Numerical Problems

1. State the law of reciprocal proportion.

a. 0.46 g of metal produces 0.77 g of metal oxide.
b. 0.805 g of the same metal displaced 760cc of H 2 gas at NTP from HCl.
c. 1.26 g of water was formed by the union of 1.12 g of oxygen with hydrogen.
show that these data illustrate the law of reciprocal proportions.
2. Ammonia contains 82.35% of nitrogen and 17.65% of hydrogen. Water contains 88.90% of oxygen and 11.10
% of hydrogen. Nitrogen trioxide contains 63.15% of oxygen and 36.85% of nitrogen. Show that these data
illustrate the law of reciprocal proportion.
3. Calculate the no of atoms and molecules of oxygen present in 64g of Oxygen?
4. Calculate the mass of a molecule of CO 2.
5. Which of the following gases has greater number of hydrogen molecule? 9 g of CH 4 or 10g of NH3.
6. How many molecules are contained in 0.35 mol of N 2?
7. Which of the following have larger number of molecules and how? 7g of Nitrogen or 1g of hydrogen.
8. What weight of Na will contain the same number of atoms as are present in 1.2 kg of Carbon (C-12) ?
9. 1 atom of an element A weighs 6.644x10 -23 g. calculate the number of gram atoms in 80 kg of it?
10. How many moles of hydrogen are left when 3x 1021 molecules of hydrogen are removed from a vessel
containing 40 g of hydrogen?
11. How many grams of H2S are contained in 0.400 mole of H2S?
12. How many grams atoms of H and S are contained in 0.400 mole of H 2S?
13. How many gram of hydrogen and sulphur are contain in 0.4 mole H 2S ?
14. How many molecules of H2S contained in 0.4 moles of it? (2053)
15. How many atoms of Hydrogen and sulphur are contained in 0.4 mole H 2S?
16. How many molecules are contained in 0.35 mol of N 2? ( 2051)
17. Copper has a density of 8.92 g/cm3. If 1 mol of copper were shaped into a cube, what would be the length of
the side of the cube? 2052
18. Calculate the mass of water having the same number of hydrogen atoms as are present in 32g of methane.
(2071)
19. How many number of oxygen are present in 3 liters of CO 2 at STP ?
20. 6 gm of an element X combine with 16 g of another element y to give 0.5 mole of a compound xy. What is
the molecular mass of xy?
21. Calculate the mass of 120cc of nitrogen at NTP. How many number of molecules are present in it?
22. 1 atom of an element A weighs 6.644x10 -23 g. calculate the number of gram atoms in 80 kg of it?
23. What weight of Na will contain the same number of atoms as are present in 1.2 kg of Carbon (C-12) ?
2067
24. Calculate the volume of 11 gm of CO2 at NTP. 2063
25. 10 gm of impure zinc reacts with excess of dilute sulphuric acid to yield zinc sulphate and hydrogen. ( Zn =
64, S=32, O=16)
a. Calculate the number of moles of H2SO4 consumed. 0.154
b. Calculate the mass of ZnSO4 formed. 24.76 g
c. What volume of hydrogen is evolved at NTP ? 3449.6cc
26. 15. How many moles of hydrogen are left when 3x 1021 molecules of hydrogen are removed from a vessel
containing 40 g of hydrogen? 0.015 2062
27. At high temperatures, sulphur combines with iron to form brown black Iron(ii) sulphide
Fe (s) + S (s) → FeS (s)
a. In one experiment 7.62 g of Fe are allowed to react with 8.67 g of S.
b. Which is the limiting reagent?
c. Calculate the mass of FeS formed.
d. How much of the excess reagent is left at the end of the reaction?
28. Given,
CaCO3 (s) +2 HCl (aq) → CaCl2 (aq) + H2O (l) + CO2 (g)
a. If 10 g of pure CaCO3 are added in a solution containing 7.665 g of HCl.
b. Find the limiting reactant.
 c. Calculate the number of moles of excess reactant left over.
d. Calculate the volume of CO2 gas produced at STP.
e. Calculate the numbers of grams of NaOH required to absorb whole of the CO 2 gas to give Na2CO3.
29. 20g of 20% pure CaCO3 is reacts with 5g of HCl to produce CaCl 2, H2O and CO2.
a. Which one is limiting reagent?
b. Calculate the mass of CaCl2 formed.
c. How many moles of water are produced?
d. What volumes of CO2 are produced if the reaction is carried out at 27 0c temperature and 760mm Hg
pressure?
30. For a reaction,
Ca(OH)2(aq) + 2NH4Cl(aq) → CaCl2(aq) + 2NH3(g)+ 2H2O (l)
The reaction is carried out by mixing 7g of pure Ca(OH) 2 and 7g of pure NH4Cl.
a. Find the limiting reactant.
b. Calculate the mole of unreacted reactant left over.
c. How many gram of CaCl2 are formed?
d. What volumes of NH3 gas are produced at 270C and 1.5 atmospheric pressure?
31. 2.4 g of magnesium is treated with 0.2 mole of sulphuric acid to yield MgSO 4 and H2.
a. Which one is limiting reactant and why?
b. Calculate the mass of excess reactant.
c. How many moles of MgSO4 are produced?
d. What mass of water will be produced if the whole H 2 formed in the reaction reacts with O2?
32. 17 g of ammonia is completely reacted with 45g of oxygen to produce NO and H 2O.
a. Find the limiting reactant.
b. Calculate the number of mole of unreacted reactant left over.
c. What volume of NO are produced at NTP ?
d. Calculate the mass of water produced.
33. What volume of CO2 gas is produced when 20 g of 20% pure CaCO 3 is completely heated?
34. 10.6 g of pure Na2CO3 if treated with 7.9 g of HCl to produce NaCl, H 2O and CO2.
a. Find the limiting reagent and calculated the mole of unreacted reagent left over.
b. What volume of CO2 gas is produced at NTP?
c. Calculate the mass of NaCl formed.
35. .(i) How much sulphuric acid containing 90% H 2SO4 by weight is needed for the production of 1000 kg of
hydrochloric acid containing 42% HCl by weight in the following reaction.
(ii) If the above reaction is carried out by mixing 11.7 gm of pure NaCl and 10 gm of pure H 2SO4, find the
limiting reactant.
36. 73 gm of conc. HCl was diluted by adding 144 gm of water. How many gram atoms of hydrogen are present
in the dilute acid?
37. . Calculate the amount of lime (CaO) that can be prepared by heating 200kg of lime stone (CaCO 3 )that is 95%
pure.
38. How much sulphuric acid containing 80% H 2SO4 by weight is required to produce 500kg of 80% HCl by
weight ?
39.