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Journal of Building Engineering 29 (2020) 101143

Contents lists available at ScienceDirect

Journal of Building Engineering


journal homepage: http://www.elsevier.com/locate/jobe

Influence of gypsum wastes on the workability of plasters: Heating process


and microstructural analysis
~ o-Rojas a, *, J. De Brito b, I. Flores-Colen b, M.F.C. Pereira c, P. Rubio-de-Hita a
M.A. Pedren
a
Departamento de Construcciones Arquitect� onicas 1, Escuela T�ecnica Superior de Arquitectura, Universidad de Sevilla, Avenida Reina Mercedes, n_ 2, 41012, Sevilla,
Spain
b
CERIS, Instituto Superior T�ecnico, Universidade de Lisboa, Av. Rovisco Pais, 1049-001, Lisboa, Portugal
c
CERENA, Instituto Superior T�ecnico, Universidade de Lisboa, Av. Rovisco Pais, 1049-001, Lisboa, Portugal

A R T I C L E I N F O A B S T R A C T

Keywords: The construction sector consumes 95% of the total production of gypsum due to its multiple applications.
Gypsum waste Gypsum plaster is one of the most common indoor coating material (pastes and mortars), but it can also be used
Workability in prefabricated products like plasterboards, blocks and decorative elements. Gypsum waste recycling provides a
Plasters
solution to an important environmental problem from the use of gypsum plaster, which is the generation of large
Heating process
Microstructural analysis
amounts of wastes at different phases (production, construction, rehabilitation and demolition).
This paper studies two different replacement alternatives of natural gypsum: Flue Gas Desulphurization (FGD)
gypsum and gypsum waste obtained from industrial plasterboard production. The influence of the previous types,
amounts of waste (25, 50, 75 and 100 wt%) and different heating temperatures (100 � C, 150 � C and 180 � C) and
processes on the workability of gypsum plasters is evaluated and discussed, based on a microstructure analysis
using XRD and SEM techniques.
This research highlights the feasibility, in terms of workability, of using Gypsum Plasterboard Waste (GPW),
without any heating process, as a replacement gypsum in plasters. Despite the fact that a higher amount of water
was necessary in the production of the mixes, a good workability was achieved. On the other hand, the unfea­
sibility of using unheated FGD as a constituent of plasters was demonstrated. However, a good performance, in
terms of workability, of the FGD was obtained when the powder was subjected to a heating process at 180 � C
during 6 h.

1. Introduction incorporating different types of waste for the generation of materials


and products in construction [2–6].
The construction sector is one of the most responsible for current The construction sector consumes 95% of the total production of
environmental problems. On the one hand, the processes of obtaining gypsum due to its multiple applications. Gypsum plaster [7,8], used as
and producing construction materials consume large amounts of natural pastes or mortars for renderings, is one of the most common indoor
resources, while generating significant amounts of waste from coating material, but it can also be used in prefabricated products like
manufacturing, construction, rehabilitation and demolition activities. In plasterboards, blocks and decorative elements [9,10]. However, this
2014, 868 million tons of construction and demolition waste (CDW) also has a negative impact on the environment because of the energy
were generated in the EU-28, representing 34.7% of the total European consumption for the manufacture of gypsum to be applied in
waste for that year [1]. Furthermore, one of the main challenges set by construction.
the European Union within the Horizon 2020 program is to be able to Gypsum plaster for construction, bassanite (CaSO4⋅0.5H2O - calcium
properly manage the waste generated, on which CDW are included. In sulphate hemihydrate) is obtained by drying calcination of natural
that context, European Directive 2008/98/CE defines a target for 2020: gypsum (CaSO4⋅2H2O - calcium sulphate dihydrate) rock at 105 � C to
70% of all CDW must be recycled. In this context, many researchers and 200 � C. After that, water must be added, generating an exothermic re­
companies in the sector have been studying the feasibility of action, explained by Le Chatelier, on which the gypsum plaster

* Corresponding author.
E-mail addresses: mpedreno@us.es, mjesus.moralesconde@gmail.com (M.A. Pedre~
no-Rojas).

https://doi.org/10.1016/j.jobe.2019.101143
Received 11 August 2019; Received in revised form 13 December 2019; Accepted 21 December 2019
Available online 25 December 2019
2352-7102/© 2019 Elsevier Ltd. All rights reserved.
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Fig. 1. Gypsums in their original state before the shaving process. A. CG (CaSO4⋅0.5H2O). B. FGD (CaSO4⋅2H2O). C. GPW after the cutting process (CaSO4⋅0.5H2O
and CaSO4⋅2H2O).

