Report generated by: Report No.

51220
CrudeSuite Desktop
© Spiral Software

CRUDE OIL ASSAY REPORT

TITLE UMM SHAIF (UNITED ARAB EMIRATES) CRUDE OIL

JANUARY 2000

DATE -

GENERATED BY CrudeSuite Desktop v.3.20 (Build 1738.11.73)

COPYRIGHT BP Oil Inc

USER sunqj0 Signed

This document contains BP Proprietary Information which is only for use within BP,
its affiliates and licensees. None of the information shall be disclosed to any party outside
the BP Group without prior consent in writing from BP Oil.

Page 1 of 29
 Crude Name Umm Shaif
Report no. 51220
PPEFA pack number PPEF881C
Sample Date 17.1.2000
Total crude oil
Density kg/l 0.8385
API 37.2
Sulphur %wt 1.31
Pour point °C -18
KV @ 20°C cSt 5.96
KV @ 40°C cSt 3.54
Acidity mg KOH/g 0.05

Yields %wt
Gas to C4 1.5
Total to 95°C 10.1
149°C 20.1
175°C 25.35
232°C 36.2
342°C 57.45
369°C 62.3
509°C 82.3
550°C 86.45
585°C -
15-95
Density kg/l 0.6734
RON (C) 62.0000

Light Distillate 15 to 149

Density kg/l 0.7106

Kerosine 149-232
Density kg/l 0.7899
Sulphur %wt 0.097
Freeze °C -56
Naphthalenes % vol 0.46
Acidity mg KOH/g 0.015
Smoke point mm 26
Cetane Index 42.8

Gas Oil 232-342

Density kg/l 0.8439
Sulphur %wt 0.88
Pour point °C -15
Acidity mg KOH/g <0.05
Cetane Index 51.5

Vacuum Gas Oil 369-509

Density kg/l 0.9139
Sulphur %wt 2.02
Nitrogen ppm wt 680
CCR %wt 0.1
RI @ 70°C 1.4899
KV @ 100°C cSt 5.96

>550
Density kg/l 1.00
Sulphur %wt 3.61
Nitrogen ppm wt 2500.00
CCR %wt 15.10
Nickel ppm wt 6.00
Vanadium ppm wt 20.00
KV @ 100°C cSt 346.00

Page 2 of 29
 MIDDLE EAST
PPEF881C UNITED ARAB EMIRATES
UMM SHAIF
SOURCE OF SAMPLE CRUDE DATA ASSAY SUMMARY/TBP DATA

Reference A05200 Gravity 37.2 Yield on Crude %wt %vol

Light Hydrocarbon Gas to C4 (corrected) 1.50 2.32
Analysis Light Distillate to 149°C (API) 18.60 21.70
Kerosine 149 - 232°C 16.10 17.08
Field UMM SHAIF H2S ppm wt 31.0 Gas oil 232 - 342°C 21.25 21.06
Methane %wt - Residue above 342°C 42.55 37.85
Ethane %wt 0.01
Propane %wt 0.16 Gas to C4 (corrected) 1.50 2.32
Export DAS ISLAND Isobutane %wt 0.23
Terminal n-Butane %wt 1.1 Total to 95°C (API) 10.10 12.75
149°C 20.10 24.01
Source sample taken during DISCHARGE 175°C 25.35 29.74
OF mv OLYMPIC SYMPHONY AT Total C1 - C4 1.5 232°C 36.20 41.09
KWINANA 342°C 57.45 62.15
369°C 62.30 66.73
Isopentane %wt 1.01 509°C 82.30 85.03
Sample Date 17-Jan-00 n-Pentane %wt 1.66 550°C 86.45 88.69
585°C - 91.10
Volume expansion of 0.3 per cent vol on
Date Rec'd 26-Apr-00 crude distributed across whole distillation

DISTILLATES

TBP cut point °C API Total C5-95 ** 95-175 C5-149 149-232 232-342 342-369 369-509 509-550
Crude (C) (C)
Yield on crude %wt 100.0 8.60 15.25 18.6 16.1 21.25 4.85 20.0 4.15
Yield on crude %vol 100.00 10.43 16.99 21.70 17.08 21.06 4.58 18.30 3.66

Density at 15°C kg/litre 0.8385 0.6734 0.7562 0.7106 0.7899 0.8439 0.8864 0.9139 0.9475
Sulphur %wt 1.31 0.095 0.067 0.077 0.097 0.880 2.010 2.020 2.550
Mercaptan sulphur %wt - 0.0801 0.0441 0.0612 0.0387 - - - -
Viscosity at 20°C cSt 5.96 - - - - - - - -
30°C 4.46 - - - - - - - -
40°C 3.54 - - - 1.05 - - - -
50°C - - - - - 2.64 6.80 - -
60°C - - - - 0.84 - - 18.00 106.00
100°C - - - - - 1.26 2.43 5.96 20.90
Cloud point °C - - - - - -15 12 - -
Pour point °C -18 - - - - -15 12 33 -
Wax (NMR) %wt - - - - - 3.6 16.2 14.7 13.8
Wax (BP237) %wt - - - - - - - - -
Total nitrogen ppm wt - - - - - 34 320 680 1300
Basic nitrogen ppm wt - - - - - - - 175 290
Organic oxygen %wt - - - - - - - 0.15 -
Acidity mgKOH/g 0.05 - - - 0.015 <0.05 <0.05 <0.05 <0.05
Carbon residue %wt 2.1 - - - - - - 0.1 1.9
Asphaltenes %wt 0.11 - - - - - - - -
Vanadium ppm wt 3 - - - - - - - -
Nickel ppm wt <2 - - - - - - - -
Iron ppm wt 3 - - - - - - - -
Arsenic ppb wt <4 - - - - - - - -
Cadmium ppb wt 72 - - - - - - - -
Copper ppb wt <10 - - - - - - - -
Lead ppb wt 50 - - - - - - - -
Mercury ppb wt <1 - - - - - - - -
Aromatics %vol - - - - 22.0 27.0 - - -
Smoke point mm - - - - 26 18 - - -
Freezing point ºC - - - - - 56.0 - 10.5 - - -
Cetane Index ASTM D976 - - - - 42.8 51.5 47.1 - -
Cetane Index IP380 - - - - 45.0 55.4 - - -
CsubA % - - - - - 16.2 19.7 19.5 21.1
Refractive index at 70°C - - - - - 1.4502 1.475 1.4899 1.511
Hydrogen content %wt - - - - 14.0 - - - -
Paraffins %wt - 84.0 64.0 73.3 - - - - -
Naphthenes %wt - 12.3 15.0 15.0 - - - - -
Aromatics %wt - 3.7 21.0 11.7 - 29.8 - - -
n-Paraffins %wt - 46.0 28.8 37.5 - - - - -
Colour stability - - - - Stable Stable 369 - 509 DWO
Naphthalenes %vol - - - - 0.46 9.01 Density at 15°C kg/l 0.9281
Viscosity at 40°C cSt 55.7
Salt lb/1000bbl 2 - - - - - 60°C cSt 22.6
Water %vol <0.05 - - - - - 100°C cSt 6.71
Viscosity index 61
Research Octane Number (C) - 62.0 - - - - Pour point °C -18
Selenium ppb wt - - - - - - - - -
H2S Evolved @ 160°C ppm wt - - - - - - - - -
Calcium (unwashed) ppm wt - - - - - - - - -
Calcium (washed) ppm wt - - - - - - - - -
Chlorine (unwashed) ppm - - - - - - - - -
Chlorine (washed) ppm - - - - - - - - -

