Department of Public Works and Highways BUREAU OF RESEARCH AND STANDARDS _| Revision No. | : on Issue Date |:| August 8, 2022 Page No. |: Tof 24 ‘SPECIFICATIONS FOR APPARATUS, EQUIPMENT & SUPPLIES (D.O. NO. 100, SERIES OF 2018) IV, MISCELLANEOUS MATERIALS Construction Lime (Hydrated) REVISION HISTORY Revision No. | Issue Date _| Description - 00 une 8, 2021 _| Original ne nS SSS KS Prepared By: ‘Noted By: /, +f } | Ag tte. He | MICHAEL by CLAASSEN RABOT | LIWA) i. DE JESUS Chemist I Engipeer IV Chemical Testing Section | Chemical/festing Section | Materials Testing Division Date: Date:Department of Public Works and Highways | Sue Date _|:| August 8, 2022 BUREAU OF RESEARCH AND STANDARDS. Revision No. 1 Page No. 2of 21 ‘SPECIFICATIONS FOR APPARATUS, EQUIPMENT & SUPPLIES. (D.O. NO. 100, SERIES OF 2018) IV. MISCELLANEOUS MATERIALS Construction Lime (Hydrated) Table of Contents ASTM C25 - Standard Test Methods for Chemical Analysis of Limestone, Quicklime, and Hydrated Lime - Sections 8, 10, 12 and 16 - Calcium Oxide by Gravimetric Method ASTM C25 - Standard Test Methods for Chemical Analysis of Limestone, Quicklime, and Hydrated Lime - Sections 8, 10, 12, 16 and 18 - Magnesium Oxide. ASTM C25 - Standard Test Methods for Chemical Analysis of Limestone, Quicklime, and Hydrated Lime - Section 22 - Carbon Dioxide by Standard Method ASTM C25 - Standard Test Methods for Chemical Analysis of Limestone, Quicklime, and Hydrated Lime - Section 30 - Unhydrated Oxides Calculated on As- Received Basis .... 1 4.1 ASTM C25 - Standard Test Methods for Chemical Analysis of Limestone, Quicklime, and Hydrated Lime - Section 16 - Calcium Oxide by Gravimetric Method..... 11 4.2, ASTM C25 - Standard Test Methods for Chemical Analysis of Limestone, Quicklime, and Hydrated Lime - Section 18 - Magnesium Oxide 11 4.3, ASTM C25 - Standard Test Methods for Chemical Analysis of Limestone, Quicklime, and Hydrated Lime - Section 22 - Carbon Dioxide by Standard Method... 11. 4.4 ASTM C25 - Standard Test Methods for Chemical Analysis of Limestone, Quicklime, and Hydrated Lime - Section 19 - Loss on Ignition. 11 4.5 ASTM C25 - Standard Test Methods for Chemical Analysis of Limestone, Quicklime, and Hydrated Lime - Section 21 - Free Moisture in Hydrated Lime.......12 4.6 ASTM C25 - Standard Test Methods for Chemical Analysis of Limestone, Quicklime, and Hydrated Lime - Section 23 - Sulfur Trioxide .. 14 ASTM C110 - Standard Test Methods for Physical Testing of Quicklime, Hydrated Lime, and Limestone - Section 6 - Standard Consistency of Lime Putty, and Plasticity of Lime Putty ASTM C110 - Standard Test Methods for Physical Testing of Quicklime, Hydrated Lime, and Limestone - Plastic Property Testing - Section 7 - Water Retention of Hydrated Lime 0 18 ASTM C110 - Standard Test Methods for Physical Testing of Quicklime, Hydrated Lime, and Limestone - Particle Size Analysis - Section 15 - Quicklit and Wet Sieve Analysis of Limestone and Hydrated LimeDepartment of Public Works and Highways | !SSue Date _| :| August 8, 2022 BUREAU OF RESEARCH AND STANDARDS. Revision No. | : OL Page No.__|: of 21 ‘SPECIFICATIONS FOR APPARATUS, EQUIPMENT & SUPPLIES (D.0. NO. 100, SERIES OF 2018) IV, MISCELLANEOUS MATERIALS Construction Lime (Hydrated) 1. ASTM C25 - Standard Test Methods for Chemical Analysis of Limestone, Quicklime, and Hydrated Lime - Sections 8, 10, 12 and 16 - Calcium Oxide by Gravimetric Method Materials Certified Reference | At least 2 or more of the following: ECRM-752-1, IPT 35, IPT 44, IRSID DO 1-1, NIST 1C, NIST 88B, BCS 368, IRSID 702-1, GBW 07214, GBW 07215, GBW 07216, GBW 07217, GBW 03106, GBW 03108 or IPT 48 or their replacement SRM/CRM; With SDS and Certificate of Analysis from the manufacturer; GHS compliant labelling; Original manufacturer's container and not repacked. [Sample container Container (preferably glass) with airtight lid/cover. 50 mL or greater volume Laboratory Glassware and Glass | Standard volumetric flasks, burets, and pipets; precision grade or better; standard-taper, interchangeable, ground-glass joints for all volumetric Containers/ reagent | glassware and distilling apparatus, colored glass (amber) for the hotties protection of solutions against light; alkali-resistant glass, and high-silica glass having exceptional resistance to thermal shock Polyethylene (for all aqueous solutions of alkalies and for standard solutions where the laboratory presence of dissolved silica or alkali from the glass would be containers/ reagent | objectionable) - high-density polyethylene having a wall thickness of at bottles least 1 mm. iSieves No. 50 (250-4m) sieve conforming to ASTM E11. Preferably 100 mm (4- in.) depth Pan and cover of the same diameter as the sieve Analytical Balance capacity < 200 g; constant-load direct-reading type; reproducibility within 0.0002 g; accuracy + 0.0002 g; sensitivity < 0.0001 g, with 220/240/220- 240 V AVR/UPS Weights National Institute of Standards and Technology (NIST) Classes S-1 or OIML Class F1 or better; 200g, 100g, 50 g, 20g, 10 g, 5g, 29, 1g, 500 mg, 200 mg, 100 mg, 50 mg, 20 mg, & 10 mg with cover Platinum Crucible | 25 to 35 ml, pure unalloyed platinum or alloyed platinum that should not decrease by more than 0.2 mg when heated at 1200°C for 1 h.Department of Public Works and Highways | sue Date | :| August 8, 2022 BUREAU OF RESEARCH AND STANDARDS —_| Revision No. | : on Page No. |: 4 of 21 ‘SPECIFICATIONS FOR APPARATUS, EQUIPMENT & SUPPLIES (D.0. NO. 100, SERIES OF 2018) IV. MISCELLANEOUS MATERIALS Construction Lime (Hydrated) Muffle Furnace with indicating pyrometer accurate within +25°C, capable of reaching 1200°C, 220/240/220-240 V or with 220/240/220-240 V AVR/UPS LI} ‘Canopy Hood for the Furnace, No