(00 INTERNATIONAL SCH [MANAV RACHNA 100" 022-23 Pre Board I Grade XI neonate ‘Subject: Chemistry (043) Duration: 3 Hours “Tee querons this question paper “ 38 inthis question ct 1b) SECTION A consists of 18 multiple-choice questions carrying See ) SECTION B consists of 7 very short answer ‘questions carrying 2 mé 44) SECTION C wonsiss of § short answer questions carrying 3 marks each with an internal choice in 2 questions. ; Sen eerie oF 2 cave ered quertions carrying 4 marks each. Each question has with internal choice with 6 printed pages- each with an are compulsory. nd calculators isnot allowed. (©) 2-Phenyl-2-pi Which of the following is reaction? (a) CICH:- CH = CHa (©) CHsCH =CH-Cl 37 | Which one of the following is diamagnetic ion? (a) Co” (®) Ni (c) Cut What will be the fraction of molecules having activation energy, Ea? @Kk (D)A (@Ac™™ BC _| What is pH of the half cell Pt}H: (g)|H" if E"H/H2 @! (by @05 G- _|In the formation of S02 by contact process; 280; + O2— 280s, the rate of re was measured as —d[O2)/dt = 2.5 x 10% mol L''s''. The rate of formation of of SOs will be (@)-5.0 x 10% mol L's (b) -1.25 x 10% mol Ls" (©) 5.00 x 10% mol L's". 1 (@)3.75 * 10% mol Ls" - ies TH [Arrange the following compounds in increasing order (CH3NEb, (CHs)2 NH, NHs, CsHsNH2 (@) CoHsNH2 < NH3 < (CH3):NH IV>1>1 @pi>tve t= i (@u>1>Mt>1V (A) IV> I> 1> TL 48 | Which of the following statements concerning methylamine is correct? 1 ‘®) Methylamine is stronger base than NH3 'b) Methylamine is less basic than NH; ©) Methylamine is slightly aci | ‘) Methylamine forms salts with alkali | Which of the following reactions to a nucleophilic assault is the least reactive? 1 b) Di- tert-butyl ketone | ae | @) Acetaldehyde d) Butanone | = ©) Di- isopropyl ketone | A substance “AP decomposes by a first-order reaction starting initially with l= 2 2.00M and after 20min, [A] becomes 0.15M. For this reaction tin is (log 2 = 0.3010, log 3 = 0.4771) L a) 53.72 min b) 50.49 min c) 48.45 min @) 46.45 min 13 | Which one has highest molar conductivity? 1 (@) [PXNHs)2 Ch] (6) [Co(NH), Cl] Cl (©) Ka[Fe(CN).] (@) [Cr(H20)6] Cl 4 | The Rosenmund reaction can produce which ofthe following carbonyl compounds? | 1 2) Methanal ) Benzaldehyde ©) Butanone 4) Acetone In QUS-18, a statement of assertion is followed by a statement of reason, Mark the] 1 correct choice as: (A) Both Assertion (A) and Reason (R) are correct and Reason is the correct explanation for Assertion, (B) Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion, (C) Assertion is correct but Reason is incorrect. (D) Assertion is incorrect but Reason is correct ‘Assertion: Bond angle in ethers is slightly Tess than the tetrahedral angle. T Reason: There is a repulsion between the two bulky (-R) groups. ‘All naturally occurring a-amino acids except glycine are optically active. | 1 Asserti a yi : Reason: Most naturally occurring amino acids have L-configuation, mn: Separation of Zr and Hfis difficult. ; aaseroas couse Zr and Hilie in the same group ofthe period tables an 2 of 6 | Chemistry | Common Pre-board | Grade — XII | Set-A i Be mw Page[- 18-7] Assertion: Acylation of amines gives a mono substituted product whereas alkylation of amines gives polysubstituted product. Reason: Acyl group sterically hinders the approach of further acyl groups. SECTION B_ 19,- | The thermal decomposi nal ¢ ion of HCO;H is a first order reaction with a rate constant of 2.4 10" sat a certain temperature, Calculate how long will it take for three- fourths of initial quantity of HCO; H to decompose. (log 0.25 = -0.6021) 20. | What do ‘D” and “represent in D ~(+) Glucose? 7 | Which two reactions of Glucose cannot be explained by open chain structure. How OR ‘can cyclic structure of glucose explain these reactions? 