Chemistry Perfect Score Guide 2011
Chemistry Perfect Score Guide 2011
CHEMISTRY
PANEL PENYEDIA DAN PEMURNI:
Pn. Wan Noor Afifah Binti Wan Yusoff (Ketua) SBPI GOMBAK
Pn. Aishah Peong Binti Abdullah SBPI TEMERLOH
Pn. Norini Binti Jaafar SEKOLAH SULTAN ALAM SHAH
Pn. Noraini Binti Zakaria SMS SULTAN MOHAMAD JIWA
Pn. Rossita Binti Radzak SMS TUANKU MUNAWIR
En Che Malik Bin Mamat SBPI BATU RAKIT
En Jong Kak Ying SMS KUCHING
En Ooi Yoong Seang SMS MUAR
Pn Sa’adah Binti Mohayuddin SMS SERI PUTERI
Pn Faridah Bt Hamat SMS TUANKU MUNAWWIR
Electrochemistry
3 Set 2
Oxidation and Reduction
Carbon compounds
5 Set 4 Manufactured Substance in Industry
Chemicals for Consumers
Paper 3 set 1
6 Set 5 Paper 3 set 2
Paper 3 set 3
GUIDELINES
&
ANSWERING TECHNIQUES
CHEMISTRY SPM
3.1 Master the topics that contains the basic concepts of chemistry :
1. The structure of the atom
2. Chemical Formulae And Equations
3. Periodic Table
4. Chemical Bond
3.2 Familiarize with different types of questions as listed below and complete the previous SPM papers:
1. Objectives questions (MCQ) (Paper 1)
2. Structured questions ( Paper 2 & 3)
3. Essays (Paper 2)
4. Planning an experiment ( Paper 3)
5. Draw and label the diagram
6. Writing chemical equation( balanced equation, ionic equation, half equation)
4.3 Answer all SPM objective questions (2003 – 2010). Objective questions for each year contain all topics. If
your score in paper 1 is 40 and above, you will able to answer questions in paper 2 & 3 easily.
The question normally starts with certain situation related to daily life.
Problem statement/ aim of the experiment / hypothesis and variable can be concluded from the situation given.
State all the variables
Manipulated variable :
Responding variable :
Constant variable: list down all the fixed variables to ensure the outcome of the responding variable is related only to
the manipulated variables.
Separate the substances and apparatus
- Separate the substances and apparatus
- Apparatus : list down the apparatus for the experiment.
Example: Rate of reaction – stop watch
Termochemistry - thermometer
Procedure :
All the steps taken in the procedure must include the apparatus used, quantity and type of substance (powder, solution, lumps
… etc).
No mark is allocated for the diagram. The complete labeled diagram can help students in :
I. Writing the steps taken in the procedure
II. Listing the apparatus and materials
Tabulation of data:
The number of columns and rows in the table is related to the manipulated and responding
variables
Units must be written for all the titles in each row and column of the table
DO NOT WRITE the observation/inference/conclusion in the table.
- No mark is awarded for the diagram. The diagram can help students write the steps taken in the
procedure.
Describe an - List of materials 1m
Can be obtained from the diagram
experiment - List of apparatus 1m
( 8 - 10 marks) - Procedure - ( 5 – 8 m)
(Paper 2) - Observation/tabulation of data/ calculation/sketch of the graph/ chemical equation /ionic equation
/conclusion …… etc.
- Any additional details relevant derived from the question.
SET
1. The Structure of Atom
2. Chemical Formulae and Equations
3. Periodic Table of Elements
4. Chemical Bonds
1 Diagram 1 shows the apparatus set-up used in an experiment to determine the empirical formula of an
oxide of copper.
Copper oxide
Burning of excess
hydrogen
Dry hydrogen
gas
Heat
DIAGRAM 1
The following data was obtained:
Mass of combustion tube + porcelain dish = 25.30 g
Mass of combustion tube + porcelain dish + copper(II) oxide = 53.30 g
Mass of combustion tube + porcelain dish + copper = 47.70 g
………………………………………………………………………………………………………..
[1 mark]
(b) Write a chemical equation for the reaction used to produce hydrogen gas.
……......................................................................................................................................................
[2 marks]
(c) How to ensure that all the copper oxide is completely reacted?
……………………………………………………………………………………………………......
………...………………………………………………………………………………………..........
[1 mark]
(d) Based on the data given, determine the empirical formula of the copper oxide.
[4 marks]
(e) Write the chemical equation for the reaction between hydrogen and the oxide of copper.
……………..........................................................................................................................................
[2 marks]
(f) After the reaction is completed, hydrogen gas is allowed to flow continuously until the copper
is cooled to room temperature. Explain why .
………….………………………………………………………………………………………….....
………….………………………………………………………………………………………….....
[1 marks]
[ 2 marks]
2 (a) 70.2 g of aluminium carbonate decomposed easily when heated to produce aluminium oxide based
on the following equation.
[Relative atomic mass: Al: 27 ; C: 12; O: 16; 1 mole of gas occupied 24 dm3 at room condition]
…………..…………………………………………………………………………………...
[1 mark]
(ii) Write a balanced chemical equation for the reaction above.
…………………………………………………………………............................................
[2 marks]
(iii) Calculate the mass of aluminium oxide that is produced.
[3 marks]
(iv) Calculate the volume of carbon dioxide gas produced at room conditions .
[3 marks]
Table 2
……….....................................................................................................................................
[1 mark]
(ii) State the name of the products formed.
……….……………………………………………………………………………………...
[1 mark]
(iii) Write a chemical equation for the reaction.
…….……………………………………………………………………………..................
[2 marks]
3 Table 3 shows the proton number and the number of neutrons for atoms P, Q, R and S.
………………………………………………………………………………………….....
[1 mark]
(ii) What is the nucleon number of atom P?
…………….……………………………………………………………………………..............
