Components

No. Formula Molar Mass Name

1. C6H14 86.177 Hexane
2. C3 H 6 O 58.080 Acetone

Constant Value
Temperature (K) 338.15 Temperature (C) 65

P [kPa] x1 [mol/mol] x2 [mol/mol] y1 [mol/mol] y2 [mol/mol]

152.774 0.268 0.732 0.528 0.472
160.133 0.375 0.625 0.570 0.43
165.040 0.495 0.505 0.613 0.387
168.160 0.648 0.352 0.675 0.325
167.506 0.690 0.31 0.690 0.31
167.640 0.768 0.232 0.740 0.26
155.707 0.905 0.095 0.840 0.16
147.521 0.975 0.025 0.940 0.06

VAN LAAR
ln g1 ln g2 g1 g2 G^E/RT
-0.55334 0.80765 0.57503 2.24262 0.44290359956255
-0.16121 0.63193 0.85112 1.88124 0.33450484363014
-0.05275 0.55185 0.94862 1.73647 0.25257487952236
-0.01361 0.50214 0.98648 1.65225 0.16793527141349
-0.00914 0.49314 0.99090 1.63745 0.14656678107418
-0.00402 0.47953 0.99599 1.61531 0.10816365580724
-0.00047 0.46216 0.99953 1.58749 0.0434815922026
-0.00003 0.45543 0.99997 1.57685 0.01135896303735

Components
 No. Formula Molar Mass Name
1. C6H14 86.177 Hexane
2. C3 H 6 O 58.080 Acetone

Constant Value
Pressure 101.33

T [K] T [C] x1 [mol/mol] x2 [mol/mol] y1 [mol/mol]

341.90 68.75 0.00000 1.00000 0.00000
332.06 58.91 0.09420 0.90580 0.33500
326.66 53.51 0.19860 0.80140 0.48300
324.72 51.57 0.29890 0.70110 0.54000
323.69 50.54 0.39830 0.60170 0.58400
323.15 50.00 0.49950 0.50050 0.61000
322.93 49.78 0.59990 0.40010 0.61600
322.99 49.84 0.69990 0.30010 0.65400
323.46 50.31 0.80070 0.19930 0.70000
324.91 51.76 0.90150 0.09850 0.79500
329.40 56.25 1.00000 0.00000 1.00000

VAN LAAR
ln g1 ln g2 g1 g2 G^E/RT
0.05621 1.05782 0
0.13637 -0.00508 1.14611 0.99494 0.00824782539267
2.60149 -0.54992 13.48379 0.57699 0.07594765864934
0.25725 -0.16094 1.29337 0.85134 -0.035944423042
0.03439 -0.05187 1.03499 0.94945 -0.0175128212848
0.00948 -0.03250 1.00952 0.96802 -0.0115305613221
0.00325 -0.02512 1.00325 0.97519 -0.0081046495271
0.00114 -0.02131 1.00114 0.97892 -0.0055985137763
0.00034 -0.01898 1.00034 0.98120 -0.0035086057847
0.00006 -0.01742 1.00006 0.98273 -0.0016614004426
-0.01633 0.00000 0.98380 0

Kurva T-xy
345.00

340.00

335.00
 Kurva T-xy
345.00

340.00

335.00

330.00
T [K]

325.00

320.00

315.00

310.00
0.00000 0.20000 0.40000 0.60000 0.80000 1.00000
x,y [mol/mol]
 Sumber data Smith vanes edisi 7
Konstanta Antoine
A B C
Hexane 13.8193 2696.04 224.317
Acetone 14.3145 2756.22 228.06

PERCOBAAN
P1 sat (Kpa) P2 sat (Kpa) g1 g2 ln g1 ln g2
90.076863870864 135.5759139669 3.34145272332 0.72660407034 1.20640565953 -0.31937356
90.076863870864 135.5759139669 2.702160683 0.81261856016 0.99405170594 -0.20749346
90.076863870864 135.5759139669 2.26898295416 0.93288102819 0.81933169328 -0.0694776
90.076863870864 135.5759139669 1.94463549395 1.14519872368 0.6650745528 0.13557818
90.076863870864 135.5759139669 1.85958960827 1.23551444426 0.62035582267 0.211487437
90.076863870864 135.5759139669 1.79322545278 1.38573591943 0.58401592725 0.326231348
90.076863870864 135.5759139669 1.60444778047 1.93429172445 0.47277963537 0.659741226
90.076863870864 135.5759139669 1.57893346024 2.61145501174 0.45674959394 0.959907542