(C) = Calculated Crude Dry Density at 15ºC (kg/l) 0.8385

** = Analysis carried out on 15-95°C fraction Crude API (from Dry Density) 37.2
These acidities may have been subject to thermal degradation
* = Summation of the poly-aromatic data from Table 18

Page 3 of 29
 Table 1

Umm Shaif Crude Oil

Properties of Residues

RESIDUES
TBP Cut point (API) °C 342 369 509 550
(C)

Yield on crude oil %wt 42.55 37.7 17.7 13.55

Yield on crude oil %vol 37.85 33.27 14.98 11.31

Density at 15°C kg/litre 0.9400 0.9475 0.9885 1.0020

Sulphur %wt 2.58 2.65 3.36 3.61

Viscosity at 50°C cSt 106.0 152.0 - -

60°C cSt - 90.5 - -
80°C cSt - 38.6 - -
100°C cSt - 19.9 153 346
120°C cSt - 11.7 67 134
150°C cSt - - 25.6 44.9

Penetration at 25ºC mm/10 - - >500 >500

Softening point °C - - 19.2 24.0
Viscosity at 60°C (Vac Cap) Pa.s - - - -

Pour point °C 27 30 27 -
Wax content (BP237) %wt - - - -
Wax content (NMR) %wt 12.5 12.0 9.0 8.0

Total nitrogen ppm wt 1280 1400 2220 2500

Basic nitrogen ppm wt - 390 635 740
Acidity mgKOH/g - <0.05 - -

Carbon residue %wt * 5.1 5.7 12.0 15.1

Asphaltenes %wt * 0.27 0.3 0.6 0.8
Vanadium ppm wt 6 7 15 20
Nickel ppm wt 2 2 5 6
Iron ppm wt 6 7 15 20

Xylene equivalent - - - 0
CsubA % - - - 21.2

Saturates %wt - 28 - 8
Aromatics %wt - 66 - 81
Resins A %wt - 5 - 9
Resins B %wt - 1 - 2

(C) = calculated value

( ) = extrapolated value
* = balanced within the reproducibility of the method
These acidities may have been subject to thermal degradation

Page 4 of 29
 Table 2

Umm Shaif Crude Oil

Individual Hydrocarbons in the 15 - 95°C Cut

TBP Cut point °C 15 - 95 15 - 95

Yield on crude oil 8.60 10.43
Position in Crude 1.5 - 10.1 2.32 - 12.75
Hydrocarbons % wt % wt % vol % vol
On Cut On Crude On Cut On Crude

ethane - - - -
propane - - - -
iso-butane 0.01 trace 0.01 trace
n-butane 0.49 0.04 0.56 0.06
neo-pentane 0.02 trace 0.02 trace
iso-pentane 11.42 0.98 12.30 1.28
n-pentane 19.19 1.65 20.56 2.15
2,2-dimethylbutane 0.29 0.02 0.30 0.03
cyclopentane 1.45 0.12 1.29 0.13
2,3-dimethylbutane 1.10 0.09 1.10 0.11
2-methylpentane 9.09 0.78 9.31 0.97
3-methylpentane 5.66 0.49 5.61 0.59
n-hexane 19.07 1.64 19.35 2.02
2,2-dimethylpentane 0.20 0.02 0.20 0.02
methylcyclopentane 4.10 0.35 3.66 0.38
2,4-dimethylpentane 0.60 0.05 0.60 0.06
2,2,3-trimethylbutane 0.03 trace 0.03 trace
benzene 2.24 0.19 1.71 0.18
3,3-dimethylpentane 0.11 0.01 0.11 0.01
cyclohexane 2.75 0.24 2.37 0.25
2-methylhexane 3.86 0.33 3.81 0.40
2,3-dimethylpentane 1.11 0.10 1.07 0.11
1,1-dimethylcyclopentane 0.24 0.02 0.21 0.02
3-methylhexane 3.66 0.31 3.57 0.37
1,cis-3-dimethylcyclopentane 0.54 0.05 0.46 0.05
1,trans-3-dimethylcyclopentane 0.48 0.04 0.41 0.04
3,ethylpentane 0.23 0.02 0.22 0.02
1,trans-2-dimethylcyclopentane 0.80 0.07 0.69 0.07
2,2,4-trimethylpentane 0.01 trace 0.01 trace
n-heptane 7.43 0.64 7.28 0.76
1,cis-2-dimethylcyclopentane
methylcyclohexane 1.64 0.14 1.40 0.15
2,2,3,3-tetramethylbutane
1,1,3-trimethylcyclopentane 0.06 0.01 0.05 0.01
2,2-dimethylhexane 0.01 trace 0.01 trace
ethylcyclopentane 0.16 0.01 0.14 0.01
2,5-dimethylhexane 0.08 0.01 0.08 0.01
2,2,3-trimethylpentane - - - -
2,4-dimethylhexane 0.10 0.01 0.09 0.01
1,trans-2-cis-4-trimethylcyclopentane 0.04 trace 0.03 trace
3,3-dimethylhexane - - - -
1,trans-2,cis-3-trimethylcyclopentane 0.03 trace 0.03 trace
2,3,4-trimethylpentane 0.01 trace 0.01 trace
2,3,3-trimethylpentane - - - -
toluene 1.47 0.13 1.14 0.12
higher boiling non-aromatics 0.24 0.02 0.21 0.02
Total 100.02 8.59 100.01 10.42

