TCVN TIEU CHUAN QUOC GIA TCVN 10736-6:2016 ISO 16000-6:2011 KHONG KHi TRONG NHA - PHAN 6: XAC DINH _ HOP CHAT HU'U CO’ BAY HOI TRONG KHONG KHi TRONG NHA VA TRONG BUONG THU’ BANG CACH LAY MAU CHU DONG TREN CHAT HAP THU — TENAX TA (R), GIAI HAP NHIET VA SAC KY KHi SU DUNG MS HOAC MS-FID Indoor air - Part 6: Determination of volatile organic compounds in indoor and test chamber air by active sampling on Tenax TA sorbent, thermal desorption and gas chromatography using MS or MS-FID HA NOI - 2016TCVN 10736-6:2016 Loi noi dau TCVN 10736-6:2016 hoan ton tong dong voi ISO 16000-6:2011 TCVN 10736-6:2016 do Ban kj thuat tiéu chudn quéc gia TCVNITC 146 Chat Iugng khéng khi bién soan, Téng cuc Tiéu chudn 80 Ivéng Chat Iveng dé nghi, 86 Khoa hee va Céng nghé céng bd. Bd TCVN 10736 (ISO 16000) Khéng khi trong nha gdm cac phan sau: TCVN 10736-1: 2015 (ISO 16000-1:2004) Phan 1: Cac khia canh chung cila ké hoach ly mau, TOWN 10736-2:2015 (ISO 16000-2:2004) Phan 2: Ké hoach idy mu formaldehyt, TON 10736-3:2015 (ISO 16000-3:2011) Phan 3: Xéc dinh formaldehyt va hop chat cacbonyl khdc trong khéng khi trong nha va khéng Kf trong buéng thir - Phuong phédp lay mau chi dong; TCYN 10736-4:2015 (ISO 16000-4:2011) Phan 4: Xdc dinh formaidehyt - Phuong phép idy mau Khuéch tan; TCVN 10736-5:2015 (ISO 16000-5:2007) Phan 5: Ké hoach I4y mau d6i véi hop chét hou co bay hoi (VOC); TCVN 10736-6:2016 (ISO 16000-6:2011) Phan 6: Xé¢ dinh hop chat hit co bay hoi trong khéng Khi trong nha va trong budng thie bang céch lay mau chi déng trén chat hdp phy Tenax TA®, gidi hap nhiét va sac ky khi sir dung MS hoac MS-FID; TCVN 10736-7:2016 (ISO 16000-7:2007) Phan 7: Chién luge léy mau dé xdc dinh néng dé soi aming truyén trong khéng kh; TCVN 10736-8:2016 (ISO 16000-8:2007) Phan 8: Xéc dinh thoi gian Ivu trung binh tai ohd coe khéng khi trong céc toa nha dé xde dinh dc tinh céc diéu kién théng gid; TCVN 10736-9:2016 (ISO 16000-9:2006) Phan 9: X4c dinh phat thai cila hop chat haw ov bay hot ti cdc sén phdm xéy dung va dé ndi thét- Phuong phap budng thi phat thai; TCVN 10736-10:2016 (ISO 16000-10:2006) Phan 10: Xéc dinh phat thai cda hop chat hau co bay hoi ti cdc san phdm xéy dung va dé ngi thét— Phuong phap ngan thi phat thai; TCVN 10736-11:2016 (ISO 16000-11:2006) Phan 11: Xéc dinh phat thai cla hop chAt hau co bay hoi tiv cc sén phdm xéy dung va dé néi that - Léy m4u, bdo quan mau va chudn bj mau thik; TCVN 10736-12:2016 (ISO 16000-12:2008) Phan 12: Chién lvoe dy mu d6i v6i polycloro biphenyl (PCB), polycloro dibenzo-p-dioxin (PCDD), polyctoro dibenzofuran (PCDF) va hydrocacbon thom da véng (PAH); ‘TCVN 10736-13:2016 (ISO 16000-3:2008) Phan 13: Xéc dinh téng (pha Khi va pha hat) polycioro bipheny! gidng dioxin (PCB) va polycioro dibenzo-p-dioxinipolycloro dibenzofuran (PCDD/PCDF) ~ Thu th8p méu trén cai loc dure hé tre bang chat hép phy; TCVN 10736-14:2016 (ISO 16000-14:2009) Phén 14: Xe dinh téng (pha khi v8 pha hat) polycloro biphenyl giéng dioxin (PCB) va polyctoro dibenzo-p-dioxin/polycloro dibenzofuran (PCDD/PCDF} — Chiét, lam sach va phan tich bang sac ky khI phan giai cao va khéi phd. ‘TCVN 10736-6:2016 B6 ISO 16000 Indoor air cdn c6 cae phan sau’ = ISO 16000-16:2008 Indoor air ~ Part 15: Sampling strategy for nitrogen dioxide (NOz) = ISO 16000-16:2008 Indoor air - Part 16: Detection and enumeration of moulds - Sampling by filtration = ISO 16000-17:2008 Indoor air - Part 17: Detection and enumeration of moulds - Culture-based method = ISO 16000-18:2011 Indoor air - Part 18: Detection and enumeration of moulds - Sampling by impaction = 180 16000-19:2012 Indoor air - Part 19: Sampling strategy for moulds = ISO 16000-20:2014 Indoor air - Part 20: Detection and enumeration of moulds ~ Determination of total spore count = ISO 16000-21:2013 Indoor air - Part 21: Detection and enumeration of moulds - Sampling from materials ~ ISO 16000-23:2009 Indoor air - Part 23: Performance test for evaluating the reduction of formaldehyde concentrations by sorptive building materials ~ ISO 16000-24:2009 Indoor air - Part 24: Performance test for evaluating the reduction of volatile organic compound (except formaldehyde} concentrations by sorptive building materials = ISO 16000-25:2014 Indoor air — Part 25: Determination of the emission of semi-volatile organic compounds by building products ~ Micro-chamber method = 1SO 16000-26:2012 Indoor air - Part 26: Sampling strategy for carbon dioxide (CO2) = 180 16000-27:2014 Indoor air ~ Part 27: Determination of settled fibrous dust on surfaces by SEM (scanning electron microscopy) (direct method) = SO 16000-28:2012 Indoor air - Part 28: Determination of odour emissions from building products using test chambers = 180 16000-29:2014 Indoor air ~ Part 29: Test methods for VOC detectors = 180 16000-30:2014 Indoor air — Part 30: Sensory testing of indoor alr ~ 180 16000-31:2014 Indoor air ~ Part 31: Measurement of flame retardants and plasticizers based on organophosphorus compounds — Phosphoric acid ester 180 16000-32:2014 Indoor air ~ Part 32: Investigation of buildings for the occurrence of pollutantsTCVN 10736-6:2016 Lai gidt thigu TCVN 10736-1 (ISO 16000-1) thidt lap c&c y8u cau chung lién quan dén phép do cc chat 6 nhiém khéng khi trong nha va cdc didu kién quan trong durgc quan sat truéc hoe trong qué trinh [dy mdu cla tleng chat 6 nhiém hoae nhom chat 6 nhiém. Khia canh cla viée xac dinh (lay mau va phan tich) va chién tuo ldy mau cla cdc chat 6 nhiém hode nhém chat 6 nhiém cu thé duoc quy dinh trong cae phan sau clia bd TCVN 10736 (ISO 16000), TCVN 10736-5 (ISO 16000-5) (gidi quy&t chién lvoe Idy m4u VOC) la mét két néi gita TCVN 10736-1 (ISO 16000-1) (tiéu chudn chung thiét 4p cdc nguyén tac) va tiéu chudn nay, dé cp dén lay mau va phép do phan tich. 1SO 16017 (xem Bidu 2 va Tai ligu tham khdo [8] va ISO 12219 PHI cong tap trung vao phép do hop chat hau ce bay hoi (VOC).TIEU CHUAN QUOC GIA TCVN 10736-6:2016 Khéng khi trong nha - Phan 6: Xac dinh hep chat hiru co bay hoi trong khéng khi trong nha va trong budng thi bang cach lay mau cht déng trén chat hdp phu Tenax TA®, giai hap nhiét va sac ky khi stv dung MS hoac MS-FID Indoor air — Part 6: Determination of volatile organic compounds in indoor and test chamber air by active sampling on Tenax TA® sorbent, thermal desorption and gas chromatography using MS or MS-FID 1 Pham vi ap dung Tigu chuan nay quy dinh phwong phép xac dinh hop chét hvu co bay hoi (VOC} trong khéng Khi trong nha va trong khong khi da ly mau dé xac dinh su phat thai cla VOC tir cdc sdn phdm hode vat lieu xay dyng va cée san phdm khée duge ding trong mai truéng trong nha sir dung budng thir va. ngan thi. Phuong phag stv dung chat hap phu Tenax®") sau d6 gidi hap nhiét (TD) va phan tich sdc ky khi (GC) ding mt hodc nhigu cét mao quan va detector ion héa ngon Ia (FID) valhoac bang detector khdi phd (MS). Phuong phap nay c6 th8 dp dung cho phép do VOC khéng phan eye va it phan cyre & ndng d6 tir dui mét micragam trén mét khdi dén vai miligam trén mét khéi. Sir dung nguyén ly duoc quy dinh trong phuong phap nay cing c6 thé phan tich duge mat s6 hop chat hou co rét dé bay hoi (VOC) va hep: chat hdru co ban bay hoi (SVOC) (xem Phy luc D).. 2. Tai ligu vign din Cac tai liéu vién dan sau rat can thiét cho viée ap dung tiéu chudn nay. Odi voi cac tai liéu vién dan ghi nam céng bé thi ap dung phién ban duge néu. 6i vi cdc tai liu vién dan khéng ghi nam cong bé thi 4p dung phién ban méi nhat, bao gém ca cdc siva adi, bd sung (néu c6). TCVN 10736-1: 2015 (ISO 16000-1:2004) Khéng khi trong nha — Phan 1: Céc khia canh chung clia ké hoach ty mau; "Tenax® [a tén thuong mai cla mot san phdm due cung cép bdi Buchem. Théng tin nay dua ra chi tao thudn loi ‘cho ngudi stv dung tiéu chudn va khdng phai ta xc nhdn cia tidu chuan vé san phdm nay. Co thé dung céc san pham tong duong néu ching cho két qua tvong ty. 7TCVN 10736-6:2016 TCVN 16017-1:2000, indoor, ambient and workplace air - Sampling and analysis of volatile organic compounds by sorbent tube/thermal desorptio/capillary ges chromatography - Part 1: Pumped sampling (Khong khi trong nha, khOng khi xung quanh, khdng Khi ving lam viée - Lay mau va phan tich hop cht hau co bay hoi bang éng hap phw/giat hp nhiét/sdc ky khi mao quan ~ Phan 1: Lay mau bang bom). 