[1 mark]
A
(b) Write the symbol for atom Q in the form Z
X
..………….………………………………………………………………………………………
[1 mark]
(c) Which atoms have the same number of valence electrons?
……………………………………………………………………………………………………
[1 mark]
……………………………………………………………………………..................................
[1 mark]
(ii) State a reason for your answer in (d) (i).
……………………………………………………………………………..................................
[1 mark]
(e) Diagram 3 shows a graph of temperature against time of substance X when it is heated until it
boils.
Temperature /oC
D E
777
B C
63
A
Time /s
t1 t2 t3 t4
Diagram 3
……….………………………………………………………………………………
[1 mark]
(ii) Complete the table below by stating the physical state of substance X at the section AB
and DE.
DE
[1 mark]
(iii) Explain why the temperature remains constant from t1 to t2.
………………………………………………………………………………………
…………………………………………………………………………………………
[2 marks]
Proton number 11 12 13 17 18
Table 4
…………………………………………………………………………………………………
[1 mark]
(b) Chlorine is in Group 17 in the Periodic Table of Elements. What is another name for group 17?
…………….……………………………………………………………………………………
[1 mark]
(c) Write the electron arrangement of aluminium atom.
………………………………………………………………………………………………………..
[1 mark]
(d) (i) Arrange the element in Table 4 according to descending order of atomic sizes
.
…………………………………………………………………………………….
[1 mark]
(ii) Explain your answer in (d) (i).
………………………………………………………………………………………
………………………………………………………………………………………
[2 marks]
(e) When sodium is burnt in chlorine gas, sodium chloride is formed.
…………………………………………………………………………………………
[1 mark]
(ii) Write the chemical equation for the reaction.
…………………………………………………………………………………………
[2 marks]
(iii) State one physical property of sodium chloride.
…………………………………………………………………………………………
[1 mark]
.....................................................................................................................................................
[1 mark]
(ii) Give a reason for your answer in (a) (i).
.....................................................................................................................................................
[1 mark]
(b) Element W exists as diatomic molecule.
State the type of chemical bond in molecule W.
...........................................................................................................................................................
[1 mark]
(c) Element V can react with element W to form a compound.
(i) Write the chemical formula for the compound formed.
..............................................................................................................................................
[1 mark]
(ii) Draw the electron arrangement for the compound formed.
[2 marks]
(iii) State one physical property for the compound formed.
.....................................................................................................................................................
[1 mark]
(d) Element U reacts with element W to form a compound .
.....................................................................................................................................................
[1 mark]
(ii) Explain briefly how the compound is formed.
.....................................................................................................................................................
.....................................................................................................................................................
.....................................................................................................................................................
[3 marks]
(iii) Draw the electron arrangement for the compound formed.
[2 marks]
Chemistry Perfect Score Module 2011 15
PAPER 2: SECTION B [ESSAY]
6 (a) Diagram 6.1 shows the electron arrangement for atom of an element from Group 17 in the
Periodic Table of Element.
Diagram 6.1
Based on Diagram 6.1,
(i) Write the electron arrangement for the atom and state the name of the element.
[2 marks]
(ii) Write a chemical equation for the reaction between the element and iron.
[2 marks]
(b) Table 7.2 shows the observation of the reaction between Group 1 elements X , Y and Z with
water.
(i) Arrange X, Y and Z in descending order of reactivity of Group I elements towards water.
Compare and explain the reactivity X and Z with water.
[6 marks]
(ii) Compare the chemical property of X, Y and Z. Give a reason for your answer.
[2 marks]
(c) Diagram 6.3 shows the electron arrangement of a molecule XY2.
Y X Y
Diagram 6.3
Based on Diagram 6.3, write the electron arrangement for atom element X and element Y.
Explain briefly how the molecule is formed from atom X and atom Y.
Explain the position of element Y in the Period Table of Element.
[8 marks]
Table 7.1
(a) State the position of element X in the Periodic Table of Elements.
Explain how you determine the group and the period of element X.
[4 marks]
(b) Atoms W and Y can form chemical bonds with atom X.
Explain how the bond is formed between :
[10 marks]
(c) Table 7.2 shows physical property of compound P and compound Q.
Table 7.2
State the type of bond in compound P and compound Q.
By choosing one physical property, explain why there is a difference between the property
of the compounds.
[6 marks]
PAPER 2 SECTION C: ESSAY
8 (a) Diagram 8 shows the apparatus set up to determine the empirical formula of oxide of metal M. M
is less reactive than hydrogen.
Thistle funnel
Oxide of metal M
Heat
Dilute acid Metal N
R
Diagram 8
(i) Name a suitable dilute acid and metal N that are used to prepare hydrogen gas.
[2 marks]
(iii) Suggest a suitable chemical substance for R and state the function of R.
[2 marks]
(iv) State the example of oxide of metal M. Describe the redoxs reaction that occurs in the combustion
tube based on the changes in oxidation number.
[6 marks]
Chemistry Perfect Score Module 2011 17
(b) The information below is about hydrocarbon Y
(ii) Describe an experiment to prepare hydrocarbon Y in the laboratory from its corresponding
alcohol.
In your answer, include the diagram of the appratus set-up, materials used, and
procedure.
[8 marks]
9 (a) (i) What is meant by empirical formula?
[1 mark]
(ii) Diagram 9.1 shows the apparatus set-up used to determine the empirical formula of oxide
of metal X.
Oxide of metal X
Heat
Diagram 9.1
(b) Diagram 9.2 shows the apparatus set-up used to determine the empirical formula of another oxide of metal.
Metal
Heat
Diagram 9.2
(h) Suggest one suitable oxide of the metal.
[1 mark]
(ii) Based one diagram 9.2, describe how you could determine the empirical formula of the named metal oxide
in the laboratory. Your description should include
- procedure of experiment
- tabulation of results
- calculation of the empirical formula
[10 marks]
(c) A carbon compound contains 84.6% of carbon and 15.4% of hydrogen by mass.
