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All thanks to our creator Almighty God for his loving mercies and kindness He has shown
me.
More than five plant supervisors, plant operators and laboratory technicians and analysts
were consulted before executing this project. Their advice has not only shown me how to
unearth the success of this project but also helped me improve my own understanding
about this project.
I am deeply grateful for their insights, encouragement and willingness to help me come out
with a successful project.
For this project I was fortunate to work with an excellent metallurgical laboratory
supervisor, Mr. Samuel Sackey, whose flexibility, patience and light touch made our
collaboration enjoyable.
I also wish to acknowledge, with gratitude, all other laboratory assistants for their diverse
efforts. I say CUDOS to your support.
I am grateful to the following colleagues for ideas, inspiration and support: Nicholas Nana
Boakye (Business Dev’t AGA), Acheampong Boateng Enoch, Ampofo Obed, Abu
Prempeh, Minnoh Kenneth Peter Junior, Owusu-Adjei Daniel and Aseidu Djan Micheal.
I am indebted to hundreds of AGA workers over my stay and made this project a pleasant
and rewarding task.
1.0 INTRODUCTION
The In-Line Leach Reactor (ILR) has been used to increase recoveries of both free
gold and sulphide related gold. In their installations to present time, significant
increases in total recoveries have been achieved. This reflects the ILR’s very fast
leach kinetics and capacity to leach coarse and high grade gold concentrates. At the
South Treatment Plant of AngloGold Ashanti, Obuasi mine, there are two installed
Inline Leach Reactors (ILR 1000 and ILR 2000) for such purpose.
This project focuses on the effect of particle size on ILR 2000 performance.
PROBLEM DEFINITION
Tails from ILR 2000 are still on the higher side currently above 180g/t. ILR tails are
been pumped to the CIL circuit for further dissolution.
Particle size of the ILR 2000 feed must be investigated to determine the optimum
particle size which will yield a maximum recovery.
PROBLEM JUSTIFICATION
Gravity gold concentrates produced by the Knelson concentrators needs be seized
into various fractions and each fraction subjected to intensive cyanidation leaching.
The leaching results would help to know at which particle size is yielding an
optimum recovery.
1.1 SCOPE
The project focuses on the effect of particle size on ILR 2000 recovery.
1.2 OBJECTIVES
To determine which particle size of the feed material yield maximum recovery.
2.0 BACKGROUND
The use of batch centrifugal concentrators has become standard practice to recover
free gravity gold from grinding circuits. Traditionally concentrates from these
separations are upgraded by shaking tables. Replacing the tables with ILR will
significantly improve recoveries and lower the security risks associated with gravity
circuits. The fast leach kinetics and aggressive chemical conditions of the ILR have
also been shown to limit the impact of sulphide minerals such as stibnite sometimes
called antimonite (a sulfide mineral with the formula Sb2S3. This soft grey material
crystallizes in an orthorhombic space group. It is the most important source for the
metalloid antimony), Pyrrhotite and pyrites in complex sulphide gold concentrates.
Accordingly, the ILR offers potential to significantly increase overall mill
recoveries.
Residence time is predicted in the laboratory and set by reactor volume and solids
feed rate. Barren solids are removed from the circuit via a de-watering cone and de-
watering screen. The pregnant solution is pumped to electrowin, resin or carbon
circuits for gold recovery.
High recovery: The target recovery of free gold for the ILR is plus 98%. Very high
recovery rates on complex sulphide-related gold can also be expected.
High security: The ILR will significantly improve gold concentrate security by
replacing the tabling step and eliminate concentrate handling.
Low operating cost– high automation: The system offers fully integrated
electronic control of all critical leach parameters and is fully automated. Recovery
costs per ounce are attractive.
Low maintenance: There are no high speeds or high wear components in the
system.
Very simple: Only one pump and one drum drive. No complex reagents.
3.0 METHODOLOGY
Safety goggles
Laboratory overall
Mass balance
DO meter
pH meter
Six 1L beakers
Electronic stirrers
The calibration of the DO meter was done by recording a room temperature (25ºC)
and adjusting the calibrating sensor to read the expected DO reading of 8.6ppm as
by the manufacturer’s data.
The pH meter was calibrated with the buffer 7 solution as it was to be used to check
the pH of basic media.
3.5 SAMPLING
Composite samples were taken from ILR 2000 feed cone at different days and
blended.
The sample was filtered and moisture content determined and then divided into two
portions. To the first portion;
Wet sizing analysis was employed to determine the percent passing with respective
sieves of aperture; 4mm, 3.35mm, 2mm, 1mm, 500µm, 300µm,150 µm,75 µm.
