Professional Documents
Culture Documents
(1) (2)
(3) (4)
[P] is prepared by controlled hydrolysis of [Q]. [P] & [Q] are respectively.
(1) Linear silicone, CH3SiCl3 (2) branched silicone, (CH3)3SiCl
(3) Cyclic silicone, (CH3)2SiCl2 (4) Cyclic silicone, CH3SiCl3
10. Which of the following is not a property of silicones ?
(1) They are combustible
(2) They are water - repellant
(3) They are polymeric liquids or solids
(4) Their viscosity does not change significaltly with rise in tamperature.
11. Tourmalene is a class of cyclosilicates with general formula.
(Ca, K, Na) (Al, Fe, Li, Mg, Mn)3 (Al, Cr, Fe, V)6 (BO3)3 (Si, Al, B)6O18 (OH, F)4
Which of the following is not a correct example of tourmalene ?
(1) CaAl3Fe6(BO3)3 S6O18F4 (2) Ca2Li3V6(BO3)3 Si6O18(OH)4
(3) KMg3Cr6(BO3)3 Si6 O18 F4 (4) CaAl9 (BO3)3 Si6O18 (OH)4
12. The silicate anion in the mineral kinoite is a chain of three SiO4 tetrahedra, that share corners with
adjacent tetrahedra. The charge of the silicate anion is :
(1) –4 (2) –8 (3) –6 (4) –2
13. The dehydration of malonic acid CH2(COOH)2 with P4O10 gives :
(1) carbon monoxide (2) carbon suboxide (3) carbon dioxide (4) all three
14. Borax on heating with cobalt oxide forms a blue bead of :
(1) Co(BO2)2 (2) CoBO2 (3) Co3(BO3)2 (4) Na3Co(BO3)2
15. The dissolution of Al(OH)3 by a solution of NaOH results in the formation of :
(1) [Al(H2O)4(OH)]2+ (2) [Al(H2O)2(OH)4]– (3) [Al(H2O)3(OH)3] (4) [Al(H2O)6(OH)3]
18. Match List (Fuels) with List II (composition) and select the correct answer using the codes given below
the lists :
List I (Fuels) List II (Composition)
(1) Water gas i. A mixture of CO and N2
(2) Producer gas ii. Methane
(3) Coal gas iii. A mixture of CO and H2
(4) Natural gas iv. A mixture of CO, H2, CH4 and CO2
(1) (2) (3) (4) (1) (2) (3) (4)
(1) iii i iv ii (2) iii i ii iv
(3) i iii iv ii (4) iii ii iv i
19. Water transported through lead pipes becomes poisonous due to the formation of:
(1) PbO (2) PbO2 (3) Pb(OH)2 (4) Pb3O4
20. When steam is passed over red hot coke, the outgoing gas contains –
(1) Producer gas (2) Water gas (3) Coal gas (4) None of the above
21. In BF3, the B-F bond length is 1.30 Å, when BF3 is allowed to be treated with Me3N, it forms an adduct,
Me3N BF3, The bond length of B-F in the adduct is :
(1) Greater than 1.30Å (2) Smaller than 1.30 Å
(3) Equal to 1.30 Å (4) None of these
22. Aluminium is extracted by the electrolysis of :
(1) alumina (2) bauxite
(3) molten cryolite. (4) alumina mixed with molten cryolite
23. A compound of boron X reacts at 200ºC temperature with NH3 to give another compound Y which is
called as inorganic benzene. The compound Y is a colourless liquid and is highly light sensitive. Its
melting point is –57ºC. The compound X with excess of NH3 and at a still higher temperature gives
boron nitride (BN)n. The compounds X and Y are respectively :
(1) BH3 and B2H6 (2) NaBH4 and C6H6 (3) B2H6 and B3N3H6 (4) B4C3 and C6H6
24. For given processes, choose the correct order of purity of silicon obtained.
I. SiO + 2C Si + 2CO
2
Ans.
Que. 11 12 13 14 15 16 17 18 19 20
Ans.
Que. 21 22 23 24 25 26 27 28 29 30
Ans.
3.
6.
7.
14. How many of the following parameters/properties are greater for diamond as compared to graphite?
Denisty, Electrical resistivity, Thermal conductivity, Stability, % s-character for hybridised orbitals,
Hardness, Bond angle, C–C (bond length), Standard enthalpy of formation.
