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TRIFERTO N.V.

Material Safety Data Sheet In accordance with (EC) No. 1907/2006 (Reach)
(EG) No. 1272/2008 and (EG) 453/2010

NPK 14-12-26+8,2MgO+1S Blend

ARTICLE 1. Identification
1.1. Name of the product: NPK 14-12-26+8,2MgO+1S
1.2. Relevant use: Product is used to add
nutrients to the soil.
1.3. Details of the issuer of the safety information sheet
Name: Triferto Belgium N.V
Address: Koopvaardijlaan 180-182
9000 Gent
België
Telephone number in case of emergency: + 32 9 255 54 00
e-mail address info@triferto.eu
1.4. Emergency telephone number National Poison
Information Centre + 32 70 245 245
Antigif Centrum (B)
ARTICLE 2. Identification of the dangers

2.1. Classification
The product is not classified as dangerous according to guideline 1999/45/EC and its
changes.1
2.2. Labelling
The product must not be labelled according to guideline 1999/45/EC.
2.3. Other dangers
In the event of fire irritating gases may be produced.

1 According to the Reach regulations a Safety Information Sheet is not necessary for this product
Revision date: 05.04.2016 page 1 of 12
Version: 3
TRIFERTO N.V.
Material Safety Data Sheet In accordance with (EC) No. 1907/2006 (Reach)
(EG) No. 1272/2008 and (EG) 453/2010

NPK 14-12-26+8,2MgO+1S Blend

ARTICLE 3. Composition of and information about the constituents

Dangerous constituent:

Name of constituent CAS Number % EC number Classification


67/548/CEE 1272/2008 CLP
Urea 57-13-6 <20 200-315-5 Not classified
Reach# 01-2119463277-33-XXX

See section 16 for the complete text and the R/S phrases and classifications that are
stated above.
There are no other ingredients present that, for as far as is known to the supplier,
and in the applicable concentrations, are classified as hazardous to one’s health and
the environment and on the basis of this have to be stated in this section.

The fertilizer may contain several of the below constituents:


- calcium phosphate
- ammonium sulphate
- diammonium phosphate
- potassium chloride
- potassium sulphate
- fillers such as dolomite powder, chalk,…
- coating material such as oil, amine, clay or talc
- trace elements (such as copper sulphate, zinc sulphate, sodium borate,….)

Revision date: 05.04.2016 page 2 of 12


Version: 3
TRIFERTO N.V.
Material Safety Data Sheet In accordance with (EC) No. 1907/2006 (Reach)
(EG) No. 1272/2008 and (EG) 453/2010

NPK 14-12-26+8,2MgO+1S Blend

ARTICLE 4. First aid measures

Swallowing Rinse the mouth with plenty of water.


Have the casualty drink plenty of water.
Do not encourage vomiting.

Ensure medical assistance if the


casualty has ingested more than 10 g.

Inhalation Take the casualty out into the fresh air


Ensure medical assistance

Contact with skin Wash the skin with water


Contact with the eyes Rinse immediately with plenty of water
Ensure medical assistance
Protection of the first aiders No actions should be carried out if there
is a risk of personal accidents or in the
case of insufficient training

ARTICLE 5. Fire prevention measures

Revision date: 05.04.2016 page 3 of 12


Version: 3
TRIFERTO N.V.
Material Safety Data Sheet In accordance with (EC) No. 1907/2006 (Reach)
(EG) No. 1272/2008 and (EG) 453/2010

NPK 14-12-26+8,2MgO+1S Blend

5.1. Fire extinguishers


Water (plenty)
5.2. Hazardous thermal decomposition products
In the event of a fire irritating vapours of carbon oxides, chlorine, sulphate oxides
and nitrogen oxides may be produced.

5.3. Protection for fire-fighters


Compressed air mask
Remark The product is not flammable, but can still maintain combustion, also
in the absence of air. When heated, the product melts, in extreme
heat the product may decompose, whereby toxic vapours are
released containing nitrogen oxides and ammonia.

ARTICLE 6. Measures in the event of unintentional release of the product

6.1. Personal protection


See sections 5 and 8
6.2. Environmental measures
Ensure that spilt or leaking material does not come into contact with any soil and
surface water.
6.3. Cleaning up
Material that has been spilt should be collected as much as possible. See also
section 13.
Ensure that fertilizer does not get into the sewer system.

