LEHDER Environmental Services Limited has attempted to obtain an updated

MSDS. No update is available for the following reason(s):

Product has been discontinued.

✔ Obsolete (eg. product no longer manufactured under this name,

manufactured or distributed by a different company and/or division).

Company no longer exists (sold, merged, receivership, etc.).

Contact information no longer valid.

Consequently no further updates will be issued. This MSDS should be used until
the product is removed from your facility.

Please advise when product is no longer on site in order to remove it from your
inventory.

LEHDER Environmental Services Limited

704 Mara Street, Suite 210, Point Edward, Ontario, Canada N7V 1X4 Phone: (519) 336-4101 Fax: (519) 336-4311
9954 - 67th Avenue, Edmonton, Alberta, Canada T6E 0P5 Phone: (780) 462-4099 Fax: (780) 462-4392
www.lehder.com
 Page: 1

SAFETY DATA SHEET Revision Date: 10/25/2011

Print Date: 6/24/2013
MSDS Number: R0002464
Saf-Acid™ CLEANER Version: 1.4
™ Trademark, Ashland or its subsidiaries,
registered in various countries67326

1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE

COMPANY/UNDERTAKING

Ashland Regulatory Information Number 1-800-325-3751

P.O. Box 2219 Telephone 614-790-3333
Columbus, OH 43216 Emergency telephone number 1-800-ASHLAND (1-800-274-
5263)

Product name Saf-Acid™ CLEANER

™ Trademark, Ashland or its subsidiaries, registered in various
countries
Product code 67326

2. HAZARDS IDENTIFICATION

Emergency Overview

Appearance: solid, green

DANGER! CAUSES SEVERE BURNS OF THE EYES AND SKIN.

Potential Health Effects

Exposure routes
Inhalation, Skin contact, Eye Contact, Ingestion

Eye contact
Can cause permanent eye injury. Symptoms include stinging, tearing, redness, and swelling of
eyes. Can injure the cornea and cause blindness.

Skin contact
Can cause permanent skin damage. Symptoms may include redness, burning, and swelling of
skin, burns, and other skin damage.

Ingestion

Page 1 / 12
 Page: 2

SAFETY DATA SHEET Revision Date: 10/25/2011

Print Date: 6/24/2013
MSDS Number: R0002464
Saf-Acid™ CLEANER Version: 1.4
™ Trademark, Ashland or its subsidiaries,
registered in various countries67326

Swallowing this material may be harmful or fatal. Symptoms may include severe stomach and
intestinal irritation (nausea, vomiting, diarrhea), abdominal pain, and vomiting of blood. Swallowing
this material may cause burns and destroy tissue in the mouth, throat, and digestive tract. Low blood
pressure and shock may occur as a result of severe tissue injury.

Inhalation
This material is a dust or may produce dust. Breathing this material may be harmful or fatal.
Symptoms may include severe irritation and burns to the nose, throat, and respiratory tract. Symptoms
are not expected at air concentrations below the recommended exposure limits, if applicable (see Section
8.).

Aggravated Medical Condition

Preexisting disorders of the following organs (or organ systems) may be aggravated by exposure
to this material:, Skin, lung (for example, asthma-like conditions), male reproductive system

Symptoms
Signs and symptoms of exposure to this material through breathing, swallowing, and/or passage
of the material through the skin may include:, stomach or intestinal upset (nausea, vomiting, diarrhea),
irritation (nose, throat, airways), Nose bleeding, Cough, central nervous system depression (dizziness,
drowsiness, weakness, fatigue, nausea, headache, unconsciousness), hair loss, Shortness of breath, lung
edema (fluid buildup in the lung tissue)

Target Organs
Overexposure to this material (or its components) has been suggested as a cause of the following
effects in laboratory animals:, effects on male fertility, testis damage

Carcinogenicity
This material is not listed as a carcinogen by the International Agency for Research on Cancer
(IARC), the National Toxicology Program (NTP), or the Occupational Safety and Health Administration
(OSHA).

Reproductive hazard
This material (or a component) has been shown to cause harm to the fetus in laboratory animal
studies. The relevance of these findings to humans is uncertain.

3. COMPOSITION/INFORMATION ON INGREDIENTS

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 Page: 3

SAFETY DATA SHEET Revision Date: 10/25/2011

Print Date: 6/24/2013
MSDS Number: R0002464
Saf-Acid™ CLEANER Version: 1.4
™ Trademark, Ashland or its subsidiaries,
registered in various countries67326

Hazardous Components CAS-No. / Trade Secret No. Concentration

SULFAMIC ACID 5329-14-6 >=90-<=100%
SODIUM BORATE DECAHYDRATE 1303-96-4 >=1.5-<5%

4. FIRST AID MEASURES

Eyes
If material gets into the eyes, immediately flush eyes gently with water for at least 15 minutes
while holding eyelids apart. If symptoms develop as a result of vapor exposure, immediately move
individual away from exposure and into fresh air before flushing as recommended above. Seek
immediate medical attention.