Fig. 2. Particle size distribution of each type of gypsum used in the study.

Fig. 3. XRD of the gypsum powders used in the study in their original state.

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Fig. 4. Comparative SEM images (2400x) of the gypsum powders, from very small particles. A. CG. B. FGD. C. GPW.

Jimenez-Rivero and García-Navarro [18,19]. They found that the eco­


Table 1 nomic and environmental cost of recycling gypsum plaster waste (GPW)
Temperature and time used for each heating process. is lower than the cost of its disposal in landfills (87% of GPW ended in
Heating process Without heating (WH) Temperature [� C] Time [h] landfills in the EU-28) according to the different economic, social and
environmental factors that they analysed. They also conducted an
– –
experimental procedure to maximize the GPW content in the production
100–6 100 6 of gypsum plasters and plasterboards [20]. Camarini et al. evaluated the
100–24 100 24
effects of several temperatures (120 � C, 150 � C and 200 � C) and heating
150–3 150 3
150–6 150 6 times (1, 2, 5, 8, 16 and 24 h) on the use of gypsum waste as a
180–3 180 3 replacement of natural gypsum. The best results were obtained when the
180–6 180 6 material was heated at 150 � C. They concluded that the mechanical and
environmental behaviour of the new gypsum-waste based materials is
better than the one obtained for commercial gypsum [21]. Finally,
rehydrates becoming a hard material as shown in eq. (1) [11,12]. Suarez et al. used 5% of recycled gypsum, as a set retarder replacing
105 to 200 � C
natural gypsum, in the generation of cement mortars. They achieved a
CaSO4 ⋅ 2H2 O → CaSO4 ⋅0:5H2 O þ 1:5H2 O→ CaSO4 ⋅2H2 O reduction of 65% in the embodied energy and CO2 emissions [22].
þ Heat (1) In addition to the commercial gypsum and the recycling of gypsum
waste, another type of gypsum has been found. It is a synthetic material,
When water is added, the material turns into the original state again. with the same chemical composition as gypsum, which is obtained from
It means that gypsum wastes generate a closed-loop recycling process on the desulphurization of gases in coal-fired power stations [23]. It is
which the chemical composition of the material does not change [13]. called flue gas desulphurization (FGD) gypsum and its use as a
That gives a solution to an important environmental problem of the use replacement of natural gypsum is widely extended around the world
of gypsum plaster, which is the generation of large amounts of wastes at [24]. However, more than 13 million tons of FGD ended in landfills each
different phases (production, construction, rehabilitation and demoli­ year in the United States [25]. For that reason, many researchers tried to
tion). According to Ahmed et al. more than 15 million tons of gypsum increase the use of that material in different sectors: gypsum products,
products ended in landfills annually in the world [14]. For that reason, cements and concretes and agriculture uses. In that sense, for con­
the use of gypsum waste as substitute of commercial one is an option struction applications, most of those investigations used a certain
that some researchers and enterprises have developed in the last years heating temperature (105–200 � C) and maintained it until all the gyp­
[15–17]. sum is transformed into Bassanite (3–24 h) [26–30].
In that sense, it must be highlighted the contributions made by Up to now, most of the studies that used gypsum wastes submitted

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Fig. 5. XRD of the FGD powders without and after the different heating processes.

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Fig. 6. SEM images of FGDs powders. A. WH. B. 100–24. C. 150–6. D. 180–6. Highlights: particle cracks (red).

