1. Recalculeu la concentració real de sosa, NaCl i de les dilucions amb el seu error aleatori.

m ftalato (g) mol ftalato mol NaOH V NaOH (mL) [NaOH] (M) Media
1.2221 0.00598423 0.00598423 22.3 0.2683512417 0.28473788
1.2927 0.00632994 0.00632994 22.4 0.2825865313
1.2387 0.00606552 0.00606552 20 0.303275879
PROMEDIO 1.25116667 0.00612656 0.00612656 21.5666667 0.28

m NaCl (g) mol NaCl V NaCl (mL) Conc NaCl

3.383 0.05788843 200 0.28944216

V NaOH (mL) V NaCl (mL) conc. NaOH conc. NaCl [NaOH]i

S1 30 0 [NaOH] (M) 0 #VALUE!
S2 20 10 [NaOH] (M) 0 #VALUE!
S3 10 20 [NaOH] (M) 0 #VALUE!
S4 5 25 [NaOH] (M) 0 #VALUE!

2. ln At front al temps

temps Serie 1 Serie 2 Serie 3 LN serie 1 LN serie 2

0 0.801 0.901 0.891 -0.221894332 -0.10425002
5 0.782 0.889 0.872 -0.245900538 -0.11765804
10 0.761 0.883 0.855 -0.273121921 -0.12443008
15 0.739 0.871 0.837 -0.302457358 -0.1381133
20 0.717 0.865 0.82 -0.332679438 -0.14502577
25 0.695 0.856 0.801 -0.363843433 -0.1554849
30 0.675 0.851 0.786 -0.393042588 -0.16134315
35 0.656 0.843 0.771 -0.42159449 -0.17078832
40 0.637 0.841 0.753 -0.450985623 -0.17316362
45 0.618 0.83 0.739 -0.481266822 -0.18632958
50 0.602 0.828 0.723 -0.507497834 -0.18874212
55 0.585 0.822 0.707 -0.536143432 -0.19601488
60 0.57 0.818 0.692 -0.562118918 -0.20089294
65 0.552 0.811 0.676 -0.594207233 -0.20948722
70 0.536 0.804 0.663 -0.623621118 -0.21815601
75 0.522 0.801 0.65 -0.650087691 -0.22189433
 80 0.509 0.793 0.638 -0.675307262 -0.23193206
85 0.495 0.788 0.622 -0.703197516 -0.23825719
90 0.483 0.778 0.611 -0.727738625 -0.25102875
95 0.469 0.773 0.6 -0.757152511 -0.25747623
100 0.458 0.766 0.585 -0.780886095 -0.26657311
105 0.446 0.759 0.572 -0.807436327 -0.2757535
110 0.433 0.755 0.562 -0.837017551 -0.28103753
115 0.423 0.747 0.549 -0.8603831 -0.29169009
120 0.41 0.743 0.538 -0.891598119 -0.29705923
125 0.4 0.736 0.533 -0.916290732 -0.30652516
130 0.39 0.729 0.517 -0.94160854 -0.31608155
135 0.377 0.726 0.508 -0.975510092 -0.32020526
140 0.371 0.718 0.497 -0.991553216 -0.33128571
145 0.36 0.713 0.49 -1.021651248 -0.33827386
150 0.353 0.708 0.476 -1.041287222 -0.34531119
155 0.341 0.703 0.469 -1.075872802 -0.35239839
160 0.332 0.696 0.459 -1.10262031 -0.36240562
165 0.325 0.693 0.45 -1.123930097 -0.36672528
170 0.316 0.686 0.441 -1.152013065 -0.37687765
175 0.307 0.685 0.433 -1.180907531 -0.37833644
180 0.301 0.677 0.423 -1.200645014 -0.39008401
185 0.293 0.678 0.415 -1.22758267 -0.38860799
190 0.289 0.671 0.409 -1.241328591 -0.39898614
195 0.28 0.664 0.398 -1.272965676 -0.40947313
200 0.27 0.661 0.391 -1.30933332 -0.41400144
205 0.267 0.659 0.384 -1.320506621 -0.41703174
210 0.258 0.649 0.377 -1.354795694 -0.43232256
215 0.252 0.648 0.371 -1.378326191 -0.43386458
220 0.247 0.641 0.362 -1.398366942 -0.44472582
225 0.242 0.639 0.355 -1.418817553 -0.44785082
230 0.236 0.632 0.355 -1.443923474 -0.45886588
235 0.231 0.628 0.343 -1.465337568 -0.46521511
240 0.223 0.622 0.336 -1.500583508 -0.47481519
245 0.219 0.619 0.331 -1.518683549 -0.47965001
250 0.213 0.611 0.323 -1.546463113 -0.49265832
255 0.207 0.609 0.317 -1.575036486 -0.49593701
260 0.203 0.605 0.312 -1.5945493 -0.50252682
265 0.2 0.601 0.306 -1.609437912 -0.50916034
270 0.195 0.595 0.301 -1.63475572 -0.51919387
275 0.19 0.595 0.296 -1.660731207 -0.51919387
280 0.183 0.59 0.29 -1.698269126 -0.52763274
285 0.182 0.585 0.283 -1.703748592 -0.53614343
 290 0.177 0.58 0.278 -1.731605546 -0.54472718
295 0.173 0.577 0.273 -1.754463684 -0.54991301
300 0.169 0.573 0.268 -1.777856564 -0.55686956

