18.08.22 - OSR - STAR CO-SC - Jee - Adv - 2020 - P2 - GTA-12 (P2) - QP

Sec: OSR.
IIT_*CO-SC Date: 18-08-22

Time: 3HRS Max. Marks: 198
Name of the Student: ___________________ H.T. NO:
18-08-22_OSR.STAR CO-SUPER CHAINA_JEE-ADV_GTA-12(P2)_SYLLABUS
PHYSICS: TOTAL SYLLABUS
CHEMISTRY: TOTAL SYLLABUS
MATHEMATICS: TOTAL SYLLABUS

Narayana IIT Academy 18-08-22_OSR.IIT_*CO-SC_JEE-Adv_GTA-12(P2)_Q’P
TIME: 3HRS IMPORTANT INSTRUCTIONS Max Marks: 198
PHYSICS
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I (Q.N : 1 – 6) Questions with Single digit integer(0-9) +3 -1 6 18
One of More Correct Options Type
Sec – II (Q.N : 7 – 12) +4 -1 6 24
(partial marking scheme) (+1)
Questions with Numerical Value Type
Sec – III (Q.N : 13 – 18) (e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐1 +4 0 6 24
27.30)
Total 18 66
CHEMISTRY
Sec – II (Q.N : 25 – 30) +4 -1 6 24
Sec – III (Q.N : 31 – 36) (e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐1 +4 0 6 24
27.30)
Total 18 66
MATHEMATICS
Sec – II (Q.N : 43 – 48) +4 -1 6 24
Sec – III (Q.N : 49 – 54) (e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐1 +4 0 6 24
27.30)
Total 18 66
SR.IIT_*CO-SC Page. No. 2

PHYSICS MAX.MARKS: 66
SECTION – 1 (Maximum Marks: 18)
This section contains SIX (06) questions.
The answer to each question is A SINGLE DIGIT INTEGER rangeing from 0 TO 9 , BOTH INCLUSIVE.
For each question, enter the correct numerical value of the answer using the mouse and the on-screen virtual
numeric
keypad in the place designated to enter answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If only the correct option is chosen.
Zero Marks: 0 If none of the option is chosen.(i.e the question is un answered)
Negative Marks: -1 In all other cases.
1. A plano-convex lens has a thickness of 4 cm. When placed on a horizontal table with
curved surface in contact with it, the apparent depth of the bottom most point on the
lens is found to be 3 cm. If the lens is inverted such that the plane face is in contact
with the table, the apparent depth of the centre of plane face is found to be 25/8 cm.
The focal length of the lens (in cm) is
2. A galvanometer of coil resistance 1 is converted into voltmeter by using a resistance

of 5  in series and same galvanometer is converted into ammeter by using a shunt of
1 . Now ammeter and voltmeter connected in circuit as shown, find the reading of
voltmeter. (in volt)
3. For the circuit show in the figure, find the peak current (in ampere) through the source.

4. A conducting sphere with inner radius R and outer radius 3R has some alloys mixed in
it due to which its resistivity changes with radial distance r according to the
function r  Kr where K is a +ve constant. Inner surface of the sphere is grounded
while outer surface of sphere in maintained at potential V0 with the help of a battery of
n a
emf V0 . Battery is ideal. The potential of the sphere at radial distance of 2R is V0 .
n b
Find (a + b).
5. A small boat is travelling downstream with velocity 5 m/s relative to river flowing with
speed 7/3 m/s. it encounters a log floating in the river at some distance from itself. It
turns by an angle of 370 and just crosses the edge of the log after 8 sec. Find time taken
(in second) by boat to just cross the edge of log if log is kept fixed.
6. In a slow reaction, heat is being evolved at a rate about 10mW in a liquid. If the heat
32
were being generated by the decay of P , a radioactive isotope of phosphorus that has
half-life of 14 days and emits only beta-particles with a mean energy of 700KeV. The
number of 32
P atoms in the liquid is A  77  1015 find A: [Take: ln 2 = 0.7]