the material to a previous calcination process (105–200 � C), reducing The GPW used for this project was taken from the waste powder
the environmental benefits of the recycling procedure [21]. produced during the plasterboards cutting process (Fig. 1C).
This paper discusses the workability of plasters produced with two
types of gypsum waste (Flue Gas Desulphurization gypsum and gypsum Fig. 2 presents the original particle size distribution of each type of
waste obtained from industrial plasterboard production), focusing on gypsum used on the experimental program. Only particles smaller than
different heating processes and on the microstructure analysis of the 1 mm were taken to generate the new composites.
plasters. This paper is a complementary to a previous publication [31] X-Ray Diffraction (XRD) method was used to obtain the chemical
on which the mechanical and environmental behaviour of the plasters composition of each gypsum. A XPERT-PRO PANALYTICAL diffrac­
were evaluated. tometer system was used, operating with a CuKα radiation with 35 mA
The paper has two main parts. In the first one (sections 2.1 and 2.2), and 40 kV as generator settings. To identify the crystalline phases High
the waste before and after heating processes is characterized and specific Score Plus with PDF2 database was used. Fig. 3 shows the diffractogram
techniques (XRD, SEM) and different heating process are presented. of each material and it can be noticed that, as expected, the commercial
In the second part (in sections 3, 4 and 5), the main results of the gypsum is mostly 100% bassanite (CaSO4⋅0.5H2O) with a small amount
paper are presented and discussed for plasters. of calcite (CaCO3), the FGD is only composed by gypsum (CaSO4⋅2H2O),
while the GPW is a mixture of these particles (gypsum and bassanite).
2. Gypsum powder wastes under analysis The characterization obtained with the XRD could also be checked
with the images from Scanning Electron Microscopy (SEM), which was
2.1. Materials characterization in their original state conducted using a FEI TENEO field emission scanning electron micro­
scope. Thus, Fig. 4 shows an important difference, related with the size
In order to develop the new gypsum plasters, three different kinds of and the shape of the particles, between the FGD and the other two
gypsum were employed (Fig. 1): materials. It was observed that commercial gypsum particles (Fig. 4A)
had an intermediate size between FGD and GPW ones (5–15 μm). The
- Commercial or natural gypsum (CG): traditional (controlled setting) FGD (Fig. 4B) had larger (20–50 μm) and very round particles, while in
gypsum for construction, or B1 gypsum according to standard UNE- the others the particles were smaller and with straighter shapes. On the
EN 13 279–1 [7], was used for comparison purposes (Fig. 1A). other hand, in the GPW sample (Fig. 4C) fibres are visible.
- Flue Gas Desulphurization (FGD) Gypsum: This synthetic material
(Fig. 1B) was generated by the desulphurization of gases in Pego’s 2.2. Materials characterization after various heating processes
coal power plant (Portugal).
- Gypsum Plasterboard Waste (GPW) from Production: The waste was Apart from using the gypsum material in their original state,
given by Gypfor, a plasterboard production plant in Sines (Portugal). different heating processes were carried out on both types of gypsum
waste under analysis, which were used to develop the new plaster

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Fig. 7. XRD of the GPW powders after the various heating processes.

composites. For all heating processes, a CONTROLS 10-D1396 labora­ 2.2.2. Gypsum plasterboard waste (GPW)
tory oven was used. The material was heated in the oven using different Fig. 7 shows the diffractograms obtained for GPW after each heating
rectangular trays of 40 � 25 cm2, in which approximately 4 kg of waste process. As expected, the amount of gypsum particles decreased with
was deposited. The waste was distributed evenly in the tray, so that the calcination. 3 h at 150 � C were enough to substitute all gypsum with
largest surface area of material was exposed to the heating procedure. bassanite. However, 6 h at 100 � C were not enough to fully eliminate the
After heating, the powder was cooled at laboratory temperature (23 � C) gypsum phase, i.e. a small part remained in the material. Finally, as in
during 3 h before using them to make the mixes. The temperature and the commercial gypsum (Fig. 3), a small amout of calcite was found in
time used for each heating process is shown in Table 1. the heated gypsum.
The SEM images obtained for GPW after the various heating pro­
2.2.1. Flue gas desulphurization gypsum (FGD) cesses, and their influence on the glass fibres, are presented in Fig. 8. The
Fig. 5 shows the results for the XRD of the FGD powders after each obtained particle size and shape of the materials were very similar to the
heating process. As expected, the amount of gypsum particles decreased ones of commercial gypsum. Furthermore, no bigger differences were
when heating occurred. However, only one of the developed calcination perceived when the heated gypsum was compared with the non-heated
methods (180 � C for 6 h) changed all the gypsum particles into bas­ one. However, Fig. 8C and D and shows that a small degradation in the
sanite. Furthermore, the calcination at 100 � C for 24 h changed a large glass fibre was found when the GPW was heated at 150 � C and 180 � C for
amount of gypsum into bassanite, and only a minimum amount of 6 h.
gypsum remained.
As shown in Fig. 6, degradation of the gypsum particles occurred 3. Workability study in plasters
when they were subjected to the heating process. Those cracks were
more significant in particles heated for 6 h at 180 � C, looking similar to In this section, the workability of using various gypsum wastes as
the images obtained for commercial gypsum (Fig. 4A). partial or complete replacement of natural gypsum in plasters was

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Fig. 8. SEM images of GPW powders (left side) and glass fibre details (right image). A. WH. B. 100–24. C. 150–6. D. 180–6. Highlights: glass fibre surface
degradation (blue).