LN Absorbancias de 1, 2 i 3 en funció del temps.

0
0 100 200 300 400 500 600 700
-0.2 0.000923725911044675
f(x) = − 0.00149025005498661
0.00400623023553117 x x
− − 0.098497329658615
0.115912634546994
0.128733351174105
R² = 0.99846898362828
f(x)==0.998995055436953
R² 0.999469048408159
− 0.00519007877292191 x − 0.252021599696344
-0.4 R² = 0.998801840597542
-0.6

-0.8
LN A

-1

-1.2

-1.4

-1.6

-1.8

-2

tiempo (s)

LN serie 1 Linear (LN serie 1) LN serie 2 Linear (LN serie 2)

LN serie 3 Linear (LN serie 3) LN serie 4 Linear (LN serie 4)

kap ln kap [OH-] ln [OH-]

Serie 1 0.0052 -5.25909665 -0.47481519 Err:502
Serie 2 0.0015 -6.50229017 -0.47965001 Err:502
Serie 3 0.004 -5.52146092 -0.49265832 Err:502
Serie 4 0.0009 -7.01311579 -0.49593701 Err:502

pendiente m= 1 orden 1

kap [OH-]. ki,i (irrev) Media ki,i (irrev)

Error Aleatorio
Ensayo 1 0.0039 -0.47481519 -0.00821372 -0.004319984 0
Ensayo 2 0.0026 -0.47965001 -0.00542062
Ensayo 3 0.0012 -0.49265832 -0.00243577
Ensayo 4 0.0006 -0.49593701 -0.00120983 Media y error:0,0130 ± 0,0019
mb el seu error aleatori.