SECTION - 2 (Maximum Marks : 24)
Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these four option(s) is
(are) correct option(s).
For each question, choose the correct option(s) to answer the question.
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are
correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
7. An adiabatic container of volume 4V0 is divided into two equal parts by rigid fixed wall
whose lower half is conducting and upper half in non-conducting. Initially the right
portion is divided into two equal parts by a freely moving massless & non conducting
piston. Section A has 2 moles while sections B and C each has one mole of the same
ideal gas with adiabatic exponent   1.5 at pressure P0. If the heater in left part is
switched on till the final pressure in section C becomes (125/27) Po. Mark the correct
statements
205 P0V0
A) Final temperature in section A
27 R
5 P0V0
B) Final temperature in section B
3R
205 P0V0
C) Final temperature in section C
27 R
368
D) Heat supplied by the Heater P0V0
9
8. In a photoelectric effect experiment, a point source of light of power 40W emits mono-
energetic photons of wavelength 1 , that can just exit photoelectrons from an isolated
metallic sphere of radius 1 cm, placed at a distance of 1 km from the light source. Now,
three other sources of wavelength 2 , 3 , and 4 which are emitting the same number of
photons as that of 1 brought near the source of 1 . Assume photo efficiency of 106
(Take 1  4960 A0 , 2  4133.33 A0 , 3  5000 A0 , 4  7200 A0 and hc  12.400 eV . A0 )

A) Number of photoelectrons emitted from the sphere per second is 2.5  109
B) The potential of the sphere when emission of photoelectron stops is 0.8 V.
C) The potential of the sphere when emission of photoelectrons stops is 0.5 V.
D) The time after which the emission of photoelectrons will stop is 1.39  103 sec
9. A small bead of mass m can slide on a frictionless fixed ring of radius r. With the help
of two identical strings of force constant k, the bead is connected to two nails A and B
each on a diameter at a distance 0.5 r from centre O of the ring. Relaxed length of each
string is negligible as compared to the radius of the ring. The bead is given a small
velocity at point C. What can you predict about subsequent motion of the bead before
any of the string strikes a nail? [ignore gravity]
A) It will keep moving with its initial speed.
B) It will oscillate simple harmonically about the point C.

C) Its angular momentum about centre o of the ring is conserved.
D) Total elastic potential energy stored in both the strings is 1.25 kr 2 .
10. A solid paraboloid of base radius R0 and height h0 is having uniform volume mass
density of s , is Inverted and placed just above the surface as shown, on a liquid having
volume mass density of L . When paraboloid is released from rest it has been observed
that when it becomes completely submerged in the liquid the paraboloid comes to the
rest again. There exist uniform gravity of g. Assume that the liquid body is very large so
that liquid level is not changing as the paraboloid enters into the liquid.
A) The phenomenon is true for all paraboloids irrespective of their dimensions as long
as density ratio is maintained.
B) The phenomenon is not true for all paraboloids irrespective of their dimensions as
long as density ratio is maintained.
L
C) The ratio of is 2.
s

D) The ratio of L is 3.
s

11. A ball of mass m  1 kg is hung vertically by a thread of length   1.50 m . Upper end of
the thread is attached to the ceiling of a trolley of mass M= 4kg. Initially, trolley is
stationary and it is free to move along horizontal rails without friction. A shell of mass
m = 1kg, moving horizontally with velocity v0  6 ms 1 , collides with the ball and gets
stuck with it. As a result, thread starts to deflect towards right ( g  10 ms 2 )
A) The maximum deflection of the thread with the vertical is 37°
B) The maximum deflection of the thread with the vertical is 45°
C) The velocity of the trolley at that instant of maximum inclination of thread is 1ms 1
D) The velocity of the trolley at that instant of maximum inclination of thread is 2 ms 1
1
12. Two blocks A and B each of mass kg is connected by a massless inextensible string
2
and kept on horizontal surface. Coefficient of friction between block and surface is
shown in figure. A force F  kt (where k = 1 N/s and t is time in second) applied on A.
Then ( g  10 m / s 2 )
A) work done by friction force on block B is zero in time interval t = 0 to t = 3s.
B) work done by friction force on block A is zero in time interval t = 0 to t = 3s.
C) work done by tension on B is also zero in time interval t = 0 to t = 3s.
D) speed of blocks at t = 10s is 27.5 m/s.