required specifications Tongs long crucible tongs, jumbo crucible tongs, julian-style crucible tongs, pouring tongs or furnace tongs for the furnace Beaker Tongs capable of handling up to 1000 mL beaker, jaws are covered/coated with fiber glass, epoxy coating or other chemical resistant material Crucible tongs capable of handling up to 50 mL crucible, stainless steel, with corrugated tip Evaporating dish preferably platinum, porcelain if platinum is not available, 30 mL or larger ‘Steam bath may be made from hotplate with water bath on top, 220/240/220-240 V ‘or with 220/240/220-240 V AVR/UPS jOven or air bath capable of maintaining a temperature of 100°C for at least 1 hour, 220/240/220-240 V or with 220/240/220-240 V AVR/UPS Hydrochloric acid (HCl) - sp gr 1.19 or 37% or concentrated or fuming, reagent grade or similar grade or better; With SDS and Certificate of Analysis from the manufacturer; GHS compliant labelling; Original manufacturer's container and not repacked. Ethyl alcohol or Ethanol - 95 or 99%, reagent grade or similar grade or better; With SDS and Certificate of Analysis from the manufacturer; GHS compliant labelling; Original manufacturer's container and not repacked. Methyl red indicator Solid; reagent grade or similar grade or better; With SDS and Certificate of Analysis from the manufacturer; GHS compliant labelling; Original manufacturer's container and not repacked, Ammonium hydroxide ‘or Ammonia solution or Ammonia (NHsOH) - sp gr 0.90 or 28-30%, reagent grade or similar grade or better; With SDS and Certificate of Analysis from the manufacturer; GHS compliant labelling; Original manufacturer's container and not repacked.Department of Public Works and Highways | sue Date_| :| August 8, 2022 BUREAU OF RESEARCH AND STANDARDS _| Revision No. | : on Page No. |: Sof 21 ‘SPECIFICATIONS FOR APPARATUS, EQUIPMENT & SUPPLIES (D.0. NO. 100, SERIES OF 2018) IV. MISCELLANEOUS MATERIALS Construction Lime (Hydrated) _ [Ammonium chloride (NH4C)) - solid; reagent grade or similar grade or better; With SDS and Certificate of Analysis from the manufacturer; GHS compliant labelling; Criginal manufacturer's container and not repacked. [Ammonium oxalate solid; reagent grade or similar grade or better; With SDS and Certificate of Analysis from the manufacturer; GHS compliant labelling; Original manufacturer's container and not repacked. lOxalic acid solid; reagent grade or similar grade or better; With SDS and Certificate of Analysis from the manufacturer; GHS compliant labelling; Original manufacturer's container and not repacked. Saturated bromine __ | reagent grade or similar grade or better; With SDS and Certificate of water Analysis from the manufacturer; GHS compliant labelling; Original manufacturer's container and not repacked. Potassium iodide Roll or strip type, with color scale starch paper Filter Paper Specifications £832 Type II Quantitative Class G or #40, Ashless Filter Paper Specifications E832 Type II Quantitative Class F or #42, Ashless. Funnel alkali-resistant glass, and high-silica glass having exceptional resistance to thermal shock (borosilicate glass) Wash Bottle No required specifications Hotplate adjustable from 100°C to 300°C or wider range, 220/240/220-240 V or with 220/240/220-240 V AVR/UPS ICharring Apparatus | Lighter or other apparatus for charting the filter paper prior to ignition Desiccator (Specify inner diameter, volume capacity or crucible capacity), With desiccant whose color changes in response to moisture concentration or an instrument for measuring moisture (e.g. a hygrometer) Desiccant magnesium perchlorate, activated alumina, sulfuric acid or anhydrous calcium sulfate treated with a color-change indicatorDepartment of Public Works and Highways BUREAU OF RESEARCH AND STANDARDS —_ | Revision No. | : oT Issue Date |:} August 8, 2022 Page No. |: Gof 21 ‘SPECIFICATIONS FOR APPARATUS, EQUIPMENT & SUPPLIES (D.0. NO. 100, SERIES OF 2018) IV. MISCELLANEOUS MATERIALS Construction Lime (Hydrated) Water Purification | capable of producing at least distilled water or any of the types described [System in ASTM D 1193, 220/240/220-240 V or with 220/240/220-240 V AVR/UPS Fumehood (Ducted | Refer to "SPECIFICATIONS FOR APPARATUS, EQUIPMENT & SUPPLIES with scrubber) (D.0. NO. 100, SERIES OF 2018). V, MISCELLANEOUS LABORATORY EQUIPMENT. Laboratory Fumehood” for the specifications ASTM C25 - Standard Test Methods for Chemical Analysis of Limestone, Quicklime, and Hydrated Lime - Sections 8, 10, 12, 16 and 18 - Magnesium Oxide Certified Reference | At least 2 or more of the following: ECRM-752-1, IPT 35, IPT 44, IRSID DO Materials 1-1, NIST 1C, NIST 88B, BCS 368, IRSID 702-1, GBW 07214, GBW 07215, GBW 07216, GBW 07217, GBW 03106, GBW 03108 or IPT 48 or their replacement SRM/CRM; With SDS and Certificate of Analysis from the manufacturer; GHS compliant labelling; Original manufacturer's container and not repacked. |Sample container Container (preferably glass) with airtight lid/cover. 