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The Evolution of Søderberg Aluminum Cell Technology in North and South


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DOI: 10.1007/s11837-013-0855-1

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JOM, Vol. 66, No. 2, 2014
DOI: 10.1007/s11837-013-0855-1
Ó 2014 The Minerals, Metals & Materials Society

The Evolution of Søderberg Aluminum Cell Technology in North


and South America

MIKE BARBER1 and ALTON T. TABEREAUX2,3

1.—2468 Wyndale Crescent, Ottawa, ON K1H 7A6, Canada. 2.—1585 Wilson Lake Shores, Muscle
Shoals, AL 35661, USA. 3.—e-mail: attaber@aol.com

In the 1940s, the horizontal stud Søderberg cells were considered to be


superior to the small 30-kA Hall prebake cells, which at that time operated at
a lower current efficiency and higher energy consumption. The amperage was
first increased on the Søderberg cells from 30 kA to 50–60 kA and then later to
90–120 kA by basically increasing the anode length and the number of anode
studs. Due to the increase in demand for aluminum metal, the less expensive
Søderberg smelters proliferated in the 1940s to the 1970s in North and South
America. In the 1970s, 24 Søderberg smelters located in North and South
America had a primary aluminum capacity over 3 million tpy. The largest
operating Søderberg smelter, Companhia Brasileira de Aluminio, has a plant
capacity over 470000 tpy and started the last new Søderberg potline in 2007.
However, poor magnetics inherent with end-to-end Søderberg cell busbar
design limited any further increase in amperage while the side-to-side pre-
bake cells were able to operate more efficiently at 200 kA and higher. Com-
pared with prebake technology, Søderberg cells are now less efficient and have
higher production costs, they are more difficult to automate and they have the
greatest environmental and health challenges. Health studies from the middle
of the 1970s showing a clear link between Søderberg tar fume exposure and
the incidence of various types of cancer lead companies to propose a program
of replacement. As a result, today there are only five Søderberg smelters
operating in North and South America with a capacity of <1 million tpy.

INTRODUCTION proved to be difficult, and by 1937 the design had


been changed to a single anode.2 The horizontal
The continuous self-baking Søderberg anode was
stud Søderberg (HSS) cell was such a success that
seen as a major advancement for the electrometal-
17 plants worldwide were built using the new
lurgical industry when it was invented by Carl W.
technology by 1937. At this point, the electrical
Søderberg in 1918. The first Søderberg anodes in
current in Søderberg cells had increased to about
aluminum cells in the early 1920s had a circular
30 kA.
cross section, but operational difficulties with this
In the early years, Søderberg-type pots had a
configuration led to the development of rectangular
number of advantages over prebake cells, including
anodes in the early 1930s. The real starting point of
the following:
the Søderberg revolution for use in aluminum elec-
trolysis cells came in 1931 at the Pechiney alumi-  Cost savings have been linked to anode prepara-
num smelter at Riouperoux, near Grenoble in tion including both reduced capital costs for the
France. This cell had two Søderberg anodes with anode plant (no forming, baking and rodding
horizontal studs, or conducting pins, and it operated facilities are required), as well as reduced oper-
initially at 22 kA although Torchet1 claimed to have ating costs.
operated pots at up to 60 kA in his patent applica-  The Søderberg anode plant is much simpler to
tion. The plant also developed a hooding system for build; therefore, a smelter can be brought into
improved gas collection and working conditions. The operation quickly.
operation of a cell with two Søderberg anodes  Anode plant production has greater flexibility; it

