OUT GOING SR(MPC) Date: 13-06-2022

Time: 3 Hrs Max. Marks: 300

13-06-2022_OUTGOING SR _JEE MAIN MODEL GTM-8 KEY&SOL

KEY
QNO. 1 2 3 4 5 6 7 8 9 10

1-10 1 1 3 1 1 1 4 1 4 2

11-20 4 1 1 3 4 1 4 1 1 3

21-30 5250 20 102 15 3 4 5 5319 100 1

31-40 4 2 3 1 3 2 4 1 2 2

41-50 3 4 2 1 2 4 3 3 2 3

51-60 7 3 9 4 2 50 477 605 3 3

61-70 2 4 3 2 1 1 3 2 1 4

71-80 3 3 3 2 4 3 4 1 3 3

81-90 3 50 2 4 8 5 1 1 -5 0

HINTS & SOLUTIONS

PHYSICS

1. X  5YZ 2
X
 Y  2 ................(i )
Z
Q Q2 [ A2T 2 ]
X  capacitance   
V W [ ML2T 2 ]
X  [ M 1 L2T 4 A2 ]
F
Z B
IL
Z  [ MT 2 A1 ]
 [ M 1 L2T 4 A2 ]
Z
[ MT 2 A1 ]2
Y  [ M 3 L2T 8 A4 ]
2. Initially, the parachutist falls under gravity
 u 2  2ah  2  9.8  50  980 m 2 s 2
He reaches the ground with speed  3 m / s, a  2 m s 2
 (3) 2  u 2  2  2  h1 or 9  980  4h1
971
or h1  or h1  242.75 m
4
 Total height = 50 + 242.75 = 292.75 = 293 m
3. Vertex B has two components of velocities, vx and v y

d ( x / 2) 1  dx  v
vx    
dt 2  dt  2
vx
Now  tan 45
vy
v
or v y  vx 
2
Velocity of vertex B , vB  vx 2  v y 2
2 2
v v v
     
2 2 2
4. Collision will be avoided if speed of the train v1 becomes equal to v2 in travelling a relative distance d.
Therefore final relative speed of trains becomes zero. The initial relative speed v12  v1  v2 . By third
equation of motion, we have
v12 2  u12 2  2a12 s
0  (v1  v2 )2  2(  0)d
(v1  v2 ) 2
or d
2
(v1  v2 ) 2
The collision can be avoided if d 
2
5. From geometry, we can write
 B 2  R 2  A2
or B 2  A2  R 2
or ( B  A)( B  A)  12 2
Given A  B  18
or 18( B  A)  144
or B  A  8
On solving above equations, we get A= 5N and B = 13N
40
6. ax  8
5
1
s x  u x t  ax t 2
2
sx  400iˆ
10
ay  2
5
1
s y  u yt  ay t 2
2
s y  100 ˆj
 
r  400i  100 ˆj
7. V  V1  V2
4 4 4
 R 3   R13   R23
3 3 3
R  3 R13  R23
8. Maximum KE  TE  PE min
1 2
or kA  9  5
2
4 2
k   8 10 4 N / m
0.012
m 2 
Time period T  2  2 4
 s
k 8 10 100
9. When two capacitors with capacitance C1 and C2 at potential V1 and V2 connected to each other by
wire, charge begin to flow from higher to lower potential till they acquire common potential. Here,
some loss of energy takes place which is given by
C1C2
Heat loss, H  (V1  V2 ) 2
2(C1  C2 )
In the equation, put V2  0, V1  V0
 C
C1  C , C2 
2
C
C
Loss of heat  2 (V  0) 2  C V 2
 C 0 6
0
2C  
 2
1
H  CV02
6
5 V
10. potential gradient   P
1000 1200
VP  6V
VP 6
and RP    100 
I 60  103

11. Mass of object remains same

Weight of object  acceleration due to gravity
W( earth ) 9 g ( earth )
 
