TRIFERTO Belgium N.V.

Material Safety Data Sheet In accordance with (EC) No. 1907/2006 (Reach)
(EG) No. 1272/2008 en (EG) 453/2010

Solferto NPK 15-10-25 + 3 MgO +B

ARTICLE 1. Identification
1.1. Name of the product: Solferto NPK 15-10-25 + 3
MgO + B
1.2. Relevant use: Product is used to supply
nutrients to the soil or directly
to the plant.
1.3. Details of the issue of the safety information sheet
Name: Triferto Belgium N.V
Address: Koopvaardijlaan 180-182
9000 Ghent
Belgium
Telephone number in case of emergency: + 32 9 255 54 00
e-mail adres info@triferto.eu
1.4. Emergency telephone number National Venomous
Information Centre + 32 70 245 245
Antigif Centrum (B)

ARTICLE 2. Identification of the dangers

2.1. Classification
Product description: Mixture
Classification according (EG) Nr. 1272/2008 [CLP]
No classification.

2.2. Labelling
Labelling according (EG) 1272/2008 [CLP]
Hazard pictogram (CLP): None
CLP signal words: None
Hazard statements (CLP): None

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 TRIFERTO Belgium N.V.
Material Safety Data Sheet In accordance with (EC) No. 1907/2006 (Reach)
(EG) No. 1272/2008 en (EG) 453/2010

Solferto NPK 15-10-25 + 3 MgO +B

Precautions: Avoid eye contact. If in eyes,

rinse immediately with
abundant amount of water and
contact a doctor/physician.
Additional label elements: Not applicable
Packaging requirements Not applicable

2.3. Other hazards

Substance complies with criteria for PBT Not applicable
according to regulation (EC) nr. 1907/2006,
annex XIII

Substance complies with criteria for zPzB Not applicable

according to regulation (EC) nr. 1907/2006,
annex XIII

Other hazards that do not require classification: In combination with water the
product can cause slippery
surface.

ARTICLE 3. Composition of and information about the constituents

Dangerous constituents :
Name of CAS Classification Type Reach registration
% EG number
constituent Number 1272/2008 CLP number
Potassium Nitrate 7757-79-1 < 45 231-818-8 Oxid. Solid 3 - H272 [1] 01-2119488224-35
Urea Phosphate 4861-19-2 <2 225-464-3 Skin Corr. 1B - H314 [1] 01-2119489460-34

Type:
[1] Substance is classified as a physical, health or environment hazard
[2] Substance with workplace exposure limits

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 TRIFERTO Belgium N.V.
Material Safety Data Sheet In accordance with (EC) No. 1907/2006 (Reach)
(EG) No. 1272/2008 en (EG) 453/2010

Solferto NPK 15-10-25 + 3 MgO +B

[3] Substance complies with criteria for PBT according to regulation (EC) no.
1907/2006 annex XIII
[4] Substance complies with criteria for vPvB according to regulation (EC) no.
1907/2006 annex XIII
See section 16 for the complete text and the R/S phrases and classifications that are
stated here above

ARTICLE 4. First Aid measures

4.1 Description of first aid measures

Ingestion Rinse the mouth with plenty of water.

Have the casualty drink plenty of
water/milk. Do not encourage vomiting.
Seek medical attention if large quantities
were ingested
Inhalation Remove person to fresh air and keep at
rest in a comfortable position. Respiratory
problems, seek medical attention.
Contact with skin Wash immediately with an abundance of
water and soap. Remove contaminated
clothing, jewelry and shoes. If irritation
persists, seek medical advice and
attention.
Contact with the eyes Rinse immediately with plenty of water.
After the first rinse, optionally remove
contact lenses and continue rinsing for
15 minutes. Ensure medical assistance
4.2 Most important symptoms and effects, both acute and delayed

After ingestion: Significant effects or critical dangers are

unknown.