(Published online January 3, 2014) 223


224 Barber and Tabereaux

is easy to start small and later to scale up return recommended 40-kA HSS lines to be built at
production. Arvida and Shawinigan smelters. By 1938, two
 No handling and cleaning of hot anode butts is potrooms at Arvida and one potroom at Shawinigan
required. were operating HSS cells at 40 kA. The results must
 There is no need to handle large amounts of anode have been good because in the following year, the
crust material or to prepare anode cover material. decision was taken to build a 42-kA potroom at
 Fewer disturbances of cell heat balance occur due Arvida.
to changing anodes. Early Hall prebake cells were
difficult to operate due to the large number of
anodes to change, up to 65. THE SECOND WORLD WAR
 VS Søderberg cells were easier to apply gas skirts The critical moment in the expansion of
to collect pot fumes compared with early prebake Søderberg technology occurred with the outbreak of
cells which initially had no cell hooding.3 WW II on September 3, 1939 as it almost immedi-
ately created a huge new demand for aluminum. In
THE EARLY YEARS: 1930s to 1940s both Canada and the United States, planners real-
ized that new production facilities would have to be
The Søderberg self-baking anode was first dem- built as quickly as possible to supply the military
onstrated in aluminum cell tests made in the plant needs for the war.
of the Aluminum Company of America (Alcoa) at
Baden, NC in 1924. The test was abandoned due to
its higher energy consumption and impurities com- Alcoa, Reynolds, and Kaiser Aluminum
pared with prebake cells. The first potline of Companies
Søderberg cells in the United States started oper-
ating at Alcoa Tennessee smelter in Maryville, TN In the 1940s, the U.S. federal government
in 1927. These Søderberg cells had one round embarked on a program that expanded aluminum
(221 cm diameter) Søderberg anode electrode as production capacity twofold over the next 4 years to
well as a circular (290 cm) cathode (shown in meet the demands of the military. The government-
Fig. 1). The operational performance of these round owned Defense Plant Corporation (DPC) spent more
Søderberg cells proved to be not competitive with than $180 million on nine aluminum reduction
the improved Hall prebake cells at that time, and plants between 1941 and 1945, some of which were
thus, they were shut down after a very brief period. operated by Alcoa and the others operated by
No more Søderberg cells were built in the United industry newcomers. During the war years, the
States until 1939 when Alcoa built a potline of aluminum capacity was split roughly evenly
40 kA HS Søderberg cells at the Tennessee plant. between Søderberg and prebake aluminum smelt-
The first HS Søderberg cells were introduced to ers. In 1946, the government-owned Søderberg
Canada in 1936 when two prototype HSS cells were plants were first leased and later sold to Reynolds
tested at the Alcan Arvida. The cells ran success- (Longview and Listerhill smelters) and Kaiser
fully, and the following year, half a potline of HSS (Tacoma smelter).
cells was built that operated at 30 kA. In the same The combined annual production of the initial
year, an Alcan expert visited Europe and on his four Søderberg smelters (14 potlines and 1927 cells)
in the United States in the 1940s was 218000 tonnes
per year. A summary of the key performance indi-
cators (KPI) is provided in Table I. for the early
Søderberg cells in the United States during the
1940s:
 The HS Søderberg smelters initially started
operating at 40 kA; in the 1950s, the HSS cell
anodes were enlarged and the potline amperage
increased to about 50 kA. In the 1960s, the potline
amperage at Reynolds Longview smelter was
increased to 70 kA.
 The average annual production capacity per
potline was 15000 tonnes.
 The average energy consumption was 18.5 kWh/
kg Al.
 The average current efficiency was 84.9%.
 The HS Søderberg potlines at Reynolds Listerhill
(shown in Fig. 2) operated for 43 years, the HS
Søderberg potlines at Tacoma operated for
Fig. 1. Circular Søderberg cathodes at the Alcoa Tennessee smelter 53 years, and the HS Søderberg potlines at
pre-1940 (Source: Alcoa). Longview operated 60 years.
The Evolution of Søderberg Aluminum Cell Technology in North and South America 225

Table I. The first four Søderberg aluminum smelters in United States in the 1940s

Startup Closure Pot Lines Cells 1940s 1970s Capacity, kWh/ CE Pot Studs
Company Location date date Years type # # kA kA tpy kg % V #
Alcoa Alcoa, TN 1939 1946 7 HSS 3 360 43 50 38676 19.3 85.0 5.50 18
Alcoa Alcoa, TN 1946 1975 29 VSS 3 360 43 60 37766 19.0 83.0 5.30 24
Reynolds Longview, WA 1941 2001 60 HSS 3 372 43 70 40440 18.0 86.0 5.19 30
Reynolds Listerhill, AL 1942 1985 43 HSS 3 595 43 55 63931 18.2 85.0 5.20 20
Kaiser Tacoma, WA 1947 2000 53 HSS 2 240 50 60 38000 18.1 85.5 5.20 20
Total 192 14 1927 218813
Average 44.4 18.5 84.9 5.28 22.4

Fig. 2. Operator breaking the side crust of a 40-kA HS Søderberg


cell at the Reynolds Listerhill smelter (Source: Reynolds Aluminum).

Alcan Aluminum
Before 1940, Alcan only had 10 prebake and
Søderberg potlines in operation 6 potlines in Arvida
and 4 old potlines in Shawinigan, with a total pro- Fig. 3. HS Søderberg potlines at the Alcan Arvida aluminum smelter
duction of only 75000 tonnes. They did not have in 1943 (Source: Rio Tinto Alcan).
enough operating experience with the new 40-kA
HS Søderberg cells at this point, so the first phase of
production increased was achieved by building six
potlines of 42-kA prebake cells in 1940. Work on the
Søderberg cells continued and by 1941, when the
greatest expansion in war-time aluminum started,
the technology was considered to be mature.
Søderberg technology was thought to be better
adapted to rapid expansion as the anode plant
requirements were much simpler. So when the call
came to increase production for the war effort, Alcan
responded by building 21 potrooms of Søderberg
cells (shown in Fig. 3) during the 1941–1943 period
that operated at 42–45 kA except for the last line
built at Isle Maligne, which operated at 50 kA, the
highest achieved by Alcan at this point. The 15 HS
Søderberg potlines at Arvida, including lines 46–57,
lines 22 and 23, and line 26 (lines 22 and 23 had
been combined into a single potline). Isle Maligne
had one HS Søderberg potline (shown in Fig. 4).
In the early 1940s, the combined annual produc-
tion for the five Søderberg smelters (24 potlines and
3775 cell) in Quebec was initially around 300000 Fig. 4. Operator breaking the side crust of a HS Søderberg cell at
tonnes per year of which all were produced with the Alcan Isle Maligne smelter (Source: Rio Tinto Alcan).
226 Barber and Tabereaux

