HYDROCARBONS: Aovees (pamtpums) = {stated comprinds} Sirutinal Hest Panes Af tins Los tumetive) chy By Cormesnba otek Cy -CEtn) = 8-6 Chay Ce Cy-ey peibie aid Hg goog Cathars < Opin chain alteanes Che A Ak Catan Gebte alten i AN A Coane <— Blech altares , Spice atvanes Figo pene 5 an wy 5 SP bgbvidcred 5 Teterabudeal geometry pCltg = Mawahy beset Dia bend CaM 4 4 ° sf Send oo 4 elie is wad ol coe su 84 ead mad! ea, a” 7 ae ra ao a cH tia 98 enh wal Co Hse sw 6 ond ang ral 3a pyitech oreeio + Altanes aoe Colourbn 4 Odourtan j Tatkelen Sete ga snenpactane — Get S56 Miyuile ngctos { Cig amd above 2 weg Aoltds s + danttly dp alters Increaks os “umber dy Conbend tmcrendes Cop be 08 gay omek almett Aematn Same) Does bilan T-bemds Jere 9 Sener meee a eye. they Bake de Waly ld TA as Platively Wzler temperatures are Tamed a LD te opens 2 Hermapencaus catalyss:~ Organi. Compl dy Trantitn tall [eh (Pths)yct] <= mineintnis cata Cocende}” eben (Crs) gtneh i, Chel He Sdackive Ruduchion cuir steal He Franafer bydiegenati 4 Sym addition woe A Sprmeb vend senda ace nat | 2 cty-ermeny + ode Rig eg cy + a we § Prometiec Skabilttation Energy 1s the deiving fone for suductionStrtlarly Wyma —a Me Nh =n os om, | Ware 5: Birch Redtuctton t cree tS gg en CRadtend anton —» Rodienl —» Corteanton) a Non—Terminad atlgne weese’ Mt tm “Sp HK Texetnal abbyne. . ta Rceew hy weed, oo * Na ace? eal on sa oy A og Oe Oo © Hydreteratsion Reatuck SReapae, __Stelmg 1 Simple boranes exe mot Selective ha Fre. gC (oneness Km AELiUASEIOn Energy LA The arising: fone for sustustion Ak atin + Mplisatte only for termtnal alten + gang ~ nek aang aie = webu ti dun bo [conn] Suated curr le tah acaba set) ety LP 00! Cot Rey Reenameny ase. enngling A AGE beranas suc im prunes 4 footy olay Lisle, eon 4 etm, feo | _o6, [rue —— 4 Gigi g oak Ga, 6% Sy 2 preperation 4 plzancs rem Alvythadtdes «2a net atte hates 200 ot ox + tary ex pred AH eigen # Prete] catison HK AtegDbadiler with ty]yt 09 oled they tax TS pe he Tae ede $= lavidey, Crowes st With mata bydetda, «) Passat » wo Maoiy Baysnt ho en ee PP Gagt flunrits) fast 3) UAtliy ex 9 Rh tae S — Aten Yoel Note Lally, Ne@HHy, Zr-Oe/eiyy do mot Madu flatly a “on oly en =H ero 4 am, gcrora f « Wucta senution + prefaned for preparation Sywmentriit athens 1A bubyres fh beranes even; Rengent with ve ware detective A sen oh sar auch —9 ene + 200) Ant Rao 9 Mep2moyt 2010) 4 Zoletyonn — ) + Anon Voy Hrary Sadly agent wrfender tea Sealad tube ee ee pin 4 Roy whey o> cones wbin Wiptor kay fobig maid uondin yo Reclashing soon, a Fly telly thn, 5 tone mcr shan Contagation with bergen x] a Gan be raduced by Lthtly Even umber dy Carbon s A Oly Carnet be prepared4 preformed for preparatlon Spomertriiak altars Even umber A CaAbond, 4 Chy Comme be prepared % *% Radical mechanism Crete mechanism Can alto be txplatmud) ta ; sen 2h ge 4 ams Mee SRR Elfentnation Ty, ee + wae os nti peoforl alkenes axe obtained sO oe one Cie Oh 4 CH -enty ctly eb — IN +N 4 AWN + Deippertion "Y nay Oza, Oh -Me, ey -o=eh, , Chron ete « ULLmann's Remetion coupling fm prenna 4 Ga} te 2 Ox Hs oom Fitting, Metlan 2- 2@~ apes hurts ft ametlon := 2Ne Ort ex Tan prantdand Reockion t= 2ex Ay eR + emmy a 1, nut Borg L ei, pat