Skin
Immediately flush skin with water for at least 15 minutes while removing contaminated clothing
and shoes. Seek immediate medical attention. Wash clothing before reuse and discard contaminated
shoes.

Ingestion
Seek immediate medical attention. Do not induce vomiting. Vomiting will cause further
damage to the mouth and throat. If individual is conscious and alert, immediately rinse mouth with water
and give milk or water to drink. If possible, do not leave individual unattended.

Inhalation
If symptoms develop, immediately move individual away from exposure and into fresh air. Seek
immediate medical attention; keep person warm and quiet. If person is not breathing, begin artificial
respiration. If breathing is difficult, administer oxygen.

Notes to physician
Hazards: Pulmonary edema may be delayed.
Treatment: No information available.

5. FIREFIGHTING MEASURES

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 Page: 4

SAFETY DATA SHEET Revision Date: 10/25/2011

Print Date: 6/24/2013
MSDS Number: R0002464
Saf-Acid™ CLEANER Version: 1.4
™ Trademark, Ashland or its subsidiaries,
registered in various countries67326

Suitable extinguishing media

Water spray

Hazardous combustion products

acid vapors, Ammonia, nitrogen oxides (NOx), sulfur oxides, magnesium oxide fumes

Precautions for fire-fighting

Wear full firefighting turn-out gear (full Bunker gear), and respiratory protection (SCBA). Use
water spray to cool fire exposed containers and structures until fire is out if it can be done with minimal
risk. Avoid spreading burning material with water used for cooling purposes.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions
For personal protection see section 8. Persons not wearing protective equipment should be
excluded from area of spill until clean-up has been completed. Avoid breathing dust.

Environmental precautions
Do not flush into surface water or sanitary sewer system.

Methods for cleaning up

Sweep up or vacuum up spillage and collect in suitable container for disposal. Pick up and
arrange disposal without creating dust.

Other information
Comply with all applicable federal, state, and local regulations.

7. HANDLING AND STORAGE

Handling
Containers of this material may be hazardous when emptied. Since emptied containers retain
product residues (vapor, liquid, and/or solid), all hazard precautions given in the data sheet must be
observed. Avoid dust formation.

Storage
Store in a cool, dry, ventilated area. Keep from freezing.
Page 4 / 12
 Page: 5

SAFETY DATA SHEET Revision Date: 10/25/2011

Print Date: 6/24/2013
MSDS Number: R0002464
Saf-Acid™ CLEANER Version: 1.4
™ Trademark, Ashland or its subsidiaries,
registered in various countries67326

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Exposure Guidelines

SODIUM BORATE DECAHYDRATE 1303-96-4

CAD BC OEL time weighted average 2 mg/m3 Inhalable
CAD BC OEL Short term exposure limit 6 mg/m3 Inhalable
CAD ON OEL time weighted average 2 mg/m3 Inhalable
CAD ON OEL Short term exposure limit 6 mg/m3 Inhalable
OEL (QUE) time weighted average 5 mg/m3
CAD AB OEL time weighted average 1 mg/m3
CAD AB OEL Short term exposure limit 3 ppm
CAD MB OEL time weighted average 2 mg/m3 Inhalable fraction.
CAD MB OEL Short term exposure limit 6 mg/m3 Inhalable fraction.
MAGNESIUM OXIDE 1309-48-4
CAD BC OEL time weighted average 3 mg/m3 Respirable dust and/or
fume.
CAD BC OEL time weighted average 10 mg/m3 Inhalable fume
CAD BC OEL Short term exposure limit 10 mg/m3 Respirable dust and/or
fume.
CAD ON OEL time weighted average 10 mg/m3 Inhalable
OEL (QUE) time weighted average 10 mg/m3 Fume.
CAD AB OEL time weighted average 10 mg/m3 Fume.
CAD MB OEL time weighted average 10 mg/m3 Inhalable fraction.

General advice
These recommendations provide general guidance for handling this product. Personal protective
equipment should be selected for individual applications and should consider factors which affect
exposure potential, such as handling practices, chemical concentrations and ventilation. It is ultimately
the responsibility of the employer to follow regulatory guidelines established by local authorities.
Avoid breathing dust.

