CEMEDINE Y-358A SDS The first edition: 20/05/2008

Publication: 21/08/2015

Safety Data Sheet

1. Chemical Product & Company Identification

Product name:.................................CEMEDINE Y-358A
Name of manufacturer:..................TAIWAN CEMEDINE CO., LTD.
Division:...........................................Quality Assurance Dept.
Address:...........................................No.76-3, Xiaguirou Shan, Danshui Dist.,
New Taipei City 251, Taiwan
Phone: .............................................886-2-2621-2600
FAX: ................................................886-2-2623-1645
Emergency phone No. : .................886-2-2621-2600

2. Hazards Identification
GHS classification and label elements of the product
GHS classification
PHYSICAL HAZARDS
Flammable liquids：Category 2
HEALTH HAZARDS
Skin corrosion／irritation : Category 3
Eye damage／eye irritation：Category 2A
Skin corrosion／irritation : Category 1
GHS label element
Pictogram

Signal word：Danger
HAZARD STATEMENT
Highly flammable liquid and vapor
Causes skin irritation.
Causes serious eye irritation
May be harmful if swallowed and enters airways

PRECATIONARY STATEMENT
Keep away from heat／sparks／open flames／hot surfaces.- No smoking.
Keep container tightly closed.
Use only outdoors or in a well-ventilated area.
Do not eat, drink or smoke when using this product.
Wear protective gloves／eye protection／face protection.
Use personal protective equipment as required.

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CEMEDINE Y-358A SDS The first edition: 20/05/2008
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Contaminated work clothing should not be allowed out of the workplace.

Do not handle until all safety precautions have been read and understood.
Do not breathe dust/fume/gas/mist/vapors/spray.
Wash contaminated parts thoroughly after handling.

3. Composition/Information on Ingredients
Substance／Preparation：Preparation
Chemical identity：Modified acrylic resin type, adhesive
Y-358A：
Ingredient name Concentration ( % ) CAS No.
Methyl Methacrylate 40 ~ 50 80-62-6
Other Acrylic monomer 25 ~ 30 CBI/ not registered
Synthetic Rubber 10 ~ 15 CBI/ not registered
Polyester Resin 10 ~ 15 CBI/ not registered
Epoxy Resin 1~5 CBI/ not registered
Cumyl hydroperoxide 1 ~ 10 80-15-9

4. First-Aid Measures
General procedures
Call a POISON CENTRE or doctor/physician if you feel unwell.
IF exposed: Call a POISON CENTER or doctor/physician.
Inhalation
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable
for breathing.
Skin contact
If skin irritation occurs: Get medical advice/attention.
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin
with water/shower. After contact with skin, seek medical advice immediately.
Take off contaminated clothing.
Eye contact
If eye irritation persists: Get medical advice/attention.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing.
Ingestion
Rinse mouth.
IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
Indication of immediate medical attention and special treatment needed, if necessar y
Immediate measures are required.

5. Fire-Fighting Measures
Suitable extinguishing media
In case of fire, use appropriate media for extinction.
Fire/CAUTION: All these products have a very low flash point. Use of water spray
when fighting fire may be inefficient.

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Fire/CAUTION : For mixtures containing a high percentage of an alcohol or polar

solvent, alcohol-resistant foam may be more effective.
Small Fires : Dry chemical, CO2, water spray or regular foam.
Specific hazards arising from the chemical
Fire may produce irritating, corrosive and/or toxic gases.
Runoff from fire control or dilution water may cause pollution.

6. Accidental Release Measures

Personnel precautions, protective equipment and emergency procedures
Do not touch or walk through spilled material.
Methods and materials for containment and cleaning up
Stop leak if you can do it without risk.
A vapor suppressing foam may be used to reduce vapors.
Absorb or cover with dry earth, sand or other non-combustible material and transfer
to containers.
Use clean non-sparking tools to collect absorbed material.
Preventive measures for secondary accident
Collect spillage.
PUBLIC SAFTY : Keep unauthorized personnel away.
PUBLIC SAFTY : Stay upwind.
PUBLIC SAFTY : Keep out of low areas.
PUBLIC SAFTY : Ventilate closed spaces before entering.
ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate
area).
All equipment used when handling the product must be grounded.
Prevent entry into waterways, sewers, basements or confined areas.

