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Sustainable

Plastics Strategy

suschem.org
Contributing partners:

SusChem
Cefic
PlasticsEurope
EuPC
ECP4
Sustainable
Plastic Strategy

Edition 2, December 2020


Content 4
Sustainable Recycling 28

1 1. P
 lastic stream preparation
(waste pre-treatment) 28

2. Plastic waste preparation 29

Introduction 7 3. Sorting and separation 29


2 3.1. Improve sorting 31
3.2. Improve separation 32

Methodology 11 4. Recycling technologies 34


4.1. C
 hemical recycling of plastics
waste by pyrolysis 36
3 4.2. C
 hemical recycling of plastic
waste by gasification 37
4.3. C
 hemical recycling of plastics
Sustainable-by-Design 16 waste by depolymerization/solvolysis 38

1. Material design 1 6 4.4. R


 ecycling by dissolution of
multi-polymer systems 38
1.1. Extend lifetime 16
1.2. Material usage vs 4.5. Mechanical recycling 39
performance 19
5. Post-processing 40
1.3. Increase recyclability 19
1.4. Biodegradation 21
1.5. Addressing micro 5
and nano-plastics 22

2. Article Design 24
Alternative Feedstock 43
2.1. Design for dismantling 24
1. A
 gricultural and forest
2.2. Decrease material usage 24
biomass waste based raw
2.3. M
 onolayer pouch and
in-mold labelling 25 materials 43

2.4. R
 efillable and recyclable 2. CO2/CO-based 44
PET bottles 26

Glossary 49

About the partners 50

About Suschem 51
6 • SUSTAINABLE PLASTICS STRATEGY
Introduction

Plastic waste is ending up in the environment, feedstock for pure polymers by using chemical
and unmanaged, is amongst the greatest recycling.
global environmental challenges of our time12.
As an industry, we believe plastic waste in the We need a holistic approach to plastic waste
environment is unacceptable and represents a based on a measurable science-based
massive loss of a valuable resource. framework that aims at preventing waste,
enabling consumer awareness, and
One of the keys to tackling plastic waste is the implementing eco-design-based solutions
creation of a circular economy. In contrast to towards a circular economy. To achieve this, we
the make, use, then dispose, of linear economy; need to continue to harness the power of
in a circular economy we keep resources in use research and innovation to address the
for as long as possible, extract the maximum reduction, reuse and recycling. This is
value from them whilst in use, then recover envisioned by the authors of this report to make
and regenerate products and materials at the circularity and resource efficiency a reality for
end of their life. The circular economy is about plastics.
recognising and capturing the value of plastics
as a resource, with the least impact on the Versatile and durable, plastics are a remarkable
climate. We have over recent years accelerated material. They allow us to meet a myriad of
the transition to a circular economy, amongst functional and aesthetic demands, whether this
other actions. is drinking clean water, playing sport, staying
connected, enjoying the comfort of home,
However, the circular economy for plastics is not visiting loved ones near and far, or helping us
just about waste. Whilst eliminating leakage to live longer and healthier lives. Plastics have
and the increased use of secondary materials become a key part of our society, defining the
is one part of the picture, the transition to way we live today, improving the quality of life
renewable feedstock completes this picture. for millions of people in Europe and across the
Long-term, plastics production should also globe. They make our lives easier, safer, and
decouple from fossil feedstock. This means using more mobile, while significantly increasing
more renewable energy and more alternative energy efficiency and lowering CO2 emissions.
feedstock from waste and renewable resources
and investing in carbon capture solutions. The European Green Deal3 aims to make
the EU’s economy sustainable by turning
Much of the plastic in use today can already climate and environmental challenges into
be recycled in some way, but according to an opportunities and making the transition just
analysis by the Ellen MacArthur Foundation, and inclusive for all. The European Green
roughly one-third of the world’s plastic Deal action plan will boost the efficient use
packaging waste is lost in the environment. In of resources by moving to a clean, circular
comparison, about 14% is collected for recycling, economy, restore biodiversity and cut pollution.
and 40% is disposed of in landfill. The remaining The EU aims to be climate neutral in 2050 and
14% is incinerated, sometimes with energy- this objective will require action by all sectors
from-waste recovery. In view of this, chemical of the economy to invest in environmentally
technologies are needed to improve the friendly technologies, support industry
labelling, identification and separation of waste to innovate, roll out cleaner, cheaper and
plastics and composites into single-component healthier forms of private and public transport,
polymers. These polymers should be reprocessed decarbonise the energy sector, ensuring
for reuse in new products and/or fully recycled as buildings are more energy efficient and

1 https://science.sciencemag.org/content/360/6384/28.full 3 https://ec.europa.eu/info/strategy/priorities-2019-2024/europe-
2 https://pubs.acs.org/doi/10.1021/acs.est.9b02900 an-green-deal_en

SUSTAINABLE PLASTICS STRATEGY • 7


improving global environmental standards. help plastic value chains boost the EU market
for recycled plastics to 10 million tonnes by
Plastic is an essential material to ensure a 2025 under the European Strategy for Plastics
sustainable future and has a vital role to play in in a circular economy (2018)7. The CPA initiative
helping Europe achieve its Green Deal ambitions. is based on voluntary pledges by industry8. In
As an industry we are committed to increasing September 2020 more than 200 organisations
circularity and resource efficiency through our are signatories of the CPA.
voluntary commitments launched in 20184,5.
Innovation as a global framework will play a key EuPC, EPC4, PlasticsEurope and a number of
role together with ongoing cooperation along the the SusChem platform participants are proud
whole plastic value chain. The complexity of this to be actively involved members of the CPA
value chain (made up of producers of plastics and contributing in the five main value chains or
chemical raw materials, converters, brand-owners, plastics-using sectors, namely: packaging,
retailers, actors of waste management...) makes automotive, construction, agriculture and
the creation of innovation ecosystems necessary electronic and electrical equipment (“EEE”).
to tackle the sustainability challenge. To achieve
this, we need to continue to harness the power of R&D needs have been identified across the five
research and innovation to significantly increase main CPA value chains (packaging, automotive,
reuse and recycling. In doing so, plastics will construction, agriculture and electronic
accelerate their contribution to the European and electrical equipment (“EEE”). The CPA
Green Deal objectives of reduced greenhouse gas commitment embraces R&D9 and Investments
(GHG) emissions and resource efficiency. including chemical recycling, Design for
recycling, Collection and sorting, Recycled
Developing high-quality and high-performance content, Monitoring and Governance.
products and solutions that are sustainable can
be highly complex and challenging. It requires To achieve overall increased sustainability based
innovative technologies and some of the best on full life cycle thinking, it is important to:
scientists, engineers and most innovative minds,
and has been the bedrock of the leaders of Innovate advanced recycling and sorting
our industry for over a century. We believe our technologies to increase the value retrieved from
industry has an essential role to play in making plastic waste,
plastics more sustainable. Developing the
• O
 ptimise and redesign value chains for
necessary levers requires a concerted effort by
optimal value (retention): from sorting to
everybody who can contribute.
renewed raw materials,

The European Commission launched the Circular • S


 ecure feedstock quality with the application
Plastics Alliance (CPA)6 in December 2018 to of testing technologies to meet purity and
quality requirements,
4 The European Plastics Industry Circular Economy Voluntary Commit-
ments (PETCORE, VINYLPLUS, ECRA and PCEP)
5 Plastics 2030, PlasticsEurope’s Voluntary Commitment to increasing 7 https://eur-lex.europa.eu/legal-content/EN/TXT/?qid=1516265440535&uri=
circularity and resource efficiency (PLASTICSEUROPE) COM:2018:28:FIN
6 https://ec.europa.eu/growth/industry/policy/circular-plastics-alliance_en 8 https://ec.europa.eu/growth/industry/policy/circular-plastics-alliance/
commitments-and-deliverables_en
9 https://ec.europa.eu/docsroom/documents/43693

8 • SUSTAINABLE PLASTICS STRATEGY


• Incorporate alternative feedstocks in the outlines the future research needed to fulfil
production of plastics: waste or by-products the objectives of the European Strategy for
from other sectors and processes, such as Plastics and the Green Deal priorities, where
biological feedstock from the agricultural the technology solutions described are part
industry, carbon-based feedstock from of an integral approach to render plastics
the chemical industry and chemical and more sustainable.
secondary plastics from the plastic industry,

• D
 esign materials with enhanced separation
and recycling properties,

• D
 esign articles/products and business
models that facilitate and encourage reuse,

• D
 evelop repair solutions that extend the
lifetime of plastic articles,

• D
 evelop technologies for the characterisation
of “recycled” or “bio-based” (drop in)
feedstock,

• S
 et a comprehensive methodology to
evaluate the environmental impact of each
product to enable reliable benchmarking of
different approaches,

• D
 evelop methodology to calculate
Environmental, Social and Governance (ESG)
parameters for standard and renewable
approaches on feedstock and durability,
to make a comparable evaluation for
investment decisions over the short, middle
and long term.

• F
 urther research actions are required to
take advantage of these ecosystems to
make plastics more sustainable. This report
presents a shared vision and demonstrates
how collaboration within the plastic value
chain can be a driving force for change. It

SUSTAINABLE PLASTICS STRATEGY • 9


10 • SUSTAINABLE PLASTICS STRATEGY
Methodology

The “Plastics Strategic Research and Innovation Thus, this document was elaborated based on
Agenda in a Circular Economy”10 was published input from numerous experts of the plastics
in 2018 and since then, several relevant initiatives value chain, involved in the European Technology
have been set up (Circular Economy Action Plan, Platform for Sustainable Chemistry - SusChem,
Circular Plastics Alliance, Horizon Europe Green the European Composites, Plastics and Polymer
Deal, etc.) The Plastics SIRA was conceived as a Processing Platform – ECP4 , European Plastics
living document to be updated to address the Converters – EuPC, and PlasticsEurope.
current situation and R&I needs in the plastic
sector and include new items if needed. All
previously involved partners (SusChem, Plastics
Europe, EuPC, ECP4) provided their input with
the aim to compile the current document
“Sustainable Plastics Strategy”.

10 http://www.suschem.org/files/library/Final_Brochure_Plastic_strate-
gy_digital.pdf

SUSTAINABLE PLASTICS STRATEGY • 11


The research and innovation priorities defined by the European Circular Plastic Alliance initiative
are presented in the following tables 2 and 3 with their correspondence to the respective R&D area
described in this document.

