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Mechanical and water absorption properties of Acacia Arabica bark fiber/


polyester composites: Effect of alkali treatment and fiber volume
fraction
Sakthi vadivel K. a,⇑, Govindasamy P. b
a
Department of Mechanical Engineering, Builders Engineering College, Tirupur, Tamilnadu, India
b
Department of Mechatronics Engineering, Mahalingam College of Engineering and Technology, Pollachi, Tamilnadu, India

a r t i c l e i n f o a b s t r a c t

Article history: In this work, the water absorption and mechanical properties of alkali (NaOH) treated and untreated
Received 17 January 2021 Acacia Arabica bark fiber composites were fabricated by hand lay-up technique. Effect of chemically trea-
Received in revised form 11 March 2021 ted fiber increased the surface roughness and mechanical properties as well as decreased the water
Accepted 6 April 2021
absorption. Moreover, fibers were randomly oriented varying from 10% to 35% volume fraction (Vf)
Available online xxxx
and also varying in the length of 10 mm to 50 mm. Tensile, flexural and water absorption tests were con-
ducted as per ASTM standard. It was found that, the 25% volume fraction with 30 mm length of fiber had
Keywords:
better properties compared with other compositions. The fractured specimens of tensile and flexural test
Mechanical properties
Acacia Arabica fiber
were evaluated under scanning electron microscope to study the fiber pull-outs of the materials.
Surface roughness Ó 2021 Elsevier Ltd. All rights reserved.
Alkali treatments Selection and peer-review under responsibility of the scientific committee of the International Confer-
ence on Multifunctional Nanomaterials.

1. Introduction volume fraction (10–30 Vf%) and length of the fiber (50–150 mm)
[5]. Extracted the pineapple fibers from pineapple leaf and studied
In recent years the awareness of using natural fibers are in high about the effect of fiber surface treatment (Alkali and silane) and
because of low weight and high strength. The natural fibers are also compared the mechanical properties of treated and untreated
extracted from natural plant so the fibers are economical. There fibers whereas the treated fibers have greater interfacial adhesion
has been a rapid growth in investigation in the natural fiber com- [6]. The new identified snake grass fibers and extracted it by man-
posite region. Compared to other materials like synthetic, the nat- ual process from snake grass plant. Isophthallic polyester resins are
ural fiber composite has more advantages in the same way low used to prepare the composite specimen of chopped snake grass
environmental impact and countless potential of applications fiber by different length of the fiber and volume fraction Vf. The
[1,2]. The unidirectional kenaf fibers composite are manufactured specimens, evaluated by tensile and flexural strength, improved
by using PLA resin, the biodegradable composite materials were significantly with the various fiber volume fraction and fiber
evaluated by means of tensile and flexural strength [3]. Investi- length [7].
gated the natural coir fibers extracted from coconut that is very Prepared the composites by using randomly short Sansevieria
cheap and abundantly available in India and evaluated the cylindrical fiber with varying fiber lengths (10 mm, 20 mm,
mechanical properties of natural fiber coir/epoxy and compared 30 mm, 40 mm & 50 mm) and weight percent (10%, 20%, 30%,
with glass fiber/epoxy [4]. Sisal and Roselle fiber hybrid composite 40% & 50%) and investigated the properties of tensile, flexural
materials are laminated by using unsaturated polyester resin. The and impact. The test indicated that a critical fiber length and opti-
fibers were extracted by simple manual method from sisal leaf mum fiber weight percent of 30 mm and 40%, respectively [8].
and Roselle plant available in south Indian regions. Laminates were Prepared the recycled sustainable wood waste fiber reinforced
fabricated and evaluated the mechanical properties by varying the composite with polymer with the objective of improving mechan-
ical properties over glass fiber reinforcement [9]. Produced Napier
⇑ Corresponding author. grass fiber laminates and investigated the tensile strength and
E-mail address: ksakthivadivel@gmail.com (K. Sakthi vadivel).
found the effect of soaking time during the alkaline treatment.

https://doi.org/10.1016/j.matpr.2021.04.057
2214-7853/Ó 2021 Elsevier Ltd. All rights reserved.
Selection and peer-review under responsibility of the scientific committee of the International Conference on Multifunctional Nanomaterials.