The relative molecular mass of this compound is 70. Calculate the molecular formula of this compound.
[Relative atomic mass: C, 12; H, 1]
[5 marks]
SET
1. Electrochemistry
2. Oxidation and Reduction
1 Diagram 1 shows the apparatus set- up for the combination of electrolytic cell and chemical cell.
Copper(II) sulphate
solution
Cell I Cell II
Diagram 1
(a) Which cell is the electrolytic cell?
……………………………………………………………………………………..……….………..
[1 mark]
(b) Based on Cell I
…………..…………………………………………………………………………………...
[1 mark]
(ii) Draw the flow of electron in Diagram 1.
[1 mark]
(iii) State the observation at copper electrode.
………………………………………………………………………………………………
[1 mark]
(c) Write half equation for the reaction at copper electrode.
…………..………………………………………………………………………………………...….
[2 marks]
(d) Based on the Cell II
(i) State the energy change in the cell.
………………………………………………………………………………….……………
[1 mark]
(ii) What can be observe at the copper(II) sulphate solution?
….……………………………………………………………………………………………
[1 mark]
(iii) Explain your answer in d(ii)
……………………………………………………………………..………….……………..
[2 marks]
Diagram 2.1
(i) Name the product formed at electrode R.
..……….…………...................................................................................................................
[1 mark]
(ii) Complete the half equation for the reaction at electrode S.
…………..............................................................................................................................
[1 mark]
(b) Diagram 2.2 shows the set up of the apparatus to investigate the reactivity of metals J, K and L.
The different metals are heated consecutively.
Diagram 2.2
Colour of residue
Metal Observations
Hot Cold
J Burns brightly Yellow White
K Glows dimly Black Black
Table 2.2
(i) State the name of metal J.
……….. ………......................................................................................................................
[1 mark]
(ii) Write a chemical equation for the reaction between metal J and oxygen.
……….……………................................................................................................................
[2 marks]
(iii) Based on the observation in Table 2.1, arrange metals J, K and L in ascending order of
reactivity towards oxygen.
……….. .…….........................................................................................................................
[1 mark]
(iv) A mixture of metal J and oxide of metal L is heated strongly.
Predict an observation. Give a reason.
. ………....................................................................................................................................
……….. ..................................................................................................................................
[2 marks]
3 (a) Table 3.1 shows the electrical conductivity of two different compounds
Table 3.1
Referring to Table 3.1, explain why there is a difference in the electrical conductivity.
[4 marks]
Copper(II) sulphate
solution
Cell X Cell Y
Diagram 3.1
Compare and contrast cell X and cell Y. Include in your answer the observations and half
equations for the reactions at the electrodes in both cells.
[8 marks]
(c) An experiment is carried out to determine the position of metals silver, L and M in the
electrochemical series. Diagram 3.2 shows the results of the experiment.
I II III
L M M
Diagram 3.2
Zn + Pb(NO3)2 → Zn(NO3)2 + Pb
(i) Write half equation for the oxidation and the reduction reactions.
[4 marks]
(ii) Identify substance that is oxidized and reduced. Explain your answer in term of transfer of
electrons.
[4 marks]
(b) Diagram 4 shows two redox reactions that take place in test tubes P and Q.
Chlorine water
(i) State the observations and write the ionic equation for the reaction in test tubes P and Q
respectively.
[6 marks]
(ii) State the name of the product formed in each test tube P and Q
[4 marks]
(iii) Describe a confirmation test to verify the product in test tube Q
[2 marks]
5 (a) Diagram 5 shows the apparatus set-up and observations for experiments 1 using 1.0 moldm-3
aqueous solution of compound XSO4 and experiment II using 0.0001 moldm-3 aqueous solution of
compound XY2.
Cathode:
Brown solid deposited
Anode:
A colorless gas is produced.
Cathode:
Brown solid deposited
II
Anode:
A colorless gas is produced.
The gas relight a glowing splinter.
Diagram 5
(i) In both experiment I and experiment II, the product formed at cathode is the same. Using
your knowledge of factors affecting the selective discharge of ions at the electrodes,
- suggest one possible cation for X2+ ion
- write the half equation for the reaction at the cathode
- state the name of the product at cathode
[4 marks]
(ii) Name the product formed at anode in experiment I. Describe a confirmatory test to identify the
gas produced.
[3 marks]
Diagram 6.1
(b) Diagram 6.2 shows a redox reaction between bromine water and iron(II) sulphate solution.
Diagram 6.2
(i) Describe the redox reaction that occur in the test tube. Your answer should include the ionic
equation and observations.
[8 marks]
(ii) Based on the oxidation reaction in (b) (i), describe a chemical test to identify the product formed
in the test tube.
[2 marks]
SET
1. Acids and Bases
2. Salts
3. Rate of reaction
4. Thermochemistry
A B C D
5 cm3 HCl 5 cm3 HCl 5 cm3 NaOH 5 cm3 NaOH
0.1 mol dm-3 0.01 mol dm-3 0.1 mol dm-3 0.01 moldm-3
Diagram 1
(a) Determine which solution has
(i) highest pH value?
…………….……………………………………………………………………………........
[1 mark]
(ii) lowest pH value?
……………………………………………………………………………………….............
[1 mark]
(b) If the hydrochloric acid in test tube B is replaced with 5 cm3 of 0 .1 mol dm-3 ethanoic acid,
predict the pH value of the solution. Explain your answer
…………………………………………………………………………………………………………...………..
…. ……………………………………………………………………………………………………
……………………………………………………………………………………………………….
[3 marks]
(c) Excess of magnesium powder is added to 5 cm3 of 0.1moldm-3 hydrochloric acid in test tube A
(i) Name the products formed.