15. Na2B4O7 NaBO2 + B2O3
NaBO2 + H2O2 + H2O compound A(aq)
The compound A the sum of oxidation states of all the oxygen atoms is X. Then the value of |X| is
16. A Boron mineral have pentaborate anion whose molecular formula is [B5O6(OH)4]–. The number of B–
O–B linkage present are.......
17. Consider the following sequence of reactions :
B2O3 + CaF2 + H2SO4 (A) + (B) + H2O
(A) + LiAlH4 (C)(g) + (D) + LiF
(C) + H2O (D) + H2
(D) + Na2CO3 (E) + NaBO2 + CO2
(E) + NH4Cl (F) + B2O3 + NaCl + H2O
What is the empirical formula mass of compound (F) ?
18. How many of the following statatment are correct ?
(1) CF4 can be prepared by reaction between SiC and F2.
(2) In SiF4 Si–F observed bond length is shorter than actual Si–F bond length
(3) (C2F4)n is known as PTFE.
(4) CCl4 react with Anyelrony HF, gives Chloro Flouro carbon (CCl2 F2)
(5) CCl4 can hydrolysis under super heating conditious.
(6) Hydrolysis of SiF4 is not complete of SiF4 is partially hydrolysis.
19. How many of the following may react with SiCl4 to produce a non-polar product ?
NaH, CH3MgCl, H2O, LiAlH4, H2SO4(l), NH3, Be
22. Compound S is :
(I) an odd-e– compound (II) (2C – 3e–)
(III) an electron deficient compound (IV) a sp2 hybridized compound
Choose the correct code :
(A) III (B) I, III (C) II, III, IV (D) I, II, IV
Ans.
Que. 11 12 13 14 15 16 17 18 19 20
Ans.
Que. 21 22 23
Ans.
p-Block Elements (B & C family)
ANSWERS
PART - I
11. (1) 12. (2) 13. (2) 14. (1) 15. (2)
16. (4) 17. (4) 18. (1) 19. (3) 20. (2)
21. (1) 22. (4) 23. (3) 24. (2) 25. (4)
26. (4) 27. (4) 28. (4) 29. (4) 30. (3)
PART - II
6. (AB)
PART - III
SOLUTIONS
PART - I
1. The EN values of Carbon family are :
Element C Si Ge Sn Pb
EN 2.5 1.8 1.8 1.8 1.9
4.
5. A is B2H6
p-Block Elements (B & C family)
B2H6 + 6 NaOH 2 Na3BO3 + 6 H2
B is Na3BO3 a salt of SBWA.
6. 2PbCO3.Pb(OH)2 Pb3O4 + CO + CO2 + H2O
PART - II
1270 K
1. (B) 2BCl3 + 3H2 2B + 6HCl
1173 K
(C) 2BCl3 B + 3Cl2
Hydrolysis Hydrolysis
4. (B) BCl3 + 3H2O H3BO3 + 3HCl ; SiCl4 + 3H2O H2SiO3 + 4HCl
(C) B + Mg Mg3B2 + H3PO4 Mix of borones B2H6
(D) 2B + 6NaOH 2Na3BO3 + 3H2 ; Si + 4NaOH Na4SiO4 + 2H2
6. (A) Both hardness can be removed by it.
(B) Zeolite : Na2Al2Si2O8.xH2O
PART - III
1. Statements (A), (B), (D) are true.
Statement (C) SnO2 is amphoteric, Ga2O3 is amphoteric.
3.
4. X : B2H6 Y : H2
NaBH4 + I2 B2H6 + H2 + 2NaI
B2H6 + C2H5OH H2 + B(OC2H5)3
B2H6 + HCl H2 + B2H5Cl
5. B2X6 + 2NH3
10.
11. (A) All 13th group elements forms trihalide even Tl+ as TlI3 BX3 AlCl3, GaCl3 InCl3 Tl+ (I3)– tri iodide ion.
(B) At high temparature only Al react direelly with N2 and gives AlN
(C) Conc. HNO3 is oxidising agent, It forms an oxide layers on Al surface, this makes al passive
towards conc. HNO3.
(D) Except Pb, all 14th group element forms MX4 tetrahalides.
12. Combustion of silicone produces solid silica.
13. Zeolites can exchange cation to release more soluble cation in aqueous solution.
14. Density, Electrical resistivity, Thermal conductivity, Hardness, C – C (bond length), Hfº.
16.