Safety Data Sheet Acetone

Version 1.2
Effective Date 23/1/18

1. IDENTIFICATION OF THE CHEMICAL AND OF THE SUPPLIER

Material Name : Acetone
Other Names/Synonyms : Dimethyl Ketone
Page | 1 Propan-2-one
Recommended use/ : Industrial Solvent. Restricted to professional users
Restricted of use

Supplier : Challenger Avenue (M) Sdn Bhd

No. 8 Lot 778, Jalan Subang 4, Subang Light Industrial Park
47610 Subang Jaya,
Selangor Darul Ehsan, Malaysia.

Telephone : + (603) 5632 2128

Fax : + (603) 5632 9155

2. HAZARDS IDENTIFICATION
GHS Classification
: Flammable liquids, Category 2
Specific target organ toxicity- single exposure, -
Category 3
Narcotics effects , Inhalation
Serious eye damage/eye irritation, Category 2A
Aspiration hazard, category 2

GHS Label Elements

Symbol (s) :

Signal Words : Danger

GHS Hazard statements : PHYSICAL HAZARDS:

H225: Highly flammable liquid and vapor.
HEALTH HAZARDS
H305: May be harmful if swallowed and enters airways.
H319: Causes serious eye irritation.
H336: May cause drowsiness or dizziness.
ENVIRONMENTAL HAZARDS:
Not classified as an environmental hazard under GHS criteria
 Safety Data Sheet Acetone
Version 1.2
Effective Date 23/1/18

GHS Precautionary Statements

Prevention : P210: Keep away from heat/sparks/open flames/hot surface. –

Page | 2 No smoking.
P243: Take precautionary measures against static discharge.

Response : P305+P351+P338: IF IN EYES: Rinse cautiously with water for

several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing.
P301+P310: IF SWALLOWED: Immediately call doctor/physician.
P331: Do NOT induce vomiting.

Storage : P403+P233: Store in a well-ventilated place. Keep container

tightly closed.

Other Hazards which do : Exposure may enhance the toxicity of other materials. Repeated
not result in classification exposure may cause skin dryness or cracking.
Slightly irritating to respiratory system.

Aggravated Medical : Pre-existing medical conditions of the following organ(s) or

Condition organ system(s) may be aggravated by exposure to this
material: Eyes. Respiratory system. Skin.

3. COMPOSITION/INFORMATION ON INGREDENTS

Chemical Identity : Propan-2-one

Synonyms : Dimethyl Ketone
propan-2-one
CAS No. : 67-64-1

Classification of components according to GHS

Chemical Name Synonyms CAS Hazard Class Hazard Conc.

(category) statement
Acetone 67-64-1 Flam. Liq., 2; H225; H319; 99.75%
Eye Dam., 2A; H336; H305;
STOT SE, 3;
Asp. Tox., 2;
 Safety Data Sheet
4. FIRST-AID MEASURES
General Information
Page | 3 Inhalation
Skin Contact
Eye Contact
Indigestion
Notes to physician
Most important
Symptoms/effects, acute
& delayed
5. FIRE-FIGHTING MEASURES
Clear fire area of all non-emergency personnel.
Specific Hazards : Containers exposed to intense heat from fires should be cooled
Acetone
Version 1.2
Effective Date 23/1/18
: Not expected to be a health hazard when used under normal
conditions.
: Removing to fresh air. If rapid recovery does not occur,
transport to nearest medical facility for additional treatment.
: Remove contaminated clothing. Flush exposed area with water
and follow by washing with soap if available.
: Immediately flush eyes with large amounts of water for at least
15 minutes while holding eyelids open. Transport to the nearest
medical facility for additional treatment.
: If swallowed, do not induce vomiting: transport to nearest
medical facility for additional treatment. If vomiting occurs
spontaneously, keep head below hips to prevent aspiration. If
any of the following delay signs and symptoms appear within the
next 6 hours, transport to the nearest medical facility: fever
greater than 38, 3°C, shortness of breath, chest
congestion or continued coughing or wheezing. Give nothing by
mouth.
: Breathing of high vapor concentrations may cause central
nervous system (CNS) depression resulting in dizziness, light-
headedness, headache, nausea and loss of coordination.
Continued inhalation may result in unconsciousness and death.
Defatting dermatitis signs and symptoms may include a burning
sensation and/or a dried/cracked appearance. Eye irritation
signs and symptoms may include a burning sensation, redness,
swelling, and/or blurred vision. If material enters lungs, signs
and symptoms may include coughing, choking, wheezing,
difficulty in breathing, chest congestion, shortness of breath,
and/or fever. Respiratory irritation signs and symptoms may
include a temporary burning sensation of the nose and throat,
coughing, and/or difficulty breathing.
with large quantities of water. The vapor is heavier than air,
spreads along the ground and distant ignition is possible.
 Safety Data Sheet Acetone
Version 1.2
Effective Date 23/1/18

