introduction 7
nywhich -OH group IS
organic compounds i
> These are hydroxy! derivatives: of alkanes and mono alkyl dt
Their general formula is CaHtwiOH OF GaHl2n420.
> The hybridization state of Cis sp"
> Geometry is tetrahedral.
> Alcohol shows chain position and functional group is
“itm is present, they shows optical isomerism: AS
> These are the
carbon.
‘omerism If chiral carbon
ose
jased on nO of -OH group.
GoH:OH
Classification of ‘Alcohol-
1. Alcohols and phenols may be classified as ~ B
Monohydric alcohol- Contains one -O group only .Eg-
Dinydricalcohol- Contains two -OH group FgBlycol
‘Trihydric alcohol- Contains three -OH group Eg- glycerol
polyhydric alcohol- Contains more than three -OH group Eg: sorbitol
2. n the basis of the nature of the carbon to which -OH atom is attached,
hydroxl derivatives are classified as 1°, 2% 3° allylic, benzyl; vinylic and
aryl derivatives.
For example:
“On the basis ofthe nature of the carbon to which -OH atom is attached-
Compounds containing sp?C-X bond-
2» and 3° alcohol: hydroxyl atom is bonded to primary, secondary or
tertiary carbon atom of an alkyl group.
te OH oH
1+ ae Dae ee
a bk be
mama *Gisoma > “ages!”
> Allylic alcohol: -OH atom is bonded t:
'o an sp?-hybri
to carbon-carbon double bond (C=C) ie. oat ye acai oy
PRIYANKA SINGHAL 8160743860 c
sono x