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Table 2
Composition of the various gypsum plaster mixes under study.
Gypsum plaster Commercial gypsum [wt. %] FGD [wt. %] Gypsum plasterboard waste [wt. %]

Reference 100 – –

FGD 25 WH 75 25 –
100–6
FGD 50 100–24 50 50 –
150–3
FGD 75 150–6 25 75 –
180–3
FGD 100 180–6 – 100 –

GPW 25 WH 75 – 25
100–6
GPW 50 100–24 50 – 50
150–3
GPW 75 150–6 25 – 75
180–3
GPW 100 180–6 – – 100

3.1. Gypsum plaster mixes

Different percentages of both types of waste, submitted to various


heating processes, were used as a substitute of natural gypsum to
develop the new gypsum plasters. All of those new mixtures are pre­
sented in Table 2.
Apart from the reference sample, four substitution ratio mixes (25,
50, 75 and 100 wt %) per type of gypsum waste and per type of heating
process were produced.

3.2. Workability and water content

Fig. 9. Flow table method. Workability is directly related with the water/gypsum (w/g) ratio of
the mixes. According to the standard [8], the water content of each mix
analysed. Workability is one of the most relevant properties of plasters in can be measured using the flow-table test (Fig. 9). The w/g ratio is
the fresh state. This property must be controlled during all the imple­ determined by trial and error until a 165 � 5 mm diameter is achieved
mentation process of the gypsum plasters in the walls or ceilings. By after a truncated cone (40 mm of height and inner diameters of 65 mm
achieving a fluid consistency, workability can be guaranteed. In that and 75 mm), filled with slurry, is removed and jolted with 15 vertical
sense, workability is directly related with the water/gypsum (w/g) ratio blows to the flow table at a constant speed of 1 revolution per second.
of the mixes. First, following the flow-table method, the w/g ratio of the reference

Fig. 10. Water/gypsum ratio of the FGD plasters.

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Fig. 11. Water/gypsum ratios of the GPW plasters.

Table 3
Physical and mechanical properties of the various gypsum plaster mixes under study.
Gypsum plaster Dry bulk density [g/cm3] Flexural strength [MPa] Compressive strength [MPa] Emod [MPa] Thermal conductivity [W/mK]

Reference 1.34 3.09 7.32 5080 0.250

FGD 50 WH 1.30 0.11 0.21 960 0.248


FGD 50 100–24 1.09 1.07 2.39 2840 0.244
FGD 50 180–6 1.08 3.15 7.65 5230 0.239
FGD 100 100–24 1.10 0.31 0.92 1760 0.241
FGD 100 180–6 1.09 3.27 7.88 5560 0.236

GPW 50 WH 1.00 1.58 4.38 3020 0.217


GPW 50 100–24 0.92 2.32 7.29 4420 0.201
GPW 50 180–6 0.90 2.46 6.74 4470 0.195
GPW 100 WH 0.98 3.41 8.61 5690 0.203
GPW 100 100–24 0.86 2.17 6.40 4360 0.186
GPW 100 180–6 0.84 2.53 6.18 4180 0.181