Error Aleatorio n-1 2

0.07556683166 t= 4.303
s= 0.02
0,28±0,02

[NaCl]i
0
0
0
0

ABSORBANCIA
temps
LN serie 3 temps serie 4 LN serie 4 0
-0.1154108515 0 0.927 -0.07580171 10
-0.1369658551 10 0.916 -0.08773891 20
-0.15665381 20 0.901 -0.10425002 30
-0.1779312085 30 0.889 -0.11765804 40
-0.1984509387 40 0.879 -0.12897038 50
-0.2218943319 50 0.867 -0.1427163 60
-0.2407984866 60 0.86 -0.15082289 70
-0.2600669054 70 0.85 -0.16251893 80
-0.2836900512 80 0.844 -0.16960278 90
-0.302457358 90 0.835 -0.18032355 100
-0.3243460568 100 0.826 -0.19116051 110
-0.3467246131 110 0.818 -0.20089294 120
-0.3681693234 120 0.809 -0.21195636 130
-0.3915622029 130 0.801 -0.22189433 140
-0.4109802888 140 0.792 -0.23319389 150
-0.4307829161 150 0.784 -0.24334626 160
-0.4494169956 160 0.775 -0.25489225 170
-0.4748151862 170 0.771 -0.26006691 180
-0.4926583198 180 0.764 -0.26918749 190
-0.5108256238 190 0.757 -0.27839203 200
-0.5361434318 200 0.75 -0.28768207 210
-0.5586162876 210 0.743 -0.29705923 220
-0.5762534291 220 0.735 -0.30788478 230
-0.5996568375 230 0.73 -0.31471074 240
-0.6198967188 240 0.723 -0.32434606 250
-0.6292338548 250 0.716 -0.33407511 260
-0.6597124045 260 0.71 -0.34249031 270
-0.6772738314 270 0.703 -0.35239839 280
-0.6991652529 280 0.694 -0.36528332 290
-0.7133498879 290 0.688 -0.37396644 300
-0.7423374248 300 0.683 -0.38126042 310
-0.7571525105 310 0.675 -0.39304259 320
-0.7787050689 320 0.671 -0.39898614 330
-0.7985076962 330 0.667 -0.40496523 340
-0.8187104035 340 0.661 -0.41400144 350
-0.837017551 350 0.654 -0.42464793 360
-0.8603830999 360 0.648 -0.43386458 370
-0.8794767588 370 0.64 -0.4462871 380
-0.8940401229 380 0.635 -0.45413028 390
-0.9213032737 390 0.629 -0.46362402 400
-0.939047719 400 0.624 -0.47160491 410
-0.9571127264 410 0.62 -0.4780358 420
-0.9755100915 420 0.613 -0.48939034 430
-0.9915532164 430 0.609 -0.49593701 440
-1.0161110672 440 0.602 -0.50749783 450
-1.0356374895 450 0.597 -0.51583817 460
-1.0356374895 460 0.592 -0.52424864 470
-1.0700248318 470 0.588 -0.53102833 480
-1.090644119 480 0.583 -0.53956809 490
-1.1056369036 490 0.576 -0.55164762 500
-1.1301029558 500 0.572 -0.55861629 510
-1.1488535051 510 0.568 -0.56563386 520
-1.1647520912 520 0.564 -0.57270103 530
-1.184170177 530 0.556 -0.58698698 540
-1.2006450142 540 0.554 -0.59059059 550
-1.2173958247 550 0.547 -0.60330648 560
-1.237874356 560 0.544 -0.60880603 570
-1.2623083813 570 0.542 -0.61248928 580
 -1.2801341653 580 0.534 -0.62735944 590