energy from hydroelectric generating stations. Alu- Vertical stud Søderberg (VSS) technology was
minum production continued to increase with eventually developed to operate Søderberg cells at
higher amperage and modernization. higher amperages, e.g., >100 kA. They had longer
The KPIs are shown in Table II for the early anodes with additional steel studs and required
Søderberg cells during this period in Canada: costly overhead cranes to plant and pull studs. VSS
plants were also seen as having better working
 In the 1940s, the Søderberg potlines initially
conditions.
operated 42–45 kA; the HSS cells were modern-
Plans were made for further expansion and for
ized in the 1960s with amperages up to 68 kA.
operating cells at a much higher current. Pechiney,
 The annual production of the 15 potlines at
Balco, Reynolds, and Elektrokemisk had started
Arvida during this period was around
working on improving VSS cell technology in the
200,000 tonnes/year, or 14,000 tonnes per potline.
late 1940s, attempting to reach 100 kA. In 1949,
 The average energy consumption was high,
Alcan built and tested a VSS cell at Arvida operat-
18.5 kWh/kg Al.
ing at 42 kA. The test cell worked well and an
 The average current efficiency was 84%.
audacious plan was made to scale up the current in
 The oldest Søderberg potlines at Beauharnois,
cells by a factor of more than two, aiming for
Shawinigan and Arvida operated from 63 years to
100 kA. This design was used in 1952 at Isle
72 years.
Maligne. The first half line started in May 1952, but
Unfortunately, the boom did not even last until the immediately it ran into severe operating problems
end of the war. By early 1944, it was evident that due to unexpected magnetic problems. The pot had
aluminum production had exceeded demand as been built with a single-entry busbar (like all the
ingots started to pile up in the smelters. Arvida earlier, smaller cells). The busbar design had to be
alone had a stockpile of 60000 tonnes. By April modified to a double-entry symmetrical arrange-
1944, Alcan had started to shut potlines in Arvida, ment before the second half of the line was built,
but still the ingots accumulated. At the end of 1944, and this modified cell design was used for the new
Alcan had closed 15 potlines in Arvida, 3 potlines in smelter at Kitimat BC in 1954.4 Unfortunately, the
Shawinigan and the entire plants at Beauharnois modifications were not a complete success as potline
and La Tuque were closed; La Tuque was closed 405 was closed in 1976 and potlines 1 and 2 in
permanently. And still the cut-backs continued; Kitimat probably have the highest specific energy
before the end of 1945, Shawinigan was completely consumption of any pot in the world. When potline
shut down including the original Hall prebake cells, 405 closed, it was running at 82–83% current effi-
and five additional potlines in Arvida were shut ciency. The operating problems in Kitimat were so
down. Alcan’s annual production was at that time severe that it was decided to change technologies for
similar to what it had been at the start of the war. the second stage of construction.
Alcan representatives visited the Pechiney alu-
THE GOLDEN YEARS: 1950 TO 1970 minum smelter at Saint Jean-de-Maurienne,
France and saw the operation of their 100-kA VSS
Canada
pots. The operation was so much better than Kiti-
By 1946, signs of economic recovery were grow- mat potlines 1 and 2 that the decision was taken to
ing, and Alcan, slowly at first, but then with use the Pechiney VSS cell technology for the rest of
increasing haste, started activating their closed the Kitimat potlines. Thus, Kitimat potlines 3, 4,
capacity. Amazingly by early 1949, all the shuttered and 5 were started in 1955–1956, using the 100-kA
capacity had been started, and still the demand for VSS design, but with the potline amperage at
aluminum increased. 105 kA. The current was increased to 125 kA in the
Prior to this period, the majority of HS Søderberg late 1960s following a program to widen the anodes
potlines operated at 42–45 kA, and stud planting from 80 in. to 100 in. (from 203 cm to 254 cm). Cell
and pulling was done manually with simple devices. start-up of a 125-kA VSS cell is shown in Fig. 5 and

Table II. The first five Søderberg aluminum smelters in Canada in the 1940s

Startup Closure Pot Lines Cells 1940s 1970s Capacity, kWh/ CE Pot Studs
Company Location date date Years type # # kA kA tpy kg % V #
Alcan Arvida 1941 2004 63 HSS 15 2000 43 62 212365 18.6 84.0 5.25 26
Alcan Schawinigan 1/1942 2014 72 HSS 4 536 43 68 57591 18.4 85.0 5.25 26
Alcan Beauharnois 1/1943 2009 66 HSS 2 268 43 68 28626 18.5 84.5 5.25 26
Alcan Tuque 11/1942 1944 2 HSS 2 268 40 42 26156 18.9 83.0 5.25 26
Alcan Isle Maligne 7/1943 2000 57 HSS 1 134 43 62 14400 18.1 85.0 5.15 26
L 403
Total 260 24 3,206 339138
Average 52.6 67.6 18.5 83.9 5.20 30.9
The Evolution of Søderberg Aluminum Cell Technology in North and South America 227