This section contains SIX (06) questions. The answer to each question is a NUMERICAL VALUE
numeric keypad in the place designated to enter answer. If the numerical value has more than two decimal
places truncate/round- off the value to TWO decimal places.
Full Marks: +4 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.
13. An electron accelerated by a potential difference V = 3.6 V, first enters a region of
uniform electric field of a parallel-plate capacitor whose plates extend over a length
  6 cm in the direction of initial velocity. The electric field is normal to the direction of
initial velocity and its strength varies with time as E  a  t where a  3200 V m 1s 1 . Then
the electron enters a region of uniform magnetic field of induction B    109 T .
Direction of magnetic field is same as that of the electric field. Calculate the pitch (in
mm) of helical path traced by the electron in the magnetic field. (Mass of electron,
m  9  10 31 kg , e  1.6  1019 C ). [Neglect the effect of induced magnetic field].
14. Find the distance (in cm) between two images of a point object formed by upper and
lower part of the lens when object is placed at 30 cm from given lens.
15. Ann is sitting on the edge of a Disc that has a radius of 6 m and is rotating steadily. Bob
is standing still on the ground at a point that is 12m from the centre of the carousel. At a
particular instant, Bob observes Ann moving directly towards him with a speed of
1 ms 1 . With what speed (in m/s) does Ann observe Bob to be moving at that same
moment?

16. The peak emission from a black body at a certain temperature occurs at a wavelength of
6000 A0 . On increasing its temperature, the total radiation emitted is increased 16 times.
These radiations are allowed to fall on a metal surface. Photoelectrons emitted by the
peak radiation at higher temperature can be bought to rest by applying a potential
equivalent to the excitation potential corresponding to the transition for the level n = 4

to n = 2 in the Bohr's hydrogen atom. The work function of the metal is given by eV
100
where  is the numerical constant. The value of  is found 53  x , find x? [Take: he =
12420 eV- A0 ]
17. A motor is installed at the top of a pole rigidly fixed on a platform. A light rod of length
r = 1 m is rigidly attached to the motor shaft at its one end and at the other end a small
ball of mass m is attached. The rod can rotated in a vertical plane with the help of the
motor. Total mass of the platform, the pole and the motor is   4 times the mass of the
ball. The motor rotates the rod at a constant angular velocity. The platform is placed on
a horizontal surface, where coefficient of friction is   1 / 3 . At which minimum
angular velocity 0 , of the rod, will the platform start sliding? Express the answer in
rad/s
18. An isosceles right triangular plate ABC of mass ‘m’ is free to rotate in vertical plane
about a fixed horizontal axis through A. It is supported by a string such that the side AB
p  mg 
is horizontal. The reaction at the support A is thus p + q is
q

CHEMISTRY MAX.MARKS: 66
numeric
19. Equivalent conductivity of AgNO3 , CaCl2 and Ca  NO3 2 at infinite dilution are 110, 230
and 196.51cm2 eqv 1 respectively. Conductivity of AgCl  aq. and H 2O is
2.4  106  cm1 and 1.4  106 1 cm 1 respectively. the solubility of AgCl in mg/litre is.
[Atomic mass : Ag =108, Cl=35.5]
20. Na2 S2O3 is used in the bleaching industry to destroy any excess Cl2 on fabric after they
have been passed through a bleach bath. 15.8 g of Na2 S2O3 react with 30.4 g of Cl2 in
excess of H 2O then the mass of Sulphur containing compound formed due to this
x
reaction is x g. This Sulphur containing compound is an acid salt. The value of is
4
21. Dithionic acid, thiosulphuric acid and dithionous acid contain x, y and z number of
 bonds respectively. Then the value of x  y  z is
22. How many compounds (including stereoisomers) of formula C4 H11 N give positive
carbylamines reaction or test?
23. How many compounds from the given list gives positive Tollen’s test?

24. Which of the following molecule shows optical isomerism

correct options.
option.
25. An ionic solid AB on heating develop Frenkel defect or Schottky defect only. To
determine which type of defect is shown by solid on heating, experiment is performed.
Assume AB is completely soluble in water and at 300.K solid does not show any type
of defect.
Experiment 1: At 300K, 200g of AB is dissolved in a solvent to get 1 L solution and
osmotic pressure is 98.52 atm.
Experiment 2: If 200 g of AB is dissolved in a solvent to get 1 L solution at 600 K (at
600 K solid shows defect) and osmotic pressure is 187.188 atm (assume volume of
solution remains same at both the temperatures).
On the basis of this experiment, select the correct statement about the solid at 600 K.
A) Solid AB shows Frenkel defect
B) Solid AB shows Schottky defect
C) On heating, density of solid decreases
D) On heating, density of solid remains same

st
26. Consider the two parallel 1 order reactions given below leading to formation of
product P1 and P2 .
It is given that x is more than y and both reactions have same value of Arrhenius
parameter (A) Select the correct statement(s)
A) The ratio of concentration of Products

 P1  increases if temperature is increased
 P2 
B) The ratio of concentration of Products

 P1  decreases if temperature is increased
 P2 
C) The ratio of concentration of products