21. | Give reasons for the following {@) _p-dichlorobenzene has a higher m.p. than its o- and m-isomers. (©) @-Butan-2-o is optically inactive oR sta" The C —Cl bond length in chlorobenzene is shorter than that in CH — Cl SY” Chloroform is stored in closed dark brown bottles. 22. [a> Write the IUPAC name of the complex [Cr(NHs),Clz]Cl ‘What type of isomerism is exhibited by the complex [Co(en)s]"*? i Write the reactions taking place at cathode and anode in lead storage battery when the battery is in use. What happens on charging the battery? is the order of the reaction whose tate constant has same units as the of reaction? How does rate of reaction change with temperature? gs P 25. Write the chemical equations to illustrate the following name reactions > GF Etard reaction_(bYAldol condensation SECTIONC 26. Write the equations for the following reactions: a) Aniline is treated with acetic anhydride followed by bromination in acetic acid medium, [+ Phenol is treated with CO2 in presence of NaOH followed by hydrolysis. ©) Tert -butyl bromide is treated with sodium ethoxide. [37” Draw the geometrical isomers exhibited by the complex [Co(en),Ch}. Wy Why is (NiCL}” paramagnetic but [Ni(CO)] diamagnetic? (At, No. 28) |i On the basis of crystal field theory, write the electronic configuration for d* ion if Ag) Predict the major product when (CHs);CH(Br)CH:CHs is heated with CaHSONa/CH5OH, OR 8) Cyanide ion acts as an ambidient nucleophile. From which end it acts as a stronger nucleophile in aqueous medium? Give reason. ) Out of 2-Bromopentane, 1-Bromopentane, 2-Bromo-2-methylbutane which ‘compound is optically active? ©) Wdentify A~ CH;-CH=CHy +HCI—A SECTIOND 31. | Read the passage carefully and answer the following question: Amino acids are classified as acidic, basic or neutral depending upon the relative number of amino and carboxyl groups in their molecule, Amino acids are usually colourless, crystalline solids. These are water-soluble, high melting solids and behave like salts rather than simple amines or carboxylic acids, This behaviour is due to the presence of both acidic (carboxyl group) and basic (amino group) groups in the same ‘molecule, In aqueous solution, the carboxyl group can lose a proton and amino group can accept a proton, giving rise to a dipolar ion known as zwitter ion. This is neutral ‘but contains both positive and negative charges. In zwitter ionic form, amino acids show amphoteric behaviour as they react both with acids and bases. Proteins are the polymers of a-amino acids and they are connected to each other by peptide bond or peptide linkage, When the number of such amino acids is more than ten, then the products are called polypeptides. A polypeptide with more than hundred amino acid residues, having molecular mass higher than 10,000u is called a protein. In Fibrous proteins, the polypeptide chains run parallel and are held together by hydrogen and disulphide bonds, then fibre-like structure is formed. Such proteins are generally insoluble in water. In Globular proteins, chains of polypeptides coil around to give a spherical shape. These are usually soluble in water. Insulin and albumins are the common examples of globular proteins. During denaturation secondary and tertiary structures are destroyed but primary structure remains intact. The coagulation of egg. white on boiling is a common example of denaturation. Another example is curdling. of milk which is caused due to the formation of lactic acid by the bacteria present in milk. Answer the following questions, rather than simple amines or carboxylic acids Amino behave Iil aaa Page 4 of 6 | Chemistry | Common Pre-board | Grade ~ XII | Set —Explain, ky What is meant by Peptide linkage? During curdling of milk, what happens to sugar present in it? OR Give one example each of Fibrous and Globular protein. 