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    JPCRD 502

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    Heat Capacities and Entropies of Organic Compounds in the Condensed Chemical Kinetics and Thermodynamics Division, National Institute of Standards and Technology, Gaithersburg, Maryland 20899 Phase. Volume Ill Eugene S. Domalski and Elizabeth D. Hearing” Received December 15,1994; revised mans received Apa 18, 1995 ‘This compilation of data on the heat capacities and entropies of organic compounds in the condensed phase is a cumulative document and includes tho following earlier published work on this subject: "Heat Capacities and Entropies of Organic Compounds in the Condensed Phase,” E. S. Domalski, W. H. Evans, and E. D. Hearing, J. Phys. Chem. Ref, Data 13, Suppl. | (1984) and “Heat Capacities and Entropies of Organic Compounds the Condensed Phase, Volume If,” E.S. Domalski and E.D. Hearing, J. Phys. Chem, Ref, Data 19, 881~1047 (1990). In addition, the literature through 1993 has been searched ‘and the pertinent data reported has been included in Volume Ill. The latter volume provides data on 5332 individual entries for 2508 discrete organic compounds for which over 2200 articles have been examined, evaluated, and referenced. In addition to values for the heat capacity and entropy at 298.15 K, phase transitions for solidsolid, solid’ liquid, aid i soe instances, svidlgas aud Tiquidges ate tabulate as encountered he articles examined and evaluated. © 1996 American Institute of Physics and American Chemical Society Key words: condeased pase entopy: evshuted data; beat capscty; organic compounds; phase tanstions wLN. Content 1. Introduction, 2. Scope of the Search, 3. Arrangement of the Data. 4. Definitions 5. Acknowledgements cee 6. References for the Introductory Discussion... 7. Table of Heat Capacities. Entropies. and Phase Transition Properties 6 8. Compound Name-Formula~CASRN Index. .....444 Bibliography 473 1. Introduction This compilation provides heat capacity and entropy data ‘on $332 individual entries for 2503 discrete organic com- ‘pounds in the liquid and solid phases. Data on tho enthalpies and entropies of phase transitions which have been deter ‘mined from calorimetric measurements are also included. (Over 2200 articles have been examined, evalusted, aud tel cerenced, This compilation is a cumulative collection of two earlier ocuments publishes! in 1OR4 and 1990 entitled Present ass 27 Repina Driv, Claksbrg, MD 20871 101996 by he US Secery of Commerce op bello the United States All pha reserve This copyright assigned othe America nse of Pryses and the Amencan Chemical Soci Repens aval fom ACS: see Reprints Lis tsk of ise (00¢7-2689/0625(1)1825/874.00 “Heat Capacities and Entropies of Organic Compounds in the Condensed Phase,” by E. S. Domalski, W. H. Evans, Ref. Dats 13, Suppl. 1 “Heat Capacities and Entropies of Organic Compounds in ‘he Condensed Phase, Volume Il,” ES. Domlski and E.D. Hearing, J. Phys Chem. Ref. Data 19, 881-1047 (1990) and also a collection of the pertinent data from the literature {rough the end of 1993, Over the period from 1984 through 1993, several large compilations have been published which contain data on the thermodynamic properticn of organs eumpuuinls i dhe Str ddensed phase; they are: “Thermodynamic Properties of Oxygen-Containing Or- ‘genie Compounds,” by I. a, Vasily ail ¥, M. Petrov, Handbook, Leningrad, 240 pages (1984), “Thermodynamic Properties of Key Organic Oxygen Compound in the Carbon Range C, to C,. Part 1. Prop erties of Condensed Phases,” by R. C. Wilhoit, 3, Chao, and K. R. Hall, J. Phys. Chem. Ref. Data 14, 1-175 (1985), “Thermodynamic and Thermophysical Properties of Or- ‘ganic Nitrogen Compounds. Part 1. Methanamine, Etha- hamine, I~ and 2-Propanamine, Benzenamine, 2-3, and 4-Methylbenzenamine” by J. Chao, N.A.M. Gada, BLE. Gammon, K.N. Marsh, AS. Rodgers, G.R. Somayajulu, and R.C. Wilhoit, J. Phys. Chem. Ref. Data 19, 1547~ 1615 (1990), “Thermodynamic and Thermophysical Properties of Or ‘ganic Nitrogen Compounds. Part Il. 1- and 2-Butanamine, 4. Phys, Chom. Ret, Data, Vol. 25, No.1, 1996 2 E. S. DOMALSKI AND E. D. HEARING 2-Methyl-I-propanamine, 2-Methyl-2-propanamine, Pyr- role, 1-, 2, 3Methylpymole, Pyridine, 2-, 3, and 4-Methylpyridine, Pyrrolicine, Piperidine, Indole, Quino. Tine, Isoquinoline, Acridine, Carbazole, Phenanthridine, I~ ‘and 2-Naphthalenamine, and 9-Methylearbazole” by A. as, M. Frenkel, N.A.M. Gadalla, S. Kudchadker, K.N. Marsh, AS. Rodgers, and R. C. Wilhoit, J. Phys. Chem. Ref, Data 22, 659-782 (1993). ‘The later compilations were useful in assisting us with the completeness of our search of the literature for papers on hheat capacities, entropies, and phase transition properties of various organic compounds. The discussions on specific compounds were especially helpful in the assignment ot a rating to our evaluation of those data 2. Scope of the Search ur coverage ofthe chemical literature extends from 1881 through 1003, References containing data on the heat capaci ties and entropies of organic compounds in the condensed pphase were obtained primarily through searching Chemical Abstracts. Additional references were located through searching the files of the Chemical Thermodynamics. Data Center of the National Institute of Standards and Technology and the Bulletin of Chemical Thermodynamics. The original papers were examined fo obtain the data which as been tabulated, to determine whether corrections should be ap- plied, and to qualitatively evaluate the reported measure- “The goal of the search has been to obtain heat capacity and entropy data for organic compounds at “room temperature however. the temperature range included is 200-450 K. This extended range was chosen so that the user would have, whenever possible, values for temperatures close to room temperature even if the measurement range did not include 298.15 K. Usually, the user can extrapolate such data 10 298.15 K or to temperatures outside of the reported range if desired, Values of the enthalpy and entropy of phase ‘ransitions—souia/soll, sollaiquld, as well as some sold ‘208, and liquid/gas transitions—obtained from calorimetric ‘measurements are included along with the data on heat ca- pacity and entropy. Mo epecifie cearoh wae made for the tran sition properties. They are included as a by-product of the search for experimental heat capacity data Corrections for relative atomic mass (atomic weiaht) and. energy units have been made, where appropriate. Values hhave been reported at “298 K" with the ice point taken as 273.1, 273.15, oF 273.16 K; the correction for this small change is much less than the precision and accuracy of the data, Some researchers did not provide tabulated values of and S as a function of temperature, but gave an equation, sults: Cp — A+ BT + CT”, In hese cases, a value for C, andlor Sat 298 K was derived from the equation provided, Some researchers have provided only graphs of C,, asa fune- tion of temperature. Far good quality graphs, estimates of C,, at 298 K were extracted and correspondingly identified. ‘Care was taken to assure that heat capacity data reported in 4. Phys. Chem, Ret, Data, Vol. 25, No. 1, 1996 Intemational Steam Table (IT) energy units were converte: to the International System of Units (SI Units). Except fo very precise data, corrections involving energy units for mos ‘measurements since about 1930 are often within the uncer tainty of the data. Older data are of lower precision so tha corrections are not needed, In general, transition tempera tures are those reported by the investigator. The effort t convert each investigator's temperature scale to the 1990 In ternational Temperature Scale was not warranted. 