50 mL or greater volume Glassware and Glass | Standard volumetric flasks, burets, and pipets; precision grade or better; Laboratory standard-taper, interchangeable, ground-glass joints for all volumetric Containers/reagent | glassware and distilling apparatus, colored glass (amber) for the bottles protection of solutions against light; alkali-resistant glass, and high-silica glass having exceptional resistance to thermal shock Polyethylene (for all aqueous solutions of alkalies and for standard solutions where the laboratory presence of dissolved silica or alkali from the glass would be lcontainers/reagent | objectionable) - high-density polyethylene having a wall thickness of at bottles least 1 mm sieves No. 50 (250-um) sieve conforming to ASTM E11. Preferably 100 mm (4- in.) depth Pan and cover of the same diameter as the sieveDepartment of Public Works and Highways BUREAU OF RESEARCH AND STANDARDS Revision No. | : on Issue Date | :} August 8, 2022 Page No. |: Tof 21 SPECIFICATIONS FOR APPARATUS, EQUIPMENT & SUPPLIES (D.0. NO. 100, SERIES OF 2018) IV. MISCELLANEOUS MATERIALS Construction Lime (Hydrated) Analytical Balance capacity < 200 g; constant-load direct-reading type; reproducibility within 0.0002 g; accuracy + 0.0002 g; sensitivity < 0.0001 g, with 220/240/220- 240 V AVR/UPS Weights National Institute of Standards and Technology (NIST) Classes S-1 or OIML Class F1 or better; 200g, 100g, 50 g, 20g, 10 g, 5g, 2g, 1g, 500 mg, 200 mg, 100 mg, 50 mg, 20 mg, & 10 mg Platinum —_Crucible | 25 to 35 mL, pure unalloyed platinum or alloyed platinum that should not with cover decrease by more than 0.2 mg when heated at 1200°C for 1 h. Muffle Furnace with indicating pyrometer accurate within #25°C, capable of reaching 1200°C, 220/240/220-240 V or with 220/240/220-240 V AVR/UPS Canopy Hood for the Furnace Tongs long crucible tongs, jumbo crucible tongs, jullan-style crucible tongs, pouring tongs or furnace tongs for the furnace Beaker Tongs capable of handling up to 1000 mL. beaker, jaws are covered/coated with fiber glass, epoxy coating or other chemical resistant material Crucible tongs capable of handling up to 50 mL crucible, stainless steel, with corrugated tip Evaporating dish _| preferably platinum, porcelain if platinum is not available, 30 mL or larger Steam bath may be made from hotplate with water bath on top, 220/240/220-240 V or with 220/240/220-240 V AVR/UPS Oven or air bath capable of maintaining a temperature of 100°C for at least 1 hour, 220/240/220-240 V or with 220/240/220-240 V AVR/UPS Hydrochloric acid —_| (HC!) - sp gr 1.19 or 37% or concentrated or fuming; reagent grade or similar grade or better; With SDS and Certificate of Analysis from the manufacturer; GHS compliant labelling; Original manufacturer's container and not repacked. Ethyl alcohol or Ethanol - 95 or 99%; reagent grade or similar grade or better; With SDS and Certificate of Analysis from the manufacturer; GHS compliant labelling; Original manufacturer's container and not repacked.Department of Public Works and Highways BUREAU OF RESEARCH AND STANDARDS Revision No. | = o1 Issue Date |:] August 8, 2022 Page No. |: Sof 21 ‘SPECIFICATIONS FOR APPARATUS, EQUIPMENT & SUPPLIES (D.0. NO. 100, SERIES OF 2018) IV. MISCELLANEOUS MATERIALS Construction Lime (Hydrated) Methyl Red Indicator | solid; reagent grade or similar grade or better; With SDS and Certificate of Analysis from the manufacturer; GHS compliant labelling; Original ‘manufacturer's container and not repacked. Ammonium ‘or Ammonia solution or Ammonia (NH:OH) - sp gr 0.90 or 28-30%; hydroxide reagent grade or similar grade or better; With SDS and Certificate of Analysis from the manufacturer; GHS compliant labelling; Original manufacturer's container and not repacked. |Ammonium chloride (NHACI) - solid; reagent grade or similar grade or better; With SDS and Certificate of Analysis from the manufacturer; GHS compliant labelling; Original manufacturer's container and not repacked. Ammonium Oxalate Solid; reagent grade or similar grade or better; With SDS and Certificate of Analysis from the manufacturer; GHS compliant labelling; Original manufacturer's container and not repacked, Oxalic acid solid; reagent grade or similar grade or better; With SDS and Certificate of Analysis from the manufacturer; GHS compliant labelling; Original manufacturer's container and not repacked, Ammonium or Diammonium phosphate (NH.):HPOs, solid; reagent grade or similar phosphate dibasic | grade or better; With SDS and Certificate of Analysis from the manufacturer; GHS compliant labelling; Original manufacturer's container and not repacked. Nitric acid (HNOs) - sp gr 1.42 or 69.0-70.0% or concentrated; reagent grade or similar grade or better; With SDS and Certificate of Analysis from the manufacturer; GHS compliant labelling; Original manufacturer's container and not repacked. Saturated bromine water reagent grade or similar grade or better; With SDS and Certificate of ‘Analysis from the manufacturer; GHS compliant labelling; Original manufacturer's container and not repacked, Potassium iodide starch paper Roll or strip type, with color scale, laboratory grade Filter Paper Specifications £832 Type II Quantitative Class G or #40, Ashless Filter Paper Specifications £832 Type II Quantitative Class F or #42, AshlessDepartment of Public Works and Highways | !ssue Date _| :| August 6, 2022 BUREAU OF RESEARCH AND STANDARDS _| Revision No. | : o1 Page No. [= ‘Sof 21 ‘SPECIFICATIONS FOR APPARATUS, EQUIPMENT & SUPPLIES (D.0. NO. 100, SERIES OF 2018) IV. MISCELLANEOUS MATERIALS Construction Lime (Hydrated) Funnel alkali-resistant glass, and high-silica glass having exceptional resistance to thermal shock (borosilicate glass) Wash Bottle No required specifications Hotplate adjustable from 100°C to 300°C or wider range, 220/240/220-240 V or with 220/240/220-240 V AVR/UPS al ICharring Apparatus | Lighter or other apparatus for charring the filter paper prior to ignition Desiccator (Specify inner diameter, volume capacity or crucible capacity), With desiccant whose color changes in response to moisture concentration or an instrument for measuring moisture (e.g. a hygrometer) Desiccant magnesium perchlorate, activated alumina, sulfuric acid or anhydrous calcium sulfate treated with a color-change indicator Water Purification | capable of producing at least distilled water or any of the types described system in ASTM D 1193, 220/240/220-240 