
(2) Development of hydrogen dry low NOx combustion micro-mix hydrogen combustion technology to industrial
technology gas turbines. This is a hydrogen dry low NOx combustion
Natural gas achieves dry low NOx combustion by lean technology that uses small hydrogen flames. As shown in
premixed combustion, in which the air and natural gas are Fig. 6, hydrogen injected from small hydrogen injection
mixed in advance and then the mixed gas is combusted. holes less than a millimeter in diameter is rapidly mixed
On the other hand, as hydrogen has high reactivity and with a cross jet flow of air, which forms small hydrogen
Hydrogen
Fig. 7 Hydrogen dry low NOx combustor for 2MW class gas turbine
45
flames with high flame stability, and also reduces NOx by
shortening the reaction time. Atsushi Horikawa
Thermal System Research Department,
Figure 7 is a hydrogen dry low NOx combustor for a Technical Institute,
2MW class gas turbine. The hydrogen burner is in the shape Corporate Technology Division
of a ring, and the number of rings can be changed according
to the hydrogen flow rate (operation conditions) 3), 4). This
enables both high combustion efficiency from the time the Kunio Okada
engine starts to lower load operation conditions and low Thermal System Research Department,
Technical Institute,
NOx combustion during higher load operation conditions.
Corporate Technology Division
We used trial combustor test parts to obtain ignition and
flame stability performance, and combustion characteristics,
NOx emissions in design conditions. Figure 8 (a) shows a
trial combustor installed in a facility that can replicate high Mitsugu Ashikaga
Project Control Department,
temperature and high pressure combustor inlet boundary Hydrogen Project Development Center,
conditions that are the same as a 2MW class gas turbine, Corporate Technology Division
and Fig. 8 (b) shows the hydrogen flame behavior inside
the combustor under conditions equivalent to 100% of the
design load. Masato Yamaguchi
In this test we confirmed stable hydrogen combustion Project Control Department,
Hydrogen Project Development Center,
and achieved less than NOx 35 ppm (O2-16%), which is
Corporate Technology Division
half of the regulation value, in the range of 50% load to
100% design load operation equivalent.
In May 2020, we started demonstration operation of
the gas turbine engine installed in this combustor in the
Yasushi Douura
Gas Turbine Engineering Department,
hydrogen gas turbine cogeneration system demonstration Energy System Group,
plant shown in Fig. 4, and successfully generated power Energy Solution Business Division,
Energy System & Plant Engineering Company
using hydrogen dry low NOx power generation for the first
time in the world.
Our next step has been proceeding with performance Yoshihiro Akebi
verifications such as stable operation and power Quality Assurance Department of Energy &
Marine Machinery System,
generation efficiency, and to reduce the environmental Quality Assurance Division,Energy System &
load. Plant Engineering Company
Conclusion
As part of the realization of a hydrogen energy supply
chain, Kawasaki is developing technology for hydrogen express our deep gratitude to NEDO.
combustion and a hydrogen fueled gas turbine. We believe
such technologies will make it possible to use hydrogen as
fuel for gas turbines, like natural gas, and can greatly
Reference
contribute to the realization of a low-carbon society and a 1) Atsushi Horikawa: Current Status of Hydrogen Fueled
hydrogen-based society in the future. Gas Turbine in Kawasaki Heavy Industries, Ltd., The
The contents in this chapter include the results Thermal and Nuclear Power, Vol. 70, No. 757 (2019)
achieved with NEDO’s support, namely, two grant projects, 2) NEDO website, https://www.nedo.go.jp/news/press/
the Demonstration Project for Establishment of Mass AA5_100945.html
Hydrogen Marine Transportation Supply Chain Derived from 3) Japanese Patent No. 6285081, “Combustor of a gas
Unused Brown Coal, and the Smart Community turbine engine”
Technology Development Project Utilizing Hydrogen 4) A. Horikawa, K. Okada, M. Wirsum, H. Funke, K.
