NEET - 2023 Test Series for Fresher _ Solution Minor Test - V

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
1 3 1 4 3 1 3 1 3 1 1 1 3 3 2 2 2 2 4 4
21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40
2 4 1 4 2 4 1 3 4 2 3 1 3 2 2 2 3 4 2 3
41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60
3 1 2 3 1 2 4 2 1 1 4 4 2 4 2 1 2 1 2 1
61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80
3 2 1 3 3 3 3 2 3 4 2 4 3 1 4 2 1 1 3 2
81 82 83 84 85 86 87 88 89 90 91 92 93 94 95 96 97 98 99 100
1 4 3 2 4 3 1 1 1 1 4 3 1 3 4 2 1 3 3 1
101 102 103 104 105 106 107 108 109 110 111 112 113 114 115 116 117 118 119 120
4 4 1 4 4 4 2 1 4 4 2 2 3 4 4 4 4 3 3 4
121 122 123 124 125 126 127 128 129 130 131 132 133 134 135 136 137 138 139 140
2 1 3 3 0 3 4 3 2 4 3 3 3 2 2 1 4 3 2 4
141 142 143 144 145 146 147 148 149 150 151 152 153 154 155 156 157 158 159 160
4 3 4 3 2 2 2 2 1 1 3 2 4 2 2 4 1 3 1 2
161 162 163 164 165 166 167 168 169 170 171 172 173 174 175 176 177 178 179 180
4 3 1 2 4 3 1 1 2 4 1 2 2 1 3 2 3 4 2 1
181 182 183 184 185 186 187 188 189 190 191 192 193 194 195 196 197 198 199 200
3 1 4 2 3 4 2 3 4 1 3 3 3 4 3 1 3 1 2 2
Solution complete reduction

3  85  1  87 6mg 3
61. Avg. atomic wt =  85.5 mole of H2 consumed  2g  3  10 mole
3 1
112 mole of metal oxide reduced
62. Mole of NO2   5  103 mol
22400 3  10 3
  10 3 mole
3
mass of NO2  5  10 3  46g  0.23g
0.1596
0.23 mol. mass of M 2O3   159.6g
Volume of NO2   0.2 ml 103
1.15
 2  M  3  O  159.6
No. of molecule = 5  103  6.023  1023
 2  M  3  16  159.6
21
 3.1  10
 M  55.8
64. Mol.wt = 2 × vapour density = 140
2
formula mass of CO = 28 67. Volume of one drop  ML
35
140
x 5 2  1.2 1.2
28 Moles in one drop  35  70  (35)2 mol
66. M 2O3  3H 2  2M  3H 2
1.2
1 mole of the metal requires 3 moles of H2 for No. of molecules in one drop  (35)2  N A

1
NEET - 2023 Test Series for Fresher _ Solution Minor Test - V
68. H 2SO4  2NaOH  Na 2SO4  2H 2O 20
NaOH =  0.5 =0.01 mol
2  M H 2SO4  Vreq  1  M NaOH  VNaOH 1000
Th e nu mber o f mo le s of H Cl =
2Vreq  10ml 100
 0.1  0.01mol
1000
Vreq  5 ml
When 0.01 moles of NaOH neutralises 0.01
69. Given that, formula of first oxide = M3O4 moles of HCl, the heat release is x kJ when
let mass of the metal = x 1 mole of NaOH neutralized 1 mole of HCl, Heat
x
3x released will be  100
% of metal in M 3O4   100 0.01
3x  64 But heat is released, negative sign = – 100
But as given % = (100  27.6)  72.4% 
80. CaCO3 (s )  CaO (s )  CO2 (g )
3x
So,  100  72.4 K p  PCO2  0.003 atm
3x  64
or x = 56 G  G   2.303RT log K p
In 2nd oxide = 27.2 + 2.303 × 2 × 1000 × log 0.003
Given, oxygen = 30% , so metal = 70% = 15.6 kcal (R = 2 cal mol–1K–1)
So, the ratio is
87. vap H   vapU   RT
70 30 U   H   RT
M :O = :
56 16
 40.66  (8.314  10 3  373)
 2 : 3  M 2O3
72. 2 g of metal carbonate is neutralised by 100 ml  37.55 KJ /mol
of 0.1 N HCl
89. wirr  Pext (V2  V1 )
 Nu mber o f gram - equi val en t of H Cl
100  0.1  10(2  1)  10atm  L
  0.01
1000 v2
Wrev   Pex  dv
Nu mber o f gram – equi vale nts of metal v1
carbonate = 0.01
V2
mass of 0.01 gram equivalent metal carbonate  2.303nRT log
= 2g V1
Mass of 1 g equivalent metal carbonate =  1 2.303  0.0821 log2/1
2
 200g  16.96 atm  L
0.01
 Equivalent mass of metal carbonate = 200 Wrev 16.96
  1.69  1.7
74. G   H  T S Wirr 10.00

0   H  T S 91. In one molecule of magnesium phosphate, 8

oxygen atom
H 30560
T    463K Hence : 0.25 mole of oxygen atom are present
S 66.00 1
in  0.25  3.125  102
V2 V 8
76. S  nR ln  2.303nR log 2
V1 V1 92. BaCO3  BaO  CO2
100 When 197 grams of BaCO3 is decomposed it
 2.303  5  8.314log forms 22.4 lit of CO2
10
= 95.73 JK–1 If 9.85 g of BaCO3 is decomposed it forms x lit
of CO2
77. The number of moles of
9.85  22.4
x  1.12
197