.
……...………………………………………………………………………………………..
[1 mark]
(ii) Write an ionic equation for the reaction in test tube A
………………………………………………………………………………………………
[1 mark]
(iii) Calculate volume of hydrogen gas released at room conditions in test tube A
[1 mol of gas occupies 24 dm3 at room conditions]
[3 marks]
…….………………………………………………………………………………………………….
[1 mark]
2. (a) Diagram 2.1 shows the pH value of glacial ethanoic acid in solvent P and solvent Q respectively.
4.8 7.0
Diagram 2.1
Solvent P: ………………………………………………………….………...………………
Solvent Q: ………………………………………………………………………………….
[2 marks]
(ii) If magnesium ribbon is added into beaker containing glacial ethanoic acid and solvent P,
what can be observed?
……………………………………….………………………………………………………
[1 mark]
(iii) Explain why ethanoic acid in solvent P and solvent Q has different the pH value.
….……………………………………………………………………………………………
….……………………………………………………………………………………………
….……………………………………………………………………………………………
...……………………………………………………………………………………………..
[3 marks]
(b) Diagram 2.2 shows the concentration of hydrochloric acid decrease when water is added into
beaker J.
Add water
250 cm3 of 0.04 moldm-3
100 cm3 of 0.5 moldm-3
hydrochloric acid
hydrochloric acid
Beaker J Beaker L
Diagram 2.2
….……………………………………………………………………………………………
.………………………………………………………………………………………………
[2 marks]
(ii) Calculate the volume of hydrochloric acid in beaker J that is needed to prepare
hydrochloric acid in beaker L.
[2 marks]
3. A student carried out an experiment to investigate the properties of three solutions. Table 3 shows the results
of the experiments.
Test tube P Q R
Set-up of
Red litmus Red litmus Magnesium
apparatus
Paper Paper
Table 3
(a) What is meant by strong alkali?
.......................................................................................................................................
[1 mark]
(b) What is the property of the solution in test tube P?
.......................................................................................................................................
[1 mark]
(c) What are the types of particles that exist in the test tubes P and Q?
(d) Is there any changes of colour of the litmus paper in test tube Q? Explain why.
......................................................................................................................................
......................................................................................................................................
[ 2 marks]
.......................................................................................................................................
[1 mark]
(ii) Write a chemical equation for the reaction in test tube R.
.......................................................................................................................................
[2 mark]
(iii) 2.4 g of magnesium is reacted completely with the solution in test tube R.
Calculate the volume of the hydrogen gas produced at room condition
[Relative atomic mass: Mg,24; 1 mol of gas occupies 24 dm3 at room conditions]
[ 2 marks]
Copper(II) sulphate
Diagram 4
a) Copper(II) nitrate solution reacts with sodium carbonate solution to form copper(II) carbonate precipitate.
(i) What is the colour of Copper(II) carbonate?
……………………………………………………………………………………………….............
[1 mark]
(ii) Name the reaction.
.............................................................................................................................................................
[1 mark]
b) Heating of copper(II) carbonate produces copper(II) oxide and gas R.
i) Name gas R.
………………………………………………………………………………………………..
[1 mark]
ii) Write the chemical equation of the reaction.
......................................................………………………………………………………......................
[2 marks]
[2 marks]
c) Copper(II) carbonate reacts with hydrochloric acid to produce copper(II) chloride. The chemical
equation is shown below.
CuCO3 + 2HCl → CuCl2 + CO2 + H2O
12.4 g copper(II) carbonate reacts completely with excess hydrochloric acid.
Calculate the mass of copper(II) chloride.
[Relative atomic mass: Cu = 64, C = 12, O=16 , Cl = 35.5, H=1)
[2 marks]
5. Three experiments were conducted to investigate the factors affecting the rate of reaction. The results are
shown in the Table 5
Experiment Reactants Temperature / 0C Time taken for all the
magnesium to dissolve/s
0.4g magnesium ribbon and 50 cm3
I 1 moldm-3 hydrochloric acid 30 100
………..………………………………………………………………………………………………
[2 marks]
(b) Calculate the number of mole of
[Relative atomic mass of Mg = 24]
(i) Magnesium
[1 mark]
(ii) Hydrochloric acid
[1 mark]
(c) If hydrochloric acid used is excess, calculate the maximum volume of hydrogen gas produce at
room temperature and pressure.
[1 mole of gas occupies the volume of 24 dm3 at room temperature and pressure]
[2 marks]
Chemistry Perfect Score Module 2011 32
(d) Calculate the average rate of reaction for Experiment I and II.
[2 marks]
(e) What is the purpose of using copper(II) sulphate?
……………….………………………………………………………………………………………
[1 mark]
(f) The factor that affects the rate of reaction in this experiment is total surface area and the use of
catalyst. State two other factors that affect the rate reaction in this experiment.
………………………………………………………………………………………………………
……..………………………………………………………………………………………………..
[2 marks]
6. An experiment is carried out to determine the heat of displacement for the reaction between copper(II)
sulphate solution and excess zinc powder. 50.0 cm3 of 0.5 mol dm 3 copper(II) sulphate solution is poured into
a plastic cup. The initial temperature of the solution is recorded after 5 minutes. 5 g of excess zinc powder is
added into a plastic cup. The mixture is stirred and the highest temperature is recorded.
The following data is obtained:
[Relative atomic mass : Cu,64; S,32; O,16; Zn, 65; Specific heat capacity of water : 4.2 Jg1 0C1]
………………….……………………………...…………………………………………………….
[1 mark]
(b) Write an ionic equation for the reaction.
………………………………………………………………………………………………………..
[1 mark]
(c) State two observations in the experiment.
(i) …………………………………………………………………………………………….…...…
(ii) ………………………………………………………………………………………………......