Page 5 of 29
 Table 3

Umm Shaif Crude Oil

Individual Aromatic Components in the 15 - 175°C Range

TBP Cut point °C 15 - 95* 95 - 149 149 - 175

Yield on crude oil %wt 8.45 10.00 5.25
Position in Crude %wt 1.5 - 10.1 10.1 - 20.1 20.1 - 25.35

Hydrocarbons %wt On Cut On Crude On Cut On Crude On Cut On Crude

benzene 2.24 0.19 0.31 0.03 0.00 trace
toluene 1.47 0.12 6.76 0.68 0.19 0.01
ethylbenzene - - 2.28 0.23 0.86 0.05
p-xylene - - 1.43 0.14 0.73 0.04
m-xylene - - 3.68 0.37 1.99 0.10
isopropylbenzene - - 0.26 0.03 0.54 0.03
o-xylene - - 2.22 0.22 1.94 0.10
n-propylbenzene - - 0.29 0.03 1.19 0.06
1-methyl-3-ethylbenzene
1-methyl-4-ethylbenzene - - 0.65 0.07 4.10 0.22
tert-butylbenzene
isobutylbenzene
1,3,5-trimethylbenzene - - 0.14 0.01 1.75 0.09
sec-butylbenzene
1-methyl-3-isopropylbenzene
1-methyl-2-ethylbenzene - - 0.27 0.03 3.16 0.17
1-methyl-4-isopropylbenzene
1,2,4-trimethylbenzene - - 0.21 0.02 4.27 0.22
1,4-diethylbenzene - - - - 0.51 0.03
1-methyl-3-n-propylbenzene
1-methyl-2-iso-propylbenzene - - - - 0.50 0.03
1-methyl-4-n-propylbenzene
1,3-diethylbenzene - - - - 0.25 0.01
n-butylbenzene
1,3-dimethyl-5-ethylbenzene - - - - 0.37 0.02
1,2-diethylbenzene - - - - 0.05 trace
1-methyl-2-n-propylbenzene - - - - 0.21 0.01
1,2,3-trimethylbenzene - - 0.03 trace 1.73 0.09
1,4-dimethyl-2-ethylbenzene - - - - 0.31 0.02
1,3-dimethyl-4-ethylbenzene - - - - 0.27 0.01
1,2-dimethyl-4-ethylbenzene - - - - 0.10 0.01
indane - - - - 0.25 0.01
C11 aromatics - - - - 0.32 0.02

Total %wt 3.71 0.31 18.53 1.85 25.59 1.34

Note:- *Summation of individual components from Table 2.

Page 6 of 29
 Table 3A

Umm Shaif Crude Oil

Individual Aromatic Components in the 15 - 175°C Range

TBP Cut point °C 15 - 95* 95 - 149 149 - 175

Yield on crude oil %vol 10.55 11.25 5.65
Position in Crude %vol 2.32 - 12.75 12.75 - 24.01 24.01 - 29.74

Hydrocarbons %vol On Cut On Crude On Cut On Crude On Cut On Crude

benzene 1.71 0.18 0.26 0.03 - -
toluene 1.14 0.12 5.79 0.65 0.17 0.01
ethylbenzene - - 1.95 0.22 0.77 0.04
p-xylene - - 1.23 0.14 0.65 0.04
m-xylene - - 3.16 0.36 1.78 0.10
isopropylbenzene - - 0.22 0.02 0.48 0.03
o-xylene - - 1.87 0.21 1.70 0.10
n-propylbenzene - - 0.25 0.03 1.07 0.06
1-methyl-3-ethylbenzene
1-methyl-4-ethylbenzene - - 0.56 0.06 3.67 0.21
tert-butylbenzene
isobutylbenzene
1,3,5-trimethylbenzene - - 0.12 0.01 1.56 0.09
sec-butylbenzene
1-methyl-3-isopropylbenzene
1-methyl-2-ethylbenzene - - 0.23 0.03 2.77 0.16
1-methyl-4-isopropylbenzene
1,2,4-trimethylbenzene - - 0.18 0.02 3.76 0.21
1,4-diethylbenzene - - - - 0.46 0.03
1-methyl-3-n-propylbenzene
1-methyl-2-iso-propylbenzene - - - - 0.44 0.02
1-methyl-4-n-propylbenzene
1,3-diethylbenzene - - - - 0.22 0.01
n-butylbenzene
1,3-dimethyl-5-ethylbenzene - - - - 0.33 0.02
1,2-diethylbenzene - - - - 0.04 trace
1-methyl-2-n-propylbenzene - - - - 0.19 0.01
1,2,3-trimethylbenzene - - 0.02 trace 1.49 0.08
1,4-dimethyl-2-ethylbenzene - - - - 0.27 0.02
1,3-dimethyl-4-ethylbenzene - - - - 0.23 0.01
1,2-dimethyl-4-ethylbenzene - - - - 0.09 0.01
indane - - - - 0.20 0.01
C11 aromatics - - - - 0.27 0.02

Total %vol 2.85 0.30 15.84 1.78 22.61 1.28

Note:- *Summation of individual components from Table 2.

