INFRA COACHING INSTITUTE

Subject : Chemistry Paper Set : 1

Standard : 12 H Date : 07-01-2023

Total Mark : 100 Time : 0H:0M


Chemistry - Section A - MCQ


[1] The compound which gives the most stable carbonium ion on dehydration is (A) 2, 4, 6− Trinitrophenol (B) Benzoic acid

CH3 − CH − CH2 OH (C) o− Nitrophenol (D) Benzenesulphonic acid

(A) |
CH3
[8] CrO3 dissolves in aqueous N aOH to give
CH3
| (A) CrO42− (B) Cr(OH)−
(B) CH3 − C − OH 3
|
CH3 (C) Cr2 O72− (D) Cr(OH)2

(C) CH3 − CH2 − CH2 − CH2 OH

[9] The half life period of a gaseous reactant undergoing thermal decomposition
CH3 was measured for various initial pressures ′ p′0 as follows :
(D) | P0 (mmHg) 250 300
CH3 − CH − CH2 − CH3 t1/2 (minutes) 135 112.5
The order of reaction is -
[2] In pyrophosphoric acid number of hydroxyl group are
(A) 0 (B) 1
(A) 2 (B) 3
(C) 2 (D) 3
(C) 4 (D) 5

[10] N H3 + O2 −−→ A + H2 O;
Pt
[3] 1 mol of an octahedral metal complex with formula MCl3 · 2 L on reaction with ∆
excess of AgNO3 gives 1 mol of AgCl. The denticity of Ligand L is ...... . (Integer A + O2 → B
answer) B + O2 + H2 O → C
A, B and C are
(A) 3 (B) 4 (A) N2 O, N O2 and HN O3 (B) N O, N O2 and HN O3
(C) 2 (D) 1 (C) N O2 , N O and HN O3 (D) N2 O, N O and HN O3

[4] Which of the following compounds will undergo decarboxylation on heating ? [11] pH of a 0.1 M monobasic acid is found to be 2. Hence its osmotic pressure at a
given temperature T K is

(A) 0.1 RT (B) 0.11 RT

(C) 1.1 RT (D) 0.01 RT

[12] The structure of salol is

(A) 2 and 3 (B) 3 and 4
(A) (B)
(C) 3 only (D) 1 and 4

[5] A sequence of how many nucleotides in messenger RN A makes a codon for an

amino acid
(A) 1 (B) 2

(C) 3 (D) 4
(C) (D)
[6] The number of electrons required to deposit 1 gm atom of aluminium (at. wt.
= 27) from a solution of aluminium chloride will be ............ N (where N is Avo-
gadro's number)

(A) 1 (B) 2

(C) 3 (D) 4

[7] Which of the following will not be soluble in sodium hydrogen carbonate? [13] Identify the strongest base from the given compounds

Page No : 1
 (A) (B) (A) 108 (B) 127

(C) 157 (D) 181

[23] The product 'B' is

(C) (D) All have same basic strength

(A) (B)

[14] The reaction of an ester RCOOR′ with an alcohol R′′ OH in the presence of
an acid gives
(C) (D)
(A) RCOOH (B) R′ COOH

(C) R′′ COOR (D) RCOOR′′

2HNO P Cl
[15] The end product of the reaction ethyl amine −−−→ B −−−−→ C is
KCN
A −−−−→
5

(A) Ethyl amine (B) Diethyl amine

[24] The half life for the reaction N2 O5 ⇌ 2N O2 + 21 O2 in 24 hrs at 30 o C. Start-
(C) Propane nitrile (D) Triethyl amine(e)Methyl amine ing with 10 g of N2 O5 how many grams of N2 O5 will remain after a period of
96 hours ........... g

[16] The IU P AC name of [Cr(en)3 ]Cl3 is (A) 1.25 (B) 0.63

(C) 1.77 (D) 0.5

(A) triethylene diaminechromium (III) chloride

(B) tris(ethylenediammine)chromium (III) chloride [25] Copper sulphate solution is electrolysed between two platinum electrodes. A
current is passed until 1.6 g of oxygen is liberated at anode. The amount of cop-
(C) tris(ethylenediamine)chromium (III) chloride per deposited at the cathode during the same period is .............. g [At. mass of
Cu = 63.6]
(D) tris(ethylene diamine)chomium (III) chlorido
(A) 6.36 (B) 63.6
[17] Sulphide ores are generally concentrated by
(C) 12.7 (D) 3.2
(A) Froth floatation process (B) Magnetic separation

(C) Gravity separation (D) By hand picking [26] Hot and conc. nitric acid when reacts with copper, the gas obtained is

(A) N2 (B) Nitrous oxide

[18] The number of moles of SO2 Cl2 in 13.5 gm is
(C) N O (D) N O2
(A) 0.1 (B) 0.2

(C) 0.3 (D) 0.4 [27] Product which is not expected to be formed is

[19] The product formed by the reaction of an aldehyde with a primary amine is

(A) carboxylic acid (B) aromatic acid

(A)
(C) Schiff's base (D) ketone

[20] How many grams of methyl alcohol should be added to 10 litre tank of water
to prevent its freezing at 268 K ? ............. g (Kf for water is 1.86 K kg mol−1 ) CH3
(B) |
(A) 880.07 (B) 899.04 CH3 − CH2 − CH = C − CH = O

(C) 886.02 (D) 868.06 (C)

[21] 2 gm of benzoic acid ( C6 H5 COOH ) dissolved in 25 gm of benzene shown

a depression in freezing point equal to 1.62 K . Molal depression constant for
benzene is 4.9 KKg mol−1 . The % of benzoic acid in dimeric form is ......... %.