V or with 220/240/220-240 V AVR/UPS Fumehood (Ducted | Refer to “SPECIFICATIONS FOR APPARATUS, EQUIPMENT & SUPPLIES ‘with scrubber) (D.0. NO, 100, SERIES OF 2018). V. MISCELLANEOUS LABORATORY EQUIPMENT. Laboratory Fumehood” for the specifications }. ASTM C25 - Standard Test Methods for Chemical Analysis of Limestone, Quicklime, and Hydrated Lime - Section 22 - Carbon Dioxide by Standard Method Analytical Balance _| capacity < 200 g; constant-load direct-reading type; reproducibility within 0.0002 g; accuracy + 0.0002 g; sensitivity < 0.0001 g, with 220/240/220- 240 V AVR/UPS |Air pump 220/240/220-240 V or with 220/240/220-240 V AVR/UPS. Carbon dioxide test | consists of Purifying Jar A, Drying Tube B, Erlenmeyer Flask C, Separatory [apparatus Funnel D, Condenser E, Gas-Washing Bottle F, U-Tube G, Gas-Washing Bottle H, trap I, Absorption Bulb J, CO, Absorption Bulb K, U-Guard Tube L, and Purifying Jar M arranged as illustrated in ASTM C25 Figure 2. Resistant to H2SOs, HCI, Magnesium Perchlorate and NaOH. With connectors between the individual components, 220/240/220-240 V air pump and support stand(s) for the whole setup. Gas wash bottle or gasDepartment of Public Works and Highways BUREAU OF RESEARCH AND STANDARDS __[ Revision No. | = ot Issue Date | :] August 8, 2022 Page No. |: 10 of 21 ‘SPECIFICATIONS FOR APPARATUS, EQUIPMENT & SUPPLIES (D.0. NO. 100, SERIES OF 2018) IV. MISCELLANEOUS MATERIALS Construction Lime (Hydrated) washing bottle may be used for A and M. Drying Tube B is U-shaped with side arms and glass stoppers. Side arms are shaped to hold rubber tubing. Erlenmeyer Flask C is 250-mL with 24/40 ground-glass joint. Separatory Funnel D has ground-glass stopper and interchangeable hollow ground- glass joint. A delivery tube bent at the end extends into the sample flask about Ya in, from the bottom. Condenser E has tubings to connect to faucet and drain. Gas-Washing Bottle F and H are 250-mL and with fritted disk and are H,SOs resistant. CO, Absorption Bulb K contains a layer of glass wool extending above the bottom outlet. Hydrochloric acid (HC) - sp gr 1.19 or 37% or concentrated or fuming; reagent grade or similar grade or better; With SDS and Certificate of Analysis from the manufacturer; GHS compliant labelling; Original manufacturer's container and not repacked. Sulfuric acid (H:S0}) - sp gr 1.84 or 96% or 95-97%; reagent grade or similar grade or better; With SDS and Certificate of Analysis from the manufacturer; GHS compliant labelling; Original manufacturer's container and not repacked. Magnesium Perchlorate or Anhydrone - solid; reagent grade or similar grade or better; With SDS and Certificate of Analysis from the manufacturer; GHS compliant labelling; Original manufacturer's container and not repacked. |Ascarite sodium hydroxide coated silica or more recent version. Mote: Ascarite ‘made from granular asbestos is unacceptable, highly toxic and illegal; With SDS and Certificate of Analysis from the manufacturer; GHS compliant labelling; Original manufacturer's container and not repacked. Zine mossy; 299%; With SDS and Certificate of Analysis from the manufacturer; GHS compliant labelling; Original manufacturer's container and not repacked. Glass wool Laboratory grade Hotplate adjustable from 100°C to 300°C or wider range, 220/240/220-240 V or with 220/240/220-240 V AVR/UPS,Department of Public Works and Highways | Sue Date | =| August 8, 2022 BUREAU OF RESEARCH AND STANDARDS —_| Revision No. |: on Page No. [=| __iiof2i ‘SPECIFICATIONS FOR APPARATUS, EQUIPMENT & SUPPLIES (D.0. NO. 100, SERIES OF 2018) IV. MISCELLANEOUS MATERIALS Construction Lime (Hydrated) Fumehood (Ducted | Refer to “SPECIFICATIONS FOR APPARATUS, EQUIPMENT & SUPPLIES with scrubber) (0.0. NO. 100, SERIES OF 2018). V. MISCELLANEOUS LABORATORY EQUIPMENT, Laboratory Fumehood” for the specifications 4, ASTM C25 - Standard Test Methods for Chemical Analysis of Limestone, Quicklime, and Hydrated Lime - Section 30 - Unhydrated Oxides Calculated on As-Received Basis 4.1 ASTM C25 - Standard Test Methods for Chemical Analysis of Limestone, Quicklime, and Hydrated Lime - Section 16 - Calcium Oxide by Gravimetric Method Refer to "ASTM C25 - Standard Test Methods for Chemical Analysis of Limestone, Quicklime, and Hydrated Lime - Section 16 - Calcium Oxide by Gravimetric Method" section of this document for the list of apparatus, equipment and supplies and their corresponding specifications 4.2. ASTM C25 - Standard Test Methods for Chemical Analysis of Limestone, Quicklime, and Hydrated Lime - Section 18 - Magnesium Oxide Refer to “ASTM C25 - Standard Test Methods for Chemical Analysis of Limestone, Quicklime, and Hydrated Lime - Section 18 - Magnesium Oxide” section of this document for the list of apparatus, equipment and supplies and their corresponding specifications 4.3. ASTM C25 - Standard Test Methods for Chemical Analysis of Limestone, Quicklime, and Hydrated Lime - Section 22 - Carbon Dioxide by Standard Method Refer to “ASTM C25 - Standard Test Methods for Chemical Analysis of Limestone, Quicklime, and Hydrated Lime - Section 22 - Carbon Dioxide by Standard Method” section of this document for the list of apparatus, equipment and supplies and their corresponding specifications 4.4 ASTM C25 - Standard Test Methods for Chemical Analysis of Limestone, Quicktime, and Hydrated Lime - Section 19 - Loss on Ignition Certified Reference | At least 2 or more of the following: ECRM-752-1, IPT 35, IPT 44, IRSID DO Materials 14, NIST 1C, NIST 888, BCS 368, IRSID 702-1, GBW 07214, GBW 07215, GBW 07216, GBW 07217, GBW 03106, GBW 03108 or IPT 48 or their replacement SRM/CRM; With SDS and Certificate of Analysis from the manufacturer; GHS compliant labelling; Original manufacturer's container || and not repacked. ‘Sample container Container (preferably glass) with airtight lid/cover. 