Fresh+Clean Air Freshener

Callington Inc. Chemwatch Hazard Alert Code: 0

Chemwatch: 5298-10 Issue Date: 01/11/2019
Version No: 8.1.1.1 Print Date: 29/01/2020
Safety Data Sheet according to OSHA HazCom Standard (2012) requirements S.GHS.USA.EN

SECTION 1 IDENTIFICATION

Product Identifier

Product name Fresh+Clean Air Freshener

Synonyms Not Available
Other means of identification Not Available

Recommended use of the chemical and restrictions on use

Relevant identified uses Air freshener.

Name, address, and telephone number of the chemical manufacturer, importer, or other responsible party
Registered company name Callington Inc.
Address 1170 Tree Swallow Drive, STE 402 Winter Springs Florida 32708 United States
Telephone +1 321 972 2034
Fax Not Available
Website www.callington.com
Email americas@callington.com

Emergency phone number

Association / Organisation CHEMWATCH EMERGENCY RESPONSE CHEMWATCH EMERGENCY RESPONSE
Emergency telephone
+1 855 237 5573 +1 855 237 5573
numbers
Other emergency telephone
+61 2 9186 1132 +61 2 9186 1132
numbers

Once connected and if the message is not in your prefered language then please dial 01

Una vez conectado y si el mensaje no está en su idioma preferido, por favor marque 02

SECTION 2 HAZARD(S) IDENTIFICATION

Classification of the substance or mixture

NFPA 704 diamond

Note: The hazard category numbers found in GHS classification in section 2

of this SDSs are NOT to be used to fill in the NFPA 704 diamond. Blue =
Health Red = Fire Yellow = Reactivity White = Special (Oxidizer or water
reactive substances)

Classification Not Applicable

Label elements

Hazard pictogram(s) Not Applicable

SIGNAL WORD NOT APPLICABLE

Hazard statement(s)
Not Applicable

Hazard(s) not otherwise classified

Not Applicable

Precautionary statement(s) Prevention

Not Applicable

Precautionary statement(s) Response

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Fresh+Clean Air Freshener

Not Applicable

Precautionary statement(s) Storage

Not Applicable

Precautionary statement(s) Disposal

Not Applicable

SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS

Substances
See section below for composition of Mixtures

Mixtures
CAS No %[weight] Name
64-17-5. <10 ethanol, denatured
Not Available >90 Ingredients determined not to be hazardous

The specific chemical identity and/or exact percentage (concentration) of composition has been withheld as a trade secret.

SECTION 4 FIRST-AID MEASURES

Description of first aid measures

If this product comes in contact with the eyes:
Wash out immediately with fresh running water.
Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper
Eye Contact
and lower lids.
Seek medical attention without delay; if pain persists or recurs seek medical attention.
Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.
If skin contact occurs:
Immediately remove all contaminated clothing, including footwear.
Skin Contact
Flush skin and hair with running water (and soap if available).
Seek medical attention in event of irritation.
If fumes or combustion products are inhaled remove from contaminated area.
Lay patient down. Keep warm and rested.
Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid procedures.
Inhalation
Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket mask as trained.
Perform CPR if necessary.
Transport to hospital, or doctor.
If swallowed do NOT induce vomiting.
If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and prevent aspiration.
Observe the patient carefully.
Ingestion
Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious.
Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink.
Seek medical advice.

Most important symptoms and effects, both acute and delayed

See Section 11

Indication of any immediate medical attention and special treatment needed

Treat symptomatically.

SECTION 5 FIRE-FIGHTING MEASURES

Extinguishing media
Water spray or fog.
Foam.
Dry chemical powder.
BCF (where regulations permit).
Carbon dioxide.

Special hazards arising from the substrate or mixture

Fire Incompatibility Avoid contamination with strong oxidising agents as ignition may result

Special protective equipment and precautions for fire-fighters

Fire Fighting
Fire/Explosion Hazard
Alert Fire Brigade and tell them location and nature of hazard.
Wear breathing apparatus plus protective gloves in the event of a fire.
Prevent, by any means available, spillage from entering drains or water courses.
Use fire fighting procedures suitable for surrounding area.
DO NOT approach containers suspected to be hot.
Cool fire exposed containers with water spray from a protected location.
If safe to do so, remove containers from path of fire.
Equipment should be thoroughly decontaminated after use.
Non combustible.
Not considered to be a significant fire risk.
Expansion or decomposition on heating may lead to violent rupture of containers.