Table 1: Polymer types and value chains considered

Polymer types Value chains


Fossil-based Bio-based

PU/PUR PLA Packaging

PS, PS-E, PS-EI Starch-based Building & Construction

PE, PE-LD, PE-LLD, PE-HD, PE-MD PHA/PHB Automotive

ABS-SAN TPS Electrical & Electronics

ABS-HIPS PEF Household, Leisure & Sports

PET PBS/PBSA Agriculture

PP PT Medical

PA Bio-PET Healthcare

PVC Bio-PE Textile

PMMA Bio-PP

PBT Bio-PA

POM Bio-PUR

PTFE

DCPD CO2 /CO-based

PC PPC

PU
Fibre Reinforced Polymer
PC
(FRP) matrices
Epoxy PEC

PU PE

12 • SUSTAINABLE PLASTICS STRATEGY


Table 2: CPA Strategic R&I needs common to 3 or more industrial sectors

CORRESPONDANCE WITH SUSCHEM/


RELEVANT TO
CPA R&I PRIORITY PLASTICS EUROPE/EPC4/EUPC CHAPTER
INDUSTRIAL SECTOR
and priority

Chemical and physical Packaging, Sustainable by Recycling:


recycling process automotive, 4.1 Chemical recycling of plastic waste by pyrolysis
development construction, 4.2 Chemical recycling of plastic waste by
agriculture and EEE gasification
4.3 Chemical recycling of plastic waste by
depolymerization/solvolysis
4.4 Recycling by dissolution of multi-polymer
systems
4.5 Mechanical recycling

Chemical and Packaging, Sustainable by Recycling:


physical recycling automotive, 3. Sorting and separation
purification/separation construction,
technologies agriculture and EEE

Polymer chain Packaging, Sustainable by Recycling:


recycling stability automotive, 1. Plastic stream preparation (waste pre-
construction, treatment)
agriculture and EEE 2 Plastic waste preparation

Quality control Packaging, Sustainable by Recycling:


and consistency of automotive, 3.2 Improve separation
recyclate construction,
agriculture and EEE

Develop and Packaging, Sustainable-by-Design:


standardise methods automotive, 1.5 Addressing micro and nano-plastics
for traceability construction,
agriculture and EEE Sustainable by Recycling:
1. Plastic stream preparation (waste pre-
treatment)
2. Plastic waste preparation
3. Sorting and separation

Improved recycled Packaging, Sustainable-by-Design:


materials properties automotive, 1.1 Extend lifetime
construction, 1.3 Increase recyclability
agriculture and EEE 1.4 Biodegradation

Better separation of Packaging, Sustainable-by-Design:


different plastics automotive, 1.3 Increase recyclability
construction, 1.4 Biodegradation
agriculture and EEE Sustainable by Recycling:
1. Plastic stream preparation (waste pre-
treatment)
3. Sorting and separation

Detect and separate Packaging, Sustainable by Recycling:


substances in waste automotive, 1. Plastic stream preparation (waste pre-
construction, treatment)
agriculture and EEE 2. Plastic waste preparation
3. Sorting and separation

SUSTAINABLE PLASTICS STRATEGY • 13


Table 3: CPA Specific R&I needs common to 2 or less industrial sectors

RELEVANT TO CORRESPONDANCE WITH SUSCHEM/


CPA R&I PRIORITY INDUSTRIAL PLASTICS EUROPE/EPC4/EUPC research
SECTOR priority

Recyclable biobased polymers Agriculture Sustainable-by-Design:


1.3 Increase recyclability
1.4 Biodegradation

Alternative Feedstock:
1. Agriculture and forest biomass waste raw
materials

Resistance to sun and crop Agriculture Sustainable-by-Design:


input 1.1 Extend lifetime
1.3 Increase recyclability
1.4 Biodegradation
2.1 Design for dismantling
2.2 Decrease material usage

Collection schemes Agriculture Sustainable-by-Design:


2.1 Design for dismantling
2.2 Decrease material usage

Sustainable by Recycling:
1. Plastic stream preparation (waste pre-
treatment)
2. Plastic waste preparation
3. Sorting and separation

Waste preparation and pre- Agriculture Sustainable by Recycling:


treatment 1. Plastic stream preparation (waste pre-
treatment)
2. Plastic waste preparation

Biodegradability in soil Agriculture Sustainable-by-Design:


1.3 Increase recyclability
1.4 Biodegradation

Plastic separation Automotive Sustainable by Recycling:


and EEE 1. Plastic stream preparation (waste pre-
treatment)
2. Plastic waste preparation
3. Sorting and separation

Using recyclates in a middle Construction Sustainable-by-Design:


layer 1.3 Increase recyclability
2.1 Design for dismantling

Pre-cleaning of waste Construction Sustainable by Recycling:


1. Plastic stream preparation (waste pre-
treatment)
2. Plastic waste preparation
3. Sorting and separation

14 • SUSTAINABLE PLASTICS STRATEGY


RELEVANT TO CORRESPONDANCE WITH SUSCHEM/
CPA R&I PRIORITY INDUSTRIAL PLASTICS EUROPE/EPC4/EUPC research
SECTOR priority

Understanding of kind of Construction Sustainable-by-Design:


products could use recycled 1.3 Increase recyclability
materials (design FROM 2.1 Design for dismantling
recycling) 2.2 Decrease material usage

R&I for packaging and electrical Packaging Sustainable-by-Design:


and electronic equipment > and EEE 1.2 Material usage vs. performance
FOOD CONTACT

Sensor and detection Packaging Sustainable by Recycling:


technologies and EEE 3. Sorting and separation

Post-consumer plastic waste Packaging Sustainable-by-Design:


recycling technologies meeting and EEE 1.3 Increase recyclability
food contact qualification 2.1 Design for dismantling
2.3 Monolayer pouch and inmold labelling
2.4 Refillable and recyclable PET bottles

Delamination technologies Packaging Sustainable-by-Design:


1.3 Increase recyclability
2.1 Design for dismantling
2.3 Monolayer pouch and inmold labelling

Sustainable by Recycling:
1. Plastic stream preparation (waste pre-
treatment)

SUSTAINABLE PLASTICS STRATEGY • 15


Sustainable-by-Design

The Sustainable-by-Design concept aims to give rise to health and environmental problems.
integrate safety, circularity and functionality The development of a common understanding
of materials and products. It embraces the and the transition to safe- and sustainable-by-
economic, environmental and social pillars design materials, including plastics, is a societal
of sustainability while maximising the urgency.
opportunities offered by the materials and
chemicals industries. Sustainable-by-Design calls 1. Material design
for an innovative systemic approach throughout
the full material cycle, from design to end of
This section elaborates on the technologies
life. Industrial relevance, societal empowerment
applied at the material design phase, aiming to
and regulatory preparedness are essential to the
improve the material sustainability.
successful implementation of the Sustainable-
by-Design concept as also recently addressed by 1.1. Extend lifetime
the European Commission.11
a) Specific Challenges: Repairing and
The key components of Sustainable-by-Design preserving polymer properties.
plastics embrace safe by design concepts
(i.e. plastics free from hazardous chemicals, Technologies aiming at reducing end-of-life
addressing micro and nano-plastics), circular plastic waste and saving resources by extending
and resource efficient materials (i.e. durable, the lifetime of polymer materials and hence
re-usable and recyclable; easy to dismantle and the article lifetime. Repairing and preserving
with the use of alternative resources including polymer properties using i.e. self-healing
plastic waste and biomass). Sustainable- polymers is a solution in a medium long-term
by-Design plastics need to offer adequate range.
performance and functionalities (i.e. lightweight,
Scope:
mechanical strength) while also enable their
sustainable production at industrial scale Several applications of polymers need
and drive the opening of new markets and to maintain their structural and physical
business models enhancing social awareness properties for long periods of time, and often
and investments for Sustainable-by-Design withstand extreme conditions, erosion and
innovation. other wear mechanisms. Structural repair is
a major challenge particularly for advanced
This section addresses technologies at composites in aerospace, windmill or automotive
the material or article level that allow the applications. Different defects are initiated
dismantling of plastic products and the during manufacturing and in-service use.
capabilities to recycle the polymers they Delamination and matrix cracking which cannot
are made of. The simulation, material and be repaired with existing technologies can occur
manufacturing steps are the key stages to which leads to high scrap rates, up to 20-30%
reach an optimum of sustainability by design. depending on the part complexity. The solutions
Moreover, plastic production, use and disposal proposed to address such specific challenges
may result in the release of chemicals which may comprise self-healing polymers based on
thermally reversible Diels-Alder reactions,
11 Plastics Sustainable-By-Design. EU Factsheet
https://op.europa.eu/en/publication-detail/-/publication/e1e5fcad-fc84-
11ea-b44f-01aa75ed71a1/

16 • SUSTAINABLE PLASTICS STRATEGY


disulphide-thiol exchange reactions, repair increase article lifetime, it is desirable to limit
polymers based on dynamic hardeners, etc… the degradation due to the ageing mechanisms
Further improvements are possible applying and improve the ageing performance. Different
more accurate and effective signals to trigger approaches have been developed like the
the healing process when needed (e.g. UV, addition of chemical additives in the plastic
pH, temperature). Accelerating the exchange or composite matrix and their controlled
reactions using linkers in order to develop more application in relevant areas throughout the
accurate and effective detection signals, novel matrix structure. To control the improvements on
repairing technologies based on the reshuffling the nano-reinforcement and polymeric matrix
of chemical bonds by applying heat and interface, there is a need to improve chemical
pressure should also be considered. compatibility and dispersion stability as well as
increasing mixing efficiency when necessary.
Technology Readiness Level
Scope:
Activities are currently at TRL 3 and shall achieve
TRL 5-6 at the end of the project. Additives and nano-additives show potential
in improving polymers performance by
adapting each material to its application
Expected Impact: requirements. Material properties at the nano-
Significant reduction of the time and and microstructure level can be programmed by
resources for material development and changing their morphology in order to control
upscaling with respect to established and adapt them to the different conditions
conditions, with a return on investment of (e.g. improving barrier properties, increasing
less than 5 years for specific market sectors. the diffusion path for gases and water, adjust
Quantifiable enhancement of the quality stiffness, rigidity, sealability). Recipe ingredients
and reliability of products, with consequent may be optimised to adjust material properties
improvement of product lifetime and to meet environmental and application
associated environmental and economic requirements thereby extending its service
benefits. lifetime without undermining the efficiency and
quality of the recycling process.

b) S
 pecific Challenges: Improving
ageing.

External conditions such as extreme temperatures,


pressure, UV exposure, humidity, mechanical
stress and others can degrade material properties
and decrease their performance. In order to

SUSTAINABLE PLASTIC STRATEGY • 17


Technology Readiness Level The application of available or emerging
Activities are currently at TRL 4-5 and shall technologies (Chemical Vapor Deposition,
achieve TRL 6-7 at the end of the project. Physical Vapor Deposition, nanolithography)
to get smart surface design for all types of
bio-based polymers or get a good control of
Expected Impact: the surface or the internal polymer structure
through processes shall be contemplated. The
At least 20% faster verification of material
development of active bio-based packages
performances is expected for highly
to meet the needs of both fresh and pre-
promising applications. At least 20%
treated food applications for specific flexible
improvement in industrial productivity,
and rigid food packages in diverse market
reliability, environmental performance,
segments is required as well as the scale up of
durability, and reduction of life-cycle costs of
existing laboratory level of smart functionally
these materials.
technologies to prototype pilot scale level.

Technology Readiness Level


c) S
 pecific Challenges: Improving
Activities are currently at TRL 5 and shall achieve
ageing performance of bio-based
TRL 7 at the end of the project.
materials.

To improve the final properties of bio-based


materials and their basic surface properties Expected Impact:
without chemical treatment and use of liquids. At least 20% improvement of materials
One solution is based on single-polymer performance is expected for promising
approach and a confined crystalline structure applications. At least 20% improvement
of PLA or PHA with low gas permeability. This in industrial productivity, reliability,
could improve barrier, anti-fog, anti-fouling and environmental performance, durability, and
antistatic surface properties of those bio-based reduction of life-cycle costs of these bio-
materials. based materials.
Scope:
Different approaches have been developed
like the addition of chemical additives in the
bio-based plastic or composites matrix or
a good control at nanoscale of the matrix
structure. Additives and nano additives can
improve polymer performances by adapting
each material to its application requirements.

