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H
istorians have nearly uniformly
suggested that the sequence
of days of the week has its
reference base in planetary information.
One notable exception is Jensen who
suggested in 1910 that the reference
base for the order of the days of the week
were the elements.1 The “Astronomical
Hypothesis” requires that, instead,
elemental information was subsequently
arbitrarily attached to the planetary
sequence. In this article we pick up
Jensen’s suggestion and demonstrate
that a compelling argument can be
made that the underlying reference
sequence for the days of the week is the
oxidative reactivity of metals known
at the time the days of the week were
codified. Once the oxidative order of the
metals was set, planets and days were
attached and subsequently codified.
This hypothesis will be referred to as
the “Oxidation/Reduction Hypothesis.”
Years
Days
Stephanos 600-700 Au Ag Fe Hg Sn Cu Pb
Al-Dimashqi 900 Au Ag Fe ? Sn Cu Pb
Chaucer 1380 Au Ag Fe Hg Sn Cu Pb
Agrippa 1533 Au Ag Fe Hg Sn Cu Pb
Corrosion Potential
NASA corrosion 2001 Au Ag Steel3 Bronze Cu Sn Pb
potential (304 & (G) 6
in seawater 316) 4, 5
http://corrosion.ksc.nasa.gov/html/galcorr.htm
1. Bronze: predominately Cu
2. Electrum: a native alloy of Ag and Au with 5-50% silver content
3. Steel: 0.2-1.5%C remainder Fe
4. Steel 304: 0.08% C; 2% Mn; 18-20% Cr; 0% Mo; 8-10.5% Ni; Balance Fe; 1% Si; 0.045% P; 0.03% S
5. Steel 316: 0.08% C; 2% Mn; 16-18% Cr; 2-3% Mo; 10-14% Ni; Balance Fe; 1% Si; 0.045% P; 0.03% S
6. Bronze G: 88% Cu; 10% Sn; 2% Zn
Purity Rank
values of the relevant metal reactions
4
(Table IV) associated with the five
metal/day assignments plotted against
the purity rank in the Celsus sequence. 3
(Figure 5 contains data for the metal
copper, although the purity sequence 2
specified by Celsus specifies the alloy
bronze. The data for copper (small
circles) is included for comparison with 1
Fig. 5). As can be observed, the most
reactive metals are lead and tin and the 0
least reactive metals are gold and silver,
0 200 400 600 800 1000 1200 1400 1600 1800
consistent with the assignment of these
metals in the purity sequence of Celsus. Date
Rather surprisingly, given the arbitrary
distance in the purity steps, a correlation Fig. 4. A plot of element/metal assignments to purity rank over history. Alchemical symbols are used
can be derived between the purity rank for the various metals. The final (1700s) sequence is from bottom to top: lead, copper, tin, mercury,
iron, silver, gold. The compilation of assignments can be found in Table III and is derived from
and the free energies of oxide formation
Nriagu.
(data for copper excluded). This
correlation was obtained by removing
the one data point for iron (Fe2O3)
which is substantially off the trend. It
300
is interesting to note that the only time
that lead is displaced from the bottom y
of the purity sequence [The Venerable
200 xM + O 2 heat
→ M x O y
Bede (673-735 AD) (Table II, Fig. 4)], it is 100
2
displaced by iron.
What is the historical event that 0
set off centuries (700-1400 AD) of
∆Gfo (kJ/mole)
For oxidations occurring in solution, is also associated with the advent The poor fit is most likely related to
the apparent formal potential, E o’, of aqua regia (mixture of nitric and the rates of reactions in nitric acid and
applies. Figure 6 gives the metal/day hydrochloric acids) which opens up the presence of ions which accelerate
sequence corresponding to Chaucer, reactions in which the metal is oxidized passivation. It is known that Fe, Ni,13-16
which appears to track the redox to a chloride complex. Sn,17-19 Pb,20,21 and Cu22,23 dissolve in
potentials of Reactions 2-3 (Table IV). (m − z ) + dilute nitric acid more rapidly than in
The correlation with the purity sequence MClz + me ⇔ M + zCl − (4)
concentrated due to the formation of
is, however, not as good as the sequence Even allowing for chloride a passivating layer that forms on the
for oxidation by fire. The relatively complexation the correlation is poorer electrode surface in concentrated nitric
poorer correlation can be explained by than for fire oxidation (omitting low acid. Thus while the formal potential for
the simultaneous introduction of aqua lying points for iron R 2 = 0.56). The the oxidation of iron (two data points
regia (HNO3/HCl) allowing oxidation poorer correlation may explain the outlined in white, Fig. 6) predicts a high
to be boosted by chloride complexation oscillations in assignments between reactivity, the kinetics of the reaction
(see Fig. 6, triangles; Table IV). Jabir 700-1400 AD. shift it into a higher “purity” rank.