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Decomposes on heating and may produce toxic fumes of carbon monoxide (CO).
May emit acrid smoke.
Other decomposition products include:
carbon dioxide (CO2)

SECTION 6 ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

See section 8

Environmental precautions
See section 12

Methods and material for containment and cleaning up

Clean up all spills immediately.

Avoid breathing vapours and contact with skin and eyes.
Control personal contact with the substance, by using protective equipment.
Minor Spills
Contain and absorb spill with sand, earth, inert material or vermiculite.
Wipe up.
Place in a suitable, labelled container for waste disposal.
Minor hazard.
Clear area of personnel.
Alert Fire Brigade and tell them location and nature of hazard.
Control personal contact with the substance, by using protective equipment as required.
Prevent spillage from entering drains or water ways.
Major Spills
Contain spill with sand, earth or vermiculite.
Collect recoverable product into labelled containers for recycling.
Absorb remaining product with sand, earth or vermiculite and place in appropriate containers for disposal.
Wash area and prevent runoff into drains or waterways.
If contamination of drains or waterways occurs, advise emergency services.

Personal Protective Equipment advice is contained in Section 8 of the SDS.

SECTION 7 HANDLING AND STORAGE

Precautions for safe handling

Remove all ignition sources.

Limit all unnecessary personal contact.
Wear protective clothing when risk of exposure occurs.
Use in a well-ventilated area.
Safe handling When handling DO NOT eat, drink or smoke.
Always wash hands with soap and water after handling.
Avoid physical damage to containers.
Use good occupational work practice.
Observe manufacturer's storage and handling recommendations contained within this SDS.
Store in original containers.
Keep containers securely sealed.
Store in a cool, dry, well-ventilated area.
Other information
Store away from incompatible materials and foodstuff containers.
Protect containers against physical damage and check regularly for leaks.
Observe manufacturer's storage and handling recommendations contained within this SDS.

Conditions for safe storage, including any incompatibilities

Suitable container Plastic container
Storage incompatibility None known

SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION

Control parameters

OCCUPATIONAL EXPOSURE LIMITS (OEL)

INGREDIENT DATA
Source Ingredient Material name TWA STEL Peak Notes
US NIOSH Recommended ethanol, Alcohol, Cologne spirit, Ethanol, EtOH, 1000 ppm / 1900 Not Not
Not Available
Exposure Limits (RELs) denatured Grain alcohol mg/m3 Available Available
US ACGIH Threshold Limit ethanol, Not TLV® Basis: URT
Ethanol Not Available 1000 ppm
Values (TLV) denatured Available irr
US OSHA Permissible Exposure ethanol, 1000 ppm / 1900 Not Not
Ethyl alcohol (Ethanol) Not Available
Levels (PELs) - Table Z1 denatured mg/m3 Available Available

EMERGENCY LIMITS
Ingredient Material name TEEL-1 TEEL-2 TEEL-3
ethanol, denatured Ethyl alcohol; (Ethanol) Not Available Not Available 15000 ppm

Ingredient Original IDLH Revised IDLH

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ethanol, denatured 3,300 ppm Not Available

Exposure controls
Appropriate engineering
General exhaust is adequate under normal operating conditions.
controls

Personal protection

Safety glasses with side shields; or as required,

Chemical goggles.
Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describing
the wearing of lenses or restrictions on use, should be created for each workplace or task. This should include a review of lens absorption
Eye and face protection and adsorption for the class of chemicals in use and an account of injury experience. Medical and first-aid personnel should be trained in
their removal and suitable equipment should be readily available. In the event of chemical exposure, begin eye irrigation immediately and
remove contact lens as soon as practicable. Lens should be removed at the first signs of eye redness or irritation - lens should be removed in
a clean environment only after workers have washed hands thoroughly. [CDC NIOSH Current Intelligence Bulletin 59], [AS/NZS 1336 or
national equivalent]
Skin protection See Hand protection below
No special equipment needed when handling small quantities.
Hands/feet protection
OTHERWISE: Wear chemical protective gloves, e.g. PVC.
Body protection See Other protection below
No special equipment needed when handling small quantities.
OTHERWISE:
Other protection Overalls.
Barrier cream.
Eyewash unit.

Respiratory protection
Type A Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSI Z88 or national equivalent)

Where the concentration of gas/particulates in the breathing zone, approaches or exceeds the "Exposure Standard" (or ES), respiratory protection is required.
Degree of protection varies with both face-piece and Class of filter; the nature of protection varies with Type of filter.

