<> SAFETY DATA SHEET ‘THE DOW CHEMICAL COMPANY Product name: ETHOCEL"™ Standard 45 Promlum Ethyicllulose eave Date 021127015, Print Dat: 071012015 “THE DOW CHEMICAL COMPANY encourages and expels youto res and understand the entre [tisb. ac nee mporant oration tnoughou ine document. We expat yeu to folow te precaubons Wentfed nth document nia yor use condos wou necessist ter spor Inetnogs o actions IDENTIFICATION Product name: ETHOCEL™ Sanda 45 Premism Etycotulces Recommend Wontifed uses: Processing aa Ceatng agont. Filer Bader, We recommend that you use tht ‘roduc na manne consetetwi the uted use your mended use nl concent wth he [iated ure, paane contact your tals or Wanncal orioe representa ‘COMPANY IDENTIFICATION ‘THE DOW CHENICAL COMPANY 2000 WILLARD H DOW CENTER FMIDLANO mi 46674-0000 Unrreo stares ‘customer Information Number 200-288-2436, SDSQvestonedow.com EMERGENCY TELEPHONE NUMBER ‘24-Hour emergency Contact 800-424-9200 {local emargeney Contact €00-424-8300 2, HAZARDS IDENTIFICATION Hazard classification ‘Tes materal a hazardous under the ceria ofthe Federal OSHA Hazaré Communication Standard 29FR "910.1200 Combustiie dst Let elements ‘Signal word: WARNING! Hazards May form combust dust concentrations in air Precautionary statoments Prevention Keon any rom heaaparslopenfamesinatsutaces, -No smcking ‘@¥ Traderaneat The Dow Ghemeal Company (DoW eran aiaiad Page TAS ‘company of DowProduct name: ETHOCEL™ Standard 4S Promium Ethylcllulose eave Date: 03122016, CGrounttond container and receving euipmart Ute exposon root sete venting! ightng!equpment ‘Fake precautionary meseues spans tnt charge ‘other hazards Sipping azar Hay form explosive dtr mixture ‘. COMPOSITION/INFORMATION ON INGREDIENTS. Synonyms: Ehyicabioss ‘Ths products asubstonce, Component ‘CASRN Concentration Celulse, et eter 0067-3 >a ono 1000% Witer 72485 20% “4-FIRST AID MEASURES. Description of frst ad measures {General advice stent fo oxposure exit fer to Section Bor spc personal petsctve upment Inalation: Move person tosh ai; fects occur, const a physician ‘Skin contact: Wash of wth plenty of water ye contact: Flush oye with plenty of water remove corac lenses ater he fet 1-2 mints hen Conte shing fr sever minutes. Oni machaniel elects expected. efct cur, const a ysl, profraby an ephihaimalogist. Ingestion: No emergency medial teatrentnecotsay ‘Most important symptoms and effects, both acute and delayed: Asie om he information found Under Desripion fest sd meatus (sbeve) and Indetion of mediate medealatoron ana pecal toatmentreaded (blow), any addtonal mpocar symstoms and elects ao described In Seton 11 Toxoatogy Information, Indication of any mmeciate medial attention and special treatment needed Notes to physician: No spine antiote Treatment of sepesure shoul be deed st the conto of Symptoms an he cna contin ofthe pair ‘5 FIREFIGHTING MEASURES ‘Suitable extinguishing media: Water, Dry cherie xingushers. Catton does fre Page Taeoduct name: ETHOCEL™ Standard 45 Premium, ve Date: 031272015, Unsuitable extinguishing media: no dta avaible ‘Special hazard arising frm the substance or micure ‘Hazardous combustion products: Outing ae, smote may cotan tho riginl material naditon to-cambuston prods of varying compestion whieh maybe tox andlor ering Cormbston prodte may icude and arent test" Carbon monoxade. Carbon daxde ‘Unusual Fire and Explosion Hazards: Do not pei cust to accumulte When suspended in ait tlstean pose an exptson hazaré, Minmize non sources i st ayers se exposed to loved ‘omperaures,sporaneous conbuston may occu. Pneumatic conveying ane oher mechanical hanelingopeatons can generat combustible Gust To reduce the poten for dost explosions, ‘ctiaty bond and ground equipment and do at pei dust to accumulte. Dust canbe gntedby ‘Save Sacharge ‘Advice for frefightors Fire Fighting Procedures: Keappecpo away. Iola fre and deny unnecessary entry. Soak ‘Moraughly with water to coal and prover fespriten Cool suroundrige wth water to calize fre zone. Hanne dry chemical or carbon oxide exinglsers maybe ord for sal es. Dust. tilenon hazard may result rem oes spplcaton afte extngusing agents. Speca protective equipment fo fretighters: Wer postive pressure sli contained breathing Spparatue (SOA) and protective fre iting clothing (relies fire hing hele, coat vouses, Sou ard goven priv aque et mma orl nd, soe fon apres locaton or ste diene. ‘6, ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures: Mate becomes Elppery when wet Use appropriate salty equipment For adsonal nfoate, refer to Sect | Exposure Contos ang Porsnal Protection. Spied materia ray cause a lpping hare Environmental precautions: Prevent rom entering in sl, dees, sewer, wateruays ander ‘under See Seton 12, Ecologia formation Methods and materiale fr containment and cleaning up: Sweep up. Use cae to minimize ‘generation of sbome dist Do ol use wate fx clean. Coleen sutabio and propa abled ontanare. Sea Sestn 1, Daposal Consideration, or ational formation. Contam sped ‘materal posse. 7. HANDLING AND STORAGE Precautions for safe handing: No smoking, open flames or sources of gion in handing and forage area. Gos housekeeping ans cooling of ust re necessary for safe Panang of product Elsa bond and pround 3 contanere, personne and equomet bole Vanser or use of ‘ator. Keop away fom heat parks and fame. Keep container cosod. Soe Section 8, EXPOSURE CONTROLS AND PERSONAL PROTECTIONProduct name: ETHOCEL" Standard 45 Premium Edhylcelulose Iogue Date 03122018, Conditions for safe storage: Store ney pace, Avoid molar 1 EXPOSURE CONTROLS/PERSONAL PROTECTION Conol parameters re mis ae ited bel, they exe a pisos aay — Ta) Celklse, ey oar ‘Dow. TA mes Exposure controls EEnginering controls: Use oa! exhaut venation, or ther engineering conto to maintain sifome lovls blow exposure it eauiromarts or uldelnes. thee ate re appeable expceure Iimtrequremerts er uielnes, general verdlaten shouldbe sufcont for most operations. Local, ‘rave entation may be necessary or sore operations. Individual protection measures Eyelfae protection: Use safety gastos (wth se sil). ter isa potenti for ‘rposure fo paces whch coud cause eye cacerior, wear chemcal ong. ‘kin protection Hand protection: Chemical protacive gloves shouldnt be needed when hansing ths mato Content wth general han praca for ny male, sn cont rou be mame. Other protection: No precautions other than lean body-covering eathing should b= readed Respiratory protection: Respiratory protection shouldbe worn when theresa potenti to trcoed the exposure mt requrarants er guideles. thee are no sppeale exposure Int Teguremerts cr guidelines, wear esis protcion when adverse eects such a8 respiratory iiaien or decor have bean experienced, where ndeslod by Your ek isonet proces, Foc most sontions, no resprtry potion shoud be Nesced however in ust amoepres. uve an approves parclte raptor. “he ollonng sculsbe efecve peso ar-puiing reapratrs: Parca ite ‘PHYSICAL AND CHEMICAL PROPERTIES Appearance Physical stato Power color ite tan odor dora to mis dor Threshold Notes data avalabe pa Not ppesbie Melting pointrange Notes data avaliable Freezing point Not apptcable Boling polnt(760 mmHg) Not applicable Flashpoint losed cup Notes deta avaliable Evaporation Rate (Butyl Acetate Not eplableto sos = Flammabity (soa, gs) May form combust cst concentration nae Pager ereProduct name: ETHOCEL™ Standard 45 Premium Etiyicllulose Date: 031122015 Lower explosion init No test cate avaiabe Upper explosion iit No test aia avaioie ‘Vapor Pressure Net applicable Relative Vapor Density (air 1) Not apleable