Rigi Liticumdzateponpete St ee daey not Tumse ath -NOs, ~ 1 8 atane 1 eaina Jere te, tle Rery-oyex 4, (ery) eatt Ey cayrery cy+ God touree SO fUnatanle Sn predente d otldte i , bog a auese, tens mylene! * Row OE Rt Chmmenten Radaschion t= ante Reels 8 tes ebay St, aby lee ey a ome Should mot poms aid Sensitive group foo 3 a eben eb peta thoy Bete reyes “ * Weleeishor Redvetton + een bn ot EM Rett ao baeny € Sul pots babe Auta group 4 Paemaation Alton diem Canbemglie e2i8s to + De. fy Nestleno Bete 2+ bythe clactaabysie- Electrolysis 4 Sodus oo Colcdum LallA oy Cadboty te asthe Crtanss totutin) hy -donn.) o-8-2, nd) Sedum austate May Catia ane tae > Te aim tam ** "ep A eyaday ey top Aredet- 4 cty-2-P v Detprepekien vy-rndusts alte peice. (@xtdatier) aceon Og ne co, (ytd 1 good fo tower hes) Photochanteal dacarbongation A palmary canvontbic oxids ring PEAY vey ets A Mapinge Reaction 1 ‘ be 2 Theowgp, Magentis Salts = oe ¢ Cn-ema=ty, > ayy aw __etg-engront EEE, oy-oty ino, ans [tel ede & plnerinatisn —» expletive 1K Highly veactiroChareah propertfes t= 4. free Radtead Substtbubion Reaction i= Yalapieatin t= Chlerinetion, Brent nation Shap Chale fntblatenn 4 ot, ML2> get Step-a i Chain propagation cf + ety —p bay 4 Hed dy tel cyt cl echy Steq-3 = chate lermbnation Mele 5 p> de? Or d+d a a fur ath sy etek soiaes day t Uy > hy ens bow + cs Foe Orowinabien + + Tass plots by vapour phase hes tay-eamerg oe % X& nbs pouiiltes with C8 4 Ce bend chavagng 3. Salphonatlon 4 Alters! (Radical mechaniye) + Ph we aaglnad mre St are teploced tf me ce fatto can nent 4 Chlerosulphenstion 4 fltanes (Raud Reactten) -= Bent sgt oly My esogel + net 5 Mikvotolatlen 4, plbanes t oO ae [o* 1) Tautecenerison noel ed he Flnerinotion —9 erplative 1 Wighy emetic 1 Reaction ocean ten 9 device Flodination —y Ravertinle 4 Dene tm erases onidihing, opens a H90, HD,, ely ete, Renee <> RTH CELE Hye > mot tye DAE BBN > awogt ate + Te, GWT A HT > B04 ty Skye the Cqyutleovturn towerds BT oe 2th 1 evination A bretnation Aly © hf, er SOxeh, Geugoet we, Com be wed os fnfltatand: os 1 Fer chleination . Bre GO Ou], od ety -e-er a) . es “os Coe Fuge, eoapic atti] 6 Rs, prttes te, 2 Mllatien & Biter 1- (Rack? cad macteniton) 4 aut os Inhibitor Colour dawn reaction) WN ES ADA sy + ~Y, oy Goo nseUw J ere mioey wt ssueesta wm et fat OM Oe CF ort Sn can wigs Rectan Rtarrangenmnent 6 Areattation Ranchers (0) Raforeing ne Anas on 09 te MBS ay aoe Aw bogene Atos] eres Aw Melee, E-G+o:aG 4 Themertfation o altenes t~ Ay Belles Beate aot Abels [ick a 8 Corbone fnterbin Remckion Lower atkanes ore Caverked to hegber ellcanes. & Dingemethane - chgry 29 mg Ea Nae a K febane Intertad bles ett qed C-€ ben eiynese 20M con Bh Oxidation, Gp Alters’: Catly + Eh) ——s x is Hythe Camplunte oridation fale, gaengroh 10. 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Frm altgnes = 4 Spmoddcten ‘z a Hh [rae PB y el eT. = * BaSOy, CoCo, wo ON " Ont adibition siolteyeatits Ry Shree, Spee ‘ton—Texeatna E * eee fan eeu fe A Renstien§ ety Bee > e-bay feottermun ten 's Tasty 2 Pes pltyt hekides i Dedgdva halogenation -- 55 deta, gy Rblteh ge) ata, gy tank, A, pelo ° : =e ° a pis [0408 gy fay + Sopety product 1 mote ty bare: voede de Bubstibetl alkene x From viene dthabides erakion 2~ 20. 