50 mL or greater volumeDepartment of Public Works and Highways | !S5ue Date | :| August 8, 2022 BUREAU OF RESEARCH AND STANDARDS. Revision No. OL Page No. of 21 ‘SPECIFICATIONS FOR APPARATUS, EQUIPMENT & SUPPLIES (D.O. NO. 100, SERIES OF 2018) IV. MISCELLANEOUS MATERIALS Construction Lime (Hydrated) Sieves No. 100 (149-im) sieve conforming to ASTM E11. Preferably 100 mm (4- in.) depth Pan and cover of the same diameter as the sieve Analytical Balance _| capacity < 200 g; constant-load direct-reading type; reproducibility within 0.0002 g; accuracy + 0.0002 g; sensitivity < 0.0001 g, with 220/240/220- 240 V AVR/UPS Weights National Institute of Standards and Technology (NIST) Classes S-1 or OIML Class F1 or better; 200g, 100g, 50g, 20g, 10g, 5g, 2g, 19, 500 mg, 200 mg, 100 mg, 50 mg, 20 mg, & 10 mg Platinum Crucible | 25 to 35 mL, pure unalloyed platinum or alloyed platinum that should not with cover decrease by more than 0.2 mg when heated at 1200°C for 1 h. Muffle Furnace with indicating pyrometer accurate within +20°C, capable of reaching 1200°C, 220/240/220-240 V or with 220/240/220-240 V AVR/UPS Canopy Hood for the Furnace Tongs long crucible tongs, jumbo crucible tongs, julian-style crucible tongs, pouring tongs or furnace tongs for the furnace Beaker Tongs capable of handling up to 1000 mL beaker, jaws are covered/coated with fiber glass, epoxy coating or other chemical resistant material Crucible tongs capable of handling up to 50 mL crucible, stainless steel, with corrugated tip 4.5 ASTM C25 - Standard Test Methods for Chemical Analysis of Limestone, Quicklime, and Hydrated Lime - Section 21 - Free Moisture in Hydrated Lime Analytical Balance _| capacity < 200 g; constant-load direct-reading type; reproducibility within 0.0002 g; accuracy + 0.0002 g; sensitivity < 0.0001 g, with 220/240/220- 240 V AVR/UPS Free Moisture Test _| Purifying Train consisting of Soda-Lime Tower A, Bottle B, Fleming Jar C, Apparatus Absorption Bulb D, Sample Flask E, Drying Oven F, and Absorption Bulb G arranged as illustrated in ASTM C25 Figure 2. Resistant to H2SO, and soda lime. With connectors between the individual components, 220/240/220-240 V air pump and support stand(s) for the whole setup.Department of Public Works and Highways BUREAU OF RESEARCH AND STANDARDS _| Revision No. | : on Issue Date | :| August 8, 2022 Page No. |= 13 of 21 ‘SPECIFICATIONS FOR APPARATUS, EQUIPMENT & SUPPLIES (D.0. NO. 100, SERIES OF 2018) IV. MISCELLANEOUS MATERIALS Construction Lime (Hydrated) ‘Gas wash bottle or gas washing bottle may be used for A, Band C. Sample Flask E is a 50-ml flat-bottom, glass-stoppered flask, supplied with a Ground glass joint and solid ground glass stopper and fitted with an interchangeable hollow ground-glass stopper, equipped with two glass entry tubes for conducting the dry air over the sample. Drying Oven F is capable of maintaining 120°C for at least 2 hours Soda-Lime solid; reagent grade or similar grade or better; With SDS and Certificate of Analysis from the manufacturer; GHS compliant labelling; Original manufacturer's container and not repacked. Calcium hydroxide | [Ca(OH)2] - (for Lime water preparation) solid; reagent grade or similar grade or better; With SDS and Certificate of Analysis from the manufacturer; GHS compliant labelling; Original manufacturer's container and not repacked, Sulfuric acid (H:S0s) - sp gr 1.84 or 96% or 95-97%; reagent grade or similar grade or better; With SDS and Certificate of Analysis from the manufacturer; GHS compliant labelling; Original manufacturer's container and not repacked. Magnesium or Anhydrone - solid; reagent grade or similar grade or better; With SDS Perchlorate and Certificate of Analysis from the manufacturer; GHS compliant labelling; Original manufacturer's container and not repacked. Glazed paper No required specifications Flexible tubing for connecting the sample bottle to the purifying train Water Purification | capable of producing at least distilled water or any of the types described system in ASTM D 1193, 220/240/220-240 V or with 220/240/220-240 V AVR/UPS Desiccator (Specify inner diameter, volume capacity or crucible capacity), With desiccant whose color changes in response to moisture concentration or an instrument for measuring moisture (e.g. a hygrometer) Desiccant magnesium perchlorate, activated alumina, sulfuric acid or anhydrous calcium sulfate treated with a color-change indicator Fumehood (Ducted | Refer to “SPECIFICATIONS FOR APPARATUS, EQUIPMENT & SUPPLIES with scrubber) (D.0. NO. 100, SERIES OF 2018). V. MISCELLANEOUS LABORATORY EQUIPMENT. Laboratory Fumehood’” for the specificationsBUREAU OF RESEARCH AND STANDARDS _| Revision No. Department of Public Works and Highways | sue Date_| :| August 8, 2022 oT Page No. 14 of 21 ‘SPECIFICATIONS FOR APPARATUS, EQUIPMENT & SUPPLIES (D.0. NO. 100, SERIES OF 2018) IV, MISCELLANEOUS MATERIALS Construction Lime (Hydrated) 4.6 ASTM C25 - Standard Test Methods for Chemical Analysis of Limestone, Quicklime, and Hydrated Lime - Section 23 - Sulfur Trioxide Certified Reference | At least 2 or more of the following: ECRM-752-1, IPT 35, IPT 44, IRSID DO Materials 1:1, NIST 1C, NIST 88B, BCS 368, IRSID 702-1, GBW 07214, GBW 07215, GBW 07216, GBW 07217, GBW 03106, GBW 03108 or IPT 48 or their replacement SRM/CRM; With SDS and Certificate of Analysis from the manufacturer; GHS compliant labelling; Original manufacturer's container and not repacked. [Sample container Container (preferably glass) with airtight lid/cover. 