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Material Safety Data Sheet
Solferto NPK 15-10-25 + 3 MgO +B
After Inhalation:
After skin contact:
After eye contact:
4.3 Indication of any immediate medical attention and special treatment needed
Remarks for physician/doctor:
ARICLE 5. Fire prevention measures
5.1. Extinguishing media:
Suitable extinguishing media:
Unsuitable extinguishing media:
5.2. Special hazards arising from the substance or mixture:
Hazards of the substance or mixture:
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TRIFERTO Belgium N.V.
In accordance with (EC) No. 1907/2006 (Reach)
(EG) No. 1272/2008 en (EG) 453/2010
Exposure to decomposition products can
lead to health problems. After exposure,
serious effects can have delayed
occurrence. Treat symptomatically.
Significant effects or critical dangers are
unknown.
Significant effects or critical dangers are
unknown.
Treat symptomatically. Immediately
contact a specialist for treatment of
poisoning when large amounts were
ingested or inhaled. After inhalation of
decomposition products produced by a
fire, delayed symptoms can occur.
Medical surveillance of 48 hours is
recommended.
Extinguish with an abundance of water.
Do not use extinguishers based on
chemicals or foam. Do not put out the fire
using steam or sand.
Mixture is not flammable but can maintain
combustion, even in the absence of oxygen.
When heated, the mixture melts and
continuous heating can cause
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 TRIFERTO Belgium N.V.
Material Safety Data Sheet In accordance with (EC) No. 1907/2006 (Reach)
(EG) No. 1272/2008 en (EG) 453/2010

Solferto NPK 15-10-25 + 3 MgO +B

decomposition which releases toxic fumes

containing nitrous oxides and ammonia
based compounds.

Decomposition products Ammonia based compounds,

Nitrous oxides
Sulphur oxides
Phosphorus oxides

5.3. Protection for fire-fighters Fire-fighters should wear appropriate

protective equipment and self-contained
breathing apparatus (SCBA) with a full face-
piece operated in positive pressure mode.
Protective clothing for fire-fighters contain:
appropriate protective gloves, safety masks
and goggles and clothing which provides
adequate protection for chemical incidents.

5.4. Additional information Oxidizing material. Fight fire from protected

location or maximum possible distance.
Contain and collect the water used to fight the
fire for later treatment and disposal.

ARTICLE 6. Measures in the event of unintentional spelling of the product

6.1. Personal protection See sections 5 and 8

6.2. Environmental measures Avoid dispersal of split material and runoff and
contact with soil, waterway, drains and sewers.
Inform the relevant authorities if the product has
caused environmental pollution.

6.3. Cleaning up Material that has been spilt should be collected as

much as possible and deposited in a suitable
container or bag. Removal of collected spills must
be done by a competent authority.

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 TRIFERTO Belgium N.V.
Material Safety Data Sheet In accordance with (EC) No. 1907/2006 (Reach)
(EG) No. 1272/2008 en (EG) 453/2010

Solferto NPK 15-10-25 + 3 MgO +B

Ensure that fertilizer does not get into the sewer

system.

ARTICLE 7. Handling and storing the product

7.1. Handling Avoid excessive formation of dust. Put on
appropriate personal protective equipment (see
section 8). Avoid contact with inflammable
products (Oil, Grease and fuel), chemically
interacting materials.
Do not mix mixture with basic products (pH > 7)
Do not eat, drink or smoke in the area where the
material is used, processed or stored.
7.2. Storage Store in original packaging, protected from direct
sunlight in a dry, cool and well ventilated area.
Keep away from heat sources and open flames
Keep away from organic materials, oil and grease
Keep away from combustible materials mentioned
in section 10.5
Product remains stable for 2 years if stored
according to all provisions

ARTICLE 8. Measures to control exposure and personal protection

8.1. Parameters to control No exposure limit values known

DNELs/DMELs
Product name Type Exposure Value Population Effects
Long-term 20,8 mg/kg
Potassium Nitrate DNEL Employees Systemic
Dermal bw/day
Long-term
Potassium Nitrate DNEL 36,7 mg/m3 Employees Systemic
Inhalation
Long-term
Potassium Nitrate DNEL 12,5 mg/kg End users Systemic
Dermal
Long-term
Potassium Nitrate DNEL 10,9 mg/m3 End users Systemic
Inhalation

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 TRIFERTO Belgium N.V.
Material Safety Data Sheet In accordance with (EC) No. 1907/2006 (Reach)
(EG) No. 1272/2008 en (EG) 453/2010