3. Arrangement of the Data ‘The table of heat capacities, entropies, and phase transi tions given in this compilation contains data entries for : variety of organic compounds. The entries here, as in the 1984 wid 1990 J. Flys. Chem, Ref. Daus publication!” a arranged in the order of the empirical formulae of the com pounds; isomers are further separated by their Wiswesse Tine Notation 3 The tater nntatinn eystem hae hoon sad represent the structure of the organic compound. Under : sgiven organic substance, the data from the pertinent paper: are included. The data from each paper form a separate entry ‘complete with identification of the reference source. Whet there are several reference entries for a compound, they an arranged chronologically by year. For each entry the dat: zgiven are: molecular (empirical) formula for the compound physical state, reference code, compound name(s), follower by the values for the heat capacity, entropy, and, where avail blo, phase transition data. The entry of information is com pleted by the molecular weight (in units of g-mol-') Wiswesser Line Notation for the compound, and an evalua tion of the presentation of the experimental results and th: quality of the data, The formula given is the empirical for ‘mula for the compound; water of hydration is shown as (n)H,O. The elements are arranged in the order C, H(D.T) followed by the other elements in alphabetical order of thei chemical symbols. One or more names are given for eacl ‘compound. No attempt has been made to conform to a rig brvusly systematic nomenctauure. Comm nancy ain! 995 tematic names are used; alternate names have been give! freely. All names used appear in the Compound Name Formula Indox in Section 8, which ehould acviet the reade ‘who is aware of the compound name but not its empirica formula. This index also contains the Chemical Abstract Service Resistry Number (CASRN) for cach compoun listed, Occasionally, a CASRN is not available due to rea sons such as: ambiguous nature of the name of the com pound as reported in the literature, partial devteration of ‘compound, or poorly defined complex formation. The bibl ‘ography is provided in Section 9. The reference code is ¢ the form XXAAA/BBBN, where XX are the last evo digit of the year of publication ofthe paper, AAA isthe first thee letters ofthe last name of the first author and BBB is the fir thee letters of the last name of the second author (if present Authors after the first wo are disregarded. N is a digit frot 2109 used to indicate a second, third, ..paper with the sam year and author codes. Thus, 60BRO/SMI2 refers to a paps HEAT CAPACITIES AND ENTROPIES OF ORGANIC COMPOUNDS: 3 by Brown and Smith appearing in 1960, the second one with authors BRO... and SML..; 44J0N is a 194 paper by Jones. ‘The full citation appears in the bibliography arranged ac~ cording to the reference codes. For papers published before 1900, al four digits forthe year are used, When audios have given @ table of simuuibed values for the heat capacity, the value at 298 K (interpolated if neces- sary) of the value nearest to that temperature is given. If experimental mescuramante ara reprecanted only hy a smoothing equation, this is used to calculate the value given. only the unsmoothed experimental results are given by the authors, ane of these is given, with the corresponding tem- perature. Such a selection is gecompanied by a remark, ‘The third-Iaw entropy is given at 298 K or at the tempera ture closest to this temperature. The value is that obtained by the authors; we have not reinegrated the heat capacity data to re-evaluate the entropy Phases are indicated by g, liq, c, ef, cil, ete. In genera, hn attempt has been made to sposify the erytalline Form of the solid phases; cis used for the form stable atthe melting point. For each phase transition, the appropriate process. ie. cig. the temperaure in kelvins. the enthaloy and entropy ‘change for the isothermal process, and when appropriate the pressure, are given. The entropy change AS is taken as AHIT unless indicated otherwise. Energy values are given in joules and can be related to the thermochemical calorie by the conversion factor: 4.1840 joules equals one thermo- chemical calorie, Pressures are given in Kilopascals, one standard atmosphere is 101.325 kP'. ‘The molecular weight is based upon che 1991 IUPAC ‘Table of International Atomic Weights." Three exceptions are made: the atomic weights af hydrogen, nitrogen. and fluorine fare taken as 1.0079, 14,0067, and 18,9984 rather than 1.00794, 14,00674, and 18:9984032, respectively. When the molecular weight differs from that originally used by the ‘authors, appropriate corrections 10 the valties have been made, ‘An indication of our general evaluation of the data re- ported is given as A (high quality), B (good), C (average). and D (low quality). This rating is based upon the method used, the details of the measurements as reported, the num- ber of measurements, purity of the sample, eaibeations, and corrections applied to the data; itis intended as a guide to those data we feel are more reliable. In addition, the number of sinificant figures siven forthe numerical values indicates roughly the quality of the data. In general, papers that are rated as being of high quality provide a detailed description fof the cryostat used, the experimental procedure. the purty and characterization of the sample. calibration results. both ‘aw and smoothed data forthe temperature range over which ‘measurements were made. and comment on the precision and auvunicy of Met data. An absence of numerical or deserip- tive information, or poor agreement with a detailed and ac- curate study can lead toa Jow rating, All of the names used 10 identify the compounds are ine cluded in the Compound Name—Formuta Index with the ap- propriate empirical formulie. Prefixes such as ser. arto but not fs0) are disregarded in the alphabetization of the names. ‘The sequencing of the compounds is based on the empiti- cal formula, The formulae are sorted alphabetically by the first atomic symbol, then by the number of atoms of this element present (Ine Hill tnoexing system’). As was the practice with the 1984 J. Phys. and Chem, Ref, Data publication,’ C, carbon, is always the fist element. This a- rangod list of formulae ic then sorted by the cecond atomic symbol (H, hydrogen, if present), and then by the number of atoms of this element. The sorting proceeds alphabetically thereafer for each element present. The following list illus- trates this scheme: CHO Isomeric compounds are further sorted by their Wiswesser Lin Notation. CHO 202 CHOC Hy 301 CsH,OCH, QIYI&1 (CH)),CHCH,OH QX1&1&1— (CH,),COH QY2&1 CH CHICH,)OH 4, Definitions Heat Capacity. The heat capacity is defined as the deriva- tive of the energy of the system with respect 10 the tempera- lure under specinea conaitions. ine neat capacity may be stated as an average value over a temperature range or the limiting value over an infinitesimal temperature change. If the system is maintained at constant volume. the hest cane ity, C.. is given by the derivative of energy with respect to temperature, €.