ARTICLE 7. Handling and storing the substance


7.1. Handling

Revision date: 05.04.2016 page 4 of 12


Version: 3
TRIFERTO N.V.
Material Safety Data Sheet In accordance with (EC) No. 1907/2006 (Reach)
(EG) No. 1272/2008 and (EG) 453/2010

NPK 14-12-26+8,2MgO+1S Blend

Avoid causing excessive formation of dust. Avoid unnecessary exposure to the


atmosphere to prevent moisture.
7.2. Storage
Store dry.
Do not store in the vicinity of flammable materials or reducing agents.
Do not expose to high temperatures.

ARTICLE 8. Measures to control exposure and personal protection.


8.1. Parameters to monitor
No limit values are known.
8.2. Measures
8.2.1.Technical measures
Localised extraction, ventilation
8.2.2. Personal protection
8.2.2.1 Eye and face protection
Goggles
8.2.2.2 Skin protection
Hand: Protective gloves
Body: Protective clothing
8.2.2.3 Respiration protection
Respirator, type P2
8.2.2.4 Thermal protection
8.2.3. Hygiene measures
No eating, drinking or smoking whilst handling the substance

ARTICLE 9. Physical and chemical properties


Revision date: 05.04.2016 page 5 of 12
Version: 3
TRIFERTO N.V.
Material Safety Data Sheet In accordance with (EC) No. 1907/2006 (Reach)
(EG) No. 1272/2008 and (EG) 453/2010

NPK 14-12-26+8,2MgO+1S Blend

9.1. Physical and chemical properties


a) Appearance Granules, dry
b) Odour Odourless
c) Odour detection threshold Not applicable
d) pH: Not determined
e) Melting point Approximately 170 °C
f) Boiling point/ boiling range Not applicable
g) Flash point Not determined
h) Evaporation speed Not determined
i) Flammability Not applicable
j) Flammability or explosion
lower/upper limit Not applicable
k) Vapour pressure Not determined
l) Vapour density Not determined
m) Bulk density 900-1100 kg/dm³
n) Solubility Highly soluble in water
o) Partition coefficient n-octanol/water Not determined
p) Spontaneous ignition temperature Not applicable
q) Decomposition temperature > 235 °C
r) Viscosity Not determined
s) Explosion properties Not applicable
t) Oxidisation properties Not determined
9.2. Other information
No additional information available

Revision date: 05.04.2016 page 6 of 12


Version: 3
TRIFERTO N.V.
Material Safety Data Sheet In accordance with (EC) No. 1907/2006 (Reach)
(EG) No. 1272/2008 and (EG) 453/2010

NPK 14-12-26+8,2MgO+1S Blend

ARTICLE 10. Stability and reactivity


10.1. Stability/reactivity
No specific test data is available for this product
10.2. Chemical stability
Stable under the conditions prescribed for storage and handling (see Article 7)
10.3. Possibility of hazardous reactions
Under normal conditions of storage and use, no hazardous reactions occur with this
product
10.4. Conditions to be avoided
Avoid contamination with metals, dust or organic materials. Avoid contact with heat,
sparks and flames. Do not expose to direct sunlight.
10.5. Materials to be avoided
Strongly alkaline, acidic and organic materials, chromates, zinc, compounds with
copper, nickel and cobalt
10.6. Hazardous decomposition products
Compound fertilisers melt and decompose upon extreme heating, whereby
poisonous vapours are released.
Remark
An NPK fertiliser that cannot deflagrate according to the IMO standard Gazen goot
proef (Mesh drain test) in accordance with the recommendations for the Transport of
Dangerous Goods, as set out in the Test Manual and Criteria, 2, part III, section 38

Revision date: 05.04.2016 page 7 of 12


Version: 3
TRIFERTO N.V.
Material Safety Data Sheet In accordance with (EC) No. 1907/2006 (Reach)
(EG) No. 1272/2008 and (EG) 453/2010

NPK 14-12-26+8,2MgO+1S Blend

ARTICLE 11. Toxicology information


11.1. information about toxicological effects
a) Acute consequences for one’s health
Negative effects for health are not probable if the product is used according to the
instructions.
b) Irritation
Significant effects or critical hazards are not known.
c) Corrosiveness
Significant effects or critical hazards are not known.
d) Hypersensitivity
Significant effects or critical hazards are not known.
e) Chronic consequences
Significant effects or critical hazards are not known.
f) Carcinogenity
Significant effects or critical hazards are not known.
g) Mutagenicity
Significant effects or critical hazards are not known.
h) Effects on one’s development
Significant effects or critical hazards are not known.