(A) 97.4 (B) 99.2 (D) All

(C) 86.0 (D) 87.5 [28] In a zero-order reaction for every 10o rise of temperature, the rate is doubled.
If the temperature is increased from 10 o C to 100 o C, the rate of the reaction
will become ......... times
[22] Copper crystallizes in f.c.c. with a unit cell length of 361 pm. What is the radius
(A) 64 (B) 128
of copper atom ? ............ pm
(C) 256 (D) 512

Page No : 2
[29] The triclinic unit cell has following parameters
(A) (B)
(A) a = b = c ; α = β = γ = 90o
(B) a = b ̸= c ; α = β = γ = 90o
(C) a ̸= b ̸= c ; α ̸= β ̸= γ ̸= 90o
(D) a = b ̸= c ; α = β = 90o , γ = 120o
[30] The structure of products E − H, respectively are

(C) (D) None of these

[35] How many secondary amine are possible with molecular formula C4 H11 N H2

(A) 4 (B) 3

(C) 2 (D) 1

[36] A(g) → 2B(g) initially 2 moles of A are taken in 5 litre vessel. After 20 min,
(A) 3, 2, 6, 7 (B) 4, 5, 6, 1 [A]t =
[B]t
. Find half life time of A in the first order reaction .......... min
2

(C) 3, 4, 5, 2 (D) 3, 2, 4, 5 (A) 20 (B) 10

[31] For a first order reaction A → B, the reaction rate at reactant concentration of (C) 40 (D) 5
0.01 M is found to be 2.0 × 10−5 M sec−1 . The half life period of the reaction
is .......... sec
[37] The Crystal Field Stablilisation Energy (CF SE) for [CoCl6 ]4− is 18000 cm−1 .
(A) 333 (B) 300 The CF SE for [CoCl4 ]2− will be ......cm−1

(C) 346.5 (D) 220 (A) 6000 (B) 16000

(C) 18000 (D) 8000

[32] The sum of number of first and second nearst neighbours in F CC closed pack-
ing
[38] The IU P AC name for the complex [Co(N O2 )(N H3 )5 ]Cl2 is :
(A) 12 (B) 6
(A) Nitro- N -pentaamminecobalt (III) chloride
(C) 18 (D) 24
(B) Nitro- N -pentaamminecobalt (II) chloride
[33] Drugs used to bind to receptors, inhibiting its natural function and blocking a
message are called. (C) Pentaamminenitrito- N -cobalt (II) chloride

(A) Agonists (B) Antagonists (D) Pentaamminenitrito- N -cobalt (III) chloride

(C) Allosterists
[34] The major product of the reaction,
[39] Compound A was treated with a large excess of CH3 M gBr. The resulting
(D) Anti histaminists product was exposed to P OCl3 /pyridine to give compound B, as one of many
products
Which of the following compounds can be A ?

Page No : 3
 (A) (A) (B)

(C) (D)

(B)

Zn−Hg
[45] −→ X − → Y ; Y is
∆
−−−−−
HCl

(A) (B)

(C)

(C) (D)

(D)
[46] Isoniazid is used in the treatment of tuberculosis and multiple sclerosis. Iden-
tify the least basic N present in it

(A) I (B) II

[40] Thermite is a mixture of (C) III (D) Not comparable

(A) F e powder and Al2 O3 (B) Al powder and F e2 O3 [47] The correct order of reactivity towards the electrophilic substitution of the
compounds aniline (I) benzene (II) and nitrobenzene (III) is
(C) Cu powder and F e2 O3 (D) Zn powder and Cr2 O3
(A) I > II > III (B) III > II > I

[41] Acetaldehyde on treatment with dil. N aOH followed by heating gives (C) II > III > I (D) I < II > III

(A) CH3 CH2 CH2 CH2 OH (B) CH3 CH2 CH2 CHO
[48] Number of electrons that Vanadium (Z = 23) has in p-orbitals is equal to ......
(C) CH3 − CH = CHCHO (D) CH3 − CH = CHCH2 OH
(A) 24 (B) 66

[42] The number of unpaired electrons in N i(CO)4 is (C) 89 (D) 12

(A) 0 (B) 1
[49] KCN reacts readily to give a cyanide with
(C) 3 (D) 5
(A) Ethyl alcohol (B) Ethyl bromide

[43] The rate constant of a first order reaction whose half-life is 480 sec , is (C) Bromobenzene (D) Chlorobenzene