sample was determined. For the reference material, made exclusively mixes that use GPW without heating. With only 5% of gypsum waste, a
with commercial gypsum, a ratio of 0.55 was achieved. water increase of 45% was obtained to reach the standard requirements,
Once this value was obtained, in a first phase, it was decided to use according to the flow table method. This behaviour is similar with the
the 0.55 ratio for the mixes with gypsum waste and adapt it depending one obtained by Camarini et al. who used citric acid as a set retarder for
on the type of material used. In the case of the plasters with FGD, it was the plasters with gypsum waste [32]. Finally, as happened with FGD
observed that, as expected, this value was excessive since it contained a plasters, it was found that when GPW heated at 180 � C was used to
high percentage of gypsum particles, requiring a smaller amount of create the new plasters, w/g ratio was, in all the cases, the same as for
water to set. On the other hand, in the GPW mixes there was a need to the reference sample (0.55).
increase the water content, as the setting process began just a few sec­
onds after adding the kneading water. Thus, the correct w/g ratio for 4. Physical and mechanical characterization of the new plasters
each composite, according to the standard [8], had to be determined.
Fig. 10 shows the w/g ratios of the various FGD composites. The The physical and mechanical characterization of the new plasters
amount of water needed decreased as the waste content increased. with a recycled gypsum matrix was reported on a previous research
Furthermore, that decrease was bigger in plasters with waste without [31]. There, the dry bulk density, the flexural and compressive strength,
heating. It was also observed that the FGD 100 WH sample could not be dynamic Young’s modulus (Emod) and thermal conductivity of the new
produced because the powder did not react with the water at all. This mixes were analysed, according to the standards [7,8]. However, and
behaviour can be justified with the diffractograms of each material trying to facilitate the interpretation of the results of the present paper, a
shown in Fig. 4. According to them, when the amount of gypsum par­ summary of the physical and mechanical characterization of these
ticles in the waste is bigger, the amount of kneading water decreases. plasters is included in Table 3.
Finally, it was observed that when FGD heated at 180 � C was used to The dry bulk density of the plasters decreased, in all cases, when the
create the new plasters, w/g ratio was, in all the cases, the same as for content of waste increased. That drop was higher in mixes that con­
the reference sample (0.55). tained waste with a more intense heating process. The mechanical tests
On the other hand, the w/g ratio for GPW plasters increased when for FGD gypsum plasters revealed that 180 � C during 6 h were needed in
the waste content went up. As seen in Fig. 11, that increase is bigger in the heating process to use that waste as substitute of the commercial

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Fig. 12. SEM images of the reference plaster. A. 600x. B. 2400x. Highlights: grouped elongated crystals (green).

gypsum in plasters. However, for GPW plasters, it was noticed that, GPW composites, which meant a more compact gypsum matrix for all
without any heating process, the waste could perfectly be used in plas­ the mixes. This could be translated into an improvement of the me­
ters, even improving the mechanical results relative to the reference chanical properties of the mixes. In all cases, a good adherence between
material. Finally, the thermal conductivity of the plasters had a slight the gypsum matrix and the glass fibres was achieved, being better in
improvement when the content of waste increased, and was better for composites with 100% of GPW. Furthermore, the compactness of the
those with a more intense heating process. matrix was better in mixes with GPW without heating.