[2 marks]
(d) Calculate,
(i) the heat released
[1 mark]
(ii) the number of moles of copper (II) sulphate reacted
[1 mark]
[2 marks]
(e) Why excess zinc powder is used in this experiment?
……...………………………………………………………..……………………………………….
[1 mark]
(f) Draw the energy level diagram for the reaction.
[2 mark]
7. 50 cm3 1.0 mol dm-3 sodium hydroxide solution is poured into a polystyrene cup. The polystyrene cup is
then placed into a beaker as shown in Diagram 5
Diagram 5
The initial temperature of sodium hydroxide solution in the polystyrene cup is measured. 10 cm3 of
hydrochloric acid is added to the 50 cm3 sodium hydroxide and the temperature increase is recorded. Then,
the heat energy released is calculated. The experiment is repeated by adding different volumes of
hydrochloric to the 50 cm3 of sodium hydroxide. The results are tabulated as shown below.
(a) Plot a graph heat energy released against volume of hydrochloric acid added.
[3 marks]
(b) (i) Based on the graph, determine the volume of hydrochloric required for complete
neutralisation with 50 cm3 1.0 mol dm-3 sodium hydroxide
[1 mark]
(ii) From your answer in (b) (i), calculate the concentration of hydrochloric acid used
in moldm-3.
[2 marks]
Chemistry Perfect Score Module 2011 34
Chemistry Perfect Score Module 2011 35
(c) Why the content in the polystyrene cup has to be stirred continuously throughout the
experiment?
………………………………………………………………………………………………………..
[1 mark]
(d) Explain briefly why the heat released becomes constant after 50 cm3 of hydrochloric acid is
added.
………………………………………………………………………………………………………
……………………………………………………………………………………………...............
[1 mark]
(e) (i) Calculate the heat energy released when 1 mole of sodium hydroxide is neutralized
by hydrochloric acid.
[1 mark]
(ii) Draw the energy level diagram for the reaction that occurred in the polystyrene cup.
[2 marks]
(f) In another experiment, 50 cm3 1.0 mol dm-3 sodium hydroxide solution is added with 50 cm3 1.0
mol dm-3 ethanoic acid.
……………………………………………………………………………………………….
[1 mark]
(ii) Give a reason for your answer in (f) (i).
………………………………………………………………………………………………
………………………………………………………………………………………………
………………………………………………………………………………………………
[2 marks]
8. A student has carried out an experiment to construct an ionic equation for the formation of lead(II) iodide.
Seven test tubes of the same size were labelled 1 to 7. A fixed volume of 5.0 cm3 of 1.0 mol dm-3
potassium iodide solution was placed in each test tube. 0.5 cm3 of 1.0 moldm-3 lead(II) nitrate solution was
added into test tube 1, 1.0 cm3 into test tube 2 and so on until 3.5 cm3 was added into test tube 7. The
heights of the precipitate formed in each test tube were measured.
Test tube
1 2 3 4 5 6 7
Volume of 1.0 moldm-3 lead(II)
nitrate solution/ cm3 0.5 1.0 1.5 2.0 2.5 3.0 3.5
(ii) Determine the volume of lead(II)nitrate solution that had reacted completely with 5.0 cm3 of
1.0 moldm-3 potassium iodide.
[1 mark]
(iii) Using the volume obtained in (a) (ii), calculate the number of moles of lead(II) ions and iodide
ions that are required for the formation of lead(II) iodide.
Then, calculate the number of moles of iodide ions that has reacted with 1 mol of lead(II) ions.
[4 marks]
(iv) Write the ionic equation for the formation of lead(II) iodide.
[2 marks]
(b) By referring to test tube 1, 5 and 7 in Table 8, state the ions that exist in the solution. Explain your
answer.
[10 marks]
(i) What are the conditions required for the production of ammonia in Haber Process? [3 marks]
(b) A student carried out two experiments to investigate the effect of concentration on the rate of reaction.
Diagram 9.1 shows the set-up of apparatus of the experiments.
II
0.2 g calcium carbonate powder Water
Air
Diagram 9.1
(i) Plot the graph of the volume of carbon dioxide gas against time for Experiment I and II on the
same axes on the graph paper provided .
[4 marks]
(ii) Calculate the average rate of reaction for Experiment I and II.
[4 marks]
(iii) Compare the rate of reaction between Experiment I and Experiment II.
Explain the differences in the rate of reaction with reference to the collision theory.
[5 marks]
10. Table 10 shows the data from Experiment I and Experiment II that were carried out to study the rate of
reaction of magnesium ribbon with two acids, X and Y .
Table 10
(ii) Calculate the number of mol of acid X or acid Y that react with excess magnesium ribbon.
[1 mark]
(iii) Based on this experiment what is meant by the rate of reaction?
[1 mark]
(b) (i) At the same axis, sketch the graph of volume of gas against time for experiment I and
experiment II.
[ 2 marks]
(ii) Compare the rate of reaction in experiment I and II . Explain your answer based on collision
theory.
[5marks]
(c) Describe one laboratory experiment to conduct the Experiment I or Experiment II to determine the
rate of reaction. Your answer should include the following :
- A labeled diagram showing the apparatus set-up
- Procedures of the experiment
- A table to collect the data
[8 marks]
11. a) A student with a wet T-shirt entered an air-conditioned room. After half an hour, the student was
shivering with coldness. Explain this pheomena with reference to changes in physical state and
energy change involved.
[2 marks]
b) Table below shows the molecular formula and heat of combustion for ethanol and propanol.
ΔH= + x kJ / mol
A + B
State four information that can be obtained from the above diagram.
[4 marks]
(c) Reaction I and II below are the thermochemical equation for the heat of precipitation.
Reaction I : AgNO3 + NaCl → AgCl + NaNO3 H = - 210 kJmol-1
Reaction II : AgNO3 + KCl → AgCl + KNO3 H = - 210 kJmol-1
Explain why the value of heat of precipitation in reactions I and II are the same.