18 • SUSTAINABLE PLASTICS STRATEGY


1.2. Material usage vs performance option is making composites from carefully
chosen waste plastics.
Technologies that aim at decreasing material
usage while maintaining or improving the Technology Readiness Level
mechanical behaviour of existing materials. Activities are currently at TRL 5 and shall achieve
TRL 8 at the end of the project.
a) S
 pecific Challenges: Improve
performance. Expected Impact:
Growing demand for high performing materials At least 20% improvement in industrial
and more complex products increases the need productivity, reliability, environmental
for material usage, in terms of quantity and performance, durability, and reduction
variety. of life-cycle costs of these materials, at
least 15% improved industrial process
Scope:
parameters and 20% faster verification of
Composites can improve the material materials performance for highly promising
performance by providing high strength and applications are expected.
stiffness without undermining the aesthetical
appearance of the final product. Composites, as
well as multilayer materials require less amounts 1.3. Increase recyclability
of material for a given functionality and have
the potential to perform as well as, or better Technologies aiming at increasing inherent
than, conventional materials such as metals recyclability of polymers.
decreasing thus the final amount of material
Specific Challenges:
use. The innovation would be in new precursor
formulations, improved reinforcement and Common petrochemical-derived polymers such
manufacturing technologies to reduce costs. as polyethylene and polypropylene take many
The development of automated manufacturing years to break down as their carbon chains do
technologies is required to reduce cycle times not contain chemical groups that could act as
and cost of manufacturing. With respect to the obvious ‘break points’ for chemical or biological
circular economy approach, the improvement of reactions. These polymer chains form crystalline
separation of dissimilar materials and recyclate regions that confer excellent thermal and
properties are real needs. A complementary mechanical properties, making the material
extremely durable, but also less amenable

SUSTAINABLE PLASTIC STRATEGY • 19


to degradation after use. In order to address of dissolution recycling. The development of
these issues new plastics shall be designed to new generation of compatibilizers could offer
facilitate recycling12. This could allow to produce a wider range of potential compatible mixture
materials able to ‘degrade on demand’, with the of polymers from such multicomponent
degradation products being chemically recycled products. The compatibilizer can upgrade
to polymer or transformed into other building mechanical properties of waste streams through
blocks. New plastics capable of maintaining compatibilization of contaminant and/or the
desirable material properties for re-use should different phases. Also, separation of layers
also be targeted, for example through self- based on specific adhesives or additives could
healing processes. Recycling of multi-layer facilitate higher purity of the output. Whenever
films, or recycling of waste from electrical and possible, recyclability can be further enhanced
electronic equipment (WEEE) is difficult due to using surface nano-textures replacing additives
the multiple types of polymers included in such for certain functionalities and using additives
products and the difficulty in separating them. to reduce the need of multilayers. The use of
waxy products from plastic waste pyrolysis as a
Scope: compatibilizer could serve two purposes:
The transformation from multicomponent a) a useful outlet for pyrolyzed plastic waste and
(multilayer or blend of polymers) compositions b) an increased recyclate quality. These would
to one compatible multiphase mixture which increase the recycling rate. Plastic containing
can be more easily reprocessed by incorporating additives which protect the polymer structure
compatibilizers is one of the possible options. can also be contemplated. Another approach
Homoplastic composites, where a single polymer for thermoset products could be based on
chemistry performs multiple functions through chemically modified polymers (e.g. PS), which
control across chain length could allow a can facilitate the thermal degradation without
single type of material used for the packaging, affecting mechanical properties. Bio-based
adhesive, and barrier layer that would simplify compatibilizers and additives based on natural or
recycling. Multi-layer materials can have an recyclable raw materials that can further reduce
overall benefit with the parallel deployment the carbon footprint from a life cycle perspective
can be an option too. Some of the proposed
12 Beyond Mechanical Recycling: Giving New Life to Plastic Waste solutions are illustrated in Figure 1.

Figure 1:
Common polymer additives used to
improve polymer recyclates
(Source: Mechanical Recycling of Packaging Plastics:
A Review13)

13 Mechanical Recycling of Packaging Plastics: A Review

20 • SUSTAINABLE PLASTICS STRATEGY


Technology Readiness Level and development of standards is needed.
Furthermore, environmental claims regarding
Activities are currently at TRL 3-5 and shall
biodegradability or compostability should
achieve TRL 6-8 at the end of the project.
comply with appropriate standards such as ISO
18606 or EN 13432 and EN 14995.

Expected Impact: Scope:


Improvement of the recycling yield, the Careful examination of standards and labelling
purity of waste and the quality of the of polymers will ensure a proper understanding
recyclable plastic. Increase the use of of terms such as recyclable, compostable,
recyclable polymers in second-generation biodegradable. Research is needed to
products. understand the biodegradation of polymers in
a broad range of industrial and environmental
conditions, how it is influenced by humidity,
pH, temperature, solvent, catalyst, light, micro-
1.4. Biodegradation organisms and enzymes, as well as the interplay
between these factors in a range of real processes
Specific Challenges: and environments. The fate and impact of
the degradation products must also be fully
Biodegradation depends on the interplay considered, as should any additives in these
between the materials properties and the plastics. In parallel, strategies to understand and
environmental conditions. Biodegradable improve the biodegradability of the currently
plastics may bring benefits over conventional non-degradable polymers are of high relevance.
plastics in applications where it is challenging Environmentally degradable polymers will
to collect a particular products from the need to be competitive in performance and
environment after use (e.g. agricultural mulch cost to become scalable, efficient, economical,
films), where it is difficult to separate plastic and sustainable. Different biodegradable
from organic waste (e.g. compostable food polymers are needed, tailored towards specific
bags) or for certain applications in the medical applications. Compostable films can have a
and personal care fields. For these applications, shelf life of one year, with identical mechanical
the key is to make separate collection of bio- properties of non-compostable films and can
waste. Such biodegradable polymers should not be converted through extrusion. At their end
be considered a substitute for recycling, or an of life, they can be composted domestically,
excuse to dispose of plastics in the environment. achieving more than 90% disintegration in
Life time of biodegradable plastics in different less than 6 months. Biodegradable polymers
conditions are key, but so far there is a lack of
experimental data to predict breakdown in
complex natural environments. Harmonisation

SUSTAINABLE PLASTIC STRATEGY • 21


can be produced from bio-sources as well as 1.5. Addressing micro and nano-
fossil sources. Different approaches towards plastics
biodegradation have a high potential such as
the enzymatic route. The design of material-
Specific Challenges:
adapted bacteria is another approach, as some
microbes can degrade plastics like PP, PE, PS to Analytical methods are needed to study
shorter hydrocarbons. Additionally, efficiency of micro and nano-plastics of different types and
microbial plastic degradation can be enhanced shapes and at different size and time scales.
with metabolic engineering. Whatever the These include high-throughput spectroscopy
solution, there is a need to get good repeatability, and microscopy techniques that generate
purity of monomer, duration, thermal stability. In reproducible data about the size distribution,
fact, still some progress is necessary to improve structure and properties of microplastics in the
properties and control the biodegradation which environment. Predictive models can simulate
needs to comply with internationally recognised the transport and distribution of micro-plastics,
biodegradability standards. which will help to understand the location, fate
and persistence of plastic waste and they may
Technology Readiness Level also allow to predict the environmental impact of
Activities are currently at TRL 4 and shall achieve new plastics before they get to market. A proper
TRL 7 at the end of the project. understanding of the process of formation and
degradation in the environment of secondary
Expected Impact: micro-plastics and nano plastics, across a range
Reduce the environmental impact associated of environments including soils, freshwater,
with the end-of-life phase of developed oceans as well as the health effects of micro
packaging products by at least 30 % compared and nano-plastics is essential. Most of the
with existing products for similar applications. plastic waste is generated on land, but plastic
Improve sustainability performance (in terms of pollution ends up in the marine environment,
biodegradability, compostability or recyclability) and plastic particles are reported to occur from
compared with existing plastics. Develop at tropical to polar areas and from beaches to deep-
least two applications utilising ‘outperforming’ sea sediments and even in remote mountain
biodegradable polymers, with improved lakes. Plastic particles have been found in the
properties compared to the current alternatives atmosphere and in terrestrial ecosystems,
based on fossil-based counterparts. such as urban and agricultural soils. The size
of a piece of plastic is an important factor in
determining its impact on the environment.
Possible risks associated with plastic particles
cannot be generalized because they comprise
a very heterogeneous group of particles that

22 • SUSTAINABLE PLASTICS STRATEGY


vary in polymer composition, additive content, burdens. Numerical modelling is one of the
size (macro-plastics: larger than 2.5 centimetres, key tools to gain insight into the distribution of
meso-plastics: 5 millimetres to 2.5 centimetres, micro-plastics in the nature. A series of numerical
microplastics: 1 micrometres to 5 millimetres, simulations have been constructed, with focus
nano-plastics: smaller than 1 micrometre), in marine environments, including the effects
shape, ageing state, and consequently in their of currents, waves, and wind as well as a series
physicochemical properties. of processes that impact how particles interact
with ocean currents, including fragmentation
Scope: and degradation highlight the importance of
Technologies to analyse and quantify micro- knowing accurately the sources or entry points of
plastics in the environment and study their marine plastic debris, including potential sources
distribution and pathways in the environment as that have not been incorporated in previous
well as their mechanical, chemical and biological studies (e.g., atmospheric contributions). These
degradation from macro- to meso-, micro- and numerical models should be contrasted with
nano-plastics. Micro-plastics analytical processes experimental data, further improved and shall
include sampling, extraction, quantitation and integrate other environments such as rivers,
quality assurance/quality control (QAQC), each water treatment plants, agricultural fields or
of them requiring further method development urban agglomerations. Secondary micro-plastics
and harmonisation. The most common approach are derived from the breakdown of larger plastic
to extracting micro-plastics is filtration and debris, both at sea and on land. Over time,
density separation. Following extraction, visual physical, chemical, photochemical and biological
counting with an optical microscope is the degradation might further degrade them to be
most common technique for quantifying micro- smaller in size converting them into nano-plastics
plastics. But this technique is labour intensive that can reach the food chain or be completely
and prone to human error. Spectroscopic degraded to CO2. The kinetics of these processes
approaches (FTIR; Raman) are the most applied under different environmental conditions is
techniques for identifying polymers collected not known yet and it is essential to predict and
through visual sorting. Improvements and minimize the accumulation of microplastics in
harmonisation on size fractions, sampling nature and reduce their impacts on humans and
approaches, extraction protocols and units the environment.
for reporting plastic abundance would help
comparison of data generated by different
research teams. Inter-laboratory proficiency
testing is recommended to give an indication
of the variation and reliability in measurements
reported in the scientific literature that may
be under- or overestimations of environmental

SUSTAINABLE PLASTIC STRATEGY • 23


Technology Readiness Level Scope:
Activities are currently at TRL 4 and shall achieve It is common that component parts of a
TRL 7 at the end of the project. same product have different characteristics
and lifetimes. Dismantling considerations,
not anticipated at the design stage, result in
materials being discarded before reaching their
Expected Impact:
end-of-life. Coupled with the growing complexity
Insight and better understanding of the of products, materials that otherwise are easily
environmental footprint associated with the recyclable lose most of their potential quality
end-of-life phase. due to the incapacity of separating mono-
material parts from each other. Design product
parts to incorporate reversible adhesives could
allow a better management of used articles
2. Article Design through easy disassembly (i. e. adhesives based
on Diels-Alder reaction, dithiol or disulphide
exchange reactions).
This section elaborates on the technologies
applied at the material design phase, aiming to Technology Readiness Level
improve its overall circularity.
Activities are currently at TRL 4 and shall achieve
2.1. Design for dismantling TRL 7 at the end of the project.

