Problem set 8 Chemical Bonding 1. Classify each bond as nonpolar covalent, polar covalent, or ionic (use the electronegativity values on page 341 of your textbook): aAI-F qo H-\.5 ES IMI > bowe wend b)Se-Br 2. g-2-y 20-4 0-5 > non-polar Covalent bond ©) Si-H A-B oe 0-6 > Ren polar Covalent bonl hr c 3:0-\.0=2-0 51.9 ionic bond 2. Arrange the elements in each set in order of decreasing electronegativity (by using only the Periodic Table): OCNF FLO>N>S = DBE > ely ary | ©)P,S, Al, DKUNaCs C7 S>P>AL - Lark > & 3. Draw a Lewis structure for each covalent compound: a) CCl b) CoHs c) OF2 d) H2Oz . Wee Ore Ove cae 4. Which of the following molecules are polar? Why? Go a) NHb Cr T peer edie XQ Polar bem gh a hy - wet ) CCl 6+ a ‘ } Fi _ ac Ser et ee sot ke nen fe COs ee ae wa apo Oal=0 eee 5. Predict the shape of each molecule and bond angle by using VSEPR model wo 8 a) NOs ( Me Je Erigonel planar Wei cu 109.6% tetrahedral b) SiH, LO i ©) OF: 8 5 dow ”. 109.5" bent pare ° iqonal Planar ee es Wey 1207 erigenal ol 6. In AICh, the electron configuration of aluminium ion is similar to which noble gases? What about chloride ion? gAl 2 15% 2st 278 get ap! ee ———S—s==t De. Betrang Madani Chemistry 100 wwe1. Find the charge of each element for these ionic compounds: te ote 20 aco ca* o acmo cas oO b) PbCly por ct” ) KBr Kt Be™ OHS yee ge NFO se ote 8. Use the following ions to write the chemical formula for each ionie compound: OG On] a Geroe by Ast Bo ae OB S* > Be,$, > Bes Ga Bros Ca Bs 9. For problem 8, write the electron configuration for each ion. They are similar to which noble gases? Colt ¢ ast ast 2ef ast 3pF 32 os 15% ast ape Ast sist 25% 2pl as™ gol ust acl? pl yell Tog 15% 25% ape 35% apt us* soll? ph ssracle ope Bert: 452 s* : 152s? gol 352 306 Br™: 15% 2s pf ast ap yt a.y10 4 pé 10, Draw a Lewis structure for each ion: a) CO Cae i H + b) NHs* [xf] 4 . * ©) FRO" [n-8-¥] 4 d) SOP aor 11. Use the electron configuration of calcium and oxygen and then Ca** and O* to show how. an ionic bond is produced between them. Ca(Qo): 1st 28% gb 35h 396 uot OB): 15* 25% 2p4 cart: 1st 2st 296 35% apf of : 18? 25" 296 Z ut (ie) ~ seer Re are tvansterest \@- ee we Dr. Bebrang Madani Chemistry 100