 P1  remains same if temperature is increased
 P2 
D) The ratio of concentration of products

 P1  remains same if temperature is decreased
 P2 
27. In an experiment it is found that at a constant temperature, rate of adsorption of gas on
solid surface follows the relation
Rate  [surface area of solid]1
A solid is taken in form of cube that has side length 1 cm. The total surface area of this
cube is x cm2 and rate of adsorption of gas is r1 . If this solid cube. Is divided equally
into 1012 cubes then total surface area available for adsorption becomes y cm 2 and rate
becomes r2
On the basis of above information, select correct statement(s)
A) x is 6 B) y is 6.0 104 C) r2 / r1  6 104 D) r2 / r1  104

28. Consider the Ellingham diagram given below
Select the correct statement(s)
A) Above diagram predicts about kinetics of reduction processes
B) Standard entropy change of C  CO2  g  is almost zero
C) Below 500 C , FeO can be reduced by coke when C converts into CO
D) Above 500 C , FeO , can be reduced by coke when C converts into CO
29. A pink solid compound (A) has the formula CoCl3 .5 NH 3 .H 2O . A 0.1 m aqueous solution
of this salt, has the depression in freezing point  T f  equal to 0.7440 C. Solid A on
heating above 1200 C gives a purple solid (B) with only NH 3 and Cl  as ligand and have
the same ratio of NH 3 : Cl as in first complex (A) Based on this information, select the
correct statement(s) if co-cordination number of cobalt remains six in A and B both.
 K ,  H O   1.86 K molal 
f 2
1
A) IUPAC name of A is Pentaammineaquacobalt (III) chloride
B) Pink solid A is diamagnetic in nature
C) Hybridisation of cobalt in pink solid is d 2 sp3
D) Purple solid is diamagnetic in nature

30. P4 on reaction with SO2Cl2 forms a compound A and an acidic gas B. Compound A can
react with NH 4Cl to form cyclophosphazenes  NPCl2 n where n  3. Compound A on
reaction with NH 4Cl forms one such cyclic compound Q with n  3 . Select the correct
statement(s)
A) A is PCl5 while B is SO2
B) A is PCl3 while B is SO2
C) One molecule of Q contains 3  bonds
D) One molecule of Q contains six P  Cl sigma bonds

31. Consider the following statements and find how many of them are correct?
a) The sublimation of iodine is due to weak I-I bond
b) The sublimation of iodine is due to lone pair- lone pair repulsion in I 2 molecule
c) Na2 SO3 on reaction with chlorine water form Na2 SO4 and HCl
d) HCl gas can be dried by passing through concentrated sulphuric acid
e) Pt on reaction with aqua regia forms nitric oxide (NO)
f) Noble gases are sparingly soluble in water
g) Very pure nitrogen can be obtained by the thermal decomposition of barium azide
h) The single N-N bond is weaker than the single P-P bond

32. Consider a 70% efficient hydrogen-oxygen fuel cell working under standard conditions
1
at 1 bar and 298K. Its cell reaction is H 2  g   O2  g   H 2O  l  The work derived from
2
the cell on the consumption of 1.0  103 mol of H 2  g  is used to compress 1.00 mol of a
monoatomic ideal gas in a thermally insulated container. What is the change in the
temperature ( in K) of the ideal gas?
The standard reduction potentials for the two half-cells are given below
O2  g   4 H   aq   4e   2 H 2O  l  , E 0  1.23V
2 H   aq   2e   H 2  g  , E 0  0.00V .
Use F  96500Cmol 1, R  8.314 J mol 1K 1
33. Consider following alloys
Bell metal, Brass, Bronze, Monel metal, German silver, Gun metal, Alnico, Number of
alloys which do not contain copper is
34. Valine, Leucine, Argnine, Glycine, Glutamic acid, Lysine, Alanine. If X is the number
of amino acids which have the isoelectronic point less than 7, then the value of  X  5 
is
35. For 10 minutes each, at 00 C , from two identical holes nitrogen and an unknown gas are
leaked into a common vessel of 4 litre capacity. The resulting pressure in vessel is 2.8
atm and the mixture contains 0.4 mole of nitrogen. What is the molar mass of unknown
gas. Take R  0.0821 L  atm  mol 1K 1 
36.
Decarboxylation takes place in the above compound via cyclic transition state. ‘X’ is
number of the atoms involved at the corners of ring of cyclic transition state. Then the
value of X 2 is

MATHEMATICS MAX.MARKS: 66
numeric
37. If x + y = 3 is tangent at (2, 1) on hyperbola, intersects asymptotes at A and B such that