Please cite this article as: K. Sakthi vadivel and P. Govindasamy, Mechanical and water absorption properties of Acacia Arabica bark fiber/polyester com-
posites: Effect of alkali treatment and fiber volume fraction, Materials Today: Proceedings, https://doi.org/10.1016/j.matpr.2021.04.057
K. Sakthi vadivel and P. Govindasamy Materials Today: Proceedings xxx (xxxx) xxx

The Napier grasses are originally from Brazil. The alkaline treat- 2.2. Polyester resin
ment established to improve the tensile strength because of bet-
ter surface roughness of Napier fiber compared to untreated [10]. The unsaturated polyester resin is commercially available and
The water absorption decreased at low fiber volume fractions and used as the matrix for the investigation. The resin was mixed with
increased in high fiber volume fractions of kenaf fiber. Scanning accelerator (Methyl Ethyl Ketone Peroxide) and the catalysts
electron microscope indicated that all the composites failed by (Cobalt Naphthalene) at a concentration of 0.01w/w [4] to cure.
fiber pull-out [11]. Studied the characterization of elephant grass The unsaturated polyester resin is one of the inexpensive resins
fiber polymer matrix composite materials, the fibers were treated used due to its excellent process ability, low water absorption abil-
with NaOH. The fibers are available in large quantities in nature ity and bonding tendency as well as mechanical properties. The
and the extraction of fiber is easy and inexpensive [12]. Alkaline typical properties of the unsaturated polyester resin are shown in
treated and untreated sugar palm fiber reinforced epoxy compos- Table 1
ite were produced and analyzed the tensile properties and
microstructure of the fractured specimens in scanning electron 2.3. Fiber treatment
microscope [13]. Analyzed the three point bending, chemical
resistance and water absorption test of Bagasse fiber unsaturated In this study, chemical treatment has been applied to the differ-
polyester composite. Fibers were treated with sodium hydroxide ent lengths of Acacia Arabica fibers to improve the surface rough-
and then with dilute sulfuric acid for improvement of results in ness. Fibers were soaked in 6% sodium hydroxide solution (NaOH)
addition to stronger interaction of fiber matrix interface com- at room temperature for 24 h [22]. The NaOH treatment has an
pared to untreated fibers [14]. effect on the thermo physical properties of the fibers. After treat-
Studied and prepared the composite of ramie fiber with alkali ment, fibers were washed with running water to remove any traces
and silane treatment and found tensile, flexural and impact of alkali on the fiber surface and dried for 48 h under room
properties of the composite increased by surface treatment. temperature.
The fracture surface showed the enhancement of fiber and
matrix interface adhesion by using scanning electron microscope
2.4. Preparation of composite specimen
[15]. Analyzed the mechanical and thermal properties of the
waste cotton fiber (ecofriendly) as reinforcement and wheat
The hand lay-up technique is used to prepare the composite
flour as matrix composite materials. Morphology of the agro-
specimen of treated and untreated Acacia fibers with randomly ori-
green-composites were studied by using X-ray diffraction and
ented and various volume fraction (Vf) like 10%, 15%, 20%, 25%, 30%
SEM [16,17]. Investigated the mechanical properties of alkaline
& 35% respectively in different lengths of 10 mm, 20 mm, 30 mm,
and silane treated short fiber and aligned long hemp fiber com-
40 mm&50 mm respectively. The one percentage of accelerators
posite material of different fiber content (0–40 wt%). The result