2m fergctigon, Pn [er gemat Jaga or ates on lane, epee men ES cay ermeny Vl oe, o (ez a jt ta on ab epeegne tN cay expe en ac ety ey a Tey eke a sorte “, oO oe ae 4 Free Aliskeds' Dabyerat ton:- eer on SEES oernee mbt, Gy Pek, 4 Thee my oe ‘ re batt 3 ee a ms 5 mer yee ed aie as ts ya ey 4 Frere aldehydes co) beteomes ‘= 1 Wing Rsachion = om oy ene : Deze + Rotmely —> ATR > tA were ON Mees Try prune Non pober Aabvost 5 “Tramt altanes ade preferred. ©, ey te, Tn pretna 4 poled Aalvests ; ofa. altenes ods preferred Der te, 5 ftom canberlie gatds t 6. Prem Estas A tithes ehactrabyts © fgoln ay Mebates + Sede Kane proce PaEEY) chamical propation 2 Cokatypte tadestio:~—ateaney ES atanes 2 Uptes holegerabien Addition tea (AdsLtcen. Rumutions) or chen er + Hew Cy thet we nines) Ame Mastewntiey predate Ae fark a AAdunduon 1 gadid to more Substituted cone Chetirephihicn Pdelitien Reaetigns i a es ce 8 oy aay, Tegan SPoeyeen | + “ GF | |L 5, ie ay Syma, Se eye ts fae i oy be be of eas ‘ee Crondinmert Clacemde mintone) Fie hedteas Auditten Reoutten i 1 Pomme ap permis X pore Gffauk od L eigen 1 hrefnre ference effet 1h ret cotervel fo prone (iarhertev predect omTov) Kaveh effec Prtimntoensbev produit t meadow cty-cynene Oa Machen t= ot uta tet x hyo, AB neo! ed Sy pons ct ferment | Het ol) hy, to prone dp WF % a ts AES eens’ fenettarmte| hy Fo retnen ap oY V4 kecemen, 9 =the rr oy Clecrophtie. 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Beige atte > Ctrrennende tiles 3 a grate + Mates 1 4 from Bly t4 gad to mere Subitilud conten: +0 from Prrodsle + Mh bonded 00" 1b orem Sabvenk 4° Oxy Sop decrnevesdation t- 1% Pbfcmattevat toy preduct 2 Mono, pe m8 free Hala Si oteey 2 Eg ct —eH1 ey, frm neny 3 nabig 4 Gyelte Transitim Stake A Mortayitey product4 prleghay Qinstin cy enea, TO Anti -additieg ey-ersey yer en Py 1 Sppradditien aslo. formation from Ateenes i (Addition of -x and -o¥ group) 1 Onidatiion Sh, _Abianes := he iE i i b Allies cewbourise + Why attines decotovsise * Bato > vert OE © GI donee duunlarite Boye A slreng onidiAtng agent H Canbonglic ads wo eye ew eermely E> ony etyrEoow Cny-eiy Bow + ely pinup tt be with fotoar chain 1150) <— ontkisy Victmad als etyrox sernery | NROn0u : 4 ety enmey, ey cryebw 4 nbn vaio, + Ogsrolyets 0. ene devas re ae , Ontdative openels Aabutive oporysio + 2385's dma and oct cman 21H cen -¢ Fragrant one May aan my OT acerzen ce Set. oe oe Delete Chane th uted for Mlpunteg feats 4 Apne fom mature pening. X geghelene for Orbiftdal nkpentng. Caty Rigo 9 CAOH), + wesc“+ nsgbsnn foe obit. opening, Catg ite 9 GOH,4 us H Muster gor Costuah ton wooed sar -2) a ae ca gies Let. a= or ca ime, on y—s—e, tS mused $4 ter on 7 ey ney ney, (etbybanitrercted —— (ey chao ° . om fies {oun Cl, — eye me | eP+ tc menge Bott Cipheeforenytakion) Co,(CO),, ptefermai ° 60+ Heft oy, ey Bou | icant ati Cote enemy Le ABB [sty 1 eral etait ety ins ON — foamed Vejndoe, cyte jigciineew ct, Commutative dene Contigative Mane >) >0) —atatiltty ord at e® a ¢ cyeenneieg eye tnnns 4 eo W2- Bdditten She additionwee eecnmetn, geen ting + Gy eo ae Addition theaddction + Rivaticntiy farrell 4 thecmedgramdcatly forowred da) stew) Maton