AB  8 2 . If centre of hyperbola is (–1, –1), then least possible value of sum of semi-
transverse axis and semi-conjugate axis is p q , where HCF (p, q) = 1 and q is
irrational number. Then, (p + q) is equal to ------------
38. If 8 harmonic means  H1 ,H2 ,H3 ,.........,H8  are inserted between two numbers a and b
5
(a < b) such that arithmetic mean of a and b is times equal to geometric mean of a and
4
 H a
b, then  8  is equal to
 b  H8 
2
39. If cos1  2  x 2   sin 1  2  x 2   tan 1 x  have no solution if x   or x  
3
 2
  min       ------------
1
(for    ), then 
 max   
40. If I  
2
x3  3x 2
dx and J  
 3x  5  dx , then e I  J equals……….
3
1
n  x  1 2
n  x  2 
41. Position vector of a point A is  aiˆ  bjˆ  ckˆ  and a 2  b2  c2  4 ; and position vector of
another point B is  p iˆ  q ˆj  r kˆ  and p 2  q 2  r 2  9 . Given  AOB = 2cos1

1
, where O
5
is origin. If AQ is perpendicular to angle bisector of AOB i.e. line OQD where D lies
on AB, then value of 25 QD equals,
 1   1 
If f '  x   0  x  R  where f : R   R and f  x    f 1 
1 1
42.  and f    0 , then
x  f  x   f  x 

is equal to ------------
sin  f  2  
1

correct options.
option.
43. Three are 5 boxes numbered from 1 to 5. There is 1 Red and 2k black balls in kth box,
k =1,2,3,4,5. From each box either one red ball is taken or one or more than one black
balls are taken. But from each box both coloured balls are never taken (ball of same
colour are all alike). Now which of the following holds good ?
A) Total number of ways of selecting odd number of red balls is 4725
B) Total number of ways of selecting even number of red balls is 5670
C) Total number of ways of selecting odd number of red balls is 5670
D) Total number of ways of selecting even number of red balls is 4725
If f : R  R be a differentiable function such that  f  x    x  f  x  , then

7
44.
f 1  x  dx is 3
2
A) The value of 0
B) f  x  is increasing for  xR
C) The area bounded by curve y  f  x  , between the ordinates x  0, x  3 & x axis is
f  3  8
   3 
7
3 f 3 4f
8 
D) The area bounded by curve y  f  x  between the ordinates, x  0, x  3 & x  axis is
f   

3  3  f  
3
4
4f  3 

45. A corridor housing the shape as shown below is ‘a’ unit wide in one of its wings & b
units wide in the other. Stick is moved from one of the wings to the other (It is assumed
that the thickness of the stick is negligible & during the motion the stick stays
horizontal)
A) The length of longest stick that can move is (a2/3+ b2/3 )3/2
B) The length of longest stick that can move is (a3/2+ b3/2 )2/3
C) The longest stick makes angle  with one of its walls & is tangent to vertex ‘O’ of
the inside then tan  = (b / a)1/3.
D) None of these
 1   1 
46. If 5 x 1  2 2   12 and 5 y 1  2 2   4  x, y  R , then correct option can be,
 x y   x y 
1 3
A) x  y  3 B) x  y  C) x  y  D) x2  y 2  5
5 5
47. The number of codes of 20 digits which can be formed using digits 0, 1, 2, 3, 4 such
that difference of consecutive digit is one is N, then
A) total number of positive integers which divides N is 40
B) N is divisible by 38
C) N is divisible by 7
D) the number of ordered pair (a, b) such that a  b = N and a, b  I+ and gcd (a, b) = 1
is 4

48. Let ABCD be a rectangle with A(0, 0), B(4, 0), C(4, 4) and D(0, 4). Rectangle is folded
in such a way that corner B always lies on line AD, then which of the following
statement(s) is/are correct?
A) As the point B moves on AD the crease thus formed will touch a fixed parabola
whose focus is at (4, 0)
B) As the point B moves on AD the crease thus formed will touch a fixed parabola
whose focus is at  , 0 
3
2  
C) As the point B moves on AD the crease thus formed will touch a fixed parabola
whose equation is y2  8  x  2 
D) As the point B moves on AD the crease thus formed will touch a fixed parabola
whose equation of directrix is y  2x