Specific Challenges: Expected Impact:


Most plastics are designed to be durable and New business opportunities for the recycling
to maintain their structure and performances industry across Europe, especially in the
during their useful life. But in sectors such area of composites and plastics where the
as packaging this durability can give rise to challenge is high. Proposals should prove
pollution, because discarded waste plastic can that the target products are recyclable or
persist in the environment for years or decades. compostable in various environments to
Allowing for plastic articles to be reused multiple reduce their overall environmental footprint.
times in refillable packaging represent a more This will make their production and use
sustainable option than providing disposable more circular.
packaged articles. Technologies aiming at easing
dismantling of products containing plastic with
the goal of increasing the volume and purity of
the collected and sorted plastic waste, resulting
in higher quantities and quality of the recycled
or reused material shall be put in place.

24 • SUSTAINABLE PLASTICS STRATEGY


2.2. Decrease material usage
Expected Impact:
Specific Challenges: Reduce the environmental footprint
The growing complexity of products, together associated with the end-of-life phase of
with the wide variety of existing polymers, developed packaging products by at least
boosts the use of multi-material design in single 30 % compared with existing products for
applications. Designing a plastic to be durable in similar applications. Produce multifunctional
time, and reusable and/or recyclable (including product with a minimum of multilayer/
organic recycling) at the end of its life, is a major multimaterial structures. Multi-material
challenge. For some applications, designing structures emerged over the last decades
plastics to be more durable and longer-lived as highly efficient packaging material,
would be a more sustainable option and should combining such different features as:
be explored. Integrate environmental criteria Oxygen barrier, thermoformability, seal
and Life Cycle Assessment (LCA) methodology behaviour, water barrier, transparency, etc.
in design in order to minimise material use and There is currently no single material that
environmental impact is an essential need. The combines all those features. Hence, one shall
final weight and the multi-material optimisation not necessarily aim at avoiding multilayer
(the right material at the right place) need to be composites if these materials can be
addressed efficiently recycled.

Scope:
Replace multilayer structures by materials with 2.3. Monolayer pouch and in-mold
targeted thickness while ensuring the same labelling
performance level. Push and facilitate the use
of composite solutions based on polymers, Specific Challenges:
versus traditional solutions, e.g. based on metals.
A reduction of packaging waste and efficient
Design parts considering weight and multi-
use of resources are required by legislations in
material optimisation (use the right material
the EU. This can be achieved through weight
at the right place and optimise its form to
reduction of single use packaging. Light
limit weight, maximise resistance) Integrate
weighted containers are however difficult to
environmental criteria in packaging design
handle and especially tedious to decorate.
in order to minimise material use, e.g. mono-
For example, thin containers (pouches) are light
material design, whilst at the same time offering
weighted and can achieve weight reduction
the same or better functionality.
targets. However, their multi-layered structure is
Technology Readiness Level not suitable for the current recycling processes

Activities are currently at TRL 4 and shall achieve


TRL 8 at the end of the project.

SUSTAINABLE PLASTIC STRATEGY • 25


since they are pre-printed, laminated and 2.4. Refillable and recyclable PET
assembled into a pouch. To overcome this bottles
challenge, a recyclable monolayer (pouch)
with decoration (in-mold labelling) needs to be
Specific Challenges:
developed.
A reduction of packaging waste as well as the
Scope: minimization of a product carbon footprint
Demonstrations of the monolayer pouch are required under several legislations in the
prototype and in-mold labelling have been EU. The deployment of a PET refillable bottles
completed in some industrial production system could strongly support these targets as
settings. Both technologies are ready to be the excessive CO2 emission can be minimized
used in the industrial scale. As a next step, the with PET material (e.g. in comparison to refillable
technologies should be installed in actual filling glass bottles). Moreover, PET is a material that
lines for an operational environment proof of can be efficiently recycled with existing recycling
concept. infrastructures.

Technology Readiness Level Scope:

Activities are currently at TRL 7 and shall achieve Establishment of PET refillable products with
TRL 9 at the end of the project. special PET grades which are resistant to the
high temperature washing lines.

Expected Impact: Technology Readiness Level

The development of monolayer pouches Activities are currently at TRL 6 and shall achieve
and in-mold labelling technologies will TRL 9 at the end of the project.
offer weight reduced packaging (i.e. PET/
PE) to the market fulfilling the product
Expected Impact:
requirements with a 20 to 25% weight
reduction. In parallel, the technologies will Single use plastic packaging is mainly
support the envisaged recycling targets used in many beverage markets including
of the Packaging and Packaging Waste the milk market. Since the PET recycling
Directive14 (PPWD) and the objectives of the infrastructure is already established, if
European Green Deal and the new Circular the reuse solution is communicated to
Economy Action Plan (CEAP) to ensure that the market, at least 20% of the market is
“all packaging on the EU market is reusable expected to accept PET refillable bottles.
or recyclable in an economically viable
way by 2030”. It will also contribute to the
objective of European Strategy for Plastics to
ensure that by 2030 “all plastics packaging
placed on the market can be reused or
recycled in a cost-effective manner”.
XXX14

14 https://ec.europa.eu/environment/waste/packaging/ongoing-re-
view-packaging-waste-directive_en.htm

26 • SUSTAINABLE PLASTICS STRATEGY


SUSTAINABLE PLASTICS STRATEGY • 27
Sustainable Recycling

1. Plastic stream preparation non-volatile, contaminants from the polymer


mass. The efficacy of such approach can be
(waste pre-treatment) enhanced by employing sensors to detect and
remove contaminants of different nature (stones,
particles, additives) and sizes. The development
Specific Challenges: of sensors with higher sensitivity/precision and
Plastic articles to be recycled contain solid lower cost would allow a better treatment of the
and liquid contaminants that result from their films and a higher quality of the final recycled
specific use and history. These contaminants can materials. As far as the removal of odour or ink
highly affect the quality of the recycling output is concerned, technologies like supercritical
and are not easily removable. Besides, they may extraction, water-based oxidant treatments,
convey notable odours that do not modify the use of a demulsifier in the washing step or
plastic physical or chemical properties, yet it biological treatments are especially attractive.
can make the recycled materials unfit for some But their implementation still requires further
specific uses. The contamination of used farm developments to reduce their respective costs.
films is a typical example: In mulching, the Technology Readiness Level
contamination of the plastic films can represent
up to 70% of the volume collected what leads to Activities are currently at TRL 5 and shall achieve
significant additional costs in terms of recovery TRL 7/8 at the end of the project.
operations and treatment. In the specific case
of plastics used in packaging, an additional
challenge resides in the removal of the inks Expected Impact:
which are often directly printed on the polymer Meeting the EU’s circular economy and
films. Removal of these inks is difficult, costly and environmental targets while demonstrating
energy intensive. As a result, plastic waste with a clear benefit, i.e. more efficient or
printed inks are often recycled as is and used in economic than the state-of-the-art in order
lower value products such as plastic shopping to enable market uptake in the short to
bags. To decrease this value loss, it is desirable to medium term. Reduction of the carbon
develop cost and energy efficient technologies footprint of the corresponding products by >
for ink removal. 30% (based on a full LCA) and demonstrate a
potential reduction in landfill waste volume
Scope:
by > 50%.
Solutions applied through continuous processes
are especially attractive. For example, the use
of solvating fluids during continuous extrusion
allows to treat flowable polymer mass by
solvating and extracting organic, and especially

28 • SUSTAINABLE PLASTICS STRATEGY


2. Plastic waste preparation Technology Readiness Level
Activities are currently at TRL 5 and shall achieve
TRL 7 at the end of the project.
Specific Challenges:
The separation of the various polymers Expected Impact:
comprised in a stack is often difficult and still
Meeting the EU’s circular economy and
needs to be performed manually most of
environmental targets while demonstrating
the time. Robotics could help and should be
a clear benefit, i.e. more efficient or
optimized. Especially after grinding, it is even
economic than the state of the art in order
more difficult to separate polymers, which
to enable market uptake in the short to
results in contaminated input streams in the
medium term. At least 20% improvement
recycling process. Ensuring high purity and high
in industrial productivity, reliability,
value recyclate requires to separate the polymers
environmental performance, durability,
in the stack in order to allow a proper sorting of
and reduction of life-cycle costs of these
the materials.
materials Demonstrate a potential reduction
Scope: in landfill waste volume.

The development of integrated solutions of


grinding machinery with thermal, chemical, and
magnetic separation should be considered and
tested in pilot lines. The increase of production
3. Sorting and separation
volume of the mills using cold base technology
could offer some leverage upon the overall Specific Challenges:
energy consumption of the mill internals and
balance of systems material flow. Besides, the The composition of waste streams of polymer
use of detection systems for ground particles articles can have high variations. Typically,
from agglomerates in order to better separate household plastic waste can be composed of a
coarse particles and consequently return them stream of rigid bottles (PET and PE) to streams
as rejects into the mill. Besides the use of mill, containing additional trays, pots and films, with
employing supercritical liquid could permit to a wide range of different polymers. Rigid plastics
separate the polymers in a stack in an efficient can contain films which are often multi-layered,
manner.

SUSTAINABLE PLASTICS STRATEGY • 29


and hence difficult to separate. Bottles can Scope:
be covered in PVC sleeve labels, or PET grade
In the case of wet sorting, approaches like
materials need to be separated from bottles
hydrocyclone and flotation still require further
and trays. Furthermore, applications polymers
developments to i) strongly reduce their
are often mixed with other materials (e.g. wood,
cost and ii) offer a better selectivity on light
metals,), and can contain legacy additives, such
polymers and polymers having the same density
as brominated flame retardants (BrFR) but also
respectively. Process to eliminate contaminants,
organic additives such as plasticizers and dyes.
sorting for higher quality batches together with
The sorting and separation of the polymers
selective precipitation should be considered. In
according to the type of additive they contain
the case of dry sorting, polymer identification
is difficult. In order to recycle efficiently these
methods based on multi-dimensional column
streams, the sorting of polymer articles by their
chromatography based technique either
constituent materials is of primary importance.
with Ultra Violet (UV), Mass Spectrometry
This sorting ensures a minimum of waste and a
(MS) or Nuclear Magnetic Resonance (NMR)
high quality and purity product. This sorting is
detection or based on spectroscopic, on optical
particularly tedious for small or light plastic items
spectroscopies like Visible (VIS), Near Infrared
due to their specific geometry, morphology,
(NIR) and RAMAN spectroscopies as well as
and low weight. The two main routes currently
Mid Infrared Thermography (MIR-T) and Laser-
employed, namely wet and dry sorting, still
Induced Breakdown Spectroscopy (LIBS) would
require further technical enhancements and
benefit from the improvement of optical
cost reduction to ensure a large deployment
sensors. A better spatial recognition would
and an increase of the overall recovery yield of
allow to automate sorting in higher speeds,
plastics. Special attention should be given to
a higher accuracy and lower detection limits
both the construction and the packaging sector
and it would permit to identify legacy additive
as well as to bio-based polymers for which the
(like brominates) at lower concentrations and
current level of recycling is not as high as for
the detection of organic additives. X-ray based
fossil-based polymers due to the lower volumes
technics like X-Ray transmission imaging (XRT)
in the market. The final goal of recycling being to
and Energy Dispersive X-ray fluorescence (XRF)
reduce the environmental impact, the solutions
could be applied to smaller recycling units if
developed should avoid using consumables,
their cost were reduced. Moreover, it would be
which generate a negative impact on the
beneficial to increase the detection capabilities
environment. High level economic, cost benefit
of these tools in order to identify a wider range
analyses for various options should exist to
of additives and increase the speed of sorting.
come to best overall approach on separation
Terahertz spectroscopy offers interesting feature,
vs recycling options, i.e. it is not always best to
although the plastic optical recognition needs
get monostreams, while other options exist for
some further improvement. When tracers are
processing of mixed streams.
used, fast and low-cost detection technics to