= (00107 where U is the internal energy 4. Phys. Chem. Ret. Data, Vol 25, No.1, 1906 4 E. S. DOMALSKI AND E. D. HEARING IF the system is maintained at constant pressure, the heat capacity, C yi given by C=(aHtoT),. where H is the enthalpy. “The values of heat capacity reported in this paper ae those at constant pressure and correspond to one mole ofa speci fied substance; the units are thus, J-mol”!-K~', Experimentally, the heat capacity, C,, 8 obtained from un ely hinge at canst pasa ovet a stl er perature change, This vale is associated with the tempera ture atthe midpoint ofthe temperature range: GRAM AT) a +12 Actual heat capacity measurements, or Coys fOr Higuids and solid are nonmally made withthe sample in equilibrium with its own vapor pressure or saturation pressure the cor rection from Cy. to Cy atthe standard pressure, 101.325 KPa (1 atm) is usually negligible fr solids and for liquids below their pouting point. For volale organic compounds in the condensed phase, a correction forthe enthalpy of vaporiza- tion of the condensed phase as well as the heat capacity of the vapor phase must be appiod For nonvolatile solid organi compounds, the relationship between C, and Cyg is given by: Cp Cax {TOP I0T ell A¥/0T) pl Where (JP/2T) gis the slope of the vapor pressure or satu- ration pressure curve and (@V/@7), is the volume expansiv- ity of the solid. Again, the magnitude of this correction is usually negligible, Entropy. For totally reversible processes, the entropy lunge of « systent is equal (© the amount Of beat, Q ab- sorbed by the system divided by the temperature, T. For an infinitesimal change in entropy: 48~ agit. Entropy and heat capacity are related by the following, expressions: (osrer yy Cy/T, at constant votume, (S147) p=C,/T. a constant pressure, casaniec, Tat equilib vapae presen along the «wo phase Fine The (calorimetric) entropy is obtained by integration of tne measured values OFC, 7 hon Ue lowest ennperaane OF measurement to the reported temperature. Various methods have been used to extrapolate from the lowest experimental temperature to zer0 kelvin, Appropriate values of the ento- pies of phase changes must be added. The entropy at zero kelvin is taken a 2ro forthe stable erystaline state, with the addition of residual (2eo point) entropy, not removed by the extrapolation, due to non-random ordering, optical isomer- ism, oF multiple electonic ground states forthe molecule. Thus, C,T)T (extrapolation) ‘J. Phys. Chem. Ref. Data, Vol. 25, No. 1, 1996 + [Peymersame nae amp) Renee + fceune For additional diseussions on the concept of eutopy, reader should consult Refs, 6 and 7. Phase Transitions. A process by which a substance unde goes @ change of physical state, i, solid-solid, solid Tiquid, solid—gas, or liquidgas, is known as a phase trans tion oF phase change. The phase change is accompanied by transfer of enerey (commonly referred to as latent heat) ar a change in volume while both temperature and pressure n ‘main constant. For a phase change which is carried out n versibly (i.e. under equilibrium conditions) at a consta emperature and pressure the total Gibbs energy remains ut changed. If there is an enthalpy (or heat) change, then follows that there will also be an entropy change for tt process, because: AH-asT- “These equations are applicable only for the temperatu: and pressure at which the phases are in equilibrium. Fe phase changes solid-solid, sofid-liquid, solid—pas, liquid {gae encountered in the accompanying table: in Saction AM refers to the isothermal enthalpy change atthe transitic temperature. Corrections can be applied to the experiment data for premelting effects to isothermal conditions. Tr pressure, unless specified, is the vapor pressure of the sul stance at the transition temperature; the correction to a sta dard state pressute is usually negligible at ordinary pressur for a solid-solid transition and for fusion, The entror change is taken as AH/T at the equilibrium pressure. Some investigators have reported the measurement + valous pase clhsigcs ft whit te vulue atl EHO are continuous, but the heat capacity is discontinuous. Du ing such phase changes no latent heat is present and tt hapa of the curve of the haat capacity plated aca funotic of temperature often resembles the Greek letter lambda a t transition point, Such a transition is called a “lambda trans tion.” In order to differentiate these anomalous transitior from ordinary phase changes, it has become customary identify normal phase changes as phase changes of the fit order and atypical phase changes as those of the second ¢ der, Ihe discontinusty which occurs in a first order pha transition is a commonly observed phenomenon: howe the discontinuity associated with a second order phase tra sition has been more difficult to identify and/or interpe Sometimes the discontinuous nature of the heat capacity {questioned in a second order transition because experimen! ‘measurements show a peak or a hump at the transition tet perature rather than an unambiguous discontinuity. A pha change which is accompanied by changes in the entropy a HEAT CAPACITIES AND ENTROPIES OF ORGANIC COMPOUNDS 5 ‘volume and whose first-order derivatives ofthe Gibbs energy with respect to temperature and pressure change discontinu- ‘ously is known as phase change ofthe fst omer, S=-(4GI3T)p and V=(9GI0P)y A phase change which is accompanied by changes inthe heat capacity, volume expansviy, and isothermal compress ibility and whose second order derivatives ofthe Gibbs en- ergy with respect to temperature and pressure change discon- Timiously is Hawn asx phase change ofthe second order. C,IT=(a81aT) p= —(POIT?) p, KV=~(aV/0P) p= —(PGLAP?) 