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SECTION – A
1. ABC
m 2 m 2
Sol. IB sin2 , IA
3 12
IB rod
IA
2. A
Sol. For open circuit, current = 0.
3. ABC
Sol. Assume x-axis along OA and y-axis perpendicular to it in the plane of ring.
After 1st collision
v
Velocity of particle = along x-axis
2
v
And velocity of ring = along y-axis
2
v ˆ v ˆ
After second collision velocity of ring = i j
2 2
Velocity of particle = 0
R 2
Time to return at point A = 4
v
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AITS-CRT-II (Paper-2)-PCM(Sol.)-JEE(Advanced)/20 2
4. AB
E 12 4
Sol. 2 4 6 E 2 1
1 1 1 2
2 4 6
12 (6.6 2 0.5)
E = 6.6, 1.1
4
5. A
Sol. VB 35 103 ( 10)3 10 5 5 VA
VA – VB = 0.
6. ABCD
Sol. L.C. = pitch / number of division on circular scale. The result has to be expressed upto
least number of significant figures.
7. B
12420
Sol. E 0 eV 3.55 eV
3500
3500 A
B E 0 A
3500 A
8. AC
Sol. L = 50
1 10 2
XC = 100 10 2
C
10 2 2 10 2 2 45°
iC ; iL
100 10 50 5 45° 20 V
2 2
i i i C L
2 10 10 2
= 1 4 = = 0.316 A 10 2
10 10
V100 = 10 2
9. A
Sol. O to A the slope is positive.
A to B the slope is negative.
B to C the slope is positive.
At A the slope is zero
10. B
Sol. O to A the graph is convex.
A to B the graph is first convex and then concave.
B to C the graph is concave.
At point A the graph is convex.
11. A
12. A
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3 AITS-CRT-II (Paper-2)-PCM(Sol.)-JEE(Advanced)/20
14. 00004.00
1 20g ' 1 4 5 15g f' 15
Sol. 300 f ,f f ' 259.80 Hz
2L 2L 5 15 300 20
15. 00000.80
1.5
Sol. 2 1 A 1 40 0.80 downward
1 5/ 4
16. 00001.00
1
Sol. h uy t gt 2
2
uy 2u 2u sin
t1 t 2 T
1 g g
g
2
17. 00002.00
Sol. F3 F1 F2 (triangle law), so resultant force 2F2 .
2F2
a
m
18. 00000.25
m m
Sol. Applying conservation of momentum mv 0 v ' v ' 2v
2 2
1m 2 1 1 GMm
Increase in mechanical energy of the system 2v mv 2 mv 2
2 2 2 2 2 2R
mgR2 mgR
4R 4
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AITS-CRT-II (Paper-2)-PCM(Sol.)-JEE(Advanced)/20 4
Chemistry PART – II
SECTION – A
19. ACD
Sol. ln [A]t = ln [A]0 – kt (for 1st order reaction)
slope of ln [A]t vs t = -k
k 0.0231 sec 1
0.693
t1 30 sec
2 0.0231
Half life is independent of initial concentration. So a plot of t1/2 vs concentration will give
a straight line parallel to x – axis.
1 100
t 90% ln 100 sec
0.0231 10
At higher temperature, value of rate constant k increases. So, the slope of the plot ln[A]t
vs t will increase and the line will become steeper.
20. AC
Sol. SO2 > CH4 (depends on van der Waal’s force)
CO > N2 (CO is polar and N2 is non-polar)
21. C
Sol. Charge = Area of (I vs t) curve
1 1
= 10 (100 10–3) + 10 (100 10–3) + 10 (100 10–3)
2 2
1 1
= + 1 + = 2 coulomb
2 2
22. BD
Sol. Both the molecules have symmetrical structure.
F
Br Cl F F
P S
Br Br
Cl F F
23. AC
Sol.
NH4 H2O
NH4OH H
Fe2 H2O
Fe OH H
The H+ ions combine with or remove OH– ions by forming water and drives the reaction
towards forward direction.