(A) 2.88 × 10−3 sec−1 (B) 1.44 × 10−3 sec−1

[50] The molarity of a solution obtained by mixing 750 mL of 0.5(M ) HCl with
250 mL of 2(M ) HCl will be .........M
(C) 1.44 sec−1 (D) 0.72 × 10−3 sec−1
(A) 0.87 (B) 1.00
[44] What is the product obtained in the following reaction ?
(C) 1.75 (D) 0.97


Chemistry - Section B - SUBJECTIVE


Page No : 4
 
S.A [2 Marks]


[54] Number of Cl = O bonds in chlorous acid, chloric acid and perchloric acid re-
[51] A tetra-atomic molecule (A) on reaction with nitrogen (I) oxide, produces two spectively are :
substances (B) and (C). (B) is a dehydrating agent in its monomeric form while Br2
[55] HO − CH2 − CH2 − CH2 − CH2 − CH = CH2 −−−→ Product ?
substance (C) is a diatomic gas which shows almost inert behaviour. The sub-
stances (A) and (B) and (C) respectively will be [56] An unknown compound (A) (molarmass = 180) on acylation gives a product
(molar mass = 390) than find the number of hydroxyl group present in com-
pound (A) .
KHSO4 LiAlH4
[52] Glycerol −−−−−−→ (A) −−−−−→ (B) ; (A) and (B) are respectively
[53] X, Y, Z reaction are respectively [57] Consider the following sequence of reactions
The end product (B) is:

[58] The boiling point of a solution of 0.1050 gm of a substance in 15.84 gram

of ether was found to be 100o C higher than that of pure ether. What is the
molecular weight of the substance [Molecular elevation constant of ether per
100g = 21.6]


Below question is for 3 marks


[62] Which of the following expressions is correct in case of a CsCl unit cell (edge
[59] Reactant (A) in this reaction is length, a )
[63] The step shown below is a recent synthesis of corannulene.
Product (A) is

[60] Compound A, C8 H10 O, is found to react with NaOI (produced by reacting Y

with N aOH) and yields a yellow precipitate with characteristic smell.
A and Y are respectively
[64] The final product [D] of the reaction is
[61] Identify product Z in the following reaction sequence O EtOH 2 mole M eM gBr
1.C6 H5 M gBr CHCl3 −−→
2
[A] −−−−→ [B] −−−−−−−−−−−−→
N aCN diethylether hv
H2 C = CHCH2 Br −−−−−→ Y −−−−−−−−−−→ Z CaOCl2 ∆
2. H3 O + [C] −−−−−−→ [D] −→ CH3 − C − CH3
||
O


Below question is for 4 marks


[68] In the following reaction sequence, structures of A and B, respectively will be

[65] Ferrous sulphate heptahydrate is used to fortify foods with iron. The amount
(in grams) of the salt required to achieve 10 ppm of iron in 100 kg of wheat is
Atomic weight : F e = 55.85; S = 32.0 O = 16.00
[66] An optically active compound X has molecular formula C4 H8 O3 . It evolves
CO2 with N aHCO3 . ′ X ′ Reacts with LiAlH4 to give an achiral compound.
′ X ′ is

[67] The number of moles of hydrogen molecules required to produce 20 moles of

ammonla through Haber's process is

Page No : 5
 INFRA COACHING INSTITUTE
Subject : Chemistry Paper Set : 1

Standard : 12 H (Answer Key) Date : 07-01-2023

Total Mark : 100 Time : 0H:0M


Chemistry - Section A - MCQ


1-B 2-C 3-C 4-C 5-C 6-C 7-C 8-A 9-C 10 - B
11 - B 12 - B 13 - A 14 - D 15 - C 16 - C 17 - A 18 - A 19 - C 20 - D

21 - B 22 - B 23 - C 24 - B 25 - A 26 - D 27 - A 28 - D 29 - C 30 - A

31 - C 32 - C 33 - B 34 - A 35 - B 36 - A 37 - D 38 - D 39 - D 40 - B

41 - C 42 - A 43 - B 44 - A 45 - C 46 - B 47 - A 48 - D 49 - B 50 - A

Page No : 6
 INFRA COACHING INSTITUTE
Subject : Chemistry Paper Set : 1

Standard : 12 H (Solutions) Date : 07-01-2023

Total Mark : 100 Time : 0H:0M


Chemistry - Section A - MCQ


[1] The compound which gives the most stable carbonium ion on dehydration is (A) 2 and 3 (B) 3 and 4

CH3 − CH − CH2 OH (C) 3 only (D) 1 and 4

(A) |
CH3
Solution:[ Correct Answer : C ]
CH3
|
(B) CH3 − C − OH
|
CH3

(C) CH3 − CH2 − CH2 − CH2 OH

CH3
(D) |
CH3 − CH − CH2 − CH3

Solution:[ Correct Answer : B ]

[5] A sequence of how many nucleotides in messenger RN A makes a codon for an
(b)Tertiary carbonium ion is the most stable and it will be given by de- amino acid
[ AIPMT 2004 ]
hydration of tertiary alcohol.
(A) 1 (B) 2
[2] In pyrophosphoric acid number of hydroxyl group are
(C) 3 (D) 4
(A) 2 (B) 3