3. Thuat noi va dinh nghia Trong tigu chudn nay, 4p dung cac thuat ngir va dinh nghia sau. 34 Hop chat hivu co’ ban bay hoi (semi-volatile organic compound) svoc Hap chat hiru co 06 dim séi trong khoang tir (240 °C dén 260 °C) dén (380 °C dén 400 °C). CHU THICH 1 Phan toai nay do Té chic Y t6 thé gid ("4 dura ra. CHU THICH 2 Biém séi ciia mot sé hep chAt la kho hodc khéng thé xae dinh durge bei vI ching phan hiyy true khi ching s6i tai ap sudt khi quyén, Ap sudt hoi la tigu chi kha dé phan loai tinh bay hoi clia hop chat 06 thé Suc dng 68 phan loai cde chat hau co! 32 Hop chat hivu co bay hoi (volatile organic compound) voc Hop chat hiru co’ cé diém s6i trong khoding tiv (50 °C dén 100 °C) dén (240 °C 6én 260°C). CHU THICH 1 Phan logi nay do TG chive Y té thé gidi ™" dua ra. CHU THICH 2. Bim s6i cia mét sé hop chdt fa kno hodc khéng thé xac dinh bdi vi ching phan hiy trudc Kh ‘ching s6i tai ap suat khi quyan, Ap sudt hoi la tiéu chi khac dé phan loai tinh bay hoi ciia hyp chat 6 tha dugc ding dé phan logi cdc chat nou co |, 33 Hp chat hitu co rat dé bay hoi (very volatile organic compound) wos Hap chat hGu co 66 diém séi trong khoang tir <0 °C dén (50 °C den 100 °C). CHU THICH 1. Phan loai nay do Té chic Y t6 thé gidi 4 dua ra. CHU THICH 2 Biém sdi cla mét s6 hgp chat Ia khd hoae khdng thé xéc dinh béi vi ching phan hiy trée khi ching s6i tai 4p sul khi quyén, Ap sudt hoi la tigu chi khdc 68 phan iogi tinh bay hoi cla hop chat c6 thé duge dang a phan toai cae chét hou co 9),TCVN 10736-6:2016 3.4 Téng cac hop chat hitu co bay hoi (total volatile organic compounds) Tvoc Tang cdc hop chat hiu co bay hoi, due ldy mau trén Tenax TA®, riva gidi trong khodng va ké cd n-hexan va n-hexadecan trén cot mao quan khéng phan cy, duge phat hién voi delector ion héa nggn Ita (TVOC-FID) ho&e detector khdi phd (TVOC-MS), va duge dinh lvgng bang chuyén di téng dién tich clia sc dé trong ctva sé phan tich dé thanh khéi lung danh dinh st dung hé sé dap tng sdc ky déi voi toluen (tung duong toluen). CHO THICH Trong khi tiéu chuan nay quy dinh vige xéc dinh tig VOC, trong thyc té thudng dura ra mot gid tr ndng a6 don Ié dé dac tinh hoa téng lugng VOC hién 06 trong khdng khi. Gia trj nay durge goi la gid tri TYOC (xem 11.3 va Bidu 13), Can phai nhdén manh rang gia tr] TVOC thu duoc phu thuge vao phuong phap lay mau va phuong phap phan tich duoc ding, va do vay can phai mé té day di céc phuong phap nay khi dién gidi. 4 Nguyén ly Thé tich m&u Khi 6a do dus lay tir khéng khi trong phéng, trong budng thir phat thai (xem TCVN 10736-9 (ISO 1600-9) hode ngéin thir phat thai (xem TCVN 10736-10 (ISO 16000-10) bang cach hut qua mot (hoae nhidu) éng h4p phy o6 chira chdt hdp phy Tenax TA®. Ong hdp phu git lai hyp chAt hdu co bay hoi (VOC), va sau d6 cde hyp chét dug: phan tich trong phang thir nghigm. Cac VOC da ldy mau due giai hdp bang nhiét va duc chuyan bang dong khi mang qua bay lanh hoae bay hp phy vao may sdc ky KhI véi mot hodc nhidu cét mao quan va detector ion hoa ngon Itva va/hoae detector khél phd. 5 Thuéc tho va vat liéu 5.1 Hop cht hiu co bay hoi dé hiéu chudn, cht lugng sac ky. §.2 Dung méi pha loang, dé chuan bi dung dich tron ln higu chudn 48 thém chudn, chat lugng sdc ky, khdng co cae hgp chat cling riva gidi voi cdc h¢p chét quan tam (5.1). CHU THICK Trong hau hét cac trvéng hop, higu qua si? dung dung mdi pha long bay hei nhidu hon dang kd ‘80 véi VOC due ph&n tich. Metanol néi chung dap Ung tiéu chi nay. Dir liéu vé strc khde va an toan d6i vei hop chat hiru co duoc dua ra, vi du nhu trong Phiéu an toan héa chat quée té (ICSC) 4, 5.3. Tenax TA®, c& hat 0,18 mm dén 0,60 mm (30 mesh dén 80 mesh). Tenax TA® Ia polyme xép trén nén 2,6-diphenylenoxit, Tenax TA® thuong pham co chia lvong tap chat phai duoc loai bé tude khi str dung chiding 48 dy mau VOC. Tién hanh {am sach bang sdy dn nhiét Tenax TA® trong dong khi mang tinh khiét. Lwa chon diéu kién lam sach sao cho khéng xdy ra su phan hty polyme, vi du tai nhiét 46 300 °C trong 10 h sir dyng déng khi mang o6 lu long 60 mL/min dén 100 mUmin cho éng lay mau nhdi sn. Nhdi Tenax TA® 64 duos lam sach trudec khi dua vao éngTCVN 10736-6:2016 14y m4u duge dan kin va bdo quan trong hOp chiva kin, khdng 6 phat thai, Kiém tra hiéu qua ella quy trinh lam sach bang cach tién hanh phan tich chat hdp phu da lam sach. CHU THICH Ong chiva chat hap phy 44 nhdi rude, d& duc 1am sach va éng han kin hai dau 06 ban sn. 5.4 Khéng Khi tiéu chudn, ndng d6 da biét cla hep chat quan tam, dug chudn bj bang mot quy trinh duge cong nhén. Cée phuong phap duge quy dinh tai ISO 6141 "I va cdc tiéu chudn thich hop lia bd ISO 6145 P1a phi hop. Chuan bj khéng khi tigu chudn tuong duong khoang 100 pg/m®, Néu quy trinh khéng ap dung trong didu kin cho phép thiét lap truy xudt day di: ndng dé tao ra dén chudn dau cla khdi lueng va/hodc thé tich, hoae néu tinh tro héa hoc eda hé théng chung khéng dug dam bao thi phai x4c nhan néng dé khi si’ dung mét quy trinh 6c tép. 5.8 Ong hap phy tigu chudn, d4 nap bang cach thém chun tw khdng khi tigu chudn (6.4), duoc chuan bi bang cach cho mét thé tich khéng kh/ tiéu chudn da biét chinh xae di qua éng hap phy, vi dy bang cdich bom, Thé tich cla Khong khi duoc lay phai khéng duoc vwot qué thé tich da qua cila té hep chat phan tich- chat hap phy. Sau khi nap, t4ch ra va lam kin dng, Chuan bi chuan mdi véi tieng mé mau. DSi vei khéng khi trong nha va khéng khi trong budng thir, nap vao dng h4p phy voi 100 mL, 200 mL, 400 mL, 1L, 21, 4 Lhoge 10 L khong khi tiéu chudn 100 g/m? da chon, 5.6 H6n hop dung dich hiéu chuan dé thém chuan long 5.6.1 Yéu cau chung. 86 én dinh va théi gian bao quan an toan cla hén hyp dung dich higu chudn phai due xc dinh. Phai chudn bj dung dich tigu chudn méi phi hop hoac néu cé bang chieng vé suv detori héa, vi dy phan wng gitra céc cén va keton. Néng 46 dung dich higu chudn phil hyp thay 4di phy thudc véo mirc chét phan tich myc ti8u dy kién trong ting m8 mu. Vi dy chudn bi dung dich cho mgt khoang 4p dung duc néu tai 5.6.2 dén 5.6.6. $6.2. Dung dich chiva khoang 10 mg/mL ting hop phan. L4y 50 mL ctia dung méi pha loang cho vao binh dinh mirc 100 mL. Can chinh x4¢ 1 g mét chat hodc cde ch4t quan tm cho vao binh dinh mirc 100 mL, bat dau véi chdt bay hoi It nhdt. Lam dy dén 100 mL bang dung méi pha loang, day binh va lac déu. 5.6.3 Dung dich chtra khoang 1000 ug/ml ting hyp phan long. Lay 50 mL dung mdi pha loang cho vao binh dinh mive 100 mL. Thém 10 mL dung dich 5.6.2. Lam day dén 100 mL bang dung mdi pha loang, day binh va lac ddu. 10TCVN 10736-6:2016 5.8.4 Dung dich chéra khoang 100 pg/mL ting hop phan long. Lay 50 mL dung méi pha long cho vao binh dinh mizc 100 mL. Thém 10 mL dung dich §.6.3. Lam day dén 100 mL bang dung méi pha lodng, day binh va lac dau. 5.6.5 Dung dich chéva khoang 10 g/mL ting hyp phan léng. Lay 50 mL dung mdi pha loang cho vao binh dinh mic 100 mL. Thém 10 mL dung dich 5.6.4. Lam day dén 100 mL bang dung méi pha loang, day binh va lac déu, 5.6.6 Dung dich chira khong 1 pg/mL ting hyp phan léng. Ly 50 mL dung méi pha long cho vao binh dinh méc 100 mL. Thém 10 mL dung dich 5.6.5. Lam day dén 100 mL bang dung méi pha foing, day binh va lc déu. 8.7 Ong hap phy tiéu chudn, nap bang cach thém chudn, duge chuan bj bang cach bom mat lweng nhé dung dich tiéu chudn tén trén éng hap phy sach, ‘Dau