Todays Goal _— 11. ee rumen cuiaet Substitution (or tenga? pas ) Re Senin lor nation, fhv (ex) Ch lin N-Bx 0m (¥) fad Sect Ra C8) (S-0-e) CMe Y, | Sod (By) toubter 3 (ey Ise}; oO OPH BE oy anager f Or a od - cl ot ys Benegtic hotoker haga Vial: = aMOP of Alkynes 1. Hydrolysis of Carbides 9) Calcivm carbide Coy A eyo. COG OS CHEqY + Ca(oH), = Bi Od? (Ht on cS CE ») mee Wee CECH + A mg(orr), mgt 4(H'o C-cee Al, % xtatagye ty + Y Allow), Bec 4airty ad sath ® Aric nop” 2) Nanu, % 7 3} a) Ale kolY \CLOH, AS 7S Nant,” None, ; AZ eo ae f A, Alekol CYS Alcea) Ae Sy3. Lower to higher Alkynes ace eH Navi * Ae te In the reaction, H~C > LNAI ig Ni Xand Y are TH OraorBr (NET 2016, P-) _ CHa Oe 7 (A) X= 2-butyne; ¥ =3-hexyne (B) X=2-butyne; voor afcoy 8 e (c X=1-butyne; voor oO” ‘1-butyne; ¥=3-hexyne 4. from haloform CHXs, AS Sone aRr oage x x Hox 6Aq x K a 4 At Properties of Alkynes 1. Acidic Nature2. Addition Reactions a. Hydrogenation Already done Hyd b. Halogenation (HX) (Already dove) mech ee > Q aaa (No “Fe arrangement) c. Kucherov Reaction ( Hydvatiey, ) LOM goa HO yg _ eal R +.) (4 time) 17 fe eagud= dil sey oe on Les dit Hse, ve Y 1 Wy RR $4, 0rar at +> Re co, as he Saye vo ne ‘ela halegeration (xt ech) Sen dove ea eee = a 4 x . Test for unsaturation or or KK —c=c— @8% 5 —c—¢- edly oak oe Byt wee [orr7erJ EN %,+Ho > Hox %* Q a Wy I oo ee x® iF tho > Hox! HER Bae a +Ve 4852) Rca “it cH e. Hydroxylation ( Atveady dove ) dil A KNndy QD @ =a ze @RY, ams | H Py by of. dikclay ie ' \\ 0. (OO x gla be e A Soy See zi 8 AN ow Oo 5) ° => — > I H cos ors ee ee + +f. Ozonolysis (Ales dove) a) Reductive ° se es (0, 0 dowl > o- diketone b) idahw: 6 _ *R: —¢2 eH ” G4 R-woon + Cotto ° +ccl 2 cw OE Ry a“ a J BD as ayeenie it % weet § oH \ CriCook + OR+H.0 3. Coupling Beacons eceuscaiee a.Linear 9 cy=c1 a> “4 EH- ce uy“b. Cyclic Coupling. ter bot tebe CFetobe) c. oxidative Coupling AR-cHc mM oS Quc=c-cec 4. Test of Terminal Alkynes Q) Stlyer Witoke test b) Cnprous chloride Ue Aj Na+ comet R-c=cH ‘Question | S Acidifies| K mn, An alkyne C,H, on reaction witha Opand subsequent acidification with HCI yields a mixture of (CH,),—CH—COOH + CH,—CH,COOH. The alkyne is @ 3-Hexyne (BY o-methyi-3-hexyne © 3-methyl-2-hexyne ©) 2-methyl-1-hexyne[Question Which of the following reagents will be able to distinguish between 1-butyne and 2-butyne? Pa (CBSE AIPMT 2012) [ Question Predict the product C obtained in the following reaction of butyne-1 CH Hy -C= CH (CBSE AIPMT 2007) ae A) Har Orb uw a (B) OHs— CH — CHE cl | | CHy—CH, —CH—CH,CI | GS cH804 40% cl are { Question i Products of the following reac as (CBSE AIPMT 2005) c (V0, CH c2ecH CH. oT 3a ydrolysis” 3" (A) CH,CHO+CH,CH,CHO (B) CH,COOH + CH,COCH, (©en,coon +HOOC.CH,CH, (D) CH,COoH + co, Question | When acetylene Is passed through dil. H,0 in presence of HgSO,, the compound formed is (CBSE AIPMT 1999) ether CHE tH — =HO ketone (C) acetic acid f D) fraserQuestion ‘A compound is treated with NaNH, to give sodium salt. Identify the compound (CBSE AIPMT 1993) CHE cH Question Reduction of 2-butyne with sodium in liquid ammonia gives predominantly (CBSE AIPMT 1993) (A) cis-2-butene > ) trans-2-butene, no reaction n-butane Question R—CH, —CCl, -R 22" R-Cac—R. The reagent is (CBSE AIPMT 1993) (A) Na HCl in H,0 C) KOHin cHion (D) — Znin alcohol Question Which one of the following has the shortest carbon-carbon bond length? (CBSE AIPMT 1992) A) Benzene ce) BE C>B>AdD @ ) Ethene UE, BL ce B< ACO OK Ethyne CY = (D) Ethane Ch—CH,{ Question Which is the most suitable reagent among the following to distinguish compound (ill) from rest of the compounds? (CBSE AIPMT 1989) | CH;—C=C-CH, I CH, —CH, —CH, ~CH, \V. CH, —CH= CH, A) 8r,/CCl, (B) Br,/CH,COOH (C) Alk.KMno, (OY ammonia AgNO, [Question | Acetylenic hydrogens are acidic because (CBSE AIPMT 1989) OK sama electron density of C- H bond in acetylene is nearer to carbon ‘ which has 50% s-character (B) _ acetylene has only one hydrogen on each carbon (C) _ acetylene contains least number of hydrogens among the possible hydrocarbons having two carbons (D) _ acetylene belong to the class of alkynes with molecular formula C,H...» In the following reaction, H,C— C= CH —S=satrontibe the number of sigma (0) bond present in the product A is (INEET (Odisha) 2019) H STA AT Flt Not all angels have wings, some have stethoscopes