IRMM-290 Series - SDS

SAFETY DATA SHEET
According to Regulation (EC) No. 1907/2006, as amended by Regulation (EU) No. 2015/830
IRMM-290 series: Plutonium nitrate, solid

Section 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier

Product name IRMM-290 series: Plutonium nitrate, solid
1.2 Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses Laboratory chemicals [PC 21]; certified reference material for laboratory reagent use only [PROC 15]
Uses advised against No information available
1.3 Details of the supplier of the safety data sheet

Company European Commission
Joint Research Centre
Directorate G – Nuclear Safety and Security
Standards for Nuclear Safety, Security and Safeguards Unit
Street address Retieseweg 111, 2440 Geel, Belgium
Telephone number +32 14 57 16 17
Fax number +32 14 59 04 06
E-mail address jrc-gee-rm-nuclear-sales@ec.europa.eu
1.4 Emergency telephone number

Telephone number Poison Centre +32 70 245 245
(Please contact your country's national Poison Centre)
Warning: THIS IS A RADIOACTIVE MATERIAL. The hazard information in this MSDS is for the Chemical Hazard
Only! For the hazard documentation concerning the radioactive material, refer to the packaging information and
insert sheet. Additionally to the safety measures described in this data sheet the user must be aware of the
radiation safety principles. Only appropriately trained staff should handle it. Please consult the Certificate for the
amount of the radioactive material. Please consult the competent authorities for the proper
notification/licensing, handling and disposal procedures.
Section 2: Hazards identification

The information in this section is for nitric acid solution.
2.1 Classification of the substance or mixture

Classification according to the criteria of Regulation EC No 1272/2008
Hazard Class Hazard Category Hazard statements

Skin Corr. Category 1A H314: Causes severe skin burns and eye damage.
2.2 Label elements

Labelling according to Regulation EC No 1272/2008 (CLP)
Hazard pictograms
Contains: nitric acid
Signal word
Danger
Reference number: IRMM-290

Version: 1.0 Page 1 of 10
Issue date: 03/07/2018
SAFETY DATA SHEET
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Hazard statements
H314 Causes severe skin burns and eye damage
Precautionary statements
P280 Wear protective gloves/protection clothing/eye protection/face protection.
P260 Do not breathe vapours.
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing.
P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
2.3 Other hazards

No data available
Section 3: Composition/information on ingredients
3.1 Substances
Identification name CAS number Weight % content Classification according to Note

EC number (or range) Regulation EC No 1272/2008
Index number
Plutonium nitrate CAS No: 14913-29-2 100 [1]
(Nitric acid, plutonium salt) EC No: 238-979-3
Additional information:
[1] For concentration and isotope amount ratio: see Certificate of Analysis
3.2 Mixtures
Not applicable
Section 4: First aid measures

4.1 Description of first aid measures

General notes Check the vital functions. Unconscious: maintain adequate airway and respiration. Respiratory arrest:
artificial respiration or oxygen. Cardiac arrest: perform resuscitation. Victim conscious with labored
breathing: half-seated. Victim in shock: on his back with legs slightly raised. Vomiting: prevent
asphyxia/aspiration pneumonia. Prevent cooling by covering the victim (no warming up). Keep
watching the victim. Give psychological aid. Keep the victim calm, avoid physical strain. Depending on
the victim´s condition: doctor/hospital.
Following inhalation Remove the victim into fresh air. Respiratory problems: consult a doctor/medical service.
Following skin contact Wash immediately with lots of water (15 minutes)/shower. Remove clothing while washing. Do
not remove clothing if it sticks to the skin. Cover wounds with sterile bandage. Consult a
doctor/medical service. If burned surface > 10 %: take victim to hospital.
Following eye contact Rinse immediately with plenty of water for 15 minutes. Do not apply neutralizing agents. Take victim
to an ophthalmologist.
Following ingestion Rinse mouth with water. Immediately after ingestion: give lots of water to drink. Do not induce
vomiting. Immediately consult a doctor/medical service.
4.2 Most important symptoms and effects, both acute and delayed
Acute symptoms
Following inhalation Irritation of the respiratory tract. Dry/sore throat. Coughing. FOLLOWING SYMPTOMS MAY APPEAR
LATER: Respiratory difficulties. Possible inflammation of the respiratory tract. Risk of lung oedema.
Following skin contact Yellow skin. Caustic burns/corrosion of the skin.
Following eye contact Corrosion of the eye tissue.
Following ingestion Nausea. Vomiting. Burns to the gastric/intestinal mucosa. Possible esophageal perforation.
4.3 Indication of any immediate medical attention and special treatment needed