Required Minimum Protection Factor Half-Face Respirator Full-Face Respirator Powered Air Respirator
up to 5 x ES Air-line* A-2 A-PAPR-2 ^
up to 10 x ES - A-3 -
10+ x ES - Air-line** -

* - Continuous Flow; ** - Continuous-flow or positive pressure demand

^ - Full-face
A(All classes) = Organic vapours, B AUS or B1 = Acid gasses, B2 = Acid gas or hydrogen cyanide(HCN), B3 = Acid gas or hydrogen cyanide(HCN), E = Sulfur dioxide(SO2), G =
Agricultural chemicals, K = Ammonia(NH3), Hg = Mercury, NO = Oxides of nitrogen, MB = Methyl bromide, AX = Low boiling point organic compounds(below 65 degC)

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties

Appearance Clear pale amber liquid with characteristic fragrance; mixes with water.

Physical state Liquid Relative density (Water = 1) <1

Partition coefficient n-octanol
Odour Not Available Not Available
/ water
Odour threshold Not Available Auto-ignition temperature (°C) Not Available
pH (as supplied) Not Available Decomposition temperature Not Available
Melting point / freezing point
Not Available Viscosity (cSt) Not Available
(°C)
Initial boiling point and boiling
78 Molecular weight (g/mol) Not Applicable
range (°C)
Flash point (°C) Not Available Taste Not Available
Evaporation rate Not Available Explosive properties Not Available
Flammability Not Available Oxidising properties Not Available
Surface Tension (dyn/cm or
Upper Explosive Limit (%) Not Available Not Available
mN/m)
Lower Explosive Limit (%) Not Available Volatile Component (%vol) Not Available
Vapour pressure (kPa) Not Available Gas group Not Available
Solubility in water Miscible pH as a solution (1%) Not Available
Vapour density (Air = 1) Not Available VOC g/L Not Available

SECTION 10 STABILITY AND REACTIVITY

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Reactivity See section 7

Unstable in the presence of incompatible materials.
Chemical stability Product is considered stable.
Hazardous polymerisation will not occur.
Possibility of hazardous
See section 7
reactions
Conditions to avoid See section 7
Incompatible materials See section 7
Hazardous decomposition
See section 5
products

SECTION 11 TOXICOLOGICAL INFORMATION

Information on toxicological effects

Inhaled Not normally a hazard due to non-volatile nature of product

Ingestion The liquid is highly discomforting Ingestion may result in nausea, abdominal irritation, pain and vomiting
The material is not thought to produce adverse health effects or skin irritation following contact (as classified by EC Directives using animal
Skin Contact models). Nevertheless, good hygiene practice requires that exposure be kept to a minimum and that suitable gloves be used in an occupational
setting.
Although the liquid is not thought to be an irritant (as classified by EC Directives), direct contact with the eye may produce transient discomfort
Eye
characterised by tearing or conjunctival redness (as with windburn).
Long-term exposure to the product is not thought to produce chronic effects adverse to the health (as classified by EC Directives using animal
Chronic
models); nevertheless exposure by all routes should be minimised as a matter of course.

TOXICITY IRRITATION
Fresh+Clean Air Freshener
Not Available Not Available

TOXICITY IRRITATION

ethanol, denatured Inhalation (rat) LC50: 124.7 mg/l/4H[2] Eye: adverse effect observed (irritating)[1]

Oral (rat) LD50: =1501 mg/kg[2] Skin: no adverse effect observed (not irritating)[1]

Legend: 1. Value obtained from Europe ECHA Registered Substances - Acute toxicity 2.* Value obtained from manufacturer's SDS. Unless otherwise
specified data extracted from RTECS - Register of Toxic Effect of chemical Substances

The material may produce severe irritation to the eye causing pronounced inflammation. Repeated or prolonged exposure to irritants may
produce conjunctivitis.
ETHANOL, DENATURED
The material may cause skin irritation after prolonged or repeated exposure and may produce on contact skin redness, swelling, the production of
vesicles, scaling and thickening of the skin.

