Electro nie Displacement €tlets eae \ / v L Permanent ¢theck« Tarn porary Polavisahion € {ec Effed- CPolavisahion €4eck) CPalarigitit'ty ) ches QO Trductive €ftect Uh) Electromerre fer Lt) amauchemerrc Uh Resonance Mesemeric € [feck ® © Hyper ce nyugs hou sia Effect Oktho effect for aude Strenglh Oke Etteck for Basic Shrevglt Skeric theck ) field chheck . Qe ©zn ductive C4het wh displacement + parla ana perme oc elects towards mora elechenegatve ane 27 atom 1s Known as inductive eftect Ho How © t | I \ —C~C- C— Gan | 1 ( vx H 4 4 h 4 4 4 4 EN lon @& u- (CO H -Ru,> -No, 7 “NF -50,H > 5 = — ~biny UBL 5 e-em >-F p—St? “Br>-I > — “oR > -OH > ~NHy > ~C2CH 7 —Ph 2 CHE CH > << uv Wee @ © Qohaide : =NO2-CN Ho -2on F Ct Br TEcauses for Induclive eeu a vahvily. ——_ (yn elechones @ Differerce er et e. () Cher Re bry brictesatvon SS i wen €& 6 om if €) ot Crh Cy N= ch O 4 6p sp Lom pound Hy britisabin a fa sem Zs EN & BY Ch “Ur, sp? 257% 24g ie sas) | 2-75 4 @) wee | $P 3 Hcecn : nes" SP Dy 4.25 N 5 eg(6) 47% oY ca 2s 3 oO 4 es nw’ Ny SP wy, 3.5_ effet -o2 > -O4 % or LC] 87 OL -OCk YQ -oh " @ “2 ie Wz iB at ciode + @, ~NR,? -84, O17 by yop or + F EHCH (@) +2S The Ae~P usich repo he © - eles is calles +t 4 avs ete 18 k[4 +r chet KA TT . b 4 wv 6S3 leg _¢ +5 b— C—C tO +-Y EN | ! Ux" np 4 h " ny m7” 7s Sys -8, 4-81 o-* OS; + Ob, + Gb = GSorder of sro ng nes of +L Groups 2S @ 9 ? * S € ‘ 26 4 —CH, > —NH >-O > -¢-F >- > «i omy cy % -H-n > -TTz 2? -CD,7 —cH, 77 7D> H iy ¥ ° No +1 No -2 Mme TL Effet c+ —t-0h qroup is If a> Geng Cap-d eel or * oP ee % 1e oetnir or on 6u IN sn oN Avr > a,c-H c—b c— T m7 MF My orvdes * +t Bowd order Ceo) _ = H2gD < T No of bows, present bofus atoms je Bond ene BE Go A erert ne € B.0 & “ AB 2 » Bort ergh GY poze 3 Le os eo 1ZBod2a A=B 268243 ode of Bt con > C-D 7 CHT ovdev te B.o ov BE order G70 cn & C- D GeEle in Vishal, * Inco mple ockele + obi Diamagnenc & Spih mull Pliuhy =2$4l = 2aeott el * EDG (élechor conabng ) + Groups R L4H, tz increases teg Stability of Corbe cah'on © ENG (Elechou witidran’ Grou ) q -R,-H, -L decresses the Stab: Al; of carbo cah'ou, “Com pare the Steely o cay bo canon ® 3 3) up sy ee © Ou, cy ‘3 d ® © © < © 6 @ 4seh -t -T 2 sp? 3? +t > Re se @ E -L* > st 3 St +t Ts C7 © ?“= DG T tte Staeilihy of FREE Laticnl = —_—_—_—____. 4 . “FO “e —_ fk : "4 “7 XN k 4 FRee ews 4 Ledlsicnt & Para mashes _ End T mcreases tee SHEL, of Cavbanrow | E0Gd ‘4 Shy > Sey? Sed re a © S Ce. oN — Hach < H-cn- ChRace Que -\ a- Cm —- @ Die R a) s e g- cw aaa fal T Se 34174 c- Ch Pp fare s N Q Dis a % 7 se 25 6-8 > -ch > Mass A Aue. on at 7D>-4Que. NO 4. (A) yee vcere - @ . oa (A) mee vee ye SY LQ I< 2 < 4c © x s (Ox bus &. Q.? 69°C 8: 3- a, oD O47 005 (a,bdit, Blo «= 3 Y= 6 As ades—-* Te Ee plain The Stapilihy of Free Rochicat x 4 Homolytic ‘\ R 1 ~H + Hx ——__——_ oy 7 Cleavage, 4 Free Radicet hss sev = or bent LLP Teigonal planey +O zéle- in V-She n Incomple octot EDG or ELG (+R, HH +1) T creases Stabs lity FER EWG (-R, -4,-T) & decreases S Heil y BRoa Gia Sit ck bree Rack cals ® : a Cy Oy iy Won >“ . ~s 7 cn 7 he @ oO, 2 eG & Gav * 2>17 J 0 © ‘ Qe cp, qe Ce OOS ' we 2 1 om estes ie © i > o> ro) he © qi - ae ny 3} “ Wn & ; No C2) oO z ee SP, 2 Sia 2 sr eX 6” J ees) a > he ro} 3 sP p> ° SP. 3s ene O wy > Oe 2 ) wo @To Explain the Leal |i ty oF Carbanie™ uw Lig, _fetemirhc © ar cl oA ” ‘ 2ave Fe nf i Cay bane sp? Trigoned Py vam idak Da Ww - E 6o R, -A, -Z) Im cresses ; lt, ot car Loniou EDG = ov ERG C+@, +447) decreases gtala lity cf Cay beauioncarbanion oF Anion compare Sabi fey © < < ont s bs Fes ons & ye 5 ve oie ow o 8 a Ay Cr > Bu? | Ko eo a oO ® Me < o a . ae a 6 S Om, Cen Pn CI 1927473 ° ee wo © w © ca-m < mer Base Lone Lowe pair Acceptor —» Aud purAttic strength [aadic Nature / To bx plas 2 oF Radihy “-A =—— Ho + A sea compegrte Gate Conjugal. Base idtenb § cebon Note: More , QO >O o NetAcc stremal Qe cnt -oH w (~~ off on 273>} ©) A My L e CJ 17372 2) ® oo @ cy ns yenn pe YD 2D 7 oO) iL 41 cb ib oe vo %H 1 oh, O39, n@e F EN © H-F < H-C < Heb < W-T ow a Qu aL wt IL. Bye Ore Be) no & od % By Pir He @ wen gh bor an bon w cr e ~° -t . 