30 • SUSTAINABLE PLASTICS STRATEGY


identify precisely the articles containing the said losses of material value. The identification of
tracer should be developed up-front. All these the different types of polymers among plastic
technics should be coupled to enhanced sorting waste is not efficient enough due to the variety
mechanisms (air valves, robotic handling), of colours, properties and shapes. Multilayer
and should be tested in pilot scale. Artificial materials, dark, and especially black coloured
intelligence (AI) algorithms to reproduce human plastics and compostable plastics are especially
recognition could yield the fabrication and use challenging when it comes to detection, sorting
of AI robot to replace hand pickers. LCA and and separation. Some mixed plastics streams
Life Cycle Costs (LCC) should be considered could fit for a chemical recycling route, when
thoroughly in the evaluation of the sorted sorting would not give good quality or is not
materials. economically sound for mechanical recycling.

Technology Readiness Level Scope:


Activities are currently at TRL 5 and shall achieve A lot of technologies exist to sort plastic wastes
TRL 7/8 at the end of the project, although some and methods for object classification comprising
are for the time being at lower level in novel the steps of: Guiding a continuous stream of
fields (1 or 2, e.g. identification of organic legacy objects from a transport mechanism directly
additives) into an unsupported path, along which the
stream is fed through a detection region;
illuminating with a radiation band in a first
Expected Impact: direction; optically scanning the detection region
At least 20% improvement in industrial to detect electromagnetic radiation reflected
productivity, reliability, environmental by the object in the detection region15. Other
performance, durability, and reduction developments relate to sorting devices and
of LCC of the materials. Demonstrate a methods for sorting products that are moved
potential reduction in landfill waste volume. in a flow through an inspection zone, wherein a
light beam is moved over the flow so that that
all products are hit by the light beam in the
inspection zone. The light of this light beam is on
3.1. Improve sorting the one hand, directly reflected as of the point of
Technologies aiming at improving the inherent impact on the products, and, on the other hand,
sorting capabilities of polymers. it is reflected in a scattered manner as of a zone
round the point of impact by the diffusion of the
Specific Challenges: light beam’s light in the products16. Generally,
2

The wide variety of plastics and diversity of 15 European Patent Application EP3450029 A
16 European Granted Patent EP2234736 B1
characteristics make the plastic sorting process
very complex and inefficient, resulting in great

SUSTAINABLE PLASTICS STRATEGY • 31


the technics are based on surface markings
through diffraction gratings, fluorescent markers Expected Impact:
or UV markers.Tracer-based sorting (TBS) is
Create new technologies and business
an optical technology which detects specific
opportunities for the recycling industry
light signals emitted by the polymers, which
across Europe, especially in the area of
have previously been exposed to a certain
plastics where the challenge is high. Towards
light source, but the cost and efficiency need
100% recycled plastic after sorting stage.
to be improved. The optical response and
Demonstrate a potential reduction in landfill
sorting effectivity of different marker-plastic
waste volume by > 50%.
combination and thermal stability are some of
Meeting the EU’s circular economy and
the main bottlenecks with the recyclability of
environmental targets while demonstrating
plastics containing markers. The repeatability
a clear benefit.
and reproducibility need to be improved in
order to increase the sorting efficiency and the
quality of the recyclable plastics. The developed
solutions can be applied to packaging as well 3.2. Improve separation
as other applications. Progress in infrared
a) Specific Challenges: Polymers
detection does not require tracers. NIR based
separation.
state-of-the-art detection systems can reliably
sort styrenic plastics out of mixed plastic waste Technologies aiming at improving the inherent
and very precisely differentiate between HIPS separation capabilities of polymers. Multilayer
and GPPS, for example. Due to the fact that or multipolymer structures are some of the
styrenic compounds have a unique signal that plastic waste streams which need an efficient
enable easy and very precise sorting, NIR sensor separation in order to improve the quality of
technology enables easy sorting of polystyrene recycled plastics and to decrease the landfill.
from mixed post-consumer plastic waste using a Multilayer polymers and composites present
multi-step process. high limitations for separation, due to the
different properties of each component. For
Technology Readiness Level
example, the presence of dynamic chemical
Activities are currently at TRL 3 and shall crosslinks in thermoset fibre reinforced
achieve TRL 8. The range is broad based on polymer composites (TS FRP) enable the
the development of new concept (low TRL) or chemical separation of the matrix from fibre
improving existing ones. The particular NIR reinforcement.
sensor technology to sort polystyrene from
mixed post-consumer plastics waste has a TRL
of 9.

32 • SUSTAINABLE PLASTICS STRATEGY


Scope:
Expected Impact:
Cross Linked Thermosets (CLT) and FRP
composites cannot be recycled throughout Create new technologies and business
re-melting due to their cross-linked three- opportunities for the recycling industry
dimensional chemical structure and their across Europe, especially in the area of
complex structure, respectively. Combining composites and plastics. Demonstrate a
nucleation and low crosslinking degrees could potential reduction in landfill waste volume
be a way to facilitate the separation of fibres by > 50%; Reduction of the carbon footprint
from the polymer matrix. In multilayers or multi- of the corresponding products by > 30%
materials, polymers should be easily separated (based on a full LCA).
into relatively pure mono-material streams. First
reversible adhesives have been demonstrated
with different approaches (shape memory- and b) S
 pecific Challenges: Separation-
hydrogen bonding, with conductive nano- maceration of polyolefins and other
ferromagnetic particles, incorporating enzymes, polymers.
vitrimers). Such laboratory feasibility needs
to be scaled up and show improvements of Polyolefin represent around 50% of the total
the chemical separation process efficiency, by annual plastic consumption in Europe. PE
optimizing time, temperature and the type recycling however is still not allowing food
of solvents. In order to get a high efficiency contact at the PE streams coming back from
in separation, it is important to get adhesion the sorting centres. Furthermore, existing PE
between multi-materials with high bonding decontamination technologies generally require
and quick bond breaking/remaking capability very high energy inputs. To fulfil the European
whatever the process uses to produce the recycling targets as well as the climate neutrality
multilayer or multi-material products (extrusion, targets, a PE recycling and decontamination
injection, etc.). The optimisation of the process process needs to be developed to allow for food
and separated material for the reuse of contact PE with minimum energy input.
separated resins and fibre reinforcements is
Scope:
crucial for the final validation of the separation
efficiency. Certain treatments can cause a maceration
of PE. This affects the PE matrix and expands
Technology Readiness Level the space between PE-chains in the matrix,
Activities are currently at TRL 4 and shall achieve enabling the washing out of contaminants such
TRL 7 at the end of the project. as smelly components, short chain fragments
(oligomers) and additives and their degradation

SUSTAINABLE PLASTICS STRATEGY • 33


products. Selection of suitable conditions for PE
maceration that reaches a maximum expansion
4. Recycling technologies
without destroying the matrix of the plastic is
a first step. Further, the search of the optimal Plastic waste is one of the most complex
conditions for the “wash out” process and to material mixtures from a recycling perspective.
return the material to a processable state. Third, The recycling effort includes various methods,
the processing in a way that is environmentally such as chemical recycling (pyrolysis,
friendly and minimizes any carbon emissions. gasification, depolymerisation), mechanical
Fourth, limitation of residuals in the Polyethylene recycling, biotechnological processes as well as
to fulfil the European Food and Safety integrated upgrading options, like direct, ex-situ
Authority (EFSA) and the USA Food and Drug catalytic pyrolysis17. The most suited materials
3

Administration (FDA) requirements. for chemical recycling by depolymerisation


are the polymers with a ceiling temperature
Technology Readiness Level Tc (temperature at which the polymer
decomposes into its monomers) slightly above
Activities are currently at TRL 3 and shall achieve
the highest processing temperature. The de-
TRL 8 at the end of the project.
polymerization of polystyrene, PMMA and PET
is advantageous since they are mass-polymers
having a “benign” ceiling temperature Tc, which
Expected Impact: is slightly below 400 °C in case of PS and HIPS.
The aim is to find a way to bring back the The de-polymerization of Polystyrene (HIPS and
PE for industrial re-use. This would mean GPPS) works with high yield and selectivity and
increasing the recycling rate of PE in line represents a technology/material combination
with the EU regulation. The successful for full circularity, enabling continuous recycling
project would affect the HDPE recycling rate loops. By depolymerization, Polystyrene is easily
dramatically since it would bring back rHDPE reversed into its constituent monomer at high
for use in food contact application areas or yield. The liquid state of the monomer facilitates
even open the possibility to use rHDPE from purification. The resulting recycled monomer
non-food origins for packaging in the food is identical to the virgin monomer and can be
industry. It would mean treated HDPE from polymerised again to virgin quality polystyrene
health care, home care and other non-food enabling all applications, including food
application can be brought back to these contact. At the ceiling temperature, polymers
markets, but without any of the restrictions decompose into their monomers, and a Tc in
of colour and smell. If the HDPE maceration a.m. range allows to rapidly produce Styrene,
is successful, this would open the way to with the upside potential of maximizing yield by
work on recirculation of LDPE and most of
17 Effect of catalyst contact mode and gas atmosphere during catalytic
the other PE species back into their original pyrolysis of waste plastics
https://www.sciencedirect.com/science/article/abs/pii/
markets. Due to the absence of colour, smell S0196890417302820
and viscosity disturbing elements they could
be used as “drop in” chemicals.