4mm, 3.35mm and 2mm size samples were combined as they were mostly scats.
Retained fractions of samples on the respective sieve were weighed and subjected
to intensive cyanidation leaching.
The assay results indicated that +300µm recorded the highest gold grade.
The second portion of the sample was also equally divided into three portions and
seized into +500 µm, -500 µm, +300 µm, -300 µm, +150 µm, -150 µm and
subjected to leaching.
150g of cyanide powder was weighed into a cleaned and dried 500 ml beaker.
500ml of water was conditioned with caustic to a pH of 12 and placed under stirrer
for homogeneous mixing of the solution.
The caustic solution was poured into portions in two different beakers.
To the fist portion; the weighed cyanide powder was then transferred into it under
the stirrer for10 minutes and then transferred into a 500ml volumetric flask and
topped with the other half of the conditioned caustic solution till it reached the
etched mark.
The cyanide solution was corked, labeled and placed on the laboratory bench.
3.7 LEACHING
The required amount of sample to be leached was weighed into individual beakers
and was repulped at 26% solids.
The samples were then placed under stirrers and left for 5 minutes to ensure
homogeneous mixing prior to conditioning of the slurry.
Individual pHs of the samples were modified to 12 by addition of lime whiles the
DO level were raised to 14ppm.
Solution profile was done throughout the process to monitor the dissolution trend of
gold in the samples for every two hours.
The DO and pH were hourly checked to maintain their level throughout the
leaching time.
The same procedure was repeated for -500µm, -300 µm and -150µm samples for
twelve hours of leaching time.
4.0 RESULTS
125
%solids = x 100
149.3
= 0.8372
= 3717.92g
Table 1.0 Weight retained, Sample head grades, Total Sulphur and Arsenic
content in various fractions.
WT RTD (g) 319.30 626.90 1567.60 776.30 562.70 270.50 317.60 4440.90
FORMULAE
Gold content =
𝑤𝑒𝑖𝑔ℎ𝑡 𝑜𝑛 𝑠𝑖𝑒𝑣𝑒
% weight retained = 𝑥 100
𝑡𝑜𝑡𝑎𝑙 𝑤𝑒𝑖𝑔ℎ𝑡 𝑜𝑓 𝑏𝑢𝑙𝑘 𝑠𝑎𝑚𝑝𝑙𝑒
Sulphur content =
Arsenic content=
Cal.
SIZE ( um ) -75 +75 +150 +300 +500 +1000 +2000 H/S
GOLD 8.26 15.83 32.59 29.27 12.67 1.19 0.19 781.23
SULPHUR 10.58 26.31 37.24 13.12 5.40 1.18 6.17 8.05
ARSENIC 14.63 28.32 34.88 13.23 6.40 2.14 0.39 6.57
%WT RTD 7.19 14.12 35.30 17.48 12.67 6.09 7.15 100.0
%PASSING 0.00 7.19 21.31 56.61 74.09 86.76 92.85
40.0
35.0
GOLD
30.0 SULPHUR
%Au, %S, %As & Wt Rtd
25.0
ARSENIC
%WT RTD
20.0
15.0
10.0
5.0
0.0
-75 +75 +150 +300 +500 +1000 +2000
SIZE [um]
The volume of cyanide used for leaching can be mathematically expressed as;
So for a sample of dry mass 150g and a consumption of 50kg/ton the volume of
cyanide solution will be;
50 𝑥 150
0.30 𝑥 1000
Particle size (µm) +2000 +1000 +500 +300 +150 +75 -75
% Rec [Ind] 93.19 92.74 88.03 93.60 80.40 66.61 88.86
Soln Au [g/t] 22.96 201.87 717.12 1036.56 484.17 482.07 624.96
% Recovery. [R+r] 94.10 94.79 88.47 92.53 77.40 62.25 86.21
Dry Mass [ g ] 80 100 150 150 150 150 150
Initial Ph 9.42 8.89 8.62 9.6 11.8 10 10.7
Finaln Ph 13.3 12.5 12.2 12.1 12.62 12.5 12.5
conc of H2O2 ppm 16 16 16 16 16 16 16
Residence time 6 6 18 18 18 18 18
Initial NaCN [kg/t] 50.0 50.0 50.0 50.0 50.0 50.0 50.0
ASSAYS
Head Grade g/t Au 21.2 153.0 781.3 1308.0 721.3 875.8 897.1
Solid Residue g/t Au 1.44 11.10 93.50 83.70 141.40 292.40 99.98
Soln. Residue g/t Au 2.87 29.60 129.60 185.10 87.50 86.60 111.60
Soln Cyanide [ppm] 650 1250 1350 507 368 453 429
Solution Ph 12.35 12.26 12.45 12.14 12.10 12.12 12.24
Filtrate volume [ml] 640.0 682.0 830.0 840.0 830.0 835.0 840.0
Final DO2 After
[ppm] 17.0 16.4 15.3 17.0 16.4 14.4 13.0
