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20/2/23, 16:37 The Science of Water Extinguishment | Firehouse
During the many discussions that followed, we also realized that the way
in which we applied the water was also fundamentally different. For
handline use, smoothbore nozzles are basically non-existent in Australia
and Europe. Interior fighting is performed utilizing combination fog
nozzles and using techniques switching between straight stream and fog as
the situation demands, in both cases aiming for maximum efficiency.
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These techniques are based on those developed by the Swedish during the
early 1980s (and somewhat earlier by U.S. Chief Lloyd Layman). They
involve a sound understanding of the science behind the prevailing fire
conditions and, in particular, those conditions that lead to rapid fire
progression.
The following article explains the science behind these techniques and
hopefully provides an insight into how Australian and European
firefighters approach the use of water.
There are times when fires go out quickly with what seems to be a
surprisingly small amount of water. Some firefighters are able to do
amazing things with a stored water extinguisher or a small low-flow, high-
pressure line, but at other times are forced from a structure despite
flowing large volumes of water. It soon becomes obvious that there is more
to extinguishment than volume alone.
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Assuming we apply the water in the correct format and put it in the right
place, the key question then becomes: How much water is needed to
extinguish a certain amount of fire? And this is where we can turn to
science for some clear-cut answers.
There are also some basic physical principles that are occurring that help
explain how water extinguishes. Simply put, gases will always flow from
higher pressure areas to areas of lower pressure and heat energy will
always flow from higher temperature (hotter) objects into lower
temperature (colder) objects until a state of equilibrium is reached. This
“flow” of energy is described by the second law of thermodynamics. Also,
the ideal gas law, as well as mechanisms for heat transfer, are useful tools
for understanding how water extinguishes.
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A fire produces heat (energy), and the heat release rate (HRR) is a
measure of the fire’s intensity. Heat is measured in joules (J). 1,000 J is a
kilojoule (kJ) and 1,000 kJ is a megajoule (MJ). A joule per second is a
watt (W).
Fires release heat over time, so it is more useful to measure energy from a
fire in watts or, as in our case with structure fires, in MW (i.e., megajoules
per second or MJ/s). To put it simply, for extinguishment, heat being
released has to be transferred to the extinguishing media (in this case
water). Consequently, the water application rate must match (and
preferably overcome) the heat release rate.
Water heats up
Let’s assume that as a droplet that’s 10 degrees C (50 degrees F) leaves the
nozzle, it travels into a layer of hot fire gases that are approximately 600
degrees C (1,112 degrees F). This represents a temperature where fire
gases (composed of pyrolysis product and unburnt products of
combustion) are approaching their auto-ignition temperature and will
become fuel for rapid fire progress. Firefighters moving through or
operating beneath these gases without cooling them do so at great risk.
Even with modern PPE, radiant heat alone will limit their ability to remain
in this area for long. This is an environment that firefighters must
immediately remove themselves from or aggressively control (cool).
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Heat will move from the higher temperature (smoke) to the lower
temperature (water droplet), and the temperature of the water will, in an
instant, rise to 100 degrees C (212 degrees F). The energy necessary to
raise the temperature of 1 kilogram (kg) of water 1 degree C is known as
the specific heat of water. Water has a higher specific heat than most
common substances, and this is one of the reasons it is such an effective
extinguishing agent. Think of how much energy it takes to heat a liter of
water to a boiling point every time you put on a kettle. Sometimes it seems
like forever waiting for that first coffee of the morning.
Smaller water droplets have larger surface area to mass of water, which
means each droplet has more surface to absorb heat energy while having
less water to heat up. These two factors mean small water droplets heat up
faster. In terms of understanding that small objects heat up the fastest, we
see this same concept applied when starting fires. Small pieces of wood
(kindling) are used as the fuel when starting fires instead of large ones,
because they have more surface area to absorb heat and less wood to heat
up to their ignition temperature.
So for a split second, our droplet of water has been heated to 100 degrees
C (212 degrees F). Though our hot fire gases have also cooled a
corresponding amount, they are still much hotter than 100 degrees C (212
degrees F), so the transfer of heat will continue from the fire gases to the
water, which will vaporize and, for another split second, become 100
degrees C (212 degrees F) steam.
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Steam heats up
When the steam is dispersed into the smoke layer, more energy will be
transferred from the smoke layer, as the smoke is still likely to be hotter
than the 100 degrees C (212 degrees F). The result will be a rise in steam
temperature. This process will continue until a thermal equilibrium exists
between the steam and the smoke. This energy absorption is known the
specific heat of steam.
Steam has a different value for the “specific heat” than water. This value is
dependent on the temperature of the steam. For this calculation, an
average value is used (300 degrees C; 572 degrees F). This process will
continue until a thermal equilibrium exists between the steam and the
smoke.
Add it all up
Q = Q1 + Q2 + Q3
= 3,052.74 kJ
Q = 3.05 MJ
When both values (Q1 and Q2) are compared, it is clear that the transition
from 100 degrees C water into 100 degrees C steam absorbs more energy
than the heating of the water until it reaches 100 degrees C. In this case,
six times more energy is needed to transform the water into steam, than is
needed to heat the water. In other words, if your water droplets are not
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turning into steam, you are leaving over 75 percent of the heat-absorbing
capacity of the water unused.
The above calculations deal only with the absorption of heat energy. When
we introduce an amount of steam into hot smoke (or fire), there are
additional processes occurring that also enhance extinguishment. Most
firefighters would know that water increases greatly in volume as it turns
to steam. Most could also relate the expansion figures of 1,700 times at
100 degrees C, but few would also know that this increases with
temperature. In fact, the expansion rate at 600 degrees C (1,112 degrees F)
is 3,980 times!
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The size of the droplet is an important parameter. If the droplets are very
small, they will evaporate too soon after leaving the nozzle and only the
smoke layer closest to the firefighter will be cooled. If the droplets are too
large, they will pass through the smoke layer without evaporating
completely. Some may hit the ceiling and will evaporate there, absorbing
heat from the ceiling. Another possibility is that they drop to the ground.
In this case, they will travel through the smoke layer a second time. The
number suggested as the ideal size for such a droplet is 0.3 mm.1 Droplets
this size should be large enough to provide penetration into the hot smoke
and yet small enough to vaporize readily.
Water can be used to extinguish fire or cool hot fire gases en route to the
fire. Although the objective in both cases is to absorb energy, the
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= 11.49 MJ/s
= 11.49 MW
This example shows that a flow of 60 gpm (230 lpm) should be capable of
quickly suppressing at least 11 MW of fire, based on energy absorption
alone. But this requires a very high percentage of efficiency, which, for
many reasons, may not be possible. Needless to say, in this example,
firefighters operating at only 50 percent efficiency should still achieve
rapid extinguishment.
Many fires—due to size, access issues and fuel type—will always need
significant amounts of water as our ability to place our water where it can
be most efficient is limited. Other fires, confined within an enclosure with
limited access to air, will need water to safely cool hot fire gases if we are
to enter and get close enough to attack the seat of the fire. Either way, a
sound understanding of the theory of water extinguishment will go a long
way to helping a firefighter choose the most efficient technique in order to
make the most of the water they have.
Endnotes
Additional References
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Hoselines & Water Appliances Hoselines & Water Appliances Operations & Training
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Product of the Day: ECO-10 The RAM XD Rapid Attack Portable Monitor Curt Isakson hammers home why
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Jonathan Hall tells why engine companies The move means FOL-DA-TANK will be in a John J. Salka Jr. is adamant when it comes
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Jonathan Hall Nov. 14, 2022 products. regarding the second hoseline and the
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