Solferto NPK 15-10-25 + 3 MgO +B

Long-term 12,5 mg/kg

Potassium Nitrate DNEL End users Systemic
Oral bw/day
Long-term
Urea Phosphate DNEL 2,92 mg/m3 Employees Systemic
Inhalation
Long-term
Urea Phosphate DNEL 0,73 mg/m3 End users Systemic
Inhalation

PNEC’s
Product name Type Detail compartment Value Detail method

Potassium Nitrate PNEC Marine 0,045 mg/l Assesment factors

Potassium Nitrate PNEC Intermittent release 4,5 mg/l 3 Assesment factors

Sewage treatment
Potassium Nitrate PNEC 18 mg/l Assesment factors
plant
Potassium Nitrate PNEC fresh water 0,45 mg/l Assesment factors

8.2. Exposure controls.

Appropriate engineering controls:
Personal protective controls:
Eye protection:
Skin protection:
If user operations generate dust, use process
enclosures, local exhaust ventilation of other
controls to keep worker exposure to airborne
contaminants below any recommended or
statutory limits.
If risk assessment concludes the need of
protection, use appropriate approved
protective equipment (safety glasses, face
shield).
If risk assessment concludes the need of
protection, use appropriate approved
protective equipment (use protective gloves)

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 TRIFERTO Belgium N.V.
Material Safety Data Sheet In accordance with (EC) No. 1907/2006 (Reach)
(EG) No. 1272/2008 en (EG) 453/2010

Solferto NPK 15-10-25 + 3 MgO +B

Body protection Personal protective equipment must be used

Respiratory protection
Hygiene precautions
Environmental exposure
according to the activities. Wear protective
clothing and impervious footwear.
If risk assessment concludes the need of
protection, use appropriate approved
protective equipment (respiratory
equipment/gas mask)
Do not eat, drink or smoke whilst handling the
product. Wash with water and soap. Securirty
shower or eyewash stations must be provided
at the workplace
Emissions from ventilation or work process
equipment should be checked to ensure they
comply with legislation.

ARTICLE 9. Physical and chemical properties

9.1. Physical and chemical properties
a) Appaerance Powder/crystalline
b) Odor Odorless
c) Odor detection threshold No data available
d) pH solution: 3,0 – 5,0
e) Melting point No data available
f) Boiling point > 210 ° C
g) Flashpoint No data available
h) Evaporation speed Not applicable. Solid beads
i) Flammability No data available
j) Flammability or explosion
lower and upper limit No data available
k) Vapor pressure No data available
l) Vapor density No data available
m) Density 900 - 1400 kg/m³
n) Solubility Water complete
Soluble in cold water
o) Partition coefficient n-octanol/water No data available.

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 TRIFERTO Belgium N.V.
Material Safety Data Sheet In accordance with (EC) No. 1907/2006 (Reach)
(EG) No. 1272/2008 en (EG) 453/2010

Solferto NPK 15-10-25 + 3 MgO +B

p) Spontaneous ignition temp. No data available

q) Decomposition products > 210° C,
r) Viscosity Not applicable
s) Explosion properties Non
t) Oxidation properties Not applicable.

9.2. Other information No additional information.

ARTICLE 10 Stability and reactivity

10.1. Stability and reactivity
10.2. Chemical stability
10.3. Possibility of hazardous reactions
10.4. Conditions to be avoided
10.5. Incompatible materials
10.6. Dangerous decomposition products
Stable under recommended storage and
handling conditions (see Section 7)
Stable under recommended storage and
handling conditions (see Section 7)
Product can react heavily with basis
substances (pH > 7), where temperature
increases con occur.
Avoid contamination with alkaline
substances, combustible materials,
reducing agents and organic matter.
Moisture-sensitive material. Hygroscopic
Keep container tightly closed. Avoid
contamination by any source including
alkaline substances, combustible
materials, reducing agents and organic
matter.
In a fire, decomposition may produce
toxic gases/fumes.