6 a A. boon « ee ee aaa < a-F @ <-% cI” @ ao o a. Qo ucey Bowes 6 ee NG @ 4b oO 8 Se uae <4. weze W? - 4 q Ze~ bot @ Hos < ie < o (i ae — SIZE 5 Spon > spon © cH- 4 - ou 3 o@ oOBasic Strength / Basie Nahyre [| Basal, he tendentg +o donste Re pur ot as Basiaty, Zlechors to H® is RY ® Basic Known e@ dengty om nm abom chert, « al a P 2 rQeo Roden + Nach = Q-c-3N* + hw bud Base pe-é-Pee) Ca K, = 2 ? (R-E-24J [nace] Basic streosih x Kee Pk. PKe = — log k, EDG CR, +1,+Z) 4 ncreases 845i ¢ Strens/Z, Ews CR,-47 Zz) J decreases nesic SengeBasic Strength / Basic Nature /Gasiaty eee OO ¥1 Basic Strength x ele density Cc” OM anakhn Sfp abr is Same Epg Tt Basic Streng te TL akboms are di herent f —>- ewG td Basie Basic Strath < a Strang it Stebi lik —————.. St is also appli eble for Same ato msCompare Basic Streng oe oa © Cyl oo SS a A a ft co Sn wo -1 ° 2<3 Oreos oye, us @E oy cH, in, 372>| oC} oy en, = Ra Eee aS eee aor cur > Gps ® aan x 6 as os ieee Gane Py TT ny wr < Ce < cy 3 : ® ¢ _ - 6 Susilly Gy < ME ONC F Basieih, « L BO Stabi be by wo @ @ @ Stability Ee 4 2 2 - - et an @ wh > 28 ree me atmacae oY < i. ¢ Q Oo. wei @ Og-% Say cg 8 op stevie 1e 2 ow 6 ey) Bssich, tor Mtg NI ry +L 4 a . CHT S By” ——Resonance Permanent alo cahisahon oy KR Slechow i4 Canyagabion 1S Known ot Lone prr eles as Re sans ce 4 EssenbHal Gondibon eK cor) ugalad Ses bem for FAGO sce ww Planer Conjugalas Sysbern Q Lone pair conjugatid sith 7 bord “oO = Ce. OGN- n= ) P - = le @ Bums cw) (4 ®Hb-c =u) L« @ @n- coer) nes @. = _ C+ © Gece cn) O : (Mh qy5 SP gh Sp2 59> sp sh se 240) oS r 4 A ~~ ai * sn — a ao A? Sy OO Si . eo Bee pe S +LLp gee Bs SME Bru ace —— ise R-H (3 UVdsy=—cHe Ch <> nwecn= u, QS) Rs2 OS 6S RH _Sl a e ae® Ce CHSC > Cae ene Sa, cet SPE S02 fery eo est Rs2 > spk os gs Cry cH HCH RH 4 Q 2 e@) H-6-C SCH E> 4. Lt sP ose Se Ser se C2 d* les Rs) Ror orara cry Fant points velated to Resonance pate manatees ® qe is permanehle aisplacement ov delocatisate™ cence pay or %K Zlechons. Because ee cernal c——oo ——— reagent’ iw ner oquivack. & © Conyageterr System musk be present In molecule having Resonance. gine ee ete ee aad Cael of, molacste PoP which par ticpae tee terete siete mers las en aie 84s @ the ctructures, which are qenerater dace ke Resonance are kmown as Resonatt Struckies(Rs” oF canonicak structtres. © he intermediate Structure of alk Ris is Kmonn 48 Resonance Hybrid CRA) a" Shuctures on the © ®s are the tmagiy thevhanel RH is the veal Shucture. othe Aw the preper tics of a melecnte ave, iia aces explained by een Cmer By (ies) ® Besonance is nok distance daperelanl etteg-© ner ‘ Charge wemsin constant im a molectl= eve 1s WO exchange ear Resonance, becante ty \ source: ok Electrons fron axkerns 2 at ® The Contribution of mosh stable Ris will be more to irs RO: ve See on The structure AS fo tne most stable RS 08 or characteris hes ef R-W swill be close ar kiculay oe @ The Wy bricdtsation state of & abm reman congtane in ath RS and also an GEIS RA — @® Only bp Slectrors Ov BS Slectrons Unctergoes ¢t —— q de \ocalisabon_in Resonances ATOMS never ——— change wer posiben: @ The amornh of energy relented ave fe Zesonance 's Ratled Resonance Energy aay the PE aiference bw en. arr LES moste gleble aus Uf known 4b RE. ROG Ma eee Oe OF RH = PE of most steble es | a meant ik release that ene typres Drew RS and ée © Coe. OANA on, Oo Sd 9 OK? eG @ im CI OQ As R 4 —_—_____--| 70" © a igs 2 2 2 Fo i. Cm SUG (3) om see > B= 3G RSL ati $ co RSI sf “a Boa oe ee cm OE RH Order & Bo b/w Cad O Rsi > RSL Cstebility ) ovder & Bo C> bre ovdey oF BL Arb>cMEE - Chemistry ALLEN + EXERCISE # O-1 1. Writecorrect orderof: 9 II @ @ KO}}en,~€-0-1 0 (©) Ph-CH, -bo-n v@ cH,-cn,—~cn-b-0-H - l eye i (© CH,-CH,-CH,-C-O-1 Gip@a-cu,-b-o-1 = clo © a-g-d-0-H cl a ez $ 4L L m +L (© CH-G-O-H ” pH, *e I i we/ Mes 2 is nce Pox © ox t oe coon 7 } . wel > cH, 5 Oa 7 7c} 160” cooH CH, -COOH i CD@HF CG WHA LZ One < w@Ht S/2e i 2 Giin@CH, << ON, C OHO ¢ MEF EW 1 “4 i Go B-CH,-CH,-0-H Lino} Hs CHO dvb 3 asc eS oa 2 L eG}CH,-CH-o-n -t G@Niryen-ci =Eth-O-_ By 9 @@CHCOOH —)CHCHOH @GHON —W GH,SO,H 5 j . E dic strength of following compounds : 9° () E-CH,-¢-0-H APL 7C7A (@cH,-cu -C-0-1 9 () cu,-cu-cn,-¢-0-4 t Dis Hm cee en avlbl>e 1 t (b) CI-CH-C-O-H. e > b >G | a@) Vacant b- ovbitet Conjugaredt Wilh —_—_ — K bond @ en. eye cnt CH o> Cys cn en,“@ alee Cn oe a= co ku ser SP en oF Ase Rs) cu ¢ =e aA . So ui NP een - Zenker Bacn-% Se RS! Qsr nres _, & B= CH cH "sep 4 4 w-s a G 3 To QD A" auu AN @ nee N—CHe CH XK NO 7 2sonsCe wv * pace @“@ Draw Ro & LY © Oo” ®en, «@ CT «© >= Sn, ( = @ Free Radi cod Gonj uy rtesi vst K bend a be AR ar _Ve @M MWeawe wo 1: i 7 wa w Qs) sr NL of . $4 Sdn ek uZ% eu aey Ben , sy ” FR w Qs @ trot Rk 4 w O © A\f\F cH@® ® bond conjugatar wilh K bend %_kond comjug Ar ih ees a WN OL Gyetne a-& Sn-cneen mes Low CHE th A= R52. “4 es3 ©. Rsi x) L egeen oa Qu Staley li rk, Oreler oF B.0 RSI >> Rs2= RS3 b=c >@ order of St a> bic mo {e @ S D ence nn Mord See SO Se SP © “se Rs) ‘ a & f Le. “1 Cazcn= cHicy Stability, R.4 s z onter of 8:2 mee crane. order of BL brareRMA Draw RS ane RY Cae oh -C=so Co E: @q7 OA Cuy- NYS — 4—Nep 2 SS as) @ we Rsv c4H- Na SE ‘eee R4© a-orbitel Resonance __—"n . Cv acent ae ovloitel con as atte wi Th Lone por .. S or, @3) ci Grin, Co uaF RA (bx- An) 7 esi gt et asa Clnn Vacant f orbileA [esi SF GUA StrergMm (1) eQ)@® Compare Prudiic Shang os (2y SRCompare AGAIC Sher [ft EE Col< Cl on, -S 4 aw o (2) & dr | - ro Se S aT © vacent pievbitel cojuyates With Lon, pair a ) Lf Lig “Sa Be ~~ Rs! “7 es.” Se? 4 a Re Gt Asp Rsrw ea Na Comple (= octlle fur ail atoms© a 4 — ch =8— c* RS) as2r Cy o— ca SHG we Rm Rr < RS2 G6) Draw fs © FN Comp late oct, fer Cr al atom — vacant d with fp Vacont P wis Ap.~~ ~ARomati€ conn] ANTIARO Conan POMRA must feller! > Com pounsh mult] Compound which Hacker! Mekel's vule Le mack | ‘ . nm cae z sno ymahie heave Unig Glecheng (F nok Aso hav Ve Cinta) Zlechors eae - = ee orale « Rem 2G to we fed= & BE Ane avomabe $i fed into PR Compound mest bePlney 9 Compound mish a Daa Now Avemahe SermNECocron a > Compornet musi cone © 3] Compound muck be uydlic be gave _— [notes ap any CD A} compouna mush heave} | Celie atom is sp OY | Bjdlic Aclecalsabron 2 Compound mus have oydic CaQegabOn OF | then com pou mea tectesc Be Wie a eae ee) | -ake CO | op trckel'S «clad A cyclic Delocabicab's in Qn a ae inal ». Won _Premah'e : —— 4 COMPOtNA Musk A Cor pound follows Above 4ol\ \ 4 Rules fov ARMS +>: AROMATIC. Anti Aremafic — Z e 2 eS) _ «8 O ‘ @ tm - it: ue & kl ape “ ae Now Aromas ev ce q ch — Se one - 9 Ru RSI ad ge lsravily Roi = K so their contributed , ordey of BO aab + order of BL > ach vw Sb Same te Ryguiz -O anes 8 Que\ EIND OUT THE CORRECT OLDER OF BonD LENGTH @ ~ os vo-u4 © Cc Or +e Que -2 . hod, N: hich is more Basie 1\Gf2 Ni or Nao and explain why ? Que3 compare Bond energy a © wt Os eS One 4 Compare stabs lity ty of Garbecahou aa a @® ® ©Ques Compare audic Strong ir Cn, — CH, 0-4 cu = Ch-0-4 S C) Que 6 Compare Stebilih, of anion g: = i a Og © oe © Que7 Compare Basic Strensglh bo, adder 6 / 2 L Ave 8 How mane R.s ave pe ssrele with 8 @ an le9S 6 El t 2 ‘Q = @ 6Cre He | ® pm Ce CDE jo rele A @Q /--\.0 le I| lo cE NSN —/ co ARO- oa La plas zle @ won ee / a te repulsion fw Hydrosens > NON Aromahe —— plone cD - wt O Amvulene looe, pee 9 we ~>y NY — Kost, wy oe Lee s . 4 ° phe vas RSI 6néle We ne Pe Rsr Lup-3 cv cD ence Feso) prez > Peri feral Resonance (or Gcumter @) Ge 14h ele: tH Pe cM SS ane So = 1aA ele 4 “ Pi ce col y XvAnnulene in- M . ane cy clic Ag dr carbons having ablernsle double bords 42 called Annuleve of @ nnulene —& 2, . &) Prrvuleneale Proanide ne.-8¥b Mele -@ i Monocpeli'e com pounds having 7 Yhan 7 membered Ying will nok exi¢k Anti Ayomat'e , or mere | Converted into NOn-planery Shucktre. Shab! oe oroley Avema he com pound c — Anvu lane -& in becauie the Shuckrre won Aremah'c) Nome Ant Are mah Q pecs mabe Oh potent composts — Patt Poe ma hie Compound © 2 Ww EEE Sr emtth ‘inte bub shape AI 2, neaglaner ak room Temp —Ler- Non _Acomabic envelope“ Non planer Vee Nom Aroma ny ae Bore ® ay Soya SFR chive Freer Compound ic Aromat, a Aig Compound Bill be Preah @O-G ®A-h~ NON Premah’e, Avaaasee oie Are mache zat Rs eriatied Rs pas 5 Compomna is Agomaric Compound 1S AROMAT I< SeanQuasi Ayomaho The Com pounst _ astch BL comes polar to alan avomaticty oy The compound 7A tsnich Chavge also unde gees wclic delocalisahon alors Lsith Huckels A - ees is Called Quast Ara mars compared, en ane Bo a coe Gales