1. A solute, S, has a KD between water and chloroform of 5.00. A 50.00-mL sample of a 0.

050
M aqueous solution of the solute is extracted with 15.00 mL of chloroform.

i. What is the extraction efficiency for this separation?

ii. What is the solute’s final concentration in each phase?
iii. What volume of chloroform is needed to extract 99.9% of the solute?

2a. What is the molecular mass of an organic compound if 16.00 g of the compound is dissolved
in 225.0 g of carbon tetrachloride raises the boiling point to 85.36 °C?
Given that; ebullioscopic constant: 5.03 °C kg mol¯1 ,boiling point: 76.72 °C

b. What is the boiling point elevation when 147 g of lactic acid (C6H10O5) is dissolved in 647 g of
cyclohexane (C6H12)? The boiling point constant for cyclohexane is 2.79 °C/m.

3. For the reaction A => Products, the following data were obtained.
Time, hrs Concentration ,M
0 1.240
1 0.960
2 0.775
3 0.655
4 0.560
5 0.502
6 0.442
7 0.402
8 0.365
9 0.335
10 0.310

Make appropriate plots using these data to test them for zero-, first- and second- order rate
laws.

Hint:

[A] against time – zero order

In [A] against time- first order

1/ [A] against time-second order