G^E/x1x2RT EROR intercept= 2.2061

2.25768 0.79784 slope= -2.4087
1.42722 0.27330 A'12 -4.93583415597
1.01040 0.46682 A'21 0.45328860886
0.73625 1.85045
0.68521 2.36779
Kurva Data Percobaan
0.60706 3.84645
0.50575 10.28158 2.5
0.46601 40.31790
2

1.5
x1x2/Gᴱ/RT

f(x) = − 2.40872491300054 x + 2.20614768862554

R² = 0.774493195042879
1

0.5

0
0.2 0.3 0.4 0.5 0.6 0.7 0
x1 [mol/mol]
 0
0.2 0.3 0.4 0.5 0.6 0.7 0
x1 [mol/mol]

Sumber data Smith vanes edisi 7

Konstanta Antoine
A B C
Hexane 13.8193 2696.04 224.317
Acetone 14.3145 2756.22 228.06
PERCOBAAN
y2 [mol/mol] P1 sat (Kpa) P2 sat (Kpa) g1 g2 ln g1
1.00000 101.48408 152.68200 0.66367 0.00000
0.66500 73.72134 111.04572 4.88808 0.66992 1.58680
0.51700 61.26909 92.36463 4.02221 0.70774 1.39183
0.46000 57.22771 86.30023 3.19889 0.77038 1.16280
0.41600 55.16990 83.21200 2.69301 0.84191 0.99066
0.39000 54.11484 81.62854 2.28674 0.96729 0.82713
0.38400 53.68964 80.99036 1.93798 1.20079 0.66165
0.34600 53.80534 81.16401 1.75976 1.43941 0.56518
0.30000 54.71854 82.53459 1.61894 1.84806 0.48177
0.20500 57.61388 86.87975 1.55100 2.42738 0.43890
0.00000 67.35953 101.50235 1.50432 0.40834

G^E/x1x2RT EROR intercept= -61.231

0.05621 1.00000 slope= 79.02
0.09666 26.87091 A'12 0.05621451459
0.47718 1.00802 A'21 -0.01633159674
-0.17152 5.58106
-0.07307 17.61856
-0.04612 35.38721 Kurva Data Percobaa
-0.03377 59.00771 50.00000
-0.02665 91.18032
-0.02199 145.83066 0.00000 f(x) = 79.0203512493983 x − 61.231393340
-0.01871 291.73072 R² = 0.084372169413805
0.00000 0.20000 0.40000 0.6000
-0.01633 1.00000 -50.00000
x1x2/Gᴱ/RT

-100.00000

-150.00000

-200.00000

-250.00000
 x1x2/G
-150.00000

-200.00000

-250.00000

-300.00000
x1 [mol/mol]

00 1.00000
AAN
G^E/RT G^E/x1x2RT x1x2/G^2/RT Kurva D
0.089535272806 0.456402785285 2.19104710190702
0.243085980211 1.0371668489 0.96416502422938 25.00000
0.3704829993653 1.482080205482 0.674727316579259
0.478691829482 2.098641929196 0.476498628035549
20.00000
0.4936066232348 2.307651347521 0.433341024879711
0.524209904935 2.94209043269 0.339894378802507
0.4905409864393 5.705623570099 0.175265680904808 15.00000
0.4693285426363 19.25450431329 0.051935899451329

10.00000

5.00000

0.00000

Data Percobaan -5.00000

x1 [mol/

Kurva P-xy
x + 2.20614768862554
170
165
160
155
P [kPa]

150
0.6 0.7 0.8 0.9 1 1.1 145
x1 [mol/mol] 140
135
0.2 0.3 0.4 0.5 0.6
x,y [mol/m
 150