Revision date: 05.04.2016 page 8 of 12


Version: 3
TRIFERTO N.V.
Material Safety Data Sheet In accordance with (EC) No. 1907/2006 (Reach)
(EG) No. 1272/2008 and (EG) 453/2010

NPK 14-12-26+8,2MgO+1S Blend

ARTICLE 12. Ecological information


12.1. Ecotoxicity
Use of extremely large quantities can contaminate the aquatic environment.
12.2.Persistence and degradability
Most inorganic compounds are not biodegradable.
12.3. Capacity for bioaccumulation
The product displays no bioaccumulation signs.
12.4.Mobility in the soil
Significant effects or critical hazards are not known.
12.5. Evaluation results for persistence, bioaccumulation and toxicity (PBT) and high
persistence and high bioaccumulation
Significant effects or critical hazards are not known.

ARTICLE 13. Instructions for removal


13.1. Removal methods
Empty sacks may contain some residual product. Do not dispose of waste in the
sink; dispose of substance and packaging in a safe manner. Disposal according to
all the applicable local and national regulations.
13.2. Hazardous waste
According to the current knowledge of the supplier, this product is not considered to
be hazardous waste as defined in EC guidelines 91/689/EC

ARTICLE 14. Information regarding transport

Revision date: 05.04.2016 page 9 of 12


Version: 3
TRIFERTO N.V.
Material Safety Data Sheet In accordance with (EC) No. 1907/2006 (Reach)
(EG) No. 1272/2008 and (EG) 453/2010

NPK 14-12-26+8,2MgO+1S Blend

Transport by Transport by Transport by Transport by


road and rail. inland sea IMDG5 air
ADR2/RID3 waterways IATA6
ADN4
14.1 UN number No specific regulations apply
14.2 UN
description
14.3 Hazard class
transport
14.4 Packaging
group
14.5 Hazard for None None None None
the surroundings
14.6 Special
precautions for
the user
14.7. Bulk transport according to Appendix II of the Marpol7l 73/78 agreement and
IBC8 code.
No specific regulations apply

2 ADR; European Agreement concerning the International Carriage of


Dangerous Goods by Road
3 RID; Regulations concerning the International Carriage of Dangerous Goods by Rail
4 ADN; European Agreement concerning the

International Carriage of Dangerous Goods by Inland Waterways


5 IMDG; International Maritime Dangerous Goods
6 IATA; International Air Transport Association
7 MARPOL; International Convention for the Prevention of Pollution From Ships
8 IBC; International Bulk Chemical Code

Revision date: 05.04.2016 page 10 of 12


Version: 3
TRIFERTO N.V.
Material Safety Data Sheet In accordance with (EC) No. 1907/2006 (Reach)
(EG) No. 1272/2008 and (EG) 453/2010

NPK 14-12-26+8,2MgO+1S Blend

ARTICLE 15. Legally required information

15.1. Safety, health and environmental regulations and legislation

Not classified as hazardous substance according to EC criteria


Classification and labelling are carried out in accordance with EC guidelines
67/548/EEC, 1999/45/EC, including amendments and the intended use.
15.2. Evaluation of the chemical safety;
No chemical safety evaluations were carried out on this product.

ARTICLE 16. Other information

Complete text of R phrases, which are referred to in Articles 2 and 3


Not Classified

Complete text of classifications which are referred to in section 2 and 3


Not Classified

All information that is issued by or on behalf of Triferto in relation to properties,


specifications, applications, etc. of the products is based on research, including
literature research, and is considered to be reliable.
Revision date: 05.04.2016 page 11 of 12
Version: 3
TRIFERTO N.V.
Material Safety Data Sheet In accordance with (EC) No. 1907/2006 (Reach)
(EG) No. 1272/2008 and (EG) 453/2010

NPK 14-12-26+8,2MgO+1S Blend

Triferto cannot, however, be held responsible for neither the functioning or the
results obtained through the use of the products or the relevant information, nor any
damage that may arise due to or to the products or the information.

In this respect the user is obliged to check the quality and all other properties of the
products.
The buyer accepts all responsibilities that are associated with the use of the products
and the information.

Revision date: 05.04.2016 page 12 of 12


Version: 3

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