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5 AITS-CRT-II (Paper-2)-PCM(Sol.)-JEE(Advanced)/20
24. ABD
Sol. (C) cannot be prepared by hydrolysis of any alkene.
25. ABC
Sol. RCOONa RCOO Na
RCOO R CO2
CH3CH2 CH3CH2 CH3CH2CH2CH3
CH3CH2 CH3
CH3CH2CH3
CH3 CH3
C2H6
26. ABCD
Sol. All the statements are correct.
27. A
Sol. OH OH
H H2O Rearranges to more
CH3
CH3 CH3 stable carbocation
Ph Ph Ph
28. C
Sol. Self explained
29. C
Sol. O Me O O Me
HO - C C- O-H HO - C H
Et Et
30. B
Sol. COOH Br
D H AgOH/ D H
Br2 /CCl4
H3C H H3C H
Ph Ph
SECTION – C
31. 00002.00
Sol. Nitrogen and bismuth do not form pentachloride. In case of ‘N’, no vacant orbitals are
present and for ‘Bi’, inert-pair effect is most prominent.
32. 00004.00
Sol. 1F deposits 1 eq or ½ mole of Cu
8F will deposit 4 mole of Cu
33. 00005.00
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AITS-CRT-II (Paper-2)-PCM(Sol.)-JEE(Advanced)/20 6
1 1 A0 1 1 100
Sol. In ; In
t avg t A t 7.2 t1 100
100
3
1 1 100
In
7.2 t 2 100 200
3
3
t2 – t1 = 7.2 In3 – 7.2In =5
2
34. 00000.46
211
Sol. 83 Bi 81Tl207 2He 4 ; total time = n half-life
initial moles 2
Moles of substance left after n halves = 4 0.125
2n 2
Moles of He produced = 2 – 0.125 = 1.875
Pressure developed due to
1.875 0.0821 300
He 0.4618 atm
100
35. 00001.55
0.0591 0.3
Sol. 1.50 E o log 3
3 0.1
Eo = 1.55
36. 00001.12
0.0591
Sol. EoCell log K eq
2
2
0.0591 D D
0.003 log 2
1.123
2 H H
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7 AITS-CRT-II (Paper-2)-PCM(Sol.)-JEE(Advanced)/20
SECTION – A
37. AB
Sol. Let the length of the sides of the rhombus be l
Area = l2 sin30 =2 l = 2 unit
OB2 = OA2 + AB2 – 2OA .AB cos150 B
C
3
= 4 + 4 – 2 (4). = 4 (2 + 3 ) 150
2
60 A
OB = 2 2 3 30
O
B 4 2 3 ,
4 2 3 1 3 , 1 3
Hence coordinates of B can be 1 3 , 1 3
or 1 3 , 1 3
38. ACD
Sol. z2 + az + a2 = 0
z = a, a2 ( where ‘’ is non real root of cube unity )
locus of z is a pair of straight lines
and arg (z) =arg(a) + arg() or arg(a) + arg(2)
2
arg(z) =
3
also, |z| = |a||| or |a| |2| |z| = |a|
39. ABCD
cos x sin x
Sol. f(x) = 2
> 0 cosx > sinx
1 sin x cos x
7 3 5
x 2, , , 2
4 4 4 4
O
-2 - 2
40. AB
Sol. 3x 6y 2z 5 0
4x 12y 3z 3 0
3x 6y 2z 5 4x 12y 3z 3
Bisectors are
9 36 4 16 144 9
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AITS-CRT-II (Paper-2)-PCM(Sol.)-JEE(Advanced)/20 8
The plane which bisects the angle between the planes that contains the origin.
13 3x 6y 2z 5 7 4x 12y 3z 3
67x 162y 47z 44 0
Further, 3x 4 6 12 2 3 0
Hence, the origin lies in the acute angle.
41. ACD
Sol. P E
2n
Cn
2n !