(C) 4 (D) 5 Solution:[ Correct Answer : C ]

(c) The four bases in m − RN A : adenine, cytosine, guanine and Uracil

Solution:[ Correct Answer : C ] have been shown to act in the form of triplet; each triplet behaving as a code
for the synthesis of a particular amino acid.
O O
|| || [6] The number of electrons required to deposit 1 gm atom of aluminium (at. wt.
Pyrophosphoric acid H − O − P − O − P − O − H = 27) from a solution of aluminium chloride will be ............ N (where N is Avo-
| | gadro's number)
[ AIIMS 1992 ]
OH OH
[3] 1 mol of an octahedral metal complex with formula MCl3 · 2 L on reaction with (A) 1 (B) 2
excess of AgNO3 gives 1 mol of AgCl. The denticity of Ligand L is ...... . (Integer
answer) (C) 3 (D) 4
[ JEE MAIN 2021 ]

(A) 3 (B) 4
Solution:[ Correct Answer : C ]
(C) 2 (D) 1
(c) 1 g atom of Al = 3 equivalent of Al = 3 faraday charge
3 mole electrons = 3 N electron.
Solution:[ Correct Answer : C ]
[7] Which of the following will not be soluble in sodium hydrogen carbonate?
[ NEET 2014 ]
MCl3 .2 L octahedral
Ex.AgNO
MCl3 · 2 L −→ 3 1 mole of AgCl (A) 2, 4, 6− Trinitrophenol (B) Benzoic acid
Its means that one Cl− ion present in ionization sphere.
∴ formula = [MCl2 L2 ] Cl (C) o− Nitrophenol (D) Benzenesulphonic acid
For octahedral complex coordination no. is 6
∴ L act as bidentate ligand

[4] Which of the following compounds will undergo decarboxylation on heating ?

Page No : 7
 Solution:[ Correct Answer : C ] Solution:[ Correct Answer : B ]

(pH+=) 2
H = 0.01 M = Cα = 0.1 × α
α = 0.1
i = 1 − α + nα
= 1 − 0.1 + 2 × 0.1
= 1.1
= 1 × CRT

[12] The structure of salol is

While 2, 4, 6 -trinitrophenol, benzoic acid and benzene sulphonic acid are (A) (B)
soluble in NaHCO3
Infact,
Acid + N aHCO3 −→ Salt + H2 CO3
This reaction is possible in forward direction if acid is more acidic than H2 CO3
o-nitrophenol is less acidic than H2 CO3 . Hence, it is not soluble in sodium
hydrogen carbonate.

[8] CrO3 dissolves in aqueous N aOH to give

(C) (D)
(A) CrO42− (B) Cr(OH)−
3

(C) Cr2 O72− (D) Cr(OH)2

Solution:[ Correct Answer : A ]

(a)CrO3 + 2N aOH → N a2 CrO4 +H2 O

Yellow solution
[9] The half life period of a gaseous reactant undergoing thermal decomposition
was measured for various initial pressures ′ p′0 as follows : Solution:[ Correct Answer : B ]
P0 (mmHg) 250 300
t1/2 (minutes) 135 112.5
The order of reaction is -
[13] Identify the strongest base from the given compounds
(A) 0 (B) 1
(A) (B)
(C) 2 (D) 3

Solution:[ Correct Answer : C ]

P(mm) 250300 400450

t1/2 (min)136112.585 75.5
Now,
t1/2 ∝ [A ]1n−1 (C) (D) All have same basic strength
0
t1/2 (1) [A0 ]n−1
2
=
t1/2 (2) [A0 ]n−1
112.5
( 400 )1n−1 ( 4 )n−1
85
= 300
= 3
1.323 = (1.333)n−1 ⇒ n − 1 = 1 ⇒ n = 2
∴ Order of reaction, n = 2

[10] N H3 + O2 −−→ A + H2 O; Solution:[ Correct Answer : A ]

Pt
∆
A + O2 → B
B + O2 + H2 O → C
A, B and C are
[14] The reaction of an ester RCOOR′ with an alcohol R′′ OH in the presence of
(A) N2 O, N O2 and HN O3 (B) N O, N O2 and HN O3 an acid gives

(A) RCOOH (B) R′ COOH

(C) N O2 , N O and HN O3 (D) N2 O, N O and HN O3
(C) R′′ COOR (D) RCOOR′′
Solution:[ Correct Answer : B ]

Ostwald proces Solution:[ Correct Answer : D ]

N H3 + O2 → N O + H2 O
H⊕
N O + O2 → N O 2 (d) R − COOR′ + R′′ OH ←→ R COOR′′ + R′ OH
N O2 + O2 + H2 O → HN O3 The exchange of alcohol residue known as alcoholysis or trans esterification

[11] pH of a 0.1 M monobasic acid is found to be 2. Hence its osmotic pressure at a [15] The end product of the reaction ethyl amine −
HNO2 P Cl5
−−→ A −−−−→ B −−−−→ C is
KCN
given temperature T K is