34 • SUSTAINABLE PLASTICS STRATEGY


optimization of reaction conditions, especially waste-to-chemicals is considered18. Gasification
4

the reactor residence time at depolymerization processes (conventional gasification, plasma


temperature. Agilyx has demonstrated in their assisted gasification) which can possibly be
Tigard (Oregon) plant the depolymerization combined with biological and chemical post-
of PS into monomers. The current challenge treatment- show a wide TRL range while
is to scale up reactor and purification (e.g. currently pilot and demo plants are under
distillation) process. The waste-to-monomers investigation. Both recycling technologies
through solvolysis and/or de-polymerization is (pyrolysis and gasification) can recycle plastic
relatively developed for some polymers such waste to chemical building blocks. Especially
as PET, polyamides and PS as stated above but for polyolefins, these might be viable options.
lacking behind for polyolefins. The chemical Biotechnological processes for plastic waste
recycling of mass consumption plastics like PE valorisation are currently at TRL 2-3. They can
or PP result in defined added-value products be suitable to be combined with integrated
(such as waxes, oils). Pyrolysis technologies upgrading options, like direct, ex-situ catalytic
(conventional pyrolysis, plasma, microwave pyrolysis19.5

assisted pyrolysis, hydrocracking, pyrolysis with


in-line reforming) have a range of maturities
that go from concept all the way to small demo 18 Technologies for chemical recycling of household plastics –
A technical review and TRL assessment
plants depending whether waste-to-fuel or https://www.sciencedirect.com/science/article/pii/S0956053X20300465
19 Effect of catalyst contact mode and gas atmosphere during catalytic
pyrolysis of waste plastics
https://www.sciencedirect.com/science/article/abs/pii/
S0196890417302820

Figure 2: CO2-equivalent
emissions of different End of Life
treatment technologies applied
for several plastic-waste streams,
in relative emissions indexed to
incineration (100 wt%).
(Source: Beyond Mechanical Recycling: Giving New
Life to Plastic Waste20)6

20 Beyond Mechanical Recycling: Giving New Life to Plastic


Waste
https://onlinelibrary.wiley.com/doi/10.1002/anie.201915651

SUSTAINABLE PLASTICS STRATEGY • 35


More fundamental research is thus needed to Specific challenges:
reach a TRL 5 by 2030. The current CO2 emission
High energy-intensity required due to high
impacts of various recycling technologies is
process temperatures. Prevention and/or
depicted in Figure 2.
removal of hazardous and corrosive compounds
that can be generated during the process add
4.1. Chemical recycling of plastics
into process complexity, scalability and safety
waste by pyrolysis
challenges. Reactor fouling due to by-products
(ash). Dehalogenation procedures are necessary,
Scope: because the oils collected in single pyrolysis
Pyrolysis is conducted at relatively high process may contain halogenated organic
temperatures and in the absence of oxygen; it is compounds, which would detrimentally impact
particularly applicable to mixed polymer waste the reuse of pyrolysis oils. Recovery/trapping of
that is not suitable for mechanical recycling. dehalogenation (e.g. by basic salts formation)
During the thermal decomposition, complex is necessary, because these can be further
product mixtures of variable composition are reutilized as raw materials. Avoidance of hetero-
produced. The decomposition products, in atoms in the input-stream by tailor made sorting
the form of liquid oil or gases, are valuable as technologies that reject those. Increase available
fuel or chemical building blocks. A mixture of input volume by tailor made sorting, e.g. Mixed
unreacted carbon char and ash remain as a Polyolefins (MPO) fraction for pyrolysis. Develop
residual. Pyrolysis is possible with or without a catalytic pyrolysis to increase monomer recovery
catalyst. Pyrolysis of mass consumption plastics from solid plastic waste. Efforts are needed to
like PE or PP result in defined value products enhance catalytic performance by increasing
(such as waxes, oils). Catalytic pyrolysis seems a conversion efficiency, selectivity and stability.
viable route to plastic waste recycling. Integrated Feedstock blend of plastic waste should still be
Cascading Catalytic Pyrolysis (ICCP) maximises used for obtaining chemicals/materials.
product value with high Benzene, Toluene and Technology Readiness Level
Xylene (BTX) and aromatics yields, while being
energy positive (overall generates heat). Feed Activities are currently at TRL 6-7 and shall
composition flexibility is high due to orientation achieve TRL 8-9 at the end of the project.
on aromatics, i.e. mixed plastics can contain
aromatics-based polymers.

36 • SUSTAINABLE PLASTICS STRATEGY


treated neither by mechanical recycling nor by
Expected Impact: pyrolysis. Temperatures below 1000 °C can be
used to recover olefins from polyolefin plastic
Demonstrate a potential reduction in landfill
waste.
waste volume. Create new technologies
and business opportunities for the recycling Specific challenges:
industry across Europe, especially in the
areas where the challenge is high. Reduce The feeding system of waste material at high
the environmental footprint associated with pressure gasification in a continuous process
the end-of-life phase of plastic products. together with the high temperature/energy
requirements need attention. Fouling due
to by-products (ash and particles) as well as
the fact that tars, heavy metals, halogens and
alkaline compounds can be released within
4.2. Chemical recycling of plastic the product gas, causing environmental and
waste by gasification operational problems for some waste streams. If
the compounds are not properly separated and
Scope: recovered from the gas stream, this has to be
addressed. Moreover, process flexibility to cope
Gasification, as a thermochemical conversion
with short-term and/or long-term variation of
process, can be considered as a promising
waste feedstock composition is needed.
technology for the chemical valorisation of
plastics waste. The conversion process takes Technology Readiness Level
place at high temperatures - preferably higher
than 1000 °C - to produce tar-free synthesis gas Activities are currently at TRL 6-7 and shall
consisting mainly of H2 and CO. Ash remains as achieve TRL 8-9 at the end of the project.
a residual whereas the non-volatile carbon char
that would remain from pyrolysis is converted
Expected Impact:
into additional syngas. Partial oxidation of the
feedstock provides the energy to reach the high Demonstrate a potential reduction in landfill
temperatures. Therefore, oxygen is the preferred waste volume. Create new technologies
gasification agent. However, steam is also utilized and business opportunities for the recycling
to moderate temperatures in the process and industry across Europe, especially in the
to increase the yield of H2. Gasification has the areas where the challenge is high. Reduce
potential to be applied where waste cannot be the environmental footprint associated with
the end-of-life phase of plastic products.

SUSTAINABLE PLASTICS STRATEGY • 37


4.3. Chemical recycling of plastics the reprocessing). Large volumes of solvent
waste by depolymerization/ and significant energy are required for solvent
solvolysis recovery. Catalyst developments to improve
the depolymerization and to direct the process
towards specific building blocks are required.
Scope:
Only a limited number of polymers exist in
Depolymerization, as a conversion process a sizable amount that can be converted via
applied on plastic waste, can deliver substantial depolymerization, since one of the main issues
advantages by leading back to the initial building is the accessibility of suitable end-of-life material
blocks (monomers), with relatively high yield (preferably mono streams). Beside the process
and selectivity at relatively low temperatures. In optimization, collection systems and sorting
solvolysis, certain polar and semi polar solvents technologies are essential to access easy-to-
(e.g. water, alcohol, glycol) are excellent reaction process waste.
media for depolymerization of plastics. During
the decomposition, a mixture of monomers, Technology Readiness Level
oligomers, solvents and residues is created. The Activities are currently at TRL 4-5 and shall
addition of catalysts can improve the reaction achieve TRL 7 at the end of the project.
metrics. Polymers to be processed by solvolysis
are for example polyurethanes, PET, textile
polyesters. For composites, depolymerization Expected Impact:
also allows the recovery of fibres and fillers.
Create new technologies and business
In addition, circularity-by-design is expected
opportunities for the recycling industry
to facilitate plastic waste treatment by
across Europe, especially in the areas
depolymerization. Ultimately, solvolysis can also
where the challenge is high. Reduce the
be applied as a pre-treatment for separation of
environmental footprint associated with
certain polymer waste streams due to its high
the end-of-life phase of challenging plastic
chemical selectivity.
products.
Specific challenges:
Ensure constant input specification of end-of-
4.4. Recycling by dissolution of
life material. Critical pre-treatment step of input
multi-polymer systems
material. Robustness of process to deal with the
potentially high content of impurities of end-
of-life materials. Batch to continuous process to Scope:
improve competitiveness at commercial scale.
Efficient recycling technologies specifically
Downstream separation and purification of
suitable for multilayer materials need further
individual monomers after depolymerisation (as
developments. Approaches like immersion in
trace solvents and other contaminants influence
chemical solutions for separation and catalytic
depolymerisation processes require better

38 • SUSTAINABLE PLASTICS STRATEGY


understanding of key parameters like processing
conditions, the nature of the polymers treated, Expected Impact:
the nature of the potential contaminants, etc.
Demonstrate a potential reduction in
Besides, scale up from lab results to pre-pilot or
landfill waste volume by > 50%. Create new
pilot lines should be performed. The chemical
technologies and business opportunities
recycling technologies described in the previous
for the recycling industry across Europe,
chapters, as far as they can deal with mixed
especially in the area of plastics where the
plastics, will be very suited for these multi-layered
challenge is high. Reduce the environmental
materials.
footprint associated with the end-of-life
Specific challenges: phase of packaging products by at least 30 %
compared with existing products for similar
Films with multiple layers made of different applications.
polymers are typically difficult to separate.
This creates an issue at the recycling stage, as
polymer types used for the different layers are
not always compatible. The interaction of filling 4.5. Mechanical recycling
goods (food) with the multi-layer packaging
containers often results in contamination of Scope:
the polymers. Additionally, these articles often
The most promising combination for enhanced
contain pigments, functional fillers, silicon layers
mechanical recycling is a) a thorough pre-sorting,
or adhesive materials, which make the recycling
combined with analytics/quality control, followed
even more difficult, as the different polymers
by b) removal of unwanted by products (such as
and additives need to be separated before the
volatile organics and/or certain halogen-organic
recycling output can be used again, especially for
compounds). The latter stage (a de-volatilization
food and medical applications.
of a recycling polymer melt) recently led to
Technology Readiness Level successful FDA approval of recycled-PE by using a
degassing process of EREMA. In order to achieve
Activities are currently at TRL 3 and shall achieve the re-introduction of cross-linked polymers that
TRL 6 at the end of the project. cannot be reprocessed under normal conditions,
stable reagents for high temperature processing
by twin-screw extruders/compounding can
be developed. New mechanical methods to
break the chemical bonds by using twin screw
extruders with the combination of high shear

SUSTAINABLE PLASTICS STRATEGY • 39


and high energy sources (radiations) offer a good polystyrene recyclate in demanding applications,
potential. New chemical compounds to enhance eventually in food contact. On the other hand,
this process can be added in combination mechanical recyclability of FRP articles is difficult,
with physical methods. New mixers based on showing usually low yield (particularly for the
extensional flow (specific reactor) to improve matrix). Besides, the fibres are significantly
dispersion and distribution quality for a wide degraded, resulting in secondary uses in lower
range of viscosity ratio and to avoid thermal value applications after each lifecycle
degradation are needed. Fibre functionalisation
and reactive compatibilization extrusion/ Technology Readiness Level
pultrusion are relevant techniques as well as the Activities shall achieve TRL 7-9 by 2030.
reactive extrusion process to improve adhesion
between the recycled fibre and polymer matrix
(compatibilization). Additives can protect the Expected Impact:
polymers subjected to these processes. For
Improve the industrial productivity, reliability,
smart mechanical recycling, a virgin polymer
environmental performance, durability, and
and/or chain repair agent can be fed to improve
reduction of life-cycle costs of these materials
the quality of the recyclate. The development
Demonstrate a potential reduction in
of mechanical recycling technologies to
landfill waste volume. At least 15% improved
accommodate bio-based plastics is also required.
industrial process parameters and 20% faster
Specific Challenges: verification of materials performance for
highly promising applications.
Even with highly precise selection and sorting
methods, polymer streams will often consist of a
mix of different grades of polymers. Mechanical
recycling allows the production of decently 5. Post-processing
clean and defined materials without chemical
treatment. The recyclate quality is affected
by feedstock quality variations and polymer Specific Challenges:
degradation. This lowers the value of the recycled After recycling, polymeric materials can still
products in many cases. Through smart recycling contain contamination residues of either
technologies this can be overcome. This is molecular or elemental nature. This is especially
done through intelligent process monitoring true for the recycling of polymer articles that
and control. Mechanical recycling of ABS is have been manufactured under older norms
very close to TRL 9 as for recent examples22. 7

using additives that subsequently have been


Mechanical Recycling of PS has a TRL of 9. Due prohibited or restricted or face future prohibition/
to polystyrene’s low diffusion properties, purity restriction. Polymers face limits on the number of
levels >99% of the polystyrene recyclate can be times they may be recycled without decreasing
achieved. These enable the use of the high purity