P[
0.6 0.7 0.8 0.9 1 1.1 145
x1 [mol/mol] 140
135
0.2 0.3 0.4 0.5 0.6
x,y [mol/m

PERCOBAAN
ln g2 G^E/RT G^E/x1x2RT x1x2/G^E/RT
-0.40997 -0.40997 0.00000
6.00000
-0.40059 -0.21338 -2.50074 -0.39988
-0.34568 -0.00061 -0.00383 -261.14520
-0.26087 0.16466 0.78576 1.27265 5.00000
-0.17208 0.29104 1.21439 0.82346
-0.03326 0.39650 1.58602 0.63051 4.00000
0.18298 0.47013 1.95872 0.51054
0.36423 0.50488 2.40371 0.41602 3.00000
0.61414 0.50815 3.18433 0.31404
0.88681 0.48302 5.43955 0.18384 2.00000

1.00000

0.00000

-1.00000

-2.00000

-3.00000

Kurva Data Percobaan

493983 x − 61.2313933405429
413805
0.40000 0.60000 0.80000 1.00000 1.20000
x1 [mol/mol]
 Kurva Data Percobaan dan Van Laar

ln γ1 van laar
ln γ2 van laar
Gᴱ/RT van laar
Gᴱ/x1x2RT van laar
ln γ1
ln γ2
Gᴱ/RT
Gᴱ/x1x2RT

x1 [mol/mol]

Kurva P-xy

0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

x,y [mol/mol]
0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
x,y [mol/mol]

Kurva Data Percobaan dan Van Laar

6.00000

5.00000

4.00000

3.00000

2.00000

1.00000

0.00000

-1.00000

-2.00000

-3.00000

x1 [mol/mol]
n laar
n laar
van laar
2RT van laar

2RT
ar

ln γ1 van laar
ln γ2 van laar
Gᴱ/RT van laar
Gᴱ/x1x2RT van laar
ln γ1
ln γ2
Gᴱ/RT
Gᴱ/x1x2RT
 y1 y2 P2 sat
P [kPa] x1 [mol/mol] x2 [mol/mol] P1 sat (Kpa)
[mol/mol] [mol/mol] (Kpa)
152.774 0.268 0.732 0.528 0.472 90.0769 135.5759
160.133 0.375 0.625 0.570 0.43 90.0769 135.5759
165.040 0.495 0.505 0.613 0.387 90.0769 135.5759
168.160 0.648 0.352 0.675 0.325 90.0769 135.5759
167.506 0.690 0.31 0.690 0.31 90.0769 135.5759
167.640 0.768 0.232 0.740 0.26 90.0769 135.5759
155.707 0.905 0.095 0.840 0.16 90.0769 135.5759
147.521 0.975 0.025 0.940 0.06 90.0769 135.5759

x2 y1 y2 P1 sat
T [K] T [C] x1 [mol/mol]
[mol/mol] [mol/mol] [mol/mol] (Kpa)
341.90 68.75 0.0000 1.0000 0.0000 1.0000 101.4841
332.06 58.91 0.0942 0.9058 0.3350 0.6650 73.7213
326.66 53.51 0.1986 0.8014 0.4830 0.5170 61.2691
324.72 51.57 0.2989 0.7011 0.5400 0.4600 57.2277
323.69 50.54 0.3983 0.6017 0.5840 0.4160 55.1699
323.15 50.00 0.4995 0.5005 0.6100 0.3900 54.1148
322.93 49.78 0.5999 0.4001 0.6160 0.3840 53.6896
322.99 49.84 0.6999 0.3001 0.6540 0.3460 53.8053
323.46 50.31 0.8007 0.1993 0.7000 0.3000 54.7185
324.91 51.76 0.9015 0.0985 0.7950 0.2050 57.6139
329.40 56.25 1.0000 0.0000 1.0000 0.0000 67.3595

T [K] x1 [mol/mol] y1 [mol/mol]

341.90 0.0000 0.0000
332.06 0.0942 0.3350
326.66 0.1986 0.4830
324.72 0.2989 0.5400
323.69 0.3983 0.5840
323.15 0.4995 0.6100
322.93 0.5999 0.6160
322.99 0.6999 0.6540
323.46 0.8007 0.7000
324.91 0.9015 0.7950
329.40 1.0000 1.0000

P [kPa] x1 [mol/mol] y1 [mol/mol]