at Leo temp. TOF ob igh tmperaine en) cree) at! Diets radon Mackion (Cyclic Transition alate ): Le SThewt $= 0tg — tere Dew te coe fe ney os Ag@— of 2 ety a G+ Gh Thos cum sn Ge — & cue By +t, Thaw " Bie — By nto prod OMTodch (one) sire) ewe ite ee dsl wade oy AG- - sffedi {1 8 Gqbirdeicok roland a Ont + Segbvdnl1 Cinante * secbybridutel xe + Cobain, odour bing , terertens A Leon atiyres are parting Aalable ty Wyo Oy, and above ade felts teenth [tawny] A Higher attewer ane Tmfoluble bn Wye A Me bet me Mut Diner egeemes ranching cd ® Mizo, > ety-ceern ee A ae 22S ud amen ' a ie © ee anaes! A Dehabegerntion oon = 8 caznen, me a B weclek + 6Age ated Ao Hered et cea me alt 5 £ oiyereH > cy + 015 2 Por = nae +e Wile allgre 2. Prem Conbemeglie. aside rer ars i pom z Nap” Sai Dade L + Hat 20 itPe ey dt ta fuep Seem FT wh cabade 1 Prods Ar Aetelte: nature dy Terminal Albgnes t- weewen oy een eye outs Faas Posy Pose Mose st Say ° > ter? > © + nre® <8 cen 2, Conate stage) i Ginsitery) PALS charatter imerentas K fnerees Nt Whe P uP 4 th (Birch adudtion) Ta es a Renemorni ols «Silver amd copper eestg hides he Senaibive » monic 90 _ 9 . fodting «Ladd sted c0, | Armeniont 2a8 be ten ond agile vital mg en ‘on Slver witreke TT sk ye rags te ne wee ed can toune peeen —] ce Magen + the 9 ange t pi tntoune econ —| pmuntid , 2 Zed "9 Cathy hk Pot Beneditat Solution t- ‘« auth, + cleric aad ue wes bom ty «Tolan tagle Snigrend ge, Raeget alkane [etsfrst , ewench + aval t 240 Til Mie eset + any + aio f Bandon with Sadtamaltgrtdas = aecee-k' + Max fore s 2 ax TA tttmnty og es an io s es heren Melbsnes ga Nuckepilte Aadiven Questions Gir Reaction weer cc Lan ors a me, 6a A-cse--e4y-a, 0 0, BE Dp i foesenp 3. Addition Reactions = Pale as at s ee Sed Grete) Cnktoadstion) (ontt additien) eeser +H, — Cope atdstien) fete k ° © Be 1 PoP 4 fe Lace cay Sanat dha Be, oto er fl er ‘1 ee bccne My teen en vtetnal dtl Peed Fema? © byob ey Lose hcp tbe ea 7 vores shee WP ee kiky sue, edad! * — ee J.[mm gti (s.098) Ce tea Onces),— ¢ tery 4 Orgocitgline flame — Gnd for entaing wate cent 09, + to (Crattomie) ne tery t aa weenen ety etyebeew ‘an a ad_hy * pe Pept $e0, ugh 23 Osfen [iyo ath, eels kere [tenedwt eo BESOIN, ec dew 4 cope to Seg odin opt ‘Sey. RE Emon Aeatzlere hes Gorkte edow iu to pl, Bally bnnpuvities Se ee wecen + Mey > cba diu” (autos wounak and bang fntect (Lewistte) t “ mars World wed TE blake ape Brith mink Lewitate Cand tn Crentmsat davng Meng mated parting ) enya ay a, i Rtg ot et am Smeal Vent H 4 Hees en}aren ean Sante mele ch, Sen ene Dimattacien “vine rycen HAWS (OL “heat (ok) oe, Tebrwnebabieg aa oss Ye easy 4d oy, sea 4 ese Nike yueseet hee beter ch these ely Combustion fhenemenen @ Myuid fale 15 chavesterind by odtare tabing fv guskines Cutane tabng for dit AG) Gy Yo-Cotane fm an bectone 4 I-wdtorafttabine intone * Ockane myemper Gtone number HY) & Boatane tv an Troccton & heptane mainture : t Coat tas 14 the mala Source dy Arenas 4M He 1 conom io high; They arm lth Aeoky flame 4 Gaenaral forerate Gamers Canene) Compounds Cn Bam nege na nf Caso poo Regs Sethe we ” ee A iets Ditka Outnone B-Pprene t Te tundily abhor Oy Te abledina madion and the Cofeukiy Asbution Earns Braun, a 4 tio