-1.2982834838 590 0.53 -0.63487827 600
-1.3167682985 600 0.524 -0.64626359 610
620
630
640
mps. 650
00 600 700
660
670
680
690
700
710
720
730
740
750
760
770
780
790
800
Linear (LN serie 2)
810
Linear (LN serie 4) 820
830
840
850
860
870
880
890
900
m teórica (g) m real (g) 910
Disolución NaOH 0,3M 6.00 6.04 920
Disolución NaCl 0,3 M 3.51 3.38 930
940
950
960
970
980
or Aleatorio 990
1000
 1010
1020
130 ± 0,0019 1030
1040
1050
1060
1070
1080
1090
1100
1110
1120
1130
1140
1150
1160
1170
1180
1190
1200
1210
1220
1230
1240
1250
1260
1270
1280
1290
1300
1310
1320
1330
1340
1350
1360
1370
1380
1390
1400
1410
1420
1430
1440
1450
1460
1470
1480
1490
1500
1510
1520
1530
1540
1550
1560
1570
1580
1590
1600
1610
1620
1630
1640
1650
1660
1670
1680
1690
1700
1710
1720
1730
1740
1750
1760
1770
1780
1790
1800
1810
1820
1830
1840
1850
1860
1870
1880
1890
1900
1910
1920
1930
1940
1950
1960
1970
1980
1990
2000
2010
2020
2030
2040
2050
2060
2070
2080
2090
2100
2110
2120
2130
2140
2150
2160
2170
2180
2190
2200
2210
2220
2230
2240
2250
2260
2270
2280
2290
2300
2310
2320
2330
2340
2350
2360
2370
2380
2390
2400
2410
2420
2430
2440
2450
2460
2470
2480
2490
2500
2510
2520
2530
2540
2550
2560
2570
2580
2590
2600
2610
2620
2630
2640
2650
2660
2670
2680
2690
2700
2710
2720
2730
2740
2750
2760
2770
2780
2790
2800
2810
2820
2830
2840
2850
2860
2870
2880
2890
2900
2910
2920
2930
2940
2950
2960
2970
2980
2990
3000
3010
3020
3030
3040
3050
3060
3070
3080
3090
3100
3110
3120
3130
3140
3150
3160
3170
3180
3190
3200
3210
3220
3230
3240
3250
3260
3270
3280
3290
3300
3310
3320
3330
3340
3350
3360
3370
3380
3390
3400
3410
3420
3430
3440
3450
3460
3470
3480
3490
3500
3510
3520
3530
3540
3550
3560
3570
3580
3590
3600
3610
3620
3630
3640
3650
3660
3670
3680
3690
3700
3710
3720
3730
3740
3750
3760
3770
3780
3790
3800
3810
3820
3830
3840
3850
3860
3870
3880
3890
3900
3910
3920
3930
3940
3950
3960
3970
3980
3990
4000
4010
4020
4030
4040
4050
4060
4070
4080
4090
4100
4110
4120
4130
4140
4150
4160
4170
4180
4190
4200
4210
4220
4230
4240
4250
4260
4270
4280
4290
4300
4310
4320
4330
4340
4350
4360
4370
4380
4390
4400
4410
4420
4430
4440
4450
4460
ABSORBANCIA
serie 4 LN serie 4
0.927 -0.07580171
0.916 -0.08773891
0.901 -0.10425002
0.889 -0.11765804
0.879 -0.12897038
0.867 -0.1427163
0
0.86 -0.15082289 0 500 1000 1500
0.85 -0.16251893
0.844 -0.16960278
0.835 -0.18032355
0.826 -0.19116051
0.818 -0.20089294
0.809 -0.21195636 -0.5
0.801 -0.22189433
0.792 -0.23319389
0.784 -0.24334626
0.775 -0.25489225