Extinguishing Media : Alcohol-resistant foam, water spray or fog. Dry chemical powder,
carbon dioxide, sand or earth may be used for small fires only.
Unsuitable Extinguishing : Do not use water in a jet.
Media
Page | 4 Protective Equipment for : Wear full protective clothing and self-contained breathing
firefighters apparatus. Proper protective protection equipment including
breathing apparatus must be worn when approaching a fire in a
confined space.

6. ACCIDENTAL RELEASE MEASURES

Observe all relevant local and international regulations. Avoid contact with spilled or released
material. For guidance on selection of personal protective equipment see Chapter 8 of this
Material Safety Data Sheet. See Chapter 13 for information on disposal.

Personal Precautions, : Isolate hazard area and deny entry to unnecessary or

Protective Equipment and unprotected personnel.
Emergency Procedures Stay upwind and keep out of low areas.

Environmental : Shut off leaks, if possible without personal risks. Remove

Precautions all possible sources of ignition in the surrounding area.
Use appropriate containment (of product and fire fighting
water) to avoid environmental contamination. Prevent
from spreading or entering drains, ditches or rivers by
using sand, earth, or other appropriate barriers. Attempt
to disperse the vapor or to direct its flow to a safe
location for example by using fog sprays. Take
precautionary measures against static discharge. Ensure
electrical continuity by bonding and grounding (earthing)
all equipment.
Ventilate contaminated area thoroughly.

Methods and Material for
Containment and Clean
Up
: For large liquid spills (> 1 drum), transfer by mechanical
means such as vacuum truck to a salvage tank for
recovery or safe disposal. Do not flush away residues with
water. Retain as contaminated waste. Allow residues to
evaporate or soak up with an appropriate absorbent
material and dispose of safely. Remove contaminated soil
and dispose of safely. For small liquid spills (< 1 drum),
transfer by mechanical means to a labelled, sealable
container for product recovery or safe disposal.
Allow residues to evaporate or soak up with an
appropriate absorbent material and dispose of safely.
Remove contaminated soil and dispose of safely.
 Safety Data Sheet Acetone
Version 1.2
Effective Date 23/1/18

7. HANDLING AND STORAGE

General Precautions : Avoid breathing vapors or contact with material. Only use
Page | 5 in well ventilated areas. Wash thoroughly after handling.

Precautions for Safe : Avoid inhaling vapor and/or mists. Avoid contact with
Handling skin, eyes, and clothing. Extinguish any naked flames. Do
not smoke. Remove ignition sources. Avoid sparks.
Electrostatic charges may be generated during pumping.
Electrostatic discharge may cause fire. Ensure electrical
continuity by bonding and grounding (earthing) all
equipment.