7, BV=(GVIAT)p=(#GIATAP)r p, where « isthe isothermal compressibiliy and fis the vol tome expansivity. The relationship between these quantities fin the pressure and temperature is given below by hren- fest's Equation." aPLAT=[C,L)~ CLDVETH(BN)~ Bi) I. APIdT=[BUf)— BUN BLK) — KA) where i and f represent the inital and final sates of the phase change For additional discussion regarding first and second order phase transitions, the reader should consult Refs. 9, 10, and 1, 5. Acknowledgments ‘The authors thank Nancy W. Young for her assistance in the search, retrieval, and collection of articles containing in- formation pertinent to this compilation. 6. References for the Introductory Discussion "HS. Domai, Wan, an ED, Heating J Phy. Cher Ref, Dats 13, Suool No.1, 286 panes (1984, , S- Domulsi std ED. Hearing, J. Phys. Chem. Re. Daa 19, 881~ 1087 0990, E.G. Smith and PA. Baker, “The Wis Ine. Chey Hil NJ, 193) “Atomic Weights of the Elements 1991, J. Phys Chem. Ref; Dats 22, S11 1884 (195. 1, D. Fas, Entropy (Metra Book Co, Ine, New Yor, 1962) PW. Ais, The Second Law (Selene American Libay, W. H. Fee aan and Co. New York, 1984) ML. W.Zemunsky, Heat sn Thermodynamics, dh Eton (McGraw Hil Book Co Inc, New York, 1957) "°C. Kite. Themul Physics Jon Wiley ané Sons, Inc. New York. 1960, NC 5, Adkins, Equi Thermodypames (Cami University Pres New Yor, 1983. Line Forma Chemical J. Phys. Chem. Ret, Data, Vol. 25, No. 1, 1996 6 E. S. DOMALSKI AND E. D. HEARING 7. Table of Heat Capacities, Entropies, and Phase Transition Properties c @ Graphite: Carbon, graphite Heat Capacity 2985 K 8498 Fat Entropy 2981 K, $2569 Exapoatin below 90 K, 0.761 Jmol K™ Molecular Weight 120110, Wiswesser Line Notation C Evaleation ACC, BIS) “Acheson No, 38 graphite SUACRAR ca S6ROBIFOX, Diamond; Carbon, dlamand Heat Capacity 295K, 6.6081 Fat" “Temperature range 9010 320 K. Type 1, horogeneos {6,930 Jmol "-K"* for Type 2, mosaic srctre olGeular Weight 121110 Wiswesser Line Notation C Evaluation c c@ seer Diamond: Carbon, dlamand Heat Capacity 78786 K 6y=8680 Fmt“ “Temperaureeange 7010 288 K. Valu is unsmecdied experimental, dum Entropy 2981SK, $=2448 mol"h KE Molecular Weight 120110, Wiswesser Line Notation © Evaluation ‘AIC,).BS) ce SDE Diamond: Caton, diamond Heat Capacity 298 I6K.—C,=6.1149 Jmol" “Temperature range 2510 300 K Entropy 28.16 K $=23782 Emo Matoelar Weight 190110 Wiewessr Line Notation © valuation B tel SRDESTYL raphe, Acheson Carbon, graphite eat Capacity 29815 K 28327 bot Tempers range 15 30K, Entropy BBISK. 25.70 emt! Molecular Weight 120310 Wisoresser Line Notation © Evaluation A Graphite: Carbon, sripite Heat Capacity 298.15 K. Gye T8 Fal “Temperate range 17 10 300 K Molecular Weight 120110 ‘Wiawesser Line Netation C Evaluation ‘ 4. Phys. Chem, Ref, Data, Vol. 25. No. 1, 1996 c © sresTY Graphite, Acheson, imines: Carbon, adit graphite Heat Capacity 29815 K, C2893 Bt" K"! Tenpeature range 13 0300 K Entropy BRISK, 283 Jmol“ ‘Molecular Weight 120110 ‘Wiwesser Line Notation © ‘Stored energy of abot 1987 J co savESIMO Diamond Carbo, diamond Heat Capacity 27768.K—C,=8.3078 mol K™* ‘Temperature range 13 to 277K, Value Is onsmootod experiment stim, Entropy 10000 K.—$=00720 Fml“-K"! ‘Aprsment with DeSoto (1953) data above 100 K. Molecule Weight 120110 ‘Wswesser Line Notation © valuation a co evn Diatood: Caen, diamond Heat Capacity 298.15 KC, =6.117 mel “Molecular Weight 120110, ‘Wiawesser Line Notation C Evaluation a ce ‘scr rept; Carbo, graphite Heat Capacity 300 K 2888 Lomo! “Temperate range 2981 1723 K Molectar Weight 120110 Wieser Line Notation C Evaluation a Special Spetosopic Electrode Grade SPR. ca ToLuTvO Crepe: Carbo, srapice Heat Capacity "29815 , 6.8979 bot Temperate range 9) 1.320, Entropy 29818 K, $5990 Sonat! T extrpslaio below 50 K Moveeaae Weight 20110, ‘Wiswesser Line Notation © Evaluation 8 Prepared by secre technique rom peoeum coke ad ou a pit eae tested at 3000°C co route eat Capacity 298.15 K Cye8473 mat ‘Temperature range 52 0 315K Eatrops D815. 28.644 emo! Molecular Weight (20110 Woswesser Line Notation C Evaluation 8 . cul tar pch by het este under peste a 2400° Density 2ig-em obeained by same proces with udtion of mea atays shew eae t 3000 HEAT CAPACITIES AND ENTROPIES OF ORGANIC COMPOUNDS. 7 ce TOLUTIVOL Graphic, pyrolytic: Carton, pyayi graphite Heat Capacity 2981SK.C,=8084 mal “empera range S100 310 K, Entropy DBISK, S531 bm! 1 exaplatin below 90K. Moleular Weight 12.0110 Evaluation 5 Prepared by deposition trom methane on hot graphite surface (2100°C), Heat weated at 3000°C ce Capit, natal Tague; Cat, atl prin eat Capacty) 29813 Ko Cy=8056 Fmt AC! Temperature ange $110 311K. Europy 29818 K. Moleuiar Weight 120110 Wisweser Line Notation C Evaluation B ToLUTVOL SoS491 bm! ce ‘Cubon, baked: Baked carton Heat Capacity 29815 K. ‘Temperature range 52 10 2K. Entropy DAIS K, explain below 80K Molecular Weight 120110 Winwenter Line Notation © TOLUTIVOL Gye9281 bol $6201 Jet")! Evaluation 8 © amo) TOTAKAWES: Heat Capacity 29815K C8598 Smo" Temperate ange $350 K Entropy DRISK, $5839 mth" luc aay 3~ 3p nee may 9 a es ETO Molecular Weight 120110 ‘Wiswesser Line Notation © alton as c @ TISHEMBEL, Graphite: Carbon. epi Heat Capacity 298K Cye812 bar Temperature range 273 to 3650 K, Cy calevlned fom saan plicable othe temperature range 2736 1000 K Wisweser Line Notation © Evaluation 8 co TRBUTIMAD Grape: Caton, graphite Heat Capacity 300K 286186 Jol” K™ Temperature ange 200103500 K, Leas surest of es Gta gives ¢,=0538657+9,11139310"*T—902728 T'~<34493 7 +i ss30p% 10" 7 —1.43688 107 cl °K 250 300 Ky Moleular Welght 12.0110 Wisreser Line Notation C Esaloation| a Rests fom an evaluation of ieratre dt ce J MARIVOL Graphite: Caron, gopie,single CHO, ta) isto Metanci ai; Formic aid Heat Capacity 298.15 K, C= 9904 me! ‘Temperature range 15 6 300K, Entroor BRISK. 1384 Sot neues 289 Jeg” K-! fr eo-pineatpy Phase Changes fig 28140 K, | AH=12678 Jmol! “Molecular Weight 46.0256, ‘Wiswesser Line Notation VQ Evaluation ” CHS, tia) ‘scat Dita carbo slide Thiocarboni aid eat Capacity 273 K Cy 1865 mo A ‘Temperature range ~95 19 20°C. Entropy 298K, S=218 bot"! utpolaton below ~95°C. Eximatod uncertainty = 25 J+m0 C Phase Changes tig 263K AH=8410 mot"! BSBA mala! Molecular Weight 110.2068 Wiswesser Line Notation SUYSHSH Evaluation B(C,).D18) CH,DO (i) 9st ‘Methanol: Methyl alcoho newt capaci 270 8, ey 78.90 3 Temperature range 99 to 270 K. Phase Changes elle VoL K, AH=6519 Jmol" ig in K, SH=308 J mol AS21751 bana A"! ‘Molecular Welght 33.0500 Winwesser Line Netatlon QU 81H Eval 8 CHDO (ha) ones Metanol-d; Methyl sleobo Heat Capacity 298.15 K S30. Molecular Weight 330500 Wiswesser Line Notation QU 1H-2 Evaluation 8 HEAT CAPACITIES AND ENTROPIES OF ORGANIC COMPOUNDS 19 cHBe (he) S8EGAIKEM Bromonsthane: Methyl bromide Heat Capacity 280 &, 1883 Jeol Temperature age 18 19 280 K Entropy BGT K,— SaiS514 mot Phase Changes cule AT78K,—aN=#73 Fmt! 880272 mol“! ig tak, aH =S979 bool 50333 mot ive 2761 k W=23912 Inet” 3528642 mot! P=101325 KPA Molecular Weight 94 9387 Evaluation * crue ig) anu ‘remorse: Methyl bromide Heat Capacity 283K, 146 Fmt “Temperature ange ~67 09°C. Mean C,, duce enperaues ‘Molecular