tapping metal from a VSS cell at the Kitimat


smelter is shown in Fig. 6.
There followed a lull in construction activities due
mostly to unfavorable economic conditions. The last
potlines 7 and 8 at Kitimat were built from 1964 to
1967 using essentially the same cell design that had
been used in lines 3–5. The first building, 8B, was
started with smaller anodes, but the next two
buildings, 8A and 7B, were started with wider
Søderberg anodes. These were to be the last new
Søderberg potlines to be built in Canada.
In the 1960s, a major program was undertaken in
Quebec to modernize and improve the productivity of
the HSS cells. The anodes were widened from 106 cm
to 157 cm and the current was boosted from 42 kA up to
Fig. 5. Pot startup of a VS Søderberg cell at the Kitimat smelter
(Source: Rio Tinto Alcan).
60 kA. This represented a 40% increase in productiv-
ity. For the 23 HS potrooms in Quebec, that amounted
to nearly 140,000 extra tonnes per year. As well,
improvements were made in pot-tending equipment
and better ventilation and gas scrubbing systems.
At the same time, British Aluminium was build-
ing a VSS aluminum smelter at Baie Comeau Que-
bec. The first potline started operation at the end of
1957 with a capacity of nearly 50,000 tonnes per
year. It used the same 100-kA pot that BACO
started at Lochaber, Scotland.
The combined annual production of the Søderberg
smelters at Kitimat and Baie Comeau (9.5 potlines
and 1454 cells) in the 1960s was about 445000 ton-
nes per year as shown in Table III.
 During this period, the Søderberg cells at Kitimat
and Baie Comeau operated from 105 kA to 135 kA.
 The average annual production capacity was
45,000 tonnes per potline at Kitimat and 55,000
tonnes per potline at Baie Comeau.
 The average energy consumption was high:
Fig. 6. Tapping metal from HSS cells at the Alcan Kitimat smelter 17.9 kWh/kg Al and Kitimat and 16.0 kWh/kg at
(Source: Rio Tinto Alcan). Baie Comeau.

Table III. Søderberg aluminum smelters started operation in Canada in the 1950s and 1960s

Startup Closure Pot Lines Cells Current Capacity, kW h/ CE Pot Studs


Company Location date date Years type # # kA tpy kg % V #
Alcan Isle Maligne 5/1951 2000 49 HSS 1 134 43 14400 18.1 83.0 5.15 26
L404
Alcan Isle Maligne 4/1952 1976 24 VSS 1 171 106 43694 19.1 82.0 5.25 60
Line 405
Alcan Kitimat L 1, 2 1954 2014* 60 VSS 2 342 105–113 99975 19.0 86.0 5.45 60
Alcan Kitimat L 3, 4, 5 1956 2014* 58 VSS 3 360 125–136 116413 18.6 86.0 5.40 58
Alcan Kitimat L 7, 8 1964 -1967 2010 46 VSS 1.5 210 126–135 68451 18.6 86.0 5.40 54
Reynolds Baie Comeau 1957 2014* 57 VSS 3 542 114 164383 15.8 90.5 4.80 54
Total 294 11.5 1759 507318
Average 121.9 18.0 87.1 5.30 52
*Planned.
228 Barber and Tabereaux

 The average current efficiency range was from minum availability for military purposes. The majority
86.0% to 90.5%. of the aluminum plants were built using Søderberg
 The Søderberg potlines at Kitimat have operated technology as at that time it was considered to offer
for 60 years and Baie Comeau operated 57 years, lower operating costs and a higher metal purity than
but both smelters are in the process of closing all the alternative choice, prebake cell technology. The
Søderberg potlines. atmospheric emissions from Søderberg cells were not a
concern at that time. Additionally, Søderberg cells were
From 1941 to 1980, when the prebake plant at
less costly than prebake cells, which require anode
Grande Baie, Quebec was built, Alcan had built no
baking furnaces as well as anode rodding facilities.
new prebake cells in Canada. It was not until 2000
All of these new smelters operated at higher
that Alcan’s prebake primary aluminum production
amperages, from 70 kA to 153 kA using longer HS
exceeded its Søderberg production.
or VS Søderberg anodes with additional steel studs.
The largest HS Søderberg cell ever developed was
United States
the 150-kA cells used at Reynolds Arkadelphia, AR,
The situation was the same in the United States as and Corpus Christi, TX, which had Søderberg an-
the aluminum industry’s cycle of rapid wartime build- odes that were 10 m in length (shown in Fig. 7).
up in the United States was repeated during the Kor- Most new smelters were located in regions of the
ean War in the 1950s. The United States government United States that had inexpensive hydroelectric
encouraged existing U.S. companies to construct addi- power, e.g., Tennessee Valley Authority (TVA) and
tional reduction plant facilities due to a deficit in alu- Bonneville Power Administration (BPA). However,
Alcoa Point Comfort, Reynolds Corpus Christi, and
Kaiser Chalmette smelters used natural gas to
generate electricity until they closed between 1982
and 1985 due to escalating costs for natural gas.
From 1951 to 1959, 1.16 million tonnes of primary
aluminum capacity was added from six new
Søderberg smelters in the United States: Reynolds
Corpus Christi, Reynolds Arkadelphia, and Reynolds
Massena; Martin Marietta Dales; Anaconda Colum-
bia Falls; and Alcoa Point Comfort. Potlines were
added at two existing smelters: Reynolds Longview
and Reynolds Listerhill as shown in Table IV.
The combined annual production of the Søderberg
smelters in the United States (39 potlines and 5252
cells) in the 1950s and 1960s was about 1500000
tonnes per year. A summary of the KPIs for the
Søderberg potlines built in the United States in
Fig. 7. A 150-kA side-by-side HS Søderberg cell at the Reynolds the 1960s and 1970s shown in Table V include
Arkadelphia smelter in the 1980s (Source: Reynolds Aluminum). the following:

