oN telat Vad Exam Corner (As per the Blue Print) | Part-A Part B Part-€ PoreD |__ (1 Mark) (2 Marks) Marks) (5 Marks) SAE ares [EE gho2 QNo. 12 Nite QNo. 30 (08 Marks 7. Sathana a RO Ans. At constant pressure the volume of a given f a Brett intake iii ee I ice is directly proportional to absolute & i) Non-polar molecules. — Fw HcrMotecutes We ae Seti Hes: 1) London forces'or Dispersion forces. Meee ee: © May 14Mar 15) ii) Dipole-Dipole forces. . VocT at constant pressure. 2. Name the type of Inter . broken in the Progess of ame s s ._ Ans. Hydrogen bonds (YS: State Boyte’s ta. (eb 17,18), ‘Ans. At constant temperature the volume of a given mass of gas is inversely proportional to pressure. a ‘Ans: pec at constant tamperature ‘Ans. The lowest hypothetical or temperature at which gases are supposed to ‘occupy zero volume is called Absolute zero. I 15 values is ~273.15* C ‘Ans. Boyle’s law ‘Ans. At constant volume presstire of a given mass ‘of gas is directly proportional to absolute ‘temperature. ‘Ans: A gas which obeys Boyle’s law, Charles” law and Avogadro law strictly is called an ideal gas. Scanned By Camera ScannerAns. Pressure exerted by the saturated water vapour is called aqueous tension, (i) The temperature at which a real gas obeys. ideal gas law over an appreciable range of pressure is called Boyle temperature Ans: (ii) The temperature above which gas can not be liquified by applying pressure is called critical temperature Gii) Volume of one mole of the gas at critical temperature is called critical volume. (iy) The pressure required to liquefy the @as at critical temperature is called as the critical pressure. Ans: 30.98°C Ans. (i) Increase (ji) decrease (iii) decrease HAND BOox Ans: Because they area to reduce su cs ‘Ans, The force of attraction between two temporay dipoles, Ex: Interaction between Noble gas atoms. Ans, It is interaction between polar molecules, Ex: Interaction between HCI molecules. a Ans. A non-polar molecule may be polarised by the presence of a polar molecule near it, thereby | making it an induced dipole. Ex: Noble Gas get polarized in the presence of polar molecule, ‘Ans. According to Boyle’s law p,V, = p,V, P,= 1 bar, V,=2.27L P,=0.2 bar V,=2 vj=BMi _thane.271_ berorbar ou Ans. V,=2L, T,=300K, V,=? T,= 320K According to Charles’ law Ps eND WT, Lo ae ssn 2a3L Scanned By Camera ScannerDL, T,=273+23.4=2964K, V, ,=273426.1 = 299.1 K ‘According to Charles’ law T,=25 +273 = 298K, T;= 10 +273 = 283K According to Combined gas law e. PU. Pia 7 A =P my, 298x649 = 676-6 mm Hg At constant Tand nV = Boyle’ ‘At constant p and n; V ec £ Ces ‘At constant p and T ; V en (Avogadré Law) yA Sy aR P proportionality constant called uni constant. On rearranging we get pV =n. Thus, where Ris gas pV=nRT p=Pressure, V= Volume, n=Numbérofmoles, "+ R= Gas constant, T : Consider one mole of an ideal gas under STP conditions (273.15 K and 1 bar pressure) It occupies a volume of 22.7L. : P=1 bar=10' Pa, V=22.7L=22.7 «107 me ue _10°Pax22.7%10"m? Amol x 273.15K = 8.314 Pam’ K" mol" 314JK* mol pV=nRT ga oc s eae Scanned By Camera ScannerAns. n=4mol, V= 15m’, pV=oRT DRT _ 48314373 _ 9969 65a Berein eee ‘Ans. Ideal gas equation is given by pV=nRT Replacing n by arene m v= ERT eM _ mT Rearranging M= RT Vp (Where d is density and M = Molecular mass of gas) ‘Ans. Low pressure and High temperature, ‘Ans. Compressibility factor (Z,) is given by |Z = 2Y_| Z> Lunder high pressure, “Ans. Compressibility factor (2) = PY Z= 1 for an ideal gas. HA ‘Ans. Gas A: Higher the critical temperature, greatrs the intermolecular force of attraction. ‘Ans. CO, because, gas with higher critical temperatue will have higher intermolecular forces. Heo liquified first. Ans. Normal boiling point: Temperature at whith the vapour pressure of a liquid becomes el to 1 aimosphere is called normal boiling pot Normal boiling point of water is 100°C. Standard boiling point: Tem; at whit + Temperature at wit the vapour pressure of the liquid becomes &@#! to | bars called standard boiling point. S boiling point of water is 99.6°C- | ns. If we imagine a line of unit length on the suit” of the liquid, the force acting rerpondiouar is ealed surface tension, 2 Pen SI unit of Surface tension is Nav, Scanned By Camera Scannerrere uaa ‘Ans. The resistance pos: \which arises due to the intemal friction between layers of fluid is called Viscosity SI unit of Viscosity / Co-efficient of Viscosity is Pascal second (Pa s). molecular forces of attraction, 2) Gas molecules have considerable volume, fe fe Gases are made up of a large number of small particles called molecules. Volume occupied by the gas molecules is negligible as compared to the total volume of the gas. There is no loss of kinetic energy during collision. The average kinetic energy of the gas molecules is directly proportional to absolute temperature, Scanned By Camera Scanner