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R.Sathia- PhD Scholar, K. Ganesh Babu- Professor, Manu Santhanam- Assistant Professor
Indian Institute of Technology Madras, Chennai, India
ABSTRACT: The objective of the present work is to find the durability of the fly ash based
Geopolymer prepared with sodium silicate and sodium hydroxide as activators. The concretes
were prepared with varying fly ash content of 350, 450 & 550 Kg/m3 and activator solution to
fly ash ratio of 0.4 and 0.5. Compressive strength in the range of 10-60 MPa was obtained.
The performance of these concretes in aggressive environments was also studied, using tests
on absorption, acid resistance and potential. Results indicated that the water absorption
decreased with an increase in the strength of the concrete and the fly ash content. All
geopolymer concretes showed excellent resistance to acid attack (3% H2SO4) compared to the
normal concrete.
1. INTRODUCTION
Geopolymer [1] is a new material which is being used for construction all over the world. As
a new material for construction not much of information is available on the durability of
geopolymer concrete. The durability of concrete is an important requirement for the
performance of the structure in aggressive environments throughout its design life period.
The durability of concrete primarily depends upon its permeability characteristics.
Impermeable concretes can resist the ingress of aggressive ions into the concrete and there by
reduce the damages occurring due to the deterioration of concrete and the corrosion of steel in
concrete. However, there appears to be no comprehensive information of the permeability
characteristics and deterioration characteristics of geopolymer concretes Moreover, for such a
comprehensive understanding it is also essential that these concretes should be well designed
at any particular strength.
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The 3rd ACF International Conference-ACF/VCA 2008
The choice of the activators mainly depends upon the reactivity and the cost of the activators
[8]. Literature indicates that sodium silicate solution in combination with sodium hydroxide
and potassium hydroxide is an effective activator. Compared to potassium hydroxide, sodium
hydroxide is cheaper and equally reactive. The chemical composition of activators used in
this study is shown in Table 2. Sodium hydroxide solution of 16M was prepared by mixing
the pellets with distilled water. The percentage of solids and liquids in the NaOH solution is
tabulated in Table 2. In order to improve the workability, a high range water reducing
admixture (SNP based) was used.
Oxides SiO2 Al2O3 Fe2O3 CaO Na2O MgO K2O SO3 LOI
% by 61.16 30.08 4.62 1.75 0.76 0.18 0.36 0.19 0.60
mass
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The 3rd ACF International Conference-ACF/VCA 2008
temperature of 85°C, and stored for 24hours.After curing; the specimens were allowed to cool
in air, demoulded and kept in open until the day of testing.
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The 3rd ACF International Conference-ACF/VCA 2008
studied through the acid attack; the corrosion potential of reinforcement has been studied
using potentials.
3.1 Absorption studies
This study was done to know the relative porosity or permeability characteristics of the
concretes, and was carried out according to ASTM C 642-82 at 28 days. The specimens used
for this test were 100 mm cubes. The percentage absorption was calculated using the equation
(2)
Absorption (%) = (w2 – w1)/ w1 x100 (2)
Where w1 = weight of specimen after complete drying at 105°C
w2 = final weight of surface dry sample after immersion in water at least 24 hours
The results of this study for all the concretes are presented in Fig.1. Fig 2 presents a typical
variation of absorption with time for the GC2 (20 MPa) concrete. The initial absorption
values (at 30 min) for all the concretes were compared with recommendations given by
Concrete Society (CEB) [10], and this comparison is presented in Table 4. From these results,
it can be seen that absorption values of the geopolymer concretes at all strength levels were
lower than the limit of 3% specified for good concretes. The final absorption results of these
mixes shows that the geopolymer concretes were having lower absorption rate compared to
normal concretes, and also decreasing with increasing strength.
Absorption (%)
Absorption rating Concrete quality
at 30 minutes
< 3.0 low good
3.0 to 5.0 average average
> 5.0 high poor
5 6
5
4
Absorption (%)
4
G2
A bsorption (% )
3
3
2 2
1
1
0
0 10 20 30 40 50 60 70 80
0
Time (hrs)
20MPa 60MPa
Fig.1 Variation in water absorption Fig.2 Variation of absorption with
time (20 MPa concrete)
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The 3rd ACF International Conference-ACF/VCA 2008
Corrosion potential is a technique used to detect the state of reinforcement without disturbing
the structure [10]. This is important because the intensity of corrosion of steel in concrete is
generally known only after the concrete has cracked or disrupted. At this stage, the
maintenance or rehabilitation of structures becomes very expensive. Therefore, it is essential
to know the state of reinforcement whether it is in active or passive condition well before the
spalling or cracking of concrete occurs. The open circuit potential of steel in different
concretes was measured by using a saturated calomel (i.e., mercury in saturated mercuric
chloride) electrode (SCE). The procedure given in ASTM C 876 was followed. The potentials
obtained are presented in Fig 3, where, we can see that the geopolymer concretes exhibited
low potentials compared to the other concretes. The potentials vary from -35 mV to -300 mV,
which shows probable corrosion indications. Generally to after 3 years only we will get stable
potentials, so, the half-cell potentials “may or may not be indicators of corrosion current”
(ASTM C 876) and, therefore, cannot be taken as absolute indicators of corrosion reactions.
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The 3rd ACF International Conference-ACF/VCA 2008
500
400
200
100
4. CONCLUSIONS
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The 3rd ACF International Conference-ACF/VCA 2008
REFERENCES
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Geopolymer ‘88’, First European conference on soft Mineralogy, Compiegne,
france.(1)
2. Rangan, B.V., and Hardjto, D. (2005), Development and properties of low calcium
fly ash based geopolymer concrete. Research report GC-1, Faculty of Engineering,
Curtin University of Technology, Perth, Australia.
3. Bakharev, T. (2005), Geopolymeric materials prepared using class Fly ash and
elevated temperature curing, Cement and Concrete Research, Vol.35, 1224-1232
4. Rangan, B.V., and Wallah, S.E. (2006), Low- calcium fly ash based geopolymer
concrete: long term properties. Research report GC-2, Faculty of Engineering,
Curtin University of Technology, Perth, Australia
5. Fernandez – Jimenez, A., and Palomo, A. (2006), Engineering properties of alkali
activated fly ash concrete. ACI material journal, Vol.106, 106-112.
6. Swanepoel, J.C., and Strydom, C.A, (2002), Utilization of fly ash in a geopolymeric
material, Applied Geochemistry, Vol.17, 1143-1148
7. Jo, B.–W., Park, S.-K and Park, M.-S. (2007). Strength and hardening
characteristics of activated fly ash mortars, Magazine of concrete research, Vol.39,
121-129.
8. Dinakar , P., and Ganesh Babu, K.(2004) High performance self compacting
concrete- A critical assessment, Proceedings of the International conference of fibre
composities, High performance concretes and smart materials, Vol II, 747-756,
Chennai, India.
9. Neville A. M. (1995) Properties of concrete, 4th Ed. New York: John Wiley & Sons.
10. CEB – FIP (1989) Diagnosis and assessment of concrete structures – state of
artreport,CEB Bulletin, 83-85.
10. Broomfield J. P. (1997) Corrosion of steel in concrete: understanding, investigation
and repair, E & FN SPON, London
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