22 Recent examples of high quality mechanical recycled ABS grades


Terluran® ECO GP-22 MR50 and Terluran® ECO GP-22 MR70, which
contain 50 and 70 percent of recycled post-consumer waste from
electrical and electronic equipment (WEEE), respectively. The product
properties of these recycled ABS grades are well within the property
profile of the virgin ABS Terluran

40 • SUSTAINABLE PLASTICS STRATEGY


properties, e.g. clarity, strength, etc., further as well as reactive compatibilization processes by
work is required to extend the number of twin screw extruders can also be contemplated.
times they can be subsequently recycled as
feedstock for the production of new polymers Technology Readiness Level
when mechanical recycling is no longer feasible. Activities are currently at TRL 5 and shall achieve
The challenges for the decontamination of the TRL 7 at the end of the project
recycled polymers are in particular: a) the smelly
components. Undesirable smells hinder the use
of i. e. rHDPE in many applications and they can Expected Impact:
also cause odour pollution in the production Create new technologies and business
process; b) the short chain fragments (oligomers) opportunities for the recycling industry
as increase in short chain fragments i. e. in a PE across Europe. Reduce the environmental
matrix affect the flow index of the polymer, one footprint associated with the end-of-life
of the critical parameters for the use of a recycled phase of developed products by at least 30%
polyolefin and c) the additives and their potential compared with existing products for similar
degradation products with different chemical applications.
structure embedded in the polymer matrix
which need to be removed.

Scope:
Developing an EFSA or FDA approved technology
to decontaminate polyolefins (PE-LD/PE-LLD;
PE-HD/PE-MD - Flexible Film (Blown or cast)
in order to recover the food contact status
after treatment similar to those existing for
PET. New, versatile, conformable and low-cost
processing technologies to prevent the release
of contaminants through barriers/encapsulation
(the exact development may be polymer
specific). Identifying or optimise modifiers or
compatibilizers and proving these additives to
minimise degradation of polymer during the
recycling steps. Property enhancers as impact
modifiers, compatibilizers and coupling agents
could also be contemplated to enhance the
properties of recyclates. Development of specific
compatibilizers with high number of active sites

SUSTAINABLE PLASTICS STRATEGY • 41


Alternative Feedstock

This section covers the innovation on plastics Challenges:


based on alternative sustainable feedstocks,
Forest residues represent an abundant and
coming from waste/residues of biomass origin,
potentially sustainable source of biomass, which
industrial gases. There is a need to provide
could be used as a feedstock for a biomass to
methodology and data to be useful to build a
chemicals, fuels and materials in future, The C6
common baseline to estimate environmental
and C5 sugars can be converted into chemical
impact of alternative feedstock and their
intermediates. Lignin, if properly converted, can
outcomes compared to standard feedstock.
serve as a source of renewable aromatic building
This should include short, mid and long-
blocks. Also, ligno-cellulosic biomass in general
term evaluation with economic impact for
can be converted to thermoplastic materials by
producers, suppliers, users. This baseline would
chemical and/or enzyme treatments. Materials
be as a support to investments’ decisions and
in which natural fibres are combined with bio-
should include the European Securities and
based thermoplastic matrix, such as Sulapac,
Markets Authority (ESMA) sustainable finance
can provide sustainable bio-based solutions
deliverables23. For degradable polymers, it is vital
to certain applications, e.g. in the area of
1

to understand which conditions are required,


packaging. Major challenges are associated with
how long it takes, and which breakdown
conversion inefficiencies for this bio-mass-to-
products they leave behind, but current
product approach. The main specific challenge
standards and test methods cannot predict
for biomass conversion into aromatics BTX
breakdown in complex natural environments24.
(Benzene, Toluene, Xylene) is finding the optimal
In addition, adequate collection and sorting
feedstock and process to maximise yield in order
facilities need to be established.
to get a cost-efficient process

Scope:
1. Agricultural and forest In the area of C6 sugars conversion, catalytic
biomass waste based raw process can achieve higher yields and better
selectivity during the conversion of sugar from
materials agricultural sources to industrial feedstock for
renewable polymer production. Specifically,
Side streams of both agricultural and forest furan dicarbocylic acid (FDCA) as a monomer
feedstock are a good source of feedstock for bio- for polyethylene furanoate (PEF) to replace
based polymers. fossil PET and muconic acid as a monomer for
biobased polyamides are promising leads. It is
important to establish proper recycling routes
23 https://www.esma.europa.eu/policy-activities/sustainable-finance
24 https://royalsocietypublishing.org/doi/10.1098/rsos.171792 for these new bio-based polymers. Cellulose
can be esterified to produce thermoplastic.
Technologies like Integrated Cascading Catalytic

43 • SUSTAINABLE PLASTICS STRATEGY


Pyrolysis (ICCP) can be used to produce building approach is the use of bio-based feedstock with
blocks for ABS, PS, PET, PO. Development of a given specification in traditional, established
the suitable additives and process so that these processes and assets. This mass allocation of
bio-based polymers are commercially viable biomaterials into a fossil-based cracker feed
options. Another possibility are the wood-plastic creates a mixture of hydrocarbons that are
composites that can be used for construction partly of plant origin instead of being 100% fossil.
applications such as decking or cladding. An advantage of this technology is the use of
existing assets reducing necessary investment
Technology Readiness Level cost and manufacturing costs compared
From TRL 5 to TRL 9 in 5 years. to fermentative down-stream technologies.
Also, the derived products have the same
Specific Challenges: performance
High-energy demand of enzymatic processes. Technology Readiness Level
Lignin, hemicellulose, cellulose, polymers
are available in large volumes and do not TRL 3 to 7 in 5 years.
interfere with food applications. However, they
exhibit high structural complexity (composite 2. CO2/CO-based
structures, higher O/C ratios, at the same time
low densities) currently resulting in high- This section covers technologies able to convert
energy demand for manufacturing them in a CO2 and or CO into polymers or building blocks
biomass-to-product strategy. Major challenges which can in turn be converted into polymers.
are associated with conversion inefficiencies.
Development of the suitable additives and Specific Challenges:
process so that these bio-based polymers are
The capture CO2 as feedstock is yet uneconomic
commercially viable options. Discrepancy of
for applications in commodity plastics since
mixed feedstock and specifically active enzymes.
the costs of CO2 capture are too high. New
Agricultural and forest waste streams are very
technologies and upscaling and optimisation
often mixtures of different bio-based products. In
of state-of-the-art CO2 capture technologies is
contrast most of the enzymes used are specific
needed to bring these costs down, as well as
to certain polymer groups.
optimisation of the processes that convert the
Scope: CO2 into plastics. Transforming CO2 via several
pathways into usable building blocks to produce
Fundamental research is necessary to find various types of polymers is required.
highly active and selective catalysts, high-yield
fermentation processes, and atom-economic
metabolic reaction pathways in order to increase
the overall process efficiencies. A chemical

SUSTAINABLE PLASTICS STRATEGY • 44


Scope:
Industrial gases need to be captured in order
to be used as feedstock and sometimes can
be used directly if the CO2 content is high
enough. For capture, a strong area of innovation
is the development of membranes or solid
sorbents for CO2 separation, for example
solvent free processes or porous dimension
optimisation. For conversion of CO2 to base
chemicals, improved catalytic systems need
to be developed both with respect to catalyst
composition and shape. With the direct
conversion of CO2, polycarbonate-etherols
(polyol) for polyurethanes, Poly(propylene)
carbonate or polyesters can be developed.
CO2-derived (poly)-olefins, PS, PMMA can be
made through different pathways. CO2-derived
vinyl monomers can derive into many different
polymers. Polymers from CO2-derived non-
olefinic intermediates for example PTHF or PU
without isocyanate can also be developed.

Technology Readiness Level


Activities are currently at TRL 5 and shall achieve
TRL 7 at the end of the project.

45 • SUSTAINABLE PLASTICS STRATEGY


SUSTAINABLE PLASTICS STRATEGY • 46
At date July 2020 the following organisations are signatories of the CPA:

A+C Plastic Kunststoff GmbH: ABN PIPE SYSTEMS; AGORIA; Agriculture Products Europe (APE
Europe); AIMPLAS; Alliance Plasturgie et Composites du Futur (Plastalliance); ALPLA Werke Alwin
Lehner GmbH & Co K; Ampacet Europe S.A.; ANL Packaging; APIP - Associação Portuguesa da
Indústria de Plásticos; APK AG; Aquafil S.p.A.; Arla Foods; Armacell Benelux SCS; ARMANDO ALVAREZ
GROUP; Asociación Española de Industriales de Plásticos (ANAIP); Aspla s.a.; Associação das Empresas
Portuguesas para o Sector do Ambiente (AEPSA); Associação Smart Waste Portugal; Association of
Chemical Industries of Slovenia at the Chamber of Commerce and Industry of Slovenia; Association
of Cities and Regions for Sustainable Resource Management (ACR+); AST Kunststoffverarbeitung
GmbH; AST Plastic Containers UK LLP; AST Plastic Packaging Benelux bvba; Aurora Kunststoffe
GmbH; Avery Dennison; BANDESUR; BASF; BERICAP Holding GmbH; Berry Global Group, Inc;
Berry RPC Verpackungen Kutenholz GmbH; Borealis; C.M.G. SpA; CAPEC - CAJAS Y PALETS EN
UNA ECONOMIA CIRCULAR; CEFLEX, A Circular Economy for Flexible Packaging; CEN-CENELEC;
Chemical Recycling Europe; Chevron Phillips Chemicals International NV; CICLOPLAST; Circular
Economy Research Center, Ecole des Ponts Business School; Cirplus; Citeo; Cobelplast NV; Coca Cola
in Europe; COEXPAN; Comité Français des Plastiques en Agriculture; Coop Italy; Coopbox Group;
Copa and Cogeca; Covestro; CROCCO SpA; CYRKL waste2resource marketplace; Danone; Dart
Products Europe; Deceuninck NV; Der Grüne Punkt- DSD Duales System Holding GmbH & Co. KG;
Digital Europe; DION S.A.; Dutch federation rubber and plastic industry, NRK; Eco Baltia group Ltd;
ECODOM; Ecoiberia S.A.; EDANA; Electric SRL; Elipso; EMSUR; EREMA Group GmbH; ERGIS S.A.;
Essenscia; Essentra Components; EURECAT; Eurocommerce; Eurocord AiSBL; EUROMAP - European
Plastics and Rubber Machinery; EuroMouldings BV; European Association of Automotive Suppliers
(CLEPA); European Automobile Manufacturers’ Association (ACEA); European Brands Association
(AIM); European Carpet and Rug Association (ECRA); European Chemical Industry Council (CEFIC);
European Composites Industry Association (EUCIA); European Composites, Plastics and Polymer
Processing Platform (ECP4); European Federation of Bottled Waters (EFBW); European Federation
of Waste Management and Environmental Services (FEAD); European Manufacturers of Expanded
Polystyrene (EUMEPS); European Organisation for Packaging and the Environment (EUROPEN);
European Plastic Pipes and Fittings Association (TEPPFA); European Plastics Converters (EuPC);
European Plastics Recycling Organisations (EPRO); European PVC Profiles and Related Building
Products Association (EPPA-profiles); European Recycling Industries’ Confederation (EuRIC);
European Resilient Flooring Manufacturers’ Institute (ERFMI); European Snacks Association (ESA);
Evertis Ibérica, S.A.; ExcelRise; Extended Producer Responsibility Alliance (EXPRA); FAMA PLAST
SRL; FCIO - Association of the Austrian Chemical Industry; FECC; Fédération de la Plasturgie et des
Composites (FED-Plasturgie); Federation of Reinforced Plastics (AVK); Fernholz GmbH & Co.KG;
Ferrero; Flexible Packaging Europe; FoodDrink Europe; Fördergemeinschaft für das Süddeutsche