He ee ce COUwt Qo oF a J CaP — dg * Ge © Z qa 2 aromas CP? = QO psi RS) ASD ore Noe H Quasi Promahe compounds are polav, 4 Soluble in pola, Solve ne a They Ave heghl re ble eee Sdenk by the Con poured s l.e@ Same ov vel. s @ / they we ®,, gs. Toe are a fhe ent (2- di Dewbero wor port uycte acta -1, 3,5, 7- Cetrs ene 1B-D/ pectere « « D ) a my P iDimers cgahor -- ee Fox ma hen 4 Dimer ‘s as Dime risation. Known Dimer © A =O Dimerisahon on prowahic “Oo &) pol) it form dimer f Ass No CS#er/S banelre nce) Vt can form Dime © oe ax nn oeRelabice WON & Ks ah complete ooinle for oll alors Az poroma icity a) Le covelent worays neatred > cope (70) E o- 2 Ga) om Sets ao m-< =a 4 @si ese psia &sv @ Sl a4 < CA-4s0 er Ma CN? asi Pow bs) SG ase >) —~2, . Gkr- 6 co Ko a© OP ~ EP Extended . . Conjugation CSS CONDUG abies Wasi > RSE <3 — OPM, — BSG Ex lence ese conju anion > Cres eeujuganes a ua eS '® \ S ‘a @ oy hen Pa, oa ty- NO bu cae ot. u Rs\ * RS RSs) < R52 op posit charts *") © Gre cles ree . (76) Ch-0- Cas curd . s " 4 (H-O-Cu— Cus C4 ee RS2 lora paw -Ve repulsion,Mesomeric E ftect : ae “ Participation of mesomeric_JvOuP in Resonance ts callest itesemene a 20 °Oe oe = oo mM. Geoup x \ cor M.E fect x Resensnce — M. Group e3@) M- € theck — Mesameric 9 TroMyp -™ Wg Reso —MesomericC qrdups are eh two pes eT zé © +™ ov «R Grup. CEPS “ ERS) @® -» & — @ Gh (Ew G) ® 4M ov +R Grp ERG ow 204) The Grup ushich wea\ease the Electros ts Cal [ed +m (+8 t Group Ldentks cation K g yes? , aX. ~A 5 «® om x tm Ca as “Through Ves oNanceorder of Strovgress of +m /+R Group S @ eo... . - thy, > — Hn > -8: 2 NR, > Ayr -Bu> BA o o —— : yew WSZ ck Gu +m of —oh > -6R e ” 5 ok 5 e 10 16 -Ci. “ $ CoD ©) generis = = m Co le ls ig attect orde® by wiky Zlechon densi G in Benzene” rive 47 b7¢—M_ ew -h uvewp CE W <) the qroup which Withdraw the eleches Throvgh regan nance is Called —m lr _—oxdev of Strovgness of —m qroupt Fn > - Rn >-NO, > —Eear- cn > So ? e — e ye oS Heer po 827 > fia, eh. nN oc ¢ Aed otariva Give tool le No, SN Hen : tu he ene vi 4 compare electtn dan sity fe Benzene eas Gi ok ea Le ees Laz 5 jn BSerngzene > dens, in 3 HH tom pare ee *. vies, o a> OD yaar — -t > 7 oPrk Identify the nate ok yeep c We AM Ty RS Sano - i = z aM fam | azn] -2 +H a 6H u- - _8n, ko le ee Se ue e @| — 2 vile —_ . — _ _ re) _ @ - - ? =, —S-06 “@ t oS uw — Ee ® _ © ~~ O/ce FY FL (9) |(10) 1 (12) \(13) (14) @ 8) [cals CS CF 0 0 “|i AC ~ as). A (16) wa cagy | a9) | Qo) Ya (2) sty] olodo Non glen 3) a (CD C8) uh O o ES O30 \cd ee 29) O om pee on “A @3) en ee ACO uw go OKs se / 5 on {cs 6) (ca k FOor w By percanjugatiom [we bond reionance | ome Cong ther etfeck Permanent delocelisabon et yg) [> ere we ob XEN LEI Te momen onto Kmown as Hy pereonsugah’on : ® sO ‘ ® ©) “ p | Res i Meee ape Oe sa meanness ae rene (AYE, 0-6 asa SR ESTA 4 , 134) Vaan 3 ‘3 a 139 02 Ps 2 an Lan dh as Hy percon gag bien in AI Kene asians) ews iti ae Tem portant points ralabhed te ay perce njygahon ae ae ; ga carban ov ©. @ career abachsl fs double bent louble ber’ ca carken asd by droq ens = “a akiichad to % carbon are Krenn as ny AO gens, aaa i ® Vy briats ahion Stoke off 4— Gren Con ver heat ce is Known as trom sp? te sr im Hy percorgrag aor? ae ae 7 6 More the number ob X- Wy deg O78 , more wil cs caitlin ee eam be tha Vy per Gryeg then shuctirs canich verls more stabil alkene, ar cavbocahn 9 ‘ ——— eres Racki’cats ——Hy percenjugabew in Carbe cahow Hy pey cenyusa hon iy ER i) o h u eet” BAe lee: 4 —_— ae cme Cl, —_ ots Nu 1 TSG ° A . Zan & 1 ~ 4 ‘ =¢ a -£ FG 4 wCompare the shebility ot Alkene OO OL EL te uo ii) Co an Uah on You nolv> ao dy a new " might Bt © 4 > =7 9 XY ~‘S 7 cae GH Giyt Cw) w () et “A, ef Cxu r HR QQ 4c. 2 re = ed see Oe 4” ave on LU certen wy A no Pe he oH 8 4 eve onic is more Stele fina —vnen L pa butene Gy is mere ENG —veow Vo Carton 2° carbon Fag 2 - GuileAN AY AW ity 2. |- hexene V- hexene Ze ex ene van s dy - CECH yen? Gy ish alkare > AIEyne Cay per cen yes aber) = Comment tes iene CH Coe CO cec7s 788 He-S= Con jug sted diene nett Ai eneCompare (a Ceability oft Carbace hou @® Ae? A @ rn > ® 4 > , C2” as £@ Ac. «OQ SO go bok. 1 wy we cn mele o 2 2 (i > = 6 2 Ee or ere " —~@ nD ci an yy) ~ R474 Wn Ragen OY an ad a i> > u>l ——————_:: T @ ge @ ® dc Less @® o4-% > cds ty S wo T ae order -C% > — -SB aCompare stabi Why ot en ® A? A? nn & @ se ora © 1 coco Ol — eo — cen R47KL R4udn 7k w% . - @ DO7Rit iy 5 xn Gin “ - —_ BAu Bau (Voarrv Byedt'S Rule un stable od spr alom Is Bridge head until One of The OY im bicgels compounds Contain min @ atows. @ S Z t ® cpt spr uns Pele Uas ble No Bredt S rule. A ceeNete Bredtis cule is nok applicable for these big Cle Compounds obick has Zero Carbon Bridge ig preset 2 op ° SI ® . 