(A) 0.1 RT (B) 0.11 RT (A) Ethyl amine (B) Diethyl amine

(C) 1.1 RT (D) 0.01 RT (C) Propane nitrile (D) Triethyl amine(e)Methyl amine

Page No : 8
 Solution:[ Correct Answer : C ] Solution:[ Correct Answer : D ]

(c) C2 H5 N H2 + HN O2 → C2 H5 O H + N2 + H2 O ∆Tf = Kf m
(A) where m = molality
C2 H5 OH + P Cl5 → C2 H5 Cl + P OCl3 + HCl 273 − 268 = 1.86 × w
(B) M ×V
C2 H5 Cl + KCN → C2 H5 CN +KCl 5 = 1.86 × 32 w
×10
(C)Propane nitrile
w = 5 ×32 × 10
[16] The IU P AC name of [Cr(en)3 ]Cl3 is 1.86
= 860.2 ≈ 868.06 g

(A) triethylene diaminechromium (III) chloride [21] 2 gm of benzoic acid ( C6 H5 COOH ) dissolved in 25 gm of benzene shown
a depression in freezing point equal to 1.62 K . Molal depression constant for
(B) tris(ethylenediammine)chromium (III) chloride benzene is 4.9 KKg mol−1 . The % of benzoic acid in dimeric form is ......... %.

(C) tris(ethylenediamine)chromium (III) chloride (A) 97.4 (B) 99.2

(D) tris(ethylene diamine)chomium (III) chlorido (C) 86.0 (D) 87.5

Solution:[ Correct Answer : C ]

Solution:[ Correct Answer : B ]
Theory based
Given,
[17] Sulphide ores are generally concentrated by WB = 2 g, Kf = 4.9 K Kg mol−1
WA = 25 g, ∆Tf = 1.62 K
(A) Froth floatation process (B) Magnetic separation Now,
WB
∆Tf = Kf × M × 1000
WB A
(C) Gravity separation (D) By hand picking MB = 4.9×2×1000 = 241.98 g/mol
1.62×25
2C6 H5 COOH ⇌ (C6 H5 COOH)2
Solution:[ Correct Answer : A ] If x is the degree of association, (1 − x) mole of benzoic acid left undissociated
8 corresponding x/2 as associated moles of C6 H5 COOH at equilibrium.
(a)Froth floatation method is based on the fact that the surface of sul- ∴ Total number of moles of particles at eqm,
phide ores is preferentially wetted by oil while that of gangue is wetted by ⇒ 1 − x + x2 = 1 − x2 = i
Normal
water. ⇒ i = Abnormal molecular mass
⇒ 1 − 2 = 241.98
x 122
[18] The number of moles of SO2 Cl2 in 13.5 gm is
⇒ x2 = 1 − 241.98 122
⇒ x = 0.992 = 99.2 %
∴ Degree of association of benzene = 99.2 %
(A) 0.1 (B) 0.2
[22] Copper crystallizes in f.c.c. with a unit cell length of 361 pm. What is the radius
(C) 0.3 (D) 0.4 of copper atom ? ............ pm

(A) 108 (B) 127

Solution:[ Correct Answer : A ]
(C) 157 (D) 181
(a) Gram molecule of SO2 Cl2 = 135
w
n= m = 13.5 = 0.1.
135 Solution:[ Correct Answer : B ]
[19] The product formed by the reaction of an aldehyde with a primary amine is
[ NEET 2016 ] For f.c.c. structure
radius of atom = √ a
= 361
√ = 127.56 pm
(A) carboxylic acid (B) aromatic acid 2 2 2 2

[23] The product 'B' is

(C) Schiff's base (D) ketone

Solution:[ Correct Answer : C ]

(A) (B)

Aldehyde + Primary amines → Schiff base (C) (D)

Schiff bases can be synthesized from an aliphatic or aromatic amine and a
carbonyl compounds by nucleophilic addition-elimination reaction

[20] How many grams of methyl alcohol should be added to 10 litre tank of water
to prevent its freezing at 268 K ? ............. g (Kf for water is 1.86 K kg mol−1 )
[ JEE MAIN 2013 ]

(A) 880.07 (B) 899.04

(C) 886.02 (D) 868.06 Solution:[ Correct Answer : C ]

It's obvious.

[24] The half life for the reaction N2 O5 ⇌ 2N O2 + 21 O2 in 24 hrs at 30 o C. Start-

ing with 10 g of N2 O5 how many grams of N2 O5 will remain after a period of
96 hours ........... g

Page No : 9
 (A) 1.25 (B) 0.63 (A) a = b = c ; α = β = γ = 90o
(B) a = b ̸= c ; α = β = γ = 90o
(C) 1.77 (D) 0.5
(C) a ̸= b ̸= c ; α ̸= β ̸= γ ̸= 90o
Solution:[ Correct Answer : B ] (D) a = b ̸= c ; α = β = 90o , γ = 120o

(b)k = 0.693
hr−1 = 2.303
log 10 Solution:[ Correct Answer : C ]
24 96 a−x
or log a−x
10
= 1.2036 or 1 − log(a − x) = 1.2036
or log(a − x) = −0.2036 = 1.7964
or (a − x) = antilog 1 .7964 = 0.6258 gm [30] The structure of products E − H, respectively are
[25] Copper sulphate solution is electrolysed between two platinum electrodes. A
current is passed until 1.6 g of oxygen is liberated at anode. The amount of cop-
per deposited at the cathode during the same period is .............. g [At. mass of
Cu = 63.6]

(A) 6.36 (B) 63.6

(C) 12.7 (D) 3.2

Solution:[ Correct Answer : A ]

For O2 , m = E×QnF
and Q = mE × nF = 0.2 F
E×Q
For Cu, m = nF = 63.5 2×F
× 0.2 F = 6.36 g
Hence; (1) is correct.