and the catalysts were mixed with unsaturated polyester resin
showed that the treated fibers were found to be improved with
for curing purpose. The composite specimens are prepared by
increased fiber content [18]. The effect of alkaline and silane
using mild steel dies of dimensions 200 mm  12 mm  4 mm.
treated on the Bamboo fibers through water absorption test
The Acacia Arabica fibers are laid over the die in random orienta-
the result showed the reduction of water absorption compared
tion, the steel roller is used for rolling process to maintain the uni-
to untreated [19]. Fabricated the composites by injection mold-
formity of fiber to improve the isotropic property and remove the
ing technique with treated and untreated kenaf fibers of varying
air bubbles. The die was closed and applied with hydraulic pres-
fiber loading from (10 – 50 wt%). The treated kenaf fibers
sure for 10 h at atmospheric temperature. Later composite plate
enhanced their tensile and flexural properties because of surface
was removed from the die and kept for two hours for post curing
roughness and strong bonding [20]. Studied the mechanical
in room temperature.
properties of the kenaf fiber polymer composite, with and with-
out sodium hydroxide (NaOH) treatment. The result shows that
the tensile strength of the treated kenaf fibers have improved 2.5. Water absorption test
as compared to untreated kenaf fibers particularly at the opti-
mum level of 6% NaOH [21]. The water absorption tests were carried for both treated and
In the present work, an attempt was made to use the newly untreated fiber composite with varying volume fraction (vf) of
identified Acacia Arabica bark fibers which extracted from the Aca- 10%, 15%, 20%, 25%, 30% & 35% respectively for the length of fiber
cia Arabica plant by easy manual and biodegradable process. The 30 mm. The test specimens were cut from the plates accordingly
fiber is abundantly available in Asia moreover this work is to ASTM D570 [5,23]. The composite specimen were immersed in
extended to prepare the polymer matrix composite besides fiber distilled water at 27 °C and noted the changes in weight of the
is kept additional for alkali treatment and analyze its water absorp- specimen for every 0.5 h, 1.0 h, 2.0 h, 24 h, 48 h & 72 h respectively
tion and mechanical properties. with digital balance 0.01 mg resolution. The weighing process was
done within 30 s by removing the surface water in specimen with
the help of filter paper for avoiding the error.
2. Experiments
2.6. Tensile testing of the composite
2.1. Fiber materials
Tensile tests were conducted for the composite specimen using
Fig. 1 shows the Acacia Arabica plant and extraction method of the universal testing machine at the testing speed of 2 mm/min.
Acacia Arabica bark fibers [22]. The stem skins were cut from Aca- The composite specimen were prepared from the composite plate
cia plant and tied into bundles and were retting in water for 6– as per ASTM D638 [7] standards. All tests were executed at room
8 days. The retted Acacia stem skin was washed in running water. temperature and results were taken as the average value of five
Then the fibers were removed from stem skin, cleaned and dried samples with size of 165 mm  13 mm  4 mm for gauge length
using the sunlight. The Acacia bark fibers were cut into different of 50 mm. In this experimentation, the tensile strength, tensile
lengths of 10 mm, 20 mm, 30 mm, 40 mm and 50 mm respectively modulus, tensile load and elongation of the composites were
for preparing composite. measured.
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K. Sakthi vadivel and P. Govindasamy Materials Today: Proceedings xxx (xxxx) xxx