7 Ze re carbon wridoe Gusbable —____——_ t nel +s rule is Bred applicable T , t —_—_—- aoe bredt S$ vule is appl'ce ble imQue 20 Honing ny Pe oS) jug able <-11 ave present ~ falleng Compound Ay" ® Ot Unskeb/e mpere Sheol J, cree EM tO bradt ase rule, cio Cc Cor Gx _— : =L'>CL> uw TT “4 Seb ly) @ " Sas Ms. —_—Heat ok Hy droqenshon Hou) DE The amount oF energy weleased Wg tro gem bem Ce additien of 4) ducivy is Called HOH, #@©® Cw +4 . + Bus Bek ene of 7 bovdls Heal *; Wydragenabon « | s Hon thy oF al (@) Compare HoH Keng a > Sri, joy iy MJ order af 07 wea tid t> fF. case DM Aleenes havivg Sam ex u te fe — eS Com pare row —_—— Ti &e ot ae cy oy shel ii > o> i Hon (>>!cese@ aE Ne EG 1 bods ave dered eM ore eens "@ Ano AWY WV w 2] CO pow . fin ii! wf pon & We t bovds yd <2 compare How ordev of Mow . te 0 O aa ica Ka Vip U> YL " (ds) jw ot po x ci eM +m du2 232 WL, dane -oky,,., oOo S&S oF oOcase@ lton ply oud / Steb “hy SF each K bors, 2G) lompere Hom per 7 eet Ree Any NMG 4WNY eS) © © Horm Ho Wo ae 7 > Hoh a eer « 69) Compare How pw bond em eo hove Hove a \ "eS re UsHeak ok Com bu stion CHoc) ISO SSN The ameounk of enegy yeleased dix to burning (Complete oxidtier) of Organic Com pound is Called Heat t Com bushon (Hod). + A= -2717 al) “\Z + 60, —> 40, * 4 no — t Krol [-butene — Hoc Case-\ ab No- of Carbons are di fperenh ———————————— | Hoc x wo of Car bons | Comp are How N=/ SY Ce ne cn cw io CR) order of Hoe 1riirlt >@ ortey of Hon pet 75 >Zcase@) Hoc fev isomers alkene (Same me) Hoc a Kh Stability of Akkene =".@ Comp sre HOC 7 co co W >i. oy Hon ay 4h Gi) aan tee evanple —_— useQ boc per Carbon (© pe wen, ) CM" tec ture ) _ | Sta bili by of each carbon (ot Pe ) er @ compart HOC pe CMe (a per <) SA aaa ® © @ @ HOC Ho He Hole Hec@ Ae 7 SO FOS C4504 LOC fer jSomeriG AKENE =—_ ew | Hot « Suv fece ares 4 So meric UAKSHR Branching | eo compare Hoc iN > > GS?Resonance Ene fy Cee d4° Hee 2~ cunt of enogy weleased Aue resonance is Called RE- oR. . table RS Pe ad fevence b/w RH amt 1 most § “* is Known as RE- S Re = pe gan pe f mast sue § €= -vet 4 caseQ) faster fhe resonance , more RE @® Promali > NOW hromshe > Anh) Armaoh'c en, a Conpere RE ~@ _w @ Ar O?> @ w me Gi wl. a “® A ? 7 » A. Gi, wa. en aw aw au pmb’© Equivelerl ey pe ks bas faster Resonance mere Re) Than non equivalent by pe £4 C OTR, neon be “~S.. aS) Oy — SNS @ie ’ 1 e @ es =P 6 er Cy £30 ° ase Shaeilih, esr 2 a5 asi > 52 hse as OE Zu L.€ arb © RE ot Come POU nd havieg Stable. RS Aas moreRE Then the compound having less crabie, 5. 4 @ \ s 25 [/ NS ols Zon erm 7 6 S aN IN © fuvan. —_— Y Rear. 4@ Re of ex tended Con juzahon is wore than Cvoss cor yugaren. eG) Come are RE 2 ALF Wye @) @ Cross conjuge bor Setended R.€ a? 6. conyugaher @® £ e fo ~/ IG tO) @ ® cse@ RE of lorg eoayaga Ben BS oe Se is mere Than Short conyagren «(@) Com pare ee @ ° F Ing > WES Cyr ee 2 ® aw @ long thatcasey) Fries Role More the ben3zened CBengene like) & huchere, move will be tne SE OY BOK MORO Rez -IS2x2= 304 RE 2-297 KI /mole KS fad — “@ Corre pe ; ene GAS Cae ane = GRE, y ¥ \L ole ZT a < oN. @ aw note © +m Slightly increases @€. o. @® Compare RE wete:@ ke is Comparast b/w different compowrds, (WeT b/w aiffarent Ro of Same Com pour) = () Compsre RE oe @ a7 KR ww Gi ob bse esuRota hon Borrier Energy (RBE) The min Amount oF energy require for across e_-bond S$ collet RGE (ase ~ ae] 4.Cla lam pare RABE yorahow wt % - we neoy Cry -h— —¢ Cty he % a 4- 4 + @ © © So [es >a ] L£>ho >: ese [b> <7” @ Bons over B< arb >cra ape 7d. RGEBoy Be / bres BL e® AL Out® 3-2 ~R2O~§ se PA vs Bo OO ETO ao ee ae Bt 2 ope7? - bare ave b> sik @oSe °F —- Le _ at. at Ny bee ° “me of ar er (4) a a. a be y7% a 7, AA “4 t Qr. ~ 277 x 7 Qo = © oe @ CG aa B-o “— _ a a) <-@ a>s adn ! 