Exposure controls
Mechanical ventilation systems used to ventilate corrosive storage or process areas must be
designed with components that are corrosion resistant. Provide appropriate exhaust ventilation at places
where dust is formed.

Eye protection

Page 5 / 12
 Page: 6

SAFETY DATA SHEET Revision Date: 10/25/2011

Print Date: 6/24/2013
MSDS Number: R0002464
Saf-Acid™ CLEANER Version: 1.4
™ Trademark, Ashland or its subsidiaries,
registered in various countries67326

Wear chemical splash goggles and face shield to protect eyes and skin from airborne dust.
Maintain eye wash station in immediate work area.

Skin and body protection

Wear appropriate chemical impervious clothing and boots whenever there is potential for skin
contact with product. Launder clothing before reuse. Maintain safety shower at all locations where skin
contact could occur. Contact your local safety equipment supplier to assist the facility in determining
proper selection of personal protective equipment for the applications/operations present at your facility.
Wear resistant gloves (consult your safety equipment supplier).
Discard gloves that show tears, pinholes, or signs of wear.

Respiratory protection
A NIOSH-approved air-purifying respirator with an appropriate cartridge and/or filter may be
permissible under certain circumstances where airborne concentrations are expected to exceed exposure
limits (if applicable) or if overexposure has otherwise been determined. Protection provided by air-
purifying respirators is limited. Use a positive pressure, air-supplied respirator if there is any potential
for uncontrolled release, exposure levels are not known or any other circumstances where an air-
purifying respirator may not provide adequate protection.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical state solid

Form powder
Colour green
pH 1.5
Vapour pressure 68.659 hPa @ 5,130 °F / 2,832 °C Calculated
Vapor Pressure
Density (+/- 0.14) 1.12 g/cm3

10. STABILITY AND REACTIVITY

Stability
Stable.

Conditions to avoid
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SAFETY DATA SHEET Revision Date: 10/25/2011

Print Date: 6/24/2013
MSDS Number: R0002464
Saf-Acid™ CLEANER Version: 1.4
™ Trademark, Ashland or its subsidiaries,
registered in various countries67326

excessive heat Keep away from heat, flame, sparks and other ignition sources.

Incompatible products
Acids, Alkali metals, Chlorine, chlorine trifluoride, metal hydrides, metal salts, phosphorus
pentachloride, strong bases, Strong oxidizing agents, strong reducing agents

Hazardous decomposition products

acid vapors, nitrogen oxides (NOx), Sulphur oxides, Ammonia

Hazardous reactions
Product will not undergo hazardous polymerization.

11. TOXICOLOGICAL INFORMATION

Acute oral toxicity

Acute oral toxicity - : no data available
Product

Acute oral toxicity - Components

SULFAMIC ACID : LD 50: 3,160 mg/kg Species: Rat
SODIUM BORATE : LD 50: 4,500 - 5,000 mg/kg Species: Rat
DECAHYDRATE

Acute inhalation toxicity

Acute inhalation toxicity - : no data available
Product

Acute dermal toxicity

Acute dermal toxicity - : no data available
Product

Acute dermal toxicity - Components

SODIUM BORATE : LD 50: > 10,000 mg/kg Species: Rabbit

Page 7 / 12
 Page: 8

SAFETY DATA SHEET Revision Date: 10/25/2011

Print Date: 6/24/2013
MSDS Number: R0002464
Saf-Acid™ CLEANER Version: 1.4
™ Trademark, Ashland or its subsidiaries,
registered in various countries67326

DECAHYDRATE

Acute toxicity (other routes of administration)

Acute toxicity (other : no data available
routes of administration)

12. ECOLOGICAL INFORMATION

Biodegradability
Biodegradability - Product : no data available

Bioaccumulation
Bioaccumulation - Product : no data available

Ecotoxicity effects
Toxicity to fish
Toxicity to fish - Product : no data available

Toxicity to fish - Components

SULFAMIC ACID : LC 50: 14.2 mg/l
Exposure time: 96 h
Species: Fathead minnow (Pimephales promelas)
Method: Static
Test Type: static test
Remarks: Mortality

SODIUM BORATE : LC 50: 1,800 mg/l

DECAHYDRATE Exposure time: 48 h
Species: Rainbow trout,donaldson trout (Oncorhynchus
mykiss)
Test Type: static test

Toxicity to daphnia and other aquatic invertebrates.

Toxicity to daphnia and : no data available

Page 8 / 12
 Page: 9

SAFETY DATA SHEET Revision Date: 10/25/2011

Print Date: 6/24/2013
MSDS Number: R0002464
Saf-Acid™ CLEANER Version: 1.4
™ Trademark, Ashland or its subsidiaries,
registered in various countries67326

other aquatic invertebrates.

