MANAV RACHNA INTERNATIONAL SCHOOL Session: 2022-23 Pre Board I Pevond clean rade — XII ig Date: 23.12.22 Subject: Chemistry (043) Duration: 3 Hours —— General Instructions on ens rer with internal choice with 6 printed pages. a) There are 38 questions in this question par Daerah b) SECTION A consists of 18 multiple-choice questions carrying | mar | TION B con Very. short answer questions carrying 2 marks each with an | © SECTION B consists of 7 internal choice in 2 questions SECTION C consists of § short answer questions carrying 3 marks each with an internal choice in 2 questions, | SECTION D consists of 2 ease- based questions carrying 4 marks each. Each question has an internal choic SECTION E consists of 3 long answer questions carrying 5 marks each. Two questions have | gy mmr cic 8) Al questions are compulsory |) Use of log tables and calculators is not allowed. Marks a SECTION A <2 | The Rosenmund reaction can produce which of the following carbonyl compounds? a) Methanal b) Benzaldehyde i © Butanone d) Acetone - Z| Which of the following is most reactive towards Syl reaction? (@) CoHsC(CHs)CHsBr (b) CoHsCHBr | (©) CcHsCH(CcHs)Br ~ (d) CoHsCH(CH3)Br Fe ion is more stable than Fe™ ion because (2) more the charge on the atom, more is its stability (b) configuration of Fe”* is 3d while Fe™* is 34°~ (c) Fe*” has a larger size than Fe** (d) Fe™ ions are coloured hence more stable W | Arrange the following compounds in increasing order of basicity: CH3NH2, (CH3)2 NH, NH3, CsHsNHp (a) CeHsNHp < NH <(CHs)2NH < CH3NH2 (b) CHsNHp < (CH3)2NH Iv>1I>0 (b) I> 1V> I> 1 © (@)IV> I> 1> 11 ~ | Ni/Ni?* (1.0 M) // Au™ (1.0 M) / Au (E° =-0.25 V for Ni*/Ni; E® = 1.5 V for Au™/ @1sV —— WAV. CLV —(20V > ‘Which of the following reactions to a nucleophilic assault is the least reacti a) Acetaldehyde — b) Di- tert ae ) Di -isopropyl ketone B (a) NH3 < en ) Why low spin tetrahedral complexes are not formed? iii) Give role of coordination compounds in extraction of metals. SECTION D I Read the passage carefully and answer the following questions: 7 Molecules of ethanoic acid (acetic acid) dimerise in benzene due to hydrogen bonding. This normally happens in solvents of low dielectric constant, In this ease the number of particles is reduced due to dimerisaion. Ifall the molecules of ethanoic acid associate in benzene, then AT, or AT for ethanoic acid will be half of the normal value. The molar mass eaiculated on the basis of this AT or AT will be twice the expected value. Such a molar mass that is either lower or higher than the expected or normal value is called vpnormal molar mass. Van't Hoff introduced a factor i, Known as the van"t Hoff factor, fo account for the extent of dissociation or association, i i ighest boiling point? Which of the following aqueous solution should have the highest 9) AVM NaOH 1.0 M Na:S0x1.0 M NHiNOS LOMBNOS TT ong b) What isthe value of van’t Hoff factor or a molecule undergoing dimerization in a solvent? pression in the freezing 19.5g of CHaFCOOH is dissolved in 500g of water. The de} point of water observed ie 1.0°C. Calculate dissociation constant of fMuoroaeetic 2u, H= 1u, F = 19u, 0 = 16u) Krofwater= 1-86 5K. (Atomic mass of iaamistry | Common Pre-board | Grade— x | SeKE ki CHSCH;CHICICOON is added 0 250g of water. K, = 1.4 x 10° (Ki 1.86 K kg mot", Atomic mass of C= 120, H = lu, Cl=35.5u, O= 16u) ids Carbohydrates are optically active polyhydroxy aldehydes or ketones or the Co 2 Which produce such units on hydrolysis. The most common sugar, used in our homes Mamed as sucrose whereas the sugar present in milk is known as lactose. The we 'onosaccharides ae joined together by an oxide linkage formed by the loss ofa water Iolecule; called glycosidic linkage. A carbohydrate that cannot be hydrolysed further 19 give simpler unit of polyhydroxy aldehyde or ketone is called a monosacel cafe is on common examples are glucose, fructose, ribose, ete. Carbohydrates that yield a) a Monosaccharide units, on hydrolysis, are called oligosaccharides. They are further Classified as disaccharides, trisaccharides, tetrasaccharides, etc., depending upon the ‘number of monosaccharides, they provide on hydrolysis, Carbohydrates which yield a Jarge number of monosaccharide units on hydrolysis are called polysaccharides. Some ‘common examples are starch, cellulose, glycogen, gums, etc. ‘What happens when D-glucose is treated with HCN. OR Write the product formed when D-glucose reacts with Conc. HNOs. aon the Haworth structure of a-D glucopyranose. What are the expected products of hydrolysis of lactose? ‘What is the basic structural difference between starch and cellulose? SECTIONE Which of the following compounds is most reactive towards nucleophilic addition | 5 reactions- . Acetaldehyde, Acetone, Benzaldehyde and Acetophenone < ca Predict the products formed - (CoHyCH,)2Cd +, 2CH3COC1—> ive simple chemical test to distinguish between Ethanal and Propanal. An organic compound (A) (molecular formula CsHi¢O) was hydrolysed with dilute sulphuric acid to give a carboxylic acid (B) and an alcohol (C). Oxidation of (©) with chromic acid produced (B). C on dehydration gives but-I-ene. Identify ABC. OR Arrange the following in increasing acidic strength - Phenol , Ethanol , Chloroacetic acid , Acetic acid Write the structures of the expected products of aldol condensation of 2-Methylpentanal. Convert Acetaldehyde into 2-Chloroacetic acid, An organic compound having molecular formula CsHyo0 does not reduce Tollens” reagent but forms an addition compound with sodium hydrogensulphite and give Positive iodoform test. On vigorous oxidation, it gives ethanoic and propanoic acid, Write the possible structure of the compound, State Kohlrausch Law. iy Define Fuel Cell. 34, 2CP* + 7H,0 What is the quantity of electricity in coulombs needed Page Sof 6 | Chemistry | Common Pre-board!Grade~XIiSet—-R» eck ae TET re ree oer cam ct be chained ic acid is 7.896 x 10° S cm’. Calculate its molar acids 390.5 § em’ mot", what is its dissociation ansition series has the highest third ionization ts form complexes? from element to element than lanthanoid