[26] Hot and conc. nitric acid when reacts with copper, the gas obtained is

(A) N2 (B) Nitrous oxide

(C) N O (D) N O2

Solution:[ Correct Answer : D ]

(d)Cu + 4HN O3 → Cu(N O3 )2 + 2N O2 + 2H2 O

[27] Product which is not expected to be formed is

(A) 3, 2, 6, 7 (B) 4, 5, 6, 1

(C) 3, 4, 5, 2 (D) 3, 2, 4, 5
(A)
Solution:[ Correct Answer : A ]

CH3
(B) |
CH3 − CH2 − CH = C − CH = O

(C)

[31] For a first order reaction A → B, the reaction rate at reactant concentration of
0.01 M is found to be 2.0 × 10−5 M sec−1 . The half life period of the reaction
is .......... sec
(A) 333 (B) 300
(D) All
(C) 346.5 (D) 220
Solution:[ Correct Answer : A ]
Solution:[ Correct Answer : C ]

[28] In a zero-order reaction for every 10o rise of temperature, the rate is doubled. r = K[A] ; t1/2 = 0.693
K
If the temperature is increased from 10 C to 100 C, the rate of the reaction
o o
will become ......... times [32] The sum of number of first and second nearst neighbours in F CC closed pack-
ing
(A) 64 (B) 128
(A) 12 (B) 6
(C) 256 (D) 512
(C) 18 (D) 24

Solution:[ Correct Answer : D ]

∆T
rate of reaction will become = (2) 10 times
100−10
= (2) 10

= 29 = 512 times

[29] The triclinic unit cell has following parameters

Page No : 10
 Solution:[ Correct Answer : C ] Solution:[ Correct Answer : A ]

[( ) ( ) ]
Lattice sites a(lx̂ + mŷ + nẑ) a l + 12 x̂ + m + 12 ŷ + nẑ
[( 1
) ( 1
) ]
a l + 2 x̂ + mŷ + n + 2 ẑ
[ ( ) ( ) ] [35] How many secondary amine are possible with molecular formula C4 H11 N H2
a lx̂ + m + 12 ŷ + n + 12 ẑ
Lattice point per conventional cell: 4 = 8 × 18 + 6 × 12 = 1 + 3 Volume (con- (A) 4 (B) 3
ventional cell): a3 Volume (primitive
√( ) cell)(: a) /4 Number of
3 nearest neighbors:
√
12 Nearest neighbor distance: a 2 2
+ a2 + (0)2 = 22 a ≈ 0.707a (C) 2 (D) 1
2
Number of second neighbors: 6 Second neighbor distance: a
For the site (0, 0, 0), ( ) ( ) ( ) Solution:[ Correct Answer : B ]
12 nearest neighbors: ± 12 , ± 12 , 0 , ± 12 , 0, ± 12 and 0, ± 12 , ± 12
6 nest nearest neighbors: (±1, 0, 0), (0, ±1, 0)and(0, 0, ±1)
There are three possible secondary amines possible with the molecular
[33] Drugs used to bind to receptors, inhibiting its natural function and blocking a formula C4 H11 N . These are listed below
message are called. 1. N −methyl n−propyl amine
[ JEE MAIN 2022 ] 2. N −methyl isopropyl amine
3. N, N −dimethyl amine
(A) Agonists (B) Antagonists
[36] A(g) → 2B(g) initially 2 moles of A are taken in 5 litre vessel. After 20 min,
(C) Allosterists (D) Anti histaminists [A] =
[B]t
. Find half life time of A in the first order reaction .......... min
t 2

(A) 20 (B) 10
Solution:[ Correct Answer : B ]
(C) 40 (D) 5
Factual

[34] The major product of the reaction,

Solution:[ Correct Answer : A ]

[37] The Crystal Field Stablilisation Energy (CF SE) for [CoCl6 ]4− is 18000 cm−1 .
The CF SE for [CoCl4 ]2− will be ......cm−1
[ NEET 2019 ]

(A) 6000 (B) 16000

(C) 18000 (D) 8000

(A) (B)
Solution:[ Correct Answer : D ]

∆tetrahedral = 4
9
× ∆octahedral
= 94 × 18000
= 8000cm−1

[38] The IU P AC name for the complex [Co(N O2 )(N H3 )5 ]Cl2 is :

(A) Nitro- N -pentaamminecobalt (III) chloride

(B) Nitro- N -pentaamminecobalt (II) chloride

(C) Pentaamminenitrito- N -cobalt (II) chloride

(D) Pentaamminenitrito- N -cobalt (III) chloride

(C) (D) None of these
Solution:[ Correct Answer : D ]

IU P AC rule

[39] Compound A was treated with a large excess of CH3 M gBr. The resulting
product was exposed to P OCl3 /pyridine to give compound B, as one of many
products
Which of the following compounds can be A ?