[4 marks]
Describe a laboratory experiment to determine the heat of reaction for the above reaction. In your
answer, include the following :
chemicals required
procedures of the experiment
results and calculation involved
[8 marks]
Diagram 13.1
a) (i) Based on the Diagram 13.1 , classify the above salts to soluble salt and insoluble salts.
[2 marks]
(ii) State the reactant used for the preparation of magnesium carbonate from magnesium nitrate in
reaction I and II
[2 marks]
(iv) Describe the preparation magnesium carbonate from magnesium nitrate in the laboratory through
reaction I
[6 marks]
b) Diagram 13.2 shows conversion of salt X when it heated strongly and dissolved in water. The solution
formed is tested with sodium hydroxide solution, NaOH.
Diagram 13.2
(i) Identify an anion that is present in salt X. Describe a chemical test to verify the anion.
[4 marks]
(ii) Identify three cations that are possible present in salt X solution.
Describe chemical test to verify the cations.
[6 marks]
SET
1. Carbon Compounds
2. Manufactured Substances in Industry
3. Chemicals for Consumers
Diagram 1
………………........……………………………………......................................................................
[2 marks]
(b) State the homologous series for compound X.
…………………………………………………………......................................................................
[1 mark]
(c) Name the compound X.
………………………………………………………….......................................................................
[1 mark]
(d) At 180oC and in the presence of nickel as catalyst, compound X can be changed into saturated
hydrocarbon compound.
(i) Name the reaction.
………………………………………………………………………..............................................
[1 mark]
(ii) Draw the structural formula for the compound formed.
[1 mark]
(e) Compound X burns completely in excess oxygen.
(i) Write a balanced chemical equation for the complete combustion of X.
.......................................................................................................................................................
[2 marks]
(ii) 2.1 g of compound X undergoes complete combustion at room conditions.
Calculate the volume of carbon dioxide gas released.
[1 mol of gas occupies 24 dm3 at room conditions; Relative atomic mass: H = 1; C = 12]
[2 marks]
Compound P Reaction I
C2H6O
Compound Q
Reaction II
Compound R
Diagram 2
(a) Name the compound P.
......………………………………………………………………………............................................
[1 mark]
(b) State the functional group of compound P.
…………………………………………………………........................................................................
[1 mark]
(c) In the reaction I, compound Q is produced when an acidified potassium dichromate (VI) solution is
added into a test tube containing compound P.
(i) Name the reaction I.
......………………………………………………………………………....................................
[1 mark]
(ii) State one observation for this reaction.
...........................………………………………………………………………………..............
[1 mark]
(iii) Draw the structural formula of compound Q.
[1 mark]
(d) In the reaction II, compound R is formed when compound P reacts with compound Q in the
presence of concentrated sulphuric acid.
(i) Name the reaction II.
......………………………......................………………………………………………..............
[1 mark]
(ii) Name the compound R.
........………………………………………………………………………..................................
[1 mark]
(iii) Give one special physical property of compound R.
.......………………………………………………………………………..................................
[1 mark]
(iv) Write the chemical equation for the reaction II.
..………………………………………………………………………........................................
[2 marks]
Chemistry Perfect Score Module 2011 45
3. (a) Diagram 3.1 shows the manufactured of ammonia and sulphuric acid.
Process I Ammonia
Ammonium sulphate
Process II Sulphuric acid
Diagram 3.1
…………………….………………………………………………………………………………
[1 mark]
(ii) Write the chemical equation for the reaction to produce ammonia in Process I.
..…………………………..………………………….……………………………………………
[2 marks]
(iii) In Process II, sulphur dioxide is reacted with oxygen to produce sulphur dioxide.
State the temperature and the catalyst used in this reaction.
…………………………………………………………………….………………………………
…………………………………………………………………………………………………….
[2 marks]
(iv) State one use of ammonium sulphate.
…………….………………………………………………………………………………………
[1 mark]
(b) Diagram 3.2 shows a structural formula of a polymer.
Diagram 3.2
……………………………………………………………………………………………………
[1 mark]
(ii) Draw the structural formula for the monomer in Diagram 3.2
[1 mark]
(c) Bronze is an alloy of copper. Draw a labeled diagram to show the arrangement of atoms in bronze.
[2 marks]
Chemistry Perfect Score Module 2011 46
4. The following equation shows how soap can be prepared.
……………………………………………………………………………………………………………
[1 mark]
(ii) State the name of the process in the above reaction.
……………………………………………………………………………………………………………
[1 mark]
(iii) Explain why potassium chloride is added during the preparation of soap.
……………………………………………………………………………………………………………
[1 mark]
(b) Two cleaning agents, X and Y, are used to wash clothes in river water and sea water. The results obtained
are shown in Table 4 below.
Cleaning agent River water Sea water
X Does not form scum Does not form scum
Y Does not form scum Forms scum
Table 4
X: ………………………………………………………………………………………………………..
Y: …………………………………………………………………………………………………………
[2 marks]
……………………………………………………………………………………………………………
[1 mark]
(iii) State the two ions present in sea water that cause the formation of scum in Y.
……………………………………………………………………………………………………………
[2 marks]
(iv) Give one disadvantage of using the cleaning agent X.
……………………………………………………………………………………………………………
[1 mark]
5. (a) A hydrocarbon M, consists of 85.7% of carbon and X% of hydrogen by mass. The relative
molecular mass of M is 56.
[Relative atomic mass: C = 12; H = 1]
6. (a) Food preservatives are substances added to food so that the food can be kept for longer periods
for time. Using two suitable examples, explain how they work as preservative.
[4 marks]
(b) The following is the information about a child.
2 years old
High fever
Whooping cough
Based on Table 6, categorise the food additives. Include in your answer the function of each
type of food additives and the disadvantages of using any two food additives.