Page 7 of 29
 Table 4

Umm Shaif Crude Oil

Hydrocarbon Type Analysis By Gas Chromatography in the 15 - 175°C Range

TBP Cut point °C 15 - 95* 95 - 149 149 - 175

Yield on crude oil %wt 8.60 10.00 5.25
Position in Crude %wt 1.5 - 10.1 10.1 - 20.1 20.1 - 25.35
Hydrocarbons %wt On Cut On Crude On Cut On Crude On Cut On Crude

c2 n-paraffin - - - - - -
c3 n-paraffin - - - - - -
c4 isoparaffin 0.01 trace - - - -
c4 n-paraffin 0.49 0.04 - - - -
c5 naphthenes 1.45 0.12 - - - -
c5 isoparaffin 11.42 0.98 - - - -
c5 n-paraffin 19.19 1.65 - - - -
c6 naphthenes 6.85 0.59 1.11 0.11 - -
c6 isoparaffin 16.14 1.39 0.30 0.03 - -
c6 n-paraffin 19.07 1.64 0.89 0.09 - -
c7 naphthenes 3.86 0.33 5.98 0.60 0.08 trace
c7 isoparaffin 9.80 0.84 4.72 0.47 - -
c7 n-paraffin 7.43 0.64 9.71 0.97 0.09 trace
c8 naphthenes 0.27 0.02 7.67 0.77 1.34 0.07
c8 isoparaffin 0.31 0.03 14.32 1.43 0.54 0.03
c8 n-paraffin - - 13.04 1.30 1.35 0.07
c9 naphthenes - - 2.38 0.24 4.12 0.22
c9 isoparaffin - - 12.61 1.26 9.45 0.50
c9 n-paraffin - - 6.03 0.60 11.32 0.59
c10 naphthenes - - 0.13 0.01 4.38 0.23
c10 isoparaffin - - 2.04 0.20 21.95 1.15
c10 n-paraffin - - 0.54 0.05 11.72 0.62
c11 naphthenes - - - - 0.87 0.05
c11 isoparaffin - - - - 5.48 0.29
c11 n-paraffin - - - - 1.72 0.09

total isoparaffin 37.68 3.24 33.99 3.40 37.42 1.96

total n-paraffin 46.18 3.97 30.21 3.02 26.20 1.37
total naphthenes 12.43 1.07 17.27 1.73 10.79 0.56
total aromatics 3.71 0.32 18.53 1.85 25.59 1.34

c6 aromatics 2.24 0.19 0.31 0.03 0.00 trace

c7 aromatics 1.47 0.13 6.76 0.68 0.19 0.01
c8 aromatics - - 9.92 0.99 6.15 0.32
c9 aromatics - - 1.54 0.15 15.42 0.81
c10+ aromatics - - 0.00 trace 3.83 0.20

Note:- *Summation of individual components from Table 2.

Page 8 of 29
 Table 4A

Umm Shaif Crude Oil

Hydrocarbon Type Analysis By Gas Chromatography in the 15 - 175°C Range

TBP Cut point °C 15 - 95* 95 - 149 149 - 175

Yield on crude oil %vol 10.55 11.25 5.65
Position in Crude %vol 2.32 - 12.75 12.75 - 24.01 24.01 - 29.74
Hydrocarbons %vol On Cut On Crude On Cut On Crude On Cut On Crude

c2 n-paraffin - - - - - -
c3 n-paraffin - - - - - -
c4 isoparaffin 0.01 trace - - - -
c4 n-paraffin 0.56 0.06 - - - -
c5 naphthenes 1.29 0.14 - - - -
c5 isoparaffin 12.30 1.30 - - - -
c5 n-paraffin 20.56 2.17 - - - -
c6 naphthenes 6.03 0.64 1.08 0.12 - -
c6 isoparaffin 16.32 1.72 0.34 0.04 - -
c6 n-paraffin 19.35 2.04 1.00 0.11 - -
c7 naphthenes 3.31 0.35 5.86 0.66 0.08 trace
c7 isoparaffin 9.61 1.01 5.11 0.57 - -
c7 n-paraffin 7.28 0.77 10.54 1.19 0.10 0.01
c8 naphthenes 0.24 0.03 7.38 0.83 1.34 0.08
c8 isoparaffin 0.28 0.03 15.00 1.69 0.59 0.03
c8 n-paraffin - - 13.78 1.55 1.48 0.08
c9 naphthenes - - 2.27 0.26 4.08 0.23
c9 isoparaffin - - 12.85 1.45 10.00 0.57
c9 n-paraffin - - 6.24 0.70 12.16 0.69
c10 naphthenes - - 0.12 0.01 4.20 0.24
c10 isoparaffin - - 2.04 0.23 22.75 1.29
c10 n-paraffin - - 0.55 0.06 12.39 0.70
c11 naphthenes - - - - 0.83 0.05
c11 isoparaffin - - - - 5.57 0.31
c11 n-paraffin - - - - 1.79 0.10

total isoparaffin 38.52 4.06 35.34 3.98 38.91 2.20

total n-paraffin 47.75 5.04 32.11 3.61 27.92 1.58
total naphthenes 10.87 1.15 16.71 1.88 10.53 0.59
total aromatics 2.86 0.30 15.84 1.78 22.64 1.28

c6 aromatics 1.71 0.18 0.26 0.03 - -

c7 aromatics 1.14 0.12 5.79 0.65 0.17 0.01
c8 aromatics - - - - - -
c9 aromatics - - - - - -
c10 aromatics - - - - - -

Note:- *Summation of individual components from Table 2.

Page 9 of 29
 Table 5

Umm Shaif Crude Oil

Properties of 369 - 550°C Cut

TBP Cut point (API) °C 369 - 550

(C)