Page No : 11
 [42] The number of unpaired electrons in N i(CO)4 is
(A) [ AIIMS 1997 ]

(A) 0 (B) 1

(C) 3 (D) 5

Solution:[ Correct Answer : A ]

(a) Due to presence of strong ligand all the e− get paired. So no. of un-
paired electrons are 0.

(B) [43] The rate constant of a first order reaction whose half-life is 480 sec , is

(A) 2.88 × 10−3 sec−1 (B) 1.44 × 10−3 sec−1

(C) 1.44 sec−1 (D) 0.72 × 10−3 sec−1

Solution:[ Correct Answer : B ]

(b)t1/2 = 0.693
k
, k= 0.693
480
= 1.44 × 10−3 sec−1 .

[44] What is the product obtained in the following reaction ?

[ AIPMT 2011 ]
(C)

(A) (B)

(D)

(C) (D)

Solution:[ Correct Answer : A ]

Solution:[ Correct Answer : D ] Followed by Markownikoffs rule.

CH3 − CH2 − C ≡ CH + HCl →
(d) P OCl3 /Pyridine is dehydrating agent. It will cause elimination of I
H2 O to give alkene |
CH3 CH2 − C = CH2
[40] Thermite is a mixture of | HI
−−→ CH3 − CH2 − C − CH3
Cl
|
(A) F e powder and Al2 O3 (B) Al powder and F e2 O3 Cl

(C) Cu powder and F e2 O3 (D) Zn powder and Cr2 O3 2 − chloro − 2 − iodo bu tan e
Zn−Hg
[45] −→ X − → Y ; Y is
∆
−−−−−
HCl
Solution:[ Correct Answer : B ]
(A) (B)
Thermite is the mixture of iron oxide F e2 O3 (rust) and aluminum pow-
der.
When it is ignited the aluminum powder reacts with the O3 part of the rust in
a highly exothermic reaction, the resulting product is molten iron. Thermite is
commonly used in welding because the molten iron has the ability to seep into
cracks in metal.

[41] Acetaldehyde on treatment with dil. N aOH followed by heating gives (C) (D)

(A) CH3 CH2 CH2 CH2 OH (B) CH3 CH2 CH2 CHO

(C) CH3 − CH = CHCHO (D) CH3 − CH = CHCH2 OH

Solution:[ Correct Answer : C ]

(c) CH3 CHO −−−−−−−→ CH3 − CH −CH2 − CHO

dil N aOH
|
OH
Aldol
Heat
−
−−−
→ CH3 − CH = CH − CHO + H2 O

Page No : 12
 [48] Number of electrons that Vanadium (Z = 23) has in p-orbitals is equal to ......
[ JEE MAIN 2021 ]
Solution:[ Correct Answer : C ]
(A) 24 (B) 66

(C) 89 (D) 12

Solution:[ Correct Answer : D ]

: 1s2 2s2 2p6 3s2 3p6 3d3 4s2

23 V
Number of electrons in p-orbitals is equal to 12.00

[46] Isoniazid is used in the treatment of tuberculosis and multiple sclerosis. Iden- [49] KCN reacts readily to give a cyanide with
tify the least basic N present in it
(A) Ethyl alcohol (B) Ethyl bromide

(C) Bromobenzene (D) Chlorobenzene

Solution:[ Correct Answer : B ]

(A) I (B) II alcohol

(b)C2 H5 Br + KCN −−−−→ C2 H5 CN + KBr

(C) III (D) Not comparable [50] The molarity of a solution obtained by mixing 750 mL of 0.5(M ) HCl with
250 mL of 2(M ) HCl will be .........M
[ JEE MAIN 2013 ]
Solution:[ Correct Answer : B ]
(A) 0.87 (B) 1.00

(C) 1.75 (D) 0.97

[47] The correct order of reactivity towards the electrophilic substitution of the
compounds aniline (I) benzene (II) and nitrobenzene (III) is
[ AIPMT 2003 ] Solution:[ Correct Answer : A ]

(A) I > II > III (B) III > II > I From Molarity equation:
M1 V1 + M2 V2 = M × V
(C) II > III > I (D) I < II > III M = M1 V1 V+M2 V2

where V = total volume

= 750×0.5+250×2 = 0.875 M
Solution:[ Correct Answer : A ] 1000

Nitro group is an electron withdrawing group. It removes electron den-

sity from aromatic nucleus.
Thus, the reactivity of nitrobenzene towards electrophilic aromatic substitution
reaction is less.
Amino group is an electron releasing group. They increase the electron density
on benzene ring.
Thus, aniline is more reactive towards electrophilic aromatic substituion
reaction than benzene.
Hence, the correct order of reactivity towards the electrophilic substitution of
the compounds, aniline (I),benzene (II),nitrobenzene (III) is I > II > III.