Fig. 1. (a) Naturally grown Acacia Arabica plant, (b) Acacia stem skin, (c) Bunddle of stem skin ready for retting in water, (d) Fiber collection.

Table 1 Mt ¼ ðwt  w0=w0Þx100%


Typical properties of the unsaturated polyester resin.
where, W0 = dry weight of sample; Wt = weight after specific time.
Appearance Yellow viscous liquid
Fig. 2 shows the water absorption of untreated fiber composite
Viscosity at 25 °C 200–300 cps
Acid value 25 ± 5 mg KOH/g for different volume of fraction specimens over a period of three
Specific gravity at 25 °C 1.11 ± 0.02 days. The percentage of water absorption for 10%vf, 15%vf, 20%vf,
Volatile content 40 ± 2 wt% 25%vf, 30%vf and 35%vf of fiber is 4%, 4.75%, 4.75%, 5.25%, 5.25%
Tensile strength 18 ± 1.5 MPa and 5.5% respectively at the beginning 0.5 h of the test. In this
Flexural strength 25 ± 2.5 MPa
1.5% difference of water absorption is obtained from 10%vf to
35%vf. Later one hour, water absorption testis wide-ranging of
2.7. Flexural testing of the composite 5.25% to 7% for 10%vfto 35%vf fiber composite respectively. In this
1.75% difference of water absorption is obtained between 10%vfto
Three point bending load (flexural) tests was conducted as per 35%vf of fiber loading. At a time period of 24 h the percentage of
ASTM D790 [7] standard by using universal testing machine at water absorption is increased when compared to 1 h and 2 h dura-
the testing speed of 2 mm/min. All tests were executed at room tion of the test. The calculated value of water absorption is 6.25%,
temperature and results were taken as the average value of five 7%, 7.25%, 7.25%, 7.75% and 8.25% of 10%vf, 15% vf, 20%vf, 25%vf,
samples with size of 125 mm  12 mm  4 mm. In this experimen- 30%vf and 35% vf of fibers respectively. The percentage of water
tation, the flexural strength, flexural modulus and deflection of the
specimens were measured.