ARTICLE 11. Toxicology information

11.1. Information about toxicological effects

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Material Safety Data Sheet
Solferto NPK 15-10-25 + 3 MgO +B
Hazard class
Acute toxicity
Oral
Potassium Nitrate
Urea Phosphate
Demal
Potassium Nitrate
Inhalation
Skin corrosion/irritation
Serious eye damage/irritation
Respiratory or skin sensitation
Germ cell mutagenicity
Carcinogenity
Reproductive toxicity
Specific target organ toxicity
(single exposure)
Specific target organ toxicity
(repeated exposure)
Aspiration hazard
ARTCLE 12. Ecological information
12.1. Eco toxicity
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TRIFERTO Belgium N.V.
In accordance with (EC) No. 1907/2006 (Reach)
(EG) No. 1272/2008 en (EG) 453/2010
Value Method
3750 mg/kg Rat OECD Guideline 405
2600 mg/kg Rat
> 5000 mg/kg bw/day Rat OECD 402
No available data
Significant effects or critical
values are unknown
Significant effects or critical
values are unknown
Significant effects or critical
values are unknown
Significant effects or critical
values are unknown
Significant effects or critical
values are unknown
Significant effects or critical
values are unknown
Significant effects or critical
values are unknown
Significant effects or critical
values are unknown
Significant effects or critical
values are unknown
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 TRIFERTO Belgium N.V.
Material Safety Data Sheet In accordance with (EC) No. 1907/2006 (Reach)
(EG) No. 1272/2008 en (EG) 453/2010

Solferto NPK 15-10-25 + 3 MgO +B

Product name Result Species Exposure

Potassium Nitrate Acute LC50: 1,378 mg/l Pisces 96 h
fresch water OECD 203
Potassium Nitrate Acute EC50: 490 mg/l Other aquatic organisms 48 h
fresch water Daphnia
Urea Phosphate LC50: > 900 mg/l Pisces
fresch water
Urea Phosphate EC50: > 100 mg/l Other aquatic organisms 48 h
fresch water Daphnia
Urea Phosphate EC50: > 100 mg/l Other aquatic organisms
Algae

12.2.Persistence and degradability

Biologically degradable in plants and soil

12.3. Capacity for bioaccumulation

Significant effects or critical values are unknown

12.4.Mobility in the soil

Nitrate-ions are mobile and ammonium-ions are adsorbed by soil particles. Phosphate
is merely transported over short distances in the soil and are afterwards immobilized.
The mobility of Potassium-ions is low due to adsorption by soil particles. Dissolved
Magnesium-ions are adsorbed by clay particles in the soil.
Leaching of nutrients into the soil occurs in the absence of clay particles.

12.5. Evaluation results for persistence, bioaccumulation and toxicity (PBT) and high
persistence and high bioaccumulation
PBT: Not applicable. Inorganic salt
vPvB: Not applicable. Inorganic salt

12.6 Other adverse effects: Significant effects or critical values are

unknown.

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 TRIFERTO Belgium N.V.
Material Safety Data Sheet In accordance with (EC) No. 1907/2006 (Reach)
(EG) No. 1272/2008 en (EG) 453/2010

Solferto NPK 15-10-25 + 3 MgO +B

ARTICLE 13. Instructions for removal

13.1. Removal methods
The generation of waste should be avoided or minimal wherever possible.
Significant quantities of waste product residues should not be disposed of via the foul
sewer but processed in a suitable effluent treatment plant. Dispose of surplus and non-
recyclable products via a licensed waste disposal contractor. Disposal of this product,
solutions and any by-products should at all times comply with the requirements of
environmental protection and waste disposal legislation and any regional local
authority requirements.

13.2. Hazardous residuals

Ensure all waste water is collected and treated via a waste water treatment plant.
Dispose of waste product or used containers according to local regulations.

ARTICLE 14. Information regarding transport

Transport by
Transport by road Transport by Transport by
inland
and rail sea air
waterways
ADR/RID IMDG IATA
ADNR
14.1 UN number No specific regulations apply
14.2 UN description - - - -
14.3 Hazard class
- - - -
transport
14.4 Packaging
- - - -
group
14.5 Environmental
See section 12 See section 12 See section 12 See section 12
hazards
14.6 Special
Necessary caution needs to be taken into account when transporting
precautions for the
non-hazardous chemicals.
user

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 TRIFERTO Belgium N.V.
Material Safety Data Sheet In accordance with (EC) No. 1907/2006 (Reach)
(EG) No. 1272/2008 en (EG) 453/2010

Solferto NPK 15-10-25 + 3 MgO +B

According to Appendix II of Marpol73/78 agreement and IBC code.