[10 marks]
7. Diagram 7 shows the flow chart for the industrial manufacture of sulphuric acid and the production of
three types of fertilizer.
Step 1 Step II
Sulphur Sulphur dioxide Substance X
Step III
+ Ammonia
Fertiliser Y
Diagram 7
(a) (i) Based on step I to step IV , describe briefly the industrial production of sulphuric acid.
[4 marks]
(ii) Write a chemical equation for the reaction between sulphuric acid and ammonia to
produce fertilizer Y.
[2 marks]
(b) Table 7 shows the diameter of the dent formed in an experiment to compare the hardness of
copper and bronze. Based on Table 7, compare the hardness between copper and bronze, explain
why ?
(c) The iron window frame of Encik Azman’s house rusts after several years but the steel window
frame of Encik Tarmizi’s house does not rust.
By using suitable examples, describe a laboratory experiment to compare the resistant to rust of
alloy compared to pure metal.
Include the following in your answer:
Procedure
Results
Conclusion
[10 marks]
8. (a) Table 8 shows the result of two sets of experiment to investigate the coagulation of latex.
Diagram 8
(iii) By using a compound Q with number of carbon atom per molecule more than one,
describe an experiment to convert compound Q to alkene.
Your answer should consist of the following:
Procedure of the experiment
A labelled diagram showing the apparatus set-up
The test to confirm the product is alkene
[9 marks]
SET
1. PAPER 3 SET 1
2. PAPER 3 SET 2
3. PAPER 3 SET 3
Thread
Weight
Meter ruler
Material X
Diagram 1.1
A steel ball bearing is taped onto the material X block using cellophane tape. A weight of 1 kilogram is
dropped at a height of 50 cm to hit the ball bearing. The diameter of the dent made on the material X
block is measured. The experiment is repeated by replacing material X block with material Y block.
Table 1.1 shows the view of the dents made on the material X and Y.
Experiment Material X Material Y
I
II
III
[3 marks]
(b) State one observation that can be obtained from this experiment.
......................................................................................................................................................................
……………………………………………………………………………………………………………..
[3 marks]
(c) Based on the average diameter of the dents on material X and Y, state the inference that can be make.
......................................................................................................................................................................
……………………………………………………………………………………………………………..
[3 marks]
(d) State the operational definition for the hardness of alloy.
......................................................................................................................................................................
……………………………………………………………………………………………………………..
[3 marks]
(e) Explain why there is difference in diameter of dents on material X and Y.
......................................................................................................................................................................
……………………………………………………………………………………………………………..
[3 marks]
(f) Suggest a suitable material for X and Y.
......................................................................................................................................................................
[3 marks]
(g) State the hypothesis for this experiment.
......................................................................................................................................................................
……………………………………………………………………………………………………………..
[3 marks]
(h) Complete table 1.2 based on the experiment.
(iii) Controlled variable: (iii) The way to maintain the control variable:
Test tube A
Iron nail coiled with metal X High intensity
of blue colour.
Test tube B
Iron nail coiled with metal Y High intensity of
pink colour
Test tube C
Iron nail coiled with metal Z Low intensity of
pink colour
Test tube D
Iron nail Low intensity of
blue colour
Diagram 2
(a) State the inference for the observation in test tube A, B, C and D.
[3 marks]
(b) Based on this experiment, explain why there is a difference in the observation between test tube A
and B.
…………………………………………………………………………………………………………
…………………………………………………………………………………………………………
[3 marks]
Chemistry Perfect Score Module 2011 54
(c) State the hypothesis for the experiment.
…………………………………………………………………………………………………………
…………………………………………………………………………………………………………
[3 marks]
(d) Based on this experiment state:
…………………………………………………………………………………………………………
…………………………………………………………………………………………………………
[3 marks]
(f) Based on this experiment classify the metals that can provide sacrificial protection and metal cannot
provide sacrificial protection to iron.
[ 3 marks]
(g) Observation in test tube D is recorded after two days. Compare the observation for the experiment
after it left for one day and two days. Explain your answer.
.
…………………………………………………………………………………………………………
…………………………………………………………………………………………………………
[3 marks]
3. Different type of alcohols produces different heat of combustions. When the number of carbon per
molecule of alcohol increases the heat of combustion increases. Table 3.1 shows the heat of combustion
of ethanol, propanol and butanol.
Alcohol Molecular formula Heat of combustion/ kJ mol-1
Ethanol C2H5OH -1376
Propanol C3H7OH -2016
Butanol C4H9OH -2678
Table 3.1
Plan a laboratory experiment to compare the heat of combustion of the alcohols. Your planning must
include the following aspects:
(a) Statement of the problem
(b) All the variables
(c) Hypothesis
(d) List of materials and apparatus
(e) Procedure
(f) Tabulation of data
[17 marks]
PAPER 3 SET 2
1. A student carried out an experiment to determine the end-point for the titration of 25.0 cm3 of 1.0 mol
dm-3 sodium hydroxide solution with hydrochloric acid. Phenolphthalein is used as the acid-base
indicator. Table 1 shows the three titrations that were conducted and the magnification of the burette
readings.
Titration I II III
No.
13
2 27
13 38
27
Table 1
Chemistry Perfect Score Module 2011 56
(a) Record the burette readings for the three titrations in the spaces provided in Table 1.
[3 marks]
(b) Construct a table and record the initial burette reading, final burette reading and the volume of
acid used for each titration.
[3 marks]
(c) Calculate the molarity of the hydrochloric acid used in the experiment.
[ 3 marks]
(d) State the operational definition for the neutralization of sodium hydroxide solution in this experiment.
……………………………………………………………………………………………………………
…………………………………………………………………………………………………………..
…………………………………………………………………………………………………………….
[3 marks]
(e) The experiment is repeated by replacing hydrochloric acid 1.0 mol dm-3 with sulphuric acid 1.0 mol
dm-3.