Table IV. New Søderberg aluminum smelters in United States in the 1950s

Startup Closure Pot Lines Cells Current Capacity, kWh/ CE Pot Studs
Company Location date date Years type # # kA tpy kg % V #
Kaiser Chalmette, 1954 1983 32 HSS 8 1120 76 225000 16.6 90.0 5.01 36
LA
Reynolds Corpus Christi, 952 1982 30 HSS 2 280 143 73000 16.6 90.0 5.01 64
TX
Reynolds Arkadelphia, 1953 1985 32 HSS 1 160 153 62000 16.6 90.0 5.01 64
AR
Martin Columbia Falls, 1955 2009 54 VSS 2 240 108 69340 16.7 91.0 5.01 50
Marietta MT
Reynolds Longview, WA 1957 2001 44 HSS 3 504 102 138279 16.4 91.5 5.04 40
Reynolds Listerhill, AL 1958 1985 27 HSS 3 522 92 127059 16.6 90.0 5.01 32
Martin Dales, WA 1958 2000 42 VSS 2 300 108 82000 16.0 88.5 4.75 50
Marietta
Alcoa Point Comfort, 1959 1978 19 VSS 7 416 70 26000 17.0 88.0 5.01 32
TX
Reynolds Massena, NY 1959 * 54 HSS 3 504 92 123000 16.3 91.5 5.01 34
Total 334 31 4046 1159678
Average 104.9 16.5 90.1 5.00 44.7
The Evolution of Søderberg Aluminum Cell Technology in North and South America 229

Table V. New Søderberg aluminum smelters in United States in the 1960s

Startup Closure Pot Lines Cells Current Capacity, kWh/ CE Pot Studs
Company Location date date Years type # # kA tpy kg % V #
Anaconda Columbia Falls, 1965 2009 44 VSS 1 120 108 34670 16.7 91.0 5.01 50
MT
Kaiser Chalmette, LA 1967 1984 17 HSS 1 160 93 39000 16.6 90.0 5.01 36
Anaconda Columbia Falls, 1968 2009 41 VSS 2 240 108 69340 16.7 91.0 5.01 50
MT
Kaiser Tacoma 1968 2000 32 HSS 1 160 93 39000 16.6 90.0 5.01 40
Martin Goldendale, 1971 2003 32 VSS 3 526 122 168000 15.1 89.0 4.50 54
Marietta WA
Total 166 8 1206 350009
Average 104.8 16.3 90.2 4.90 46.0

 The majority of the Søderberg cells operated at soon by the construction of a new 96000-tpa VS
100 kA; two HS Søderberg plants operated from Søderberg plant at Poco de Caldas, Brazil, in 1970
143 kA to 153 kA. using Alcoa technology; a new 28000-tpa HS Søder-
 The average annual production capacity was berg potline at Aratu, Brazil, in 1970; and further
41000 tonnes per potline. expansions of VS Søderberg potlines by CBA in 1970
 The average energy consumption was high: and in 1977 and a third 26500-tpa HS Søderberg
17 DCkWh/kg Al. potline was built at Ouro Preto smelter in 1978.
 The average current efficiency was 90.2%. The combined annual production of the Søderberg
 The Søderberg potlines at Massena, NY, contin- smelters in the South America (18 potlines and 2676
ued to operate after 54 years, but it is currently is cells) in the 1990s was about 1244000 tonnes per
in the process of closing potlines. year. The KPI shown in Table VI for the Søderberg
cells during in South America were:
Further expansion of primary aluminum smelters
continued in the 1960s although at a slower pace as  Seventy-two percent of the Søderberg cells oper-
shown in Table VI. Two new Søderberg smelters ated >100 kA; VSS cells at Paranam smelter
were added by Anaconda at Columbia Falls, MT, operated at 160 kA.
and Martin Marietta at Goldendale, WA; additional  The average production per potline was 33000
Søderberg potlines were added at the Kaiser tonnes per potline.
Chalmette and Tacoma smelters.  The average energy consumption was 15.2 kWh/
kg Al with low values from 14.5 kWh/kg to
South America 14.9 kWh/kg Al at the CBA and Aratu smelter.
 The average current efficiency was 88.8%.
The primary aluminum industry has also taken  The VS Søderberg potlines at CBA and one HS
root in South America. A small smelter initially Søderberg potline at Ouro Preto are continuing to
owned by Elquisa started operations in Ouro Preto operate.
MG, Brazil, in 1945 using HS Søderberg technology
supplied by Elektrokemisk, but it closed in July
TECHNOLOGY IMPROVEMENTS
1946 due to financial problems. The smelter was
bought by Alcan in 1950 and was restarted in The amperage was increased in many Søderberg
August 1951 with a capacity of 1800 tpa. In 1956, potlines by increasing the anode area to reduce the
the production was expanded to 6000 tpa, and in cell resistance by making anodes wider or longer
1958, a second potline Reducao II with a capacity of and adding additional studs to cells. The relation-
23000 tpa was started using an HS Søderberg pot ship between Søderberg anode (bottom) area and
design from Alcan Arvida. In June 1955, a new VS amperage is in the range of 111000 cm2/cell per 100
Søderberg plant was started by Companhia amperes for VSS cells and 136000 cm2/cell per
Brasileira de Aluminio (CBA) located at Aluminio 100 kA for HSS cells (shown in Fig. 8); there are 42–
near Sao Paulo, Brazil, with a capacity of 10000 tpa 45 studs/cell per 100 kA. The average anode current
using Søderberg technology from Montecatini. density was 0.90 A/cm2 for HS cells and 0.74 A/cm2
By 1960, the region was ready for rapid expansion; for VS cells.
in 1963, a 65000-tpa VS Søderberg smelter was built Of the many technological improvements in the
at Vera Cruz, Mexico, using Alcoa technology; in Søderberg plants, one of the most significant was
1965, a 30000-tpa VS Søderberg smelter was built at certainly the introduction of lithium into the elec-
Paranam, Surinam, using Alcoa technology; and the trolyte chemistry. Interestingly, Charles Martin
VS Søderberg potlines at the CBA plant in Aluminio, Hall mentioned the possible use of lithium in his
Brazil, were expanded. These plants were followed 1886 patent.5 Starting in the 1960s, lithium was
230 Barber and Tabereaux