Yield on crude oil %wt 24.15

Yield on crude oil %vol 21.96

Density at 15ºC kg/litre 0.9195

Sulphur %wt 2.11

Viscosity at 60ºC cSt 23.20

Viscosity at 100ºC cSt 7.15

Wax content (BP237) %wt -

Wax content (NMR) %wt 14.5
Total nitrogen ppm wt 790

Basic nitrogen ppm wt 195

Acidity mgKOH/g <0.01

Carbon Residue %wt 0.41

Refractive index at 70ºC 1.4935

(C) = calculated value

These acidities may have been subject to thermal degradation

Page 10 of 29
 Table 6

Umm Shaif Crude Oil

TBP data

6.00 50
TBP Cut point (API) °C 50 55 60 65 70 75 80 85 90 95 6.13 55
Total distillate %wt 4.64 5.11 5.61 6.14 6.70 7.30 7.94 8.62 9.34 10.10 6.26 60
%vol 6.13 6.13 6.26 7.87 9.93 10.35 10.38 10.99 11.34 12.75 7.87 65
9.93 70
10.35 75
TBP Cut point (API) °C 100 105 110 115 120 125 130 135 140 145 10.38 80
Total distillate %wt 10.90 11.72 12.59 13.48 14.40 15.34 16.30 17.28 18.28 19.29 10.99 85
%vol 14.71 15.36 15.61 16.51 18.26 18.71 20.38 20.97 22.29 23.19 11.34 90
12.75 95
14.71 100
TBP Cut point (API) °C 150 155 160 165 170 175 180 185 190 195 15.36 105
Total distillate %wt 20.30 21.33 22.35 23.37 24.37 25.35 26.30 27.23 28.15 29.07 15.61 110
%vol 24.22 25.42 26.55 27.64 28.70 29.74 30.76 31.76 32.75 33.72 16.51 115
18.26 120
18.71 125
TBP Cut point (API) °C 200 205 210 215 220 225 230 235 240 245 20.38 130
Total distillate %wt 30.00 30.95 31.91 32.88 33.86 34.84 35.81 36.78 37.74 38.69 20.97 135
%vol 34.70 35.69 36.68 37.69 38.69 39.70 40.70 41.69 42.67 43.64 22.29 140
23.19 145
24.22 150
TBP Cut point (API) °C 250 255 260 265 270 275 280 285 290 295 25.42 155
Total distillate %wt 39.64 40.59 41.55 42.52 43.49 44.47 45.45 46.43 47.40 48.37 26.55 160
%vol 44.61 45.58 46.56 47.53 48.50 49.48 50.46 51.43 52.40 53.36 27.64 165
28.70 170
29.74 175
TBP Cut point (API) °C 300 305 310 315 320 325 330 335 340 345 30.76 180
Total distillate %wt 49.33 50.29 51.25 52.22 53.18 54.15 55.12 56.10 57.07 58.02 31.76 185
%vol 54.30 55.24 56.19 57.13 58.06 59.00 59.93 60.86 61.79 62.70 32.75 190
33.72 195
34.70 200
TBP Cut point (API) °C 350 355 360 365 370 375 380 385 390 395 35.69 205
Total distillate %wt 58.96 59.87 60.76 61.63 62.46 63.27 64.06 64.83 65.60 66.38 36.68 210
%vol 63.59 64.45 65.29 66.10 66.88 67.64 68.37 69.09 69.81 70.53 37.69 215
38.69 220
39.70 225
TBP Cut point (API) °C 400 410 420 430 440 450 460 470 480 490 40.70 230
Total distillate %wt 67.16 68.74 70.31 71.88 73.40 74.85 76.19 77.47 78.73 79.99 41.69 235
%vol 71.26 72.71 74.16 75.60 76.98 78.30 79.52 80.69 81.84 82.97 42.67 240
43.64 245
44.61 250
TBP Cut point (API) °C 500 510 520 525 530 540 550 600 650 700 45.58 255
Total distillate %wt 81.23 82.42 83.53 84.06 84.57 85.54 86.45 90.20 93.00 95.15 46.56 260
%vol 84.07 85.13 86.12 86.59 87.04 87.90 88.69 91.98 94.35 96.02 47.53 265
48.50 270
49.48 275
50.46 280
51.43 285
52.40 290
53.36 295
54.30 300
55.24 305
56.19 310
57.13 315
58.06 320
59.00 325
59.93 330
60.86 335
61.79 340
62.70 345
63.59 350
64.45 355
65.29 360
66.10 365
66.88 370
67.64 375
68.37 380
69.09 385
69.81 390
70.53 395
71.26 400
72.71 410
74.16 420
75.60 430
76.98 440
78.30 450
79.52 460
80.69 470
81.84 480
82.97 490
84.07 500
85.13 510
86.12 520
86.59 525
87.04 530
87.90 540
88.69 550
91.98 600
94.35 650
96.02 700

Page 11 of 29
 Table 7

Umm Shaif Crude Oil

Properties of 550-585°C and Residue >585°C fractions

Cut Point
TBP Cut point (API) ºC 550-585 >585

Yield on crude oil %wt - -

Yield on crude oil %vol 2.41 8.90

Density at 15ºC kg/litre - -

Sulphur %wt - -

Viscosity at 50ºC cSt - -

60ºC cSt - -
80ºC cSt - -
100ºC cSt - -
120ºC cSt - -
150ºC cSt - -

Penetration at 25°C 10/mm - -

Softening point °C - -
Viscosity at 60°C (Vac Cap) - -

Wax content (BP237) %wt - -

Wax content (NMR) %wt - -

Total nitrogen ppm wt - -

Basic nitrogen ppm wt - -
Acidity mgKOH/g - -

Carbon residue %wt - -

Asphaltenes %wt - -
Vanadium ppm wt - -
Nickel ppm wt - -
Iron ppm wt - -

Xylene equivalent - -

Saturates %wt - -
Aromatics %wt - -
Resins A %wt - -
Resins B %wt - -

(C) = calculated value

( ) = extrapolated value
These acidities may have been subject to thermal degradation

