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Calculate the specific volume of superheated steam at 100 bar a and

623.1515 (350C) using (a)the ideal gas law,and (b)the vander waals
equation if the actual spcific volume of stream at the above
condition is 0.022 42m3/kg find the percentage error in the above
cases.

p 100 BAR
T 623.15 K
R 0.083145 m3.bar/(kmol.K)
Pc 221.2 bar
Tc 647.3 K
a 5.524362351
b 0.03041351633

i v f(v) f'(v)
1 1 50.50318868195.8180456
2 0.7420912433
14.59088473
89.32208935
3 0.5787398837
4.040949894
42.51489725
4 0.4836920263
0.9871015683
22.64768459
5 0.4401069276
0.163173152
15.35008465
6 0.4294768134
0.008601046408
13.743143
7 0.4288509707
0.00002895578241
13.65064843
8 0.4288488495
0.0000000003320727582
13.65033533
9 0.4288488495 0 13.65033533
10 0.4288488495 0 13.65033533
11 0.4288488495 0 13.65033533
12 0.4288488495 0 13.65033533
13 0.4288488495 0 13.65033533
14 0.4288488495 0 13.65033533
15 0.4288488495 0 13.65033533

v=0.42889

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