5. Microstructural analysis 6. Conclusions

In order to justify the behaviour of each type of plaster when various In this research, the workability of plasters with Flue Gas Desul­
gypsum wastes were added to the mixture, a SEM analysis was carried phurization Gypsum (FGD) and Gypsum Plasterboard Waste (GPW), as
out. partial or total replacement of natural gypsum, was analysed, including
Fig. 12 shows the SEM images obtained for the reference plaster, several heating processes. In addition, a microstructural analysis using
exclusively made with commercial gypsum. In it, all the material had XRD and SEM was carried out. The following conclusions were obtained:
reacted when water was added to the mix, generating a homogeneous
structure of grouped elongated crystals that have a length between 20 - The XRD and SEM analysis of the two gypsum wastes (in powder)
μm and 40 μm. Those measurements were in accordance with other used in this study in their original state showed that FGD is fully
studies of the literature [12,33,34]. composed of gypsum particles, while GPW had a mixture of gypsum
Fig. 13 presents the SEM images obtained for FGD25 WH, FGD25 and bassanite in its chemical composition. Furthermore, the presence
100–24, FGD100 100–24, FGD25 150–6, FGD100 150–6, FGD25 180–6 of glass fibres in GPW was found using SEM.
and FGD100 180-6 plasters. The gypsum particles did not react with the - The gypsum powder wastes under study were subjected to various
kneading water. Furthermore, the adherence between those particles heating processes. It could be noticed that, for FGD, the calcination at
and the rest of the matrix was not good enough. Big pores (50–75 μm) 180 � C for 6 h was the only one that changed all the gypsum particles
appeared in the plasters. Only commercial gypsum particles (Fig. 13A, B into bassanite. However, 3 h at 150 � C were enough to substitute all
and D), and the small percentage of bassanite particles from FGD after the gypsum by bassanite in GPW. In addition, a small surface
the heating processes (Fig. 13C), reacted with water creating gypsum degradation in the glass fibres was perceived when the GPW was
crystals in the plaster. In addition, in that case crystals were not as heated at 150 � C and 180 � C for 6 h.
elongated as the ones of the reference plaster, having a more flattened - In terms of workability of the plasters, it was observed that the
shape [35]. water/gypsum ratio adequate for the reference sample was excessive
The SEM image of plaster FGD100 150–6 (Fig. 13E) seemed very for FGD mixes, since they contained a high percentage of gypsum
similar to the ones of the FGD powders (Fig. 6). This meant that no particles, requiring a smaller amount of water to set (up to 54.5%
particles had reacted with the water, forecasting a bad behaviour of that less). On the other hand, in the GPW mixtures the need to increase
plaster composite. the amount of water was detected (up to 236.4% more), as the setting
Finally, the SEM images of plasters FGD25 180–6 and FGD100 180–6 process began just a few seconds after adding the water to the mix.
(Fig. 13F and G) seemed very similar to the ones of the reference ma­ - The SEM analysis of the FGD plasters showed that the gypsum par­
terials (Fig. 12). In them, it could be seen that all the particles have ticles did not react with the water in order to create the plaster.
reacted with the water, forming crystals very similar to those obtained Moreover, the adherence between those particles and the rest of the
for commercial gypsum. In addition, FGD100 180-6 sample (Fig. 13G) matrix was not good enough. On the other hand, the SEM images of
showed larger crystals and a more compact matrix than the reference plasters with FGD heated at 180 � C for 6 h formed crystals, very
plaster. similar to those obtained for commercial gypsum.
SEM images of some GPW plasters are shown in Fig. 14. The internal - The internal structure of the matrices of GPW plasters is very similar
structure of the matrices was very similar to that of the reference one to that of the reference mix. However, the crystal lengths were
(Fig. 12). Those results are analogous to those achieved by Camarini and shorter (5–15 μm vs. 20–40 μm) for GPW composites, which meant a
Pinheiro, who also obtained a very similar structure for both types of more compact gypsum matrix for all the mixes. In all cases, a good
plasters [36]. However, the crystal lengths were shorter (5–15 μm) for adherence between the gypsum matrix and the glass fibres was

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Fig. 13. SEM images of FGD plasters (600x). A. FGD25 WH sample. B. FGD25 100-24 sample. C. FGD100 100-24 sample. D. FGD25 150-6 sample. E. FGD100 150-6
sample. F. FGD25 180-6 sample. G. FGD100 180-6 sample. Highlights: dihydrate original state particles (blue), gypsum crystals (green) and bad adherence between
these materials (red).

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Fig. 14. SEM images of GPW plasters (600x). A. GPW25 WH sample. B. GPW100 WH sample. C. GPW25 100-24 sample. D. GPW100 100-24 sample. E. GPW25 150-6
sample. F. GPW100 150-6 sample. Highlights: glass fibre good adherence (blue) and compact gypsum matrix (green).

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achieved, being better in composites with 100% of GPW. Addition­ [9] J. De Brito, I. Flores-Colen, Gypsum plasters, in: Materials for Construction and
Civil Engineering, Springer, Cham, 2015, pp. 123–184.
ally, the compactness of the matrix was better in mixes that used
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GPW without heating. G. Camarini, Gypsum plaster waste recycling: a potential environmental and
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� Carbon footprint analysis of calcined gypsum production in the
Czech Republic, J. Clean. Prod. 177 (2018) 795–802.
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unheated GPW was used. On the other hand, the unfeasibility of using hydration reactions—the case of gypsum plasters, Cement Concr. Res. 39 (4)
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support provided by the FPU Program of Spain’s Ministry of Education desulfurization gypsum in sustainable wallboard production, Coal Combustion and
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facturers and companies: Gypfor, Gyptec and EDP. The authors also [27] D.Y. Lei, L.P. Guo, W. Sun, J.P. Liu, C.W. Miao, Study on properties of untreated
FGD-based high-strength building materials, Constr. Build. Mater. 153 (2017)
acknowledge the support of the CERIS research unit from IST, and FCT 765–773.
(Foundation for Science and Technology).COMPLIANCE WITH [28] C. Leiva, C.G. Arenas, L.F. Vilches, J. Vale, A. Gimenez, J.C. Ballesteros,
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