cudi cia éng h4p phy Idy mau duge lép vao véi bé born khdng gia nhiét cia sdc ky khi (6.10) cho dong khi tro lam sach di qua voi 100 mL/min, va bom tir 1 pL dén 5 yl phan nhé dung dich tigu chudn phii hop di qua vach ngn. Sau 5 min, thdo éng ra va day kin. Chuan bi éng chudn mdi v6i tizng mé mau. ua dung dich chudn tén trén dng hdp phy qua b6 bom GC dugrc xem la céch t6i wu dé dua dung dich chuan, do cae thanh phan cham ti lop day hdp phy trong pha khi, Cach khac, dung dich chuan co thé duge dua tryc tiép (én trén lop hap phu bang xyranh (6.3). Can phai chuan bj hén hyp higu chudn trong diéu kién nhiét dé xung quanh duc kiém soat. True khi sir dung, lam néng dung dich phi hep. CHU THICH 1 Khi chudn bj cdc éng chudn 06 chtva chét phan tich SVOC, viée chuyén higu qua duoc cai thién néu c4u hinh cla bd bom cho phép dau chop olla xy ranh tiép xc t6t voi co ché git Iai chat hdp phy (vi dy iuai hoae thay tinh frit) trong dng. CHU THICH 2 Ong tiéu chudn c6 chira WWOC thugng durge chudn bi tir khdng kh ti8u chudn (xem 5.4 va 5.5) hoac ti khi chudn dam dgc 66 ban sn, Béi véi khi chuan dam dao, thich hyp dé dua vao dau cudi lay mau cita cac ng hap phy trong mBt dong khi mang qua bé bom GC chwa duoc gia nhiét. CHU THICK 3. Néu éng tisu chudn duge chudn bj bang céch dua phan dung dich tt nhiéu dung dich hoac khi chudn, didu phi hop (rude tidn 1a diva chudn chia cac thanh phan c6 diém soi cao hon va dua cae thanh phan c6 diém séi thip nhdt vao cudi cling. Vide nay sé gidm thidu riii ro cht phan tich bi pha ve trong qué trinh nap ctia dng chuan. 5,8 Ong chuan dugc nap truéc, ban san, da dugc ching nhan, co san va co thé duoc ding dé thiét lp kiém soat chat ong phan tich va dé higu chuan thudng nhat. 5.9 Khi mang tro, vi du He, Ar, Nz. 86 tinh khiét cla khi mang phai cho phép phat hién duoc 0,5 ng toluen trong mdt tan bom. ohTCVN 10736-6:2016 THAN TRONG — Chat lwgng khi mang [a rét quan trong, vi ch4t nhiém ban cé thé bi gif lai trong de khi due fam giau trong bay lanh cling véi cde chat durge phan tich. 6 Thiét bj, dung cu Thiét bj dyng cy phéng tht nghiém thdng thong va cdc thiét bj, dyng cy sau 6.1. Ong hap phy, lam bang thép khéng gi hode thiy tinh, c6 chira it nhdt 200 mg chat hdp phy Tenax TA® (5.3), co ndp van bang kim loai va dai sat polytetrafluceten (PTFE), ‘Ong 66 dudng kinh ngoai 6,4 mm (0,25 in.), dudng kinh trong mm, va chiéu dai 89 mm (3,5 in.) dép ng cc yéu cau va duge ding trong nhidu bd gidi hap nhiét thueng mai, Sir dung béng thy tinh d& khiv hoat tinh hoc cdc co ché phi hyp khac, vi dy frit thép khOng gi a8 gitr lai ch4t hdp phy trong éng. CHU THICH 1. Gi tr inch dug dua ra chi dung 48 tham khdo. ‘Ong hdp phy da lam sach truéc chira Tenax TA® c6 ban s8n. Céch khac, éng hdp phy 06 thé duge nhdi day trong phéng thir nghiém nhu sau. Can mét lvgng thich hyp chat hap phy, sir dung khéng it hon 200 mg chat hdp phy cho tung éng 8 uy tri kha nang hép thy. 88 nhdi éng, cho mét nét bang bong thiy tinh 68 Khé hoat tinh hodc mot lu6i bang thép khdng gi vao mét dau cla dng. Cho chat hép phy vao éng, hit néu can. Bat mat nut hoae mét lu6i bé sung trén kip hp phu & dau cbn lai dé gi cdc chat trong ng. CHU THICH 2. Xée dinh thé tich di qua duce quy dinh & ISO 16017-1:2000, Phu lye B. Th8 tich di qua # 18 véi kich thude cla éng lay mau va chat long cia ch4t hdp phy. Nhu mt bign phap tuong d4i, gdp dai chiéu dai lop. trong khi dudng kinh dng dug git? khéng ddi 38 gdp é6i thé tich ldy mau an toan (SSV). 6.2 B dng hap phy. Bé l4y mau, hai ng hdp phu néi véi nhau khi st? dung nap van kim loai c6 khop: néi bang st PTFE. 6.3. Xy ranh chinh xac, c6 thé doc dén 0,1 pL. 6.4 Bom lay mau, dap Ung cdc yéu cau ctia EN 1232I"] hod ASTM 03686 "I, 6.5 Ong, bing polyetylen (PE) hoae PTFE, dudng kinh phi: hop duge ding dé dam bao khong rd 1 va khit véi cd bom va 6ng lay mau. Ong t4y mu khéng dug ding voi dng nhya phia trrdc ca lop hdp phy. Can tre tir dng 06 thé dua chat nhi&m ban. 6,6 Thiét bj higu chudn dong. Thiét bi bong bong xa phdng hode thiét bi phu hop khdc 48 higu chudn déng kh, 12TCVN 10736-6:2016 6.7 BO sic ky khi (GC), lap viva voi detector ion hoa nggn liva va/hodc detector khdi phd o6 thé phat hign mét lugng bom it nhat 1 ng toluen voi ti sé tin higu trén nhiéu it nhdt bang 5 trén 1. 6.8 Cét mao quan. Mét cot mao quan GC pha hop durge Ira chon dé tach chat phan tich trong mau, Cot fién két 100 % dimetylpolysiloxan 30 m dén 60 m, dudng kinh trong 0,25 mm één 0,32 mm va 46 day pha 0,25 pm dén 0,5 um la mat vi dy vé cét da duge chéng minh phi hgp dé phan tich VOC trong khéng kh trong nha, khéng khi trong budng tht? phat thai (theo ISO 16000-8), va khong khi trong ngan thir phat thai (theo ISO 1600-10). CHU THICH Cot dimetyipolysiioxan, vi du oot HP-1, khong tach 3-caren tiy 2-etyl1-hexanol véi chuong trinh 18 no 46, hole khéng tach m- va pexylen. 6.9 Thiét bi giai hdp nhiét, dé giai h4p nhiét hai giai doan cla éng hdp phy va chuyén hoi 44 giai hap theo dng khi mang vao GC. 6.10 Phuong tién bom dé chuan bi cac dung dich chudn bang cch thém chuan léng (ty chon). BO bom sc ky khi theo quy wdc hodc thiét bj tong dvong cé thd duge dung 48 chudin bi c&c chun higu chuan. Thiét bi nay c6 thé dug ding tai ché, hodc cé thé duge gan tach biét. B6 bom can phai khong lam gia nhiét 48 gidm ri ro cia sy truyén nhiét sang éng va nhing rui ro cla chat phan tich di qua. Phia sau cia bd bom can phai [am phu hop néu can dé khit voi dng lay mau. Didu nay cé thé thye hén thuan tién bang cach nén khép néi voi mét dai ch O. CHU THICH Khi chuan bj dng chudn chira chat phan tich SVOC, viée chuyén hiéu qua dug cai thién néu cdu hinh ca b6 bom cho phép dau ch6p ctia xy ranh to tiép xe tét voi co ché git lai chat hdp phy (vi du luéi hoze thiy tinh fri) trong éng. 6.11 Higu chuan bom, Hiéu chudn bom voi dng hdp phu lap trong hé thong, st dung ding hé da hiéu chudn bén ngoai phi hep. 7 On dinh va bao quan dng hdp phu 7.4 On din Truéc méi lan lay mau, dn dinh cho éng hp phy da {am sach trude & 300 °C trong 10 min trong khi mang tro véi Ivy lugng déng 60 mL/min dén 100 mLfmin, dé loai bd vét cht bay hoi hiru co’ c6 thé bj bay trén éng. Phan tich mét s6 dai dign cac 6ng dé duoc chudn bj cho gid tri trang, stv dung thong sé phan tich thong nhat 48 42m bao rang gid tri mu trang gidi hap nhiét la dU nhd. Mire gid tri tang éng hdp phu cé thé duoc ch4p nhan néu pic tao ra khdng lon hon 10 % dign tich pic dién hinh cia chat phan tich quan tém, Néu gid tri trang khéng dug chap nhén, phai chuan bi lai éng bang céch lap lai 7 HP-1 1a tén thuoing mai cia mot san ph4m duc cung cdp bdi Agilent, Inc. Thong tin nay dua ra chi tao thuan Igi cho ngudi sir dung tiéu chudn va khéng phai la x4c nhan ota tiéu chuan vé san pham nay, 13TCVN 10736-6:2016 quy trinh én dink. Néu sau khi én dinh Iai, gia tri trdng v4n khong duge chap nhan, cc éng phai duoc nap day lai (xem quy trinh tai 6.1). 