Kerenaret freonda not applicable FMI 14 cononty Util fy Hey fren 1 Flee eatinguitter manufading, Compan st wohan heated 1 ents torte fume Mh Pima (ck Coe, A bybrocanom Compatah ene Lakvowtd chain and m tender ingand the colourtan Aslution turn’ Gran, 5A bytrocanom Compahal 4 ene Satunted chain and a bendene ing = named ot datteative ty Langer Rrudturak nck Ip the Chater ts Umtotumted ; cmapound f mamed os devivakive dy chain Stoustuce forges. tet: Tine Renskimt hogy A Molasabar frvrala. Ci, cpus, douse bends hack A Gergana add om Bix habrgen atoms behave differently fm abit ently Lteadly halal [tydrapenated Unhaturaaal Commands with opene forens trlapentde x Bogert denst dasebourise A eoLk Amann Kandy (oak om prokengl bs 7 do net dacobousibe or, 4 £ Broken dove to cay 4 yo) A Ladanting’s prisms x So net aad om to bengent A Benge useler qos Clecbrophite Substitution tensions * Dessay parattat Q Liske i Tn twés; Kebale propel Ring Structure dh Gensene + clus Digrat EBL eure eae Tangent vee seat eed hae + Merostreng ind Gages contre g-o.7e a + beste, pti vais TD TD Fate -ngs urmac! Ct th 4 OD; AM e350 Kowal! Gt oy — Oy atte noes kre! Madoc cement fir _stesitity ond structure a, Benger de Resonernen Theory Berane 1 Raonanca bgboih 4p Kebadet end keraberd Unpatted elistien tn pure fronbitel: there Res 150m RE mal nkyiraited Orbits oewbap Satiratly Le form 34 beat mot! Tetendes ach ove fymmcbotentiy daocabited Rina Currant in Ranzene54 beat mot! Tetendes ach ove fymmebrtentiy dalocabited Ring Current in Benzene Tsomevitatton (n_Congee A Merebubetttatad :- only me fype betause eth carbon ode tdanbisal Sw an- " A Ditubsettubd :- Goth Subsettets same: (* taomert ut Both sumrertumtr Affe Jone 4 48 Othe eta Pam oe pate phony A Tithantibuted 1 Au thier Suseftuent groups che dnfical © 8 Utomect ke fb PATO nppmemctsienk — Syrmasical * geseme dA dipfout subtitatent 6-Temers » 2 ax 3 » ZAge Bes. 4S different Subeettuants € 10 lamers ox Mngtana Vests Bergent satddle oth vp be ite take, phanals, Cratebs, naphthanbne Catiabie oh Heng st oo asde tu aide Citah, Nathalins, Outnaltns Cretodade ottgeet Gran dt ©) 210 - se Conbazete, Antatoe, phanontivent. Mntiecane O28, Q-{9y piten Rabe ae-avn, catten [6509 6 ~ fash singl Goons ate) Tan oh. 2 Rare albenes A Wtph teperatine crating potral Cherntene ant how boiling feocttens) git 4 where alkanes ond ableanat A Hytesfovmning i) catatyie referentng tnd promuue os 1 atforming (r= cotabypt) 4 dagdreppnation 1p Geltsabion Mtomakisasion 5 tomer’ sation Us og S Any sate OL Cs 6 Hag a: ote q + f+ Uo Rito, ao Die lar Fem Bleanes t= OO eke ge teyeen oe, B Fete, mas yf checnenp emencn Aaut, dy) Fe fae senresen pneren Atme , Gl+ Gh g aor Be ya wise BI J. rta oa 3 oJCI ene Mea OF Lepemtats] 5: tem planet t- zn Cause) oS Gr» 6 Reducston Atagerbum Aathr twit spo. @) Gallsel Go) Hewot on) peat @ Srch jung GA NaSnoy S wo WI ET ae nam ve iv oH/s 1 Deearnntn Mea ath with Sedans Gt won 225 Ts mot 22> GI 88 Radstion Canter cmpuunds = Sigh +a oO tae tl 1 _Mgasaty ts 4 Sutdente anid so . iy wth — HS, Seam, heat on) "item ut Desulphanal th HySty, Seam, oy ee Be Dein ste Despestian + Manes ate genmally colar tas Ueyutde cod sabcdt K Tototubh niyo; bub Arlt fn Orgente delves