Acute Toxicity Carcinogenicity

Skin Irritation/Corrosion Reproductivity
Serious Eye Damage/Irritation STOT - Single Exposure
Respiratory or Skin
STOT - Repeated Exposure
sensitisation
Mutagenicity Aspiration Hazard
Legend: – Data either not available or does not fill the criteria for classification
– Data available to make classification

SECTION 12 ECOLOGICAL INFORMATION

Toxicity

ENDPOINT TEST DURATION (HR) SPECIES VALUE SOURCE

Fresh+Clean Air Freshener Not Not Not
Not Available Not Available
Available Available Available

ENDPOINT TEST DURATION (HR) SPECIES VALUE SOURCE

LC50 96 Fish 285.505mg/L 3
EC50 96 Algae or other aquatic plants 1791.903mg/L 3
LC50 96 Fish 285.505mg/L 3

ethanol, denatured EC50 96 Algae or other aquatic plants 1791.903mg/L 3

LC50 96 Fish 11-mg/L 2
EC50 48 Crustacea 2mg/L 4
EC50 96 Algae or other aquatic plants 17.921mg/L 4
NOEC 2016 Fish 0.000375mg/L 4

Legend: Extracted from 1. IUCLID Toxicity Data 2. Europe ECHA Registered Substances - Ecotoxicological Information - Aquatic Toxicity 3. EPIWIN Suite
V3.12 (QSAR) - Aquatic Toxicity Data (Estimated) 4. US EPA, Ecotox database - Aquatic Toxicity Data 5. ECETOC Aquatic Hazard Assessment

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Data 6. NITE (Japan) - Bioconcentration Data 7. METI (Japan) - Bioconcentration Data 8. Vendor Data

DO NOT discharge into sewer or waterways.

Persistence and degradability

Ingredient Persistence: Water/Soil Persistence: Air
ethanol, denatured LOW (Half-life = 2.17 days) LOW (Half-life = 5.08 days)

Bioaccumulative potential
Ingredient Bioaccumulation
ethanol, denatured LOW (LogKOW = -0.31)

Mobility in soil
Ingredient Mobility
ethanol, denatured HIGH (KOC = 1)

SECTION 13 DISPOSAL CONSIDERATIONS

Waste treatment methods

Recycle wherever possible or consult manufacturer for recycling options.

Consult State Land Waste Management Authority for disposal.
Product / Packaging disposal
Bury residue in an authorised landfill.
Recycle containers if possible, or dispose of in an authorised landfill.

SECTION 14 TRANSPORT INFORMATION

Labels Required
Marine Pollutant NO

Land transport (DOT): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS

Air transport (ICAO-IATA / DGR): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS

Sea transport (IMDG-Code / GGVSee): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS

Transport in bulk according to Annex II of MARPOL and the IBC code

Not Applicable

SECTION 15 REGULATORY INFORMATION

Safety, health and environmental regulations / legislation specific for the substance or mixture

ETHANOL, DENATURED IS FOUND ON THE FOLLOWING REGULATORY LISTS

GESAMP/EHS Composite List - GESAMP Hazard Profiles
IMO IBC Code Chapter 17: Summary of minimum requirements
IMO IBC Code Chapter 18: List of products to which the Code does not apply
IMO MARPOL 73/78 (Annex II) - List of Other Liquid Substances
IMO Provisional Categorization of Liquid Substances - List 2: Pollutant only mixtures
containing at least 99% by weight of components already assessed by IMO
IMO Provisional Categorization of Liquid Substances - List 3: (Trade-named) mixtures
containing at least 99% by weight of components already assessed by IMO, presenting
safety hazards
International Air Transport Association (IATA) Dangerous Goods Regulations
International Maritime Dangerous Goods Requirements (IMDG Code)
United Nations Recommendations on the Transport of Dangerous Goods Model
Regulations
US - Alaska Limits for Air Contaminants
US - California Permissible Exposure Limits for Chemical Contaminants
US - Hawaii Air Contaminant Limits
US - Idaho - Limits for Air Contaminants
US - Idaho Toxic Air Pollutants Non- Carcinogenic Increments - Occupational Exposure
Limits
US - Michigan Exposure Limits for Air Contaminants
US - Minnesota Permissible Exposure Limits (PELs)
US - Oregon Permissible Exposure Limits (Z-1)
US - Tennessee Occupational Exposure Limits - Limits For Air Contaminants
US - Vermont Permissible Exposure Limits Table Z-1-A Final Rule Limits for Air
Contaminants
US - Vermont Permissible Exposure Limits Table Z-1-A Transitional Limits for Air
Contaminants
US - Washington Permissible exposure limits of air contaminants
US - Wyoming Toxic and Hazardous Substances Table Z1 Limits for Air Contaminants
US ACGIH Threshold Limit Values (Spanish)
US ACGIH Threshold Limit Values (TLV)
US AIHA Workplace Environmental Exposure Levels (WEELs)
US Department of Transportation (DOT), Hazardous Material Table
US DOE Temporary Emergency Exposure Limits (TEELs)
US DOT Coast Guard Bulk Hazardous Materials - List of Flammable and Combustible
Bulk Liquid Cargoes
US NIOSH Recommended Exposure Limits (RELs)
US NIOSH Recommended Exposure Limits (RELs) (Spanish)
US OSHA Permissible Exposure Levels (PELs) - Table Z1
US OSHA Permissible Exposure Limits - Annotated Table Z-1 (Spanish)
US Postal Service (USPS) Hazardous Materials Table: Postal Service Mailability Guide
US Postal Service (USPS) Numerical Listing of Proper Shipping Names by
Identification (ID) Number
US Spacecraft Maximum Allowable Concentrations (SMACs) for Airborne
Contaminants
US Toxic Substances Control Act (TSCA) - Chemical Substance Inventory
US TSCA Chemical Substance Inventory - Interim List of Active Substances