Relative Density water ®t) Notest dota avaliable Water sotubity Insonbie in water Parton cooficlent:n- ro data avaiable octanolwatar ‘Autosgnition temperature No eet. dsa avaiable Decomposition temperature Notact daa avaiable Kinematic Viscosity Notes dala avalable Explosive properties Not explosive ‘Oxidizng properties, ro data avaiable Molecular weight No test cata avatable NOTE: The physica cota presented stove are typical values and should natbe construed asa specteaton 10. STABILITY AND REACTIVITY Reactivity: no dts vase ‘chemical stability: Stile under recommended storage conditions, See Storage, Seton. Possibly of hazardous reactions: Polymerization wil not occur Conditions to avoid: Avoid temperatures shove 160°C (920°F) Exposure to elevated temperatres ‘can-eause productto decompose. Aol slate dschage. Avid mou Incompatible materiale: Avid contact with oning materi Hazardous decomposition products: Decomposition products depend upon temperate, a 0p ‘ad the presence of ener materials TI. TOXICOLOGICAL INFORMATION. Taxco internation an thi product or its components appesrin this secon when such dt Is cvalabe Acute toxlity ‘Acute oral toxiy ‘Very low tony walowed. Harmful efets nt antepstod tem swallowing eal amounts. 080, Rat > 6.000 mah Page soeProduct name: ETHOCEL™ Standard 45 Premium Euiylcelulose at: 031272015 ‘Acute dermal toxcty Prolonged skin corat sully to resutinabserpton of arf arent, Ls, Rabb, > 5.000 mao ‘Acute inhalation toxety ‘ss product ‘The LCSO has not been determined \Vapers are unl do pisical properties. No adverse eects are arial rom single ‘posure to dust. Forespeatry ean and rarot ofets”Novelevant data fund ‘kin corrosonfetation Prolonged exposure nt el to couse significant ein tation Serious eye damageleye ination Mechanar on Senaitzation For ekinsonetization Ne rtvent ata found For respirator sentation: Ne acter ta ound Specific Target Organ Systemic Tex (Single Exposure) valuabon of avatbie data sugges thal hs tor shot an STOT-SE toxicant ‘Specific Target Organ Systemic Toxic (Reposted Exposure) Repestd ngeston of sla clluoses by humans has net resutod in known siifcart adverse se Carcinogenicity Feorthe mar components): Oi not cause cancer in iaboretery animal. Teratogeniy Noreovan deta found Reproductive toxicity Netlovant det ound Mutagenicity Novelovan dat found ‘Aspiration Hazard Based on pica properties, not key tobe an aspiration azar Tz, ECOLOGICAL INFORMATION.Product name: ETHOCEL™ Standard 4S Premium Ethylcoluloee Inoue Date: 031122018, cotoxicolgiainfomaton an this produto is components appear in is section whon such dat ‘eavarabe, ‘Toxiety “Acute toxic to fa Netexpecedf be actly tox to aqua organisms, Persistence and dograabity Blodogradail: No appreciable biodegradation expected. Bioaccumulatve potential ‘loaceumlation: No bocancataion i expected because of the elabvty high molecular weg (MW greater than 100) obit in sot "No relvant data found 13, DISPOSAL CONSIDERATIONS, Disposal methods: 00 NOT DUUP INTO ANY SEWERS. ON THE GROUND, OR INTO ANY BODY GEWATER: Al depos! pacices mut be n cmmlance wih all Fedora, StateProvncil enc lees), ‘Bus and regulations. Regustons may vary n fleet ocatans. Waele chaactrzatons 2nd omplanos wth applicable we ae the responsibly sol cf te waste gonerator AS YOUR SUPPLER WE HAVE NO CONTROL OVER THE MANAGEMENT PRACTICES OR MANUFACTURING PROCESSES OF PARTIES HANDLING OR USING THIS MATERIAL. THE INFORMATION PRESENTED HERE PERTAINS ONLY TO THE PRODUCT AS SHIPPED IN TS INTENDED CONDITION AS DESCRIBED IN MSDS SECTION: Composition Information. FOR. UNUSED & UNCONTAMINATED PRODUCT. the pretered options cle ending tow lcanee, permites: Recycler Recamee Insneratc ar the thermal debrution device. —— Ta, TRANSPORT INFORMATION. or Net regulated for