Weight 93:387 ‘Wiswesser Line Notation 1 Evaluation D CHC! Gig) CChoronshane; Methyl erie ‘Temper range ~30 0 40°C. Molecular Weight 50.4877 ‘Wiwesser Line Notation Gl 24sH0 Eval C CHC tg) soawasoRr (Chormeane; Mey eho Heat Capacity 29315 K, C808 bmot"!.K"? Tempest ange 243 303 KC, repo a 20°C 1.595 Fg! Kohand e300 1.632 Fg RK Moleular Weight 503877 ‘Whewesser Line Notation Gi Evaleation 2 CH tis) Chlormcthane: Mtl choise Tempera rane 121 28967 K, Vas unsmoated experiment asim ANESAST Enuropy MBSHK—S=14008 Jamal Lt ig HIS48K A =6491 bot 8523666 Jal"! vi 24498 k, Aln=2isis Foi Pot01328 KPa, Molecular Weight $0877 Wiswessr Line Notation GI ‘Coes in OMESIAST?, CHLCFOP Gig) 6oFURRET Methlphophony hlorouorige Meat Capacity 298.15 K, Tenperaee ge 15 10 335 K S817 bat Entropy B8BISK——$=21640 Jmol"! Phase Changes fig 28070 K 1853 Fm 28 baal -K ‘Molecular Weight 116.593, \Wisweser Line Notation OPP! Evalation * cHaL0P (6 seFURRE! Mau lpspny etre Heat Capacity 29818K—Cy=151 2 mal. “Temper rage 1510 335K. Entropy B88ISK 216486 Joma? ase Changes tig 618K, A H=18076 Fm 8528906 mak"! ‘Molecular Weight 1529139 ‘Winwesser Line Notation OPC valuation a CHAS!) TIsaMKos2 “Tichororetysiane Meat Capacity 29819 Kya 68. JU"! 17 December, 1070. Cy(lg)=255285 * 0041327 + 1009307"? (19737 6 300K) cama Entcopy DEISK, $2628 mot"! have Changes ig 19737 K,——Ae8845 Fo! AS54531 Fa Molecular Welght 1494792 Evatoaton| = Debye empertre 9884 K, CHOP (ig) 6FURREL ‘Metylghophony toi Heat Capacky 29818K 2145.16 mal “Temperate rage 15 10 335K, nteopy BRISK, $9208.86 pmol AC! Phase Changes tie 26K, ARNE Ema! AS25026 ma Molecular Weight 100.0047 |Winwesser Line Notation OPEF CHA tig) Heat Capacity 298K, Gyr M8 Samo “Temperate range ~86 1 35°C. Mean , five emperares. Molecular Weight 131.9392 Evaluation D sSKUR, 4. Phys. Chem, Ret. Dat, Vol. 25. No.1. 1995 20 E. S. DOMALSKI AND E. D. HEARING cH i) STHARIMOE Tedomahane; Methyl iodide Heat Capacity 300 K Gy98268 Fok LK “Temperature range 283 10309. ‘Molecular Weight 141.9592 Wisweser Line Notation 1 Eralation B cnt ta) 62L0WMOE Heat Capacty 2982 K, 28276 be" ‘Tenpeatre ange 293 to 308 K Molecular Weight 141.9392 Evaluation 8 ant og SSCARLAY Todometane: Mth iodide Heat Capacity 29815 K, 2.78 bol! (Ore tpi Molecular Weight 1519392 Wisweser Line Notation 1 Evaluation ‘« cH) ose, Todomethane: Methyl iodide Hest Capacity 208185, ‘One temperature. Molecular Weight 141.9392 ‘iswesser Line Notation 1 HNO tig) orwat, Fomamid, Methnamide Heat Capacity 292 K, 2105 bal ‘One temperature Molecular Weight 45. 0:08 ‘Wiswesser Line Notation 2VH Evaluation > HNO ig) 6ssomic00 Formamide; Mthnamide Heat Capaciy 298K, 10r6 Fol“ ase Changes tig 282k, AH=1980 J mot"! ‘3522804 mel sttectar Web 4.0408 ‘Wiswesser Line Notation ZH Evaluation 8 HNO ih GORASIGAN. Formamide; Methnomide Heat Capacity 295 K Temperate range 293 10 373K, Molecular Weight 450508 ‘Wiswesser Line Notation ZV Pralation c | Bhvs. Chem Rot Ontn, Vol. 25. No.1, 1996 CHNO Ci) Formamid; Methanamide Meat Capacity 29815K (re temperature ‘Molecular Weight 45.0408 ‘Wiswesser Line Notation 2H Evaluation a avis 108.11 mat“! CHO Gia) Heat Capacity 29815 K, C2107 bam". ‘Ope temperature. Molecular Weigh 4.0408, Winweotr Line Notation ZH Evaluation 8 renoNe CANO (i) Formamide: Methnamide eat Capacity 29815 K,——Cy=107.62 mol! ‘Ope temperate. ‘Molecular Weight 4.0408 ‘Wiawesser Line Notation V1 Evaluation A 76skors HSNO ig) Formamide; Methane Heat Capacty 20618 K, ‘One temperature Molecular Weight 5.0408 Wiswesser Line Notation ZH. r7voR! CHNO (ig Formamig: Methnamide Heat Capacty— 2981SK,—, ‘One temperate Moteclar Weight 45.0808 ‘Wirwesser Line Notation 2VH Evaluation @ TAEWE 21079 met"! CHNO (igh saDEWE Formamide; Methnamide Heat Capacity 298ISK, Gy rmat"K" 275 16 300K) Phase Changes tg 77500, AH=8661 Io 1036 Smat"-K* Molecular Weight 5.0208 Wiswesser Line Notation ZH Evaluation a CHANG; ig) ow Niromethane Heat Capacity 280, 105 pmol! (One temperature. Motecotar Weight 61.0802 ‘Wiawesser Line Notation WN Evaluation D HEAT CAPACITIES AND ENTROPIES OF ORGANIC COMPOUNDS 2 CHAO, aw ‘Naromethane Heat Capacty 298 K. ,=100 Seat"! “Temper range 288 co 348 K, Equation ony “Molecular Weight 01.0402 ‘Wiswesser Line Notation WNL valuation c CHO; i) ATIONGIA ‘Niromethine Meat Capacity 29815K, = 10898. K! “Temperate range 15 to 300 K Batropy 29818 K $2171.98 moth fig 277K it =9705 Fm! A5=3964 Jmol KO! lis BRISK, a=342T1 mer! oe90 PA Molecular Weight 61.0402 ‘Winwesser Line Notation WN! HNO, a) SOHOUIMAS ‘Naroethane Heat Capacity 313K, 1088 mol“ ‘Temperature range 31310363 K. Molecular Weight 61.0402 ‘Wiewesser Line Notation WNI Evaluation B HNO; he) SoERWES Nivomstane Heat Capacity 308K, 10622 Fm" Molecular Weight 610302 \Wisweser Line Notation WN Evaluation 3 HNO, igh SSGRASMI Met iat Heat Capacty 2982 K. CRILI9S mot “Temperature arge 1310298 Eawopy 82K, $2168 be! Phase Changes oa 1902, 28282 bm AS@43.33 Bmo-K Molecular Weight 77.0396 ‘Wewester Line Notation WNOT Evaluation - ‘Sodium methoride Heat Capacity 29815K 968.45 J mol" Temperate range $190 K Enropy DAI, S138 bmorK Phase Changes “Aromlousrepion ner 38 K with excess enapy of 48.12 Sma, excess enopy of 1.80 mK Molecular Weght 521239| ‘Wigwesser Line Notation 1 NA, Evaluation ‘ oH sevoortr Mette Heat Capacty “Tenperate range 0 1028, Phase Changes elled anssk, H9355 Jmol! 824557 bol eg 0st, lige stk, oD RPA Data fom 37FRAICLU and 39FRAICLU. Molecular Weight 16.0826 Wiewesser Line Notation 1 Evaluation a HNO) osMac Urea Heat Capacity 298 K, 807 em ‘te enperee Cy pv ar Vetch h * ‘Molecular Weight 60.0554 Wiswesser Line Notation ZVZ Evaluation D cH) 2n0msn.aT Urea Heat Capacity 2980. 1153 3mat"h ‘Temperature range 86 to 300 K. Value is ansmouthed experimental sum, utrapolation below a6 K, no details “Molecular Weight 0.0554 Wiswesser Line Notation 2VZ Fralvaton Bie .C¢S) cH) SSPARMUE Heat Capacty 2980, Cp=9888 J moth Temperature range 98 0 298 K Valve is unsmoothed experiment Entropy ak, S=108.4 Jono Extapolton below 90 K, 38.18 Jmol”! Molecolar Weight 6.0554 ‘Wiswesser Line Notation 2VZ valuation B(C,).C1S) Ur Heat Capacty 293K One tempers teeter 0 0998 ‘Wiswesser Line Notation ZVZ Evaluation c HNO) son ventur Urea Heat Canacity 7081S K 208 1 tana Temperature range 1910 318 K. Molecular Weight 60.0554 Wiswesser Line Notation ZV7Z 4. Phys. Chem. Ret, Data, Vo. 25, No, 1, 1996, 22 E. 8. DOMALSKI AND E. D. HEARING cHNO 6) GesaSivoK Ures Heat Capacity 298.15 K 6,900 Jt"! “Temperate range 90 to 298 Malecolar Weight 60.0558 Wiswesser Line Notation ZZ Evaluation ‘a om) sovoasct Ure Heat Capacity “Temperate range 323 10 493 K. Equation only: C,=323238 268.10 TH SOLO Phase Changes ig 058K, AH 13610 m0" S88 oA! Molecular Weight 600558 Evaluation 5 ry samt, S6KOZDAL, y=9808 01K! AS + oRIOT H05%10 ‘T-861X10"'T (240 0400), Enteopy DUIS K, 810695 Fmar-! Phase Changes ig Mss K, 8H=13900 mot"! $128 mK Molecular Weight 600558 ‘Wiswesser Line Notation 2VZ Evaluation » cane orpeuren Uren Phase Changes ig 065K, 314990 Fm! Molecular Weight 60.0558 Wiswesser Line Notation ZZ Evaluation s cHN0 SSGAMIBRO Uren Heat Capacity 308.7, 6,980 Sonat“ “Tengeratse range 3030 $13 K. Phase Changes lia 406 K. AH 14800 Fo! 382357 onal! Molecular Weight 600558 Wiswesser Line Notation 2VZ Evaluation ® CHW,0 61 S3ANDMAT Heat Capacity 29815K 29279 mat" Temperature range £3 vo 310 K Entropy 29815 K, $-10826 Fomor“! Molecular weigt 0953 Wisweser Line Notation 22 Evaluation x J Phs. Chem. Ret Data, Vol. 25. No.1. 