Write the expression for K, and K, for the following reactions Nog) + 3Haq) == 2NH30) Select the heterogeneous equilibrium from the following reactions (A) Cacos(s) == Ca0(s) + CO, (g) (@) Ha(g) + Lig) == 2H1(9) Ata certain temperature 2 moles of carbonmonoxide and 3 moles of chlorine were allowed to reach equilibrium according to the reaction COg) + Clr ——*COC! in a § lit vessel. At equilibrium if one mole of CO is present then equilibrium constant for the reaction is.In an equilibrium A+B = C+D; a and 8 are mixed in a vessel at temperature T. The inital concentration of A was twice the inital ‘centration of B. After the equilibrium has established, concentration of C was thrice the equilibrium concentration of B. Calculate K., Reaction between nitrogen and oxygen takes place as follows: 2N,(9)+0,(g)——=2N,0(g) If @ mixture of 0.482 mol of N; and 0.933 mol of O2 is placed in a reaction vessel of volume 10L and allowed to form NO at a temperature for which K, = 2.0x10~7 . Determine the composition of the equilibrium mixture. Ammonium carbamate dissociates as NH,COONH, (s) = 2NH, (g) +CO, (a) In a closed vessels containing ammonium carbamate in equilibrium, ammonia is added such that partial pressure of NH; now equals to original total pressure. Calculate the ratio of total pressure ow the original pressure. How much PCI, must be added to a one litre vessel at 250°C in order to obtain a concentration of 0.1 mole of Cz? K. for PCle= PCI + Cl. is 0.0414 molfitre. (A) 0.3415 mole (B) 1.4315 mole (C) 2.4316 mole (D) 4.315 mole For the reaction: CO,(g) + Ha(g) <= CO(g) + H-0(9), K is found to be 16 at a given temperature. Originally equal numbers of moles of Hz and CO, were placed in the flask. At equilibrium, the pressure of H, is 1.20 atm. What is the partial pressure of CO and H:0? (A) 4.80 atm each (B) 9.60 atm each (C) 2.40 atm each (D) 1.20 atm each When sulphur in the form of S, is heated at 900K, the inital pressure of one atm falls by 29% at equilibrium. Find out K, for the following reaction: S, (g) = 4S, (9) (A) 1.16atm? (8) 0.71 atm? (C) 2.55atm? (0) 5.4 atm?Re ed Under what conditi ions will the followir ic ir ono rates ena go in the forward direction? (b) 280,(6)+Oy(g) = 2804(q) + 45 kcal, (C) Ne(Q) + O2(g) = 2NO(Q) - 43.2 k cal (4) 2NO(g) + O,(@) + 2NOx(g) +27.8 k cl. (@) C(s) + H0(g) = CO,(g) + H,(g) + y k cal. (f) PCIs(g) = PCh(g) + Ch(Q)- y k ca. (g) NzO.(g) = 2NO,(g) - 14 k cal. iz K, for the reaction Aig) +B —=C,) +D,,), is 20 at 25°C. Ifa container contains 1, 2, 4, 5 moles per litre of A,,), Bj, Cj) and D., respectively at 25°C, then the reaction shall proceeds in direction, 3. Inreaction: NzOx(g) = 2NOz(Q), what wil be the value of K. at 35°C if N2Os is dissociated to the extent of 20% under a pressure of 1 atmosphere. 4, Ifa given quantity of phosphorus pentachloride is heated to 250°C and allowed to come 19 equlbrium at atmospheric pressure it is found to be dissociated to the extent of 80% into phosphorous trichloride and chlorine. if now, the pressure on this mixture is increased 0 that finally the equilbrium mixture occupies only one half of its original volume (temperature maintained constant). (a) What will be the % dissociation atthe new pressure? {b) What wil be the effect of adding He gas keeping the volume fixed at V2. 5, The degree of cissociation is 0.4 at 400 K and 1.0 atm for the gaseous reaction PCI, <=PCI, +Ci,. Assuming ideal behaviour of al the gases, calculate the density of equim mixture at 400 K and 1.0 atmosphere. (Atomic mass of P= 31.0 and Cl = 35.5) 6. __Atconstant temperature, the equibrium constant (K) forthe decomposition reaction N,O, <= 2NO; is expressed by K,= (dap), where P= total pressure, the following statements is tue? (A) K, increases with increase of P (8) Ky increases with increases of a (©) Ky increases with decreases of a (0) K, remains constant with change in P and a. ITJEE-2122-CHEMISTRY= CHEMICAL EQUILIBRIUMMEGACOSM nn 7. NaNO, (s) = NaNo, (s)+ 40.(9) AH=4ve When NaNO, is heated in a closed vessel, oxygen Is liberated and NaNOz is left behind, At equilibrium: (A) addition of NaNO: favours reverse reaction (8) addition of NaNO; favours forward reaction (C) increasing temperature favours forward reaction (0) decreasing pressure favours reverse reaction 8 At temperature T, a compound AB2(g) dissociates according to the reaction 2AB, (9) = 2A8() +8, (9) with degree of dissociation x, which is small compared with unity. The expression for x in terms of, the equilibrium constant K, and total pressure P is x=(22)" ) x-() Ky" (©) x= *)ANSWERS TOJEXERCISES Exercise — 1 kee NE [Pn NIP? r ONTAP ary] (A) is a heterogeneous equilibrium. 25 18 [Na 31 7 A a © 0.0483 mol L™ ; [0,] = 0.0933 mol L™; [NO] = 6.610"! mol Exercise -2 (a) Low T, High P, excess of Nz and Hz. (b) Low T, High P, excess of SOz and O2. (©) High T, any P, excess of Nz and O2 (d) Low T, High P, excess of NO and O2 {e) Low T, Low P, excess of C and H20 (0) High T, Low P, excess of PCls (g) High T, Low P, excess of NzOx. Forward 6.59 x 10° mole litre” 0 sath ealibum composition ofthe syst. 4.53 glltre (0) (c) a)