1
49. If S   k 51 , then value of S is equal to ------------
k1 Ck
Let S be the sum of digits of all the real coefficients of 1  i x  . If log 2 S  N , then
2015
50.
value of N is equal to,
1 1 1 1
51. If S  1    ....... , then [ S ] is equal to (where [.] denotes the greatest
2 3 4 1000000
integer function)
1
52. Locus of a point P which divides all chords of slope of parabola x2 = 4y in the ratio 1
2
: 2 internally is another parabola with vertex  ,  and length of latus rectum , then
a b c
9 9 9
the value of ab2c2 is,
53. If all the roots of the equation x1008  a1 x1007  a2 x1006  .....  a1006 x 2  1008 x  1  0 are real, then
a2
value of is,
a1
e dx I 1
54. If I  1/ e log x 2
, then   -------------
x 4 2e

18.08.22 - OSR - STAR CO-SC - Jee - Adv - 2020 - P2 - GTA-12 (P2) - QP

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18.08.22 - OSR - STAR CO-SC - Jee - Adv - 2020 - P2 - GTA-12 (P2) - QP

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Sec: OSR.

IIT_*CO-SC Date: 18-08-22

Name of the Student: ___________________ H.T. NO:

18-08-22_OSR.STAR CO-SUPER CHAINA_JEE-ADV_GTA-12(P2)_SYLLABUS

PHYSICS: TOTAL SYLLABUS

CHEMISTRY: TOTAL SYLLABUS

MATHEMATICS: TOTAL SYLLABUS

SR.IIT_*CO-SC Page. No. 2

2. A galvanometer of coil resistance 1 is converted into voltmeter by using a resistance

voltmeter. (in volt)

SR.IIT_*CO-SC Page. No. 3

SR.IIT_*CO-SC Page. No. 4

SR.IIT_*CO-SC Page. No. 5

B) It will oscillate simple harmonically about the point C.

SR.IIT_*CO-SC Page. No. 6

A) The maximum deflection of the thread with the vertical is 37°

B) The maximum deflection of the thread with the vertical is 45°

D) The velocity of the trolley at that instant of maximum inclination of thread is 2 ms 1

A) work done by friction force on block B is zero in time interval t = 0 to t = 3s.

B) work done by friction force on block A is zero in time interval t = 0 to t = 3s.

C) work done by tension on B is also zero in time interval t = 0 to t = 3s.

D) speed of blocks at t = 10s is 27.5 m/s.

SR.IIT_*CO-SC Page. No. 7

SR.IIT_*CO-SC Page. No. 8

SR.IIT_*CO-SC Page. No. 9

and 196.51cm2 eqv 1 respectively. Conductivity of AgCl  aq. and H 2O is

[Atomic mass : Ag =108, Cl=35.5]

SR.IIT_*CO-SC Page. No. 10

SECTION - 2 (Maximum Marks : 24)

A) Solid AB shows Frenkel defect

B) Solid AB shows Schottky defect

C) On heating, density of solid decreases

D) On heating, density of solid remains same

SR.IIT_*CO-SC Page. No. 11

A) The ratio of concentration of Products

B) The ratio of concentration of Products

C) The ratio of concentration of products

D) The ratio of concentration of products

SR.IIT_*CO-SC Page. No. 12

Select the correct statement(s)

A) Above diagram predicts about kinetics of reduction processes

B) Standard entropy change of C  CO2  g  is almost zero

C) Below 500 C , FeO can be reduced by coke when C converts into CO

D) Above 500 C , FeO , can be reduced by coke when C converts into CO

A) IUPAC name of A is Pentaammineaquacobalt (III) chloride

B) Pink solid A is diamagnetic in nature

C) Hybridisation of cobalt in pink solid is d 2 sp3

D) Purple solid is diamagnetic in nature

SR.IIT_*CO-SC Page. No. 13

A) A is PCl5 while B is SO2

B) A is PCl3 while B is SO2

C) One molecule of Q contains 3  bonds

D) One molecule of Q contains six P  Cl sigma bonds

SECTION - 3 (Maximum Marks : 24)

a) The sublimation of iodine is due to weak I-I bond

d) HCl gas can be dried by passing through concentrated sulphuric acid

e) Pt on reaction with aqua regia forms nitric oxide (NO)

f) Noble gases are sparingly soluble in water

SR.IIT_*CO-SC Page. No. 14

Use F  96500Cmol 1, R  8.314 J mol 1K 1

33. Consider following alloys

SR.IIT_*CO-SC Page. No. 15

37. If x + y = 3 is tangent at (2, 1) on hyperbola, intersects asymptotes at A and B such that