Helwan University 2nd semester

Science Faculty Academic year 2020-2021

Department: 2 nd year/phy.&chem. Time allowed: 1.30 hours
Role /June Course Code: Ph 223 Ph .M
Dr/Omnia Ahmed

Final Atomic and molecular Spectra Exam

The used constants: ,
s
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Choose the Correct answer of the following questions and then shaded perfectly the circle corresponding
to its symbol in the answer card: (35questions, each point 2, total 70 points)
36. Absorption spectrum results when an electron in an atom undergoes a transition from
a) Higher energy level to a lower one b) Lower energy level to a higher one
c) Intermediate levels d) All of the mentioned

37. The necessary condition for absorption spectrum is that __________

a) should be greater than the energy difference
b) should be smaller than the energy difference
c) should be equal to the energy difference
d) none of the mentioned

38 .What kind of spectrum is the following image?

a) Absorption spectrum b) Emission spectrum

c) Continuous (visible) spectrum d) this is not a spectrum of any kind

39. The radius of the Bohr orbit depends on which of the following?

40. What will be the longest wavelength in the Balmer series of hydrogen spectrum?
a) 6557 × 10-10 m b) 5557 × 10-10 m c) 9557 × 10-10 m d) 1557 × 10-10 m

41. In terms of Bohr radius , the radius of the second Bohr orbit of a hydrogen atom is given by
a) Twice Bohr radius b) 4 times Bohr radius
c) Same Bohr radius d) Half Bohr radius

42. The ionization energy for hydrogen atom is 13.6 eV. The ionization energy for the ground state of
is approximately
a) 13.6 b) 27.2 c) 40.8 d) 122.4 eV
43. Which atomic orbital is spherical in shape?
a) 2s b) 3p c) 3d d) 4f
44. Calculate the energy required to excite a hydrogen atom by causing an electronic transition from the
energy level with n = 1 to the level with n = 4. Recall that the quantized energies of the levels in the
hydrogen atom are given by:

1
45. Which quantum numbers gives the shell to which the electron belongs?
a) n b) l c) m d) s
46. Which of the following is the correct expression for the orbital angular momentum?
√( + 𝐛 √ ( + 𝐜 √( + √ ( +

47. How many values does the spin quantum number have?
a) 2 b) 2l c) 2n d) 2me

48. In Bohr, theory of hydrogen atom be the frequency of revolution of the hydrogen atom in the
nth orbit, then

49. Energy of an electron in the nth Bohr orbit is

𝑬 𝑬 𝑬 𝑬

50. Lyman series of hydrogen spectrum falls in the

a) VIS region b) UV region c) IR region d) none of these

51. The total energy of an electron in the nth orbit of hydrogen atom is

𝝅𝜺 𝒓 𝝅𝜺 𝒓 𝝅𝜺 𝒓 𝝅𝜺 𝒓

52. The constant is called

a) Planck's constant b) Rydberg constant
c) Fine structure constant d) Boltzman constant

53. If the azimuthal number , the electron orbit is Sommerfeld model becomes a
a) circle b) ellipse c) straight line d) none of these

54. The state of an atom obeying L-S coupling is represented by

( ( ( (

55. The value of Landé splitting factor for s state

a) 0 b) 1 c) 2 d)

56. If an electron has orbital angular momentum quantum number , then it will have an orbital
angular momentum equal to
a) b) c) √ d) √

57. If according to Bohr model of the hydrogen the ionization energy of the atom in its ground state is,
13.6 eV then the energy required to ionize the atom from its first excited state will be
a) b) c) d)

58. Which statement about the four quantum numbers which describe electrons in atoms is incorrect?
(a) n = principal quantum number, n = 1, 2, 3, ......
(b) = subsidiary (or azimuthal) quantum number, l = 1, 2, 3, ... , (n+1)
(c) ml = magnetic quantum number, ml = (-l), .... , 0, .... , (+l)
(d) ms = spin quantum number, ms = +1/2 or -1/2.
(e) The magnetic quantum number is related to the orientation of atomic orbitals in space.
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59. The spin gyromagnetic ratio g(spin) associated with an electron in an atom is given by

60. The value of Bohr magneton is

61. On which of the following levels of hydrogen the spin –orbit interaction has no effect?
a) s-level b) p-level c) d-level d) f-level

62. The value of spin quantum number of an electron in hydrogen atom is

+

63. The Larmor precessional frequency of an electron of charge e in a magnetic field is

𝝅
a) b) c) d)
𝝅 𝝅 𝝅
64. Zeeman shift in terms of wavelength is given by
𝝅
a) ( ) b) ± ( ) c) ( ) d) ( )
𝝅 𝝅 𝝅
65. At-higher magnetic fields, the splitting of spectral lines is disturbed. This effect is called __________
a) Stark Effect b) Inverse Zeeman Effect c) Paschen-back effect d) Anomalous Zeeman effect

66. The perturbation due to the magnetic field is given by ________

a) µ.B b) µ.E c) -µ. E d) -µ. B

67. In which orbital does the splitting occur?

a) s b) p c) d d) f

68. The multiplicity for the given oxygen atom equals

a) 3 b) 1 c) 4 d) 2

69. At 1.5 T the chemical shift between water and fat protons results in a frequency difference of
approximately 220 Hz. What would be their frequency difference at 3.0T?
a) 110 b) 220 c) 440 d) 660

70. The normal Zeeman Effect a level of given splits into

a) levels b) levels c) ( + levels d) ( levels
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Best wishes for success
Dr/Omnia Ahmed