Such of Célars Aleotabs she, x bengne tp a ibe wig x Se ighdy inflarmoable ; berms wlth Sealy flame Fntatatle Pr th. donschy bos the nO Gack solvent fav fate, Resins, 5H cher had bm dry cleaning 3 a moter fact (Bergot) fn marufacteving Wibrobergene ; anugh, dyes ete,io a moter yee ny fn manufactoring 4 Mitroheraene Churteot propertion on te bs Adios Ravchtnt = pee yp gttet imoua CURE en) Bie 0 eee it ve Powocrfut frteabiecde KeMesle , a tala or © fe 4 Ge 7 dings, dager Ste, * Hg FO «Goa cleat wre ° bow rrcbala fa we oa chon [mo Bergen ng gets walter * a lle cI ae “o = U+ a a a thle Fer adduct 4 Aide hath In Gengene. w“ 6s C+ Arctaabives CHE C9 Capsr- Borin Choate oe un er Adelibien 405 on vit hy oss Bot noe G the, 2 fs euigt Boy —> oe ee en CO + 5 02 Qdabion Kagedions t- + Combustion: —gigt io, —> 6a 4 51,9, ot en » WHEE Benner do nat ondinge entdadion ith Meng oniing agents But bn prune dy a undoge onestien eo sats gs 3 o rotten tad or etat) oD * Kear [oi cor) se Saestfe emeealat 0 sg, ©) > Late ore Bangzlic oratnteg, aligt dengan yes wipes seaéannd with ney ong op o bu be wnat, GS Go bu ~~ EG TEN oe sete — : a Moe Se oy neve te Ortehsfealy oe ws geo» Sales, OS 5 rs © Parkiah ontdation A Terminal ~eh 4p abpbegene, th oniditad te -8-4 Interenacbiate Mee ee ead spnatrate TR A yt rwon SA geese, one ice ‘te GS cray0 leely a “ aed 3. Clctsoylilic Substitution Reoctions t eLctaltno'. oot |- debe comptes | Pr eatend intermadioke Te. cemyphat a 2 ren Bao é A =Tp P14 fan ranetive and more Sduative * Gua Me ee nts Gent Te Oth more Reactive pnd fin sebeck ve. Ot oe me, Gow Stniberly Ty tn prema 4, Bergen In prone q Aly there 14 cuchanye Breen diate formation 4 C-tempben Diutth W daw te Cocemplat. frmation Get lh Grew om beeing Berne ta taseverd oes + Craze Sudghorstion att © t 4 sabopte ‘ trlmany Haag. Hua Pulenary ipotopic eftest > Rate 4 Meoction depend pen CH a) CD bend chenege- Seeondany Latopie sft Pate $ anction do rot dapand upen cn oi) CD fond churge- X Te Sulphanation ; Tedinablen thotofic. effet 1A Condtdind Gla > De > Qh Covey meee Bang | oP stati ae Substibution SuackionS ota rreversinke we Gt tn Stim Gy vnen | 09 ete y Bry PAM, Seu i fy ef O+e, tr SS ee ne © f r pdt e tuee-t-o5), Crabbe gar CF ut. 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Meortion oa dha a es cancdnogente Zyuek anon a 4 formed dating, Trcomplante, Cornvottion Sy “Tabetun, Coal, pubrelauen pradasts the, Dita and Contpe cater 2 jel “6 ose owes 2 Bengenthmane a> Ben pa Benarpm a spite rt assis a Dimabi lactogen ¥ Doactivating Groups — Elucken with Arasving reaps daAahi lise C-comelet Compal Lo berger e 8 t 4 geng ieee yp pe AeAtabi lise complet Computed Lo benjent 4 Beg > Bay > ney > -s0gh > Ln > bee >Lin > - + Orthos, Patac dinacting greg Strong ack tvating t= modemtaty activating Meant ackivatiog 1 ently deus tulog 4 mete divesting geoueste ‘strong deactivating: -Nz, ty , —Sits , -en, -NO oma 9 12, Bits , Bhs , eo, Moderately deativabing to 2 ‘Aromatic hydrocarbon ~ Nomenclature, isomerism, stability, preparation, Physical] Property and chemical property of benzene, Ortho, meta and para directing groups| i 27. Which of the folowing substituted benzene derivatives would furnish three isomer