Which will show goometrical i8omcrism '!

(A l CH,Cl-1 = NOH
Q.U ..
Which of the following is/are correct mal.Cbin; ?
---
w
(A) CH,-C-OH and H-C---OCH
w
1
- Mctamers

(B) CH ,-CH,-C =CH and CH,-C =C-cH,

- Position isomers .
H,C)C=NOH
(C) H1C
(C) CH,CH,CH,NH, and CH -ctt-CH
(D) HO-N = N-OH I I J

Which of the following molecules is/are identical with NH,

that represented by - Tautomen;
(D) CH3°"½0H and (CHJ 20
- Functional isomer

Q.15 Which of the following statements arc correct:

(A) Any chiral compound with a single asynnnetric
carbon must have a positive optical rotation if the
compound has the R configuration
HrhCH3
(B) !fa strucrure has no plane of symmetry it is chiral
(A) H3CbHOH (C) All asymmetric carbons are stereocentres.
(D)Alcobol and ether are functional isomers

CH3 Q.16 The isomerism observed in alkanes is :

H3CffiH (A) metamerism
(B) chain isomerism
(C) H><;.XOH
(C) position isomerism
OH
(D) geometrical isomerism
Which conformation of n-Butane has both plane of
symmetry and centre of symmetry absent ? Co.prebemioa # I (Q. No. 17 to 19)
(A) fully eclipsed (B) Gauche Taatoaerisa :
(C) Partially eclipsed (D)Anti Structural Isomers that undergo rapid interconversions
Which of the following statements is/are not correct? and exist in dynamic equilibrium are known as
(A) Metamerism belongs to the category of structural Tautomers and relationship between them is known as
1somensm Tautomerism. Tautomers generally have different
(B) Tautomeric structures are the resonating structures functional groups.
of a molecule At equilibrium more stable tautomer is present in higher
(C) Keto form is always more stable than the enol form amount but the ratio remains same until and unless
(D) Geometrical isomerism is shown only by alkenes change is made externally. Tautomerism actually arises
due to rapid oscillation of an atom between two
3 Which of the following statements is/are correct?
(A) A meso compound has chiral centres but exhibits polyvalent atoms in a molecule.
no optical activity
(B) A meso compound has no chiral centres and thus fl OH
I
are optically inactive. TH 2- CH -..;;--- CH, = CH
(C) A meso compound has molecules which are
superirnposable on their mirror images even though H Keto form enol form
they contain chiral centres
Above is an example of Keto-enol tautomerism.
(D) A meso compound is optically inactive because
the rotation caused by any molecule is cancelled Condition for this type of keto enol tautomerism is
by an equal and opposite rotation caused by presence of a-H. Amount of enol at equilibrium is
another molecule that is the mirror image of the known as enolic content It is more if enol is more stable
first and less ifketo is more stable.
49