-1
0.771 -0.26006691
0.764 -0.26918749 -1
0.757 -0.27839203
0.75 -0.28768207
0.743 -0.29705923
0.735 -0.30788478
0.73 -0.31471074
0.723 -0.32434606
0.716 -0.33407511 -1.5

0.71 -0.34249031
0.703 -0.35239839
0.694 -0.36528332
0.688 -0.37396644
0.683 -0.38126042
0.675 -0.39304259 -2
0.671 -0.39898614
0.667 -0.40496523
0.661 -0.41400144
0.654 -0.42464793
0.648 -0.43386458
0.64 -0.4462871
0.635 -0.45413028
0.629 -0.46362402
0.624 -0.47160491
0.62 -0.4780358
0.613 -0.48939034
0.609 -0.49593701
0.602 -0.50749783
0.597 -0.51583817
0.592 -0.52424864
0.588 -0.53102833
0.583 -0.53956809
0.576 -0.55164762
0.572 -0.55861629
0.568 -0.56563386
0.564 -0.57270103
0.556 -0.58698698
0.554 -0.59059059
0.547 -0.60330648
0.544 -0.60880603
0.542 -0.61248928
0.534 -0.62735944
 0.53 -0.63487827
0.524 -0.64626359
0.519 -0.6558514
0.516 -0.66164851
0.511 -0.67138569
0.507 -0.67924428
0.502 -0.68915516
0.499 -0.69514918
0.494 -0.70521976
0.489 -0.71539279
0.485 -0.72360639
0.482 -0.72981116
0.479 -0.73605468
0.472 -0.75077629
0.468 -0.75928698
0.467 -0.76142602
0.461 -0.77435724
0.456 -0.78526247
0.457 -0.78307189
0.45 -0.7985077
0.447 -0.80519668
0.441 -0.8187104
0.44 -0.82098055
0.434 -0.83471074
0.433 -0.83701755
0.43 -0.84397007
0.428 -0.84863208
0.422 -0.86274996
0.418 -0.87227385
0.415 -0.87947676
0.408 -0.8964881
0.407 -0.89894209
0.403 -0.90881872
0.4 -0.91629073
0.399 -0.91879386
0.395 -0.92886951
0.391 -0.93904772
0.39 -0.94160854
0.387 -0.94933059
0.381 -0.9649559
0.38 -0.96758403
0.376 -0.97816614
0.374 -0.98349948
0.37 -0.99425227
0.366 -1.00512195
0.363 -1.01335244
0.36 -1.02165125
0.357 -1.0300195
0.356 -1.03282455
0.352 -1.0441241
0.352 -1.0441241
0.349 -1.05268336
0.347 -1.0584305
0.341 -1.0758728
0.339 -1.08175517
0.337 -1.08767235
0.335 -1.09362475
0.332 -1.10262031
0.33 -1.10866262
0.327 -1.11779511
0.327 -1.11779511
0.323 -1.13010296
0.318 -1.1457039
0.317 -1.14885351
0.317 -1.14885351
0.316 -1.15201307
0.309 -1.174414
0.308 -1.1776555
0.306 -1.18417018
0.305 -1.1874435
0.302 -1.19732826
0.301 -1.20064501
0.299 -1.20731171
0.297 -1.21402314
0.294 -1.22417551
0.289 -1.24132859
0.289 -1.24132859
0.287 -1.24827306
0.285 -1.2552661
0.283 -1.26230838
0.281 -1.26940061
0.279 -1.2765435
0.279 -1.2765435
0.276 -1.28735441
0.275 -1.29098418
0.271 -1.30563646
0.27 -1.30933332
0.268 -1.3167683
0.265 -1.32802545
0.265 -1.32802545
0.264 -1.33180618
0.261 -1.34323487
0.261 -1.34323487
0.258 -1.35479569
0.257 -1.35867919
0.253 -1.37436579
0.252 -1.37832619
0.249 -1.39030238
0.251 -1.38230234
0.247 -1.39836694
0.248 -1.39432653
0.245 -1.40649707
0.245 -1.40649707
0.242 -1.41881755
0.242 -1.41881755
0.24 -1.42711636
0.238 -1.43548461
0.238 -1.43548461
0.237 -1.43969514
0.233 -1.45671683
0.232 -1.46101791
0.232 -1.46101791
0.23 -1.46967597
0.228 -1.47840965
0.227 -1.48280526
0.225 -1.49165488
0.223 -1.50058351
0.223 -1.50058351
0.222 -1.5050779
0.22 -1.51412773
0.221 -1.50959258
0.218 -1.52326022
0.217 -1.52785793
0.213 -1.54646311
0.215 -1.53711725
0.214 -1.54177926
0.212 -1.551169
0.21 -1.56064775
0.207 -1.57503649
0.207 -1.57503649
0.206 -1.57987911
0.205 -1.5847453
0.204 -1.58963529
0.203 -1.5945493
0.204 -1.58963529
0.201 -1.60445037
0.197 -1.62455155
0.199 -1.61445045
0.197 -1.62455155
0.196 -1.62964062
0.197 -1.62455155
0.196 -1.62964062
0.193 -1.64506509
0.193 -1.64506509
0.192 -1.65025991
0.193 -1.64506509
0.191 -1.65548185
0.189 -1.66600826
0.19 -1.66073121
0.187 -1.67664666
0.187 -1.67664666
0.185 -1.68739945
0.185 -1.68739945
0.184 -1.69281952
0.183 -1.69826913
0.181 -1.70925825
0.18 -1.71479843
0.18 -1.71479843
0.18 -1.71479843
0.182 -1.70374859
0.181 -1.70925825
0.178 -1.72597173
0.177 -1.73160555
0.178 -1.72597173
0.179 -1.72036947
0.177 -1.73160555
0.175 -1.74296931
0.175 -1.74296931
0.174 -1.74869998
0.174 -1.74869998
0.172 -1.7602608
0.173 -1.75446368
0.171 -1.76609172
0.169 -1.77785656
0.169 -1.77785656
0.169 -1.77785656
0.167 -1.78976147
0.168 -1.7837913
0.167 -1.78976147
0.165 -1.80180981
0.166 -1.79576749
0.164 -1.80788885
0.164 -1.80788885
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