when one more substituen is introduced? doa et ee es OC Ke Oo She kvimaalyi Start 0 tae , ee J Pa @ “fom oO oe coo @ oeno v4 o 29, Nirobenzene and acetanide on bromination gives major product respectvely + (1) Meta nitro bromo benzene and meta nitro acetanilide Cinta, AF Meta nto bromo benzene and p-bromo acetaniide (GI wo {@) prio brome benzene and o-brome acetanilide (4) eniro brome benzene and p-bromo acetanilide(@) pritro brome benzene and o-bromo acetanilide (4) ernie bromo benzene and p-bromo acetanide 30. Sulphonation differs from most of electrophilic aromatic substitution reaction withthe fact thatthe reaction je (1) Explosive Leh Reversible (@) Takes place at high temperature (4) Takes place below 0° 31, ~CH, ~ CH, group is an example of (1) Strongly activating group (2) Strongly deactivating group (8) Weakly deactivating group Weakly activating group 132, The order of activity of the various o- and p-drector group is. (1) o> > 0H >— 000 cH, > — NH, wl 8 > Hint,» —on>—0—coch, 6) —NH> o> —0H>—ococH, ) —NH,>—oH>—cocH,> —o* : — ae 38. Nivobenzene canbe prepared ombenzene by using a mixture of ene H,S0, andeoné- FINO, in hentai more FINO, ys esa AS Base @) Acid (3) Reducing agent ~ (4) Catalyst 24, Prenat 288 Eats og OI In the above reaction A and B are (1) Benzene and nitrosobenzene (2) Benzene and dinitrobenzene UaFeenzene and nitrobenzene (4) Toluene and m-nitrobenzene 35, Inwhich ofthe following, nitration wil take place at mpostion? Sc, NO, NH, , oy wm ow wi “4 @ wmaw @ maw Cart a [Alkynes - Nomenclature, isomerism, preparation and properties] 21. 1, 2-dibromo propane on treatment with x moles of NaNH, followed by treatment with ethyl bromide gave a entyne, The value of x is orth, pentyn. The val of Oy-eze-c-elly21. 1, 2-dibromo propane on treatment with x moles of NaNH, followed by treatment with ethyl bromide gave a 3. The value of x is eins, Panty Oy-eze-c-elly (1) One or sates gy, eg PaO» 2) THO caf time ON ES Oe For 22. Wich of he folowing metal ponders used fo convert choromethane ino acetyene by heating the lter with it? Lt ty peeen () Ne me 22 Aiba al 23. Which ofthe folowing does not give a white recite with AgNO, soltion? (1) Propyne once (2) Viny! acetylene § SS" BY -cyciopropyl but2yne ~~) Butyne-t ee / 24. Which is most suitable reagent among the following to distinguish compound (C) ftom rest of the compound? cHc=c—cH, (B) CH,CH,CH,CH, (© cHcHS (0)cH,cH=cH, () Br, in col, (2) Br, in CH,COOH @) Alk. KMn0, UAT IGNO, | NH,OH 25. How is following transformation best carried out? ty (8) 010, NaHS0, {Ya @) H,s0yH4,0 er Hesoynso, © © (4) Ho, 2. Acopound Cy, ratte win snengicl Ae, schon to ge aha bot and en xian wth het and alkaline KNnO, gives the acd (CH,),CHCOOH. Compound X may be f7a-methyi-t-butyne (2) 3-methy/-t-butene (@) 2Metnyi1, 3-butadiene @) tpentyne[alkenes — properties, Dienes] 12 Arrange the folowing in decreasing order of ashyerogen a SOF > > @iei>in @) u>in>t @ mans 13, When HC! is passed through propene in the presence of benzoyl peroxide, it gives ae (1) repropy chloride eae propyl chloride as @) 2 chioro ethanol (4) Benzoyl chloride 14, Observe the following reactions and predict the major products A and B. (0 Agee ae CJ @) AaB bo ae CJ] ; & erm OY ore OY, mae 15. Which ofthe follguing species isan intermediate in tho reaction shown below? 