SAFETY DATA SHEET
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No data available
Section 5: Firefighting measures

5.1 Extinguishing media

Suitable extinguishing media Adapt extinguishing media to the environment.
Unsuitable extinguishing media No unsuitable extinguishing media known.
5.2 Special hazards arising from the substance or mixture

Hazardous combustion products On heating/burning: release of toxic and corrosive gases/vapours (nitrous vapours).
5.3 Advice for firefighters

Instructions Dilute toxic gases with water spray. Take account of toxic fire-fighting water. Use water moderately
and if possible collect or contain it. Take account of toxic/corrosive precipitation water.
Special protective equipment for firefighters Heat/fire exposure: compressed air/oxygen apparatus. Gloves. Face-shield. Corrosion-proof suit.
Section 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

No naked flames.
6.1.1 For non-emergency personnel
Protective equipment See section 8.2.
Emergency procedures No data available.
6.1.2 For emergency responders
Gloves. Face-shield. Corrosion-proof suit.
Suitable protective clothing See section 8.2.
6.2 Environmental precautions:

Dam up the liquid spill. Prevent soil and water pollution. Prevent spreading in sewers.
6.3 Methods and material for containment and cleaning up

6.3.1 For containment Take up liquid spill into inert absorbent material e.g.: sand, earth, vermiculite. Scoop absorbed
substance into closing containers.
6.3.2 For cleaning up Carefully collect the spill/leftovers.
Contaminated surfaces: clean (treat) with an excess of water.
Take collected spill to manufacturer/competent authority.
Wash clothing and equipment after handling.
6.3.3 Other information See section 8.2.
6.4 Reference to other sections

See sections 8 and 13.
TION 7: Handling and
Section 7: Handling and storage
7.1 Precautions for safe handling

Protective measures See section 8.2.
Measures to prevent fire Keep away from naked flames/heat.
Measures to prevent aerosol and dust generation Keep container tightly closed.
Measures to protect the environment Do not discharge the waste into the drain.
Advice on general occupational hygiene Observe strict hygiene. Remove contaminated clothing immediately.
7.2 Conditions for safe storage, including any incompatibilities

Technical measures and storage requirements Meet the legal requirements. Keep locked up. Unauthorized persons are not admitted.
Packaging materials Suitable packaging material: Glass.
Unsuitable packaging material: No data available.

SAFETY DATA SHEET
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Requirements for storage rooms and vessels Keep away from: Reducing agents, (strong) bases, metal powders, combustible materials.
7.3 Specific end use(s)