2.8. Scanning electron microscope

The surfaces of the fractured specimens of tensile and flexural


composite were examined directly by scanning electron micro-
scope (SEM) of model VEGA3 TESCAN. The surface morphology of
the fracture specimens was then studied over SEM images in dif-
ferent magnifications to conclude the effect of surface treatment
and fiber pull-out on Acacia Arabica fiber composite materials
through interfacial adhesion of the samples [24].

3. Result and discussion

3.1. Water absorption

Water absorption test was determined by the weight gain rela-


tive to the dry weight of the samples. The moisture content of a Fig. 2. Percentage of water absorption verses soaking time for different volume
sample was calculated as follows fraction of untreated Acacia Arabica fiber.

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K. Sakthi vadivel and P. Govindasamy Materials Today: Proceedings xxx (xxxx) xxx

absorption for 48 h of 10%vf, 15%vf, 20%vf, 25%vf, 30%vf and 35% vf


is 6.5%, 7%, 7.5%, 8%,8.5% and 8.75 respectively increased when
compared to previous time interval. At 72 h test period, the water
absorption result shows that the same percentage maintained in
48 h. At 10% fiber volume fractions of the untreated composite
specimens absorbs the least water and 35% volume fraction of fiber
absorbs high water compared to all other fiber volume fractions.
Finally the water absorption test shows that the percentage of
water absorption is increased with untreated fiber volume fraction.
Fig. 3 shows the water absorption of treated fiber composite
specimens for different volume fraction over a period of three days.
The percentage of water absorption for 10%vf, 15% vf, 20%vf, 25%vf,
30%vf and 35%vf fiber is 3.25%, 3.5%, 3.5%, 3.75%, 4%, 4.25% respec-
tively at beginning 0.5 h of the test. In this 0.75% difference of
water absorption is obtained from 10% vf to 35% vf. At a time per-
iod of 24 h the percentage of water absorption is increased when
compared to 0.5 h, 1 h and 2 h duration of the test. The calculated
value of water absorption is 4%, 4.25%, 4.25%, 4.5%, 4.75% and 5% of Fig. 4. Effect of tensile strength verses volume fraction of untreated Acacia fiber
10%vf, 15%vf, 20%vf, 25%vf, 30%vf and 35%vf of fiber respectively. with different fiber lengths.
The percentage of water absorption for 48 h of 10%vf, 15%vf, 20%
vf, 25%vf, 30%vf and 35% vf is 5.5%, 7%, 8.75% and 8.75 respectively
was increased when compared to previous time interval and the 30 mm fiber length. The tensile strength of 20%vf shows the mini-
water absorption saturated in 72 h of test. Finally the water mum and maximum value of 15.65 MPa and 18.62 MPa respec-
absorption is increased with increase of fiber content. tively. The percentage increased between the maximum and
A comparison of treated and untreated water absorption test minimum tensile strength for 20%Vf is 15.95%.The 25%vffiber vol-
reveals that water absorption is increased in 35%vf fiber volume ume fraction shows the tensile strength of19.92 MPa, 21.82 MPa,
fraction. The 8.75% and 5% of water absorption showed in 23.5 MPa, 22.16 MPa and 22 MPa for 10 mm, 20 mm, 30 mm,
untreated and treated fiber composite respectively. In this 3.5% 40 mm, 50 mm respectively. Maximum tensile strength of
variance of water absorption between treated and untreated com- 23.5 MPa is obtained for 30 mm fiber length in the present work
posite specimen was due to enrichment of surface roughness by when the percentage volume fraction is 25 because the composite
fiber treatment. have higher fiber ends, bonding and accumulation than the others.
The tensile strength is suddenly reduced to 19.02 MPa-16.45 MPa
and 13.22 MPa-11.52 MPa for different fiber lengths when the per-
3.2. Tensile properties centage of volume fraction is 30%vf and 35%vf respectively. From
this we find the main reason for the reduction in tensile strength
Fig. 4 shows the tensile strength of untreated Acacia fiber com- is the load and stress transfer between the fiber and the resin is
posites compared with the various fiber volume fraction for vari- highly reduced due to the less matrix content in composite.
ous fiber length. The variation of tensile strength depends on Fig. 5 shows the tensile strength of chemically treated Acacia
fiber loading and length of the fiber. The minimum tensile strength fiber composite compared with the various fiber volume fraction
of the composites having 10%vf for 10 mm, 20 mm, 30 mm, 40 mm, for various fiber length. In 10%Vf fiber volume fraction having ten-
50 mm is 9.78 MPa, 11.02 MPa, 12.28 MPa, 11.22 MPa and sile strength of minimum and maximum 11.85 MPa and 15.06 MPa
10.92 MPa respectively. In this 30 mm fiber length shows the max- respectively. In this 30 mm fiber length obtained the maximum
imum strength of 12.28 MPa and minimum of 9.78 MPa for 10 mm tensile strength. The strength found in 15%vf fiber volume fraction
fiber length. In 15%vf fiber volume fraction of tensile strength is 16.22Mpa for 10 mm fiber length and increased to 19.2 MPa for
shows that the value is increased gradually upto 14.45 MPa for 30 mm fiber length and slightly decreased in 40 mm and 50 mm