Conditions for Safe : Must be stored in a well- ventilated area, away from
Storage sunlight, ignition sources and other sources of heat. Keep
away from aerosols, flammables, oxidizing agents,
corrosives and from other flammable products which are
not harmful or toxic to man or to the environment.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Occupational Exposure Limits

Material Source Type ppm mg/m3 Notation

Acetone ACGIH TWA 500 ppm
ACGIH STEL 750 ppm
CN OEL TWA 300 mg/m3
CN OEL STEL 450 mg/m3

Material Source Hazard Designation

Acetone ACGIH Not classifiable as a human carcinogen.

Appropriate Engineering : The level of protection and types of controls necessary will
Controls vary depending upon potential exposure conditions. Select
controls based on a risk assessment of local circumstances.
Appropriate measures include: Provide adequate ventilation
in storage areas. Local exhaust ventilation is recommended
Eye washes and showers for emergency use.
 Safety Data Sheet Acetone
Version 1.2
Effective Date 23/1/18

Individual Protection : Personal protective equipment (PPE) should meet

Measures recommended national standards.
If engineering controls do not maintain airborne
Page | 6 concentrations to a level which is adequate to protect
worker health, select respiratory protection equipment
suitable for the specific conditions of use and meeting
relevant legislation. Check with PPE suppliers.

Hand Protection : Where hand contact with the product may occur
the use of gloves approved to relevant standards (e.g.
Europe: EN374, US: F739, AS/NZS: 2161) made from the
following materials may provide suitable chemical
protection: Nitrile rubber. PVC. Viton. Personal hygiene is a
key element of effective hand care

Eye Protection : Chemical splash goggles (chemical monogoggles).

Body protection : Use protective clothing which is chemical resistant to this

material. Safety shoes and boots should also be chemical
resistant.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : Clear Liquid

Odour : Characteristic
Initial Boiling point and : 56 °C
boiling range
Melting / freezing point : -94 °C
Flash point : -18 °C
Explosion / Flammability : ca. 2.1 – 13 %(V)
limits in air
Auto-ignition temperature : 540 °C (ASTM D-2155)
Vapour pressure : 24.7 kPa at 20 °C
Density : 790 – 792 kg/m3 at 20 °C (ASTM D-4052)
Water solubility : at 20 °C Completely miscible.
Decomposition temperature : Note: Stable under normal conditions of use.
Vapour density (air=1) : 2 at 20 °C
Electrical conductivity : 20 µS/m at 20 °C (ASTM D-4308)
Evaporation rate (nBuAc=1) : 5.6 (ASTM D 3539, nBuAc=1)
2 (DIN 53170, di-ethyl ether=1)
Surface tension : 22.8 mN/m at 20 °C
 Safety Data Sheet
10. STABILITY AND REACTIVITY
Chemical Stability
Page | 7 Conditions to Avoid
Incompatible Materials
Hazardous
Decomposition Products
Possibility of Hazardous
Reactions
Sensitivity to Static
Discharge
11. TOXICOLOGICAL INFORMATION
Information on Toxicological effects
Likely Routes of
Exposure
Acute Toxicity
Acute Oral Toxicity
Acute Dermal Toxicity
Acute Inhalation
Toxicity
Skin Corrosion / lrritation
Serious Eye
Damage/Irritation
Respiratory Irritation
Respiratory or skin
sensitization
Aspiration hazard
Acetone
Version 1.2
Effective Date 23/1/18
: Stable under normal conditions of use.
: Avoid heat, sparks, open flames and other ignition sources.
: Strong oxidizing agents.
: None expected under normal use conditions.
: Data not available.
: Data not available.
: Exposure may occur via inhalation, ingestion, skin absorption,
skin or eye contact, and accidental ingestion.
: Low toxicity: LD5O >5000 mg/kg, Rat
: Low toxicity: LD5O >5000 mg/kg Rabbit
: Low toxicity if inhaled.
High concentrations may cause central nervous system
depression resulting in headaches, dizziness and nausea;
continued inhalation may result in unconsciousness and/or
death.
: Not irritating to skin.
Prolonged/repeated contact may cause defatting of the skin
which can lead to dermatitis.
: Irritating to eyes.
: Slightly irritating to respiratory system.
: Not a skin sensitizer.
: Aspiration into the lungs when swallowed or vomited may
cause chemical pneumonitis which can be fatal.
 Safety Data Sheet Acetone
Version 1.2
Effective Date 23/1/18

Germ Cell Mutagenicity : Not mutagenic.