No data available.
Section 8: Exposure controls/personal protection

8.1 Control parameters
8.1.1 Occupational exposure limit values
SUBSTANCE NAME : Nitric acid

CAS number : 7697-37-2
EC number : 231-714-2
Limit value- Eight hours Limit value- Short term
Country
ppm mg/m3 ppm mg/m3
Austria 1 2,6
Belgium 1 2,6
Denmark 2 5 4 10
European Union 1 2,6
Finland 0,5 1,3 1 (1) 2,6 (1)
France 1 2,6
Germany (AGS) 1 (1) 2,6 (1)
Hungary 2,6
Ireland 1 (1) 2,6 (1)
Italy 1 2,6
Latvia 0,78 2 1 (1) 2,6 (1)
Spain 1 2,6
Sweden 2 5 5 (1) 13 (1)
Switzerland 2 5 2 5
The Netherlands 1,3
Turkey 1 (1) 2,6 (1)
USA - NIOSH 2 5 4 (1) 10 (1)
USA - OSHA 2 5
United Kingdom 1 2,6
Poland 1,4 2,6
REMARKS
European Union Bold-type: Indicative Occupational Exposure Limit Values [2,3] and Limit Values for
Occupational Exposure [4] ~ (for references see bibliography)
Finland (1) 15 minutes average value
France Italic type: Indicative statutory limit values

Germany (AGS) (1) 15 minutes average value
Ireland (1) 15 minutes reference period
Latvia (1) 15 minutes average value
Poland nitric acid (V)
Sweden (1) Short-term value, 15 minutes average value
Turkey (1) 15 minutes average value
USA - NIOSH (1) 15 minutes average value
Source: Based on GESTIS International Limit values Database

SAFETY DATA SHEET
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8.1.2 Sampling methods
Product name Test Number

Nitric Acid OSHA CSI
Nitric Acid (Acids, inorganic) NIOSH 7903
Nitric Acid OSHA ID 165SG
8.1.3 DNEL/PNEC values

EC number : 231-714-2
DNELs
Workers General population

Route of Acute Acute Chronic Chronic Acute Acute effects Chronic Chronic
exposure effect local effects effects local effects effect local systemic effects effects
systemic systemic local systemic
Not Not
Oral Not required [1] [2]
relevant relevant
Inhalation 2.6 mg/m³ [2] 2.6 mg/m³ [2] 1.3 mg/m³ [2] 1.3 mg/m³ [2]
high high hazard high hazard high hazard

hazard (no (no (no (no
Dermal [1] [2] [2] [2]
threshold threshold threshold threshold
derived) derived) derived) derived)
REMARKS
Note [1]: No-threshold effect and/or no dose-response information available
Note [2]: Low hazard (no threshold derived)
Source: European Chemicals Agency, http://echa.europa.eu/

EC number : 231-714-2
PNECs
Environmental protection target PNEC

Freshwater no hazard identified
Freshwater sediments no hazard identified
s
Marine water no hazard identified
Marine sediments no hazard identified
Food chain no potential for bioaccumulation
Microorganisms in sewage treatment no hazard identified
Soil (agricultural) no hazard identified
Air no hazard identified
Source: European Chemicals Agency, http://echa.europa.eu/
8.2 Exposure controls
8.2.1 Appropriate engineering controls

Keep away from naked flames/heat. Measures the concentration in the air regularly. Carry operations in the open/under local exhaust/ventilation or with
respiratory protection.
8.2.2 Personal protection equipment

Observe strict hygiene. Keep container tightly closed. Do not eat, drink or smoke during work.

SAFETY DATA SHEET
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8.2.2.1 Eye and face protection Face shield.

8.2.2.2 Skin protection
Hand protection Gloves.
Materials (excellent resistance) Butyl rubber, viton, neoprene, PVC.
Materials (good resistance) Polyethylene, polyethylene/ethylene vinylalcohol, nitrile rubber, natural rubber.
Materials (poor resistance) PVA.
Other skin protection Corrosion-proof clothing.
8.2.2.3 Respiratory protection Wear gas mask with filter type B if conc. in air > exposure limit.
8.2.2.4 Thermal hazards No data available.
8.2.3 Environmental exposure controls

See headings 6.2, 6.3 and 13
Section 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties

Physical state Solid
Colour No data available
Odour threshold No data available
pH No data available
Melting point/freezing point No data available
Initial boiling point and boiling range No data available
Flash point No data available
Evaporation rate No data available
Flammability No data available
Vapour pressure No data available
Relative vapour density No data available
Relative density No data available
Solubility No data available
Partition coefficient: n-octanol/water No data available
Particle size No data available
Auto-ignition temperature No data available
Decomposition temperature No data available
Dynamic viscosity No data available
Kinematic viscosity No data available
Explosive properties No data available
Oxidising properties No data available
9.2 Other information

No data available
Section 10: Stability and reactivity

10.1 Reactivity
Substance has acid reaction.
10.2 Chemical stability
No data available.
10.3 Possibility of hazardous reactions
No data available.
10.4 Conditions to avoid
Keep away from naked flames/heat.
10.5 Incompatible materials
Combustible materials, reducing agents, (strong) bases, metal powders.
10.6 Hazardous decomposition products
On heating/burning: release of toxic and corrosive gases/vapours (nitrous vapours).
Section 11: Toxicological information

SAFETY DATA SHEET
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11.1 Information on toxicological effects

Data obtained from Source: European Chemicals Agency, http://echa.europa.eu/
Acute toxicity
IRMM-290
No (test) data available
Nitric Acid
Route of exposure Parameter Method Value Exposure time Species Value Remark
determination
Inhalation LC50 OECD 403 > 2.65 mg/L air 4 h Rat nitric acid
(referring to containing 0.8 %
pure nitric acid) aerosol fraction
Conclusion:
Acute toxicity oral : No data (study waived based on corrosivity of the test substance)
Acute toxicity dermal: No data (study waived based on corrosivity of the test substance)
Acute toxicity inhalation: Not sufficient data available for classification.
Corrosion/irritation
IRMM-290
Nitric Acid
Strong acid (pH < 2,0).
Corrosive due to low pH.
Conclusion:
Causes severe skin burns and eye damage.
Respiratory or skin sensitisation

IRMM-290
Nitric acid
According to the REACH Regulation, testing for skin sensitization does not need to be conducted if the substance is a strong acid (pH < 2,0) and/or is classified
for skin corrosion.
Specific target organ toxicity

IRMM-290
Mutagenicity
IRMM-290
Nitric acid
Data inconclusive
Carcinogenicity
IRMM-290
Sodium nitrate (surrogate for Nitric acid) is no complete carcinogen in rats, but did increase the incidence of urinary bladder cancer in rats when it was given
after administration of a carcinogen.
A 2-year study in rats and a lifespan mice study showed no increased tumour incidence.
Conclusion: Data inconclusive
Reproductive toxicity
IRMM-290
Potassium nitrate (surrogate for Nitric acid)
Parameter Method Value Exposure time Species Effect Value
determination

SAFETY DATA SHEET
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Developmental toxicity NOAEL OECD 422 >= 1 500 mg/kg 28 days Rat No effects Experimental
bw/day (male/female) observed at the value
(nominal) maximum
concentration
tested
Effects on fertility (oral NOEC OECD 422 >= 1 500 mg/kg 28 days Rat No effects Experimental
route) bw/day (male/female) observed at value
(nominal) the maximum
concentration
tested
Conclusion: Conclusive but not sufficient for classification.
Conclusion CMR:
Data inconclusive for carcinogenicity
Data inconclusive for mutagenic or genotoxic toxicity
Data conclusive but not sufficient for classification for reprotoxic or developmental toxicity
Toxicity other effects

IRMM-290
Nitric acid was not associated with moderate cough, asthma, or shortness of breath.
Nitric acid fumes (1.6 ppm) for 10 minutes did not produce acute bronchoconstriction in normal adults.
Chronic effects from short and long-term exposure