7.2, Bao quan cac dng hdp phy da dn dinh truéc khi lay mau Day kin cdc éng hap phy da dn dinh bang nap van kim loai voi dai sat PTFE va bao quan trong mot thing chiva khdng 6 sy phat khi thai tai nhiét do phdng. Sir dung dng [dy mau da dn dinh trong véng bén tuan. On dinh lai cdc éng duc bao quan nhiéu hon bén tun truéc khi ly mau. 8 Lay mau 8.1 Lay mu khéng khi trong nha Lap hé théng l4y mu. Néu cé nhidu éng dugc ding 48 dam bao rang thé tich di qua déi véi mot dng va chat phan tich quan tm khéng | vugt qua, chudn bj mét b6 dng bang cach ndi cdc ng thanh day voi bd éng hap phu (6.2). Néi bom véi éng hp phy hoac lién két éng bang éng PE hodc PTFE. Khoi dng bom va ghi lvu lugng lay mau hode doc trén may ghi, ghi lai thei gian khéi dng, nhiét 46 va néu cn, ca ap sudt khong Khi cho tinh toan. Luu lweng dong thich hgp a trong khoaing tir 50 mL/min dén. 200 mL/min. Khi két thc giai doan léy mau, ghi lai lu lvong dong hoac doc trén may ghi, t&t bom va ghi lai thoi gian, nhiét d6, va néu cn, cd dp sudt khéng khi. Thao éng idy mu ra khdi hé théng Ky mau va day kin cd hai dau éng sir dung nap van 06 dai PTFE. Néu Iuu tugng ly mau duege x4¢ dinh bang cach sir dung mat thiét bi do [uu lugng duge tich hop, vi dy ding hd do dong khdi lveng, néi éng !4y mau vai hé théng l4y mau, khdi dong bom, ghi lai thei gian va Ivu luong hoge 6 doc dang ky. Ghi lai nhiét dé va néu can, ca dp sudt khéng khi. Luu tong dong thich hop Ia trong khodng tir 50 mL/min dén 200 mLimin. Kat thie giai doan ly mau, ghi tai luu lyong dong hoac sé doc, tat bom va ghi Iai thoi gian bom da duge tat. Thao dng ldy mAu khdi hé théng lay mau va day kin cd hai dau éng st dyng np van co dai PTFE. Lay mu khng Khi trong nha phai dug thy hign cé tinh dén cac khia canh chung ctia chién luge ly mu nhu dug quy dinh tal TCVN 10736-1 (ISO 16000-1). Cé thé lay mau véi wu lwgng nhd hon 50 mUmin néu ngudi van hanh thdy cdn thiét, vi du dé dam bao thai gian ldy mau dai hon, 8.2, Lay mau khéng khi budng thr Lap dat né théng 1dy mau. Néu lwu lugng ldy mau duge xac dinh bang may higu chudn, khéi dong bom, ghi lai lvu lvgng Idy mau. Luu lwong dy mau phi hop trong khodng tir $0 mL/min én 200 mUimin. Néu ly mau ti mét budng phat thai, lwu Ivong lay mau khdng duge vuet qua 80 % Ivu lugng khong Khi cia budng dé. Néi éng l4y mau véi I6i ra budng thy hodc céng ly mau cla budng thir phat thai, ghi lai théi gian dng duge néi. Ghi lai nhigt 46 va néu can, cd 4p sudt khong kh, Khi két thie. giai doan lay mau, thao éng ldy mau ra khdi dng !4y mau budng thik, ghi lai théi gian th4o éng, {ap lai 14TCVN 10736-6:2016 phép xac dinh luu lvong ldy mau va t&t bom. Tho éng ly mau ra khdi hé théng l4y mau va day kin cd hai dau dng st dyng nap van cé dai PTFE. Néu Ivu lugng l4y mau dugc xac dinh bang céch st dung mét thiét bj do tuu lugng tich hyo, vi dy dang hd do dong khdi lueng, ndi dng ly mAu voi hé thong ty mau, khoi d6ng bom, ghi lai thdi gian va Izu lugng hode doc trén may ghi, Ghi lai nhigt 49 va néu can 4p suat khong khi, Luu lurgng ding thich hgp la trong khoang tir 50 mL/min dén 200 mL/min. Khi két thc giai doan lay mau, ghi tai lu lveng dong hoac sé doc, t&t bom va ghi lai thdi gian bom da duge tat. Thao éng dy mau ra khdi hé théng lay mau va day kin cd hai dau éng sir dung nap van cé éai PTFE. 8.3. Thé tich ldy mau ‘SSV, nghia la lgng khi c6 thé duc lay mau khéng cd VOC, duge néu tai Phu luc B. Noi chung, thé tich l4y mu pha hop khi fay m&u VOC tl khéng khi trong nha khong phai céng nghiép la 1 L dén SL d6i voi dng ldy mau chtra 200 mg Tenax TA®. Trong phép do phat thai vat liéu, loai vat ligu va 66 lao hoa, hé sé tai va téc dé trac di khdng khi trong budng xéc dinh thé tich ldy mu phis hop. Thé tich dy méu Ién nhat khuyén ¢40, théng thudng <5 L. Tha tich ly mau phi dugc diéu chinh dén néng d6 dy kién. Khi ndng d6 ldy mau chua biét, nén lay it nhAt ba mu song song véi thé tich fy m4u khdc nhau. Néu két qua phan tich khéng phy thugc vao thé tich lay mau, da khéng xay ra su lot qua cila chat phan tich. 8.4 Bao quan mau da nap Ong lay mau da nap phai duoc day kin va bao quan trong hép chira khong c6 Khi phat thai & nhiét 46 méi trudng xung quanh. Tac dong cla vigc bao quan l8n VOC da nap tir khéng khi trong nha ho&c khéng khi trong budng thir la chwa biét, mac du mét sé dé ligu (xem Phy luc C) cho rang chting c6 thé bn trong vai thang & nhiét d6 phdng. Dé tranh nhieng thay ddi cd thé xdy ra, mau phai dug phan tich ‘cng som cng tét va nén trong pham vi bén tuan sau khi y mau, 8.5 Mau trang hién trvdng Mau trdng hién trudng phai la éng Idy m4u Tenax TA® tuong ty voi nhteng éng duge dung dé ly mau VOC. C4c éng nay duce xt ly ngoai hién trudng giéng nhu déi véi cdc éng mau, ngoai triv déi voi giai oan thy ota lay mu, Mau tréng hién truéng can phai doe danh dau, bao quan va phan lich cing vOi mu thy. Trong chvong trinh phan tich, Khoang 10 % mau phan tich am mau Néu chi thuc hién mot s6 phép do, c4n phai chuan bi va phan tich it nhAt mot mau trang hién trveng. g hign twang 9 Phan tich 9.1 Yéu cau chung D4i voi phan tich, VOC bj gidi h4p nhiét tur cdc éng lay mau. Tach ting VOC st dung cot mao quan trong s&c ky khi va phat hién bang detector ion héa ngon Ita (FID) va detector khéi phd (MS) hoac chiTCVN 10736-6:2016 MS. MS 06 thé durgc ding cho cd nhan dang va dinh Ivong hop chat, trong khi chi tin hiéu FID éuge ding dé dinh lvong hop chat, Khi si dyng detector ion ha ngon lira cing v6i detector khdi phd dé phan tich, cdc detector o6 thé lp vira voi ce sac ky khi giéng nhau hodc véi cdc sc ky khi khac nhau. Trong truéng hop sau, phai si’ yng bé bom mau va cdc théng sé tach nhuy nhau trong ¢4 hai thiét bi dé tao ra sdc dd cé thé so sénh duge, Knhi thye hién dinh lugng sir dung FID, hén hop chudn higu chudn cia c4c ndng 46 khac nhau hode it nhat mét mc higu chudn phai duge phan tich véi tieng bé mau nh la mét kiém tra tinh nang cla hé théng. Khi ste dung MS dé dinh lvong, hén hop chudn hiéu chudn it nht ba, nam hode bay, hodc nhiéu hon ndng 46 khac nhau phai dug phan tich véi ting bd mau 48 hiéu chan. C6 thé stv dung chuan ndi, vi du hop chat danh dau déng vi dé kiém soat tinh nang cia dy mau va phan tich, 9.2. Giai hdp nhiét Lya chon thoi gian giai hap va tuu lugng khi giai hdp sao cho hiéu suat gidi hdp doi voi octadecan la lon hon 95 %. Xac dinh higu suat giai hap Guge quy dinh tai ISO 16017-1. Didu kién giai hap dién hinh cho phan tich VOC str dung bay lanh thir c4p va éng lay mau chia 200 mg dén 250 mg Tenax TA® duce néu dudi day. Nhiét do gigi hép 260 °C dén 280 °C. Co thé yéu cau nhiét dé gidi hdp khac néu cdc lop h4p phu khdc dua diing trong 6ng tay mau (vi dy 6i voi phan tich VVOC theo ISO 16017-1 hoe Phu luc D, hode thu hai dinh lung SVOC). Néu sir dung nhiét d6 gidi hap khdc, phi gidi thich trong béo cdo thir nghiém. Thdi gian giai hap 5 min dén 15 min Luu lugng khi gidi hap 30 mUmin dén 50 mL/min Nhiét 46 cao ciia bay tanh 260°C dén 300 °C Nhiét 46 thdp cia bay tanh -30 °C dén +20 °C Chat hdp phy bay tanh Tenax TA? Nhiét 46 dueng chuyén, 150°C dén 225 °C Tile ngdt/chia dong TI ngat ti éng mau dén bay thir cdp va ti bay thir cdp 6én Ot phn tich (néu 4p dyng) cdn phai duge (ya chon phy thude vao néng 46 khéng khi dy kién, (xem hung dan cla nha san xuét thiét bj gidi hdp nhiét), 16TCVN 10736-6:2016 CHU THICH Nhiéu chét bay hoi VVOC cé thé di qua bay lanh trong diéu kién nay va khong xa¢ dinh dinh ivgng bang phan tich (xem Phy lyc D va thang tin cdch thie phan tich dinh iugng VVOC va SVOC). Bidu kign phan tich, va chdt phan tich thay thé d6i véi nhigu hgp chdt hon duge néu tei 0.6.1 9.3. Chong trinh nhiét 46 Chuong trinh nhiét d6 cite cét phan tich la cdn thiét khi phan tich hn hep cae chat chi ra khac nhau trong diém s6i va d} phan cyc dé dat éuge céc gidi phdp tét trong thei gian nhd nat, 9.4 Phan tich mau Phan tich mau VOC tét nhdt nén trong vong bén tudn ké tl khi lay mu, Phan tich mau tréng hién trudng va céc chudn phi hep gidng nh déi voi mau. Nhan dang VOC bang MS va dinh lugng chung tir sdc dd FID hoe MS. 10 Nhan dang VOC don lé é nhan dang VOC don Ié, khéng phai myc tiéu, phan tich mau cling véi van hanh MS trong ché dé quét. Nnan dang VOC don |é dug phat hign trong mau sir dung may khéi phd se dé ion ting va thei gian Iuu cia hyp cht. So sanh téng sc 48 ion véi khéi phd cia hop chat tinh khidt hodc tai ligu cb sn (thu vién) ctia khdi phd. Cting 6 thé sir dung sdc dd lam chudn duce Ivu tai phong thir nghiém. Tuong quan cia théi gian Iwu cia VOC don lé vai thi gian lwu cia hop chat duge ding dé higu chuan trén cét don phai twong duong nhau, Nhan dang cang nhiéu hep chat cang tét, dc biét chung dai dién 10 pic lon nhat va ching dai dién & néng d6 lon hon 2 ugfm®, Danh sach cAc VOC theo kinh nghiém tai thoi diém céng bé, thudng