152.774 0.268 0.528
160.133 0.375 0.570
165.040 0.495 0.613
168.160 0.648 0.675
167.506 0.690 0.690
167.640 0.768 0.740
155.707 0.905 0.840
147.521 0.975 0.940
 g1 g2 ln g1 ln g2 G^E/RT G^E/x1x2RT x1x2/G^2/RT
3.3415 0.7266 1.2064 -0.3194 0.0895 0.4564 2.1910
2.7022 0.8126 0.9941 -0.2075 0.2431 1.0372 0.9642
2.2690 0.9329 0.8193 -0.0695 0.3705 1.4821 0.6747
1.9446 1.1452 0.6651 0.1356 0.4787 2.0986 0.4765
1.8596 1.2355 0.6204 0.2115 0.4936 2.3077 0.4333
1.7932 1.3857 0.5840 0.3262 0.5242 2.9421 0.3399
1.6044 1.9343 0.4728 0.6597 0.4905 5.7056 0.1753
1.5789 2.6115 0.4567 0.9599 0.4693 19.2545 0.0519

P2 sat
g1 g2 ln g1 ln g2 G^E/RT G^E/x1x2RT
(Kpa)
152.6820 0.6637 0.0000 -0.4100 -0.4100
111.0457 4.8881 0.6699 1.5868 -0.4006 -0.2134 -2.5007
92.3646 4.0222 0.7077 1.3918 -0.3457 -0.0006 -0.0038
86.3002 3.1989 0.7704 1.1628 -0.2609 0.1647 0.7858
83.2120 2.6930 0.8419 0.9907 -0.1721 0.2910 1.2144
81.6285 2.2867 0.9673 0.8271 -0.0333 0.3965 1.5860
80.9904 1.9380 1.2008 0.6616 0.1830 0.4701 1.9587
81.1640 1.7598 1.4394 0.5652 0.3642 0.5049 2.4037
82.5346 1.6189 1.8481 0.4818 0.6141 0.5082 3.1843
86.8798 1.5510 2.4274 0.4389 0.8868 0.4830 5.4396
101.5023 1.5043 0.4083
 ln g1 ln g2 g1 g2 G^E/RT G^E/x1x2RT
-0.55334 0.80765 0.57503 2.24262 0.442904 2.25768
-0.16121 0.63193 0.85112 1.88124 0.334505 1.42722
-0.05275 0.55185 0.94862 1.73647 0.252575 1.01040
-0.01361 0.50214 0.98648 1.65225 0.167935 0.73625
-0.00914 0.49314 0.99090 1.63745 0.146567 0.68521
-0.00402 0.47953 0.99599 1.61531 0.108164 0.60706
-0.00047 0.46216 0.99953 1.58749 0.043482 0.50575
-0.00003 0.45543 0.99997 1.57685 0.011359 0.46601

x1x2/G^2/RT ln g1 ln g2 g1 g2 G^E/RT G^E/x1x2RT

0.0000 0.0562 1.0578 0.0000 0.0562
-0.3999 0.1364 -0.0051 1.1461 0.9949 0.0082 0.0967
-261.1452 2.6015 -0.5499 13.4838 0.5770 0.0759 0.4772
1.2726 0.2573 -0.1609 1.2934 0.8513 -0.0359 -0.1715
0.8235 0.0344 -0.0519 1.0350 0.9495 -0.0175 -0.0731
0.6305 0.0095 -0.0325 1.0095 0.9680 -0.0115 -0.0461
0.5105 0.0032 -0.0251 1.0033 0.9752 -0.0081 -0.0338
0.4160 0.0011 -0.0213 1.0011 0.9789 -0.0056 -0.0267
0.3140 0.0003 -0.0190 1.0003 0.9812 -0.0035 -0.0220
0.1838 0.0001 -0.0174 1.0001 0.9827 -0.0017 -0.0187
-0.0163 0.0000 0.9838 0.0000 -0.0163
 EROR
0.79784
0.27330
0.46682
1.85045
2.36779
3.84645
10.28158
40.31790

EROR
1.0000
26.8709
1.0080
5.5811
17.6186
35.3872
59.0077
91.1803
145.8307
291.7307
1.0000