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If you know your feed composition and flow rate,

steam flow, dry gas composition and P(out) and


T(out) at the reformer outlet, you can calculate dry
gas flow rate at the reformer outlet by doing
carbon balance. Once you know dry gas flow rate
at the reformer outlet you can calculate steam flow
at the reformer outlet by doing oxygen balance.
Then you can calculate equilibrium constant for the
actual steam reformaing reaction, and find T(eq).
ATE for steam reforming reaction is equal to
T(out)-T(eq).
You can apply the same method, basically, to
calculate ATE for the high temperature shift
reaction. ATE for shift reaction equals to T(eq)-
T(out).

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