gap trong khéng khi trong nha va due phat thai tt vat ligu duge néu trong Phy luc A. Murc 46 yéu cau ca nh&n dang dat duoc néu dién tich pic sc 48 cia VOC duge nhan dang Khi dug cong twong ng voi it nhat hai phan ba tang dién tich cla tét cd cdc pic trong s4c dé riva gidi trong khoang va ké ca n-hexan dén n-hexadecan. Ciing co thé sir dyng ché do giam sat ion lva chon (SIM) cla van hanh MS. Viéc Iya chon ty thudc nguwoi van hanh, phai co kién thir vé sy khac nhau gitra ché d6 SIM va ché dé quét. 41 Néng dé chat phan tich trong mau khi 444 Khai quat Hop chét 44 nhan dang dug dinh Iveng bang cach st? dung hé sé dap tg ting chat khi hop chat chudn o6 sn. Trong trudng hop khac, viée dinh lugng duc bao céo theo toluen. Hop chat khong dug nhén dang due dinh luong sir dung hé s6 dap tng toluen 41.2 Hop chat hiru co bay hoi Hé sé dap tng riéng theo hep cht va d6 tuyén tinh cua FID va MS di voi hop chat quan tam duge xée dinh bang hé théng hiéu chudn va phan tich voi dung dich chuan (5.5, 5.6.3, 5.6.4, 5.6.5, 5.6.6 7TCVN 10736- 016. hodc §.9). Chuan bi dudng higu chudn si dung ft nhat ba ndng G6 khéc nhau trén dai tuyén tinh (tét hon si dung ndm hoac sau néng dé kha nhau). Nong dé thdp nhat duoc ding dé higu chudn phai bang hoac thdp hon néng 46 thdp nhdt cla mau, Dién tich pic cla sc dd VOC don [8 th 18 voi khdilvgng cla hyp chat dug bom vao. Béi voi ting hop chat, mi twong quan gitea khdi lugng clia chat phan tich bom vao va dién tich pic tong Ung duge xac dinh. D6 déc cia dong higu chudn trén dai tuyén tinh a hé sé dap ng ola VOC duge nghién cou: Asi= bss tes, (1) Trong a6 As. 1a dién tich pic chat phan tich trong sac dé ciia dung dich chudn, tinh bang don vj dién tich; bs. 14 46 déc cla dudng hiéu chudn; my la khéi kegng cila chat phan tich trong dung dich chuan, tinh bang nanogam; cs la giao cat cla géc toa 6 vai dvong hiéu chuan — néu dudng higu chuan di qua géc toa do, cx Khéi tvong chat phan tich, ma, tinh bang nanogam, cé trong mau duc tinh tl din tich pic detector st dung hé 86 dap tng cila chat phan tich: ) Trong 46 Ax 1a dién tich pic, tinh bang don vi dign tich cla chat phan tich trong sac dé cla mau; bs, [a d6 déc cia dudng hiéu chudn; cx la giao cat toa 46 voi duéng higu chudn - néu dudng higu chudn di qua géc toa 66, ca = 0. Néng 6 khdi tvong, pa, tinh bang microgam trén mét khdi, cia VOC da nh4n dang trong mau Khi due tinh theo Céng thee (3) mM Pa (3) Trong do ma la khéi lugng cla chat phan tich c6 trong éng ty mau, tinh bang nanogam; ma 1a khdi lvgng clia chat phan tich trong éng trang, tinh bing nanogam:; VW thé tich fay mu, tinh bang lit, Néu can, néng 46 due diéu chinh vé 23 °C va 101,3 kPa: 18TCVN 10736-6:2016 101,3 (¢+273) =p, sere) Pp 296 Paso 4) Trong 46 p tap sudt thyc té oda khi mau, tinh bang kilopascal; tla nhigt 49 thye cua khi mau, tinh bang d9 Celsius. ‘Binh Iugng céc hep chat khéng duge nh&n dang trong mau st dung hé sé dap tng hiéu chudn déi véi toluen, 11.3. Tong cac hop chat hu co bay hoi Néng 46 TVOC dug xéc dinh nhur sau: Xem xt toan bé dién tich cla sc dé tir n-hexan dén n-hexadecan. Sir dung hé sé ddp tng toluen, chuyén dién tich thanh don vi khdi Iugng toluen. Sir dyng Cong thirc (3), tinh ndng dé khéi lueng TVOC trong khi ly mdu. Xac dinh gid tri TVOC cua éng trang cé tinh dén nén, slr dung cing quy trinh va ldy két qua TVOC méu trie di gid tri nay d8 cho gid tri TVOC da higu chinh. Théng s6 cia mot ,phé tiéu chudn” hodc théng sé MS tuong dyong, phai duge thiét lap khi st» dung MS cho muc dich nay. Néu khéng, siv dung FID la thich hep hon. CHU THICH 1 Nhiing khuyén cdo nay dug dua ra dé nang cao tinh tong thich cla két qué TVOC. CHU THICH 2. TVOC xac dinh Guy theo tvong dyong toluen 1a ban dinh {uong, vi ting hop chat trong hén hyp ¢6 thé cb hé 36 dap Ung thay déi nhiéu so voi hé s6 dap Ung toluen. 11.4 Hop chat VOC va SVOC quan sat dye ngoai khoang TVOC 8 cb durge théng tin vé hyp chat hiu co bd sung 6 trong khdng khi trong nha hod phat thai tir sn phdm di vao khéng khi budng thir, khéng chi phi: hop dé xc dinh VOC ma con cho mot sé théng tin vé WOC va SVOC, nghTa la hyp chat hivu co riva gidi truce n-hexan va sau n-hexadecan. Vé van 48 nay, huéng dan dugc néu tai Phu luc D. 12 Dac tinh tinh nang ‘Trude khi sir dung phuong phap nay, dc tinh tinh nang oan phai duge xac dinh theo TCVN 9595-3 (ISOMEC Guide 98-3)". Téi thiéu, phép xac dinh nay cn bao gdm wee Iveng d6 khong dam bao cc thanh han tiv cdc ngudn sau: a) Lay mau 4) Dang khi; 2) Thai gian; 3) Nhiét 46; 19TCVN 10736-6:2016 4) Ap suat; 5) Higu sudt ldy mau; b) Tinh tich hop lay mau: 1) Phuong phap va tinh én dinh; 2) 86 dn dinh mau trang; c) Higu suét giai hdp; d) Higu chun: 1) Dung dich chudn; 2) Tinh khéng khép eda ham chudn; e) Phan tich: 1) BG lap | 2) Mic d6 trang; f} Anh huéng cla mdi trudng: 1) Nhiét d6 lay mau 2) BO Am lay mau; 3) Cant, 9) D6 lap lai hign tredng; h)_ Kg thuat budng do: 1) Trao adi khong khi, 2) Chuan bj mu thir. 86 chinh xéc va d@ tp lai cla phwong phap do ld céc hé s6 quan trong, phai duge xéc dinh dé danh gia két qua va tinh phi hgp cita phuong phép voi myc dich 4a dinh. 84 chinh xc cla phwong phap do VOC cé thé dug xdc dinh néu cé thé tao ra khong khi c6 ndng 46 dé biét (microgam tren mét khéi) mét cach tin cy, Vie nay tong d6i khé thyc hign va do vay phan lon eae nghién ctu chi xde dinh 46 lap tai cla phuong phap do ching bang cach lay mu lap tir khéng khi khdng doi. Trong nghien ciru clorobutadien trong khéng khi trong nha, do khéng dam bao cla két quad do duge danh gié dya trén nguyén ly olla TCVN 9695-3 (ISOMEC Guide 98-3). 6 khdng dim bdo két hop tuong déi cho phép do hexaclobutadien tai mirc thé tich 0,6 x 10° bang + 12 % va 49 khéng dam bao tuong déi mé r6ng (tai 46 tin cay 95 %) bang + 23 % Ml, 20TCVN 10736-6:2016 89 lap lai ca dy mau hydrocacbon khong phan cuc tty binh chia khdng khi cé chira sau VOC 48 dugc bao cao "7, 61 voi m&u 2 L, 46 lap lai cla Tenax TA® nhé hon 10 %, va cla mau 0,5 L bang 12%, CHU THICH Trong thir phat thai vat ligu, phép so sanh lién phong thir nghiém 44 dugc té chic dé danh gid tinh théng nhdt gia cac phng th nghiém dén dac tinh phat thai VOC tt vat ligu va san pham trong nha. Kat qua ‘cla cdc phép so sénh lién phéng nay dé duge céng bé M81", 13. Bao cao thir nghiém Bao odo thir nghiém bao gom it nhat nhteng théng tin sau: a) Myc dich ctia phép do; b) M6 ta vj tri ly mau; ©) Thdi diém va ngay ly may; d) — Didu kién dy mau (nhiét 46, 46 Am twong 46i); e) _Vign dan tigu chuan nay; f) M6 ta day ati quy trinh ly mau; g) M6 td ddy 4d quy trinh phan tich; h) Gidi han phat hién va dinh lwong cia phutong phap phan tich; i) — Néng 46 ctia hop chat da nhan dang, cling voi s6 CAS, bao gdm ca nguyén tac tinh toan va hiéu chudn d& dung; J) DO khOng dim bao cla kat qua duoc bao cdo. K&t qua c6 thé duo hoan thién bang ndng 46 khdi lveng TVOCrie hoa TVOCus tinh theo toluen. 14 Kiém soat chat lvong Muc kiém soat chat lugng phi hyp phai duoc ap dung, bao gém ca kiém tra xe nhan sau day: a) Mau trang hign trudng duoc chuan bi theo 8.5. ) Mire d6 mau trang dng hap phy duoc chdp nhdn néu pic tao ra khéng én hon 10 % dién tich pic dién hinh cia chat phan tich dang quan tam; ¢) Higu sudt gidi hdp VOC 06 thé duc xac dinh nh duoc néu tai ISO 18017-1 va can phai lon hon 95 %. Mat sd tuu y thém vé kiém tra hiéu suat giai hdp dugc néu tai 0.5.2. qd Higu sudt ldy mau c6 thé dug kiém soat bang cach st’ dung dng dat sau hac lay mau voi thé tich lay mu khac, nhé hon thé tich ly mu an toan.€) 8 lap lai cla phureng phép do 44 duge xéc dinh, vi du st dung viée lay mau va phan tich mau dup. 86 l4p lai cia mAu dip phai trong Khoang 15 %, 88 thu hdi cla hydrocacben rira giai trong khoang sdc ky tir n-hexan dén n-hexadecan lén hon 95 %. 