Cogeneration Systems, and the commissioned project, Kusterer: “Application of Low NOx Micro-Mix Hydrogen
Research and Developments of Hydrogen Combustion Combustion to 2MW Class Industrial Gas Turbine
Technology for Hydrogen Gas Turbines. We would like to Combustor,” IGTC2019 Tokyo (2019)
47
Table 2 Standards and guidelines for hydrogen safety
Hydrogen safety AIAA G-095 : Guide to Safety of Hydrogen and Hydrogen Systems (2014)
located. The High Pressure Gas Safety Act is one of them standards, and moreover, they have established a product
and regulations for hydrogen supply facilities are being development scheme based on risk assessment by
developed. manufacturers or operators. In Japan, related laws and
On the other hand, for the carriage of liquefied gases in regulations are changing from a specification-based
bulk by ships, the ships should comply with the relevant approach that defines specific criteria, to a performance-
requirements in the IGC Code, set by the International based approach, which only defines a specific level of
Maritime Organization (IMO). However, the requirements performance and leaves it up to manufacturers how they
for liquefied hydrogen are not specified in the Code. For achieve the requirements. In the latter approach,
this reason, in 2013 Ministry of Land, Infrastructure, risk assessment becomes an effective method of
Transport and Tourism established a working group of demonstrating accountability. Risk assessment is a series
experts and started discussions on safety standards. of steps in which risk inherent in systems is identified,
Japan made a proposal to the IMO, and interim estimated and evaluated. And it determines proper risk
recommendations for carriage of liquefied hydrogen in bulk reduction measures to be planned according to the results.
were adopted in 2016 2). As the interim recommendations In order to provide safety hydrogen products, from a
require that safety measures be considered based on a risk technical standpoint, we are required to design products
assessment, the assessment results on the basic design based on adequate risk assessment results and also to
of the pilot ship Kawasaki designed have been published conduct phenomenological experiments to clarify the
by the IMO 3). After that, Class NK instituted Guidelines for behavior of hydrogen and numerical analyses using proven
Liquefied Hydrogen Carriers corresponding to the interim methods. Also, from the standpoint of project execution,
recommendations. Major standards and guidelines are we are required an integrated approach considering an
shown in Table 2. occupational safety, health, and environmental.
Method Features
conducted for the pilot project are shown in Table 4. An the hydrogen gas showed a higher ascent velocity and
image of a HAZOP study workshop, which is one of the smaller horizontal dispersion. In addition, it was observed
assessment methods, is shown in Figure 1. from the temperature distribution that low temperature
gas stagnated on the ground for LNG , but the same
(1) Hydrogen behavior phenomenological experiment behavior was not observed for hydrogen.
In order to identify various hydrogen behaviors that can
be caused by an accident, we conducted a variety of (2) Numerical analysis
experiments in collaboration with third parties. Figure 2 ( i ) Hydrogen leak analysis
shows the results of liquefied hydrogen and LNG Because a ship has limited space in which to install
dispersion tests conducted in 2013. In these tests, we equipment, some of the hydrogen cargo pipeline and
released approximately six liters of liquefied hydrogen and equipment have to be installed in an enclosed space.
LNG from approximately 0.9 meters above stainless steel Under such circumstances, if a hydrogen leakage occurs, it
materials on the ground, observed the consequent vapor is essential that the leakage be detected immediately and
cloud distribution, and evaluated the spread speed and the the enclosed space be ventilated to exhaust the leaking
effects caused by the material of the surface onto which gas.
the liquids were spilled. It was found that both of the low To address that, we first assumed the leakage
temperature fluids cooled the surrounding atmosphere and conditions based on possible scenarios, such as leakage
formed vapor clouds during the process of evaporation, but points, cross-section area, direction and physical properties
Conducted in
Name Scope External expert
〔year〕
49
Temperature
16°C
-40°C
(a) Vapor cloud distribution of liquefied hydrogen (b) Temperature distribution of liquefied hydrogen
Temperature
30°C
-40°C
(c) Vapor cloud distribution of LNG (d) Temperature distribution of LNG
and then we performed ventilation analysis for the ventilated smoothly. Figure 4 shows that the hydrogen
enclosed space using CFD. Ventilation flow analysis for leakage (colored light blue) from a pipe connection quickly
room-temperature air in a cargo machinery room is shown reached the exhaust port.