- Product

Toxicity to algae
Toxicity to algae - : no data available
Product

Toxicity to bacteria
Toxicity to bacteria - : no data available
Product

13. DISPOSAL CONSIDERATIONS

Waste disposal methods

Dispose of in accordance with all applicable local, state and federal regulations.

14. TRANSPORT INFORMATION

REGULATION
ID PROPER SHIPPING NAME *HAZARD SUBSIDIARY PACKING MARINE
NUMBER CLASS HAZARDS GROUP POLLUTANT
/ LTD. QTY.
U.S. DOT - ROAD
UN 2967 Sulfamic acid 8 III

U.S. DOT - RAIL

UN 2967 Sulfamic acid 8 III

U.S. DOT - INLAND WATERWAYS

UN 2967 Sulfamic acid 8 III

Page 9 / 12
 Page: 10

SAFETY DATA SHEET Revision Date: 10/25/2011

Print Date: 6/24/2013
MSDS Number: R0002464
Saf-Acid™ CLEANER Version: 1.4
™ Trademark, Ashland or its subsidiaries,
registered in various countries67326

TRANSPORT CANADA - ROAD

UN 2967 SULFAMIC ACID 8 III

TRANSPORT CANADA - RAIL

UN 2967 SULFAMIC ACID 8 III

TRANSPORT CANADA - INLAND WATERWAYS

UN 2967 SULFAMIC ACID 8 III

INTERNATIONAL MARITIME DANGEROUS GOODS

UN 2967 SULPHAMIC ACID 8 III

INTERNATIONAL AIR TRANSPORT ASSOCIATION - CARGO

UN 2967 Sulphamic acid 8 III

INTERNATIONAL AIR TRANSPORT ASSOCIATION - PASSENGER

UN 2967 Sulphamic acid 8 III

MEXICAN REGULATION FOR THE LAND TRANSPORT OF HAZARDOUS MATERIALS AND

WASTES
UN 2967 ACIDO SULFAMICO 8 III
*ORM = ORM-D, CBL = COMBUSTIBLE LIQUID

Dangerous goods descriptions (if indicated above) may not reflect quantity, end-use or region-specific
exceptions that can be applied. Consult shipping documents for descriptions that are specific to the
shipment.

15. REGULATORY INFORMATION

WHMIS Classification
E Corrosive Material

WHMIS Ingredient Disclosure List IDL: No component is listed on the WHMIS ingredients disclosure
list.

Page 10 / 12
 Page: 11

SAFETY DATA SHEET Revision Date: 10/25/2011

Print Date: 6/24/2013
MSDS Number: R0002464
Saf-Acid™ CLEANER Version: 1.4
™ Trademark, Ashland or its subsidiaries,
registered in various countries67326

This product has been classified in accordance with the hazard criteria of the Controlled Products
Regulations (CPR) and the MSDS contains all the information required by the CPR.

Canadian National Pollutant Release Inventory (NPRI)

MAGNESIUM OXIDE 1.00 %

Notification status
US. Toxic Substances Control Act y (positive listing)
Canada. Canadian Environmental Protection Act (CEPA). y (positive listing)
Domestic Substances List (DSL). (Can. Gaz. Part II, Vol. 133)
Australia. Industrial Chemical (Notification and Assessment) y (positive listing)
Act
New Zealand. Inventory of Chemicals (NZIoC), as published y (positive listing)
by ERMA New Zealand
Japan. Kashin-Hou Law List n (Negative listing)
Korea. Toxic Chemical Control Law (TCCL) List y (positive listing)
Philippines. The Toxic Substances and Hazardous and Nuclear y (positive listing)
Waste Control Act
China. Inventory of Existing Chemical Substances y (positive listing)

HMIS NFPA
Health 3 3
Flammability 0 0
Physical hazards 1
Instability 1
Specific Hazard -- --

Page 11 / 12
 Page: 12

SAFETY DATA SHEET Revision Date: 10/25/2011

Print Date: 6/24/2013
MSDS Number: R0002464
Saf-Acid™ CLEANER Version: 1.4
™ Trademark, Ashland or its subsidiaries,
registered in various countries67326

16. OTHER INFORMATION

The information accumulated herein is believed to be accurate but is not warranted to be whether
originating with the company or not. Recipients are advised to confirm in advance of need that the
information is current, applicable, and suitable to their circumstances. This MSDS has been prepared by
Ashland's Environmental Health and Safety Department (1-800-325-3751).

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