W( planet ) 4 g ( planet )
2 2
9 GM ( earth ) R ( planet ) M ( earth ) R ( planet )
    
4 GM ( planet ) R 2( earth ) M ( planet ) R 2 ( earth )
R 2 ( planet ) R 2 ( earth ) R
 9 2
 R 2 ( planet )  
R ( earth ) 2 2
 tR
12. i  i0 (1  e l
)
 tR
20
i0  i0 (1  e l )
100
 tR
5
2
e
2
t ln 5
R
0  103
t (1.6)
0.1  0.9
t  0.016 sec
 
p
13. Electric field due to dipole on equitorial plane, E   k 3
r
 
p
At point P, FP  k 3 Q …(i)
y
  
 p 
At point P , FP    k 3
Q …(ii)
 ( y / 3) 
From equation (i) and (ii),
  
FP  27 FP  27 F
 A  m 
sin  
14. Given  m  A, as    2 
 A
sin  
2
 A A
sin  
  2   2 cos A
 A 2
sin  
2

 A  2cos 1  
2
hc
15. k1  

2hc 3hc
k 2  3k1     3
 
hc
so 2 

hc
so  
2
h h h2
16.   k
p 2mk 2m 2
hc
But, 0 
k
2mc 2
From equation (i) and equation (ii) 0 
h
17. Given circuit is a balanced wheatstone bridge circuit, hence it can be redrawn as follows
e 2 10
E (l )    0.4  0.16V
( R  Rh  r ) L 10  40  0 1
 T 
18.   1  2 
 T1 
1  T2 
 1  
6  T1 
T2 5 6T
  T 1  2 ........(1)
T1 6 5
1  T2  62 
 1   ............(2)
3  T1 
From eqn (1) and (2)
 T2  310 K and T1  372 K

19. Using, sin max  12  22

Here, 2  1
sin    2  12    1  sin 2 
mv 1 2 2K
20. Radius, r  K  mv ; v 
qB 2 m
2 Km
So, r 
qB
Here, K and B are same for all, then r  m / q
For He atom, m  4m p and q  2 p
 re  rp  rHe
21. The given situation can be drawn graphically as shown in the figure. Work done = Area under F-x
graph = Area of rectangle ABCD + Area of trapezium BCFE
1
W  (200 15)  (100  200)  15  3000  2250
2
W  5250 J
  
22.   r  F
 [(2  2)iˆ  (0  3) ˆj  (0  4) kˆ ]  [4iˆ  3 ˆj  4kˆ ]
 16 ˆj  12kˆ
 16 2  12 2  20 units
23. Given, temperature of oxygen molecules, T = 27°C
Pressure of oxygen
RT
lmean 
2 d 2 N A P
1.38  300 1023

2  3.14  (0.3  109 ) 2 1.01 105
 102 10 9 m  102 nm

24.

E
i
R V
  E 
V  R
 Rr 
E (5)
1.25  ........(1)
5 V
E (2)
1 .............(2)
2 V
From eqn 1 & 2
3 5
E 
2 10
value of x  15
XC  X L
25. tan 45 
R
XC  X L  R
1
L  R
c
1
 (300)(0.03)  1
c
1 1
 10 c
c 10  300
1
c  103
3
2 m
26. Pitch  (v cos  )T and T 
qB
2 m
 Pitch  (v cos  )
qB
2  1.67 1027 
 (4 105 cos 60)    4 cm
0.3  1.69 10 19 
t 25
27. t1/ n  5
n 5
210 4 206
28. 84 Po 2 He 82 Pb

Q  (209.982876  4.002603  205.97455)C 2

 5.422 MeV
From conservation of momentum
 K1  5.319 MeV  5319 KeV
29. According to question, when n diode is forward biased

Vdiode  0.5V
Safe limit of current, I  10mA  102 A
 Rmin  ?
Voltage through resistance
VR  1.5  0.5  1 volt
iR  1( VR )
1 1
 Rmin   2  100
i 10
AM 20
30. Modualtion index    1
AC 20

CHEMISTRY
31. Conceptual

32. Nylon 6, 6 is used in making bristles for brushes

3
33. (i) In  MnCl6  - central metal has 4 unpaired electrons.