Page 12 of 29
 Table 8

Umm Shaif Crude Oil

Crude Oil SIMDIS Results

Total Crude % wt
Temp °C

Recovery C1-C7 10.1

Recovery 149 20.3

Recovery 175 26.5

Recovery 232 37.0

Recovery 342 58.6

Recovery 369 63.3

Recovery 509 83.9

Recovery 550 87.8

Recovery 600 91.8

Recovery 720 97.2

Recovery >720 2.8

Page 13 of 29
 Table 9

Umm Shaif Crude Oil

Hydrocarbon Type Analysis By Gas Chromatography in the 175 - 200°C Range

TBP Cut point °C 175 - 200 175 - 200

Yield on crude oil - 4.96
Position in Crude 25.35 - 30. 29.74 - 34.7
Hydrocarbons % wt % wt % vol % vol
On Cut On Crude On Cut On Crude

c6 naphthenes - - - -
c6 isoparaffin - - - -
c6 n-paraffin - - - -
c6 aromatics - - - -
c7 naphthenes - - - -
c7 isoparaffin - - - -
c7 n-paraffin - - - -
c7 aromatics - - - -
c8 naphthenes - - - -
c8 isoparaffin - - - -
c8 n-paraffin - - - -
c8 aromatics - - - -
c9 naphthenes - - - -
c9 isoparaffin - - - -
c9 n-paraffin - - - -
c9 aromatics - - - -
c10 naphthenes - - - -
c10 isoparaffin - - - -
c10 n-paraffin - - - -
c10 aromatics - - - -
c11 naphthenes - - - -
c11 isoparaffin - - - -
c11 n-paraffin - - - -
c11 aromatics - - - -

total isoparaffin 0.00 0.00 0.00 0.00

total n-paraffin 0.00 0.00 0.00 0.00
total naphthenes 0.00 0.00 0.00 0.00
total aromatics 0.00 0.00 0.00 0.00

High Boiling Aromatics - - - -

High Boiling Saturates - - - -
Polynaphthene - - - -

Page 14 of 29
 Table 10

Umm Shaif Crude Oil

Residue Metals Analysis (raw experimental data)

Cut Point
TBP Cut point (API) °C >369 >509 >550 >585 On Crude
Average

Yield on crude oil %wt 37.70 17.70 13.55 - 100.00

Yield on crude oil %vol 33.27 14.98 11.31 8.90 100.00

Aluminium mg/kg - - - - -
Barium mg/kg - - - - -
Boron mg/kg - - - - -
Calcium mg/kg - - - - -
Chromium mg/kg - - - - -
Copper mg/kg - - - - -
Lead mg/kg - - - - -
Magnesium mg/kg - - - - -
Manganese mg/kg - - - - -
Molybdenum mg/kg - - - - -
Potassium mg/kg - - - - -
Silicon mg/kg - - - - -
Silver mg/kg - - - - -
Sodium mg/kg - - - - -
Tin mg/kg - - - - -
Titanium mg/kg - - - - -
Zinc mg/kg - - - - -
Phosphorus mg/kg - - - - -

(C) = Calculated

Page 15 of 29
 Table 11

Umm Shaif Crude Oil

Properties of 15-232 distillates

TBP cut point ºC API 95-149 149-175 175-232 15-175 15-200

Yield on crude oil %wt 10.00 5.25 - - -

Yield on crude oil %vol 11.26 5.73 11.35 27.43 32.39
Density at 15°C kg/litre - - - - -
Sulphur %wt - - - - -
Mercaptan sulphur %wt - - - - -
IP342 Hydrogen Sulphide %wt - - - - -
IP342 Elemental Sulphur %wt - - - - -
Total Nitrogen %wt - - - - -
Acidity mgKOH/g - - - - -
Pour point °C - - - - -
Freezing point ºC - - - - -
Mercury ppb wt - - - - -
Naphthalenes %vol - - - - -
Chlorine ppm - - - - -

Page 16 of 29
 Table 12

Umm Shaif Crude Oil

ASTM D86 distillation data in the 149 - 342°C range

TBP Cut point °C 149 - 232 232 - 342

Yield on crude oil %wt 16.10 21.25
Yield on crude oil %vol 17.08 21.06

On Cut On Cut

Initial Boiling point ºC - -

5% recovered ºC - -
10% recovered ºC - -
20% recovered ºC - -
30% recovered ºC - -
40% recovered ºC - -
50% recovered ºC - -
60% recovered ºC - -
70% recovered ºC - -
80% recovered ºC - -
90% recovered ºC - -
95% recovered ºC - -
Final Boiling Point ºC - -
Loss %vol - -
Residue %vol - -
Recovery %vol - -

Page 17 of 29
 Table 13
Umm Shaif Crude Oil
TAN and Betz NAN Analysis

Total Acid Betz NAN

Assay Distillation Number Number Percent Betz Nan
(mgKOH/g) (mgKOH/g) of TAN

Crude 0.05 - -

15-95ºC - - -
95-149ºC - - -
149-232ºC 0.02 - -
232-342ºC <0.05 - -
342-369ºC <0.05 - -
15-369ºC (C) - -
>369 (calc from crude and (IBP-369)) - -
>369ºC <0.05 - -
369-509 <0.05 - -
509-550 <0.05 - -
>550 - - -
Atmospheric stage (IBP-369 & >369) balanced on
crude 0.00 0.00
Atmospheric stage % Recovery >369 0.0 -
Vacuum stage (369-550 & >550) balanced on >369 0.00 0.00
Vacuum stage % Recovery >550 - -
% recovery of vac dist 369 vs target 369 - -

Total Acid Betz NAN

Minimum Residence Distillation Number Number Percent Betz Nan
(mgKOH/g) (mgKOH/g) of ACI

15-369ºC - - -
>369ºC (Calc from vac dist'n) - - -
369-509ºC - - -
509-550ºC - - -
>550ºC - - -

>369 calc from crude - (IBP-369) - -

Vac dist >369stage
Atmospheric vs Atmos dist &>369
(IBP-550 % recovery
>550) balanced on - -
crude - -
% Recovery - -

Final Flask temperature = 335 ºC

These calculations assume that <0.05 = 0
(C) = Calculated

Page 18 of 29
 Table 14
Umm Shaif Crude Oil
Asphaltene Solvency
Software version 2.0b

Solvent used for CSPa -

Solvent Power (SP) -
Asphaltene Critical Solvent Power (CSPa) -
Insolubles at Zero solvent power (PSN) -
Crude Solids Number (CSN) -

Asphaltenes
Solvent % Solvent Power Insolubles
wt% on crude
- - -
- - -
- - -
- - -
- - -
- - -
- - -
- - -
- - -
- - -
- - -
- - -
- - -
- - -

Notes: table for asphaltene crudes

Page 19 of 29
 Table 15
Umm Shaif Crude Oil
Asphaltene and Wax Solvency
Software version 2.0b

Solvent used for CSPw -

Solvent used for CSPa (UV) -
Solvent Power (SP) -
Asphaltene Critical Solvent Power (CSPa) -
Wax Critical Solvent Power (CSPw) -
Insolubles at Zero solvent power (PSN) -
Crude Solids Number (CSN) -