50 mL or greater volume Glassware and Glass | Standard volumetric flasks, burets, and pipets; precision grade or better; Laboratory standard-taper, interchangeable, ground-glass joints for all volumetric Containers/ reagent | glassware and distilling apparatus, colored glass (amber) for the bottles protection of solutions against light; alkali-resistant glass, and high-silica glass having exceptional resistance to thermal shock Polyethylene (for all aqueous solutions of alkalies and for standard solutions where the laboratory presence of dissolved silica or alkali from the glass would be lcontainers/ reagent | objectionable) - high-density polyethylene having a wall thickness of at bottles least 1 mm Analytical Balance _| capacity < 200 g; constant-load direct-reading type; reproducibility within 0.0002 g; accuracy + 0.0002 g; sensitivity < 0.0001 g, with 220/240/220- 240 V AVR/UPS Weights National Institute of Standards and Technology (NIST) Classes S-1 or OIML Class F1 or better; 200g, 100g, 50g, 20g, 109, 5g, 29, 1 9, 500 mg, 200 mg, 100 mg, 50 mg, 20 mg, & 10 mg Platinum —_ Crucible | 25 to 35 mL, pure unalloyed platinum or alloyed platinum that should not with cover decrease by more than 0.2 mg when heated at 1200°C for 1h. Muffle Furnace with indicating pyrometer accurate within +25°C, capable of reaching 1200°C, 220/240/220-240 V or with 220/240/220-240 V AVR/UPS ‘Canopy Hood for the Furnace. No required specifications.BUREAU OF RESEARCH AND STANDARDS _| Revision No. Department of Public Works and Highways | !SSue Date_| | August 8, 2022 OL Page No. 15 of 21 ‘SPECIFICATIONS FOR APPARATUS, EQUIPMENT & SUPPLIES (D.0. NO. 100, SERIES OF 2018) IV. MISCELLANEOUS MATERIALS Construction Lime (Hydrated) Tongs long crucible tongs, jumbo crucible tongs, julian-style crucible tongs, pouring tongs or furnace tongs for the furnace Beaker Tongs capable of handling up to 1000 mL beaker, jaws are covered/coated with fiber glass, epoxy coating or other chemical resistant material Crucible tongs capable of handling up to 50 mL crucible, stainless steel, with corrugated tip Glass stirring rod No required specifications Hydrochloric acid _| (HCI) - sp gr 1.19 or 37% or concentrated or funing; reagent grade or similar grade or better; With SDS and Certificate of Analysis from the manufacturer; GHS compliant labelling; Original manufacturer's container and not repacked. ‘Ammonium or Ammonia solution or Ammonia (NHsOH) - sp gr 0.90 or 28-30%; hydroxide reagent grade or similar grade or better; With SDS and Certificate of Analysis from the manufacturer; GHS compliant labelling; Original manufacturer's container and not repacked. Barium —_—_ chloride dihydrate (BaCk+2H,0). solid; reagent grade or similar grade or better; With SDS and Certificate of Analysis from the manufacturer; GHS compliant labelling; Original manufacturer's container and not repacked. Filter Paper ‘Specifications E832 Type II Quantitative Class G or #40, Ashless Filter Paper Specifications E832 Type II Quantitative Class F or #42, Ashless Funnel alkali-resistant glass, and high-silica glass having exceptional resistance to thermal shock (borosilicate glass) Hotplate adjustable from 100°C to 300°C or wider range, 220/240/220-240 V or with 220/240/220-240 V AVR/UPS Charring Apparatus | Lighter or other apparatus for charring the filter paper prior to ignition Desiccator (Specify inner diameter, volume capacity or crucible capacity), With desiccant whose color changes in response to moisture concentration or an instrument for measuring moisture (e.g. a hygrometer) Desiccant magnesium perchlorate, activated alumina, sulfuric acid or anhydrous calcium sulfate treated with a color-change indicatorDepartment of Public Works and Highways | Sue Date | =| August 8, 2022 BUREAU OF RESEARCH AND STANDARDS _| Revision No. o1 Page No. 16 of 21 ‘SPECIFICATIONS FOR APPARATUS, EQUIPMENT & SUPPLIES (D.O. NO. 100, SERIES OF 2018) IV, MISCELLANEOUS MATERIALS Construction Lime (Hydrated) Water Purification | capable of producing at least distilled water or any of the types described System in ASTM D 1193, 220/240/220-240 V or with 220/240/220-240 V AVR/UPS Fumehood (Ducted | Refer to “SPECIFICATIONS FOR APPARATUS, EQUIPMENT & SUPPLIES with scrubber) (0.0. NO. 100, SERIES OF 2018). V, MISCELLANEOUS LABORATORY EQUIPMENT. Laboratory Fumehood” for the specifications 5. ASTM C110 - Standard Test Methods for Physical Testing of Quicklime, Hydrated Lime, and Limestone - Section 6 - Standard Consistency of Lime Putty, and Plasticity of Lime Putty Modified Vicat Conforms to ASTM C110 or has the following specifications: shall consist Apparatus of a bracket, A, bearing a movable brass rod, B, 6.3 mm in diameter and of suitable length to fit the Vicat bracket. A plunger, C, 12.5 mm in diameter, made of aluminum tubing, shall be attached to the lower end of the rod. The total weight of the rod with plunger shall be 30 g. The lower end of the plunger shall be closed without shoulders or curvature and the tube may be loaded with shot to the specified weight. The total weight required may also be obtained by means of a weight, D, screwed into the rod. The rod can be held in any position by means of a screw, E, and has a mark midway between the ends which moves under a scale, F, graduated in millimetres, attached to the bracket, A. Mold conical ring mold made of a noncorroding, nonabsorbent material, and an inside diameter of 70 mm at the base and 60 mm at the top, and a height of 40 mm. Base Plate The base plate for supporting the ring mold shall be of plate glass and about 100 mm square Mechanical Mixers | Vac-Umixer (800 cm3 Vac-U-Mix bowl,), Hobart N-50 Mixer or similar mixers Mixing bow! Can fit the Mechanical Mixer (above) being used Flat Trowel / Spatula | sharpened