3 adh ar. bee Bo bs& Compare BG @rx se Ene Gane aae — = / — ~ Oo7l_ l - Co _ = ase Asru a - une gae Bot a vb Z = BL= vo Qs) > US2=LB Kel ———— — bs lane our i) compare BL 7 io Orcr Y- C Bo -*77 no / cor oe 2 17% fel - — @) (om pave GE et l He We & < > — a) o ) 4, : tats HE a sea ly EO ijpi>- 4 wy BE (5) Worpare bE qr As ——_——_ wo 277d Ce —frar Br C4 2145 -r ® 1 a 2 ® ® Ae {-8 te lL. De J a Cy ee “NN geal Sti lity BE c> bFe ot cocompare stebi Ily of _ corte oh (ewe) a @® ° 2 e @ afer (D7 OFS 7 OR” we CD? Oe Qe or @ —a-a? jo 7 a ae & ee on 5 ey? es > ah =~ = a) +E a @ enone setts & os ay Om a To ] bey cr? CQ ( Levars emit ( aay yi+n att i} © C4 o sent “tL sesomerie tect Cte, om) or Hype orjageten eqech Con oh) apenas fram ovme “ hens C wot from mets) C+t ow 2) eperele ant very less gon is Ais Hence cteperdent, ¢ 4 fe Os oom oY Ana Lor - f] - my a We —~ 5 = sults yee i IF | a pars pos? VIP) Luduchve effeck drm othe > mer para position ah? itCompare stebi lily cf canbocalnen Compare stabil” @ On, Oa v= per "gfe Sad Ch cr Clave oO oO w a mr a) @>irg emJal tt On a -te oO oom Ou Ou. ’ = ~ = &) a ou mo v= -Lop7vo0 TET tm Oy On = ® cm - a @& co as gp >) 1977 DP “t den OS a) © w © Q ® Z ae - © Sp 8d > Y, ? re Resoner’ co Resonance [” Dancing hesonence Ve. yet ao 5 wo “e. Q @ eh — 6 a wo = »f = ss o> aol lo Od SN gm yewisr Te CAN ayia 9 oe oeSiR CHect CSteric Inhibifior of reso nance) eS Tbilisi Hen Resonane Awe te Steric iwdlyance is cated SIR effec « @ © @ Essenhal wradihou fov SIR eect. cons. A) Both G at Ga mash bul kay : Yead Fo oo N Tromp other than smaNer grep are Baky TO Comt @ nileash one Freep CG) ow G2) myr be SP™ wenen Vr atkithed ty beniene yi . Note. More the bulkier 97O4P, more eHective —_— SIR effect.pre Sdewiky the Lom pound Ta whith CI eters '5 present an SP san @ *C os ® car a) ca? s eB “> = & Dey L ” @ xanee be cr tS io mn os ee set GS Ser q Relahve sree bile Free Radical OO 7 OF 2” are eat At te. rhe ns ? en +t Resonenie 4A, +L cow Compare grab li by -€ Compare sremility ad Relahve Seo Liky, of catbanion 2 Oo 2-o7o" > ayer - rE 2 2 2 rar yr? 7 Ae “es 2 :2 s& ve? 41compare Stebill oF Core anion wae S ? se Ost @ 8@ Peeidic Srenglh ov adic NeAne adic Ses as s Oo +4 & HA =e OH A njugete Suse Pride chersth A stately os eye Compare adic thensg i rT vA a u P “re “s Ron a ge" es pk OO peudic ng LElectronic Displacement Effects Q.27 In the given pair of compounds select the one in each pair having hi ey 7 es : @ 8 ana f \ @cu,=cu-6-cu= cH, and eae Neca N u & < v Nf Np =CH-NH and HN=CH-NH Qpn- at mic, CH-Br . < CH, OH w) oO and CH, =CH-CH, wo ST and Oo ~ 0 o ee oT ems On. p= Cit-ontang Ch, Seen OATS and ANANA > < cat . @)cu,coon and CH,COONa CH-OH (3 COS-C" OO 200 fies, a ow |] and CH, = CH - CH = CH-CH = CH, Q.28 In the given pair of compounds select the one in each pair having lesser resonance energy 2 Pal Avo > eS : (a) COF and HCO” Bw , SF (b) [>e and CH, = CH - CH; =e eo a < © @ p> and CH, = CH - GH, © Q.29 In which of the following pairs first one is having more resonance energy than the second one - > 2 A445 a woAW.O é Pah ve oy. 2 AN, (D) None of these ee cao j i 1 i EJEE-Chemistry ALLEN Q.30 In which of the following molecules x electron density in ring is minimum, Xo; No} oct S NO» oO Ol © oO ° HN Xo, Q.31 In which of the following molecules m~ electron density in ring is maximum SP NH; OCH “ cor ao © oO (>) co Q.32 Arrange following compounds in decreasing order of reactivity of ring towards attack of electron van em on, ote, ye CH, H—C—CH, CH,—C—CH, H—C—CH, QO 6G a © oO 2B (A)i> ii> ili > iv (B)ili>iv>ii>i (Ci>iv ii © (i> i> iv>iit Q.33 In which of the following molecule all the effect namely inductive, mesomeric & hyperconjugation Os oa ‘6m oD ae & Hy uid 8 LE Q.34 Which one of the following molecules has all the effect, namely inductive, mesomeric and hyperconjugative? «ci (B) CH,-CH = CH, (© CH, -CH=CH-C-CH, (D) CH, = CH-CH=CH, 0 Q.35 Select the correct statement (i) Delocalisation of c-electron is hyperconjugation (Gi) Delocalisation of n-electron is resonance, (ii Permanent pa ductive effect (A)i&ili (Byii Rit iki (yi displacement of o-electron is iii 36 Which of the following