Revision in Electronic

State and solid

Dr. Omar Mahmoud

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 Revision in Electronic State and solid

question 1 : Why the potential energy of S1 is greater than T1 ??

Q2: Give the reason, Electronic state in carbonyl compounds is always triplet state excitation

Q3: Give the reason, Electronic state in olefinic compounds is always singlet state excitation

Q4: Discuss Franck Condon peak for absorption and emission Principle Dr. Omar Mahmoud

Q5: Explain the significance of Singlet- triplet splitting energy ΔEs,t 01061015940

Q6 : Write about Photochromism of benzophenone using PMMA

Q7:Molecular oxygen is a crucial species in chemistry and biology.

(a) Draw the energy levels in molecular oxygen and the electronic notations of its ground and first two excited
electronic states.
Q8: Draw the M.O energy level of molecular oxygen in ground and calculate the multiplicity

Q9: Draw the relative energy and notation of ground and first and second excited state of O2

Q10: Draw the MO level of of molecular Nitrogen N2

Q11: Draw the MO level of of molecular NO

Q12: explain with drawing the Bonding of aqueous iodine

Q13: Write equations describing both photodynamic therapy (PDT) and drug
photo-toxicity based on singlet oxygen generation.

Q14:Explain the Photodynamic therapy (PDT)

Q15: Draw and label each of the following energy level Jablonski diagram for photophysical deactivation pathways
of electronically excited state
Q16:Construct the energy level diagram of species in a typical sensitization experiment in a typical triplet
sensitization experiment in which a mixture of naphthalene and benzophenone was irradiated through a 315
nm cut-in filter given the following absorption data
For naphthalene So S1 at 385 nm and So T1 at 465 nm
For benzophenone So S1 at 385 nm and So -T1 at 413 nm
The cut-in filter that absorbs below 315 nm.[hint : the energy in kcalmol-1 obtain as 28500/λ(nm)

Q17; Among the factors enhancing ic and vc is molecular flexibility, explain how this principle is applied in
each of the following
Dr. Omar Mahmoud
❑ Fingerprint development press
❑ DNA quantification using fluorescent stains press
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❑ Salmonella detection by MUCAP reagent press

Q18; Describe the methods of estimation the alendronate drug

Question 19: Explain the reason for each of the following:

❑ HClO4 and not HCl is commonly used in adjusting the pH of dye laser media
❑ R6G-I- solutions are strongly fluorescent in ethanol but non-fluorescent in chloroform
Q20: Describe briefly each of the following techniques

[1] the factors enhancing each of the following photophysical processes

[a] ic and vc [b], isc

[2].heat evolution is associated with (vc) but not with either (isc) or (ic)
[3].HClO4 and not HCl is commonly used in adjusting of pH of dye laser media

[Q22].Discuss the oxygen sensor based on molecular fluorescence

Q23: Give the reason :Absorption spectra of 2-naphthyl phenyl ketone at 450 nm is increased in presence
O2 in solution

Q24: Write about the Raman effect leading to stock, anti-Stock and Rayleigh line

Q25: Compare between fluorescence and phosphorescence

Q26:Discuss Polymer-photo stabilization Dr. Omar Mahmoud

Q27: Write about the origin of Stock shift 01061015940

Q28:Explain how can using the fluorescence quantitive of photosynthesis process efficiency
 Q31: Describe briefly each of the following techniques

[1].protein emission is dominated by tryptophan emission

Dr. Omar Mahmoud
[2].green- fluorescent grade anthracene is of lower price compared with blue-fluorescent grade
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[3].Note all nanomaterials are classified as quantum dot (QD)

Q30:Discuss the hyperthermia effect of gold nanorod in cancer treatment

Q31: Describe briefly each of the following techniques

[1].Application of gold nanoparticles in DNA sequencing and gold nanorods in cancer treatment

Q32:- Discuss the micro-electrode methods to determine DNA- sequence Dr. Omar Mahmoud

Q33:Describe briefly each of the following techniques 01061015940

[1].Application of SPIO as MRI contrast dye

Q34:- Discuss the idea of MRI

Q35: explain the idea of Ultra high detection bioassay [Prostate cancer]
 Q36 Draw and label each of the following energy level diagrams [1]. Photo catalytic effect of TiO2

Q37: In table( and suitable drawings if necessary) to contrast each pair of the following term
(a). UV. Visible spectroscopy versus excitation spectroscopy

Q38 Define Shpol’skii spectrum

Q39:Write short note about Aflatoxin analysis

Q40: Estimation of toxicity in hydrolysis of aspirin (acetyl-salicylic acid) using fluorescence
emission ( explain how and why)
Q41: Draw and label Fluorescence activated cell sorting (FACS) Apparatus used in flow cytometry

Q42:In fluorescent activated cell sorting (FACS) put numbers in the following table below each
component according to their sequence in the measuring apparatus then transfer the table in your
answer sheet

01061015940 Dr. Omar Mahmoud

 Q43: 9 aminoacridine Used in study of photosynthesis process efficiency (Explain )

Q44: Explain the importance of Polarized Fluorescence Dr. Omar Mahmoud

Q45Applications of Polarized Fluorescence 01061015940

Q46: Describe briefly each of the following techniques

[1].Polymerized crystalline colloidal arrays (PCCAs)technique and its application and their application in ionic and biological
sensing

Q47: Discuss the photo assisted chemotherapy

Q48: Explain how can you calculate the radiation energy required to protection the rats from rickets

Q49: Describe briefly each of the following techniques

[1].Modification of Teflon and polymethyl methacrylate(PMMA) surface

Q50: Describe briefly each of the following techniques

[1].polymorphism of drugs
Q51:Write about polymorphism in Anthracene

Q52: Discuss the effect of polymorphism on chemical reactivity(cinnamic acid)

Q53: Define F centers:

Q54: Draw and label each of the following energy level

diagrams
[1].The phase diagram of the cationic surfactant cetyltrimethylammonium ammonium bromide (CTAB) in water showing
the hexagonal, cubic and lamellar liquid crystal phases.
[2].Application of liquid crystal eg. (CTAB) in the synthesis of mesoporous silicate

Q55: Describe briefly each of the following techniques

[1]. Clay versus zeolites

Q56: Describe briefly each of the following techniques
[1].Zone refining technique

[2]. The DSC calorigram of polyethylene terephthalate (PET).

 Q57:How can you perform each of the following:
(a) Determine the solid fat index (SFI) using differential scanning calorimetry.(DSC)

Q58: Define The cloud point and the Kraft Point.

Q59: Give the reason for each of the following
[1].Differential scanning calorimetry (DSC) technique is superior to differential thermal analysis (DTA)
Q 60: In not more than ten words, define each of the following terms:

[1].A plasmon
[2].A mesogen
[3].An exciton
[4].An amorphous state [5].The aspect ratio (R) of nanorods

Q61: Explain the using of DSC in reaction kinetics

Q62: Uses tables (and suitable drawing if necessary) to contrast each pair of the following terms

[1]. Differential scanning calorimeter(DSC) versus differential thermal analysis(DTA)

[2]. Clay and zeolite
[3]. Amorphous and crystaline
(4). UV. Visible spectroscopy versus excitation spectroscopy