Chemistry - Section B - SUBJECTIVE



S.A [2 Marks]


[53] X, Y, Z reaction are respectively

[51] A tetra-atomic molecule (A) on reaction with nitrogen (I) oxide, produces two
substances (B) and (C). (B) is a dehydrating agent in its monomeric form while
substance (C) is a diatomic gas which shows almost inert behaviour. The sub-
stances (A) and (B) and (C) respectively will be
Solution:
P4 + 10N2 O → P4 O10 + N2
So A is P4 which is a tetra-atomic molecule.
B is P4 O10 which is dehydrating agent.
C is N2 is diatomic gas which shows almost inert character.
KHSO LiAlH
[52] Glycerol −−−−−−→
4
(A) −−−−−→
4
(B) ; (A) and (B) are respectively

Solution:
Solution:
X = Hydroboration oxidation,Y = oxymercuration and demercuration, Z =
Simple hydration reaction

[54] Number of Cl = O bonds in chlorous acid, chloric acid and perchloric acid re-
spectively are :
[ JEE MAIN 2021 ]

Page No : 13
 [57] Consider the following sequence of reactions
The end product (B) is:
Solution:

Solution:

Number of Cl = O bonds
Br
[55] HO − CH2 − CH2 − CH2 − CH2 − CH = CH2 −−−→
2
Product ?

Solution:

[56] An unknown compound (A) (molarmass = 180) on acylation gives a product

(molar mass = 390) than find the number of hydroxyl group present in com-
pound (A) .
Solution:
m′ −m
(a) Number of Hydroxyl group n = 42 [58] The boiling point of a solution of 0.1050 gm of a substance in 15.84 gram
Where m′ = mass of product of ether was found to be 100o C higher than that of pure ether. What is the
m = unknown compound molecular weight of the substance [Molecular elevation constant of ether per
n = 390−180 =5 100g = 21.6]
42
Solution:
×w×1000
(b)m = Kb∆T ×W
= 143.18
b


Below question is for 3 marks


[59] Reactant (A) in this reaction is

Solution:
In CsCl, Cl− lie at corners of simple cube and Cs+ at the body centre, Hence,
along the body
√ diagonal,√Cs and Cl touch each other so
+ −

FD = b = a2 + a2 = 2a
In △F D, √
c2 = a2 + b2 = a2 + ( 2a)2 = a2 + 2a2
2
c =√3a 2

c = 3a
Solution: AS√△AF D is an equilibrium triangles,
∴ 3a = √ 4r
⇒ r = 43a
√ √
Hence, rc + ra = 2r = 2 × 3a
4
= 3a
2

[63] The step shown below is a recent synthesis of corannulene.

Product (A) is
[60] Compound A, C8 H10 O, is found to react with NaOI (produced by reacting Y
with N aOH) and yields a yellow precipitate with characteristic smell.
A and Y are respectively
[ NEET 2018 ]
Solution:

Solution:
(a) P d/C (or) Se is used to aromatize the acyclic ring.

[64] The final product [D] of the reaction is

O EtOH 2 mole M eM gBr
CHCl3 −−→
2
[A] −−−−→ [B] −−−−−−−−−−−−→
hv
Haloform reaction is shown by compound having CaOCl2 ∆
[C] −−−−−−→ [D] −→ CH3 − C − CH3
||
[61] Identify product Z in the following reaction sequence O
1.C6 H5 M gBr
N aCN diethylether Solution:
H2 C = CHCH2 Br −−−−−→ Y −−−−−−−−−−→ Z
2. H3 O +

Solution:

[62] Which of the following expressions is correct in case of a CsCl unit cell (edge
length, a )

Page No : 14
 
Below question is for 4 marks


[68] In the following reaction sequence, structures of A and B, respectively will be

[ JEE MAIN 2020 ]
[65] Ferrous sulphate heptahydrate is used to fortify foods with iron. The amount
(in grams) of the salt required to achieve 10 ppm of iron in 100 kg of wheat is
Atomic weight : F e = 55.85; S = 32.0 O = 16.00
[ JEE MAIN 2020 ]
Solution:
FeSO4 · 7H2 O(M = 277.85)
ppm = wt.wt.ofofwheat
Fe
× 106
let the wt. of salt be = wgm Solution:
w
moles = 277.85
( W )
wt. of Fe = 277.85 × 55.85 gm
W ×55.85
10 = 277.85
105
× 106
277.85
W = 55.85
= 4.97

[66] An optically active compound X has molecular formula C4 H8 O3 . It evolves

CO2 with N aHCO3 . ′ X ′ Reacts with LiAlH4 to give an achiral compound.
′ X ′ is

Solution:

[67] The number of moles of hydrogen molecules required to produce 20 moles of

ammonla through Haber's process is
[ NEET 2019 ]
Solution:
N2 (g) + 3H2 (g) → 2NH3 (g)
2 mole NH3 (g) requires 3 mole H2 (g)
20 mole NH3 (g) requires
= 23 × 20 mole H2 (g)
= 30 mole

Page No : 15