straight-edged steel blade 100 to 150 mm in length. The edges when placed on a plane surface shall not depart from straightness by more than 1 mm.Department of Public Works and Highways | sue Date _| :| August 8, 2022 BUREAU OF RESEARCH AND STANDARDS _| Revision No. | : on Page No. _[:[ _i7of2i ‘SPECIFICATIONS FOR APPARATUS, EQUIPMENT & SUPPLIES (D.0. NO. 100, SERIES OF 2018) IV. MISCELLANEOUS MATERIALS Construction Lime (Hydrated) |Cover for mixing bow! Sufficient diameter or size to cover mixing bow! Weighing Device or Laboratory Balance capacity > 1000 g but less than 5000 g for high quality balances or 2000 g for regular balances; readability < 0.1 g; maintenance tolerance < 0.325 g; reproducibility < 0.325 g; sensitivity < 0.65 g (maintenance tolerance, reproducibility and sensitivity are calculated using a 650 g cement for cement paste preparation as test load), 220/240/220-240 V or with 220/240/220-240 V AVR/UPS if electronic Graduated Cylinder Class A borosilicate glass; 200 or 250-mL + 2.0 mL capacity; subdivided to at least 5 mL graduation lines but be omitted for the lowest 25 mL. for a 250-mL graduate; main graduation lines shall extend at least three quarters of the way around the graduate and shall be numbered Plasticimeter Emley Plasticimeter or plasticimeter conforming to ASTM C110 Figure 2, plasticity base plate should be porcelain, with at least 10 extra porcelain plasticity base plates, plasticity base plates should conform to ASTM C110 Section 6.2.3 joven capable of maintaining a temperature of 110 + 5°C. 220/240/220-240 V or with 220/240/220-240 V AVR/UPS |Canopy hood for Oven No required specifications Hydrochloric acid (HCl) - sp gr 1.19 or 37% or concentrated or fuming; reagent grade or similar grade or better; With SDS and Certificate of Analysis from the manufacturer; GHS compliant labelling; Original manufacturer's container and not repacked. Desiccator (Specify inner diameter, volume capacity or crucible capacity), With desiccant whose color changes in response to moisture concentration or an instrument for measuring moisture (e.g. a hygrometer) Desiccant (for desiccators that use desiccant) Silica gel or better performing desiccant. Color changes in response to moisture concentration [Stop watch or timing device Resolution of 1s or betterDepartment of Public Works and Highways | sue Date_| :| August 8, 2022 BUREAU OF RESEARCH AND STANDARDS Revision No. O1 Page No. 18 of 21, ‘SPECIFICATIONS FOR APPARATUS, EQUIPMENT & SUPPLIES (D.0. NO. 100, SERIES OF 2018) IV, MISCELLANEOUS MATERIALS Construction Lime (Hydrated) 6. ASTM C110 - Standard Test Methods for Physical Testing of Quicklime, Hydrated Lime, and Limestone - Plastic Property Testing - Section 7 - Water Retention of Hydrated Lime Weighing Device or | capacity > 1000 g but less than 5000 g for high quality balances or 2000 Laboratory Balance |g for regular balances; readability < 0.1 g; maintenance tolerance < 0.325 g; reproducibility < 0.325 g; sensitivity < 0.65 g (maintenance tolerance, reproducibility and sensitivity are calculated using a 650 g ‘cement for cement paste preparation as test load); 220/240/220-240 V ‘or with 220/240/220-240 V AVR/UPS if electronic Weights Former NBS Class P and F reference masses, OIML Class M1 reference ‘masses or better Glass Graduated | Ciass A borosilicate glass; 200 or 250-mL + 2.0 mL capacity; subdivided cylinder to at least 5 mL graduation lines but be omitted for the lowest 25 mL. for a 250-mL graduate; main graduation lines shall extend at least three quarters of the way around the graduate and shall be numbered Tamper conforms to ASTM C109 of has the following specifications: nonabsorptive, nonabrasive, nonbrittle material such as a rubber ‘compound having a Shore A durometer hardness of 80 + 10 or seasoned ‘ak wood rendered nonabsorptive by immersion for 15 min in paraffin at ~392 °F or [200 °C]; cross section of about Y» by 1 in. or [13 by 25 mm] and a convenient length of about 5 to 6 in. or [120 to 150 mm]; tamping face shall be fiat and at right angles to the length of the tamper \Straightedge conforms to ASTM C185 or has the following specifications: steel straightedge; > 200 mm long; 1.5 mm < thickness < 3.5 Flow Table, Flow | conforms to ASTM C 230 (Please refer directly to ASTM C 230 when Mold, and Caliper —_| checking due to the complexity of required specifications). 220/240/220- 240 V or with 220/240/220-240 V AVR/UPS if electronic Light oil SAE-10Department of Public Works and Highways | Issue Date _| :| August 8, 2022 BUREAU OF RESEARCH AND STANDARDS Revision No. | : OL Page No. |: 19 of 21 ‘SPECIFICATIONS FOR APPARATUS, EQUIPMENT & SUPPLIES (D.0. NO. 100, SERIES OF 2018) IV. MISCELLANEOUS MATERIALS Construction Lime (Hydrated) Mixer conforms to ASTM C 305 or has the following specifications: electrically driven mechanical mixer of the epicyclic type, which imparts both a planetary and a revolving motion to the mixer paddle; minimum of two controlled speeds (Rheostat adjustment of speed is not acceptable); first oF slow speed has a paddle revolution = 140 + 5 r/min & planetary motion of ~62 r/min; second speed has a paddle revolution = 285 + 10 r/min & planetary motion of ~125 r/min; electric motor at least 124 W (1/6 hp); equipped with either an adjustment screw which is an integral part of the mixer or a clearance adjustment bracket such as the one shown in ASTM C 305 Figure 1 and conforms to ASTM C305 Note 1 to provide clearance between the lower end of the paddle and the bottom of the bow! that is not greater than 2.5 mm but not less than 0.8 mm when the bow! is in the mixing position; 220/240/220-240 V or with 220/240/220-240 V AVR/UPS Paddle conforms to ASTM C 305 or has the following