IRMM-290
Section 12: Ecological information

12.1 Toxicity
Data obtained from Source: European Chemicals Agency, http://echa.europa.eu/
IRMM-290
Nitric acid
Aquatic toxicity
The main characteristic of the nitric acid that drives its toxicity is embedded in the fact it is a (strong) acid that dissociates in water into its respective ions H+
and NO3- and will affect the environment and its organisms by decreasing the pH.
Regulatory aquatic ecotoxicity studies should be conducted at relevant environmental pH (i.e. pH 6 -9). At this pH, exposure to nitric acid comes down to
exposure to nitrate ions.
Short term toxicity to fish
Toxic effects observed due to low pH. As regulatory ecotoxicity tests need to be conducted at pH 6-9, nitric acid will not cause adverse effects to fish when in
this pH range. Studies conducted with sodium nitrate in marine and freshwater fish showed no effects (LC50 ≥ 1000 mg nitrate/L)
Long term toxicity to fish
Studies done on sodium nitrate (surrogate for Nitric acid) confirm the low long-term toxicity of sodium nitrate.
Short-term toxicity to aquatic invertebrates
As regulatory ecotoxicity tests need to be conducted at pH 6-9, nitric acid will not cause adverse effects to daphnids when in this pH range.
Long term toxicity to aquatic invertebrates
No effects are expected to occur
Toxicity to aquatic algae and cyanobacteria
Potassium nitrate (surrogate for Nitric acid): derived NOEC = 6.75 mmol/L (i.e. 419 mg nitrate/L). Organisms: several marine benthic diatoms
Toxicity to microorganism
Sodium nitrate (surrogate for Nitric acid): 3h-EC50 of >1000 mg/L.
Sediment toxicity: no data available
Terrestrial toxicity: no data available
Conclusion:
pH shift

SAFETY DATA SHEET
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The increasing nitrate concentration is judged to have a minor effect on aquatic organisms compared to the effect of pH. The substance will therefore not be
classified for environmental hazards, based on the available information.
Effect on sediment and terrestrial organisms: No data available
12.2 Persistence and degradability

No (test) data available.
12.3 Bioaccumulative potential

12.4 Mobility in soil

12.5 Results of PBT and vPvB assessment

Does not contain component(s) that meet(s) the criteria of PBT and/or vPvB as listed in Annex XIII of Regulation (EC) No 1907/2006.
12.6 Other adverse effects

No data available
Section 13: Disposal considerations
13.1 Waste treatment methods

13.1.1 Product / Packaging disposal
Waste codes / waste designations according to LoW (Directive 2008/98/EC, decision 2001/118/EC).
Waste material code
16 05 (gases in pressure containers and discarded chemicals).
16 05 06* (gases in pressure containers and discarded chemicals: laboratory chemicals, consisting of or containing dangerous substances, including mixtures
of laboratory chemicals). Depending on branch of industry and production process, also other waste codes may be applicable. Hazardous waste according to
Directive 2008/98/EC.
Waste material code packaging
15 01 10* (packaging containing residues of or contaminated by dangerous substances).
13.1.2 Waste treatment-relevant information

Recycle/reuse. Remove waste in accordance with local and/or national regulations. Hazardous waste shall not be mixed together with other waste. Different
types of hazardous waste shall not be mixed together if this may entail a risk of pollution or create problems for the further management of the waste.
Hazardous waste shall be managed responsibly. All entities that store, transport or handle hazardous waste shall take the necessary measures to prevent risks
of pollution or damage to people or animals.
Section 14: Transport information
14.1 UN number
Determined by the Radiation Safety requirements.
14.2 UN proper shipping name

14.3Transport hazard class(es)

14.4 Packing group

14.5 Environmental hazards

14.6 Special precautions for user


SAFETY DATA SHEET
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14.7 Transport in bulk according to Annex II of MARPOL and the IBC Code
Section 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
EU regulations
Restrictions on use
Contains component(s) subject to restrictions of Annex XVII of Regulation EC) No. 1907/2006: restrictions on the manufacture, placing on the market
and use of certain dangerous substances, mixtures and articles.
Reference legislation:
See column 1:3
See column 1:40
15.2 Chemical Safety Assessment

No chemical Safety Assessment has been carried out by the supplier.
Section 16: Other information
16.1 Abbreviations and acronyms