22Phy luc A (Tham khdo) Vi dy hyp chat phat hign trong khéng khi trong nha va tir sin pham xay dyng trong budéng thir Bang A.1 - Vi dy hop chat phat hign trong khéng khi trong nha va phat thai ter san pham xay dyng trong buéng ther 2121 Hop chat héa hoe Hydrocacbon thom TCVN 10736-6:2016 1,2,3-Trimethyibenzen 526-738 176 1,2,4,5-Tetramethyibenzen 9593-2 197 4,2,4-Trimethylbenzen 95-636 169 1.3,5-Trimethyibenzen 108-67-8 165 1,3-Diisopropylbenzan 99-62-7 203 1.4-Disopropyibenzen 1-Methy!-2-propyloenzen 1074-17-5, ‘-Methyi-propyibenzen 1074-43-17 175 ‘-Propenyivenzen 627-503 175 2Ethyiolven e143 185 -Ethylolvene/4-ethyoluen 620-14-41622-96-6 162 2-Phenyloctan TRO 123 [4-Phenyleyoichexen 4906-16-5 [ord [S-Phenyldecan 4507-115 $-Phenyundecan 4537-189 je Mathystyren 98-63. 165 Tih3-2 100-41-4 Benzen Ethyibenzen Ethy(ybenzene/Ethynylbenzen 538-743 444 Isopropylbenzen 98-828 192 medp-Methyistyren 100-60-11622-97-9 168/169 mp-Xyian 108-38-3/106-42-3 139/138 Naphthalen 91-203 28 e-Butylbenzen 104-51-8 mPropyibenzen 103-65-1 lo-Methyistycen 15-4 loXylen 98-47-6 styren 400-42-5 FToluen 108-88-3 23TCVN 10736-| Bang A. ((iép theo) Hop chit ha hoe sh cas Hydrocacbon béo m-Cs dén n-Cyg, ‘Deven 372.058 7 Oden 71-660 121 2.2.4.6 6-Pentametiyepian 13475826 178 | 2,6,6-Trimethyloctan 62016-37-9 2atetihexan sae % 2atetyinonan 971980 767 e-tethyoctan ware 78 -2-Methyipentan 107-83-5 o> 2: Dimethyoctan 15868808 158 [S-Methylhexan 589-34-4 92 | 34Methyloctan 2216-33-3 143 |3-Methyipentan 96-14-0 63% |4-Methyidecan 2047-72-5 189 Isododecan 31807-55-3 216 n-Decan 124-18-5 174 -Dodecan 112403 26 n-Heptan 142-82-5 98 -Hexadecan ou763 287 [piece 110-543 3 -Nenan fo 11 p-Oetan 11-659 135 |-Pentadecan 629-62-9 21 n-Tetadecan e004 254 o-Teidecan €20505 26 n-Undecan 1120-214 198 Alkan ving 1,4-Dimethyicyclohexan $89-90-2 1-Methyl-4-methylethylcyclohexan 6069-98-3/1878-82-6 167 cisivans) [Cycohexen 110.827 a etnylyetonexan 108-072 103 Methyleyclopentan 96-97-7 72 24Bang A.1 (tiép theo) TCVN 10736-6:2016 Hap chit héa hee sécas ons e-Caryonhyen eran 25 ja-Pinen 20-56-8 156. |B-Pinen 18172-67-3 164 a-caren 13466-78-8 167 ecCedren 409-014 262 |Camphen 79-92-5 158. |Limonen. 138-86-3 176 Longiclen a75207 254 | Turpentin 8006-64-2 150 dén 180 Con 1-Butanol 71-26-3, 118 Hexanol 11273 158 4-Octanol 111-875 194 ‘Pontanal 741-0 137 | 1-Propanol 11-23-8 7 2-cayhtexenol 104-76-7 182 2-Methy--propancl (sabutana)) 788-4 708 B-Methy&propanct 75-650 82 2 Propanol 67-63-0 a2 2.6-Di-t-buty-4-methylphenol (BHT) 128-370 265 Cyctohexanol 108-930 161 Pronot 108-952 782 22.4-Tamethy,2pentanedil 25266774 254 isobutyrate iycol va glyool ele *-Mathory-2-propanol 107-98-2 118 2-Butoxyethanol 176-2 171 p-Buoryethoxyethonal 112345 zt 2-Ethoxyethanol 110-80-5 136 2-Methoxyethanol 109-86-4 125, /2-Phenoxyethanol 122-99-6 245, |3-Phenyi-t-propanol 6180-61-6 235 | 2-(2-Butoxyethoxy)ethane! 112-34-5 230 Dimethoxyethan ToT 88 Dimethoxymethan 109-87-5 4a Propylene glycok L 57-556 189 25TCVN 10736-6:2016 26 Bang A.1 (ti6p theo) Hop chat héa hee sé cas eames ‘Aldehyd 2-Butenat 123738 104 2-Deceral 2497-25-8 2-Ethyhexanal 123.057 168 2-Furancarboealdehyd 8-04 162 2-Heptenal (cslirans) ~ ”$7266-86-1118829-65-5 190 dén 91 6 50 mmHg 2-Nonenal 2463-53-8 100 dén 102 8 16 mmHg| f-Pentenal 167697-0 116 dn 125 -Undecenal 1997-833 |Acetaldehyd 75-07-0 2 Benzaldehyd 100-527 178 Bulanat 123.728 7% Decanal 1232 208 Heptanal iri 183 Hexenal 66254 129 Nonanal 124196 180 loctenal 728430 7 Pentanal 110-62-3 103, Propanal 123-38-6 ag? Keton 2-Butanon (methyl ety Keton) 78998 a | 2-Methytcyclohexanon ‘583-60-8 163 2-Methylcyclopentanon 1120-725, 139 ‘3-Methy!-2-butanon 563-80-4 95 _| 4-Methy-2-pentanon (methyt yo8401 17 isobuty! Keton) 3,5,5-Trimethyicyckshex-2-enon 7859-1 24 |Aceton: C 67-64-1 56> JAcetophenon 98-86-2 202 [cycionexaron 108-04-1 155 cyclopentancn 120923 “130 Halecacbon 1\4,4:2-Telrachloroetvan 630-208 120 11.2;2-Tetrachloroethan 7938-5 146 1.1.1-Trichloroethan 7155-6 74 4A2-Trichloroethan | 79:00-5 “44 1 2-Dichloroetan 107-062 au 1 a-Dichlorobenzen 106-46-7 173Hop chat héa hoe [Carbon tetrachtorid Bang A.t (tiép theo) SéCAS TCVN 10736-6:2016 Diém séi [Chiorabenzen Dichloromethan 75-082 40> Teteachioroethen 127-18-4 12 Trichloroethen 2,2-Dimethylpropanoic axit 7598-9 Acetic axit 6419-7 118 Butyric anit 107-92-6 163 Heptanoic ait 111-1668 223 Hexadecanoic axit 57-103 360 Hexancie axit 142-624 202 Isobutyric at 79-31-2 153 [Octanoic axit 124-07-2 240 Pentanoic axit 109-524 106 Propanoic axit 79-094 141 2-Ethoxyethyl acetat 1114-15-98 2-Ethylnexyl acetat 103-09-3 198 2-Methoxyethyl acetat 110-49-6 145 Bory aca Buty! acetat Butyl format 592-84-7 107 Ethyl acetat 7 Ethyl acryiat 140-88-5. 100 cbc ioe ite Isopropy\ acetat 1108-21-46 90 Linalool acetat 115-95-7 220 ie aa Bas a Methyl methacrytat 80-62-6 100 Propyl acetal 109-60-4 102, 2a. thnanyeenareoa aes00 i Vinyl acetat 108-05-4 Te Dibutyl phthatat 84-74-2 340 ina ata [ea i 27TCVN 10736-6:2016 28 Bang A.1 (két thic) Hop chat héa nge Khae 14-Dioxan 123.911 “-Methy2-pyrrolidinon 872.50-4 2-Pentyifuran Aniline [Caprotactam Indene Nitrobenzen [CAG THICH 1 THB ich dy man fo2n cho hai hi co duge nu trong Phy tye 8. JCHO THICH 2 __Khi phn teh VOC ria gli trade mhexan, 6 thé ding che chdt hép phu hod totn dug: du tal 180 1801741, 8 Gis wjeda t-prenyleyeohexen, © ce ap chit sé 05 aibm 261 hp hon ata hexan khdng dug gi el inh tong bing Tenax TACKN sir dung kich hub ng ty miu va ths ch Ky mau due khuyén cée trong iby chub nay.Phy lye B (Tham khdo) TCVN 10736-6:2016 Thé tich fay mau an toan déi véi hoi higu co Iya chon lay mau [én Tenax TA® Bang B.1 cung cp di ligu vé thé tich wu trén cue va SSV déi v6i hoi hGu co duge tay mau trén dng hdp phy chira 200 mg Tenax TA® tai 20 °C 1121119412, $4 CAS cla hop chat duge ligt ké trong Bang A.1. Bang B.1 - Thé tich tdy mu an toan déi v6t hoi hibu co la chon ly mau fn Tenax TAS Bidm | Apsuit | Thatich ssv ssv tren Hop chét hou co sét bd two gam sc | kPa25°c) 1 1 ue *c Hydrocacton Hoxan 69 16 64 32 16 110 Hepian 98 47 4 7 85 130 [Octan 728 1A 160 20 390 140 Nonan 161 05 1400) 700 3500) 150 Decan 174 0.13 $200 2100 | 10108 180 [Undecan 196 0.14 25x10 | 12x10 | 650x108 170 Dodecan 216 04 [126x108 | 63x i0¢ | 3.0% 108 180 Benzen 80 10, 8 62 3t 120 FTotuen M1 23 76 38 130 140 bxyien 136-G6n 144] 600 300. 1800 140 Ethyibenzen| 136 098 360 180 900 148 Propytbenzen __| 88 03 1700 850 4000 160 isopropyibenzen 182 Of 360 480 2400 160 Ethyitoluen 162 2.000 1000) 5.000 160 Timetnyibenzen 165 dn 176| 0,1546n0.2| 3600 1.800 8900 470 Styren 145 0.88) Methylstyren 167 23 hydrocact [Carbon tetrachlond 62 a “2-Dichloroethan 54 a 11 teTrichloroethan 74 Khong khuyén cdo Tenax TA® ,4,2-Trchloroathan 114 8 4 170 120 f.t,1.2-Terachoroethan 130 | 06dén07| 160 78 380 0 | 2-Tetcachloroethan 146 067 340 370 260 150 Trichtoroethyten 87 27 142 56 28 120 Tetrachloroethylen 124 187 6 48 240 150 (Ghiorobenzen 131 12 2 26 130 | 29TCVN 10736-6:2016 30 Bang B.1 (iét thitc) suat Hop chat héa hc bl hot ssv gam sc | KPa @s'o) 1 \ Wg Este va glycol ete thy acetat 71 97 72. 