Foundations of Thermodynamics

1 ∂V -1 ∂V α ∂P
PV=nRT α = V( ∂T )P κ = V ( ∂P )T = (∂T)V
κ
2 ∂U ∂H
(P + a n 2 )( V - nb ) = nRT Cv = ( ∂T )V CP = (∂T )P
V
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∂T
dU = dq + dw dU = TdS - PdV (∂V )S = -(∂P
∂S )V
H = U + PV dH = TdS + VdP (∂T ∂V
∂P )S = ( ∂S )P
A = U - TS dA = -SdT - PdV (∂P ∂S
∂T)V = (∂V )T
G = H - TS dG = -SdT + VdP (∂V ∂S
∂T )P = -(∂P )T
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(∂U ∂P
∂V )T = -P + T(∂T)V
∂U ∂V
Cp - CV = ( P + (∂V )T )( ∂T )P
α2
(∂H )
∂P T = V - T ( ∂V
)
∂T P = -µ C
JT P C p - CV = T (∂P
) ( ∂V
∂T V ∂T P ) = VT
κ

T V cst. T P cst. T
S ∆S = ⌠ TP dT
C
@ cst.P ∆S = ⌠ α dV ∆S = - ∫ αV dP
⌡ κ
⌡
∆S = CP ln T2/T1 ∆S = nR ln V2/V1 ∆S = -nR ln P2/P1
A ∆A = - ∫ S dT @ cst.V ∆A = - ∫ P dV ∆A = ∫ PVκ dP
∆A = -nRT ln V2/V1 ∆A = nRT ln P2/P1
G ∆G = - ∫ S dT @ cst.P ∆G = - ⌠ 1 dV ∆G = ∫ V dP
∆rG2 ∆rG1 1 1 ⌡κ
- = ∆rHo- ( - )
T2 T1 T2 T1
∆G = -nRT ln V2/V1 ∆G = nRT ln P2/P1