2n
2 n!n!2n 2n
1 2 3 ....x 2n
n!n!2n 2n
1 3 5 .... 2n 1
n! 2n
Now,
n
2r 1 1 3 5 .... 2n 1
r 1 2r
2 4 6 ....... 2n
1 3 5 ....... 2n 1
1 2 3 .... n 2n
2
n n Cr 1 n n 2
n
r 0 2
Cr
2n 2n r 0
1
n n 2nCn
22
Also,
n 2
r 0
n
Cr 2n
Cn
2n
2n 22n
Cr
r 0
42. AC
n n 1 n2 n 1 1
Sol. f n n! n 1 ! n 2! n! nn! n 1n 1!
1 1 1 1 0 0
[Applying C3 C3 C2 and C2 C2 C1 ]
2
n 1n 1 ! nn! n! n 1 n n! n! n2 n 1
2
Thus, f n is divisible by n! and n n 1
43. AD
(1 sin x)(1 sin x) cos x cos x dt
Sol. I
2 2
sin x(1 sin x) sin x(1 sin x) 1 1 1 2
sin x t
4 2 2
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9 AITS-CRT-II (Paper-2)-PCM(Sol.)-JEE(Advanced)/20
44. ABD
9 8 8 4 8 8 5 0 0 0 0 0
Sol. A 4A 5I3 8 9 8 8 4 8 0 5 0 0 0 0 0
2
8 8 9 8 8 4 0 0 5 0 0 0
1
Multiplying by A 1, A 4I 5A 1 0 A 1 A 4I
5
2
A 0 A 0 A 2 is invertible.
45. A
46. A
Sol. (for Q.45 & Q.46)
We have (t2 + t3) (t2 + t1) = – 4
t 22 t 2 t1 t 3 t1t 3 4 0 … (1)
2 2
(t1 + t3) – 4(t1t3 + 4) 0 (t1 – t3) 16
t2 + t4 = – (t1 + t3) and t2t4 = t1t3 + 4 (Because t2 and t4 are the roots of the equation (1))
also let y1 and y2 are y-coordinates of intersection points of the tangents at (A, C) and (B,
D) then
y1 = t1 + t3 and y2 = t2 + t4 y1 + y2 = 0.
47. C
48. C
Sol. (for Q.47 & Q.48)
(I) x 0 x 9 3
2
(II) 13 x 2 x 1 x 2 x 6 0
x 3, 2
(III) x 5 1 x 2 x x 2 x 4
(IV) Put x 1 t 2 , to obtain
t 1 t 1 2
which is satisfied for each t 1
SECTION – C
49. 00000.60
Sol. b + c = 4a
sinB + sinC = 4sinA
BC BC
cos 4 cos
2 2
B C B C B C B C
cos cos sin sin 4 cos cos sin sin
2 2 2 2 2 2 2 2
B C B C
3 cos cos 5 sin sin
2 2 2 2
50. 00002.62
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AITS-CRT-II (Paper-2)-PCM(Sol.)-JEE(Advanced)/20 10
51. 00009.50
Sol. cos 4x 2cos2 2x 1
2
2 2 cos2 x 1 1
2 4 cos 4
x 1 4 cos2 x 1
8 cos4 x 8 cos2 x 1
a0 1, a1 8, a2 8
5a0 a1 a2 5
52. 00000.50
x tan 2x 2x tan x
Sol. lim
x 0 4 sin4 x
x 2 tan x
lim 2 tan x
x 0 4 sin4 x 1 tan2 x
2x tan x 1 1 tan2 x
lim
x 0 4 sin4 x 2
1 tan x
2x tan3 x
lim
x 0
4 sin4 x 1 tan2 x
1 x 1 1
lim
2 x 0 sin x cos x 1 tan2 x
3
1 1 1 1
.1. 3 .
2 1 1 0 2
53. 00000.20
sin2
x sin 2
Sol. I sin1 sin1
2cos 0 2cos
sin1 sin
2
3
I
I or 1
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11 AITS-CRT-II (Paper-2)-PCM(Sol.)-JEE(Advanced)/20
54. 00000.75
73
Sol. In CAE, AE2 AC2 CE2 2AC.CE cos C
9
Also, in CAE
AC2 AE2 CE 2 8 3
cos tan
2. AC. AE 73 8
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