In homogeneous solution an
2 M x O y + 2yH + + 2ye → xM + yH 2O
autocatalytic decomposition sequence
for nitric acid has been proposed24 1.5
Formal Potential, V
NO3−− + 2H++ + 2e → NO2−−+ H2O (5)
3 2 2 1
0
NO++ + e → NO (8)
−
2NO + NO3− + H++ + H2O → 3HNO2 (9) -0.5
3 2 2
R2 = 0.56
The variability in the reactivity of
-1
the nitric acid based on concentration
0 1 2 3 4 5 6 7 8
is derived from control of Reactions 6,
7, and 8 which drive the catalytic Chaucer (1380 A.D.) Purity Rank
Reaction 9. Passivation may occur
through adsorption of NO2 - to the metal Fig. 6. A plot of Chaucer’s (1380 AD) metal sequence vs. the standard electrochemical voltage (vs.
surface.25 With time the adsorbate layer NHE) of relevant half reactions. The symbols for the metals are the same as in Fig. 4. Reactions are
shown in Table IV. Triangular symbols represent reactions taking place in a chloride matrix such as
may convert to more stable species aqua regia. The three normal data points for iron correspond to Fe3O2 between pH 2-4. The low lying
diffusion blocking layers.26 In the white boxed data points for iron correspond to Fe/Fe3+ and Fe/Fe2+. See text for a discussion.
process zero valent iron can be converted
to Fe2O3.27 In Fig. 6, the three data points
which fall directly on the regression are purity sequence by counting the days of charge transport in clay films with
for Fe2O3 pH2- 4. The formation of the backwards from Saturday to Sunday. applications in photochemistry and
initial film may be disrupted by chloride The “Oxidation/Reduction” sequence microbial use of clays as terminal
ions. It is interesting to speculate that is based on accurate metallurgical electron acceptors. She has authored
the variability of the acid (nitric vs. knowledge of the reactivity of metals to 60 research papers, edited a book on
aqua regia) and the complexity of the air oxidation. The resulting metal/days clay electrochemistry, and is currently
nitric acid reaction may account for the subsequently have planets attached to preparing an electrochemistry text for
700-year lag in stabilizing the sequence them in an arbitrary force-fit. Occam’s Wiley. She is a passionate gardener and
of metals to the planet/days. Razor test, (the simplest hypothesis is attempting to learn the cimbalom,
Clue 3, the sporadic appearance of should be most accurate) suggests that a Hungarian hammered dulcimer.
mercury as a metal/day, supports the the “Oxidation/Reduction” sequence is Lincoln is an obsession. She is also the
idea that the sequence of metal/days superior. The “Oxidation/Reduction” author of three plays, one of which
should reflect metallurgical knowledge. hypothesis requires only seven data explores the relationship of humanity
Mercury was known as a pure element points (reactivity of the metals) to with lead and has had several directed
by about 500 BCE but does not show define the days of the week, while the readings. She may be reached by email
up as a metal/day in the Babylonia “Astronomical Hypothesis” requires at afitch@luc.edu.
list (1600-1400 BCE). In Roman times seven astronomical observations
while mercury was used to recover to then be “sorted” by a relatively References
gold from embroidery it was not used complicated scheme in which the metals
in ore refinement. Mercury’s first are attached to the days of the week
counting backwards from Saturday 1. E. Zerubavel, The Seven Day Circle:
unambiguous appearance is in ~650 AD
toward Sunday. The “Oxidation/ The History and Meaning of the
but it does not become embedded in
Reduction” hypothesis also accounts for Week, University of Chicago Press,
the days until Chaucer’s list. At that
variations in the metal/day assignments Chicago (1989).
period in history mercury was used
prior to codification (see the Babylonian 2. F. H. Colson, Classical Review, 41,
in metal ore recovery.4 By the time of
list, Celsus’ list, and the list of Vettius 41 (1926).
Agrippa (1533 AD), Hg had become well
Valens). 3. R. Beck, Planetary Gods and
used in metallurgy in the processing of
Planetary Orders in the Mysteries
silver ores in Mexico, accounting for its
of Mithras, E. J. Brill, Leiden,
subsequent “permanent” inclusion in About the Author Netherlands (1988).
the metal/day sequence.28
4. P. T. Craddock, Early Metal Mining
A lanah Fitch is Professor of Chemistry and Production, Smithsonian
Conclusion at Loyola University of Chicago. She Institution Press, Washington, DC
is the 2007 recipient of the American (1995).
The two hypotheses outlined Chemical Society Giddings Award for 5. K. Nassau, The Physics and
above seek to explain the codified Excellence in Education in Analytical Chemistry of Color: The Fifteen
sequence of the seven-day week. The Chemistry. In 2005 she received an Causes of Color, John A. Wiley &
“Astronomical Hypothesis” is based NSF Discovery Corps Fellowship to link Sons, New York (1983).
on an approximately accurate sidereal instrumentation at Loyola University 6. J. Slater, Quantum Theory of Matter,
period of the planets counted to fit Chicago with classes in East Africa. McGraw-Hill Press, New York
seven 24-hour days, resulting in a In 2000 she was named a Loyola (1951).
week that begins on Saturday. Metals University Faculty Scholar. Her current
are then arbitrarily force-fit to that research includes electroactive planar
planet/day sequence to achieve a metal waveguides to elucidate mechanisms
www.electrochem.org
The Electrochemical Society Interface • Summer 2010 29
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