9%-00, @ Cpe Oder 16. What is the major product formed for the folowing reaction? cH, —C=cH—cH, —ommau my cH, ° ) cH, —CycHo—cH, @ chock, -Hoocen, on, oH OH on bi aha @ cy—b—cH,cn, ox, bn, 17, The olefin which on czonclysis ives CH,CH,CHO and CH,CHO is a Sg (1) Butt-ene (2) Pont-t-ene \ 8 Pent2-ene (4) Semethytt-butene 18, Postion of double bond inakenes can be identfed by (1) Bromine water Se ia (9) Ammonia! siver nitrate solution (4) Hydrogenation 18. Which of the folowing reactions are considered as oxidation reactions?\y) Sromine water 2) uzonorysis ae pe preniaare Pi eciar es cancers eee cine ae ome Yh 28 ee h, - @ w Kee, a o CY ee oe ” wren ee pg at wh (at ‘0 @ aw @uiay 20. Reaction of one melecleof HBr wih one molecule of 1,3 butadane a 40°C pes predominanty (1) ‘-brome-2-btene under kinetilly controled condition - @) Sbreme-duene under nemodyramialy aneted consten FZ Pest (3) 3-bromo-butene under kinetically controlled condition “orcro-2-butee under terodynamicaly convoted reectons [Alkenes - Structure, nomenclature, isomerism and preparation] CAF 22-dmetynt zene Sa @) 2metrypent2-ene 2S @) Cishex2-0ne (@) Hextene AF 8. Reaction of 2 pheny!t-bromo cyclo pentane on reaction with alcaholic KOH produces (1) 2-phenyl cyclopentene + 3 phenyl cyclopentene gv . . (@) ‘-pheny! cyclopentene only 2? aon, a, eL ‘1-phenyl cyclopentene + 3 phenyl cyclopenter (4) 3-pheny! eyclopentene only 9. The major product in the acid catalysed dehydration of 2-pentanol is ialeae a (3) Pent-3-ene (4) Methylbut-1-ene 50. Taman prot seg ten <6 ‘\, . Crate pre seems, ph Bf ou Be Loe by, ay by cH, Hoy wh ® Qhorean KO, oct Horo HICH), Tea we 11. In which of the following reactions ethylene is formed? ws (1) GyH,OH, di H,S0,.0°C en, sa 2)GCHOD, cone. H,S0,, 170°C @ACHBr ZA? A. AB C.H.OH. cone. H.S0.. 170°C11. myn oF we rrowng reactons emvene 1 ormea (1) C,HOH, di H,S0, °C e488, 1305" (2)GGH,0D, conc. H,S0,, 170°C G2CH,Br, Zn, 44 ww ) C,H,OH, cone. H,SO,, 170°C TIN sification and preparation, Properties of alkanes] [atkanes ~ Nomenclature, c ra a ee eer ae a eae cere wl be wth ramatey (1) Ethyl chloride and butyl chloride (2) Methy chloride and m-peny! bromide (8) Ethyl bromide and n-butyl bromide ‘propy bromide 2 ~ 4 2. On treating a mixture of two alky! halides with sodium metal in dry ether, 2-methy! propane was obtained. The alky! halides are Zetioropopane & chloromethine 2) 2eheropropane& chlooathane () Chloommthane&choroshane A) Chlramthane& -torpepane 3.__ In the following compounds the decreasing order of B.P. is —~ aan, ae, achazane Wo ~~ mA >) > (my > aMy> MH 3) a> amy> 4) (my >) >) 4. The rebave react of 1, 2" and 3 hyrogens in chlrraton reacion hasbeen fund to be 1:38: 5 Int reason aur Eyes a ‘ Ao Be hag Sp Oy Bor bee, sine s a eo Thera othe anit edt 8. Cand gps tbe () 1:38:50 TO as ta:6:6 @)a:78:8:8 @tre81 5. The order of reactivity of halogens in aliphatic substitution reactions is (1) Br, > Cl, > (2) Ol,> Br, > F, F, > Cl, > Br, (8) F,> Br, > Cl, 6. The product obtained on heating heptane with Cr,0, -Al,O3 at 600" C in (1) Syclohexane (2) Cyclotinexene tae J (4) Cycloheptane