3
(ii) In  CoF6  - central metal has 4 unpaired electrons

3
(iii) In  FeF6  - central metal has 5 unpaired electrons.

3
(iv) In  Fe  CN 6  - central metal has 1 unpaired.

34. Zinc – Galvanising Iron

Cast iron – railway sleepers
Nickel steel – measuring Tapes
Chrome steel – Crushing Machines
35.

NH 2 N 2 Cl

A: B: C: NN OH

P – hydroxylazobenzene (Orange dye)

36.

Species N2 N 2 N 2 N 22
Bond order 3 2.5 2.5 2
N 2 and N 2 has same bond order but N 2 has more number of anti bonding electrons so less stable.

37. CH 3  F :1.847 D ; CH 3  Cl :1.860 D ; CH 3  Br :1.830 D CH 3 I :1.636 D

38. ClO 4 forms ‘4’ canonical forms.

39. CrO72  CrO 42  No change in O.S. of chromium.

40. Vanishing cream (O/W) emulsion

Butter - (W/O) emulsion
Cell fluids – Solid in liquid Type of colloids
Whipped cream – Gas in liquid type of Colloids
41. Oxygen forms covalent hydride.

O
||
42. ‘P’ is CH 3  C  H

43. C is Aspirin  It inhibits the synthesis of a chemical known as prostaglandins which stimulate
inflammation in the tissue and cause pain.

44. (a) 4 LiNO3  2 Li 2O  4NO 2  O2


Paramagnetic gases

(b) In NaHCO3 , HCO3 ions are linked into a polymeric chain.

(c) K – metal gives violet colour to flame.

(d) Csaq  is a good conductor in aqueous solution with more mobility.

45.

OH


H

1700 C


46. Order of basic strength is  C2 H5 2 NH   C2 H5 3 N  C2 H 5 NH 2  NH 3

47. Bond order in N 2 is 3.

O22   1

O 2  1.5

CN   3

CO32   1.33

48. A  Butyl butanoate.

 B  Butanoic Acid

C  Butanol – 1
49. Solar radiation is not responsible for ozone layer depletion.

50. A : SiF4  4H 2 O  H4SiO4  4HF

0
1000 C
B : H 4SiO 4   SiO 2  2H 2O

C : SiO 2  Na 2 CO 3 
 Na 2SiO 3  CO 2

51. Cm (96)

Outer electronic configuration is 5f 7 6d1 7s 2

 Cm 3  5f 7
52. 4.523 + 2.3 + 6.24 = 13.063

As 2.3 has least no.of decimal places i.e., one.

Therefore sum should be reported to one decimal place only.
After rounding off reported sum = 13.1.
 no.of significant figures = 3.

53. If n = 3, total number of electrons  2n 2 =  2  32  18

Out of 18, 9 electrons have ms  1  2  and 9 electrons have ms   12  .

54.

H
|
CH 3  C CH 2  CH 3
|
CH 3
Isopentane

H H Br
| | |
Br  CH 2  C* CH 2  CH 3 CH 3  C C* CH 3
| | |
CH 3 CH3 H

Number of chiral carbon atoms = 2

Optically active isomers = 4.

55. As the concentration is reduced to half, t1/ 2 is doubled, so the order of the reaction is 2.

56. N1V1  N 2 V2
 (axalic acid) =  KMnO4 

N1  M1  n  factor   0.1 M  2  0.2 N

N 2  M 2  n  factor   0.1 M  5  0.5 N

0.2  V1  0.5  20

0.5  20
V1   50 ml
0.2
57. In an open vessel PV is constant

n1T1  n 2 T2

 3
1 300  1   T2
 5

2
300   T2
5

 T2  750K  750  273  477 0 C

58. H  H P  H R

3C 2 H 2  C 6 H 6

H  85  3 230 

= - 605 kJ (magnitude is 605)

0.059 1
59. E  Eo  log 
n H 

0.059
0.177  0  log  H  
1

log  H    3

 pH   log  H  

= - (-3) = 3.
   