36 18 120 Propyl acetat 102 33 36 8 2 140 Isopropyl acetat 90 63 2 6 3 120 Buty acetat 126 19 170 5 420 150 Isobutyl acetat 118 27 288 130 650 130 Buty acetat 98 — Kong khuyn cdo Tenax TAS Methyl acrat et siott 13 Co 120 thy acryiat 100 39 8 24 120 120 Methyl methacrylat 100 37 55 ar 130 [0 Methoxyethanol 125 08 é 3 15 120 Ethoxyethanol 136 a5 0 5 % 130 [Butoxyethanol 170 os 70 35 170 140 Metnexypropanat 118 | 12@0°C) | __a7 3 a 115 Methoxyethyl acetat 145 027 16 8 40 120 Ethoxyethy!acetat 186 0.16 30 5 75 140 utexyethylacetat 192 04 150 750 160 ‘Aldohyd va keton 2-Butanon (methy! ethyi 0 103 64 32 16 420 keton) Metny isobutyl keton 118 08 82 28 130 140 (Cyciohexanon 165 0.46 340 170 850 150 3.5.5°Trimethyloyciohex-2- 214 0.08 +4000 3600 28 000 90 enon Furtral 162 05 800 300 1500) 200 én n-Butanot 118 087 10 5 25 120 isobutarol 108 56 28 14 120 -Butanot 8 Khong khuyén cdo Tenax TA® [Octanot 180 Phenot 182 Pyricin 116 16 faniin 184 0.08) nitrobenzen an 0.02 2800 | 14000 | 70000 200TCVN 10736-6:2016 Phy luc (Tham khao) 96 thu héi cla dung mél sau bao quan trén 6ng hap phy Tenax TA® Bang C.1 cung c4p dé ligu vé a6 thu hdi dung mdi trong bao quan trén éng hdp phy Tenax TA® {ISO 16017-1}, S6 CAS cila hyp chat duge liét ké tai Bang A.1 Bang C.1 - Bé thu hai cia dung méi sau khi bao quan trén éng hap phy Tenax TA® ‘Thai gian bao quan $ thing | Thoi glan bao quan 17 thang corundi | PPV TO anti | Béchum trungbinn? | {hésdbién | fringbinh | (he s6bién ‘aBng) : ‘d6ng) % % % % Hyp chét hou co [Undecan 1002 02 Dodecan 101.8 15 1015) O8 Benzen 98,7 20 98,6 oe | FTouen {100,07 18 (100.0) 08 pxyien 99,9 7. 99.8 oF fo-xyien 700.0 w7_ {sas oF Ethybenzen 99.6 04 97.9 13 Propylbenzen 87 45 985 o7 Isopropyibenzen 10.9 98,9 18 972 13 rap-Etryltouen 10,5 8 7 98,9 42 o-Ethyttoluen 54 400.1 18 t 98.9 Or 1,2.4-TAmethylbenzen 10,8 100.4 13 99,4 08 4.3.5-Timethylbenzen 10,7 400,0 15 99,1 Os Trimethyibenzen 102 1016 05 101.3 08 Hn‘Thoi gian bao quan 5 thang Bang C.4 (két thie) Thoi gian béo quan 11 théng 2-Butanon (methyl ethyl keton) Nap. 186 thu Adi BG chum 8% chym Hop chat héa hoc trungdinh? | (hésébién ] OSthuhd! | (ng 56 bién ‘48ng) | trung binh 8ng) L cs % % % Este va glycol ate thy! acetat 103 378 10 10050 25 Propy! acetal 109 1008 47 98.1 08 Isopropyl acetat 84 870 04 14 Butyl acetat 108 100.3 16 06 Isobutylacetat 10,7 1002 14 oF Methoxyethancl 89 or 37 4 16 Ethoxyethano! 104 8 25 2, 33 [Butoxyetnanct 100 1006 aa 1001 30 Methoxypropanal 104 953 36 99,0 42 Methoxyethy! acetat 125 7006 14 98.9) 14 Ethonyethylacetat 114 998 22 987 28 Butoxyethy!acetat us 1018 18 939 1d ethyl isobutyl Keton 08 10,7 08 Cyelahexaron 42 100.7 06 2-Methyleyelohexanon 05 1084 13 2-Methylcyciohexaron 10 1030 7 #-Methyicydohexanon 14 102.7 08 3.8 5-Trimethyloyclohex2-enon 08 77 42 Butanol 90 8 3.0 69 12 [isobutenot 89 938 35 64 19 32 CGhudn nea vé tolven = 100,TCVN 10736-6:2016 Phy lye D (Tham khao) Xc dinh hop chat hiru co rat dé bay hoi va hop chat hiru co’ ban bay hoi cling véi hp chat hivu co bay hoi Dt Gioi thigu Phy luc nay mé ta quy trinh 48 lay mau va do phat thai VVOC va SVOC cing voi phat thai VOC tir vat ligu xy dyrng trong buéng va ngan the. Hop cht VVOC va SVOC cé lién quan theo quy utc vi chting ria gidi rede n-hexan va sau n-hexadecan tong Ung trén cot khong phan cye (potydimetylsiloxan). Phu luc nay dua ra hudng d4n éuoc néu trong ISO 16017-1 v8 Iva chon va stv dung cdc chat h4p phy thich hop va cae diéu kién phan tich cho nhiéu hop chat hou co pha hoi. D2 Nguyén ly Thé tich do dugc cla khéng khi tir budng thir phat thai hode ngan thir phat thai dugc born voi lvu lugng dang dugc kiém soat qua mét éng cé chiva tb hyp cac chat h4p phy 43 duge s4p xép dd lam tang 9 manh cla chat hp phu. Chat hu co pha hoi duoc bay riéng biét trén lp hap phy do khéng khi di qua. Trong qua trinh phan tich tiép sau, hgp chat da gid lai duoc gi nhiét va dong khi mang hdi lvu. Cac chat phan tich da gidi hép nay duge quét qua mot bay tap trung dug chuyén vao GC 6 mt cét mao quan (hoc nhiéu cSt) va detector MS, 6 FID bd sung tuy chon, & 46 ching duge nh&n dang va do. \Ap tle cde dng stv dung Chi tiét quy trinh t4y mau va phan tich VVOC va SVOC cling voi VOC dug quy dinh chi tiét tai phan chinh cia tiéu chuan ndy ngoal triv nhOing didu duoc néu duvéi day. 0.3 Thudc thir va vat ligu D.3.1 Vidy lop chat hdp phy 0.3.1.1 Béng thach anh hode I6p thiy tinhithach anh, sach (nghia la ip khéng tao ra cac chét nhan tao anh hudng dang ké dén phan tich} va knéng dé tao thanh hat. D.3.1.2. Tenax TA® 9 o@ hat 0,2 mm dén 0,5 mm (35 mesh dén 80 mesh). Tenax TA® Id mt polymer xép nén 2,6-diphenylenoxit. 33TCVN 10736-6:2016 0.3.4.3 Chat hép phy cacbon den, nhu Cacbonpack X® > hodc Cacbongraph 5 TD® 4, c& hat 0,25 mm dén 0,5 mm (40 mesh dén 60 mesh). Chat hap phu cacbon va avec phu hep voi VVOC co 4p suat hoi nhé hon ap suat hoi dién hinh cho hydrocacbon Cy. D.3.1.4 Lép chat h4p phy kich thuéc sang phan ti? cacbon (rat manh) cing cé thé duge ding tai dau cudi khéng l4y mau cia éng a8 bay VOC cé 4p sudt hoi lan hon dp sudt hoi dién hinh cho. hydrocacbon Cz. Tuy nhién, chil y rang cac 6p chat hdp phy nay ia khéng ua nuéc hoan toan. Do vay, néu lop chat hp phy nhu vay ¢6 trong 46, dng can phai duge lm sach kh6 theo hudng ly mau tude khi phan tich. D.3.2 Chuan bj éng tléu chuan ‘Ong tiéu chudn diye chudn bi bang c4ch dua chuan pha léng hoac pha khi vao cudi giai doan ly mau ota éng hép phu da duge didu kién héa trong ding khi mang 50 m{UJmin dén 100 mL/min nh quy dinh tais4 Can phai chudn bi chudn pha lodng trong mét dung méi hode khéng bi |ép chat h4p phy manh nhat cd trong éng git lai (metanol la mét vi dy phé bién) hoac trong mét dung mdi san sang xéc dinh (sac ky) tt hyp chat chinh can quan tam. Néu mt hegng 1én dung mdi bj éng hdp phy gid lai trong qué trinh bd ‘sung chuan léng, thi giam thiéu thé tich bom, vi du dén 1 pL hode nhé hon. Néu yéu cdu khoang hyp chat quan tam ctia ca chuan pha khi va pha léng, chudn pha long cdn phai duge dua vao trwac tién va tam sach dung méi nh yéu cau, Sau d6 chuan pha khi duc dua vao. ‘Dm bao rang the tich di qua khéng vet qué gidi han trong qué trinh thém chuan. D4 Thiét bj D.4.1 Ong thép khong gi, dng thép boc chat tro hodc dng thy tinh, nhdi sn mat hodc nhidu lop hap phy. Ong c6 kich thuée dugc quy dinh tai 6,1 c6 thé duge nhdi dén ba lop h4p phy dé me rong khong chat bay hoi can phan tich. Nhiéu lop h4p phu phai duoc sdp xép trong lép riéng ré (dai) dé lam tang khd nang hdp phu dén cudi dng lay mau (xem Hinh 0.1). Khéi lugng 200 mg Tenax TA® duge dung dé lay mau va phan tich VOC va cing trong thich vi phép do dinh lvgng phan pha hoi cia m6t sé hyp chat cé diém sdi cao hon, vi du diém séi dén n-Cz. CHU THICH 1 Ti trong cua Tenax TA® la bién dong. Tuy nhién, 200 mg Tenax TA® thurang c6 dé day ~ 40 mm trong éng kim loai loi § mm va ~ 60 mm trong dng thay tinh 161 4 mm. » Cacbonpack X 18 lén thyong mai clia Supelco. Théng tin nay dva ra chi tao thuén Igi cho ngudi si dung tigu chuan va khdng phdi [a xac nhan cla tiéu chudn vé san phdm nay. C4c san phdm twong duong 06 thé duoc dng néu ching cho két qua nhw nhau. ® Cacbongraph 5 TO {a tén thong mai cla Lara. Théng tin nay duza ra chi tao thudn loi cho ngudi sir dyng tiéu chun va khong phai la xd¢ nhgn ciza tiéu chudn vé san phém nay. Céc san phdm tong duong co thé cuoe ding néu ching cho k&t qué ahy nhau. 4TCVN 10736-6:2016 BE tao thuan [gi thu hdi cdc chat ban bay hoi (dac biét chat nay cd diém séi lon hon n-C22) bang cach chén them mét day méng (5 mm dén 10 mm) bong thach anh & phia trudc clia 200 mg Tenax TA®, CHU THICH 2 Lua chon Cacbopack X® hogc Cacbograph TD® nhu chat hép phy manh hon 86 tao thuan Io cho vige [uu va phan tich dinh long hop chét bay hei nhu 1,3-butadien, nhung nude khéng bi gi lai dang ké thr tbuéng khdng kif hoge ng’in khong khi. CHU THICH 3 Cach khac, tham chi 6p hép phy manh hon la od san (vi dy ray phan tir cacbon) cho phép hyp chat rét dé bay hoi nh hydrocacbon Ca va vinyl clorua bi bay. Tuy nhién, éng nhdi sn chat hép phy rat menh C6 xu hung f& mot sé gi nuz6e (xem ISO 16017-1) va thutng cdn thém mét burée lam sach khd trude khi phan tich nhigt (TD)-GC/MS(FID). CHU THICH 4 Ong thép khéng gi hodc éng kim logi dug boc thép khong gi cé Idi 5 mm c6 kha nangicung lugng ai vai cd 200 mg Tenax TA® va 20 mm Iép hap phu manh hon. CHU THICH § C6 thé nhdi mat éng kim loai voi tat cé ba lp hdp phi khdng c6 tac dong dang ké dén khdi lugng Tenax TA®. Mét vi du vé sy két hop la: bong thach anh (Smm); Tenax TA® (175 mg, ~ 35 mm); va 20 mm cia Cacbograph 5 TD® hoac Cacbopack X®. TAt cd lop h4p phy