compound is correctly matched with number of hyperconjugating structures (involving C—H bond) “Se oro © SAR) CH=CH, 6)Acce ae ORTHO EFecer cag reat CHOY Cin cheery Ortho Subs h'ta Fes Bengzoic acd (Subshinted by eo ie Mes einen Boley, Gob) Ts move acide then ibis corresponding mek on pana _dubstr titel benzoic ad eed tue bo sia (steric inhibibon of resonant), which is Kmown 4s ovthe Effech fer actly , t(Pcompare aide S$ tremalt cas pete. uk of PARE ey fm iS ae Gah ES Os Cree EC = € si a = Pia eso memes ite ese sheng tt [SEB hs ory mien ~~ 0 ve edfechve @ ee < C move welley qronp, mere oH Sie 2 . @ ortho Her @>TmD ® HE CHE CH Be SOE ° . ro give mo > R-t-on QD hs > R-C-o D> ho-C-2 ws — “ oe o oe tine, © eye en & ceen & Cg OR pte (Ae “ yale 4 re Ma 7 He 7 Me + yt AleesBasic Stveng ih / Basig Nateve / Bosraly qe tentenry te donald the pur Slechous is Known 95 Basiat, Gr Basie strenght, ) to He oe Gwangth « Ele densinty tL Basie shrengte «x Ky x PKe Base K L Shrengh, Gfab! Wit Compar@ Basic Shreng7h . pe cna, 6 cm - CRo oF. C8 ‘oa uM m4 PS en cu LA o aX \ <4 2 cy hg o™s ae 5 " 77g eyORTHO Effect FoR pasictty Csi) ee ee Wyant : Okthe Subse titled aniline CSuberé tuted bg bidleg- qemp isles Batic than its corresponding — mua oh pana Subst rulil aniline, due yo siP Csterie inbhit/hon of prrtenahen), whieh je Know™ ee EE a oaths elfect for Basre! de Lompare Basic strength . ny ye ieee ny were aN wa omy ett Lowey, jee i Son7e? © or Th, oa tL ies) x ni Ne rere eo a NS] i <—_ a we 5 ee 1 ped inom (3) ER amReachow ssesf Problems OD were lou “A-Cecow66 6 Sox roe S Tio aed I Iv cH, oor (A) CH=C=CH, (B) CH,-CH=CH, Wored-circr, mr caegecr, % [acer Electronic Displacement Effects EEN @Oo— Co QO psy ee 7 6? YORE Cae ses anfhrcccanonich sites of naphthalene. Examine them and find correct statement among, the following : (A) All C=C bonds are of same length (B) Cl - C2 bond is shorter than C2 - C3 bond. (C) Cl - C2 bond is longer than C2 - C3 bond (D) None Q.38 Which of the following has longest C - O bond : © 9 wey oC oC ot ti Gu iy yh oe Uat2t 7% 1} \ Among these compounds, the correct order of C— N bond lengths is : “ ()IV>I>I> I (B)I>1>11>1V (I> 1>1>1V_ (D)II>1>1V>1 Q40 CL bond is shortest in ro wer ee or oN Li (A) (B) (C) 7 ( CT ( CT Qu Which of the following molecule has longest C=C bond length ? : CH, e+ ¥ (A) CH, 'H, (B) CH,-CH=CH, (C) CH,-(-CH=CH, (D) CH-C= Hi, i 3am CH, +H CH, any Q.42 Which of the following molecule has shortest C=C bond length ? o se Hy Q.43 C—C and C=C bond lengths are unequal in: (ae (A) Benzene 5G 1.3-dutediccne YG 1.3-cyctohexa-d-ene oC) AS Q-44 Among the following molecules, the correct order of C- C bond length is (C,H, is benzene) (A) GH, > CH, > CyH, > CH (B) CH >C,H,> CH, > CH, (C) GH, > CH, > CyH, > CoH, (D) GH, > CH, > CH, > CoH,JEE-Chemistry 2 ALLEX 3 0H9* cu LcH-no, 1 cn o= CBG ote CH,=CH-NO, Il Gy 38 7 79 CH, = CH-Cl mM Zz? Uv oe cH, Vv Which of the following is the correct order of C-C bond lengths among these compounds : inners (B)IV>UI>H>1 (C)I>IN>I>1V (D)H>1I>1>1V Q.46 Which of the following is (are) the correct order of bond lengths : WhC-C>C=C>CHC>C=aN (B)C=N>C=O0>C=C WOC=C>C=N>C=0 WyC-C>C=C>cacoc-1 OF Q.47 In which of the following pairs, indicated bond havit aay fa) Oe and CH, a (6) Clax CH t 'ss bond dissociation energy = < (b) CH;-C=CH and HC=2CH weit i CH=Cil,and_ CH, H ae CHy (d) C, and DN cyan, ‘O i ft It One Son, Say Q.48 In which of the following pai indicated bond is of greater strength : (@) CH,-CH,—Br and CH, -CH (b) CH, -CH=cH= t > rand CH; -CH-CHy a Br ° oy © cuy~ Nerand CH, -CH, Z6l @ CH, =CHECH =CH, and CH, =CHl, zCH;—CH, < ca, (©) CH, =CH;CH=CH, and CH,=CH3NO, () l-— and i cme : Sa Call Call Ku alIn] cea oe som tibet en dig CRONE BEAM EMT Electronic Displacement Ejfets HH : < shal a aa CH-CH-H “ss at ie the correct order of bond dissociation energy (provided bond undergoes homolytic cleavage): (A) C-H> C-H>C!-H>C!-H (B) C-H > C-H>C!-H>Ct-H (©) CLH> CLH>C?