ranspot ‘tassitcation for SEA transport (MMOsMOG): Not regulated fr wanspet ‘Transportin bulk Cone ht regulations before ansporing ocean buk According to Annex ort ‘SFMARPOL 7378 and the Tac ortee code Classification for AIR transport (ATAICAO): Not regulated fr taneport This iforation i nc intended to convey a specie regulatory or cperatonl ‘equemantsinfomaten rltng to this pose Transporatoneasfeaons may vty by contanesProduct name: ETHOCEL" Standard 45 Premium Ethyicelulose Iesue Dat: 03122015, \elume and may be infuenced by regina county varatons In repuatons. Acéional ‘ransporaton eft infomation can be obained trough an auloied sales or customer sence Topresertabve, lathe responsi of te tanepoting organization f follow spies aus, ‘epastons andres reiting toe anaporaon athe ator 15, REGULATORY INFORMATION (OSHA Hazard Communication Standard ‘This prodet it 8azstaous Chemica’ defined bythe OSHA Hazard Communication Standas, 25 CFR 1910-1200, ‘Superfund Amendments and Reauthorization Act of 188 Tel (Emergency Planning and {Community Righto-Know Act of 1886) Sections 911 and 312 ‘Fis predut ent hazardous chamieal under 29CFR 101, 1200, ane heer isnot covered by Tie fo SARA ‘Superfund Amendments and Reauthorization Act of 198 Tite Il (Emergency Planning and Community Right-to-Know Act of 1968) Section 313 ‘This materal doos not conta any chemical components wth inown CAS numbers thst exceed the thvsahald (De Minne) reporting vel establishes by SARA Tiel Secion 313 ‘Comprehensive Environmental Response, Compensation, and Lisblty Act of 1980 (CERCLA) Section 03, ‘This material doesnot contain any components wih CERCLA RO, Pennsylvania Worker and Community Righ-To-Know Act: ‘Fatne teat of ou knowledge. th produ os nl contain emia atevele which equerepetng California Proposition 8 (Safe Drinking Wator and Toxic Enforcement Act of 1886) ‘This rodiet contains noted substances knoato te Sat of Calf fo caus carer, bith detest or oh Yepeductne harm, etlovele which wou requre a warning under te ati United Stats TSCA Inventor (TSCA) [Allcomponers ofthis product are mn compliance wth he inventory sting requrements ofthe US. ‘Tou Subetaneee Conte Act (TSCA) Chemica Sustares Inverter 16. OTHER INFORMATION. Product Literature ‘ditnal formation on this and cher products may be oblaned by ving cur webpage Revision IGenfleston Number: 101188527 A001 sue Ost: 03272015 Version: 40 PasteMost recent revisions) are nod bythe bold, double bare inletthand margin thoughout is (document Legend ow IS Dew India Ryne Guiting TWA Tie Weights Average (TWA) Information Source and References “Tle SS is prepared by Produ Rogustory Srvies and Hazard Conmmuntstions Groups em ‘Maton supped by nema references ulti our company. ‘THE DOW CHEMICAL COMPANY urgos each customer or recient of this (M)SOS to study # Cartland coneut appropriate expertise, as recesary o appropriate become aware of and Uidereting the data consis its (A)SOS and any azarceastoeted wth tre product. The Intomaton hers roids goo fh and besoved to bo acuTate aso th efecive date shown ‘hove, Howaver no waranty, expres o pled, s given. Regulatory requlemerts are subject 0 ‘hange and may fr between varous eats tthe buyer users responsi to ensue that his activins comply wih a eset tata, provincial o local laws. The formation presented here pertains anf the prosct as shoped. Sie codon fo se ofthe product arene under he enue) ef ne manuacur tls the bujertueore dy fo determine ve condone necessary forthe fe use ofthe product Due othe acento sources fr information suchas manacer. pec ()SDSe we are not and earns be responsi for (MSDS cbtined ftom ay sure other faveuseves. tiyou have oad an (MSDS trom another sure or you se retour ale [ning you navel caren please contact us for tha most cure vers. Pagers