in Figure 3, and hydrogen behavior analysis for when (ii) Analysis of hydrogen behavior in liquefied hydrogen
cryogenic hydrogen gas leaks from 5 mm2 hole is shown in storage tank by rapid pressure release
Figure 4. In Figure 3, each color of the lines represents the While we have designed a liquefied hydrogen storage
air residual time from the inlet port to the exhaust port, tank adopting state-of-the-art thermal insulation
which shows that the air taken in from the inlet was technology, it is impossible to completely prevent the
Exhaust port
Inlet port
排気口
Exhaust port
Leak hydrogen
吸気口
Inlet port
vaporization of liquefied hydrogen caused by heat ingress increase. Because of this, prior to unloading after a voyage,
into a tank under operation. As hydrogen vaporization by we need to release the internal pressure of the tank to
heat ingress increases the pressure inside a tank, we atmospheric pressure. However, when the internal
designed our liquefied hydrogen tank at loading/unloading pressure is released too rapidly, the vapor-liquid will lose
terminals to prevent the internal pressure from exceeding the thermal equilibrium, which might cause rapid
the designated level by releasing boil-off gas from its vaporization of liquefied hydrogen.
ventilation facilities. On the other hand, the liquefied In order to clarify this complex hydrogen behavior inside
hydrogen carrier of this pilot project adopts a pressure a tank, we conducted the rapid internal pressure releasing
accumulator storage tank, which does not release any boil- experiments and numerical analysis for the experiments
off gas during the voyage but allows the inner pressure to with the University of Tokyo using the JAXA’s 30 m 3
340
6 6
330
Height〔m〕
Height〔m〕
4 4
320 2 2
Pressure〔kPaG〕
0 0
-1 0 1 -1 0 1
310 Width〔m〕 Width〔m〕
after 6 sec. after 8 sec.
Height〔m〕
6
300
290 2
0
-1 0 1
Experiment result
280 CFD analysis
Width〔m〕
after 1 sec.
270
0 5 10 15
Time〔sec〕
51
cylindrical liquefied hydrogen storage tanks, and we are
PMP (Project Management Professional)
examining the changes in the pressure and temperature
Katsuhiro Kanbe
inside the tank and analyzing how gas is produced from HSE & Standard Promotion Department,
the liquid phase 4). Figure 5 is an image of the storage tank Hydrogen Project Development Center,
under analysis. Figure 6 is sample data of the experiments Corporate Technology Division
Overseas Offices
Taipei Office
15F, Fu-key Bldg., 99 Jen-Ai Road, Section 2, Taipei, Taiwan
Tel. +886-2-2322-1752 / Fax. +886-2-2322-5009
Edited and Published by : Corporate Technology Division, Kawasaki Heavy Industries, Ltd.
1-1, Kawasaki-cho, Akashi, Hyogo 673-8666, Japan
URL: www.khi.co.jp
Publisher : Hiroshi Nakatani, General Manager, Corporate Technology Division
Chief editor : Hironobu Urabe, General Manager, Corporate Technology Planning Center
Corporate Technology Division
Designed and Printed by : SYUKODO CO., LTD.
9-16 Nakajima-cho, Naka-ku Hiroshima City, Hiroshima 730-0811, Japan
URL: www.syukodo.co.jp
“duAro”, the “duAro” logo, “Successor”, “VIPDM” registered trademarks of Kawasaki Heavy
Industries, Ltd.
The “HEA” logo registered trademark of Hydrogen Engineering Australia Pty Ltd.
Company names, product names and service names mentioned in this journal may be used as
trademarks by the respective companies.