47 • SUSTAINABLE PLASTICS STRATEGY


Kunststoff-Zentrum e.V.; Formteile - Ben Neudel GmbH; Fuerst GmbH; GCR GROUP; Gesamtverband
Kunststoffverarbeitende Industrie e. V. (GKV); GKV/TecPart - Verband Technische Kunststoff-Produkte
e.V.; GREEN PLASTURGIE; Greiner Packaging International; Groupe Barbier; Groupe Guillin; Gruppo
Fabbri Vignola SpA; GSK Consumer Healthcare; Henkel AG & Co. KG; Home Appliance Europe
(APPLIA); Ibacplast, s.l.; IFFPG; IKEM – Innovation and Chemical Industries in Sweden; Incoplas;
INDESLA PACKAGING, SL; Industrievereinigung Kunststoffverpackungen e.V. (IK); Infiana Germany
GmbH & Co. KG; International Association for Soaps, Detergents and Maintenance Products (AISE);
INTRAPLAS - Indústria Transformadora de Plásticos, S.A.; ipa-plast KG; Italian Plastics and Rubber
Processing Machinery and Moulds Manufacturers Association (AMAPLAST); IVK Europe; IVL Swedish
Environmental Research Institute; Joh. Sieben GmbH; Jokey SE; KIMIDE e.K. Resource & Waste
Management; KISICO GmbH; Klöckner Pentaplast – KP Films; Komunala Kranj d.o.o.; Kurtz Holding
GmbH & Co. Beteiligungs KG; LATI Industria Termoplastici S.p.A; Leygatech; Lightweight Containers;
Liveo Research GmbH; L’Oréal; MAAG GmbH; MACPAC SA; Madreperla spa; Magyar Márkaszövetség
(Branded Goods Association Hungary); Mars; Menshen Group; MEPOL S.R.L.; Mixer Spa; MKV GmbH
Kunststoffgranulate; MOL Group; Mondelēz International; MULTIVAC Sepp Haggenmüller SE &
Co. KG; Municipal Waste Europe (MWE); MURAPLAST d.o.o.; Nestlé; Norwich Plastics; OIKOKIKLIOS
S.A.; OneCircle; Online Laminating & Technology Center GmbH & Co KG; Orgalim; Orkla ASA; PEKU
Folien GmbH; Pepsico; Petcore Europe; PET-Verpackungen GmbH; pielleitalia; PIEP-Polo Inovação
Engenharia de Polímeros; Plasta d.o.o.; PLASTIC SENSE FOUNDATION; Plastics Europe; Plastics
Recyclers Europe (PRE); PLASTIGAUR S.A.; PLASTIKA KRITIS SA; Plastika Skaza d.o.o.; Plastikourgeio;
Plastipolis; Plastship GmbH; Polyolefins Circular Economy Platform (PCEP); Pöppelmann Holding
GmbH & Co. KG; Portugal; PREMATÉCNICA S.A.; Pro Form Kft.; Producer Responsibility Organisations
Packaging Alliance (PROsPA); Recticel; Reifenhäuser GmbH & Co. KG Maschinenfabrik; REMONDIS
Recycling; RENOLIT SE; RETAL; Ribawood, S.A; RKW SE; ROBOPLAST S.R.L.; Schwarz Gruppe; Serioplast
Global Services S.p.A.; Seufert Transparente Verpackungen GmbH; Siemens AG; Silver Plastics GmbH
& Co. KG; Simap Srl; SINTAC RECYCLING; SIRAP GEMA SPA; SiriusPro GmbH; SKYTECH SAS; Soft Drinks
Europe (UNESDA); Stabilplastik; Stelioplast Roland Stengel Kunststoffverarbeitung; Styrenics Circular
Solutions (SCS); Südpack Verpackungen GmbH & Co.KG; SULAYR GLOBAL SERVICE; Sund Holding;
Tama Group; Texplast GmbH; The Compost Bag Company nv; Thees Plastic Recycling; Thrace Group;
TNO; TOMRA; TRIA S.p.A.; Trioplast Industrier AB; UAB Putoksnis; Unilever; Unionplast - Federazione
Gomma Plastica; Valencian Plastics Companies Association (AVEP); Verpa Folie Weidhausen; Versalis
SpA; Vinylplus; VTT; WEEE Forum; Wellplast AB.

SUSTAINABLE PLASTICS STRATEGY • 48


Glossary

ABS-HIPS Acrylonitrile-butadiene-styrene – PEC Polyester carbonate


High Impact polystyrene PEF Polyethylene Furanoate
ABS-SAN Acrylonitrile-butadiene-styrene – PET Polyethylene terephthalate
Styrene acrylonitrile PHA/PHB Polyhydroxyalkanoates /
AI Artificial intelligence Polyhydroxybutyrate
BrFR Brominated flame retardants PLA Polylactic acid
BTX Benzene, Toluene Xylene PMMA Polymethyl methacrylate
CLT Cross-linked thermosets PO Polyolefin
CO2 Carbon dioxide POM Polyoxymethylene
CVD Chemical vapour deposition PP Polypropylene
DCPD Polydicyclopentadiene PPC Polypropylene carbonate
DEHP Di-2-ethylhexyl phthalate PS Polystyrene
EFSA European Food Standards PT Polythiophene
Agency PTFE Polytetrafluoroethylene
EPS Expanded polystyrene PTHF Polytetrahydrofuran
FDA (US) Food and Drug Administration PU/PUR Polyurethane
FRP Fibre reinforced polymer PVC Polyvinyl chloride
HBCD Hexabromocyclododecane PVD Physical vapour deposition
ICCP Integrated Cascading Catalytic SIRA Strategic Innovation and
Pyrolysis Research Agenda
LCA Life Cycle Assessment TBS Tracer based sorting
LCC Life Cycle Costs TPS Toughened polystyrene
LIBS Laser-Induced Breakdown TRL Technology readiness level
Spectroscopy TS FRP Thermoset Fibre reinforced
MIR-T Mid Infrared Thermography polymer
MPW Mixed post-consumer waste UV Ultraviolet
NIR Near infrared VIS Visible
PA Polyamide (aka Nylon) WEEE Waste from electrical and
PA6/PA66 Nylon 6 / Nylon 66 electronic equipment
Pb Lead XRF X-ray fluorescence
PBS/PBSA Polybutylene Succinate / XRT X-ray transmission
Polybutylene Succinate Adipate
PBT Polybutylene terephthalate (also
PTMT)
PC Polycarbonate
PE Polyethyene
PE-HD Polyethyene - high density
PE-LD Polyethyene – low density
PE-LLD Polyethyene - linear low density
PE-MD Polyethyene - medium density
Glossary

49 • SUSTAINABLE PLASTICS STRATEGY


About the partners

SusChem is the European Technology Platform for Sustainable


Chemistry. It is a forum that brings together industry, academia, policy
makers and the wider society. SusChem was officially launched in
2004 as a European Commission supported initiative to revitalise and
inspire European chemistry and industrial biotechnology research,
development and innovation in a sustainable way.
www.suschem.org

The European Chemical Industry Council - Cefic is a committed


partner to EU policymakers, facilitating dialogue with industry and
sharing broad-based expertise. Cefic represents large, medium and
small chemical companies across Europe, which directly provide
1.2 million jobs and account for 14.7% of world chemical production.
Based in Brussels since its founding in 1972, Cefic interacts on behalf of
its members with international and EU institutions, non-governmental
organisations, the international media, and other stakeholders.
www.cefic.org

PlasticsEurope is a leading European trade association with centres in


Brussels, Frankfurt, London, Madrid, Milan and Paris. The association
networks with European and national plastics associations and has
more than 100 member companies that produce over 90% of all
polymers across the EU28 member states plus Norway, Switzerland
and Turkey.
www.plasticseurope.org

European Plastics Converters (EuPC) is the EU-level trade association,


based in Brussels, representing more than 50 000 companies in
Europe, which produce over 50 million tonnes of plastic products
every
year. Plastics converters (sometimes called «Processors») are the heart
of the plastics industry. They manufacture plastics semi-finished
and finished products for an extremely wide range of industrial
and consumer markets - the automotive electrical and electronic,
packaging, construction and healthcare industries, to name but a few.
www.plasticsconverters.eu

The European Composites, Plastics and Polymer Processing


Platform (ECP4) is an industry-driven collaboration that unites
25 members from 13 countries amongst the top-level European
research institutions, regional plastic clusters, and EU-level industrial
organisations of plastics and composites converters. ECP4 brings
innovation partners together to identify opportunities for collaborative
research.
www.ecp4.eu

SUSTAINABLE PLASTICS STRATEGY • 50


About SusChem

SusChem is the European Technology Platform At SusChem we believe that sustainable


for Sustainable Chemistry. It is a forum that chemistry can inspire a change of pace and the
brings together industry, academia, policy new mind-set that society needs in order to
makers and the wider society. become (more) sustainable, smart and inclusive.
In partnership with European and national public
SusChem’s vision is for a competitive and authorities, SusChem contributes to initiatives
innovative Europe where sustainable chemistry that aim to provide sustainable solutions to
and biotechnology together provide solutions for society’s big challenges. Together we develop
future generations. and lead large-scale, integrated research and
innovation programmes with chemical sciences
SusChem’s mission is to initiate and inspire at their core. These public private initiatives link
European chemical and biochemical innovation research and partners along the value chain
to respond effectively to societal’s challenges by to real world markets through accelerated
providing sustainable solutions. innovations.

SusChem across Europe

SusChem has established a network of National NTPs help to connect SusChem thinking with
Technology Platforms (NTPs) in 17 countries national and regional programmes. It also
across Europe: Austria, Belgium, Bulgaria, facilitates transnational collaboration and advice
Czech Republic, France, Germany, Greece, SusChem at the European level on collective
Italy, Netherlands, Poland, Romania, Slovenia, national priorities that need to be considered in
Spain, Switzerland, Sweden, Finland, and United European initiatives.
Kingdom.

Credits

Images:
Anders Jacobsen - Unsplash.com
David Hackett - Unsplash.com
Jonathan Chng - Unsplash.com
Oleksiy Mark - Shutterstock
Extarz - Shutterstock
lzf - Shutterstock

Copyright © 2020 SusChem. All rights reserved.

Version 2.0

51 • SUSTAINABLE PLASTICS STRATEGY


SUSTAINABLE PLASTICS STRATEGY • 52
SusChem Secretariat

Address Contact us

The European Technology Platform T +32.2.436.94.18


for Sustainable Chemistry E suschem@suschem.org
Rue Belliard 40 www.suschem.org
@SusChem
1040 Brussels

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