increasingly added (usually in the form of Li2CO3

Studs

4.65, 4.42 28, 30

2800, 30000 15.4, 14.9 88.2, 88.7 4.45, 4.42 32, 58

56.5
58

64
50

50
chips or pellets) to Søderberg cells to decrease their

#
fluoride emissions and increase current efficiency.
Although its use was often questioned in the alu-

4.34

5.00
4.80

5.18

4.50
Pot

minum industry, it was eventually used in all


V

Søderberg plants in Canada as well as all HS


Søderberg plants in the United States.
Lithium was used to reduce the vapor pressure
(along with reducing the AlF3 content in bath) and
88.5

89.0

88.0
88.0

91.3

88.8
CE
%

the liquidus temperature of the electrolyte and


thereby reduce the emission of fluorides from cells;
it gave reductions of 25–35% and thus allowed
23500, 26500 15.7, 14.9
kWh/

Søderberg plants to meet environmental regula-


14.5

16.9
16.3

16.0

15.2
kg

tions. In addition, lithium ions increased the elec-


trical conductivity of the electrolyte, which
permitted cells to operate at a wider ac-distance
Capacity,

and/or higher amperage with increased production.


1244170
472585

30000
65300

96000
tpy

A major disadvantage of using lithium as an addi-


tive in the electrolyte is that it results in a signifi-
cant concentration of lithium in the aluminum
metal produced in these cells, 10–20 ppm. The pre-
70, 90, 128
Current

sence of lithium in aluminum has been shown to be


64.5, 61

61, 125

110.5
160
112

128

deleterious for various uses of primary aluminum,


kA

e.g., production of magnesium-containing alumi-


num alloy sheet or plate as well as other products.
Consequently, in 1984 Alcan invented the ‘‘TAC’’
142, 168

176, 96
Cells

1508

2676

process (treatment of aluminum in crucibles) that


222

288
76
#

effectively removes lithium from aluminum by


reaction with AlF3 powder injected directly
Lines

into aluminum metal in large metal transfer


2, 7

18
#
2

1
2

crucibles.6
While substantial improvements in paste formu-
1970, 1982 2010, 2010 40, 28 HSS, VSS

lation and the gas exhaust systems had been made


type
HSS

VSS

VSS
VSS

VSS
Pot

in many plants, it was recognized that workers were


still being exposed to dust, heat, and polycyclic
aromatic hydrocarbons (PAH) emissions. As a
Table VI. Søderberg aluminum smelters in South America

55, 35*
Years

result, companies embarked on programs to develop


316
52*

43*
34
29

and implement new mobile equipment with air-


conditioned cabs. This represented very complex
engineering challenges. The old potrooms tended to
Closure

be small and crowded, leaving little space for vehicle


date

1999
1992
*

access. Wheel-breakers had been introduced in the


VS potrooms in the late 1960s (see Fig. 9), and in
the late 1970s work started on the HS vehicle fleet.
1958, 1978

Alumino, Sao Paulo, 1961–2007


Startup

New machines were introduced for crust breaking,


date

1965
1963

1970

trimming, stud planting, and pulling, and finally,


the most complex, a machine for raising the rods
connecting the studs to the anode busbar.
By the 1970s, the expansion of Søderberg cell
Paranam, Surname
Vera Cruz, Mexico

Artu, Saramenha,

Pocos de Caldas,

technology had reached 23 Søderberg smelters


Ouro Preto,
Location

located in North and South America, which had a


Brazil

Brazil

Brazil

Brazil

combined primary aluminum capacity over 3 million


tpa (shown in Fig. 10).

THE DECLINE OF SØDERBERG CELLS


Although Søderberg plants would continue to be
Vera Cruz
Company

built in the Americas after 1980 (Aratu VS Søderberg


Alumino

Average

in 1982, and a continued expansion program by CBA


Alcan

Alcan
Alcoa

Alcoa

Total
CBA

stretching from 1982 until 2007), the glory years of


Søderberg cell technology were over.
The Evolution of Søderberg Aluminum Cell Technology in North and South America 231

Fig. 8. The relationship between anode area and amperage in Søderberg cells.