7. Handling and Storage

Precautions for safe handling
Preventive measures
(Exposure Control for handling personnel)
Do not breathe dust/fume/gas/mist/vapors/spray.
(Protective measures against fire & explosion)
Keep away from ignition sources. - No smoking.
Ground/bond container and receiving equipment
Use explosion-proof electrical/ventilating/lighting/.../equipment.
Use only non-sparking tools.
Take precautionary measures against static discharge.
Safety Measures/Incompatibility
Use only outdoors or in a well-ventilated area.
Wear protective gloves/eye protection/face protection.
Conditions for safe storage, including any incompatibilities
Recommendation for storage
Keep container tightly closed.

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Store locked up.

Store in well-ventilated place. Keep container tightly closed.
Store in a well-ventilated place. Keep cool.

8. Exposure Control/Personal Protection

Construction control : Close room should has ventilation system.
Control factors : TWA TLV
Methyl Methacrylate 100 ppm 100 ppm
Personal protection equipment
Respirators protection not required in a ventilation area.
Hands protection rubber or plastic gloves ( depends ).
Eyes protection chemical safety goggles ( depends ).
Skin and body protection
Hygiene practices : Obey the operation rule and prevent unnecessary contact , be careful
during handing , and wash hands after handling.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical properties
Appearance：viscous liquid
Odor：slight acrylic odor
Color：A/Blue
PH(Value)：Not applicable.
Boiling point：100.5℃ (Methyl Methacrylate)
Specific gravity ( water=1 )：A 1.02
Solubility in water ( % by wt. )：not miscible or difficult to mix
Vapor pressure ( at 30℃ )：A 29mmHg
Vapor density ( air =1 )：A ＞1.0
Flashing point：10℃ (Seta flash tester)
Flashing limit：LEL 1.7% UEL 8.2%.

10. Stability and Reactivity

Chemical stability
This product is considered a stable material under normal condition.

11. Toxicological Information

Symptoms related to the physical, chemical and toxicological characteristics
Acute toxicity
Oral toxicity data
(Methyl methacrylate) : LD50 mouse 7872 mg/kg
(Cumyl hydroperoxide) : LD50 mouse 382 mg/kg
Inhalation toxicity data
(Methyl methacrylate) : LC50 mouse 78000 ppm / 4H
(Cumyl hydroperoxide) : LD50 mouse 200 ppm / 4H

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12. Ecological Information

Ecotoxicity
Acuatic toxicity
Acuatic toxicity(component(s) data)
(Methyl methacrylate) : LC50 0.089 mg / L / 96H

13. Disposal Considerations

Description of waste residues and information on their safe handling and methods of
disposal
Avoid release to the environment (- if this is not the intended use).
Dispose of contents/container in accordance with local/national regulation
Industrial disposals control law, Taiwan
Specifically controlled Industrial waste except hardly flammables

14. Transport Information

IATA
UN No, UN CLASS
UN No：1133
UN CLASS：3
PG：II
Proper shipping name：ADHESIVES containing flammable liquid
ERG GUIDE NO：128
Pollutant
Noxious Liquid； Cat. Y：Methyl methacrylate
Special precautions in connection with transport or conveyance

15. Regulatory Information

Road and traffic safety regulation.
Ensure this material in compliance with federal requirements and ensure conformity to
local regulations, TAIWAN fire service law class NO. 2
Regulations of Hazard Communication on Dangerous and Harmful Materials
LABOR SAFETY AND HEALTH LAW

16. OTHER INFORMATION

Reference web site
http://www.eric.org.tw/Chm_/Chm_index.aspx?viewPage=GHS_ALL&year=95
http://www.eric.org.tw/Chm_/Chm_index.aspx?viewPage=MSDS_ALL&type=M
SDS&year=95
http://ghs.cla.gov.tw/tw/search.asp
http://ghs.cla.gov.tw/tw/Mark_SDS_List.asp?PageMode=GHS_SDS
http://www.eric.org.tw/Chm_/Chm_index.aspx?viewPage=MSDS_ALL&type=M
anual&year=95
http://flora2.epa.gov.tw/toxicweb/ToxicUC4/database1.asp

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Other information
The data given here is based on current knowledge and experience. The purpose of
this Safety Data Sheet is to describe the products in terms of their safety requirements.
The data does not signify any warranty with regard to the products' properties.

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