phai duge gi & phan gia (thueng 60 mm) cla ‘ng, nghia la phan tiép xc tryc tiép véi Id giai hp dng cia thiét bj (xem Hinh .7). CHU THICH 6 Can phai giai hap t4t ca 6p hdp phy vei dong khi mang trong huéng nguee dong voi dong khong ikhi trong khoang thdi gian lay mu (xem Hinh D.1). CHU DAN 1 Ong thép khong gi hoe éng dure bc thep 2 Sgithach anh § mm ~35 mm, 175 mg Tenax TA® 20 mm chat hap phu manh hon, vi du Cacbongraph STD hoae Cacbonpack X LO x0 git bud thép Lui thép git lai chét hdp phy ‘Lugi thep git Iai chat hap phy hoge bong thach anh 0,5 mm Lug’ thép gi lai chat hdp phy Dong khi gidi hap ‘Dong khi lay mau Hinh D.1 - Vi du éng kim loai nhéi nhigu lop hap phu dé mo réng khoang bay hoi cia chat myc tigu ee ev)8HAse 36TCVN 10736-6:2016 CHU THICH 7 Xéc dinh thé tich di qua duge quy dinh tai ISO 16017-1:2000, Phy Iyc B. Thé tich hdp phy hoac thé tich git lai duce diing lam thud do dé manh cua chdt hdp phy (ai lye) d4i véi hoi hu co. Ching phy thudc vao nhiét dé va 1118 voi kich thud cla éng léy mau va lveng chat hép phy. Dién hinh, SSV duge dat tai 2/3 cla thé tich di qua. Nhu mét bién phap gan dung, gép 46i chiéu dai day trong khi durdng kinh éng dug git? khéng déi & gdp d0i thé tich hp phy. Tuong ty, nhu mot bién phap gan ding, ting nhiét do cua éng trong qua trinh lay méu 10 °C, gidm mt niva thé tich di qua. Chi ¥ rang phan l6n thé tich di qua va sé ligu thé tich lay mu an toan (vi dy tai Phy tye B va ISO 16017-1:2000) dug baa c&o tai 20°C. CHU THICH 8 Luu long déng cia bom téi vu déi vai dng nhidu {op hdp phy ea kich thute d& dure mé t trong khong 20 mLimin én 100 mLimin, CHU THICH 9 Ong bang thép khéng gl boc chat trer hoc éng thiy tinh duoc wa ding hon 68 quan trac hop chat phan Gng, gay mei. Cach tiép can khac la ding cac dng ma méi éng chiva mét chat hdp phy dugc lam tang do manh dugc néi tiép véi nhau va truéc tién néi véi dng 6 cha chat hdp phu kém nhat trong day lay mau. Tuy nhién, é8y Ia cach tiép c&n khong hiéu qua a6i ve 4c ngudn cin ay mau va phan tich, Ong hdp phy da duge nhdi tude cling nhy éng 44 duoc didu kién héa trude c6 ban sdn trén thi trudng. Cach khée, éng hap phy o6 thé dug nap day trong phong thir nghiém nhu quy éinh tai 6.1. 0.4.2 Cét mao quan GC. Thyc hign theo quy dinh ky thuat duge néu tai 6.8. C6 thé cn cot mao quan top film day hon va/hode dai hon néu quan tam dén VVOC. D.4.3 Thiét bi gidi hap nhiét. Phan tich déng thdi cac hop chat c6 khoding bay hoi réng, VVOC, VOC va SVOC dug tao thuan Igi bang cach sir dung nhiéu chap hap phy. Ching duge stv dung néi tiép voi nhau dé lam tng dé hp phy, ca trong éng mau va trong bay thu va bang cach gidi hap x4 nguoc. Xa ngugc 66 nghia la dong khi duoc ding dé gidi hap mau ra khéi dng hap phu hoac bay tp trung phai theo hudng ngvoc voi hudng duye ding trong lay mau hode bay, Trong cach nay, hop chat od diém. 861 lon hon duge bay va thoat (gidi hdp) khdi cht hdp phy phia truéc (yéu hon) va khéng bao gid tiép xte véi chat h4p phy (manb hon). 0.5 Ldy mau khéng khi budng thw hode khéng khi ngdin thie 0.5.1 Yéu cdu chung Dam bao rang éng mau & nhiét 66 gan bang nhau véi khong khi budng thir dé ngdn ngiva nti ro ngung tu nue trong éng mau khi 4y mu khi phat thai ty mau am. 0.5.2 Bao quan dng mau ‘Ong phai duoc day ndp ngay sau khi ly mau, dt trong hop chua kin va khong ¢6 chat phat thai va due b&o quan & noi sach. Ong duge nhdi voi mét lop hdp phy cé thé éuge bdo quan & nhiét 46 phéng, Ong nhiéu lop hdp phy cdn phai bao quan 6 trong td lanh dé giam thidu rui ro di chuyén chat phan tich trong éng. Phan tich cdc éng cang sém cang tét va khong dé qua bén tuan,TCVN 10736-6:2016 Np cla dng mau bao quan dai han trong td lanh can phai due han kin lai khi mau dat dén nhiat 46 bdo quan t6i thidu cia dng, Can phai fam cén bang cae éng mau bdo quan trong tl lanh bang voi nhiét dé phéng truée Khi chung duoc mé 68 phan tich. CHU THICH Thong tin va thu hdi VOC ti éng hdp phy sau khi do quan duac néu trong tiéu chudn nay va 1S 16017-1, D.6 Phan tich D.6.1 Diu kién phan tich Khi phan tich cdc hep chat cé dc tinh bay hoi trong mét dai rong, diéu dac biét quan trong la higu suat gidi hdp dat duge yéu cau téi thiéu (nghia la > 95 %) déi véi tizng hop chat. Vi du didu kién thiy nh: sau Nhiét d6 giai hap 200 °C dén 320 °C ‘Thdi gian gidi h4p 5 min dén 15 min Luu lveng dong khi giai hép 20 ml/min dén 50 mimin Nhiét 46 cao clla bay lanh 250 °C dén 330 °C Nhiét 46 th4p cila bay lanh =150 °C (hé théng TD tap trung tinh thé) -30 °C dén +30 °C (hép phy trong bay) Chat h4p phu bay lanh. Thach anh/Tenax TA%/cacbon den (hodc kich thud sang phan tty cacbon) Nhiét 46 chuyén trén duvong lay mau 150 °C dén 220 °C. Chyong trinh 16 GC 35 °C dn 40 °C trong 3 min, § °Cimin dén 10 *Cimin dén 300 °C, 300 °C trong § min Ti sé chiangat ti ng lay mau voi by thir hai va tir bay thc hai dén et phan tich (néu ap dung) can phai duoc Iva chon phu thudc vao néng dé hoi dy kién. (Xem théng tin tl: nha san xuat thiét bi giai hap abit). CHU THICH Cé thé c&n dat nhiét 46 gidi hdp thap hon va nhiét a6 dong thap hon (vi dy 80 °C dén 120 °C) dé 4am bao 46 thu hii dinh lwgng va phan tich céc loai phan tong, gay mui cing nh mecaptan va amin. Nhu trong trréng hop éng mau, sir dung mdt day chat hdp phy [am tang manh trong bay tap trung mé@ réng khoang bay hoi ciia chat phan tich cé thé do trong mot lan phan tich. Gidi hap bay x4 nguge duge yéu du. 37TCVN 10736-6:2016 4 gidm thidu cdc tac déng nhan tao, cn phai d&t didu kién nhiét d6 va nhiét 46 lm sach dng I6n hon nhiét €6 gidi hap phan tich ti 10 °C dén 20 °C, nhung khéng vurgt qué nhiét 46 lon mht cla chat hap phy bén ving nhiét kém nhat trong éng. D.6.2 Kiém tra higu suat giai hap Hiéu suat gidi hp c6 thé duge xac dinh str dung quy trinh quy dinh tai ISO 16017-1 hoae bang cach tién hanh tuan ty phan tich TD-GC/MS/FID !ap lai cla mot chudn don, Déi voi cach tiép cn sau, ngét dong xa tw chat hdp phu [nghia la ngat dong xd trong qua trinh gidi hép (ng) dau val hode giai hap (bay) the hai] dugs thu gom lai dinh luong vao dng hap phy da diéu kién hoa tong ty vai dng duge ding cho vic thu thap hoi. Khi mu d@ thu thap lai doe phan tich, céc dong xa ngét duge thu thap lai ln niva. Vige nay cho phép tuan ty phan tich lp lai duege tién hanh trén mat chudn don. Néu bat ky hp chat cho dé thu héi thap hon do thu hdi dy kién (tong tng ti sé ngdl/chia vafhoac véi do thu hdi cia cac hop chat khac trong chudn) do quy trinh tiép sau, digu nay chi ra higu sudt giai hdp kém 461 vi hop chat nay. D.7_ X4c dinh néng dé cia hoi phat thai trong khéng khi budng thir hoge ngan they Co thé dinh lung VVOC va SVOC trong clung phan tich nhu VOC, néu cae bude thich hep duge tién hanh trong ly mu va phan tich nh dug mé ta trong Phy Ic nay. Cac diém chinh bao gdm: a) Si dung chat hap phu phu hop hoadc mét day chat hdp phy trong dng ldy mu (xem 0.4.1); b) Sir dung mét chat hap phy phi hop hozc mot day chat hdp phu trong bay tap trung (xem 0.6.1); c)_ Lya chon e6t GC va diéu kién phan tich GC tuong thich véi khoaing bay hoi cla chét phan tich ma rong (xem 0.4.2 va 0.6.1). Higu nang lay mau va phn tich déi voi hop chat ngoai khoang TVOC cé thé durge kidm tra xdc nhdn str dung kiém tra duoc mé ta déi vai VOC, xem Bidu 14. CHU THICH 1. Si dung ba chat h4p phy, béng thach anh, Tenax TA® va cacbon den manh (nh durgc mé ta tai 0.4.1 va Hinh D.1), trong od dng mau va bay tap trung, cing véi gidi hép xé nguge, cho phép phan tich dinh lugng dang thei hop chat trong khoang bay hoi tty n-Ce dén n-Cas va ln hon. Cac chat hép phy nay va nude do vvay khéng lam t&ng sii ro c&n 1rd ca nud khi thi khi phat thai tir cde sn phdm va vat ligu 4m, néu thye hién ccéc bién php phdng gira thang thueng sy ngung ty dugc mé to D4, CHU THICH 2 Huéng dan thém vé Iva chon chat hdp phy 661 vei |4y mau nhidu chét bay hoi duce néu tai 10 160171 38