A number of factors contributed to the decline, as


follows:
 Energy costs Most of the Søderberg plants had
been built when energy costs were low. As a
result, extra money was not invested to imple-
ment large busbar cross sections as high voltage
drops were offset by lower capital costs. In
addition, almost all Søderberg potrooms had an
end-to-end cell arrangement, which increased
busbar lengths, and thus voltage drops. And
finally, Søderberg cells have a lower current
efficiency than modern prebake cells, so their
energy costs per tonne of aluminum are higher.
 Amperage levels Once amperage levels started to
exceed 120–150 kA, MHD effects became too strong
to be adequately compensated for in an end-to-end
pot cell arrangement, and consequently, as Søder- Fig. 9. A wheel breaker machine breaking the side crust at the Alcan
berg cells became larger, their operation became Kitimat VS Søderberg smelter (Source: Rio Tinto Alcan).
more difficult and unsustainable.
 Health In 1975, the Canadian Federal Health
Protection Branch signaled the presence of an working atmosphere during anode baking and stud
unusual number of bladder cancer cases in the replacement (as shown in Fig. 11). By comparison,
Chicoutimi area, including Arvida.7 In 1979, Gibbs the PAH components of coal tar pitch in prebake
and Horowitz8 published a report linking Søder- anodes are destroyed when heated to 1150–1200°C
berg potroom workers to an increased risk of lung in anode baking furnaces.
cancer. In both cases, tar fumes from the Søderberg  Environment In the 1990s, the aluminum indus-
anodes were identified as being the probably toxic try also became aware of the harmful effect of the
agent. More recent studies in France, Canada, and perfluorocarbons (PFC), which are potent green-
Norway have confirmed the elevated risk of blad- house gases that develop during anode effects.
der cancer for Søderberg potroom workers. The tar Originally Søderberg smelters operated with a
fumes were found to contain PAHs. Some of its high anode effect frequency, typically 1–2 AE/
components such as benzo[a]pyrene (BaP) were pot-day, due to its large side-break and alumina
identified as being mutagenic and highly carcino- feeding operations at 2–4 h intervals. Eventu-
genic. The sources of PAH is the coal tar pitch ally, some Søderberg potlines have been retrofit-
binder of the anode. The PAH problem is unique to ted with point feeder technology to reduce anode
the Søderberg operation as they are emitted to the effects and CO2 equivalent emissions.
232 Barber and Tabereaux

Fig. 10. The expansion of primary aluminum production from Søderberg smelters, 1940–2010.

 Manpower Søderberg potlines typically use twice as


many work hours per tonne of metal as prebake
plants. In addition, due to a lack of space and the
nature of the work, it has proved very challenging
and expensive to mechanize or automate work.
The cumulative shutdown of Søderberg capacity in
North and South America from 1940 to 2013 (shown
in Fig. 12) indicates that there have been four major
crisis periods.

Period 1
In 1974, the OPEC Middle East oil embargo initi-
ated a worldwide energy crisis. Between October
1973 and January 1974, world oil prices quadrupled,
affecting the price of electrical generation. This was
followed a couple of years later by an increase in
natural gas prices. As a result, aluminum capacity
was closed in the United States, Japan, and in Wes-
tern Europe, and new capacity added since the late
1970s has been only in regions with low-cost energy.

Period 2
This period corresponds to a major increase in
power costs by the TVA as it affected smelters in the Fig. 11. Stud pulling from a VS Søderberg cell with ‘‘wet’’ anode
southeast United States with the closure of 18 pot- paste (Source: Reynolds Aluminum).
lines.

Period 3
Period 4
Period 3 includes a number of factors. Skyroc-
keting electrical power prices resulted due to the Period 4 corresponds to the 2008–2009 global
California electricity US Western energy crisis of recession that began with a marked global economic
2000 and 2001 as California had a shortage of decline beginning in August 2007 as a liquidity
electricity. Only two of the original 10 aluminum crisis and took a particularly sharp downward turn
smelters in the Northwest are still operating. In in September 2008. It resulted in the plummet in
addition, old capacity in Quebec was shut down as the price of primarily aluminum from US $3,000/mt
new replacement smelters were built, and in Suri- (July 2008) to $1,340/mt (March 2009). This was
nam, the Alcoa Paranam plant was closed due to low followed by record high metal inventories. LME
rainfall affecting hydroelectric power generation. aluminum inventories more than tripled from 1.2
The Evolution of Søderberg Aluminum Cell Technology in North and South America 233

Fig. 12. The decline in primary aluminum production from Søderberg smelters in North and South America, 1940–2013.

million tonnes pre-crisis to more than 4.5 million


tonnes by the middle of 2009. Stockpiles in ware-
house climbed to record levels above 5 million ton-
nes in 2011–2013 and consequently depressed
aluminum prices. The LME 3-month price was
US$1880 in September 2013.
The major recession periods, 1980s, 2000 and
2008 with higher operating costs and continued
weakness in aluminum prices initiated the closure
of Søderberg smelters with dated technology and
higher costs in North and South America as noted in
Fig. 13.