Carcinogenicity : Not expected to be carcinogenic.

Page | 8 Reproductive and : Not expected to impair fertility. Not a developmental

Developmental Toxicity toxicant.

Specific target organ : May cause drowsiness or dizziness.

toxicity - single exposure

Specific target organ : Not expected to be a hazard.

toxicity - repeated
exposure

12. ECOLOGICAL INFORMATION

Acute Toxicity
Fish : Practically nontoxic: LC/EC/1C50 > 100 mg/I
Aquatic Invertebrates : Practically nontoxic: LC/EC/1C50> 100 mg/I
Algae : Practically nontoxic: LC/EC/1C50 > 100 mg/I
Microorganisms : Practically nontoxic: LC/EC/1C50 > 100 mg/I
Chronic Toxicity
Fish : Data not available.
Aquatic Invertebrates : NOEC/NOEL> 10 <=100 mg/I (based on test data)
Mobility : If product enters soil, it will be mobile and may contaminate
groundwater. Dissolves in water.
Persistence/degradability : Readily biodegradable.
Bio accumulative : Not expected to bio accumulate significantly.
Potential

Other Adverse Effects : None known.

13. DISPOSAL CONSIDERATIONS

Material Disposal : Recover or recycle if possible. It is the responsibility of the

waste generator to determine the toxicity and physical
properties of the material generated to determine the
proper waste classification and disposal methods in
compliance with applicable regulations. Do not dispose into
the environment, in drains or in water courses. Waste
product should not be allowed to contaminate soil or water.
 Safety Data Sheet Acetone
Version 1.2
Effective Date 23/1/18

Container Disposal : Drain container thoroughly. After draining, vent in a safe

place away from sparks and fire. Residues may cause an
explosion hazard. Do not puncture, cut or weld uncleansed
Page | 9 drums. Send to drum recoverer or metal reclaimer.
Local Legislation : Local regulations may be more stringent than regional or
national requirements and must be complied with.

14. TRANSPORT INFORMATION

Land (as per ADR classification): Regulated
Class :3
Packing group : II
UN No. : 1090
Danger label (primary risk) :3
Proper shipping name : ACETONE
Environmentally Hazardous : No

IMDG
Identification number UN 1090
Proper shipping name ACETONE
Class I Division 3
Packing group II
Marine pollutant: No

AIR-IATA (Country variations may apply)

UN No. : 1090
Proper shipping name : Acetone
Class / Division :3
Packing group : II

15. REGULATORY INFORMATION

The regulatory information is not intended to be comprehensive. Other regulations may apply
to this material.

Following rules, regulations and standards are providing regulatory information on safe use,
storage, transportation, loading, and unloading, classification and labelling of chemicals. The
latest version of the regulations/ standards are used for SDS
 Safety Data Sheet Acetone
Version 1.2
Effective Date 23/1/18

16. OTHER INFORMATION

GHS Hazard statements

Page | 10
H225 Highly flammable liquid and vapor.
H305 May be harmful if swallowed and enters airways.
H319 Causes serious eye irritation.
H336 May cause drowsiness or dizziness.

SDS Version Number : 1.2 – updated from version 1.1 dated 3/1/18
SDS Effective Date : 23/1/2018
SDS Expiry Date : 22/1/2023
SDS Distribution : The information in this document should be made available to
all who may handle the product

Disclaimer: All information presented herein is given in good faith and is based on sources and
test considered to be reliable but cannot be guaranteed. It is the user’s full responsibility to
accept risk for the safety, toxicity, handling, storage, and use of the product as well as to
determine the suitability of the product for a specific purpose. We give no warranty as to the
results to be obtained in using the product, therefore all risk must be assumed by the user.