‘Seat Number BP 102T Pharmaceutical Analysis - I (711102) P. Pages : 3 Time : Three Hours Instructions to Candidates: 4. Do not write anything on question paper except Seat No. ¥ 2. Graph or diagram should be drawn with the black ink pen being used fg¥ writing paper or black HB pencil. 3. Students should note, no supplement will be provided. & Y 4, All questions are compulsory. v 5. Draw well labelled diagram wherever necessary. 4: Multiple choice questions. 20 i) Non aqueous titration is carried out for rid a) Water insoluble drugs b) Weakly acidiagug c) Weakley baric drugs d) All ” ii) Which one is Aprotic solvents a) Chloroform b) Beng ¢) Both d) No iii) Proteogenic solvent is a) Sulphuric acid Hydrochloric acid ©) Nitric acid All Kv iv) Protophillic solvent is ¢ a) Sodium hydroxide ¢ b) Lithium methoxide ¢) Sodium methoxide a d) None v) Which one is useft oven acu reton a) leveling Solvgats b) differentiating solvents ©) both * d) None vi) Perchioriggid can be standardized by using. a) BengBic acid b) Oellic acid ¢)_ Potassium hydrogen phthalate ‘Tartaric acid “jx Which one is used as indicator for non-aqueous titration? a) Crystal violet b) Thymol blue c) Oracet blue B d) All 4 P.T.O‘Bal - 003 vil) Which ofthe following is added forthe titration of halogen acid salt of weak bases? a) Lead acetate b) Mercuric acetate ¢) Bismuth iodide d) Copper Sulphide ix) Potentiometric titration is used in nonaqueous titration when a) Colour of solution is high b) Colour of solution is low c) Both d) None x) Which one is polydentate. a) Ethylene diamine b) EDTA c) Both d) None xi) Which one is sequestering agent? a) Salicylaldoxime b) _ 8-hydroxy quinoline c) EDTA d) All xii) The complexomettic tiation where EDTA is used, carried oy basic pH. Why? a) For the stability of complex formed ! b) Reaction rate is optimum in basic pH » ¢) There is less number of side Reaction ? d) All ie Ki xii) Dimercaprol is used as complexing agent for copfeson of. a) Mercury b)Arseni ©) Lead a) xiv) Indicator used in complexometric tira a) Eriochrome black T b) _gStylencl orange ©) Mordant black Il d xy) In which the following titration g®xidation-reduction” (Redox) step can be expected é _ a) Acid-base titration, —b) —Ceriometry ¢) Gay-lussac methogs" d) Aquametry xvi) Which of the followi@a is volumetry. a) Potentiomet b) _ Voltammetry c) Gravimet d) Geometry photometric Reaction base Reaction ©) _gigentometric Reaction dy Precipitation Reaction Bsccharimety is the practical application of a) Acidimetry b) Alkalimetry ¢) Potentiometry 4) Polurimetry es term for expressing the concentration and used in‘Bal - 003 xix) Which cell used in potentiometry. a) Combined glass electrode b) Normal hydrogen electrode c) Low type electrode d) Dip type electrode xx) Saturated Calomel electrode involver saturated solution of. a) KCI b) KBr » o) kJ d) KIO3 » ) Solve any two, é 20 a) Explain theories of indicator used in acid-base titration, ¥ 5) Write note on Volhard method. Explain the array on sodium chloride ae Reaction. ¢ FS ©) Whats gravimetric analysis? Explain different steps involve ingravimetric analysis. Write any seven. 35 a) State and explain the low of mass action. b) Write note on Redox indicator. ©) Explain the factor affecting purity of preci 2) Define errors & Explain its type in Analyftal Chemistry, ©) Explain Fajan's method in deta gh f) Add a note on masking & DewiSking agents, 9) Explain in details non-aqySous titration. h) Explain Mohr's met in detail, pron, and factor calculations for sodium chloride array. i) Give princip!