Federal Regulations

Superfund Amendments and Reauthorization Act of 1986 (SARA)

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SECTION 311/312 HAZARD CATEGORIES

Flammable (Gases, Aerosols, Liquids, or Solids) No
Gas under pressure No
Explosive No
Self-heating No
Pyrophoric (Liquid or Solid) No
Pyrophoric Gas No
Corrosive to metal No
Oxidizer (Liquid, Solid or Gas) No
Organic Peroxide No
Self-reactive No
In contact with water emits flammable gas No
Combustible Dust No
Carcinogenicity No
Acute toxicity (any route of exposure) No
Reproductive toxicity No
Skin Corrosion or Irritation No
Respiratory or Skin Sensitization No
Serious eye damage or eye irritation No
Specific target organ toxicity (single or repeated exposure) No
Aspiration Hazard No
Germ cell mutagenicity No
Simple Asphyxiant No
Hazards Not Otherwise Classified No

US. EPA CERCLA HAZARDOUS SUBSTANCES AND REPORTABLE QUANTITIES (40 CFR 302.4)
None Reported

State Regulations

US. CALIFORNIA PROPOSITION 65

None Reported

National Inventory Status

National Inventory Status
Australia - AICS Yes
Canada - DSL Yes
Canada - NDSL No (ethanol, denatured)
China - IECSC Yes
Europe - EINEC / ELINCS / NLP Yes
Japan - ENCS Yes
Korea - KECI Yes
New Zealand - NZIoC Yes
Philippines - PICCS Yes
USA - TSCA Yes
Taiwan - TCSI Yes
Mexico - INSQ Yes
Vietnam - NCI Yes
Russia - ARIPS Yes
Yes = All CAS declared ingredients are on the inventory
Legend:
No = One or more of the CAS listed ingredients are not on the inventory and are not exempt from listing(see specific ingredients in brackets)

SECTION 16 OTHER INFORMATION

Revision Date 01/11/2019

Initial Date 14/03/2018

SDS Version Summary

Version Issue Date Sections Updated
7.1.1.1 02/05/2019 Chronic Health, Classification, Ingredients
8.1.1.1 01/11/2019 One-off system update. NOTE: This may or may not change the GHS classification

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Other information
Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification
committee using available literature references.

The SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks in the workplace or
other settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current or available engineering controls must be considered.

Definitions and abbreviations

PC TWA: Permissible Concentration-Time Weighted Average
PC STEL: Permissible Concentration-Short Term Exposure Limit
IARC: International Agency for Research on Cancer
ACGIH: American Conference of Governmental Industrial Hygienists
STEL: Short Term Exposure Limit
TEEL: Temporary Emergency Exposure Limit
IDLH: Immediately Dangerous to Life or Health Concentrations
OSF: Odour Safety Factor
NOAEL :No Observed Adverse Effect Level
LOAEL: Lowest Observed Adverse Effect Level
TLV: Threshold Limit Value
LOD: Limit Of Detection
OTV: Odour Threshold Value
BCF: BioConcentration Factors
BEI: Biological Exposure Index

This document is copyright.

Apart from any fair dealing for the purposes of private study, research, review or criticism, as permitted under the Copyright Act, no part may be reproduced by any process without
written permission from CHEMWATCH.
TEL (+61 3) 9572 4700.

end of SDS