CALCULATIONS
CN Consumpt'n
[kg/t] 44.80 41.48 42.53 47.16 47.96 47.48 47.60
Calc. Head [Au g/t] 24.40 212.97 810.62 1120.26 625.57 774.47 724.94
Metal Bal. 1.154 1.392 1.038 0.856 0.867 0.884 0.808
LEACHIMNG RESULTS FOR -500 µm, -300 µm, and -150 µm SAMPLES
ASSAYS
Head Grade g/t Au
992.9 1224.8 960.3
Solid Residue g/t Au
76.98 78.21 100.80
Soln. Residue g/t Au
158.80 191.20 111.80
Soln Cyanide [ppm]
6750 5800 4100
Solution Ph
13.37 13.49 13.40
Filtrate volume [ml]
820.0 830.0 720.0
Final DO2 After [ppm]
16.4 14.4 13.0
CALCULATIONS
CN Consumpt'n [kg/t]
13.10 17.91 20.48
Calc. Head [Au g/t]
945.09 1136.18 905.76
Metal Bal.
0.952 0.928 0.943
𝐶𝑎𝑙𝑐𝑢𝑙𝑎𝑡𝑒𝑑 ℎ𝑒𝑎𝑑
Metal balance = 𝐴𝑠𝑠𝑎𝑦 ℎ𝑒𝑎𝑑
100.0
90.0
80.0
70.0
% Au Dissolution
60.0
% Au Dist
50.0
%Diss [Ind]
40.0
30.0
20.0
10.0
0.0
2000 1000 500 300 150 75 -75
Mesh [µm]
A graph of Au distribution against Dissolution for -500 µm, -300 µm and -150µm
94.0 110.0
% Au Dist 100.0
93.0
% Diss 90.0
92.0
% Au Distribution
% Au Dissolution
80.0
91.0
70.0
90.0
60.0
89.0
50.0
88.0 40.0
-150 -300 -500 As Is
Mesh [um]
5.0 DISCUSSIONS
At the end of the test work it was realized that 35.3% of the bulk sample was
captured at particle size of +150µm followed by +300µm particle size also
recording a value of 17.48% of the total bulk.
The mass distribution result of the sample evidently shows the contribution of the
SAG mill to the overall volume of gravity gold concentrates from the Knelson
concentrators.
This is not to say that the ball mill doesn’t contribute to the total volume but then
there is a possibility of the free gold from the ball mill being finer than that of the
sag mill might escape during the concentration process.
In total, +2000 µm and +1000 µm particle sizes only contributed 13.24% of the
total bulk sample.
A good leaching test work was done with recoveries 94.79% down to 62.25%.
From the leaching data +1000 µm gave a highest recovery followed by +2000 µm
particle sizes but these two only contribute 13.24% of total sample and a gold
content of 1.38%.
With these results it is evidently clear that particle sizes with high gold contents are
+300 µm and +150 µm.
Secondly, leaching results of -500 µm, -300 µm and -150 µm also shows that,
-300µm is recoverable compared to the others.
It was realized that finer particle sizes were recording lower recoveries and their
total sulphur contributions can account for such a trend. As the particle sizes
recorded higher total sulphur values, this is an indication that gold contents are
occluded in them and hence making them not leachable.
More also, the Pyrites to Arsenopyrite ratios of the fractions also give rise to such
an expectation of results. The higher the ratio value, the higher the Arsenopyrite
content in the sample and the less the recoverable the sample as the much of the
gold content in the sample would be occluded in the arsenopyrite.
CONCLUSSION
• +150µm particle sizes recorded 35.3% followed by +300µm particle size also
recording a value of 17.48% of the total bulk. The mass distribution result of the
sample evidently shows the contribution of the SAG mill to the overall volume of
gravity gold concentrates
• Particle sizes to the gravity concentration are of acceptable range and mesh
fractions were all leachable with -300µm particle sizes given the maximum
recovery of 93.12%.
• +150µm and +75µm particles sizes were less leachable and recorded sulphur
content of 37.24% and 26.31% respectively
6.2 RECOMMENDATIONS
• Further test works should be carried on to ascertain the gold distribution trend of
ILR 2000 feed materials
Taggart, AF., Handbook of Mineral Dressing, John Wiley and Sons Inc., NY (1945)