(i) Predict the volume of sulphuric acid needed to neutralise the sodium hydroxide solution.
…..……..............................................................................................................................................
…….................................................................................................................................................
…….................................................................................................................................................
[3 marks]
(f) Table 1 shows the results of an experiment to investigate the pH values of acids.
Solution pH value
Hydrochloric acid, 1.0 mol dm-3 2.0
Ethanoic acid, 1.0 mol dm-3 5.0
Table 1
For this experiment, state
(i) The manipulated variable
.........................................................................................................................................................
(ii) The responding variable
…….................................................................................................................................................
(iii) The fixed variable
…….................................................................................................................................................
[3 marks]
……………………………………………………………………………………………………………
…………………………………………………………………………………………………………..
…………………………………………………………………………………………………………….
[3 marks]
(h) Classify the following substances into substances with pH value less than 7 and pH value more than 7.
[3 marks]
2. Diagram 2.1 shows the apparatus set up for the preparation of ester in the laboratory.
water in
water out
Mixture of alchohol +
carboxylic acid and a few
drops of concentrated
sulphuric acid
heat
Table 2.1 show some examples of the types of alcohol and carboxylic acid used to prepare ester.
Alcohol Carboxylic Acid Observation
Methanol Ethanoic acid Sweet pleasant smell
Ethanol Propanoic acid Sweet pleasant smell
Propanol Methanoic acid Sweet pleasant smell
Table 2.1
[3 marks]
(c) Propyl butanoate is an ester that is formed from the reaction between an alcohol and carboxylic
acid.
Name the alcohol and carboxylic acid needed to prepare the ester.
Alcohol: .....................................................................................................................................
(d) Table 2.2 shows the observation for an experiment to differentiate between alkanes and alkenes.
Experiment Hexane Hexene
Added with bromine water No change Brown bromine decolourised
Added with acidified potassium No change Purple solution decolourised
manganate (VII) solution
Table 2.2
Manipulated variable.:.....................................................................................................
Responding variable..:....................................................................................................
….……………………………………………………………………………………………
…...……………………………………………………………………………………………
……………………………………………………………………………………………….
[3 marks]
Based on the above diagram, plan one laboratory experiment to compare the effectiveness of cleaning
agents A mad B on cleansing action in hard water.
Your planning should include the following aspects:
(a) Aim
(b) All the variables
(c) Statement of the hypothesis
(d) List of substances and apparatus
(e) Procedure of the experiment
(f) Tabulation of data
[17 marks]
Wind shield
Thermometer
Copper tin
Water
Methanol
Initial temperature:.........................
Wind shield
Thermometer
Copper tin
Water
Methanol
Highest temperature:...................
Diagram 1.1
.......................................................................................................................................................[
3 marks]
(ii) Give one inference based on the observation in (a)(ii).
.......................................................................................................................................................
[3 marks]
Methanol
ON ON
OFF
354.9548 g OFF
353.4012 g
Ethanol
OFF
ON ON
342.0201 g OFF
339.7892 g
Propanol
ON ON
OFF
364.4303 g OFF
360.8702 g
Butanol
ON ON
OFF
332.9891 g OFF
328.9790 g
Diagram 1.2
Based on Diagram 1.2,
(i) state the mass of the alcohols used in space provided into two decimal places.
[ 3 marks]
(ii) Tabulate the initial mass, final mass and mass of alcohol used for the four alcohols in this
experiment.
[3 marks]
Chemistry Perfect Score Module 2011 62
(c) Calculate the heat of combustion of methanol.
[Specific heat capacity of water = 4.2 J g-1 oC-1]
[3 marks]
(d) Table 1.1 shows the heat of combustion of ethanol (C2H5OH), propanol (C3H7OH) and butanol
(C4H9OH).
Alcohol Molecular Formulae Heat of combustion/kJ mol-1
Ethanol C2H5OH 970
Propanol C3H7OH 1400
Butanol C4H9OH 1860
Table 1.1
For this experiment, state:
(i) The manipulated variable.................................................................................
..............................................................................................................................................................
..............................................................................................................................................................
.............................................................................................................................................................
[3 marks]
(e) If the experiment is repeated using pentanol, predict the heat of combustion of pentane.
............................................................................................................................................................
[3 marks].
(f) State the operational definition for the heat of combustion of methanol.
............................................................................................................................................................
............................................................................................................................................................
...........................................................................................................................................................
[3 marks]
(g) The actual heat of combustion for ethanol is 1376 kJ mol-1.
State three reasons why the experimental value heat of combustion for ethanol is less than the
actual value.
1. ................................................................................................................................................
2. ................................................................................................................................................
3. ................................................................................................................................................
[3 marks]
Chemistry Perfect Score Module 2011 63
(h) Table 1.2 shows the list of carbon compounds and their molecular formula.
Carbon compound Molecular formula
Hexene C6H12
Propanoic acid C2H5COOH
Ethanol C2H5OH
Methane CH4
Classify the above carbon compounds into hydrocarbon and non hydrocarbon.
[3 marks]
2. Diagram 2.1 and 2.2 show Experiment I and Experiment II to investigate the effect of type of
electrodes on the products formed at the electrodes.
Experiment I
After 30 minutes
Carbon Carbon
electrodes electrodes
Diagram 2.1
Experiment II
After 30 minutes
Copper electrodes
Diagram 2.2
Based on Diagram 2.1 and Diagram 2.2 above, plan a laboratory experiment to investigate the effect
of the type of electrode to the product at anode.
Your answer should consist of the following:
(a) Aim of experiment
(b) All the variables
(c) Hypothesis
(d) List of materials and apparatus
(e) Procedure
(f) Tabulation of data
[17 marks]
END OF QUESTION PAPER
Chemistry Perfect Score Module 2011 64