specifications: readily removable, made of stainless steel, and conforms to the basic design in ASTM C305 Figure 2. dimensions of the paddle shall be such that when in the mixing position the paddle outline conforms to the contour of the bowl used with the mixer, and the clearance between corresponding Points on the edge of the paddle and the side of the bow! in the position of closest approach shall be ~4.0 mm but not less than 0.8 mm. Mixing Bow! conforms to ASTM C 305 or has the following specifications: nominal capacity of 4.73 L, general shape and comply with the limiting dimensions in ASTM C305 Figure 3, made of stainless steel; shall be so equipped that it will be positively held in the mixing apparatus in a fixed position during the mixing procedure; provide an enclosure around the mixing bowl or a lid to minimize evaporation of water during periods of rest of the mixture; the enclosure or lid shall be made of non-absorbing material that is resistant to deterioration from the alkaline environment of cement pastes and mortarsBUREAU OF RESEARCH AND STANDARDS. Revision No. Department of Public Works and Highways | S5ue Date_| :| August 8, 2022 OL Page No. 20 of 21, ‘SPECIFICATIONS FOR APPARATUS, EQUIPMENT & SUPPLIES (D.0. NO. 100, SERIES OF 2018) IV. MISCELLANEOUS MATERIALS Construction Lime (Hydrated) Scraper semirigid rubber blade attached to a handle about 150 mm long. The blade shall be about 75 mm long, 50 mm wide, and tapered to a thin edge about 2 mm thick Filtration Assembly _| apparatus as shown in ASTM 1506 Figure 1. Consists of a perforated dish resting on a funnel, which is connected by a three-way stopcock to a vacuum flask, to which a controlled vacuum is applied. The perforated dish shall be made of metal not attacked by masonry mortar or plaster (Stainless steel, brass, and bronze are suitable metals for this purpose). The metal base of the dish shall have a thickness of 2.0 + 0.3 mm and shall conform to the requirements given in Fig. 1. The stopcock bore shall have a 4.0 0.5-mm diameter, and the connecting glass tubing shall have a minimum inside diameter of 4 mm. The length of the tubing projecting into the 1-L fiask from the stopcock shall extend at least 25 mm below the center line of the vacuum connection, The contact surfaces of the funnel and Perforated dish shall be plane and may need to be lapped to ensure intimate contact. An airtight seal shall be maintained between the funnel and the dish during the test. This shall be accomplished by either of the following procedures. (1) A synthetic (grease-resistant) rubber gasket may be permanently sealed to the top of the funnel using petrotatum or light Grease to ensure a seal between the gasket and dish. (2) The top of the funnel may be lightly coated with petroleum or light grease to ensure a seal between the funnel and dish. Care should be taken to ensure that one of the holes in the perforated dish become clogged. Hardened, smooth, not rapid filter paper shall be used. It shall be 150 mm in diameter and be placed so as to completely cover the perforations in the dish. Controlled — Vacuum | A vacuum gage capable of reading at least 9-kPa pressure in 0.1-kPa Source increments (Vacuum values are all given as pressure relative to atmospheric pressure, Gages reading pressure in other units are acceptable as long as their capacity and scale increments comply with the levels specified), connected to a miniature vacuum regulator having a maximum 55-kPa capacity, which is then connected to a vacuum pump or water aspirator as shown in ASTM C1506 Figure 1. Connection is made between the vacuum flask and the vacuum gage.Department of Public Works and Highways | Sue Date | :| August 8, 2022 BUREAU OF RESEARCH AND STANDARDS Revision No. | : o1 Page No. [:| _2iof2i ‘SPECIFICATIONS FOR APPARATUS, EQUIPMENT & SUPPLIES (D.0. NO. 100, SERIES OF 2018) IV. MISCELLANEOUS MATERIALS Construction Lime (Hydrated) Thermohygrometer | temperature accurate to within + 2.0°C or better at 15°C to 35°C, humidity accurate to within +1 % RH or better at 45 to 95 % RH 7. ASTM C110 - Standard Test Methods for Physical Testing of Quicklime, Hydrated Lime, and Limestone - Particle Size Analysis - Section 15 - Quicklime Residue and Wet Sieve Analysis of Limestone and Hydrated Lime Sieve 0.850 mm (No. 20) sieve conforming to ASTM E11. Preferably 100 mm (4-in.) depth Sieve 0.600 mm (No. 30) sieve conforming to ASTM E11. Preferably 100 mm (4 in.) depth Sieve 0.075 mm (No, 200) sieve conforming to ASTM E14, Preferably 100 mm (Ain) depth Pan and cover same diameter as the sieves Spray Nozzle Conforms to ASTM C 430 or has the following specifications: constructed of metal not subject to corrosion by water, and 17.5 mm (0.69 in.) in inside diameter with a central hole drilled in line with the longitudinal axis, an intermediate row of eight holes drilled 6 mm (0.23 in.) center-to-center at an angle of 5° from the longitudinal axis, and an outer row of eight holes drilled 11 mm (0.44 in.) center-to-center at an angle of 10° from the longitudinal axis; holes = 0.5 mm (0.02 in.) in diameter; flow rate is between 1500 and 3000 g/min at 69 + 3 kPa (10 + 0.4 psi) Pressure Gage Conforms to ASTM C 110 or has the following specifications: 75 mm (3- )) minimum diameter, graduated in 6.9 kPa (1-psi) increments and maximum capacity of 207 kPa (30-psi). The accuracy at 69 kPa (10 psi) shall be +1.7 kPa (0.25 psi). With connectors to attach the pressure gauge to the water faucet and a rubber tubing at the output side to connect to the spray nozzle Oven capable of maintaining a temperature of 110 + 5°C. 220/240/220-240 V or with 220/240/220-240 V AVR/UPS Canopy hood for Oven | No required specifications