1996 CHN,O-HNO, ©) SSNURE Ure tte Heat Capacty 281K C= 1586 ma -K-! Temperate ange 601 330K Entropy D8ISKS=1892 moh. K"! Motecalar Weight 125.0582 Wisweser Line Notation ZZ &WNQ Eraluaton ” cHNS ©) owes. “Ticea Heat Capacty —29815.K, #9690 a“. K~! Tenperatae ge. atrooy BGISK. | SH11S8 math) Moleclar Weight 761160 Wisveser Line Notation ZZUS Evaluation & 5008 meal: 200K, AS=O71 mK" A slight in the hea capacity appears becweea 210 and 260K. CANS © szToRs Thiouea Heat Capacty —29815.K, "9690 mol“! ‘One temperature, C, dats piven as IST PRUE, Daa £ SSTWESICHA, Phase Changes os 2915K,AH=112000 a! 823956 Fano Moleatar Weight 761160 ‘Wiswesser Line Notation Z7US Evaluation ® CHNS © 0VANN Heat Capacity 298.15 K,C=1254 mot“! Tengerate range $10 340 K Entropy BRISK $1402 moth K! Moleclar Weight 71160 ‘Winweser Line Notation NCSH &ZH valotion, 8 CUNS sven ‘Ammon ieyanat Phase Changes clled 007k, H=3200 Po! AS=89 Fol Molecular Weight 761160 ‘Wiswesser Line Notation NCSH & 24 Evalotion * Thioures 11.22 euarhlovoetaneelatrate Heat Capcity 281K Cyn406 sme! Tengertue range 13 1 380K Phase Changes lle 24k, H=5940 30 AS=2R1 Fema! AS=113 eal Moteclar Weight 396.1975 ‘Wiswesser Line Notation ZYZUS 3 &OYGYGG HEAT CAPACITIES AND ENTROPIES OF ORGANIC COMPOUNDS 23 CUNO: TSKRULIC Niopuaniine Heat Capacity 298 K, 6521293 See! Tenge ange 2004 40 Equi on ‘Molecular Weight 1080582 Wiswesser Line Notation WNMYZUM. Evaluation c 0.0 igh SOFIIAFA Methanol-dy: Mey lecboldy Ore temperature Molecular Weight 36.0744 Wieser Line Notation QH &1H.2 42412 3 CUDO ti) S2FILIAA Heat Capacity 29815. C,=848 Jonot“!.K"! (One empecaure “Molecular Weight 35.0563 wes bine Notation Ye athe 3 Evalvation 8 CHO ig) ssi Methanol: Met aleabol Heat Capacity 298 K, 83 eno KO! “Temperature range 288 to 335 K. teen Mtg 920820 Wiswesser Line Notation Qt Bvaleation| D CHO Cin) onwaL Methn Met lhl Heat Capacity 291K, e791 Molecular Weight 32.0520 Wisweser Line Notation QI Evaluation D HO ©) 25MAAWAL Methanol Mey let! “Tempore range 83 t0173 Phase Changes ig 6K, (811-2196 s-mot"! Molecular Weight 32.0320 \Wieweser Lie Notation Q] Evaluation c CHO tig) 250AR Methanol: ety let Heat Capacity 290. K 6.2799 met Temperature range 89 10290 K, Vue Is sramoothed experimental xu Eowropy 2981, 1364 mat"! Exraolation below 90 K. 4075 al Phase Changes elle Tol 311=590 01"! 35°36 J moth! ella isa Wwe 21% tinal" SSH Smo Molecular Weight 32.020 Wisweser Line Notation Qi CHO ig) 29KELS ‘Methanol; Methyl alco Heat Capacity” 2920 K, 62799 Jem! Tempers range 16 to 295 K. Vabe's nsmooted expermental ane, Entropy 29815 K, 268 bn9tK Phase Changes elel s74K, AH=645.5 5 mot" 35=4.10 mol Mig 1752, SH =3167 Fema! |85=1808 Jmol"?! Molecular Weight 32.0820 ‘Winwesser Line Notation Qt Bvaloation 8 CHO Gig) 2SPARIKEL Methanol Mey labo! Extpolton below 90 K, 343 Jsmol"-K", Revision of previous a “Molecular Weight 32.0520 valuation c CHO Ci) ‘Methanol: Methyl alcoho Heat Capacity” 270K, cy “Temperate range 100 19790 Molecular Weight 320120 Wisvesser Line Notation Qt vataation| B 29MITAIAR, 782 Sal! CHO (i ‘Methanol Methyl alcohol Meet Capacty” 31315 , ‘Tempera ange 40 to 110°C. Molecular Weight 320520 Wiswesser Line Notation Qt sIFOGIN 678856 bt" K-! cH ora Metano; Mey aol Heat Capacity 205K, GP 840 bm! ‘Temperature range $1028 K Eons 1635 K, Soh mat Molecular Weight 32.0820 Wiswesser Line Notation QI Evaluation 4 CHO a) orm Meta Mey alobol Heat Capacity 3008 K, C866 bmalK! ‘One temperature ‘Molecular Weight 32.020 Wiswesser Line Notation Qt Evaluation c “J. Phys. Chem. Ref. Data, Vol 25, No. 1, 1996 24 CHO (ia) ‘Methanol: Methyl aleoba Heat Capacity 270 K, Temperature range 9 0 210. Phase Changes elle 178K, ig W754, Molecular Weight 32.020 Weve Line Notation 1 Evaluation CHO (ia) ethno: Meth lobo! Meat Capacity 323, Tengerature range 52310 353K, Wiswesser Line Notation Qt valuation B CHO ay Methanol; Mey aleabol Heat Capacity 311K Mesa value 2110 56°C. ‘Molecular Weight 32.0120, Wisweser Line Notation Qt valeation ¢ CHO tia) Heat Capacity "2982 K, “Temperature ange 10 to 60°C Molecular Weight 32.0420 Weweer Ll Notation Qt valuation e cH ws) Methanol: Mey! alcool Heat Capacity 120K, “Temperature ange 200 [20 K. Phase Changes es 10s. ig isk Molecular Weight 320320 ese Lie Netaon QL CHO Cig) Heat Capacity) 3132, ‘One temperature. Molecular Weight 32.0420, ‘Wiswesser Lint Notation Q1 Evaluation 8 E. $. DOMALSKI AND E. D. HEARING <9sTVGUP 187 Fm!" 11 Sma! 51. Fmt 159 J mot 1801 em -K! coswuzie 6.2808 bm! (oKAT Gy 858 Fm! sssuasue 66839 Feo H=1540 5 mot" 851495 Fm! TORAZIPAZ, Cy 888 Fat 1 Phve Cham Rat ate, Vol. 25, No.1. 1996 CHO (igh ‘Methanol Methyl lesbo Heat Capacity 29815 K, Temperate range 9 10 332 K Batropy DBISK, Phase Changes lle Is734K, ig 17559, ‘Molecular Weight 32.0520, ‘Wiswesser Line Notation QL Evalvaton a CHO (i) ‘Methanol Methyl alcoho Heat Capacy 298K, Molecular Weight 320520 ‘Wiewesser Line Notation Q1 Evaluation 2 CHO id Methanol: Met lho! Heat Capaclty "27215 , One temperature Molecular Weight 32.0220 Woes Lie Nataton OF Evaluation emo cap Metana: Mey lho! Heat Capacty 28815 K, ‘One temper Motecalar Weigh 32.0120 Wiswesser Line Notation Qt Evaluation 8 CHO (ia) ‘Methanol Nit scab Heat Capacity 29815 K, ‘Ope temperature Molecular Weight 320420, Wiewesser Line Notation QI valuation 2 CHO ig) eran ety eo Heat Capacity 29815 K, Molecular Weight 32.820 Wiswesser Line Notation QI ‘Metianol Methyl alcool Heat Capacity 29815 K, ‘Temperature range 298.15, 313.18 K TICARW Gy°8113 eat s 119 FR 8=6360 1 m0"! S404 Jeol =32154 mot AS=1831 ot! ‘NDEs 67887 mot! HATNE Cye808 Fano! C2890 Fo vic 8192 bao! zeus 28147 aK sscos. 680.2 Peal HEAT CAPACITIES AND ENTROPIES OF ORGANIC COMPOUNDS 25 CHO Cia) 6KORKUK ‘Methaol Methyl alcohl Meat Capacity 298 K 1.32 mol Moleolar Weight 32.0220 Wiswesser Line Notation QI Evaloation| B cHo tia) S60GMUR Methanol: Met! lho! Heat Capacty— 2981SK $8028 Fath ‘One temper. Moleular Weight 32.0820, Winweser Lie Notation QI Evalvation B CHO ih soTaNrTOY Methanol: Methyl alot Heat Capacty 219K C2420 Fm SK ‘One peat Molecular Weight 32.220 Wiswesser Line Notation QI Evaluation CHO O) STLANICRI Heat Capacity 29818K C810 mah ‘te tempecre Molecular Weight 32.0420 ‘Wises Line Nouton Qt Evaluation 3 CHO) SSANDIPAT Methanol; Methyl lahat Heat Capacity 2981S K 28024 Ema! ‘Ope temperate. Molecular Weight 32.022 Wiswester Line Notation Qi Eraluation 8 CHO tis) sHOKAOGA ‘Methanol Mey kha! ew Capac) 9815 KC, 8035 Fath (Ore emer Moleular Weight 32.0820, Wisweser Line Notation QI HO OKHAVZYK, Methana: Mey! aloha Heat Cpacty — 2981SKCy=8LA1 bot“ K"! “Temper ange 175 338K. Unseoted exeinental dtu Molecar Weis 2.220 Wiswesser Line Notation QI Eraluation 3 CHO tig) OnFILIAFA, Metro Mey esha Heat Capacity 298.15 K 79 al") K"! ‘te pera Moleclar Weight 320520 ‘Wisweser Line Notation Q1 Evaloation| 5 CHO, A) Onhoforme it Neat Capacity 298 K, “Tenperne range 293 to 06 K Molecular Weight 640408 ‘Wieser Line Notation QYQQ Evaluation D CHS i) Heat Capacty 280 K ‘Temperate range 150280 K Entropy BID, Phase Changes ete 176K, ig 15016, ls mek, Dnata Weg 38.1020 sine 21586 dol". 