Wax + Asphaltenes
Solvent % Solvent Power Insolubles
wt% on crude
- - -
- - -
- - -
- - -
- - -
- - -
- - -
- - -
- - -
- - -
- - -
- - -
- - -
- - -

UV Asphaltenes
Solvent % Solvent Power Insolubles
wt% on crude
- - -
- - -
- - -
- - -
- - -
- - -
- - -
- - -
- - -
- - -
- - -
- - -
- - -
- - -

Page 20 of 29
 Table 16
Umm Shaif Crude Oil

C1- C8 % WT
methane -
ethane 0.01
propane 0.16
iso-butane 0.23
n-butane 1.10
iso-pentane 1.01
n-pentane 1.66
2,2-Dimethylbutane -
Cyclopentane + 2,3-Dimethylbutane 0.22
2-Methylpentane 0.80
3-methylpentane 0.51
n-hexane 1.71
2,2-dimethylpentane 0.02
methylcyclopentane 0.40
2,4-dimethylpentane 0.07
2,2,3-trimethylbutane 0.00
Benzene 0.23
3,3-dimethylpentane 0.02
cyclohexane 0.33
2-methylhexane + 2,3-dimethylpentane 0.67
1,1-dimethylcyclopentane 0.04
3-methylhexane 0.54
trans-1,3-dimethylcyclopentane 0.08
cis-1,3-dimethylcyclopentane 0.07
1,2-dimethylcyclopentane + 3-ethylpentane 0.00
n-heptane 1.66
Methylcyclohexane -
1,1,3-trimethylcyclopentane -
2,2-dimethylhexane -
ethylcyclopentane -
2,5-dimethylhexane -
2,4-dimethylhexane -
trans,cis-1,2,4-trimethylcyclopentane -
3,3-dimethylhexane -
trans,cis-1,2,3-trimethylcyclopentane -
2,3,4-trimethylpentane -
toluene -
2,3-dimethylhexane -
2-methyl-3-ethylpentane +
0.00
1,1,2-trimethylcyclopentane
2-methylheptane -
4-methylheptane -
cis-1,3-dimethylcyclohexane -
trans-1,4-dimethylcyclohexane +
0.00
3-methylheptane
3-ethylhexane -
1,1-dimethylcyclohexane -
1,3-ethylmethylcyclopentane -
2,2,5-trimethylhexane -
trans-1,3-ethylmethylcyclopentane -
trans-1,2-ethylmethylcyclohexane -
trans-1,2-dimethylcyclohexane -
trans-1,3- & cis-1,4-dimethylcyclohexane 0.00
n octane -

Page 21 of 29
Page 22 of 29
 Table 17
Umm Shaif Crude Oil
100pt SIMDIS data

BP Distribution table - Percent

Recovered BP
mass% °C
0.5 -
1 -
2 -
3 -
4 -
5 -
6 -
7 -
8 -
9 -
10 -
11 -
12 -
13 -
14 -
15 -
16 -
17 -
18 -
19 -
20 -
21 -
22 -
23 -
24 -
25 -
26 -
27 -
28 -
29 -
30 -
31 -
32 -
33 -
34 -
35 -
36 -
37 -
38 -
39 -
40 -
41 -
42 -
43 -
44 -
45 -
46 -
47 -
48 -
49 -
50 -
51 -
52 -

Page 23 of 29
 53 -
54 -
55 -
56 -
57 -
58 -
59 -
60 -
61 -
62 -
63 -
64 -
65 -
66 -
67 -
68 -
69 -
70 -
71 -
72 -
73 -
74 -
75 -
76 -
77 -
78 -
79 -
80 -
81 -
82 -
83 -
84 -
85 -
86 -
87 -
88 -
89 -
90 -
91 -
92 -
93 -
94 -
95 -
96 -
97 -
98 -
99 -
99.5 -