THE FUTURE OF SØDERBERG CELLS


Of the 108 Søderberg potlines that once operated
Fig. 13. The world price for primary aluminum and smelter costs
from 1983 to 2013.
in the Americas, only 22 potlines are still in opera-
tion, and there have already been announcements
concerning the closing of 12 potlines. Of the
remaining 12 Søderberg potlines, 11 are located in
Brazil with 9 of them being operated by CBA. By
2015, all aluminum smelters in Canada using
Søderberg technology will be closed. At that point,
all aluminum smelters in Canada will use the more
efficient and environmental cleaner modern pre-
bake anode technology.
Major aluminum companies have developed
improved Søderberg technology to reduce worker
exposure to PAH compounds in the workplace as
well as the emission of fluorides into the atmo-
sphere. For example, in the late 1970s, the Sumi-
tomo aluminum company marketed and sold their
Søderberg pot technology, which consisted of ‘‘dry’’
anode paste with a lower pitch content and the
introduction of pot crust bar breakers for automat-
ing alumina additions (shown in Fig. 14) as well as
graphitic cathode blocks and larger anodes to
reduce energy consumption.9 Dry scrubbers were
Fig. 14. Sumitomo side breaker bars on a VS Søderberg cell introduced to capture and recycle fluoride emis-
(Source: Reynolds Aluminum). sions, and lithium was introduced as an additive to
234 Barber and Tabereaux

consumption. However, the major focus of the


technology is to improve the environmental perfor-
mance by (I) better alumina feeding control tech-
nology using point feeders to reduce the frequency
of anode effects and the greenhouse gas emissions,
and (II) introducing a closed anode top to nearly
eliminate the PAH emissions.10–12 Rusal has
developed different methods for hooding and sealing
Søderberg pots and implemented point feeders and
a colloidal anode with pitch content close to that of a
prebaked anode in Søderberg potlines at the Kraz-
noyarsk aluminum smelter in Russia.13
However, Søderberg smelters are facing chal-
lenging environmental requirements as the indus-
try expects even more stringent emission
Fig. 15. Removal of large chunks of Søderberg anode from a VSS
cell at the Kitimat smelter (Source: Rio Tinto Alcan).
requirements in the years to come. If environmental
and working atmosphere issues are addressed and
resolved to the satisfaction of regulatory officials,
the electrolyte to reduce fluoride emissions. Much and if economic conditions improve with higher
work was done improving the capture efficiency of metal prices, then Søderberg cells will certainly
the exhaust systems. continue to operate for years to come—the last
With Søderberg anodes, baked carbon quality was survivors of a once highly successful technology.
always an issue, especially after the conversion
ACKNOWLEDGEMENTS
to dry anode paste. And as the anodes became big-
ger, maintaining homogeneous quality became more The book, ‘‘Global Mission—The Story of Alcan’’
difficult. At the same time, the anodes became more was consulted extensively when writing the section
sensitive to changes in raw materials, particularly on Alcan history.14 In addition, we would like to
coke quality. This resulted in increased suscepti- thank Claude Gilbert and others at the Arvida
bility to air burn, heavy dust formation, cracking, Research and Development Centre for their help in
and even the separation of large chunks of carbon providing details of Alcan’s operating history.
from the anode block. Dust skimming and the
removal of loose carbon became an inevitable part of REFERENCES
daily operations (shown in Fig. 15).
1. P. Torchet, U.S. Patent 2,073,356 (9 March 1937).
Changes were made in Søderberg paste formula- 2. H. Morsel, Histoire Technique de la Production d’Alumin-
tion and anode operating practices to lower tar fume ium (Grenoble: Presses Universities de Grenoble, 1991).
emissions and reduce their toxicity. Workers were 3. J.P. McGeer, JOM 38, 27 (1986).
better protected as well. The use of high-perfor- 4. G. Holywell, Personal Communications (2013).
mance respiratory protection became mandatory. 5. C.M. Hall, U.S. Patent 400,664 (1889).
6. G. Dube, U.S. Patent 4,470,846 (11 September 1984).
Where possible, workers were inside closed cabins 7. D.T. Wigle, Lancet 2, 83 (1977).
provided with air conditioning and high-efficiency 8. G.W. Gibbs and I. Horowitz, J. Occup. Med. 21, 347 (May
filtering. To the extent possible, tasks were auto- 1979).
mated. Yet despite very significant improvements, 9. G. Holywell, The Canadian Metallurgical & Materials
Landscape 1960 to 2011 (Montreal, QC: The Metallurgy and
Søderberg plants continued to fall further behind Materials Society of the Canadian Institute of Mining,
the performance of the new generation of prebake Metallurgy and Petroleum, 2011), pp. 177–201.
plants. 10. T.B. Pedersen, A.K. Syrdal, and A. Saethre, Light Metals
These improvements lowered the PAH emissions 1995, ed. J.W. Evans (Warrendale, PA: TMS, 1995),
and made feeding the pot easier. More recently, pp. 253–256.
11. T.B. Pedersen, M. Jensen, K. Kalgraf, W. Larsen, and A.T.
successful and valuable improvements have been Olsen, Light Metals 2008, ed. D.H. DeYoung (Warrendale,
reported in Søderberg pot design and operation in PA: TMS, 2008), pp. 239–244.
some countries, mainly in Norway, Spain, and 12. A.K. Syrdal, Light Metals 2002, ed. W. Schneider (Warren-
Russia. Improvements to Søderberg cell technology dale, PA: TMS, 2002), pp. 319–325.
13. V. Mann, Light Metals 2006, ed. T.J. Galloway (Warrendale,
were made at the Elkem Lista smelter in Norway in PA: TMS, 2006), pp. 181–183.
the 1990s and were implemented recently at the 14. D.C. Campbell, Global Mission—The Story of Alcan, Vol. I to
Alcoa La Coruna and Aviles smelters in Spain to 1950 (Toronto, ON: Ontario Publication Company,
improve current efficiency and reduce energy 1985–1990).

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