2RUSIOSB, ,=8906 mat" $165.22 mot! H=2197 mh" 8-160 Fone! ‘8H =5908 Jmol! 98529992 Jamal ‘324568 J" '98=8802 Jana! Pe101325 Ps STASTISIL «, 10.80 mot" “engeratue rage 14 to 259 K. Value is unseated experimental $1992 bet"! oc suerte lui, usin exalted heat apace ‘Wiewesser Line Notation Sit Evaluation rn CHN ig) ‘Aminometian; Metin Heat Capacity 25928, Eropy 29815 K, Phase Changes ti 7970 K, liye 2084 Molecular Weight 3.0572 ‘Wiswesser Line Notation 21 CUNO © Heat Capacity 23815, “Tenperaure ange 601 380 K Emropy RISK, Molecular Weight 131700 ‘Wiswesser Line Notation ZVO42 valuation a CHAN Oe) Semssbuide “Temperature ange $0 30K Enwopy 2818 K Molecular Weight 75.0700 valet * H=9138 bm" 8523413 mol SSNUR/BER 1106 S01" S=1196 0"! s6LEBKUL, 21196 S-n0t" 4. Phys. Chem. Rot. Dat, Vol. 25, No.1, 1996 26 E. S. DOMALSKI AND E. D. HEARING CHAOS 9) SHNURIER Thur nae Heat Capacity, RISK, Gat mat * “Tengen range $10 330 Entropy DMLISK, 0218S han" Phase Changes ied sa K, an=240 sme! 820150 mar" Molecule Weight 139.1288 ‘Winweser Line Notation ZYZUS &WNQ Eralaton * HNO, 6) SSNURIBER Heat Capacity 29815 K,——Cy=1586 2m" “Tempera ange 13 0 350K Entropy 29815 K 192 A? Wirweser Line Notation ZZ NO Evaluation a cHNS 6) srToRsAB “Thieme Heat Capacity 29815K—_C=1109 Jmol KE ee emperor, daa given a 12177. 2 Phase Changes oe BW6ISK, ——AM=128800 wot AS=4219 Joa ‘Wirreser Line Notation ZYMZUS Evaluation ® a) NUR ER Heat Capacity 2981SK. 21143 mat “Tener range 8 0 320K trop BRISK S=1282 hmoFK" Phase Changes elle 289K A= TOO Fmt 3820250 mat 8 Motes Weight 91.1306 Wiawester Line Notation ZYMZUS Evaluation = CHNS GD SSNURIBER “Thneicarbaride Heat Capac RISK, Cj=1163 mak Entropy SISK S=182 hme. Phase Changes ciel 2689, SH=700 5 not" Molar Weight 91.1306 ‘Wiaweser Lie Notation ZYMZUS valuation * cow oxvaMMar Metyiammenium ate dy Temper rage 13 303 K, Data atv Phase Changes lel Molecular Weight 1650170, ‘Wiowesser Line Notun 21 AIH 1282 6 vation 8 160K. AS=88 Fmt! 4 Phvs, Chem. Ret, Dat, Vol 25, No.1. 1996 CHAINOS, 121,06) May ammonium alain lan ans Hea Cxpucty 200K ya 7aR eat IC! Temper rage 519 300K Entropy 0K. 521642 ba * hve Changes SK Anomaly: Schr pe soma ewes 65 and 120K, mai 230 K enpy ested 0 Be beens 6 and 9 Smo". 196 ‘Asouly: Due to fee tution of metylanmonim group (CHB ‘Mader Weight 7 3882 ‘Wisweser Line Notation AL Z1 $-04°2 QHD Evahaton A cHex © sata esha ois Heat Capac 2981S K,———C,=9092 Jmat.K “Tempers ange 12 10 298K Entropy Bek S188 ma ACE sing meatal Hl low 220 K aes $= 138. Jom" Pause illest amos, Aiteimt pat! AS=807 mot KE eet wisK ——AH=2810 mat * 51066 Lt" Moteur Welt 67.518 ‘Wiener Line Notation 2) &OH Evaluation A CHEN) nGeNL! Heat Capacity 200K Gp2792 soma “enperace ange 30 0 460K. C,()"1554 0514T+820%1C Phe" 200 0 480K), eset sora k, = 160 Fel AS=4m2 ema IC caled 804K SH=3S10 Pmot cm S19 K Aaa Fr S159 Sma! DMotcalar Weigh 11.959 Realtor A crysenry 0) ono ‘etme wtromoptmtt) Heat Capaity HOS C,=1707 Sam “Tenprae age 13 19 300 K Usted experiment tur, Phase Changes cv ts, H=190 not"! SSe112 5a ceatvenl 1st0K. ‘AH Dm let 2363 An=ITi0 mo S282 bao" Molecular Weight 78.971 Wrwener Line Notation 21 Ps Evalaton a HEAT CAPACITIES AND ENTROPIES OF ORGANIC COMPOUNDS a crigeXsa ©) s10NOMAT ‘Met amo tin bromide Heat Capacity 29815K,——C,=17045 Joma" “Temperate ange 1310 300K. Entropy BRISK, $3022 hm! Phase Changes eVelv 460K. AH=16 1-00 8-057 Pot eve i882, A= 1000 J-mot" 45~602 mot cued m94K, AH=2290 m0"! AS=18 98 Jmol"h ive plus etek “Moleclar Weight 40 911 ‘Winwesser Line Notation IZH SN ES valuation » CHEN) sisaTisoce Semicarhside hyeochloie Heat Capacity 33K 2125 Jomo “Pergo ne On 10°C. Mean val Motecalar Weight 111.5309 ‘Wiewesser Line Notation 2VMZ &GH. Evaluation c CHLONPD (0) s0oNomMaT “Metylammosia tihlrplumbar( Heat Capacity 30023K, C=1902 Jl" “Temperate range 13 wo 300 K. Unsmooted experiment datum hace Changes culvead wnisK, AM=2400 Ima" AS=146 fmol cae wma. H=1920 Ema" 82100 moth Molecular Weaht 345.6241 ‘Wisweser Line Notation Zi &-PB.G0G Evalotion » CHIN) sevaMocu Metylanmonium ode Heat Capacity 298.15 K 6.29898 Fomot"K Tempesee mage 10 300 K. Entropy BEISK, hat Phase Changes ellet 165.1 K Undercooted aw metastable & Molecular Weight 1389536 Winwesser Line Notaton 21 8 Eraluation 4 ‘at iven or 6 ohase ro 1010 220 Kt a phase anston at PaO Ky AH/=2970 Fa, AS=135 Jmol Methylamoni eiodplambste() 24K, 21896 J-m01"K! Tempera ringe (30 365K. Unimooed experimental datum nase Changes lt, 61K, 322980 Jo! As=190 Fama" ellet 04 K, Molecular Weght 619.9786 Wisweser Line Notation 21 &-P. It Evaluation a CHAN; hi) SUASTIENN Metythyerazine Heat Capacity 2981SK—Gy=13493 mol “Temperature ange 151 298K: Entropy BRISK, $=16594 m0" K"! Phase Changes tia 20079, AW=10418 Jmol AS=i719 mo" lige 285K AH=40367 Fat"! 45219539 J mot" kPa Moleclar Weight 46.0718 ‘Wiswesser Lie Notation ZL Evaluation 8 CHNO: (0 2acLUMAR, “Ammon carbamate Heat Capaiy 2953 K p= 131.00 Fs! “Temperate range 13 to 296 K ‘Molecular Weight 78.0706 \Wisweser Lie Notation 2VQ &ZH CHNS |) srTORSAB “Thocabelydaide Heat Capacity 29815 K Cyn 1253 mal (te temperate. C, daa given as L180) KF ‘Phase Changes oe 29RISK,——AM=152100 Fot* ‘8528101 bol" -K"! ‘Molecular Weight 16.1452 ‘Wieesser Line Notation ZMYMZUS Evaluation 8 a © “eaiodomethane B6ISK #2598 mol"! swoneeutr wegmt 2190090 ‘Wirwesser Line Notation DIL Evaluation a cKNS TOVAN-WES Poti hceyaate Heat Capacty— 29818K, 28853 mol“ “Temperate range $19 40 K Entropy BSISK, S143 Lao Molecular Weight 97.1760 Evalation * ots hneyanate Phase Changes lle 413K, 590-701 Fol"! Dependent oa hetnglooting ate Molecular Weight 971760 ‘Wiswesser Line Notation K SCN 4. Phys. Chem. Ret. Data, Vol 25, No.1, 1986 28 E. S, DOMALSKI AND E. D. HEARING cos tig) STKEMUGIA Carbonyl suide Heat Capacity 220, Cy27128 mo “Temper ge 20 10 220. Entropy 2291 K, 2631 JK Phase lig 13433 K, aH ~4728 ot"! lige m9 k, 8H=18506J-moI"* {S=8802 bm Pet01.325 kPa oecaar Weight 60.0708 ‘Wievesser Line Notation SCO Braluation s csi) TBROMAN ‘Caton ile ‘Temperature range 1S 10 297 K. Value is unsmoothed experimental aun, Entropy 29818 K, 1510 bmok-K ig W6LIEK, —— AH=4389 J-met"! s=77.24 bok Molecar Weight 76.1310 Evaluation A 8 ih 3oMAzS ‘Cubon dslide Heat Capacity 293K, 2778 bm ‘Temperate range ~100 10 20°C, Molecular Weight 76.1310 ‘Wiewesser