Page 24 of 29
 Table 18
Umm Shaif Crude Oil
poly-aromatic data

Aromatics 175-232 175-232 *232-342 *232-342 *342-369

%wt %vol %wt %vol %wt

1 ring - - 16.8 16.3 -
2 ring - - 12.2 10.1 -
3 ring+ - - 0.8 0.6 -

Page 25 of 29
*342-369

%vol
-
-
-

Page 26 of 29
 METHODS OF TEST LIST

TEST PRODUCT METHOD BASED ON METHOD REPEATABILITY REPRODUCIBILITY

Acidity FBP<250°C IP354/ASTM D3242 - 0.0132 × X 0.0406 × X

FBP>250°C In-house - MT/FLC/06 ASTM D664 / IP177 +/- 0.05 -
API Gravity Calc. 141.5/(density @ 15°C + 0.0005) - 131.5 - - -
Aromatics Content FIA Kerosine IP156/ASTM D1319 - 1.60% 3.50%
1,2,3 Ring Gas Oil IP391/95 - 5% 10%
Arsenic Crude Oil In-house - ICPMS - MT-IMS04 - 10% rel or +/- LOD -
Asphaltenes Residues IP143 - 10% 20%
Cadmium Crude Oil In-house - ICPMS - MT-IMS04 - 10% rel or +/- LOD -
Carbon Residue (Conradson) MCRT Residues ASTM D4530 - X2/3 × 0.077 X2/3 × 0.245
Cetane Index Distillates IP380/ASTM D976 - See Method See Method
Cloud Point Distillates IP219/ASTM D2500 - 2°C 4°C
Cloud Point (automatic) Distillates ASTM D5771 - 2°C 4°C
Colour Stability Distillates In-house - MT/FLC/01 ASTM D1500 0.5 -
Copper Crude Oil In-house - ICPMS - MT-IMS04 - 10% rel or +/- LOD -
Crude Simdis Crude Oil IP-PM-CF98 - - -
C sub A Distillates IP392 - 0.59 x1/3 1.37 x1/3
Density IP365 - 0.0003 0.0014
Dewaxing Waxy Dist. In-house - MT/FLC/03 - +/- 3 % wt -
Distillation Crude Oil ASTM D2892 (mod) - 0.5%wt 1.0%wt
Residue ASTM D5236 (mod) - 0.5%wt 1.0%wt
Freezing Point Distillates IP16/ASTM D2386 - 0.7°C 2.6°C
GC Research Octane Number Gasoline Calculated from GC individuals - - -
Hydrocarbon Analysis by GC
Aromatics Light Distillates IP262 (modified) - 5% rel. 10% rel.
C1 - C5 Crude Oil IP344 - 5% rel. 10% rel.
Individuals Gasoline In-house - MT/CMS/03 ASTM D5134 5% rel. 10% rel.
nP,iP,N,A Light Distillates IP382 (modified to include iP's) - 5% rel. 10% rel.
Hydrogen Content Distillates In-house - Micro - MT-MCR-15 ASTM D5291 0.30% -
Hydrogen Sulphide Crude Oil IP272 (modified) - See Method See Method
Lead Crude Oil In-house - ICPMS - MT-IMS04 - 10% rel or +/- LOD -
Mercury (Indication Only) Crude Oil In-house - HG-MT-1A - 10% rel or +/- LOD -
Naphthalenes Content Distillates ASTM D1840 - 0.05%vol. 0.11%vol
Nickel Content Crude Oil In-house - XRF - MT/ELE/05 - 2ppm 3ppm
Distillates In-house - ICP - MT/ELE/03 ASTM D 5185 / IP 437 +/- 0.2ppm wt/wt or if > 5% rel. -
Residues In-house - ICP - MT/ELE/01 ASTM D 5185, 4951 / IP 437 +/- 1ppm wt/wt or if > 3% rel. -
Nitrogen (Total) <100 ppm IP379/ASTM D4629 - 3% rel. 5%rel.
>100 ppm In-house - Micro - MT/ELE/12 IP379 3% rel. 5% rel.
Nitrogen (Basic) Heavy Dists. MT-FST-1406 - if >50 3% of amount -
Residues IP 276 (modified) - See Method See Method
Oxygen (Organic) Distillates In-house - Micro - MT-MCR-14 ASTM D5622 0.05 %wt 0.10 %wt
Pour Point IP15/ASTM D97 - 3°C 6°C
Pour Point (automatic) ASTM D5950 - 3°C 6°C
Refractive Index Distillates In-house - MT/FLC/02 ASTM D1218 0.0002 -
Residue Composition
Saturates Residues In-house - MT-LCH-07 IP469 4% rel. 10% rel.
Aromatics Residues In-house - MT-LCH-07 IP469 5% rel 10% rel.
Resins A Residues In-house - MT-LCH-07 IP469 10% rel. 20% rel.
Resins B Residues In-house - MT-LCH-07 IP469 10% rel. 20% rel.
Residue Hardness
Penetration Residues IP49 - 3% rel. 8% rel.
Softening Point Residues IP58 - 1°C 2.5°C
Salt Content Crude IP265 - 0.3 × X 1.6 × X
Smoke Point Distillate IP57 - 2mm 3mm
Sulphur (Total) Crude Oil In-house -XRF - MT/ELE/05 - 2% rel. 5% rel.
Distillates In-house -XRF - MT/ELE/05 - 2% rel. 5% rel.
Residues In-house - ICP - MT/ELE/01 ASTM D 5185, 4951 / IP 437 3% rel. -
Sulphur (Mercaptan) Distillate IP 30 Doctor Test - - -
Sulphur (Mercaptan) Distillate IP342/ASTM D3227 - 0.00007+0.027X 0.00031+0.042X
Vanadium Content Crude Oil In-house - XRF - MT/ELE/05 - 2ppm 3ppm
Distillates In-house - ICP - MT/ELE/03 ASTM D 5185 / IP 437 +/- 0.2ppm wt/wt or if > 5% rel -
Residues In-house - ICP - MT/ELE/01 ASTM D 5185, 4951 / IP 437 +/- 1ppm wt/wt or if > 3% rel. -
Viscosity (Kinematic) Distillates IP71/ASTM D445 - 0.35% rel. 0.70% rel.
Residues IP71/ASTM D445 - See Method See Method
Viscosity Index IP226/ASTM D2270 - See Method See Method
Water Content Crude IP74/ASTM D95 - 10% rel. 20% rel.
Wax Content Distillates In-house - NMR - MT/FLC/07 - 1.3% rel -
Residues In-house - MT/FLC/237 - 10% rel -
Xylene Equivalent Residues In-house - MT/FLC/05 - 2.9 9.9

Methods in bold are UKAS accredited

The repeatability and reproducibility figures quoted above are based on average values for crude oils and distillation
products. For results which are significantly higher or lower the test method should be consulted for a more accurate
statement of precision. A dash indicates that a precision statement has not yet been established or is not relevant.

Page 27 of 29
T °C VOL % T°C VOL % T °C VOL % T °C
50 6.13 160 26.55 270 48.50 380
55 6.13 165 27.64 275 49.48 385
60 6.26 170 28.70 280 50.46 390
65 7.87 175 29.74 285 51.43 395
70 9.93 180 30.76 290 52.40 400
75 10.35 185 31.76 295 53.36 410
80 10.38 190 32.75 300 54.30 420
85 10.99 195 33.72 305 55.24 430
90 11.34 200 34.70 310 56.19 440
95 12.75 205 35.69 315 57.13 450
100 14.71 210 36.68 320 58.06 460
105 15.36 215 37.69 325 59.00 470
110 15.61 220 38.69 330 59.93 480
115 16.51 225 39.70 335 60.86 490
120 18.26 230 40.70 340 61.79 500
125 18.71 235 41.69 345 62.70 510
130 20.38 240 42.67 350 63.59 520
135 20.97 245 43.64 355 64.45 525
140 22.29 250 44.61 360 65.29 530
145 23.19 255 45.58 365 66.10 540
150 24.22 260 46.56 370 66.88 550
155 25.42 265 47.53 375 67.64 600
VOL %
68.37
69.09
69.81
70.53
71.26
72.71
74.16
75.60
76.98
78.30
79.52
80.69
81.84
82.97
84.07
85.13
86.12
86.59
87.04
87.90
88.69
91.98