14.7 Bulk transport
Not applicable

ARTICLE 15. Legally required information

15.1. Safety, health and environmental regulations and legislation

EU Regulations
 EC No. 1907/2006 (REACH)
 EC No. 2003/2003 of the European Parliament of the councel of 13
October 2003 relating fertilizers.

15.2. Evaluation of the chemical safety;

No chemical safety assessments has been executed

ARTICLE 16. Other information

Complete text of R phrases, which are referred to in Articles 2 and 3.
Not Classified

Complete text of classifications, which are referred to in Articles 2 and 3.

H272 – May intensify fire; oxidizer
H314 – Can cause severe skin burns and eye damage

Abbreviations and acronyms:

ATE = Acute Toxicity Estimate
CLP = Classification, Labelling and Packaging Regulation (EC No. 1272/2008)
DMEL = Derived Minimal Effect Level
DNEL = Derived No Effect Level

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 TRIFERTO Belgium N.V.
Material Safety Data Sheet In accordance with (EC) No. 1907/2006 (Reach)
(EG) No. 1272/2008 en (EG) 453/2010

Solferto NPK 15-10-25 + 3 MgO +B

EUH statement = CLP-specific Hazard statement

PBT = Persistent, Bio accumulative and Toxic
PNEC = Predicted No Effect Concentration
RRN = Reach Registration Number
vPvB = Very Persistent and Very Bio accumulative

Key literature references and sources for data:

REGULATION (EC) No. 1907/2006 OF THE EUROPEAN PARLIAMENT AND
OF THE COUNCIL OF 18 DECEMBER 2006, with successive adaptations,
amendments, and corrigenda.
REGULATION (EC) No. 1272/2006 OF THE EUROPEAN PARLIAMENT AND
OF THE COUNCIL OF 18 DECEMBER 2006, with successive adaptations,
amendments, and corrigenda
ECHA, European Chemicals Agency, Classification and Labelling Database
DIRECTIVE 2012/18/EU OF THE EUROPEAN PARLIAMENT AND OF THE
COUNCIL OF 4 JULY 2012
European Agreement concerning the International Carriage of Dangerous
Goods by Road (ADR), latest revision
Directive 2008/68/EC of the European Parliament and of Council of 24
September 2008 on the inland transport of dangerous goods, with successive
amendments.
REGULATION (EC) No. 2003/2003 OF THE EUROPEAN PARLIAMENT AND
OF THE COUNCIL OF 13 OCTOBER 2003 RELATING TO FERTILIZESERS,
with successive adaptations, amendments, and corrigenda.
American Conference of Governmental Industrial Hygienists, Threshold Limit
Values for Chemical Substances, latest edition.
Corrosion Data Survey, Sixth Edition, 1985, National Association of Corrosion
Engineers.
ERG 2012 Emergency Response Guidebook
IARC Monographs on the Evaluation of Carcinogenic Risks to Humans

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 TRIFERTO Belgium N.V.
Material Safety Data Sheet In accordance with (EC) No. 1907/2006 (Reach)
(EG) No. 1272/2008 en (EG) 453/2010

Solferto NPK 15-10-25 + 3 MgO +B

The Fertilizer Institute, Toxicity Testing Results, March 2003 Substance

Information Exchange Forum Database.
Substance Information Exchange Forum Database.

All information that is issued by or on behalf of Triferto in relation to properties,

specifications, applications, etc of the product is based on research, including
literature research and is considered to be reliable.

Triferto cannot, however, be held responsible for neither the functioning or the results
obtained through the use of the products or the relevant information, nor any damage
that may arise due to or to the products or the information.

In this respect the user is obliged to check the quality and all other properties of the
product.
The buyer accepts all responsibilities that are associated with the use of the product
and information.

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