PBT-substances = persistent, bioaccumulative and toxic substances
CLP (EU-GHS) Classification, labelling and packaging (Globally Harmonised System in Europe)
SDS Safety Data Sheet
CAS - Chemical Abstracts Service
EINECS/ELINCS - European Inventory of Existing Commercial Chemical Substances/EU List of Notified Chemical Substances
DNEL - Derived No Effect Level
PNEC - Predicted No Effect Concentration
LD50 - Lethal Dose 50%
LC50 - Lethal Concentration 50%
PBT - Persistent, Bioaccumulative, Toxic
vPvB - very Persistent, very Bioaccumulative
ADR - European Agreement Concerning the International Carriage of Dangerous Goods by Road
ICAO/IATA - International Civil Aviation Organization/International Air Transport Association
IMO/IMDG - International Maritime Organization/International Maritime Dangerous Goods Code
MARPOL - International Convention for the Prevention of Pollution from Ships
BCF - Bioconcentration factor
VOC - Volatile Organic Compounds
16.2 Relevant H-statements (number and full text)

Full text of any H-statements referred to under headings 2 and 3:
H314: Causes severe skin burns and eye damage.
DISCLAIMER OF LIABILITY To our best of our knowledge, the information contained herein is accurate and reliable as of the date of
publication, however we do not assume any liability whatsoever for the accuracy and completeness of such information. Nothing herein
shall constitute any warranty of merchantability or fitness for a particular purpose. The information given is designed only as a guide for
safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality
specification. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising
out of or in any way connected with the handling, storage, use or disposal of the product. No liability can be accepted in respect of the use
of this product in conjunction with other materials. The information contained herein relates exclusively to this product when not used in
conjunction with any third party materials.


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SAFETY DATA SHEET

IRMM-290 series: Plutonium nitrate, solid

1.1 Product identifier

Uses advised against No information available

1.3 Details of the supplier of the safety data sheet

1.4 Emergency telephone number

Section 2: Hazards identification

2.1 Classification of the substance or mixture

Hazard Class Hazard Category Hazard statements

2.2 Label elements

Contains: nitric acid

Reference number: IRMM-290

2.3 Other hazards

Section 3: Composition/information on ingredients

Identification name CAS number Weight % content Classification according to Note

Section 4: First aid measures

4.1 Description of first aid measures

Reference number: IRMM-290

Section 5: Firefighting measures

5.1 Extinguishing media

5.2 Special hazards arising from the substance or mixture

5.3 Advice for firefighters

Section 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

6.2 Environmental precautions:

6.3 Methods and material for containment and cleaning up

6.4 Reference to other sections

7.1 Precautions for safe handling

7.2 Conditions for safe storage, including any incompatibilities

Reference number: IRMM-290

7.3 Specific end use(s)

Section 8: Exposure controls/personal protection

8.1 Control parameters

8.1.1 Occupational exposure limit values

SUBSTANCE NAME : Nitric acid

France Italic type: Indicative statutory limit values

Source: Based on GESTIS International Limit values Database

Reference number: IRMM-290

8.1.2 Sampling methods

Product name Test Number

8.1.3 DNEL/PNEC values

SUBSTANCE NAME : Nitric acid

Workers General population

high high hazard high hazard high hazard

SUBSTANCE NAME : Nitric acid

Environmental protection target PNEC

8.2 Exposure controls

8.2.1 Appropriate engineering controls

8.2.2 Personal protection equipment

Reference number: IRMM-290

8.2.2.1 Eye and face protection Face shield.

8.2.3 Environmental exposure controls

Section 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

9.2 Other information

Section 10: Stability and reactivity

Section 11: Toxicological information

Reference number: IRMM-290

The information in this section is for nitric acid solution.

11.1 Information on toxicological effects

Respiratory or skin sensitisation

Specific target organ toxicity

Reference number: IRMM-290