Line Notation SCS Evaluation c Si) ora Cara disuse eat Capacty 3012 Gy 761 MI One temperate. Molecular Weight 76.1310 ‘Winwesse Line Notation SCS as sz {Carton siulide Heat Capacity 29831 K, 67489 bot". “emperatre range 7 10 31°C. Value & ensmocthed experimental Molecular Weight 1.1310, ‘Wiewesser Line Notation SCS valuation B cs, tia) ssstATuP Carbon disfie Heat Capacky 298, CP me 8 “Temperate range 286 0 317 K Moleclar Weight 76.1310 ‘Wiswesser Line Notation SCS valuation 2 ‘J. Phys. Chem. Ref. Data, Vol 25, No. 1.1996 Se ig) scat (Carbon diene Hest Capacity 298K, 887 mt! Entropy 28K 1653. ml" Phase Changes tig 205k, Molecolar Weight 162.9310, ‘Wiswesser Line Notation -SE-C-SE- Evaluation B BED. Cig) sowovs 1.2 Ditromoethane-d, Heat Capacity 310K. y= 9.2 emo ‘One temperate ‘Molecular Weight 1918864 Evaluation c Cit 0g) wunuse 1.2 Dibromoteeafuorcthane Heat Capacity 29815 K y= 1708 J mol “Temperate range 8 0 300 K. 29815 K, $2994 Jomo Phase Changes ewig 16285 K, AH =10367 J." as=a122 mar ‘Molecolar Weight 250.8236 ‘Wiwesser Line Notation FXFEXFFE Evaluation x CaBesFs a) ssves7 1.2 Ditromotetafsorethane eat Capacity 98.15 K Gyo moth CE “Temperanre range 298 to 318K Cy(bmal +0.1220(71K} 29810 318K ‘Molecular Weight 259.8236 Evaluation ‘* C20 yH,0 (6) satan (Caleiom oxalate monchyérte Heat Capacity 29878 KC, 91824 Jem! “Temperature anes 1940300 K. Cale is usmoctbed expeime Entropy 28K, $1860 Jem" !-K! Molecular Weight 146.112 Winwecer Tine Nafaion OUUD CA ROH Evaluation Garg) stow “Chertiuroethee; “Tirochlooetylene CChororiturseylene: Trituorchiorot? Heat Capacity 23480 K “Temperature ange 16 0 25 K Entropy 2480. S=200 66 Jat" Phase Changes ig 150K. AH=55526 Jmol"! 9524828 mel Molecular Weight 116.702 Winwesser Line Notation GYFUYFF Esaluation « HEAT CAPACITIES AND ENTROPIES OF ORGANIC COMPOUNDS, 29 Gar; a) sAGOLROL, ‘Casetnete: Coleritannetven: Tierra Tauro ene Phase Canoes ot es sit=s082 mot" Motclar Wei 16.702 ‘Wiener Line Notation GYFUYFE (cw), ©) sor Poinhancrailene: Payetuororyt ‘hie Hen Capety 290% cyto hm "Foner rugs Ow 24 °C, Vas ven for ingen ant Sonne samples. Vesper enone ut slow-oued sagt. Ussnooded experi itn, tc ight 1161902 ‘Wiswes Line tain PXGEXER* (GER, as) SoyARKAY Folyiuoretaetyee:Plyturiy “empsrtne ange 29810 873K. Equation. Vl per momar Moeclar Weihe 16 702 Peas oa) neve ‘opium: Fujita! Heat Capacty 2981S, Cyaorz2 mK Cymmr 298 13 KIC TORDS Hil. trey DISK S100 Smo ‘oxy, 29818 KY 11027 DK cha ak, BH =4699 mot 3589 ma Mote Wet 116702 Nee Lie Nan NCEE) Pralatin Gar, ssasti Pesunohioratane “Tepes range 1510234 K. Vale ute experiment eatery DDK S=24808 mor ctl mak. 312268 5m! 3823278 011! vie ouosk, — Aveisiiomr S283 JK Wisweser Line Notatian GXFPXFFF iCuFy ig 7PER eat Copacy 28S C1099 Fm “enpentue age =I88 0 20°C. Ves unsmocted exgrineal Molclar Weight 1705215 ‘Weve Lint Notation GXFFXGF? Potable of omer COR, ig s7eERe 12-Dec-1122 eeauoetae: Far 114 Heat Capadty 283K C1699 mat “empentre aage ~I88 0 20°C aes smoot expres Molecular Weight 1708216 ‘Whieser Line Notatlon OXFFXOFF Pretubly miu of omer. Shows peaks in Bet capcey at ied, 140°C and 100°C, wich oy be lay anions Cas, i SIKOUKOS, 12-Diclo11.2.2-eeatustae ion 114 Heat Copacty 98S CyB Sema Entropy 215K, 2.0 SK Phase Changes ssa ak H=1212 omar! SSe1L am ” AS=1958 Jo aig wane, A=15t0 Jn" Macau Weight 1709216 ” ‘Wiswesee Line Ntaba GXFRXGEF elation A CxeUr, sss Deer. 224erethane: Foo 16 Tien Capac | Pest. empersue stay equaion oly Moleclar Weight 150s236 ence Lie Nite GXFENGE Cr, ti) RE 2h 122 ease: Feo 13 Tempe ang —20 «61°C Motel Welt 187.3782 Palatino CEs sor, 12 Techie 22a: Fan 105 Meat Capacity 382K e270 Far Temperate singe 30101 °C Mota Welht 157.3963 ‘Wiens Lie Notton GRGEXOFF Balaton 8 4 Py Com. HO. Data, WoL. 25, NO. 1,19 30 E. S, DOMALSKI AND E. D. HEARING COR, tl) -soneNcH 1.1.2-Trichlvo-1.2.2-iuooehane; Freon 113 eat Capacty 98.15 K, Gye 1798 mot"! ‘Molecalar Weight 1873782 Wiswesser Line Notation GXGEXGFF ‘tlelted rom equation, Evaluation 2 COE, the) SIKOLKOS: yL2-Tricloo-,22-iuooehan; Frcon 113 Hieat Capacity 29613 KC HZ mol OK “Temperature eange 8. 300 Entropy 2981 K, $2898 Je" KP Phase Changes lle ask, ela 20692 K, 8-104 Jmol ‘Molecolr Weight 1873762 ‘Winwessr Line Notation GXGFXGEF Evaluation » GOLF, ad EGOLIKOL ',1.2Trihloo-1.22-iuoroethan; Freon 113 ig 27393. -2326 knot"! AS-849 mar Moleolar Weight 187.3762 ‘wiowesser Line Notation OXOFKOFF Evaluation . GCF, tla) SSVESZAB 1.L.2Tishlro-22.fuoroethane: Freon 113 Heat Capacty29815K, Cy 1729 mat“! “Temperate range 298 10 SIR K" C,Osmat = 11321 “SO 1981(TK) (240 19 337K). Molecolar Weight 183762 ‘Wowesser Line Notation GXGEXGFF CCF a) 2 WIRIBRA Heat Capacity 3031S KC, 1725 mat" “Temperature ange 288 to 503 K.p=06 MP, Molecular Weight 18.3762 Wiewesser Line Notation GAGEAGEE Evaluation x COMFy_h s7ortiwoo ht Tihloroituorostane Phase Changes Solplatic ent tig aw750, AH=a110 -m0t" SSe16 mol kK \Wisweser Line Notation GXGGXEFF valuation a 4. Phys. Chem. Rel Data, Vol 25, No. 1, 1996 CO, hg) sisvowt LL Ticlororuoretane Heit Capacty 29K 16K, Cy=1686 Jmol 1K" “Temperature range 298.15 10 3181S K. C,smolhK“}= 108 +0200 (TK) 258 © 318 K. ‘Molecalar Weight 1873762 ‘Wioweser Line Notation GXCOXFFF Evaleation a cc ti) “Teashorothylene;Tewaeloroeene Heat Capacity 298 K, Gy ‘Temperature range 291 10 $10 K. Molar Weight 165.8340 ‘Wiswesser Line Notation GYGUYGG valuation D 181k 1469 Semel eeu op “Teachlorethylee;Teacloroetene eat Capacity 298 K, = 1882 Feat 8 “Temperature rnge 16 0119 °C, mean, wo temperatures -Mecuae Wetght 1638340 ‘Wiwesser Line Notation GYGUYGG raluatlon D GAL (0) s2cron “Tetachlooethyen; Tercheroethene Heat Capacty 298.15 K, Cy t46 Fema K" Terperuce sage 299,15 K. Ose date pint given, ‘Molecalar Weight 165.8340 ‘Winwesse Line Notation GYGUYGG Eval a C1 iy sexovme “Tachloroethylene;Teuaclocetene Meat Copectty 20818 Cy 1S79 Fat LK! “Temperature sange 6 10 300 K. entropy 29818 , $2206 mot"! Phase Changes : 352526 mo! tig ‘3H/=10880 J moi" AS=4538 emal™ ‘Moteeuar Weight 165.8540 ‘Wiawesser Line Notation GYGUYGG valuation * CC ih sown “Tetchlroetylene;Teacloroetene ‘One temperate Molectar Weight 1658340 Wiewesser Line Notation GYGUYGG C1476 Emo car, ¥GOLK 11 -tetachornieorgemane Phase Changes ig 342K, =3990 Semel! AS*127 mK" Molecular Weight 203.8308 Whoweser Line Notation GXGGXGE Evaluation a HEAT CAPACITIES AND ENTHOPIES OF ORGANIG COMPOUNDS a Gaur, 09) STYARRAY Heat Capacity 398K CestPA6 Fa KE “ener ange 298 1 373K Eun Maleclar Weight 2033306 Palaten 8 "ace hero-2-iuorotane Heat Capacity 381SK | Cont7552 meh “Tengerate rage 12 31D K, Compl dn deposed 2 VENI Enver “bes, 27384 bel" {Lw eaoy of sion nus pone po eng Phase Changes 351253 Jmol Molecalar Wg 2038308 ‘Wisse Line Notion GXGEXGGE cuts ie) TeKISSUG Heat Capacity 200 pA 17899 BK Yairopy OK oh 29K, aH=3665 mot SSeS mt Molenar Weight 2033308 ‘inwener Line Notation OXGEXOGE *\.22-Tewoclore-2-

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