-H>@)-H 4D) Cl-H> CL H>C)-H>C-H Q.50 Compare the C-N bond-length in the following species: uN) WX p20 ar ore a) “ @ SS? © Be C7 ers q 2 ° 6) Q.51 In which case, C ~ O bond length is shorter for I compound : (B) Ce or oOpe L devi the Compountg) which react with Dil Naou dissolve with pif Nao.) : Cov on on r oy $25" coa-™ onsen _ = = £ babii # Reachons with nantes a ® Fy at BO> Gry boo Heo - é Sneeo aes NF 44-0 L a “ cA save w.Base {~ 20 cele eo e wa POD & yc ltens pols — — —_ tm Base Sebi, #4 Base Reaction Favoured — SB in Fwd diveckou s@ aod sat SG jf! wel Tne Compound Bich is mere acetic Syn : noe thong Cov para mobaphel Sy) sir velene co, with NaH COR. No,prob. whi , Sdanlify Tae com pownd ) Which yaleate Co, with NaHeo,, r@) any Reon @ om, ~®au & $23" To . orn’ een 2 tte OM @ a NGhto3 -@* ive ' ol ae GHCo, ” Picvic N s car tool < 2 “ no aul H-0 hy a SG om wa Co C) R-of Thay 4° wok s @”° : 20 vo} 2ase @ I Co, wilh no ‘o Squaric seit Nancoy oO” od , N ar» weyReachon with ma Q PO wae? 2 ee @ R-c-o"" aa” R- Cond + Ww ke ah ? fo! Gs tH © Re-o-mn MOF | 2 o@, —_— R-é-0 Mgr + cut. 2 22 © R-<2-4 NG Ne r,s 2 LN ———>_—k-« One + 4 nse bl US EON Qa homshe(") ch ~ sbcls oss A Sole ich 45 5(A) Sen, Vem (A) 8 WArt@ ppt S) © oO 2 Oo: ® oer povp mah'e ya Te © 6&3 )- 71 1” oO cermus _x Pro dhe =Separahon of organit Compotnd from Their mixtire al Salven 1 ; ' AMINE INVERSION Cétpeng = Solvent Umbrella a4 Lnversion of Lone paw + ae nibeg en is Known «3 GmMmMe Mversion C plibbng ) Rg @) Ou a y® . a Ay = ‘ =—— be ‘ Ney = 0) SHS TS CSP™ character) x @ Bord angle tre" ® TS Babky gro esily undergoes 7 . PE JN Hipbirg @ ®nete only grt period Clemenk Show Fup ring 5» Ge Qe Bt 41~ ZINN, eh Rar es ma “ —— ® © 9 sPrabrd st Ym ch period clemerts £0 met % Show 4libpi “4 Cc Reason Severn ing effect ) gph akon in & menbered U membered ving ov bridge lized aban do rel Show Hippirg @ 6) SNAG, x yo xX Ls Basie set Bor Shee Flipping Resson angle Qeain. oo 77 ‘ Crs ot oe oe) a Clippig uP Note = my “9 wy der rapars Basicthy Azre ° CTs 7 an a are, © ————_—TSOomMERIS™ Ba eee Lame Di flevent Compounds h oh Molecular formula Cur), bul di Her ent tm alleadt one pi icakh or chemi cak property are Knann as iomert and ericson, thely velationship (s Kmown 48 {som HAP Tiomers have same Molecular formula (MF) waight Cm) Mame molecnler fees Gage ee CUD) poe/pou/ rnd Tsomers have Tiomernt have Thomery have Same ae c Tiomers ave diferent in wmplele lvpadc name ¢ < inducing Lsomers ave, didterenk j So a He in akleast pe comme. ome Physical oy chemical Po Noke: Beal isomen have fame Me bak dilbert —- oes TS kteve in complete. WR AC Name anol Gan ot Separatig fom ach other ab wom temperature, dup Note "Con formahions (or con formes) Wn REE a ee es —— es iSomers | because hey inbey convert inke eachother vo fash AF Room tem Soh is AcdionlE bo ceperate them ob eeIndex of 4ydagen de tice CzHDa) of Un$eahyr shios C pov) or Degree ov Double bond eqicualent ( dee) No of Vy malecules we quired be banvar Satya test into Spen chain que gwes com powed known as THOT Dov neutral Compound |s oy DAE case co mpownd is given &y MF @ foe Warcerben $ ee 1H oO CyHg po CuMin Conn +s) LHD (peu © CoH, THD20 ® Le Hay ~ Ce Hig DoE © “eng fe Sew DGE© a haleg ee is pracenr in ME _—————_——— a sVw—“_owoOO —x +H Ga cl © fe Hs C! — > Cg Ha CeMig +H —Gv, -F ca Cou @ Ce Hy By Footy Cu te 0 ‘ +2H © % exyge ts preseuk yo ME 9gneve Oxy ger nL “2 cyte cg, 4eo Cube _~ He mae DGBEI -° Ceo. tt Coy &) Hea ———3 See P-7 DOF Hh DBE © 2b Ni bdgen is) present _ > —N -H —-N i c Cc Cs Hh Ss H, N —~J s To 7 Ss t —4 0GE=-!Case @ of halide, oxy g@n, NIbVIEL awe preset _ WW m0109—_'_—'1 —~ +H —o —-n -4 -F +n u om @ nerve T4 aK toe —3o —-N -" DoE =¥ th +H (Hahide en) Oxyaen -u eS) Qi tragen negativeCae@) Sh Comporrd 1S given by Shuchrre oh ee | Kn bons = 1 D@t ovfrHD 1 Riny = ! DBE a ex @ Cie C4 ~, C4 fmcue cuP = . SH Hs CHE CHE CH, New CH.Me Me Ph Y | (a) Me-C*—(b) Ph—-C" Me Ph aun lan gtuee Gu, &, awa) ©) © = oe an wo © oO - Bob’ bw Electronic Displacement Effects a ch oe cp are: au 42 “He HE © @ CH Me, CMe, Hoo 3) g Sr¢ (Me~C @ 6 yen {Ws ® ea CO ® coe Oo pen Marace ne aK =7 Ro case) lo = . “ fe Dov im 3p Shruchyye pev =: R-1 DHE~? 6-1-5 st. cqtt > CaHig THD Cubane pourS-! ay con, es Ge ce eRiy THDCalcalakon eh DBE bby for muls OE J Z @am, +2) -OD nyene of C im Dov = —_ > a v no GH en ED Ceue im give BE worry) -6 ‘ pow ET TE Ge et 2 e (4-6 _ % -4 Zz 2 O », oe ~H. cw yeyrr diel) Oo D2 oor" waren