60. : F X e  F :

MATHEMATICS
2
61. Det value   tan x  2 x  tan x  x   0
 tan x  2 x and tan x  x
 Draw the graphs
In the given interval 2 solutions possible
n n  n  1 2
62. Use 1  x   1  nx  x  .........  2  (small positive)  3
2
nP
63. r
 r!  6  r  3
nCr
nP  504  9.8.7  n  9
3

64.  x  n   x for n  z
 f  x   100  x

f  3   100  0.732   73.2

 f  3    73
 
45  r r
65. Tr 1  45C  4  5  7 10
r
For rational terms
r  0,10, 20,30, 40
No of irrational terms  46  5  41
66.   p  q   p   q
dy xy 1
67.  
dx x  1 x  1
I.F= e  x  x  1
G.S is y.e  x  x  1  e  x  c
1
 0, 1  C  0  y 
x 1
1  2 n1n2 2
68. 2  2
 n1 1  n2 2   x1  x2  
n1  n2 n1  n2 
 a  b sin  
69. f    log   is odd function
 a  b sin  
70. n  s   216
5 5 5 125
P  x  0  . . 
6 6 6 216
1 5 5 3! 75
P  x  1  . . . 
6 6 6 2! 216
1 1 5 3! 15
P  x  2  . . . 
6 6 6 2! 216
1 1 1 1
P  x  3  . . 
6 6 6 216
1  75  2  15  3  1
Mean   xi P  X  xi  
216
 108 1
 
216 2
4
1 6
71. T5  T41  10C  x     210 x 2
4 x
6
1 210 4
T7  10C  x
 x   x2
 
6

 1 
K  210  x 2  2   210  2   420
 x 
1
72. Circle passes through focii of ellipse. Area of  ABC  2ae.b  abe
2
 x2  1
73. g   x    g  x  and  0
 P 
74. For t  0, x  t , y  2t 2  y  2 x 2
t  0, x  3t and y  0
75. 1  sin 360  sin180  cos180
76. Let the required line be L1   L2  0
2 2 2 2
77. a  b  a b   a .b   116   4  12
dy 3x 2
78. y2  x3 and 
dx 2 y
h2 dv 2a
79. r2   a2 and  0  h 
4 dh 3
80. f  0   f  0 

2
81.  x  2  y2  9
2 2
 x  2    y  3  16 where z  x  iy
Equation of radical axis is S |  S  0  3 y  1  0
n 1
82. a.c0   a  d  .c1   a  2d  .c2  .......   a  nd  .cn   2a  nd  2 
a bc  0 
83. 2 2  take a  0, b  1, c  1
2
a  b  c  2
3 1
84. p ;q
4 4
P  X  1  0.99  1  P  X  0   0.99
1
1  nC p 0 q n  0.99   0.01
0 4n
 4n  100  n  4,5,6,......., 
 dy y  y
85.   cos 2  
dx x x
dx
y  vx   sec 2 v.dv   
x
 y
 tan     log x  c
 x
 
1,   c  1
 4
 y e
 tan     log x  1  log  
 x x
  e 
y  x tan 1  log   
  x 

x  e  y  e tan 1  0   0
86. 15C  15C
2 r 2 r 2

2 r  2  r  2  15  r  5
87. Use cos  A  B  cos  A  B   cos 2 A  sin 2 B
88.  AB AC AD   0
 
x y z x 1 y 1 z  2
89.   and  
1 1 1 2 3 1
2 2
90. a  c  b  c  a  b  2c