4) Which type of interactions are responsible for making the a -helix structure stable? 32. | Molecules of ethanoie acid (acetic acid) dimerise in benzene due to hydrogen bonding. This normally happens in solvents of low dielectric constant. In this case the number of particles is reduced due to dimerisation. If all the molecules of ethanoic acid associate in benzene, then AT, or AT; for ethanoic acid will be half of the normal value. The molar mass calculated on the basis of this AT, or AT; will be twice the expected value, Such a molar mass that is either lower or higher than the expected or normal value is called abnormal molar mass, Van't Hoff introduced a factor i, known as the van't Hoff factor, to account for the extent of dissociation or association. 8 Which of the following aqueous solution should have the highest boiling point? 1.0 M NaOH , 1,0 M Na:SQ4,1,0 M NH4NOs, 1.0 M KNOs Nef Define Van't Hoff Factor. ©) Determine the osmotic pressure of a solution prepared by dissolving 25 mg of K:SO, in 2 litre of water at 25°C, assuming that it is completely dissociated. ‘(Atomic mass of K = 39u, S = 32u, 0 = 16u) OR Determine the amount of CaCl; (i = 2.47) dissolved in 2.5 litre of water such that its osmotic pressure is 0.75 atm at 27°C. (Atomic mass of Ca = 40u, Cl = 35.Su) SECTION E a) In an aqueous solution, how does specific conductivity of electrolytes change with the addition of water? [ef How will the pH of brine (aq. NaCI solution) be affected when it is electrolyzed? ©) Calculate AG? and equilibrium constant for the reaction: 2Cr(s) + 3Cd”? (aq) ——> 2Cr? (aq) +3 Ca(s) E°CrCr=-0.74V E'Cd"/Cd=-0.40 V Antilog 34,501 = 3.17 X 10 oR a) How much electricity in terms of Faraday is required to produce 40-0 g of Al from molten Al,O; (Atomic Mass of Al=27u)? b) Unlike dry cell, the mercury cell has a constant cell potential throughout its useful life. Why? > ©) How does saline medium and alkaline medium affect rusting of iron? d) Calculate the emf of the cell in which the following reaction takes place: Ni(s) + 2Ag" (0.002 M) ——>ni** (0.160 M) + 2Ag(s) Given that (cell) E° = 1.05 V, Log 2 = 0.3010, Log 10=1 — 34. ]a) Cyclohexanone forms cyanohydrin in good yield but | 5 2, 2-trimethyleyclohexanone does not. Give reason. Draw structure of semicarbazone of cyclobutanone. ip Give simple chemical test to distinguish between Acetophenone and Benzophenone. d) Complete the following- 3 san Prechoard | Grade — XII | Set- Aa) >) a as > _til NSH \C,H,CHO + CH,CH,CHO—" CHO eal, ‘COOH OR Arrange the following : D-Benzaldehyde, p-tolualdehyde, p-nitrobenzaldehyde, acetophenone (in increasing order of their reactivity in nucleophilic addition reaction) “Benzoic acid, 4-Nitrobenzoic acid, 3, S-Dinitrobenzoic acid, 4-Methoxybenzoie acid (acid strength) Draw the structures of p-Nitropropiophenone. Predict the product when Cyclohexanecarbaldehyde reacts with zinc amalgam and cone HCl. An organic compound with the molecular formula CoHioO forms 2, 4-DNP derivative, reduces Tollen’s. reagent and undergoes Cannizzaro reaction. Identify the compound. a) b) ‘When an oxide of manganese (A) is fused with KOH in the presence of an oxidizing agent and dissolved in water, it gives a dark green solution of compound (B). Compound (B) disproportionates in acidic solution to give purple compound (C). Write the reactions involved to identify A,B and C. Answer the following questions: SP Which clemert of the first-transition"©eriesshas highest second icization enthalpy? Which clement of the first transition series has lowest enthalpy of atomization? iii)-Although fluorine is more electronegative than oxygen, but the ability of oxygen to stabilize higher oxidation states exceeds that of fluorine. Why?