Fig. 3. Percentage of water absorption verses soaking time for different volume Fig. 5. Effect of tensile strength verses volume fraction of treated Acacia fiber with
fraction of treated Acacia fiber. different fiber lengths.

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K. Sakthi vadivel and P. Govindasamy Materials Today: Proceedings xxx (xxxx) xxx

fiber length, this shows the increase of fiber length because of Fig. 7 shows the flexural strength of chemically treated Acacia
varying volume fraction. In 20%vfthe maximum and minimum fiber composites are compared with the various fiber volume frac-
strength is 23.5 MPa and 20.02 MPa respectively. The 25%vf fiber tions for various fiber lengths. In 10%Vf fiber, volume fraction has
volume fraction shows the tensile strength of 22.62 MPa, flexural strength of minimum and maximum 19.16 MPa and
24.32 MPa, 28.62 MPa, 26.66 MPa and 24.62 MPa for 10 mm, 22.26 MPa respectively. In this 30 mm fiber length obtained the
20 mm, 30 mm, 40 mm, 50 mm respectively. Maximum tensile maximum flexural strength. The strength found in 15%vf fiber vol-
strength of 28.62 MPa is obtained for 30 mm chemically treated ume fraction is 24.02Mpa for 10 mm fiber length and increased to
fiber length and 25%vf fiber loading. The tensile strength are sud- 28 MPa for 30 mm fiber length and slightly decreased in 40 mm
denly reduced to 21.32 MPa-24.98 MPa and 14.25 MPa-16.73 MPa and 50 mm fiber length. The flexural strength for 20%vf shows the
for different fiber lengths when the percentage of volume fraction minimum and maximum value of30.5 MPa and 34.02 MPa respec-
is 30%vf and 35%vf respectively. This could be due to interfacial tively. The 25%vf fiber volume fraction shows the flexural strength
adhesion between the fiber and matrix in addition constructs the of 37.96 MPa, 39.12 MPa, 42.68 MPa, 41 MPa and 40.58 MPa for
debonding leading to a decrease in the tensile strength. 10 mm, 20 mm, 30 mm, 40 mm, 50 mm respectively. Maximum
A comparison on treated and untreated fiber composite, reveals flexural strength of 42.68 MPa was obtained for 30 mm fiber length
that the maximum tensile strength is 28.62MPain treated and in the treated fiber. The flexural strength was suddenly reduced,
23.5 MPa in untreated specimen for 30 mm fiber length and the when the percentage of volume fraction is 30%vf and 35%vf .
maximum value was achieved at 25%vf. In this 17.88% difference A comparison on treated and untreated fiber composite reveals
in tensile strength was due to improvement of fibers surface adhe- that the maximum flexural strength is 42.68 MPa in treated and
sion characteristics by removing natural impurities, as well as, cre- 36.25 MPa in untreated specimen for 30 mm fiber length and the
ating a rough surface structure. The improvement in the tensile maximum value was achieved at 25%vf. In this 15.06% difference
strength of the composites is because at these particular composi- in flexural strength was due to the improvement of fibers surface
tions the Acacia fiber can effectively transfer the load from the roughness by alkali treatment. Compiling tensile and flexural test
matrix. results (Figs. 4-7), it is noticed that the unsaturated polyester resin
reinforced composite gradually increased in alkali treated Acacia
3.3. Flexural properties fiber upto 25% vf of 30 mm fiber length when compared to
untreated.
Fig. 6 shows the flexural strength of untreated Acacia fiber com-
posite compared with the various fiber volume fraction of various 3.4. SEM analysis of composite specimen
fiber length. The variation of flexural strength depends on fiber
loading and length of the fiber. The Minimum flexural strength of The morphology of the fractured surface of tensile specimens of
the composites having 10%vf for 10 mm, 20 mm, 30 mm, 40 mm, composites with untreated and treated fiber were investigated by
50 mm is 16.96 MPa, 18.32 MPa, 19.26 MPa, 18.92 MPa and SEM. Fig. 8 shows the evident of fiber pull-out of 10% vf in tensile
17.24 MPa respectively. In this 30 mm fiber length shows the max- fractured specimen. Fiber pull-out occurs mainly due to poor inter-
imum strength of 19.26 MPa and minimum of 16.96 MPa for facial bonding and limited fiber loading. Fig. 9 shows the SEM
10 mm fiber length. In 15%vf fiber volume fraction of flexural micrograph of tensile fractured specimen of 25%vf. Tensile and
strength shows that the value increased gradually upto flexural strength values have established that the adhesion
25.02 MPa for 30 mm fiber length. The flexural strength for 20%vf between the fiber and matrix was good and the fiber pull-out
shows the minimum and maximum value of 25.12 MPa and was not so predominant.
30.12 MPa respectively. The 25%vf fiber volume fraction show the Fig. 10 show the SEM image of fractured specimen, the result of
flexural strength of 31.46 MPa, 33.96 MPa, 36.25 MPa, 34.98 MPa micrograph was clearly visible on surface roughness of the fiber
and 33.26 MPa for 10 mm, 20 mm, 30 mm, 40 mm, 50 mm respec- and less fibers crack when compared to untreated fiber. The good
tively. Maximum flexural strength of 36.25 MPa was obtained for surface roughness proved that the effective stress transfer from
30 mm fiber length in the present work. The flexural strength the matrix to the fiber. The SEM analysis indicated that the inter-
reduced suddenly when the percentage of volume fraction is 30% facial bonding of matrix-fiber was better defined with treated Aca-
vf and 35%vf. cia fiber.

Fig. 6. Effect of flexural strength verses volume fraction of untreated Acacia fiber Fig. 7. Effect of flexural strength verses volume fraction of treated Acacia fiber with
with different fiber lengths. different fiber lengths.

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K. Sakthi vadivel and P. Govindasamy Materials Today: Proceedings xxx (xxxx) xxx

Fig. 8. SEM micrograph of the fractured specimen of 10%vf (a) Untreated, (b) Treated.

Fig. 9. SEM micrograph of the fractured specimen of 25%vf (a) Untreated, (b) Treated.

Fig. 10. SEM micrograph for surface roughness of the fractured specimen of 25%vf (a) Untreated, (b) Treated.

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K. Sakthi vadivel and P. Govindasamy Materials Today: Proceedings xxx (xxxx) xxx

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Declaration of Competing Interest
performance of industrial hemp fibre reinforced polylactide biocomposites,
Compos. A Appl. Sci. Manuf. 42 (2011) 310–319.
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Technol. Eng. 49 (2010) 45–52.
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Influence of alkaline treatment and fiber loading on the physical and
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